Chem101 General Chemistry. Lecture 11 Unsaturated Hydrocarbons
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1 hem101 General hemistry Lecture 11 Unsaturated ydrocarbons
2 Unsaturated ydrocarbons ontain one or more double or triple carbon-carbon bond. University of Wisconsin-Eau laire hem101 - Lecture 11 2
3 Unsaturated ydrocarbons There are three classes of unsaturated hydrocarbons: - Alkenes have at least one carbon-carbon double bond ethylene University of Wisconsin-Eau laire hem101 - Lecture 11 3
4 Unsaturated ydrocarbons There are three classes of unsaturated hydrocarbons: - Alkynes have at least one carbon-carbon triple bond acetylene (common name) University of Wisconsin-Eau laire hem101 - Lecture 11 4
5 Unsaturated ydrocarbons University of Wisconsin-Eau laire hem101 - Lecture 11 5
6 Unsaturated ydrocarbons There are three classes of unsaturated hydrocarbons: - Aromatics are rings with alternating double and single bonds. University of Wisconsin-Eau laire hem101 - Lecture 11 5
7 Unsaturated ydrocarbons There are three classes of unsaturated hydrocarbons: - Aromatics are rings with alternating double and single bonds. benzene University of Wisconsin-Eau laire hem101 - Lecture 11 5
8 Unsaturated ydrocarbons There are three classes of unsaturated hydrocarbons: - Aromatics are rings with alternating double and single bonds. benzene University of Wisconsin-Eau laire hem101 - Lecture 11 5
9 Nomenclature of Alkenes Nomenclature means a systematic set of names. The presence of double bonds means that there is even a greater number of possible isomers than for alkanes. We will use the IUPA system for naming alkenes and alkynes. University of Wisconsin-Eau laire hem101 - Lecture 11 6
10 Nomenclature of Alkenes IUPA Rules: 1 ount the carbons in the longest chain that contains the double bond to determine the root name, 2 Use the ending -ene to designate the presence of a double bond. 3 Number the longest chain so that the carbons participating in the double bond have the lowest possible number. 4 In the prefix, locate the double bond by using the lower of the two carbon numbers. University of Wisconsin-Eau laire hem101 - Lecture 11 7
11 Nomenclature of Alkenes IUPA Rules (con d): 5 Also in the prefix, identify and locate any substituent groups that are attached to the longest chain containing the double bond. 6 ombine the prefix, root and ending names for the attached groups and the longest chain into the complete name. 7 If the molecule contains more than one double bond, the prefixes di-, tri-, tetra before the -ene ending. University of Wisconsin-Eau laire hem101 - Lecture 11 8
12 Exercise 12.1(p388) Select the compounds that can be correctly called unsaturated and classify each one as an alkene or an alkyne: a b. c. 3 d. 3 e. 3 2 f. University of Wisconsin-Eau laire hem101 - Lecture 11 9
13 Exercise 12.3 (p388) Give the IUPA name for the following compounds: a b c. University of Wisconsin-Eau laire hem101 - Lecture 11 10
14 sp 2 ybridization The orbitals containing the valence electrons in alkenes also hybridize But it is done differently than for alkanes University of Wisconsin-Eau laire hem101 - Lecture 11 11
15 sp 2 ybridization The 2s orbital mixes with two of the 2p orbitals to form three sp 2 hybrid orbitals This leaves the remaining 2p orbital unhybridized. University of Wisconsin-Eau laire hem101 - Lecture 11 12
16 sp 2 ybridization The three sp 2 hybrid orbitals are oriented in the same plane and separated by 120 from one another. The unhybridized 2p orbital is oriented at right angles to the sp 2 orbitals University of Wisconsin-Eau laire hem101 - Lecture 11 13
17 sp 2 ybridization University of Wisconsin-Eau laire hem101 - Lecture 11 14
18 sp 2 ybridization The three sp 2 hybrid each form and σ bond to another atom. The 2p orbital forms a second bond to one of the three atoms. - This second bond is called π (pi) bond. University of Wisconsin-Eau laire hem101 - Lecture 11 15
19 sp 2 ybridization University of Wisconsin-Eau laire hem101 - Lecture 11 16
20 σ and π Bonds s and p atomic orbitals: University of Wisconsin-Eau laire hem101 - Lecture 11 17
21 σ and π Bonds Two half-filled s orbitals overlapping to form a σ bond: University of Wisconsin-Eau laire hem101 - Lecture 11 18
22 σ and π Bonds A half-filled s orbital overlapping with a p orbital to form a σ bond: University of Wisconsin-Eau laire hem101 - Lecture 11 19
23 σ and π Bonds A half-filled p orbital overlapping with a p orbital to form a σ bond: University of Wisconsin-Eau laire hem101 - Lecture 11 20
24 σ and π Bonds A half-filled p orbital overlapping with a p orbital to form a π bond: University of Wisconsin-Eau laire hem101 - Lecture 11 21
25 σ and π Bonds A double-bond is a combination of a σ bond and a π bond: University of Wisconsin-Eau laire hem101 - Lecture 11 22
26 σ and π Bonds A double-bond is a combination of a σ bond and a π bond: University of Wisconsin-Eau laire hem101 - Lecture 11 23
27 Geometry of Alkenes This places the two carbons, and the four other atoms that these two carbons are bonded to, all in the same plane. - The bond angles between the three bonds are all approximately 120. University of Wisconsin-Eau laire hem101 - Lecture 11 24
28 Geometry of Alkenes Unlike single bonds, there is no free rotation about double bonds. This situation can produce additional isomers. - These isomers are called geometric isomers. University of Wisconsin-Eau laire hem101 - Lecture 11 25
29 Geometry of Alkenes The following strategy can be applied to determine if a double bond is producing a pair of stereo isomers A B D - If A and B are different, and and D are different, then there is a pair of geometric isomers. University of Wisconsin-Eau laire hem101 - Lecture 11 26
30 Geometry of Alkenes An example of this is provided by 2 butene 3 3 cis-2-butene 3 - These are two different molecules. - They have different physical properties: 3 trans-2-butene Isomer Melting Point { } Boiling Point { } Density {g/ml} cis-2-butene trans-2-butene University of Wisconsin-Eau laire hem101 - Lecture 11 27
31 Geometry of Alkenes An example of this is provided by 2 butene The cis prefix is used to indicate that the hydrocarbon chain enters and leaves on the same side of the double bond. Whereas the trans prefix is used to indicate that the hydrocarbon chain enters and leaves on opposite sides of the double bond. University of Wisconsin-Eau laire hem101 - Lecture 11 28
32 Seeing: The Difference Between cis and trans. University of Wisconsin-Eau laire hem101 - Lecture 11 29
33 Physical Properties of Alkenes The physical properties of alkenes are very similar to those of alkanes. University of Wisconsin-Eau laire hem101 - Lecture 11 30
34 hemical Properties of Alkenes We learned that alkanes are fairly un reactive. - Except combustion reactions, alkanes do not undergo very many types of reactions. Alkenes can also undergo combustion reactions. In addition, unlike the carbon-carbon single bonds found in alkanes, the double bonds found in alkenes are chemically reactive. University of Wisconsin-Eau laire hem101 - Lecture 11 31
35 hemical Properties of Alkenes They are particularly susceptible to a type of reaction called the addition reaction. A B + A B Addition reactions have two reactants and one product. University of Wisconsin-Eau laire hem101 - Lecture 11 32
36 hemical Properties of Alkenes A B + A B In this reaction A and B represent two atoms or two groups of atoms that are bonded to one another by a single bond. - A and B can be the same. University of Wisconsin-Eau laire hem101 - Lecture 11 33
37 hemical Properties of Alkenes We will look at four different examples of addition reactions: - alogenation - Addition of halogens F-F, l-l, Br-Br, I-I - ydrogenation - Addition of hydrogen - - Addition of ydrogen halides -F, -l, -Br, -I - ydration - Addition of water -O University of Wisconsin-Eau laire hem101 - Lecture 11 34
38 hemical Properties of Alkenes alogenation - Addition of halogens F-F, l-l, Br-Br, I-I + Br Br Br Br alkene bromine (halogen) haloalkane - This reaction is often used to test for the presence of alkenes Bromine is brown and the alkene and haloalkane are colorless The loss of bromine s brown color is a positive test for alkenes University of Wisconsin-Eau laire hem101 - Lecture 11 35
39 hemical Properties of Alkenes ydrogenation - Addition of hydrogen - - Pt, Pd or Ni + alkene hydrogen alkane The Pt, Pd, or Ni written above the arrow indicates that this reaction is catalyzed by platinum, palladium or nickel. - This commercially important reaction is used to convert polyunsaturated vegetable oils, which are liquid, to partially hydrogenated oils, which are solids. University of Wisconsin-Eau laire hem101 - Lecture 11 36
40 hemical Properties of Alkenes Addition of ydrogen halides - -F, -l, -Br, -I l + l alkene hydrogen halide haloalkane - Because the substituents being added are different, it is possible to obtain two different products for the reaction University of Wisconsin-Eau laire hem101 - Lecture 11 37
41 hemical Properties of Alkenes Addition of ydrogen halides - -F, -l, -Br, -I Br Br bromopropane or propene hydrogen bromide Br bromopropane University of Wisconsin-Eau laire hem101 - Lecture 11 38
42 hemical Properties of Alkenes Addition of ydrogen halides - -F, -l, -Br, -I When there are two possible products, one is usually favored greatly over the other. Markovnikov s Rule can be used to predict which product will be favored: - The hydrogen will attach itself to the carbon that has the greatest number of hydrogens. - The rich get richer University of Wisconsin-Eau laire hem101 - Lecture 11 39
43 hemical Properties of Alkenes Addition of ydrogen halides - -F, -l, -Br, -I - For the previous example, 2-bromopropane will be the major product of the reaction Br bromopropane >> Br bromopropane University of Wisconsin-Eau laire hem101 - Lecture 11 40
44 hemical Properties of Alkenes ydration - Addition of water - -O 2 SO 4 + O O alkene water alcohol The 2 SO 4 above the arrow is sulfuric acid. It is used as a catalyst in the hydration reaction - This is biochemically important reaction used in the breakdown of food for obtaining energy. University of Wisconsin-Eau laire hem101 - Lecture 11 41
45 hemical Properties of Alkenes ydration - Addition of water - -O O O O fumaric acid O + O water fumarse O O OO malic acid O - fumarase is an enzyme catalyst, which is able to carry out the reaction under the mild conditions found in a living cell. - Malic acid is an α-hydroxy acid and is what makes apples sour. (The genus name for apple is Malus) University of Wisconsin-Eau laire hem101 - Lecture 11 42
46 hemical Properties of Alkenes Summary of alkene addition reactions: University of Wisconsin-Eau laire hem101 - Lecture 11 43
47 Addition Polymers A polymer is a chain of monomer units - Like beads on a string. Addition polymers are commercially very important: - Polyethylene - Polypropylene - Polystyrene - Polyvinylchloride (PV) - Polytetrafluoroethylene (Teflon) University of Wisconsin-Eau laire hem101 - Lecture 11 44
48 Addition Polymers Though important commercially, addition polymerization is not commonly used in biological systems. We will encounter other types of polymerization when we discuss proteins and nucleic acids. University of Wisconsin-Eau laire hem101 - Lecture 11 45
49 Alkynes Alkynes contain carbon-carbon triple bonds. To form a triple bond requires sp hybridization University of Wisconsin-Eau laire hem101 - Lecture 11 46
50 Alkynes University of Wisconsin-Eau laire hem101 - Lecture 11 47
51 Alkynes University of Wisconsin-Eau laire hem101 - Lecture 11 48
52 Alkynes Alkynes are very reactive and therefore not found in biological system. An example of an alkyne is acetylene, which is used in oxy-acetylene welding torches. acetylene The IUPA system for naming alkynes is the same as for alkenes, but uses the -yne ending. The IUPA name for acetylene is ethyne. University of Wisconsin-Eau laire hem101 - Lecture 11 49
53 Aromatic compounds Often are very fragrant, hence the name aromatic. It was discovered that these compounds are highly unsaturated hydrocarbons. owever, there low reactivity is more like that of alkanes, rather than alkenes or alkynes. Benzene, which is representative of the aromatic compounds, has a molecular formula of 6 6. University of Wisconsin-Eau laire hem101 - Lecture 11 50
54 Aromatic compounds Friedrich Kekulé proposed a structure for benzene in e proposed a rich structure with alternating double and single bonds. KekulŽ Structures for Benzene University of Wisconsin-Eau laire hem101 - Lecture 11 51
55 Aromatic compounds Friedrich Kekulé proposed a structure for benzene in e proposed a rich structure with alternating double and single bonds. KekulŽ Structures for Benzene University of Wisconsin-Eau laire hem101 - Lecture 11 51
56 Aromatic compounds All of the carbons in the benzene ring are sp 2 hybridized. It is now recognized that the electrons in the unhybridized p orbitals can travel completely around the ring. - They are said to be delocalized. University of Wisconsin-Eau laire hem101 - Lecture 11 52
57 Aromatic ompounds The electrons in the p orbitals are delocalized around the ring: University of Wisconsin-Eau laire hem101 - Lecture 11 53
58 Aromatic ompounds When drawing structures that contain aromatic rings, we emphasize the delocalization by representing the π-bonds by a circle: University of Wisconsin-Eau laire hem101 - Lecture 11 54
59 Aromatic ompounds University of Wisconsin-Eau laire hem101 - Lecture 11 55
60 Aromatic ompounds University of Wisconsin-Eau laire hem101 - Lecture 11 56
61 Aromatic ompounds IUPA names - When a single hydrogen is replaced the compounds is named as a derivative of benzene. Br 2 3 Bromobenzene Ethylbenzene University of Wisconsin-Eau laire hem101 - Lecture 11 57
62 Aromatic ompounds ommon names - Some aromatic compounds have common names that have stuck: 3 O Toluene Phenol Note: Eventhough the hydrogens and carbons are not shown, it is understood that they are present. University of Wisconsin-Eau laire hem101 - Lecture 11 58
63 Aromatic ompounds The physical properties of aromatic compounds are similar to other hydrocarbons. The chemical properties of aromatic compounds are more similar to those of the alkanes than to the alkenes. - This is because the delocalization of the p orbital electrons make the double bonds in aromatic compounds more resistant to addition reactions than the double bonds in alkenes University of Wisconsin-Eau laire hem101 - Lecture 11 59
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