Emulsions. Fundamentals and Applications in the Petroleum Industry
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1 ADVANCES IN CHEMISTRY SERIES 231 Downloaded via on July 23, 2018 at 08:49:52 (UTC). See for options on how to legitimately share published articles. Emulsions Fundamentals and Applications in the Petroleum Industry Laurier L. Schramm, EDITOR Petroleum Recovery Institute Based on a short course developed by the Editor entitled "Petroleum Emulsions and Applied Emulsion Technology" and sponsored by the Petroleum Recovery Institute, Calgary. American Chemical Society, Washington, DC 1992
2 Library of Congress Cataloging-in-Publication Data Emulsions: fundamentals and applications in the petroleum industry / Laurier L. Schramm, editor. p cm. (Advances in Chemistry Series : 231. Based on a short course developed by the editor entitled Petroleum Emulsions and Applied Emulsion Technology and sponsored by the Petroleum Recovery Institute, Calgary, Alberta, Canada, December, Includes bibliographical references and index. ISBN Emusions Congresses. 2. Petroleum Congresses. I. Schramm, Laurier Lincoln. II. Petroleum Recovery Institute. III. Series. QD1.A355 no. 231 [TP156.E6] 540 s dc [665.5] CIP The paper used in this publication meets the minimum requirements of American National Standard for Information Sciences Permanence of Paper for Printed Library Materials, ANSI Z Copyright 1992 American Chemical Society All Rights Reserved. The appearance of the code at the bottom of the first page of each chapter in this volume indicates the copyright owner's consent that reprographic copies of the chapter may be made for personal or internal use or for the personal or internal use of specific clients. This consent is given on the condition, however, that the copier pay the stated per-copy fee through the Copyright Clearance Center, Inc., 27 Congress Street, Salem, MA 01970, for copying beyond that permitted by Sections 107 or 108 of the U.S. Copyright Law. This consent does not extend to copying or transmission by any means graphic or electronic for any other purpose, such as for general distribution, for advertising or promotional purposes, for creating a new collective work, for resale, or for information storage and retrieval systems. The copying fee for each chapter is indicated in the code at the bottom of the first page of the chapter. The citation of trade names and/or names of manufacturers in this publication is not to be construed as an endorsement or as approval by ACS of the commercial products or services referenced herein; nor should the mere reference herein to any drawing, specification, chemical process, or other data be regarded as a license or as a conveyance of any right or permission to the holder, reader, or any other person or corporation, to manufacture, reproduce, use, or sell any patented invention or copyrighted work that may in any way be related thereto. Registered names, trademarks, etc., used in this publication, even without specific indication thereof, are not to be considered unprotected by law. PRINTED IN THE UNITED STATES OF AMERICA American Chemical Society Library th St., N.W. Washington D.C
3 Advances in Chemistry Series M. Joan Comstock, Series Editor 1992 ACS Books Advisory Board V. Dean Adams Tennessee Technological University Alexis T. Bell University of California Berkeley Dennis W. Hess Lehigh University Mary A. Kaiser Ε. I. du Pont de Nemours and Company Gretchen S. Kohl Dow-Corning Corporation Bonnie Lawlor Institute for Scientific Information John L. Massingill Dow Chemical Company Robert McGorrin Kraft General Foods Julius J. Menn Plant Sciences Institute, U.S. Department of Agriculture Marshall Phillips Office of Agricultural Biotechnology, U.S. Department of Agriculture A. Truman Schwartz Macalaster College Stephen A. Szabo Conoco Inc. Robert A. Weiss University of Connecticut
4 FOREWORD The ADVANCES IN CHEMISTRY SERIES was founded in 1949 by the American Chemical Society as an outlet for symposia and collections of data in special areas of topical interest that could not be accommodated in the Society's journals. It provides a medium for symposia that would otherwise be fragmented because their papers would be distributed among several journals or not published at all. Papers are reviewed critically according to ACS editorial standards and receive the careful attention and processing characteristic of ACS publications. Volumes in the ADVANCES IN CHEMISTRY SERIES maintain the integrity of the symposia on which they are based; however, verbatim reproductions of previously published papers are not accepted. Papers may include reports of research as well as reviews, because symposia may embrace both types of presentation.
5 ABOUT THE EDITOR LAURIER L. SCHRAMM is a senior staff research scientist and group leader for chemical improved oil recovery at the Petroleum Recovery Institute in Calgary, Alberta, Canada. He is also an adjunct associate professor of chemistry at the University of Calgary, where he lectures in applied colloid and interface chemistry. He received his B.Sc. (Hons.) in chemistry from Carleton University in 1976 and a Ph.D. in physical and colloid chemistry in 1980 from Dalhousie University, where he studied as a Killam Scholar. From 1980 to 1988 he held research positions with Syncrude Canada Ltd. in its Edmonton Research Centre. His research interests have included many aspects of colloid and interface science applied to the petroleum industry, including research into mechanisms of new processes for the enhanced recovery of light to heavy crude oils, such as foam, polymer, and surfactant flooding, and research into fundamental and applied aspects of the hot-water flotation process for recovering bitumen from oil sands. These have involved investigations into the rheology of emulsions, suspensions, hydrocarbons, and oil foams; the electrokinetic properties of dispersed solids, oil, and gases in aqueous solutions; dynamic surface and interfacial tensions and phase attachments; and the reactions and interactions of surfactants in solution. Dr. Schramm is a member of the Chemical Institute of Canada (including serving on the Local Section Executive), the American Chemical Society, and the International Association of Colloid and Interface Scientists. He has published some 30 scientific papers and has 10 patents. This is his first book project.
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