Chapter 8. Chemical Equations and Reactions

Transcription

1 Chapter 8 Chemical Equations and Reactions

2 Chemical Equations Represents, w/ symbols & formulas, the reactants & products in a chemical reaction Requirements Must represent the known facts Must contain correct formulas Must satisfy the law of conservation (NH 4 ) 2 Cr 2 O 7 (s) N 2 (g) + Cr 2 O 3 (s) + 4H 2 O(g)

3 Indication of a Chemical Reaction Production of light or heat. Production of gas or smoke. Formation of a precipitate (ppt). Color change.

4 Diatomic Molecules Elements that normally exist as diatomic molecules. H 2, N 2, O 2, F 2, Cl 2, Br 2 and I 2

5 Word & Formula Equations Word Equation chemical equation represented w/ words Methane Gas + Oxygen Gas Carbon Dioxide Gas + Water Vapor Formula Equation chemical equation represented w/ formulas & symbols CH 4 (g) + 2O 2 (g) CO 2 (g) + 2H 2 O (g) Coefficient Small whole number used to balance the equation

6 Common Symbols in Equations Symbol (s) (l) (aq) (g) Explanation Yields indicates result of reaction Reversible Reaction Reactant or Product in solid state Precipitate (alternative for solid) Reactant or Product in liquid state Reactant or Product in aqueous solution (dissolved in water) Reactant or Product in gas Gaseous Product (alternative for gas) Reactants are Heated

7 Practice Solid Sodium hydroxide reacts with nitric acid in a solution to produce sodium nitrate and water when heated. Write a word and formula equation for this sentence.

8 2 nd Practice Equation Aluminum sulfate and calcium hydroxide are used in a water purification process. When added to water they dissolve and react to produce two insoluble (solid) products, aluminum hydroxide and calcium sulfate. Write a word and formula equation representing this reaction.

9 Silver Reactions

10 Thermite Reaction Thermite

11 Balancing Equations Mass of Reactants must equal Mass of Products No Atoms can be lost during the reaction

12 8.2 Types of Chemical Equations Synthesis (Composition) A + X AX Decomposition AX A + X Single Replacement A + BX AX + B Double Replacement AX + BY AY + BX Combustion C x H y + O 2 CO 2 + H 2 O

13 Synthesis Reactions A + X AX Formation of: Binary Ionic Compounds Binary Molecular Compounds Formation of Metal Hydroxides Oxyacids

14 Reaction of Metals with Nonmetals Example 1 Mg + O 2 Example 2 Fe + O 2 Example 3 Na + Cl 2

15 Reaction of two Nonmetals Reactions are dependant upon the amounts of each reactant available. Example 1 C + O 2 Example 2 S + O 2 Example 3(limited amount of Oxygen) C + O 2

16 Synthesis Reactions of Metal Oxides w/ Water M x O y + H 2 O M (OH) y metal oxide + water metal hydroxide Example 1 CaO + H 2 O

17 Synthesis Reactions of Nonmetal Oxides w/ Water NOTE: The acid produce has the nonmetal in the same oxidation state as it was in the nonmetal oxide. NM x O y + H 2 O H x NMO y nonmetal oxide + water Oxyacid Example 1 SO 3 + H 2 O Example 2 N 2 O 5 + H 2 O

18 Decomposition AX A + X Binary Compounds Metal Carbonates Metal Hydroxides Metal Chlorates Oxyacids

19 Decomposition of Binary Compounds AX A + X Example 1 HgO Example 2 H 2 O

20 Decomposition of Metal Carbonates MCO 3 MO + CO 2 metal carbonate metal oxide + carbon dioxide Example 1 CaCO 3

21 Decomposition of Metal Hydroxides MOH MO + H 2 O Metal hydroxide metal oxide + water Example 1 Ca(OH) 2

22 Decomposition of Metal Chlorates M(ClO 3 ) MCl + O 2 metal chlorate metal chloride + oxygen Example 1 KClO 3

23 Decomposition of Acids Acid Nonmetal Oxides + H 2 O Nonmetals in the nonmetal oxides will have the same oxidation state as it did in the acid. Example 1 H 2 SO 4 Example 2 HNO 2

24 Single Replacement Reactions A + BX AX + B Y + BX BY + X Replacement of a Metal by another Metal Al + Fe(NO 3 ) 3 Replacement of Hydrogen in Water by a Metal Na + H 2 O Must check the activity series to make sure the lone element has a greater activity than the element in the compound.

25 lithium potassium barium strontium calcium sodium magnesium aluminum zinc chromium iron cadmium cobalt nickel tin lead Hydrogen antimony arsenic bismuth copper mercury silver palladium platinum gold Can react with cold water and acids, replacing hydrogen. Will form Metal Hydroxide and Hydrogen when added to water. Can react with steam and acids, replacing the hydrogen. Can react with acids, replacing the hydrogen. React with oxygen, forming oxides. Fairly unreactive. Form oxides only indirectly.

26 Single Replacement Reactions Replacement of Hydrogen in an Acid by a Metal Mg + HCl Replacement of Halogens Cl 2 + KBr

27 Double Replacement Reactions AX + BY AY + BX Positive Ions (cations) in Both Compounds Switch Places Positive Ions are Written First Pb(NO 3 ) 2 + KI HCl + NaOH

28 Combustion : Complete C x H y (O z ) + O 2 CO 2 + H 2 O C 2 H 6 + O 2 C 6 H 6 O 2 + O 2 Combustion InComplete C x H y (O z ) + O 2 CO + H 2 O

29 Types of Chemical Reactions Synthesis Reactions: A + B AB Reaction of Elements with Oxygen E + O 2 EO Reactions of Two Nonmetals NM1 + NM2 Binary Molecular Compound Reactions of Metals w/ Nonmetals other than Oxygen M + NM Binary Ionic Compound Synthesis Reactions of Metal Oxides w/ Water MxOy + H 2 O Mx(OH)y

30 Decomposition: AX A + X Decomposition of Binary Compounds E1E2 E1 + E2 Decomposition of Metal Carbonates MCO 3 MO + CO 2 Decomposition of Metal Hydroxides MOH MO + H 2 O Decomposition of Metal Chlorates M(ClO3) MCl + O 2 Decomposition of Acids Acid Nonmetal Oxides + H 2 O

31 Single Replacement Reactions: A + BX AX + B Replacement of a Metal by another Metal A + BX AX + B where A & B are Metals Replacement of Hydrogen in Water by a Metal M + H 2 O MOH + H 2 where M is a Metal Replacement of Hydrogen in an Acid by a Metal M + HX MX + H 2 Replacement of Halogens X 2 + AY AX + Y 2 Where X & Y are halogens Double Replacement Reactions B 1 G 1 + B 2 G 2 B 1 G 2 + B 2 G 1 Where B is a Cation and G is an Anion Combustion Reactions C x H y (O z ) + O 2 CO 2 + H 2 O