Supplementary Figure S1 a, wireframe view of the crystal structure of compound 11. b, view of the pyridinium sites. c, crystal packing of compound
|
|
- Stella Cobb
- 5 years ago
- Views:
Transcription
1 a b c Supplementary Figure S1 a, wireframe view of the crystal structure of compound 11. b, view of the pyridinium sites. c, crystal packing of compound 11. 1
2 a b c Supplementary Figure S2 a, wireframe view of the crystal structure of compound 12. b, schematic view of the position of the pyridinium cations. c, crystal packing showing the fixed parts of the structure corresponding to the octahedral core, green, and the mobile parts corresponding to the octyl chains and pyridinium, red. 2
3 a b c d Supplementary Figure S3 1 H-NMR spectra in DMF d 7. a, cage 1 (purple), b, calix[4]arene 7 and pyridine (4 equiv, green), c, compound 7 and uranyl nitrate (1.33 equiv, red), d, compound 7 alone (blue). In all cases compound 7 was at 6 mm concentration. 3
4 a b c 4
5 d Supplementary Figure S4 DOSY-NMR spectra in DMF d 7 at 300 K. a, compound 7, b, compound 7 and uranyl nitrate (1.33 equiv), c, calix[4]arene 7 and pyridine (4 equiv), d, cage 1. In all cases compound 7 was at 6 mm concentration. 5
6 a b c d a b c d Supplementary Figure S5 1 H-NMR full spectra (top) and zoom (bottom) in DMF d 7. a, cage 2 (purple), b, calix[5]arene 8 and pyridine (5 equiv, green), c, compound 8 and uranyl nitrate (1.7 equiv, red), d, compound 8 alone (blue). In all cases calix[5]arene 8 was at 12 mm concentration. 6
7 a b c 7
8 d Supplementary Figure S6 DOSY-NMR spectra in DMF d 7 at 300 K. a, compound 8, b, calix[5]arene 8 and uranyl nitrate (1.7 equiv), c, calix[5]arene 8 and pyridine (5 equiv) and d, cage 2. In all cases compound 8 was at 12mM concentration. 8
9 Supplementary Figure S7 1 H-NMR spectrum of cage 11 in DMF d 7. Component 9 is at 16 mm concentration. Signals at 7.46 and 1.20 ppm correspond to ligand 9, whereas signals at 8.35 and 2.22 ppm correspond to cage 11. 9
10 Supplementary Figure S8 DOSY NMR spectrum of cage 11 in DMF d 7 at 300 K. Ligand 9 was at 6 mm concentration. 10
11 Supplementary Figure S9 1 H-NMR spectrum of cage 12 in 1:1 DMF d 7 :TCE d 2. Ligand 10 is at 19 mm concentration. Signals at 7.38 and 1.95 ppm correspond to ligand 10, whereas signals at 8.25 and 2.22 ppm correspond to cage
12 Supplementary Figure S10 DOSY NMR experiment of cage 12 in 1:1 DMF d 7 :TCE d 2 at 300 K. Compound 10 was at 19 mm concentration. 12
13 Supplementary Figure S11 DLS experiments in DMF at 293 K. Composition of DLS spectra of cage 1 (red line), 2 (green line), 11 (blue line) and 12 (black line). 13
14 Supplementary Figure S12. Ortep drawing of cage 1. (Ellipsoids are drawn at 50% probability. Carbon: black, Oxygen: red, Uranium: green). 14
15 Supplementary Figure S13. Ortep drawing of cage 1 with cyclen. (Ellipsoids are drawn at 50% probability. Carbon: black, Nitrogen: blue, Oxygen: red, Uranium: green). 15
16 Supplementary Figure S14. Ortep drawing of cage 2. (Ellipsoids are drawn at 50% probability. Carbon: black, Oxygen: red, Uranium: green). 16
17 Supplementary Figure S15. Ortep drawing of cage 11. (Ellipsoids are drawn at 50% probability. Carbon: black, Oxygen: red, Uranium: green). 17
18 Supplementary Figure S16. Ortep drawing of cage 12. (Ellipsoids are drawn at 50% probability. Carbon: black, Oxygen: red, Uranium: green). 18
19 a b c Supplementary Figure S17. NMR and HRMS spectra of compound 6: a, 1 H-NMR spectrum in d 6 -DMSO, b, 13 C- NMR spectrum in d 6 -DMSO, c, ESI-HRMS. 19
20 a b c Supplementary Figure S18. NMR and HRMS spectra of compound 8: a, 1 H-NMR spectrum in d 6 -DMSO, b, 13 C- NMR spectrum in d 6 -DMSO, c, MALDI-HRMS. 20
21 Cage [ligand] [UO 2+ 2 ] (mm) (mm) I cage I ligand K app (mm -13 ) x x x Supplementary Table S1. Apparent constants of formation of cages 1, 11 and 12 calculated from the equation reported above. 1 H-NMR spectra were measured in DMF d 7 at 300 K. Cage [ligand] mm [UO 2 2+ ] mm I cage I ligand K app (mm -31 ) x Supplementary Table S2. Stability constants for cage 2 calculated from the equation reported above. 1 H-NMR spectrum was measured in DMF d 7 at 300 K. 21
22 Supplementary methods Procedures 25,26,27,28-Tetrahydroxycalix[4]arene-5,11,17,23-tetracarboxylic acid (7) To a stirred mixture of tetraformylcalix[4]arene (5) (381 mg, mmol) in DMSO (7.1 ml) and sodium dihydrogen phosphate (85 mg, mmol) in 1 ml of water, a solution of sodium chlorite (642 mg, 5.68 mmol) in 6 ml of water was added drop-wise over 3h at room temperature. After stirring overnight at room temperature, the reaction mixture was acidified with 5M aq. HCl and the solid formed was filtered, washed with water and dried to obtain compound 7 as a light yellow solid (368 mg, 86%). 1 H-NMR (400 MHz, dimethylsulphoxide-d 6 (DMSO-d 6 ), 398K) δ 7.64 (s, 8H, CH), 3.91 (s, 8H, CH 2 ). 13 C- NMR (100 MHz, DMSO-d 6 ) δ (C quat -OH), (COOH), (CH), (C- CH 2 ), (C-COOH). HRMS (m/z): [M - ] calcd. for C 32 H 23 O ; found Characterisation of cages in the solid state Single crystal X-ray diffraction data of 1. The measured crystal was removed from the mixture, placed on a slide and quickly covered with vacuum grease and Paratone-N as protecting oil. Afterwards, it was scooped with a Cryoloop and mounted on the goniometer head. Single crystal X-ray diffraction data of 1 were collected on a Bruker Kappa APEX II DUO diffractometer equipped with an APPEX 2 4K CCD area detector, a Microsource with Cu Kα radiation and an Oxford Cryostream 700 low temperature device (T = -173 C). Full-sphere data collection was used with ω and ϕ scans. Programs used: Data collection Apex2 V (Bruker- Nonius 2008), data reduction Saint + Version 7.60A (Bruker AXS 2008) and absorption correction SADABS V (2008). The structure solution and refinement were carried out using SHELXTL V
23 Crystallographic data at 100(2) K: C 96 H 60 O 59 U 4, Mr = gmol -1, Crystal dimensions: 0.20 x 0.15 x 0.15 mm 3, cubic, space group: Fm-3m, a = b = c = (2) Å, V = 38281(4) Å 3, Z = 8, ρ calc = Mg/m 3, R 1 = (0.1207), wr 2 = (0.3773), for 621 reflections with I>2σ(I) (for 683 reflections [R int : ] ) with a total of reflections measured, 2θ=81.84º, 77 parameters and 130 restrains. CCDC deposit number Residual electron densities in the solvent-accessible void, due to disordered solvent molecules as well as counterions, were treated with the PLATON SQUEEZE program 47 Before this treatment the maximum remained electron density was 6.37, R 1 = and wr 2 = for all data with 529 unique reflections out of 683 with I > 2σ(I). The asymmetric unit is made up of 1/8 of a calix[4]arene molecule, 1/6 of a uranyl cation unit and three water molecules with occupancy of ¼, ¼ and 1/8. Two of them lie on a 48i Wyckoff site and one in the 24e becoming a full water molecule in the unit cell. Anisotropic displacements of the calix[4]arene were restrained and water molecules were also restrained so they approximated to isotropic behaviour. Hydrogen atom positions of all water molecules were neither located nor calculated. Single crystal X-ray diffraction data of 1 with cyclen. The measured crystal was removed from the mixture, placed on a slide and quickly covered with vacuum grease and Paratone-N as protecting oil. Afterwards, it was scooped with a Cryoloop and mounted on the goniometer head. Single crystal X-ray diffraction data were collected on a Bruker Kappa APEX II DUO diffractometer equipped with an APPEX 2 4K CCD area detector, a Microsource with Mo Kα radiation and an Oxford Cryostream 700 low temperature device (T = -173 C). Full-sphere data collection was used with ω and ϕ scans. Programs used: Data collection, Apex2 V (Bruker- Nonius 2008), data reduction, Saint + Version 7.60A (Bruker AXS 2008) and absorption correction, SADABS V (2008). Structure solution and refinement were carried out using SHELXTL V Crystallographic data at 100(2) K: C 208 H 168 N 8 O 96 U 8, Mr = gmol -1, Crystal dimensions: 0.10 x 0.05 x 0.05 mm 3, tetragonal, space group: I4/m, a = b = (3) Å, c = (3) Å, V = 16614(3) Å 3, Z = 2, ρ calc = Mg/m 3, R 1 = (0.1187), wr 2 = (0.2186), for 3943 reflections with I>2σ(I) (for 6864 reflections [R int = ] ) 23
24 with a total of reflections measured, 2θ=48.58º, 538 parameters and 1097 restrains. CCDC deposit number Residual electron densities in the solvent-accessible void due to disordered solvent molecules were treated with the PLATON SQUEEZE program 47 Before the treatment of SQUEEZE program the maximum remained electron density was 2.11, R 1 = and wr 2 = for all data with 3844 unique reflections out of 6864 with I > 2σ(I). The asymmetric unit is made up of ¾ of a calix[4]arene molecule, one uranyl cation unit, ¼ of cyclen molecule and one water molecule. The ¾ of the calix[4]arene molecule was distributed in two calix[4]arene molecules in which ¼ and ½ are present in the asymmetric unit. The uranyl cation unit is disordered over two positions with 50% occupancy in each site and the anisotropic displacement parameters were restrained. As a result, the ¼ of the calix[4]arene molecule was disordered over two positions (50:50) and one of the carboxylates groups of the other molecule is also disordered over two positions (50:50). Anisotropic displacements of the calix[4]arene were restrained. The cyclen molecule is distributed over two positions in which only 1/8 of the molecule is present. Distances of the nitrogen and carbon atoms were restrained as well as anisotropic displacement parameters. Two of the water molecules lie in a 4e and 8h Wyckoff sites and the remaining water molecule occupancy has been fixed to 25% of occupancy. Hydrogen atom positions of all water molecules were neither located nor calculated. Single crystal X-ray diffraction data of 2. The measured crystal was removed from the mixture, placed on a slide and quickly covered with vacuum grease and Paratone-N as protecting oil. Afterwards, it was scooped with a Cryoloop and mounted on the goniometer head. Single crystal X-ray diffraction data were collected on a Bruker Kappa APEX II DUO diffractometer equipped with an APPEX 2 4K CCD area detector, a Microsource with Mo Kα radiation and an Oxford Cryostream 700 low temperature device (T = -173 C). Full-sphere data collection was used with ω and ϕ scans. Programs used: Data collection Apex2 V (Bruker- Nonius 2008), data reduction Saint + Version 7.60A (Bruker AXS 2008) and absorption correction SADABS V (2008). Structure solution and refinement were carried out using SIR and SHELXTL V , respectively. 24
25 Crystallographic data at 100(2) K: C 490 H 312 N 1 O 232 U 20, Mr = gmol -1, crystal dimensions: 0.10 x 0.10 x 0.10 mm 3, orthorhombic, space group: Cmca, a = (4) Å, b = (4) Å, c = (4) Å, V = (17) Å 3, Z = 4, ρ calc = Mg/m 3, R 1 = (0.2319), wr 2 = (0.4379), for reflections with I>2σ(I) (for reflections [R int : ] ) with a total of reflections measured, 2θ=35.5º, 1726 parameters and 1614 restrains. CCDC deposit number The asymmetric unit contains three calix[5]arene molecules and five uranyl units over six positions, two of them lying on a 8f Wickoff site. Half pyridinium molecule was located as well as five water positions. The distances within the pyridinium molecule were constrained. Anisotropic displacements of the calix[5]arene molecules were restrained and water and pyridinium molecules were restrained so they approximate to isotropic behaviour. Hydrogen atom positions of all water molecules were neither located nor calculated. Accessible void remains in the structure since a jumble of residual peak could not be modelled with chemical sense. Single crystal X-ray diffraction data of 11. The measured crystal was removed from the solution, placed on a slide and quickly covered with vacuum grease and Paratone-N as protecting oil. Afterwards, it was scooped with a Cryoloop and mounted on the goniometer head. Single crystal X-ray diffraction data of 11 were collected on a Bruker-Nonius diffractometer equipped with an APPEX 2 4K CCD area detector, a FR591 rotating anode with Mo Kα radiation, Montel mirrors and an Oxford Cryostream 700 low temperature device (T = -173 C). Full-sphere data collection was used with ω and ϕ scans. Programs used: Data collection Apex2 V (Bruker-Nonius 2008), data reduction Saint + Version 7.60A (Bruker AXS 2008) and absorption correction SADABS V (2008). Structure solution and Refinement were carried out using SIR and SHELXTL V , respectively. Crystallographic data at 100(2) K: C 278 H 279 N 3 O 88 U 8, Mr = gmol -1, Crystal dimensions: 0.10 x 0.02 x 0.02 mm 3, orthorhombic, space group: Ibam, a = (13) Å, b = (2) Å, c = (19) Å, V = 41310(4) Å 3, Z = 4, ρ calc = Mg/m 3, R 1 = (0.2838), wr 2 = (0.4272), for 7947 reflections with I>2σ(I) (for reflections [R int : ] ) with a total of reflections measured, 2θ=48.74º,
26 parameters and 1489 restrains. CCDC deposit number Residual electron densities in the solvent-accessible void due to disordered solvent molecules as well as counterions were treated with the PLATON SQUEEZE program 47. Before the treatment of SQUEEZE program the remaining maximum electron density was 18.37, R 1 = and wr 2 = for all data with 7947 unique reflections out of with I > 2σ(I). The asymmetric unit is made up in total of one and a half O-propyl calix[4]arene molecule, two uranyl units, and one pyridinium over two positions. The O-propyl chains which showed disorder were modelled in two positions with 50% of occupancy in each site. Distances within O-propyl chains and pyridinium molecules were restrained as well as the anisotropic displacements of the O-propyl chains, the calix[4]arenes and pyridinium molecules. 26
27 Single crystal X-ray diffraction data of 12 The measured crystal was removed from the mixture, placed on a slide and quickly covered with vacuum grease and Paratone-N as protecting oil. Afterwards, it was scooped with a Cryoloop and mounted on the goniometer head. Single crystal X-ray diffraction data were collected on a Bruker Kappa APEX II DUO diffractometer equipped with an APPEX 2 4K CCD area detector, a Microsource with Mo Kα radiation and an Oxford Cryostream 700 low temperature device (T = -173 C). Full-sphere data collection was used with ω and ϕ scans. Programs used: Data collection Apex2 V (Bruker- Nonius 2008), data reduction, Saint + Version 7.60A (Bruker AXS 2008) and absorption correction, SADABS V (2008). Structure solution and Refinement were carried out using SHELXTL V Crystallographic data at 100(2) K: C 424 H 544 N 8 O 94 U 8, Mr = gmol -1, Crystal dimensions: 0.20 x 0.10 x 0.10 mm 3, tetragonal, space group: I4 1 /a, a = b = (3) Å, c = (4) Å, V = 46592(8) Å 3, Z = 4, ρ calc = Mg/m 3, R 1 = (0.2791), wr 2 = (0.4319), for 6630 reflections with I>2σ(I) (for reflections [R int : ]) with a total of reflections measured, 2θ=43.32º, 1212 parameters and 1638 restrains. CCDC deposit number The capsule in asymmetric unit is made up of one and a half O-octyl calix[4]arene molecules and two uranyl units. One of the uranyl units was disordered over two positions with a 50% of occupancy in each site. Consequently, the two carboxylate groups coordinated to the uranyl cation were also disordered (50:50). Distances of the oxygen and carbon atoms in the O-octyl chains were restrained. Moreover, distances between atoms of the neighbouring O-octyl were been restrained to fulfil the minimum required distances between neighbouring atoms. Anisotropic displacements of the O-octyl chains and the calix[4]arenes were restrained. The charges were balanced by two pyridinium molecules, one of them disordered over two sites (75:25). Anisotropic displacements were restrained. Two water molecules were also present in the asymmetric unit, one of them lying in a 8e Wyckoff site and the hydrogen atom positions were neither located nor calculated. 27
28 Characterisation of cages in solution DOSY NMR diffusion coefficients, calculated on the basis of monodimensional fitting and expressed in cm 2 /s are: 7 (3.50 E-06), DMF-d 7 ((1.45 ± 0.07) E-05) 7 and uranyl nitrate (1.33 eq) (3.40 E-06), DMF-d 7 ((1.44 ± 0.07) E-05) 7 and pyridine (4 eq) (3.51 E-06), DMF-d 7 ((1.45 ± 0.05) E-05) Cage 1 ((1.76 ± 0.05) E-06), free ligand 7 (3.26 E-06), DMF-d 7 ((1.4 ± 0.1) E-05) DOSY NMR diffusion coefficients, calculated on the basis of monodimensional fitting and expressed in cm 2 /s are: 8 ((3.02 ± 0.01) E-06), DMF-d 7 ((1.46 ± 0.01) E-05) 8 and uranyl nitrate (1.7 eq) ((2.75 ± 0.02) E-06), DMF-d 7 ((1.36 ± 0.02) E-05) 8 and pyridine (5 eq) ((2.99 ± 0.01) E-06), DMF-d 7 ((1.46 ± 0.03) E-05) Cage 2 ((1.5 ± 0.3) E-06), free ligand 8 ((2.3 ± 0.2) E-06), DMF-d 7 ((1.3 ± 0.2) E- 05). DOSY NMR diffusion coefficients, calculated on the basis of monodimensional fitting and expressed in cm 2 /s are: cage 11 ((1.76 ± 0.09) E-06), 9 ((3.09 ± 0.07) E-06), DMF-d 7 ((1.4 ± 0.1) E-05). DOSY NMR diffusion coefficients, calculated on the basis of monodimensional fitting and expressed in cm 2 /s, are: Cage 12 ((6.7 ± 0.2) E-07), 10 ((1.259 ± 0.009) E-06), DMF d 7 ((6.68 ± 0.02) E-06), TCE d 2 (5.46 E-06). 28
29 Dynamic Light Scattering (DLS) Solutions in DMF of mixture of components forming the cages were analyzed by a Dynamic Light Scattering instrument. Corrections were carried out only for the solvent (refractive index and viscosity). Calix[4]arene 7 (17 mm concentration), uranyl nitrate (1.33 equiv) and pyridine (4 equiv) Calix[5]arene 8 (10 mm concentration), uranyl nitrate (1.7 equiv) and pyridine (5 equiv) Calix[4]arene 9 (13 mm concentration), uranyl nitrate (1.33 equiv) and pyridine (4 equiv) Calix[4]arene 10 (13 mm concentration), uranyl nitrate (1.33 equiv) and pyridine (4 equiv) Average hydrodynamic radii observed: 1: ± nm 2: ± nm 11: ± nm 12: ± nm. Stability constants The equilibrium for the octahedral cages can be expressed by the following equation: UO 2 (NO 3 ) 6H 2 O + 24Py Cage Py-H NO H 2 O Assuming that the deprotonation of calixarene 7 is quantitative and the uranyl nitrate is completely dissociated, we can neglect in the equilibrium the species Py, Py-H +, NO
30 The apparent overall formation constants of octahedral cages 1, 11 and 12 can be calculated as follows from the relative areas of the aromatic CH peaks (ligand and cage) in the corresponding NMR spectra (equation illustrated for cage 1): K app = [Cage 1]/ {[7] 6 [UO 2+ 2 ] 8 eq } [Cage 1] and [7] at equilibrium can be calculated by integration of the corresponding proton signals in the 1 H-NMR spectrum. On the other hand, [UO 2+ 2 ] eq can be obtained by subtracting eight equivalents of cage from the initial concentration of uranyl nitrate [UO 2+ 2 ]. K app = [Cage 1]/ {[7] 6 ([UO 2+ 2 ] -8 [Cage 1]) 8 } The equilibrium for the icosahedral cages can be expressed by the following equation: UO 2 (NO 3 ) 2 6H 2 O + 60Py Cage Py-H NO H 2 O The apparent overall constant of formation of the icosahedral cage 2 can be calculated by the following equation, after assuming the same approximations done in the previous case: K app = [Cage 2] / {[8] 12 x [UO 2 ] 20 eq } [Cage 2] and [8] at the equilibrium can be calculated by integration of the corresponding proton signals in the 1 H-NMR. Instead, [UO 2+ 2 ] eq can be obtained by subtracting twenty equivalents of cage from the initial concentration of uranyl nitrate [UO 2+ 2 ]. K app = [Cage 2] / {[8] 12 x ([UO 2+ 2 ] 20 x [Cage 2]) 20 } 30
31 Supplementary references 46 Sheldrix, G. M. SHELXTL Crystallographic System Ver 6.14, Bruker AXS Inc., Madison, Wisconsin, Spek, A. L. Acta Crystallogr., Sect. A: Fundam. Crystallogr., 46, C34 (1990). 48 Caliandro, R. et al. Advances in ab initio protein phasing by Patterson deconvolution techniques. J. Appl. Cryst. 40, (2008). 31
Spain c Departament de Química Orgànica, Universitat de Barcelona, c/ Martí I Franqués 1-11, 08080, Barcelona, Spain.
a Institute of Chemical Research of Catalonia, Av. Països Catalans, 16, 43007 Tarragona, Spain. b Departament de Química, Universitat Autònoma de Barcelona, Cerdanyola del Vallès, E-08193 Barcelona, Spain
More informationWhite Phosphorus is Air-Stable Within a Self-Assembled Tetrahedral Capsule
www.sciencemag.org/cgi/content/full/324/5935/1697/dc1 Supporting Online Material for White Phosphorus is Air-Stable Within a Self-Assembled Tetrahedral Capsule Prasenjit Mal, Boris Breiner, Kari Rissanen,
More informationion, as obtained from a search of the Cambridge Structural database (CSD), December 2013.
Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2014 SI Figure S1. The reported bridging modes of the CO 3 2- ion, as obtained from a
More informationManganese-Calcium Clusters Supported by Calixarenes
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2014 Manganese-Calcium Clusters Supported by Calixarenes Rebecca O. Fuller, George A. Koutsantonis*,
More informationElectronic Supplementary Information (ESI)
Electronic Supplementary Information (ESI) S1 Experimental Section: Materials and methods: All commercially available chemicals were used as supplied without further purification. The Q[5] was synthesized
More informationSupporting Information
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2015 Supporting Information Single-Crystal-to-Single-Crystal Transformation of an Anion Exchangeable
More informationmetal-organic compounds
metal-organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 Poly[tetra-l-cyanido-dipyridinecadmium(II)zinc(II)] Sheng Li,* Kun Tang and Fu-Li Zhang College of Medicine,
More informationSupporting Information
Supporting Information Wiley-VCH 2007 69451 Weinheim, Germany Carbene Activation of P 4 and Subsequent Derivatization Jason D. Masuda, Wolfgang W. Schoeller, Bruno Donnadieu, and Guy Bertrand * [*] Dr.
More informationReversible dioxygen binding on asymmetric dinuclear rhodium centres
Electronic Supporting Information for Reversible dioxygen binding on asymmetric dinuclear rhodium centres Takayuki Nakajima,* Miyuki Sakamoto, Sachi Kurai, Bunsho Kure, Tomoaki Tanase* Department of Chemistry,
More informationSUPPLEMENTARY INFORMATION
Supplementary Information SUPPLEMENTARY INFORMATION Networked molecular cages as crystalline sponges for fullerenes and other guests Yasuhide Inokuma, Tatsuhiko Arai and Makoto Fujita Contents 1. Materials
More information1,4-Dihydropyridyl Complexes of Magnesium: Synthesis by Pyridine. Insertion into the Magnesium-Silicon Bond of Triphenylsilyls and
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2018 Electronic Supporting Information 1,4-Dihydropyridyl Complexes of Magnesium: Synthesis
More informationSelective total encapsulation of the sulfate anion by neutral nano-jars
Supporting Information for Selective total encapsulation of the sulfate anion by neutral nano-jars Isurika R. Fernando, Stuart A. Surmann, Alexander A. Urech, Alexander M. Poulsen and Gellert Mezei* Department
More informationSupporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Information A cage-based cationic body-centered tetragonal metal-organic framework:
More informationIron Complexes of a Bidentate Picolyl NHC Ligand: Synthesis, Structure and Reactivity
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2016 Supplementary Information for Iron Complexes of a Bidentate Picolyl HC Ligand: Synthesis,
More informationElectronic Supplementary Information for: Gram-scale Synthesis of a Bench-Stable 5,5 -Unsubstituted Terpyrrole
Electronic Supplementary Information for: Gram-scale Synthesis of a Bench-Stable 5,5 -Unsubstituted Terpyrrole James T. Brewster II, a Hadiqa Zafar, a Matthew McVeigh, a Christopher D. Wight, a Gonzalo
More informationmetal-organic compounds
metal-organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 Tetraaquabis(nicotinamide-jN 1 )nickel(ii) bis(2-fluorobenzoate) Tuncer Hökelek, a * Hakan Dal, b Barış
More informationStabilization of a Reactive Polynuclear Silver Carbide Cluster through the Encapsulation within Supramolecular Cage
Supporting Information Stabilization of a Reactive Polynuclear Silver Carbide Cluster through the Encapsulation within Supramolecular Cage Cai-Yan Gao, Liang Zhao,* and Mei-Xiang Wang* The Key Laboratory
More informationAll materials and reagents were obtained commercially and used without further
Reversible shrinkage and expansion of a blue photofluorescene cadmium coordination polymer and in situ tetrazole ligand synthesis Hong Deng,* a Yong-Cai Qiu, a Ying-Hua Li, a Zhi-Hui liu, a Rong-Hua Zeng,
More informationSupporting Information
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2016 Supporting Information Over or under: Hydride attack at the metal versus the coordinated
More informationSupporting Information
Supporting Information Wiley-VCH 2008 69451 Weinheim, Germany Supporting Information Quantitative evaluation of anion-π interactions in solution Guzmán Gil-Ramirez, a Eduardo C. Escudero-Adan, a Jordi
More informationOrthorhombic, Pbca a = (3) Å b = (15) Å c = (4) Å V = (9) Å 3. Data collection. Refinement
organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 N 0 -(3,4-Dimethylbenzylidene)furan-2- carbohydrazide Yu-Feng Li a and Fang-Fang Jian b * a Microscale Science
More informationSupporting Information
Supporting Information Tris(allyl)indium Compounds: Synthesis and Structural Characterization Ilja Peckermann, Gerhard Raabe, Thomas P. Spaniol and Jun Okuda* Synthesis and characterization Figure S1:
More informationelectronic reprint 2-Hydroxy-3-methoxybenzaldehyde (o-vanillin) revisited David Shin and Peter Müller
Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 Editors: W.T. A. Harrison, H. Stoeckli-Evans, E. R.T. Tiekink and M. Weil 2-Hydroxy-3-methoxybenzaldehyde (o-vanillin) revisited
More informationHydrophobic Ionic Liquids with Strongly Coordinating Anions
Supporting material Hydrophobic Ionic Liquids with Strongly Coordinating Anions Hasan Mehdi, Koen Binnemans*, Kristof Van Hecke, Luc Van Meervelt, Peter Nockemann* Experimental details: General techniques.
More informationSupporting Information
Supporting Information Dative Boron-Nitrogen Bonds in Structural Supramolecular Chemistry: Multicomponent Assembly of Prismatic Organic Cages Burcak Icli, Erin Sheepwash, Thomas Riis-Johannessen, Kurt
More information(1) Single Crystal XRD Data of 6b and 6c 2-3
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Synthesis of anti- 2, 3-dihydro-1, 2, 3-trisubstituted-1H-naphth [1, 2-e][1, 3] oxazine derivatives
More informationHassan Osseili, Debabrata Mukherjee, Klaus Beckerle, Thomas P. Spaniol, and Jun Okuda*
Supporting Information Me6TREN-Supported Alkali Metal Hydridotriphenylborates [(L)M][HBPh3] (M = Li, Na, K): Synthesis, Structure, and Reactivity Hassan Osseili, Debabrata Mukherjee, Klaus Beckerle, Thomas
More informationSupplementary Information
Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics. This journal is the Owner Societies 2014 Supplementary Information Introducing Asymmetry in Tetradentate Azadipyrromethene
More informationReversible uptake of HgCl 2 in a porous coordination polymer based on the dual functions of carboxylate and thioether
Supplementary Information Reversible uptake of HgCl 2 in a porous coordination polymer based on the dual functions of carboxylate and thioether Xiao-Ping Zhou, a Zhengtao Xu,*,a Matthias Zeller, b Allen
More informationHalogen bonded dimers and ribbons from the self-assembly of 3-halobenzophenones Patricia A. A. M. Vaz, João Rocha, Artur M. S. Silva and Samuel Guieu
Electronic Supplementary Material (ES) for CrystEngComm. This journal is The Royal Society of Chemistry 27 Halogen bonded dimers and ribbons from the self-assembly of -halobenzophenones Patricia A. A.
More informationSupplementary Material (ESI) for CrystEngComm. An ideal metal-organic rhombic dodecahedron for highly efficient
Supplementary Material (ESI) for CrystEngComm An ideal metal-organic rhombic dodecahedron for highly efficient adsorption of dyes in an aqueous solution Yuan-Chun He, Jin Yang,* Wei-Qiu Kan, and Jian-Fang
More informationSupporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 205 Supporting Information Synthesis and Structures of N-Arylcyano-β-diketiminate Zinc Complexes
More informationmetal-organic compounds
metal-organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 Dichloridotris(trimethylphosphine)- nickel(ii) Ruixia Cao, Qibao Wang and Hongjian Sun* School of Chemistry
More information= (1) V = (12) Å 3 Z =4 Mo K radiation. Data collection. Refinement. R[F 2 >2(F 2 )] = wr(f 2 ) = S = reflections
organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 S-Benzylisothiouronium nitrate P. Hemalatha a and V. Veeravazhuthi b * a Department of Physics, PSG College of
More informationSupplementary Information. Single Crystal X-Ray Diffraction
Supplementary Information Single Crystal X-Ray Diffraction Single crystal diffraction data were collected on an Oxford Diffraction Gemini R Ultra diffractometer equipped with a Ruby CCD-detector with Mo-K
More informationb = (13) Å c = (13) Å = (2) V = (19) Å 3 Z =2 Data collection Refinement
organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 b = 12.4861 (13) Å c = 12.9683 (13) Å = 90.748 (2) V = 1051.10 (19) Å 3 Z =2 Mo K radiation = 3.87 mm 1 T = 193
More informationElectronic Supporting Information
Electronic Supporting Information Solid-State Coexistence of {Zr 12 } and {Zr 6 } Zirconium Oxocarboxylate Clusters Iurie L. Malaestean, Meliha Kutluca Alıcı, Claire Besson, Arkady Ellern and Paul Kögerler*
More informationFluorous Metal Organic Frameworks with Superior Adsorption and Hydrophobic Properties toward Oil Spill Cleanup and Hydrocarbon Storage
SUPPORTING INFORMATION Fluorous Metal Organic Frameworks with Superior Adsorption and Hydrophobic Properties toward Oil Spill Cleanup and Hydrocarbon Storage Chi Yang, a Ushasree Kaipa, a Qian Zhang Mather,
More informationSupporting Information
Supporting Information Selective Metal Cation Capture by Soft Anionic Metal-Organic Frameworks via Drastic Single-crystal-to-single-crystal Transformations Jian Tian, Laxmikant V. Saraf, Birgit Schwenzer,
More informationJuan Manuel Herrera, Enrique Colacio, Corine Mathonière, Duane Choquesillo-Lazarte, and Michael D. Ward. Supporting information
Cyanide-bridged tetradecanuclear Ru II 3M II 11 clusters (M II = Zn II and Cu II ) based on the high connectivity building block [Ru 3 (HAT)(CN) 12 ] 6+ : structural and photophysical properties Juan Manuel
More informationSupporting Information. for. Angew. Chem. Int. Ed Wiley-VCH 2004
Supporting Information for Angew. Chem. Int. Ed. 246736 Wiley-VCH 24 69451 Weinheim, Germany 1 Challenges in Engineering Spin Crossover. Structures and Magnetic Properties of six Alcohol Solvates of Iron(II)
More informationmetal-organic compounds
metal-organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 = 86.130 (2) = 81.155 (2) = 76.289 (3) V = 699.69 (4) Å 3 Z =2 Mo K radiation = 1.58 mm 1 T = 293 (2) K
More informationDavid L. Davies,*, 1 Charles E. Ellul, 1 Stuart A. Macgregor,*, 2 Claire L. McMullin 2 and Kuldip Singh. 1. Table of contents. General information
Experimental Supporting Information for Experimental and DFT Studies Explain Solvent Control of C-H Activation and Product Selectivity in the Rh(III)-Catalyzed Formation of eutral and Cationic Heterocycles
More informationSupporting Information. for. Advanced Functional Materials, adfm Wiley-VCH 2007
Supporting Information for Advanced Functional Materials, adfm.200601202 Wiley-VCH 2007 69451 Weinheim, Germany [Supporting Information] Optical Sensor Based on Nanomaterial for the Selective Detection
More informationElectronic Supplementary Information
Electronic Supplementary Information Thermally Reversible Single-Crystal to Single-Crystal Transformation of Mononuclear to Dinuclear Zn(II) Complexes By[2+2] Cycloaddition Reaction Raghavender Medishetty,
More informationCrystal structure analysis of N,2-diphenylacetamide
International Journal of ChemTech Research CODEN (USA): IJCRGG ISSN: 0974-4290 Vol.9, No.04 pp 301-305, 2016 Crystal structure analysis of N,2-diphenylacetamide K. Elumalai 1, Subramaniyan Sathiyaraj 2,
More informationPrabhat Gautam, Bhausaheb Dhokale, Shaikh M. Mobin and Rajneesh Misra*
Supporting Information Ferrocenyl BODIPYs: Synthesis, Structure and Properties Prabhat Gautam, Bhausaheb Dhokale, Shaikh M. Mobin and Rajneesh Misra* Department of Chemistry, Indian Institute of Technology
More informationData collection. Refinement. R[F 2 >2(F 2 )] = wr(f 2 ) = S = reflections 92 parameters
organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 1,1 0 -(Butane-1,4-diyl)dipyridinium dibromide dihydrate Ming-Qiang Wu, a Xin Xiao, a Yun-Qian Zhang, a * Sai-Feng
More informationSupporting Information. Table of Contents
Supporting Information Selective Anion Exchange and Tunable Luminescent Behaviors of Metal-Organic Framework Based Supramolecular Isomers Biplab Manna, Shweta Singh, Avishek Karmakar, Aamod V.Desai and
More informationA supramoleculear self-assembled flexible open framework based on coordination honeycomb layers possessing octahedral and tetrahedral Co II geometries
Supporting Information A supramoleculear self-assembled flexible open framework based on coordination honeycomb layers possessing octahedral and tetrahedral Co II geometries Yang Zou,* a Yuanyuan Li, a
More informationOxidation of cobalt(ii) bispidine complexes with dioxygen
10.1071/CH16674_AC CSIRO 2017 1 2 3 Australian Journal of Chemistry 2017, 70(5), 576-580 Supplementary Material Oxidation of cobalt(ii) bispidine complexes with dioxygen 4 5 6 Peter Comba *, Bianca Pokrandt
More informationNickel-Mediated Stepwise Transformation of CO to Acetaldehyde and Ethanol
Nickel-Mediated Stepwise Transformation of CO to Acetaldehyde and Ethanol Ailing Zhang, Sakthi Raje, Jianguo Liu, Xiaoyan Li, Raja Angamuthu, Chen-Ho Tung, and Wenguang Wang* School of Chemistry and Chemical
More informationThe oxide-route for the preparation of
Supporting Information for: The oxide-route for the preparation of mercury(ii) N-heterocyclic carbene complexes. Simon Pelz and Fabian Mohr* Fachbereich C-Anorganische Chemie, Bergische Universität Wuppertal,
More informationaddenda and errata [N,N 0 -Bis(4-bromobenzylidene)-2,2-dimethylpropane-j Corrigendum Reza Kia, a Hoong-Kun Fun a * and Hadi Kargar b
addenda and errata Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 [N,N 0 -Bis(4-bromobenzylidene)-2,2-dimethylpropane-j 2 N,N 0 ]iodidocopper(i). Corrigendum Reza Kia, a Hoong-Kun
More informationAn unprecedented 2D 3D metal-organic polyrotaxane. framework constructed from cadmium and flexible star-like
Electronic Supplementary Information An unprecedented 2D 3D metal-organic polyrotaxane framework constructed from cadmium and flexible star-like ligand Hua Wu, a,b Hai-Yan Liu, a Ying-Ying Liu, a Jin Yang,*
More informationSynthetic, Structural, and Mechanistic Aspects of an Amine Activation Process Mediated at a Zwitterionic Pd(II) Center
Synthetic, Structural, and Mechanistic Aspects of an Amine Activation Process Mediated at a Zwitterionic Pd(II) Center Supporting Information Connie C. Lu and Jonas C. Peters* Division of Chemistry and
More informationCu(I)-MOF: naked-eye colorimetric sensor for humidity and. formaldehyde in single-crystal-to-single-crystal fashion
Supporting Information for Cu(I)-MOF: naked-eye colorimetric sensor for humidity and formaldehyde in single-crystal-to-single-crystal fashion Yang Yu, Xiao-Meng Zhang, Jian-Ping Ma, Qi-Kui Liu, Peng Wang,
More information4-(4-Hydroxymethyl-1H-1,2,3-triazol-1-yl)benzoic acid
University of Malaya From the SelectedWorks of Hairul Anuar Bin Tajuddin 2011 4-(4-Hydroxymethyl-1H-1,2,3-triazol-1-yl)benzoic acid Hairul Anuar Bin Tajuddin, University of Malaya Available at: https://works.bepress.com/hairulanuar_tajuddin/6/
More informationStimuli-Responsive Pd 2 L 4 Metallosupramolecular Cages: Towards Targeted Cisplatin Drug Delivery.
Supporting Information Stimuli-Responsive Pd 2 L 4 Metallosupramolecular Cages: Towards Targeted Cisplatin Drug Delivery. James E. M. Lewis, a Emma L. Gavey, a Scott A. Cameron, a and James D. Crowley*
More informationScandium and Yttrium Metallocene Borohydride Complexes: Comparisons of (BH 4 ) 1 vs (BPh 4 ) 1 Coordination and Reactivity
Scandium and Yttrium Metallocene Borohydride Complexes: Comparisons of (BH 4 ) 1 vs (BPh 4 ) 1 Coordination and Reactivity Selvan Demir, Nathan A. Siladke, Joseph W. Ziller, and William J. Evans * Department
More informationSynthesis of Vinyl Germylenes
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Material for Synthesis of Vinyl Germylenes Małgorzata Walewska, Judith Baumgartner,*
More informationSupporting Information for. Hydrogen-Bond Symmetry in Difluoromaleate Monoanion
S1 Supporting Information for Hydrogen-Bond Symmetry in Difluoromaleate Monoanion Charles L. Perrin,* Phaneendrasai Karri, Curtis Moore, and Arnold L. Rheingold Department of Chemistry, University of California
More informationZ =8 Mo K radiation = 0.35 mm 1. Data collection. Refinement. R[F 2 >2(F 2 )] = wr(f 2 ) = S = reflections
organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 4-Amino-3-(4-pyridyl)-1,2,4-triazole- 5(4H)-thione Fang Zou, Wei-Min Xuan, Xue-Ming Fang and Hui Zhang* State
More information,
2013. 54, 6. 1115 1120 UDC 548.737:547.12 CHARACTERIZATION AND CRYSTAL STRUCTURES OF SOLVATED N -(4-HYDROXY-3-NITROBENZYLIDENE)-3-METHYLBENZOHYDRAZIDE AND N -(4-DIMETHYLAMINOBENZYLIDENE)-3-METHYLBENZOHYDRAZIDE
More informationReversible 1,2-Alkyl Migration to Carbene and Ammonia Activation in an NHC-Zirconium Complex.
Reversible 1,2-Alkyl Migration to Carbene and Ammonia Activation in an NHC-Zirconium Complex. Emmanuelle Despagnet-Ayoub, Michael K. Takase, Jay A. Labinger and John E. Bercaw Contents 1. Experimental
More informationSupporting Information
Supporting Information Copyright Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, 2011 Transformation of Nickelalactones to Methyl Acrylate: On the Way to a Catalytic Conversion of Carbon Dioxide S. Y.
More informationSupplemental Information
Supplemental Information Template-controlled Face-to-Face Stacking of Olefinic and Aromatic Carboxylic Acids in the Solid State Xuefeng Mei, Shuanglong Liu and Christian Wolf* Department of Chemistry,
More informationb = (9) Å c = (7) Å = (1) V = (16) Å 3 Z =4 Data collection Refinement
organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 8-Iodoquinolinium triiodide tetrahydrofuran solvate Jung-Ho Son and James D. Hoefelmeyer* Department of Chemistry,
More informationmetal-organic compounds
metal-organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 Bis{tris[3-(2-pyridyl)-1H-pyrazole]- zinc(ii)} dodecamolybdosilicate hexahydrate Xiutang Zhang, a,b * Peihai
More informationSupporting Information for the Article Entitled
Supporting Information for the Article Entitled Catalytic Production of Isothiocyanates via a Mo(II) / Mo(IV) Cycle for the Soft Sulfur Oxidation of Isonitriles authored by Wesley S. Farrell, Peter Y.
More informationChanging and challenging times for service crystallography. Electronic Supplementary Information
Changing and challenging times for service crystallography Simon J Coles,* a and Philip A Gale* a Electronic Supplementary Information Instrument descriptions and experimental protocols The following firstly
More informationSupporting Information
Electronic Supplementary Material (ESI) for rganic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2018 Supporting Information An Unprecedented Tandem Synthesis of Fluorescent
More informationMicroporous Manganese Formate: A Simple Metal-Organic Porous Material with High Framework Stability and Highly Selective Gas Sorption Properties
Supporting Information Microporous Manganese Formate: A Simple Metal-Organic Porous Material with High Framework Stability and Highly Selective Gas Sorption Properties Danil N. Dybtsev, Hyungphil Chun,
More informationTotal Synthesis of Gonytolides C and G, Lachnone C, and. Formal Synthesis of Blennolide C and Diversonol
. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry Total Synthesis of Gonytolides C and G, Lachnone C, and Formal Synthesis
More informationSupporting Information
Supporting Information Wiley-VCH 2008 69451 Weinheim, Germany Supporting Information Unmasking Representative Structures of TMP-Active Hauser and Turbo Hauser Bases Pablo García-Álvarez, David V. Graham,
More information3-Bromomethyl pyridine
M 3 L 2 metallo-cryptophanes: [2]catenane and simple cages James J. Henkelis, Tanya K. Ronson, Lindsay P. Harding and Michaele J. Hardie Supplementary Material Synthesis Chemicals were obtained from commercial
More informationSupporting Information
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2017 Supporting Information Sulfonato-imino copper(ii) complexes : fast and general Chan-
More informationSupplementary Information. Two Cyclotriveratrylene Metal-Organic Frameworks as Effective Catalysts
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2018 Supplementary Information Two Cyclotriveratrylene Metal-Organic Frameworks as Effective
More informationSupporting Information
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2014 Supporting Information Unraveling the Origins of Catalyst Degradation in Non-heme Ironbased
More informationA Mixed Crystal Lanthanide Zeolite-like Metal-Organic. Framework as a Fluorescent Indicator for Lysophosphatidic. Acid, a Cancer Biomarker
Supporting Information for A Mixed Crystal Lanthanide Zeolite-like Metal-Organic Framework as a Fluorescent Indicator for Lysophosphatidic Acid, a Cancer Biomarker Shi- Yuan Zhang,, Wei Shi, *, Peng Cheng,
More informationSigma Bond Metathesis with Pentamethylcyclopentadienyl Ligands in Sterically. Thomas J. Mueller, Joseph W. Ziller, and William J.
Sigma Bond Metathesis with Pentamethylcyclopentadienyl Ligands in Sterically Crowded (C 5 Me 5 ) 3 M Complexes Thomas J. Mueller, Joseph W. Ziller, and William J. Evans * Department of Chemistry, University
More informationControllable Growth of Bulk Cubic-Phase CH 3 NH 3 PbI 3 Single Crystal with Exciting Room-Temperature Stability
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information Controllable Growth of Bulk Cubic-Phase CH 3 NH 3 PbI
More informationSupporting Information
Supporting Information Unprecedented solvent-dependent sensitivities in highly efficient detection of metal ions and nitroaromatic compounds by a fluorescent Ba MOF Rongming Wang, Xiaobin Liu, Ao Huang,
More informationZiessel a* Supporting Information (75 pages) Table of Contents. 1) General Methods S2
S1 Chemistry at Boron: Synthesis and Properties of Red to Near-IR Fluorescent Dyes based on Boron Substituted Diisoindolomethene Frameworks Gilles Ulrich, a, * Sebastien Goeb a, Antoinette De Nicola a,
More informationSupporting information for the manuscript. Synthesis and Structure of Nitride-Bridged Uranium(III) Complexes
Supporting information for the manuscript Synthesis and Structure of Nitride-Bridged Uranium(III) Complexes Lucile Chatelain, Rosario Scopelliti, and Marinella Mazzanti* ISIC, Ecole Polytechnique Fédérale
More informationBenzene Absorption in a Protuberant-Grid-Type Zinc(II) Organic Framework Triggered by the Migration of Guest Water Molecules
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information Benzene Absorption in a Protuberant-Grid-Type Zinc(II)
More informationElectronic Supplementary Information
Electronic Supplementary Information Early-Late Heterobimetallic Rh-Ti and Rh-Zr Complexes via Addition of Early Metal Chlorides to Mono- and Divalent Rhodium Dan A. Smith and Oleg V. Ozerov* Department
More informationSupplementary Information
Site-Selective Cyclometalation of a Metal-Organic Framework Phuong V. Dau, Min Kim, and Seth M. Cohen* Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive,
More informationSupplementary Information
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2017 Supplementary Information Intermolecular Sulfenoamination of Alkenes with
More informationSupporting Information. Table of Contents
Supporting Information Cyclo-P 3 Complexes of Vanadium. Redox Properties and Origin of the 31 P NMR Chemical Shift. Balazs Pinter,, Kyle T. Smith, Masahiro Kamitani, Eva M. Zolnhofer,ǁ Ba L. Tran, Skye
More informationSUPPORTING INFORMATION
SUPPORTING INFORMATION Table of Contents S1 1. General materials and methods S2 2. Syntheses of {Pd 84 } and {Pd 17 } S3-S4 3. MS studies of {Pd 84 }, {Pd 17 } and the two-component reactions S5-S6 4.
More informationthe multiple helices
Supporting Information A 3D porous metal-organic framework containing nanotubes based on the multiple helices Lei Hou,* Li-Na Jia, Wen-Juan Shi, Li-Yun Du, Jiang Li, Yao-Yu Wang* and Qi-Zhen Shi Key Laboratory
More informationSupplementary Information: Selective Catalytic Oxidation of Sugar Alcohols to Lactic acid
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 2014 Supplementary Information: Selective Catalytic Oxidation of Sugar Alcohols to Lactic acid
More informationStabilizing vitamin D 3 by conformationally selective co-crystallization
Supporting Information for Stabilizing vitamin D 3 by conformationally selective co-crystallization Jian-Rong Wang, Chun Zhou, Xueping Yu and Xuefeng Mei* Pharmaceutical Analytical & Solid-State Chemistry
More informationSupplementary Information
Supplementary Information Tuning the Luminescence of Metal-Organic Frameworks for Detection of Energetic Heterocyclic Compounds Yuexin Guo, Xiao Feng,*, Tianyu Han, Shan Wang, Zhengguo Lin, Yuping Dong,
More informationmetal-organic compounds
metal-organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 Propane-1,2-diammonium bis(pyridine- 2,6-dicarboxylato-j 3 O,N,O 0 )nickelate(ii) tetrahydrate Hossein Aghabozorg,
More informationSupporting Information
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2015 Supporting Information Bridging different Co 4 -calix[4]arene building blocks into grids, cages
More informationOne-dimensional organization of free radicals via halogen bonding. Supporting information
One-dimensional organization of free radicals via halogen bonding Guillermo Mínguez Espallargas,* a Alejandro Recuenco, a Francisco M. Romero, a Lee Brammer, b and Stefano Libri. b a Instituto de Ciencia
More informationSupporting Information
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2015 A rare case of a dye co-crystal showing better dyeing performance Hui-Fen Qian, Yin-Ge Wang,
More informationUniversity of Chinese Academy of Sciences, Beijing , China. To whom correspondence should be addressed :
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2018 NaBaM III Q 3 (M III = Al, Ga; Q = S, Se): First quaternary chalcogenides with the isolated
More information