UNIT 11 Practice Test Page 1 of 13 Equilibrium

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1 UNIT 11 Practice Test Page 1 of 13 Do NOT write on this test. $0.10/page lost or damaged fee. 1. In which of the following does the reaction go farthest to completion? A. K = 10 5 B. K = 10 5 C. K = 1000 D. K = 100 E. K = 1. The equilibrium constant, K c, for the reaction H (g) + I (g) HI(g) is 55 at 45 C. The value for the equilibrium constant will be changed if A. concentrations are given in atmospheres instead of mol/l. B. a catalyst is added to the reaction system. C. the size of a reaction vessel is doubled. D. the temperature is changed to 400 C. E. additional HI is added to the reaction system. 3. Which of the following statements is true in a reaction system at equilibrium? A. The number of collisions per unit time between reactants is equal to the number of collisions per unit time between products. B. Reactants are reacting to form products at the same rate as products are reacting to form reactants. C. The product of the concentrations of the reactants is equal to the product of the concentrations of the products. D. All concentrations of reactants and products are the same. E. No products are being formed, and no reactants are being formed. 4. Which of the following correctly describes the equilibrium constant for the gas-phase reaction between H and O to form gaseous H O HO HO A. B. HO HO C. HO H O D. HO HO E. K HO c

2 UNIT 11 Practice Test Page of The reaction of a mixture of SO and O at a given temperature is represented by the equation SO (g) + ½ O (g) SO 3 (g) When the equilibrium is established, which of the following ratios is constant, regardless of the initial concentrations of SO and O SO3 A. SOO SOO B. SO C. D. E. 3 SO SO SO3 SO O 3 1 O SO3 1 SO O 6. For the reaction system CoO(s) + H (g) Co(s) + H O(g) at 550 C, K = 67. The equilibrium constant expression is A. CoOH CoHO B. CoHO CoOH C. CoH O H D. H HO E. HO H 7. Carbon tetrachloride reacts with oxygen at high temperatures to produce chlorine and carbonyl chloride. CCl 4 (g) + O (g) COCl (g) + Cl (g) K c = 1.9 x What is K c for the following: COCl (g) + Cl (g) CCl 4 (g) + ½ O (g) A. 5. x 10 0 B..3 x C. 4.4 x 10 9 D. 1.9 x E. 1.9 x 10 19

3 UNIT 11 Practice Test Page 3 of For the following reaction systems at 500 K I. NOCl(g) NO(g) + Cl (g) K p = 1.7 x 10 II. NO (g) NO(g) + O (g) K p = 5.9 x 10 5 III. SO(g) SO (g) + O (g) K p = 1.3 x 10 5 the reaction's tendency to go to completion increases in the order A. I < II < III. B. III < II < I. C. II < I < III. D. II < III < I. E. III < I < II. 9. Consider the equilibrium N (g) + 3 H (g) NH 3 (g) at a certain temperature. An equilibrium mixture in a 4.00-L vessel contains 1.60 mol NH 3, mol N, and 1.0 mol H. What is the value of K c? A B. 9.6 C D E For the reaction system: HI(g) H (g) + I (g) K c = 0.00 at 70 K. If the initial concentrations of HI, H, and I are all 1.50x10 3 M at 70 K, which one of the following statements is correct? A. The system is at equilibrium. B. The concentrations of HI and I will increase as the system is approaching equilibrium. C. The concentrations of H and HI will decrease as the system is approaching equilibrium. D. The concentration HI will increase as the system is approaching equilibrium. E. The concentrations of H and I will increase as the system is approaching equilibrium. 11. In an experiment, mol H and mol I are mixed in a 1.00-L container and the reaction forms HI. If K c = 50.0 for this reaction, what is the equilibrium concentration of HI? I (g) + H (g) HI(g) A M B M C M D M E M 1. Exactly 1.0 mol N O 4 is placed in an empty 1.0-L container and is allowed to reach equilibrium described by the equation N O 4 (g) NO (g) If at equilibrium the N O 4 is 0% dissociated, what is the value of the equilibrium constant (in units of mol/l) for the reaction under these conditions? A B. 0. C. 0.5 D. 0 E. 400

4 UNIT 11 Practice Test Page 4 of For the equilibrium PCl 5 (g) PCl 3 (g) + Cl (g) K c = 4.0 at 8 C. Pure PCl 5 is added to the reaction system. At equilibrium there is M PCl 5. What is the concentration of PCl 3 in this system? A M B. 0.0 M C M D M E. 1.6 M 14. Hydrogen iodide undergoes decomposition according to the equation HI(g) H (g) + I (g) The equilibrium constant at 45 C for this system is If 1.0 mol each of H, I, and HI were placed together in a 1-L container at 45 C, then A. the concentration of HI would decrease. B. the value of K would increase to 1.0. C. because of reaction, the total number of molecules would decrease. D. because of reaction, the total number of molecules would increase. E. the concentration of H would decrease. The information that follows is for the following two questions, 15 & 16. At a given temperature, mol NO, 0.00 mol Cl, and mol ClNO were placed in a 5.0-L container. The following equilibrium is established: ClNO(g) NO(g) + Cl (g) 15. At equilibrium, mol ClNO are present. How many moles of Cl are present at equilibrium? A B C D E What is the value of the equilibrium constant K c? A x 10 4 B x 10 4 C D E Which of the following equilibria would not be affected by pressure changes at constant temperature? A. FeO(s) + CO(g) Fe(s) + CO (g) B. CaCO 3 (s) CaO(s) + CO (g) C. H O(g) H (g) + ½ O (g) D. NO(g) + O (g) NO (g) E. PCl 5 (l) PCl 3 (g) + Cl (g)

5 UNIT 11 Practice Test Page 5 of Consider the reaction S Cl (l) + CCl 4 (l) CS (g) + 3 Cl (g) H = 84.3 kj If the above reactants and products are contained in a closed vessel and the reaction system is at equilibrium, the number of moles of CS can be increased by A. adding some S Cl to the system. B. removing some CCl 4 from the system. C. decreasing the size of the reaction vessel. D. increasing the temperature of the reaction system. E. adding some Cl to the system. 19. The reaction of carbon monoxide and iodine pentoxide as represented by the equation 5 CO(g) + I O 5 (g) I (g) + 5 CO (g) is endothermic. The yield could be increased by A. increasing the pressure. B. decreasing the pressure. C. increasing the temperature. D. decreasing the temperature. E. decreasing the volume of the reaction vessel. 0. Which of the following equilibria would not be affected by volume changes at constant temperature? A. CO(g) + O (g) CO (g) B. NO (g) N O 4 (g) C. NO(g) + 3 F (g) F 3 NO(g) D. BF 3 (g) + NH 3 (g) H 3 NBF 3 (s) E. O 3 (g) + NO(g) NO (g) + O (g) 1. For the reaction system H (g) + I (g) HI(g), K = 55 at 45 C. For the system HI(g) ½ H (g) + ½ I (g), K at 45 C is A. 55 B. 55 C D E. 3.3 x For which of the following systems at equilibrium and at constant temperature will decreasing the volume cause the equilibrium to shift to the right? A. N (g) + 3 H (g) NH 3 (g) B. H O(g) H (g) + O (g) C. NO (g) NO(g) + O (g) D. NH 4 Cl(s) NH 3 (g) + HCl(g) E. H (g) + Cl (g) HCl(g) 3. In which of the following reactions does an instantaneous increase in the volume of the reaction vessel favor formation of the products? A. MgO(s) + CO (g) MgCO 3 (s) B. PCl 5 (g) PCl 3 (g) + Cl (g) C. H (g) + I (g) HI(g) D. N (g) + O (g) NO(g) E. N (g) + 3 H (g) NH 3 (g)

6 UNIT 11 Practice Test Page 6 of For which of the following reactions are the numerical values of K p and K c the same? A. CO(g) + O (g) CO (g) B. PCl 5 (g) PCl 3 (g) + Cl (g) C. N (g) + 3 H (g) NH 3 (g) D. H O(g) H (g) + O (g) E. H (g) + I (g) HI(g)

7 UNIT 11 Practice Test Page 7 of 13 Answer Key: 1. A. D 3. B 4. C 5. D 6. E 7. B 8. B 9. B 10. D 11. A 1. B 13. C 14. E 15. C 16. B 17. A 18. D 19. C 0. E 1. C. A 3. B 4. E

8 UNIT 11 Practice Test Page 8 of 13 Answer Justifications: 1. A By going farthest to completion, the statement implies that the reaction creates a lot of products. Since the equilibrium constant is determined by taking a ratio of products to reactants, the higher the equilibrium constant shows the further completion of the reaction. This means that the farther completion is Response A.. D Only one variable alters the value of the equilibrium constant that is the temperature. 3. B Response B is true since it states the definition of dynamic equilibrium. If Response A had stated that the number of collisions at the correct energy per unit time between reactants is equal to the number of collisions at the correct energy per unit time between products, then it would have been correct since it followed the Collision Theory. Response C and D are completely untrue as the probability that the quantity (and multiplied version, product ) of the concentrations of the reactants is equivalent to the quantity (and multiplied version, product ) concentrations of the products is slim. Response E is definitively what will be macroscopically observed, even though the reaction continues to occur both in the forward reaction and the reverse. 4. C First, determine the gas-phase reaction between H with O and H O. The balanced reaction looks like: H + O H O Then, write the expression of the equilibrium constant, K, by placing products in the numerator, with the coefficient as its exponent, and placing reactants in the denominator, with their coefficients as their exponents: K c HO H O 5. D The only ratio that is ever constant is the equilibrium constant, presenting a ratio between created products to remaining reactants. Therefore, the only ratio that is constant is the expression of the equilibrium constant. This should appear as: SO3 SO O However, the reaction can occur in coefficients of multiples, such as: SO (g) + O (g) SO 3 (g) So, as long as the ratio provides a stoichiometric relationship to the reaction, the ratio remains constant. SO3 SO3 Since, the stoichiometric relationship is constant. SO O SO O 6. E For any reaction, developing an equilibrium constant expression first requires that the reaction s equation is balanced. This equation is balanced. Next, only aqueous solutions and gaseous species can be entered into the equilibrium constant expression, not solid or liquid species. Therefore, CoO and Co can not be included in the equilibrium constant expression. This leaves only the gaseous water and hydrogen Response E.

9 UNIT 11 Practice Test Page 9 of B First, compare the original reaction with the reaction being provided. The original reaction has coefficients that are two times larger than those of the new reaction. In addition, the new reaction is occurring in the opposite direction of that of the original reaction. This means that the equilibrium constant of the new reaction is the square-root and inverse of the original equilibrium constant: Knew 1.3x x B The tendency of a reaction to go to completion implies that the reaction has headed far to right, creating a larger number of products and reducing the number of reactants. This would, in turn, create an equilibrium constant value that was larger. Therefore, the reaction that has headed in the forward direction the most is I. The reaction that has gone to completion the least, with the lowest K p, is III. This places III lower than II, which is lower than I. 9. B First, write the equilibrium expression for the reaction: K c NH3 N H 3 Next, fill in the mole values corresponding to each species after converting them to molarities: 1.60mol K 4.00 c L mol 1.0mol L 4.00L 10. D In order to make an interpretation of the system and how it may or may not approach equilibrium, solve for the quotient. Remember that the equation for the quotient is equivalent to the equation for the equilibrium constant: HI Q HI Plug in the concentrations for the corresponding species: x x10 Q x10 This shows that Q is larger than K c, meaning that there are currently too many products than there should be at equilibrium. This will cause the reaction to reverse and create more reactants. This makes response A incorrect since the reaction is not at equilibrium. The responses B and C suggest that the quantities of the reactants and products will be increasing; since the Q value shows that only the reactants will increase, neither of these responses is correct. Finally, response D suggests that the reaction will head to the left, while response E suggests that the reaction will head to the right. Since this reaction will head to the left, response D is correct.

10 UNIT 11 Practice Test Page 10 of A In order to solve this question, an ICE chart must be created. I (g) + H (g) HI(g) I 0.100mol 0.100mol L 1.00L C x x +x E (0.100M x) (0.100M x) (x) Now, plug these quantities into the equilibrium constant expression: HI x H I x x x x 4x x 50x 4x 046x 10x 0.5 solver; x = M, 0.139M Both numbers appear correct, however, if the value were plugged into the expression for H or I (0.1 x), it would create a negative value ( = 0.039). Therefore, the correct x value is Now, plug this value into the expression for HI: (x) = ( * 0.078) = M 1. B In order to solve this question, an ICE chart must be created. N O 4 (g) NO (g) I 1.0mol 0 1.0L C x = (1.0M)(0.) = 0. +x = +()(0.) = +0.4 ( ) = 0.40M E (1.0 0.) = 0.80 M Now, plug these quantities into the equilibrium constant expression: NO NO **This is a good example of a multiple choice question that you could do without a calculator. 13. C In order to solve this question, an ICE chart must be created. PCl 5 (g) PCl 3 (g) + Cl (g) I Plenty of reactant 0 0 C x +x +x E M x x Now, plug these quantities into the equilibrium constant expression: PCl3Cl xx 4.0 PCl = x 0.40 = x = [PCl 3 ] = [Cl ] **This is a good example of a multiple choice question that you could do without a calculator.

11 UNIT 11 Practice Test Page 11 of E Because the quantities of the reactants and products are provided, but are not necessarily at equilibrium, it is a good opportunity to utilize a quotient, Q. Remember that the expression for the quotient is identical to the expression of the equilibrium constant, but the values that can be entered into the quotient can be at any point during the reaction. Set up the quotient expression and then plug in the concentrations, not moles: 1.0mol HI Q 1L 1.0 HI 1.0mol 1.0mol 1L 1L Now, compare this value to the equilibrium constant. Since Q > K, there are currently too many products so the reaction will proceed in the reverse direction. Response B makes no sense, since the value of K will not change unless the temperature changes. Neither response C nor D make sense since if the reaction goes to the right, it would mean that every two molecules of HI that are reacted, one molecule of hydrogen and one molecule of iodine would be created, and vice versa for the reaction going to the left. This means that this reaction would maintain the number of total molecules regardless of the direction of shift. Response A suggests that the reaction is headed in the forward direction, which has just been shown otherwise. And finally, response E suggests that the reaction is headed in the reverse direction, which it is. 15. C In order to solve this question, an ICE chart can be created. Notice, the ICE chart will be completed in moles. ClNO(g) NO(g) + Cl (g) I mol mol 0.00 mol C +x x x E mol (0.3 x) (0. x) Notice that the quantity of ClNO has increased from initial to equilibrium. This shows that the amount of ClNO that was changed is a positive 0.1 moles. Since the balanced equation provides a ClNO : NO : 1 Cl ratio, the addition of 0.1 mole to the ClNO means that the Cl will be reduced by 0.05 mole. Cl = = 0.15 moles 16. B Completing the ICE chart from question 15 above, ClNO(g) NO(g) + Cl (g) I mol mol 0.00 mol C +x x x E mol ( ) = 0. mol ( ) = 0.15 mol Plug the equilibrium mole quantities into the equilibrium constant expression as molarities: 0.mol 0.15mol 5L 5L x10 0.6mol L 17. A Reactions that involve gases tend to be affected by pressure changes, while reactions that do not have any gases will definitively not be affected by pressure changes. Notice that no reaction is entirely void of gases. Reactions that involved gases with equivalent moles of gas on both sides of the reaction will have rates that are affected by a pressure change equally. So look at how many gaseous particles appear on each side of the reactions: Response A: 1 gaseous reactant to 1 gaseous product Response B: 0 gaseous reactants to 1 gaseous product Response C: 1 gaseous reactant to 1 ½ gaseous products Response D: 3 gaseous reactants to gaseous products Response E: 1 gaseous reactant to gaseous products

12 UNIT 11 Practice Test Page 1 of 13 The only reaction that has equivalent moles of gas on both sides of the reaction is response A. Therefore, it will not be affected by altering the pressure. 18. D In order to increase the number of CS moles, the equilibrium reaction must be stressed so that it causes a shift toward the CS, which is on the product s side. This can be caused by removing the other product (Cl ), by increasing the temperature for this endothermic reaction, and by decreasing the pressure/ increasing the volume of the system. The only response that follows one of these stresses is response D. Notice that altering the quantities of reactants (as in responses A or B) does not cause any shift, since the reactants do not have concentrations, as they are liquids. 19. C The yield, remember, means the creation of products. Therefore, the equilibrium reaction must be stressed so that it shifts to the product s side. This can be caused by adding more reactant or by increasing the temperature for this endothermic reaction. The only response that follows one of these stresses is response C. Notice that altering the pressure of this reaction (as in responses A or B, or similarly by response E) does not cause any shift, since there are 6 moles of gaseous reactants and 6 moles of gaseous products. 0. E Reactions that involve gases tend to be affected by pressure changes, while reactions that do not have any gases will definitively not be affected by pressure changes. The same is true of volume changes. Notice that no reaction is entirely void of gases. Reactions that involved gases with equivalent moles of gas on both sides of the reaction will have rates equally affected by a volume change. So look at how many gaseous particles appear on each side of the reactions: Response A: 3 gaseous reactants to gaseous products Response B: gaseous reactants to 1 gaseous product Response C: 5 gaseous reactants to gaseous products Response D: gaseous reactants to 0 gaseous products Response E: gaseous reactants to gaseous products The only reaction that has equivalent moles of gas on both sides of the reaction is response E. Therefore, it will not be affected by altering the volume. 1. C First, notice that the first reaction presented has the same temperature as the second reaction. Next, compare the second reaction to the first reaction. The second reaction is reversed, compared to the first reaction. This means that the new K value will be the inverse of the original K value. The second reaction is also ½ the coefficients of the first reaction. This means that the new K value will be the square root of the original K value. Putting this all together, 1 1 Knew K 55 old. A Reactions that involve gases tend to be affected by volume changes. If a decrease in volume causes a shift to the right, the number of gaseous particles on the right side of the reaction must be lower than the number of gaseous particles on the left side. So look at how many gaseous particles appear on each side of the reactions: Response A: 4 gaseous reactants to gaseous products Response B: gaseous reactants to 3 gaseous productx Response C: gaseous reactants to 3 gaseous products Response D: 0 gaseous reactants to gaseous products Response E: gaseous reactants to gaseous products

13 UNIT 11 Practice Test Page 13 of 13 The only reaction that has fewer moles of gas on the product s side is response A. Therefore, it is the only one that will shift right when the volume is decreased. 3. B Reactions that involve gases tend to be affected by volume changes. If an increase in volume causes formation of products, the number of gaseous particles on the right side of the reaction must be higher than the number of gaseous particles on the left side. So look at how many gaseous particles appear on each side of the reactions: Response A: 1 gaseous reactant to 0 gaseous products Response B: 1 gaseous reactant to gaseous products Response C: gaseous reactants to gaseous products Response D: gaseous reactants to gaseous products Response E: 4 gaseous reactants to gaseous products The only reaction that has more moles of gas on the product s side is response B. Therefore, it is the only one that will shift right when the volume is increased. 4. E Reactions that involve gases relate their pressure equilibrium constant to their concentration equilibrium constant through the equation: K p = K c (RT) n In order for K p and K c to be equal, the quantity (RT) n must be removed by having a n = 0. This only occurs when the number of gaseous product moles is equal to the number of gaseous reactant moles. So look at how many gaseous particles appear on each side of the reactions: Response A: 3 gaseous reactants to gaseous products Response B: 1 gaseous reactant to gaseous products Response C: 4 gaseous reactants to gaseous products Response D: gaseous reactants to 3 gaseous products Response E: gaseous reactants to gaseous products The only reaction that has equal gaseous moles on the both sides of the reaction is response E. Therefore, it is the only one that will have equal K p and K values.

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