CH 3 CH 2 C=CCH 2 CH 3 CH 2 CH 2 OH
|
|
- Myrtle Curtis
- 5 years ago
- Views:
Transcription
1 CHE 325 ALCOLS, DIOLS, AND THIOLS CHAP 15 ASSIGN 1. What is the correct IUPAC name for the following compound? CH 2 C=CCH 2 CH 2 CH 2 A. 3-methyl-4-ethyl-3-hexen-6-ol B. 4-ethyl-3-methyl-3,6-hexenol C. 3-ethyl-4-methyl-3-hexen-1-ol D. 3-methyl-4-(2-hydroxyethyl)-3-hexene E. 3-(2-hydroxyethyl)- 3-methyl-3-hexene 2. The major industrial process in use today for the production of methanol is the: A. hydration of ethyne. B. distillation of wood. C. hydrogenation of carbon dioxide. D. reduction of methanal. E. catalytic reduction of carbon monoxide. 3. Which of the following reagents might serve as the basis for a simple chemical test that would distinguish between pure 1-butene and CH 2CH 2CH 2? A. Bromine in carbon tetrachloride B. Dilute aqueous potassium permanganate C. Chromic oxide in aqueous sulfuric acid D. All of these E. None of these 4. Which compound would have the highest boiling point? A. CH 2CH 2 B. CH 2O C. CH 2CH 2 D. () 2CH E. HOCH 2CH 2 5. What is the product of the following reaction? 6. Which one of the following is not readily oxidized by K 2Cr 2O 7 in H 2SO 4/H 2O? A. 1-butanol B. sec-butyl alcohol C. 2-methyl-1-propanol D. 2-methyl-2-butanol 7. Which one of the following diols would cleave into two fragments with HIO 4? A. 1,3-hexanediol B. 2,4-hexanediol C. 3,4-hexanediol D. 1,6-hexanediol 8. Identify the reagent needed to carry out the following conversion. A. K 2Cr 2O 7, H 2SO 4/H 2O B. PCC/CH 2Cl 2 C. OsO 4, () 3CO, () 3C, - D. Na 2Cr 2O 7/H 2SO 4 / H 2O E. NaBH 4 F. LiAlH 4 1
2 9. Compound A, C 6H 12O, is readily oxidized with K 2Cr 2O 7 in H 2SO 4/H 2O to give compound B, C 6H 10O. Compound B has four peaks in its C-13 NMR (broadband decoupled). Which one of the following fits the data for compound A? 10. The alcohol product(s) of the reduction of 2-methyl-3-pentanone with LiAlH 4 is(are) A. a single enantiomer. B. a racemic mixture. C. two diastereomers. D. two constitutional isomers. 11. Which of the following syntheses gives 3-methyl-1-hexanol? 12. Which of the following reagents will convert cyclohexene into cis-1,2-cyclohexanediol? A. OsO 4, () 3CO, () 3C, B. HIO 4 C. O 3 followed by Zn/H 2O D. CO 3H (peroxyacetic acid) 13. What is the product of the following reaction sequence? A. cyclopentene oxide B. cyclopentene C. cyclopentane D. cis-1,2-cyclopentanediol 14. To which side, if any, would the reaction below lie? A. to the right B. to the left C. equally to both sides D. this reaction cannot occur 2
3 15. Which of the following is the ester formed between methanol and nitric acid, HNO 3? 16. The lithium aluminum hydride reduction of this ester would yield: O O 1. LiAlH 4 2. H 2 O? 17. What product(s) would you expect from the following reaction? 18. Which one of the following reaction steps work best to carry out the transformation shown below? 19. What is the product of the synthetic sequence below? 3
4 20. Which of the following would be true of the reaction shown? A. A carbon is oxidized in this reaction. B. A carbon is reduced in this reaction. C. The bromine is oxidized in this reaction. D. The bromine is reduced in this reaction. E. This cannot be considered as an oxidation/reduction reaction. 21. Which of the following reactions would you expect to produce 2-pentanol? A. B. C. D. All of these reactions would produce 2-pentanol. E. Only two of these reactions would produce 2-pentanol. Which ones? 22. What is the major product of the following reaction? 23. What reagents would you use to carry out the following reaction? 24. Which of the following would NOT efficiently accomplish the reaction shown? A. NaH B. Na (metal) C. NH 2 D. K (metal) E. 25. What is the final product of the following reactions? A. 2,3-dimethyl-3-pentanol B. 2,3-dimethyl-2-pentanol C. 2,4-dimethyl-3-pentanol D. 2,2-dimethyl-3-pentanol 4
5 26. Predict the major product of the following reaction. A B C D E 27. Which of the following reactions could be used to make cyclohexanecarbonitrile from cyclohexanol? Two of these would work. Which ones? 28. If the following reaction proceeds as indicated, what mechanistic pathway does it most likely follow? A. E2 B. E1 C. S N2 D. S N1 E. free-radical halogenation 29. What major product would you expect from the following reaction? 30. Which of the alcohols listed below would you expect to react most rapidly with HBr? A. CH 2CH 2CH 2CH 2CH 2 B. (CH 2) 2CH 2CH 2 C. (CH 2) 2CH D. CH 2CH 2CH 2CH 2 E. (CH 2) 2C() 5
6 31. Predict the major product of the following reaction. 32. Which would be the best way to carry out the following synthesis? CH 2 CH? CH 2 CH 2 CH 2 A. (1) HA, heat; (2) H 3O +, H 2O, heat B. (1) () 3COK / () 3C; (2) BH 3:THF, then H 2O 2, - C. (1) () 3COK / () 3C; (2) H 3O +, then H 2O, heat D. (1) K, C 2H 5; (2) BH 3:THF, then H 2O 2, - E. (1) K, C 2H 5; (2) HA, heat; (3) H 3O +, H 2O, heat Br 33. trans-3-methylcyclopentanol is treated with SO 2Cl in the presence of base. The product of this reaction is then heated with KI in methanol. What is the final product? A. trans-1-iodo-3-methylcyclopentane B. cis-1-iodo-3-methylcyclopentane C. 1-Methylcyclopentene D. 2-Methylcyclopentene E. 3-Methylcyclopentene 34. Select the structure of the major product formed from the following reaction. A. I B. II C. III D. IV E. V 1. Hg(OOC ) 2 THF, H 2 O 2. NaBH 4, Na? CH 2 HO I II III IV V 6
7 35. Oxymercuration-demercuration of 3-methylcyclopentene produces this/these product(s): A. I B. II C. III D. IV E. Both III and IV HO CH 2 I II III IV EXTRA CREDIT 36. The tertiary alcohol below was reacted with PCC in CH 2Cl 2 and gave a product, C 12H 12O. The product had a strong absorption in the IR spectrum at 1700 cm -1. Predict which of the following is the product. (Note: PCC is pyridinium chlorochromate, [C 5H 5NH + ][ClCrO 3 ].) 37. (2R,3S )-3-Bromo-2-methyl-1-butanol is the IUPAC name for which of the following alcohols? NAME DATE ANSWER SHEET CHE 325 CHAP 15 ASSIGN SS II
Chemistry 262 Homework 2 Part II Winter 2018
Chemistry 262 Homework 2 Part II Winter 2018 The following homework covers Chapter 10 in Loudon & Parise s Organic Chemistry, 6 th ed. and contains 24 questions, valued at 0.3333 point each, as well as
More informationChemistry 3351 Organic Chemistry/Final Exam Monday: Dec. 17 th from 1:30 pm 4:00pm
- 1 - Chemistry 3351 Organic Chemistry/Final Exam Monday: Dec. 17 th from 1:30 pm 4:00pm Name: (please print, 1 pt) Page Possible Points Score 1 1 2 9 3 10 4 12 5 14 6 14 7 10 8 15 9 10 10 10 11 10 12
More informationCHE 275 REACTIONS OF ALKENES: ADDITION REACTIONS CHAP 8 ASSIGN
HE 275 REATINS F ALKENES: ADDITIN REATINS HAP 8 ASSIGN 1. Which reagent or test could be used to distinguish between 2-methyl-2-pentene and 2-methylpentane? A. Br 2/l 4 B. KMn 4,. oncd. H 2S 4 D. Two of
More informationChapter 8 Alkenes and Alkynes II: Addition Reactions. Alkenes are electron rich. Additions to Alkenes
Additions to Alkenes Chapter 8 Alkenes and Alkynes II: Addition Reactions Generally the reaction is exothermic because one p and one s bond are converted to two s bonds Alkenes are electron rich The carbocation
More informationALCOHOLS AND PHENOLS; ETHERS AND EPOXIDES; THIOLS AND SULFIDES
ALCOHOLS AND PHENOLS; ETHERS AND EPOXIDES; THIOLS AND SULFIDES A STUDENT SHOULD BE ABLE TO: 1. Give the IUPAC name when given the structure, and draw the structure given the name of open-chain and monocyclic
More informationALCOHOLS AND PHENOLS
ALCOHOLS AND PHENOLS ALCOHOLS AND PHENOLS Alcohols contain an OH group connected to a a saturated C (sp3) They are important solvents and synthesis intermediates Phenols contain an OH group connected to
More informationChemistry 51 Summer 2006 Final Exam
Chemistry 51 Summer 2006 Final Exam 1. This is a two-hour, closed book exam. All answers are to be put on the question sheets. 2. Use the backsides of these pages for scratch paper. None other permitted.
More informationA) I B) II C) III D) IV E) V
Exam Name SHORT ANSWER. Write the word or phrase that best completes each statement or answers the question. 1) Complete the following reaction and provide a detailed, step-by-step mechanism for the process.
More informationCHEM 203 Exam 2. Name Multiple Choice Identify the letter of the choice that best completes the statement or answers the question.
CHEM 203 Exam 2 Name Multiple Choice Identify the letter of the choice that best completes the statement or answers the question. 1. What is the IUPAC name of 5-ethyl-2,3-dimethyl-6-hexanol 2-ethyl-4-isopropyl-1-pentanol
More information8. What is the slow, rate-determining step, in the acidcatalyzed dehydration of 2-methyl-2-propanol?
CHEMISTRY 313-03 MIDTERM # 2 answer key October 25, 2011 Statistics: Average: 68 pts (68%); Highest: 100 pts (100%); Lowest: 30 pts (30%) Number of students performing at or above average: 56 (54%) Number
More informationCARBONYL COMPOUNDS: OXIDATION-REDUCTION REACTION
CARBONYL COMPOUNDS: OXIDATION-REDUCTION REACTION Introduction Several functional groups contain the carbonyl group Carbonyl groups can be converted into alcohols by various reactions Structure of the Carbonyl
More informationChapter 7. dehydration
hapter 7 7.1 ne problem with elimination reactions is that mixtures of products are often formed. For example, treatment of 2-bromo-2-methylbutane with K in ethanol yields a mixture of two alkene products.
More informationFINAL EXAM Organic Chemistry Chemistry 225b; 9 A.M., Friday, May 9, NAME (print): Section Day: Section Time:
FINAL EXAM Organic Chemistry Chemistry 225b; 9 A.M., Friday, May 9, 2008 NAME (print): TA: Section Day: Section Time: Take a few moments to look over the exam. Do problems first with which you are most
More informationChapter 8 Alkenes and Alkynes II: Addition Reactions
Chapter 8 Alkenes and Alkynes II: Addition Reactions Introduction: Additions to Alkenes Generally the reaction is exothermic because one π and one σ bond are converted to two σ bonds The π electrons of
More information2. Which one of the following structures represents a different compound from the other three?
1. Provide a Newman projection of the most stable conformation of 2-methylpentane, (CH 3 ) 2 CHCH 2 CH 2 CH 3, looking along the C2-C3 bond 2. Which one of the following structures represents a different
More information(A) 10 (B) 10 (C) 140 (D) 140 (E) 70 7.Calculate the ionization energy, in kj/mol, of a mole of hydrogen atoms in the ground state.
80 1.The term that describes the following series Ne, F -, 2-, and N 3- is (A) Isotopic (C) isobar anionic 2.Which oxide of chlorine is unstable? (B) isoelectronic allotropic (A) Cl 2 (B) Cl 2 3 (C) Cl
More informationChapter 12 Alcohols from Carbonyl Compounds: Oxidation-Reduction and Organometallic Compounds
Chapter 12 Alcohols from Carbonyl Compounds: Oxidation-Reduction and Organometallic Compounds Introduction Several functional groups contain the carbonyl group Carbonyl groups can be converted into alcohols
More informationCHEM 242 ETHERS, EPOXIDES, AND SULFIDES CHAP 17 ASSIGN
CHEM 242 ETHERS, EPOXIDES, AND SULFIDES CHAP 17 ASSIGN 1. Which of the following is the correct name of the compound below? A) benzyl ethyl ether B) ethyl phenyl ether C) ethylbenzene ether D) ethoxy phenoxy
More informationYour course TA (Steve, Jenn-C, Jenn-P):
CHM 1321 Second Midterm April 3, 2008 1 Your Name: Student #: Your course TA (Steve, Jenn-C, Jenn-P): Exercise 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 key 1. Deliver only the solution
More information1) (100 pts) 5) (20 pts) 3) (35 pts) 4) (25pts. Total (200 pts) More Tutorial at
Name: Perm number: Question 1) (100 pts) 2) (20 pts) 3) (35 pts) 4) (25pts 5) (20 pts) Total (200 pts) Your score 1. MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers
More informationC h a p t e r N i n e: Addition Reactions of Alkenes
C h a p t e r N i n e: Addition Reactions of Alkenes. H C 2 H Biosynthesis of a prostaglandin from arachidonic acid: intermediate intramolecular radical addition CHM 321: Summary of Important Concepts
More informationChapter 8 Alkenes and Alkynes II: Addition Reactions "
Chapter 8 Alkenes and Alkynes II: Addition Reactions Additions to Alkenes Generally the reaction is exothermic because one π and one σ bond are converted to two σ bonds Alkenes are electron rich The π
More informationLevel 2 Chemistry, 2015
91165 911650 2SUPERVISOR S Level 2 Chemistry, 2015 91165 Demonstrate understanding of the properties of selected organic compounds 9.30 a.m. Monday 23 November 2015 Credits: Four Achievement Achievement
More informationCHAPTER HYDROCARBONS. Chapterwise Previous year Qs. (a) Na (b) HCl in H2O (c) KOH in C2H5OH (d) Zn in alcohol. Ans: (c)
122 CHAPTER HYDROCARBONS 1. Acetylenic hydrogens are acidic because [1989] Sigma electron density of C Hbond in acetylene is nearer to carbon, which has 50% s- character Acetylene has only open hydrogen
More informationBut in organic terms: Oxidation: loss of H 2 ; addition of O or O 2 ; addition of X 2 (halogens).
Reactions of Alcohols Alcohols are versatile organic compounds since they undergo a wide variety of transformations the majority of which are either oxidation or reduction type reactions. Normally: Oxidation
More informationHomework - Chapter 14 Chem 2320
omework - Chapter 14 Chem 2320 Name 1. Label each alcohol in the the following compounds as primary, secondary, tertiary, enol, or aryl. 2. Fill in the blanks in the following sentences. Enols are in equilibrium
More informationCH Organic Chemistry I (Katz) Practice Exam #3- Fall 2013
C2710 - rganic Chemistry I (Katz) Practice Exam #3- all 2013 Name: Score: Part I - Choose the best answer and write the letter of your choice in the space provided. (32 pts) 1. f the following, which reaction
More informationDAMIETTA UNIVERSITY CHEM-103: BASIC ORGANIC CHEMISTRY LECTURE
DAMIETTA UNIVERSITY CHEM-103: BASIC ORGANIC CHEMISTRY LECTURE 6 Dr Ali El-Agamey 1 Oxidation States Easy for inorganic salts: CrO 4 2- reduced to Cr 2 O 3. KMnO 4 reduced to MnO 2. Oxidation: Gain of O,
More informationChem 2320 Final 210 points Dr. Luther Giddings
Chem 2320 Final 210 points Dr. Luther Giddings Name Phone or E-Mail Instructions: This is a closed book, closed notebook test. You may not discuss this exam with anyone, either during or after the exam,
More information2. Which of the following is an intermediate in the Markovnikov addition of HBr to 2- methylcyclohexene?
Quiz 7.1 Alkene Additions and Hydrohalogenations 1. Which is the most stable carbocation? 2. Which of the following is an intermediate in the Markovnikov addition of HBr to 2- methylcyclohexene? 3. What
More informationi. NaCN ii. 70% H 2 SO 4, reflux
CHE 325 CARBXYLIC ACID CHAP 18 AIGN 1. In which of the following sequences are the compounds listed in order of decreasing acidity? A. CH 3CH > H 2 > CH 3CH 2H > HC CH > NH 3 B. CH 3CH 2H > CH 3CH > H
More informationExam 2 Chem 109a Fall 2004
Exam 2 Chem 109a Fall 2004 Please put your name and perm number on both the exam and the scantron sheet. Next, answer the following 34 multiple-choice questions on the scantron sheet. Then choose one A-type
More informationB. A transition state represents a maximum on the reaction path diagram and can be isolated.
Practice Hour Exam 2, Chemistry 2210, Organic Chemistry I 1. The most stable carbocation is: 2. Which of the following statements is true of transition states? A. A transition state represents a minimum
More informationmuch more stable then the
8.1 Give the structure and name of the product that would be obtained from the ionic addition of I to propene. I I I 8.3 Provide mechanistic explanations for the following observations:(a)the addition
More informationPhysical Properties. Alcohols can be: CH CH 2 OH CH 2 CH 3 C OH CH 3. Secondary alcohol. Primary alcohol. Tertiary alcohol
Chapter 10: Structure and Synthesis of Alcohols 100 Physical Properties Alcohols can be: CH 3 CH 3 CH CH 2 OH * Primary alcohol CH 3 OH CH * CH 2 CH 3 Secondary alcohol CH 3 CH 3 * C OH CH 3 Tertiary alcohol
More informationPart I. Multiple choice. (4 points each.) Choose the one best answer and mark your answer on the ScanTron sheet.
Test 3 Chemistry 2321 April 25, 2003 McMurry, Chapters 9-11 103 Total Points Name Please Print Part I. Multiple choice. (4 points each.) Choose the one best answer and mark your answer on the ScanTron
More informationUnit 2 Review: Organic Chemistry. 1. Terms for which you should be able to write or apply the definitions:
Unit 2 Review: Organic Chemistry 1. Terms for which you should be able to write or apply the definitions: organic compound aliphatic hydrocarbons saturated miscible functional group aromatic hydrocarbons
More informationAs time allows, additional practice questions for Exam 2 follow. This is an incomplete collection. Content & emphasis will vary.
Chem 226 Exam 2 Fall 2005: will cover Bruice, Chaps 3 through 6; Note: review e-mail & inclass quizzes and Worksheets, suggest on-line practice questions and quizzes plus ACS rganic Chemistry Guide As
More informationA. IV > III > II > I B. IV > II > III > I C. III > IV > II > I D. III > IV > I > II
Practice Final Exam, Chemistry 2220, Organic Chemistry II 1. Rank the designated protons by 1 H NMR chemical shift ( ), highest first. A. IV > III > II > I B. IV > II > III > I C. III > IV > II > I D.
More informationIB Topics 10, 20 & 21 MC Practice
IB Topics 10, 20 & 21 MC Practice 1. What is the major product of the reaction between HCl and but-2-ene? 1,2-dichlorobutane 2,3-dichlorobutane 1-chlorobutane 2-chlorobutane 2. Which compound can be oxidized
More informationIntroduction & Definitions Catalytic Hydrogenations Dissolving Metal Reduction Reduction by Addition of H- and H+ Oxidation of Alcohols Oxidation of
CEM 241- UNIT 4 xidation/reduction Reactions Redox chemistry 1 utline Introduction & Definitions Catalytic ydrogenations Dissolving Metal Reduction Reduction by Addition of - and + xidation of Alcohols
More informationOrganic Chemistry 1 CHM 2210 Exam 4 (December 10, 2001)
Exam 4 (December 10, 2001) Name (print): Signature: Student ID Number: There are 12 multiple choice problems (4 points each) on this exam. Record the answers to the multiple choice questions on THIS PAGE.
More informationc. Cyclohexanone Chemistry 262 Homework 2 Part II Winter 2018
Chemistry 262 Homework 2 Part II Winter 2018 The following homework covers Chapter 10 in Loudon & Parise s Organic Chemistry, 6 th ed. and contains 24 questions, valued at 0.3333 point each, as well as
More informationOrganic Chemistry. REACTIONS Grade 12 Physical Science Mrs KL Faling
Organic Chemistry REACTIONS Grade 12 Physical Science Mrs KL Faling SUBSTITUTION REACTIONS This is a reaction where an atom or group of atoms is replaced by another atom or group of atoms Substitution
More informationUNIVERSITY OF SWAZILAND FINAL EXAMINATION 2013, DECEMBER
UNIVERSITY OF SWAZILAND FINAL EXAMINATION 2013, DECEMBER TITLE OF PAPER COURSE NUMBER Introductory Organic Chemistry C203 TIME Three Hours INSTRUCTIONS Section A is compulsory. Answer any three questions
More informationLearning Guide for Chapter 11 - Alkenes I
Learning Guide for Chapter 11 - Alkenes I I. Introduction to alkenes - p 1 bond structure, classifying alkenes, reactivity, physical properties, occurrences and uses, spectroscopy, stabilty II. Unsaturation
More informationREACTION AND SYNTHESIS REVIEW
REACTION AND SYNTHESIS REVIEW A STUDENT SHOULD BE ABLE TO PREDICT PRODUCTS, IDENTIFY REACTANTS, GIVE REACTION CONDITIONS, PROPOSE SYNTHESES, AND PROPOSE MECHANISMS (AS LISTED BELOW). REVIEW THE MECHANISM
More informationCHE 325 ALDEHYDES AND KETONES I CHAP 18 ASSIGN OCH 3 HCN C 4 H 7 NO. would be: CH 3 B. CH 3CH 2COOCH 3
CE 325 ALDEYDES AND KETNES I CAP 18 ASSIGN 1. What is the correct IUPAC name for the following compound A. 2-Methyl-5-heptanone B. 7-Methyl-4-octanone C. 6-Isopropyl-4-octanone D. Isobutyl propyl ketone
More informationCH320/328 M Spring 2014
CH320/328 M Spring 2014 HW Set #3 Multiple Choice Identify the choice that best completes the statement or answers the question. There is only one correct response for each question. Carefully record your
More informationChapter 1 Reactions of Organic Compounds. Reactions Involving Hydrocarbons
Chapter 1 Reactions of Organic Compounds Reactions Involving Hydrocarbons Reactions of Alkanes Single bonds (C-C) are strong and very hard to break, therefore these compounds are relatively unreactive
More informationModule9. Nuclear Magnetic Resonance Spectroscopy Nuclear Magnetic Resonance (NMR) spectroscopy - Chemical shift - Integration of signal area
1 CHEMISTRY 263 HOME WORK Lecture Topics: Module7. Hydrogenation of Alkenes The Function of the Catalyst - Syn and anti- addition Hydrogenation of Alkynes - Syn- addition of hydrogen: Synthesis of cis-alkenes
More informationReactions of Chapter 10 Worksheet and Key
1) Alcohol Fermentation Reactions of Chapter 10 Worksheet and Key Alcohol fermentation is a series of chemical reaction that convert sugar molecules, such a glucose, into ethanol and C 2. The overall reaction
More informationTest Bank for Organic Chemistry 2nd Edition by Klein
Test Bank for Organic Chemistry 2nd Edition by Klein Chapter Fourteen Topic: Introduction to Ethers Section: 14.1 1. Which of the following compounds is(are) classified as ethers? & IV D) I & III E) all
More informationChapter 8 - Alkenes and Alkynes II Addition Reactions of Alkenes - Electrons in the π bond of alkenes react with electrophiles
Andrew Rosen Chapter 8 - Alkenes and Alkynes II 8.1 - Addition Reactions of Alkenes - Electrons in the π bond of alkenes react with electrophiles 8.2 - Electrophilic Addition of Hydrogen Halides to Alkenes:
More informationChemistry 2.5 AS WORKBOOK. Working to Excellence Working to Excellence
Chemistry 2.5 AS 91165 Demonstrate understanding of the properties of selected organic compounds WORKBOOK Working to Excellence Working to Excellence CONTENTS 1. Writing Excellence answers to Cis-Trans
More informationCHEM 241 ALKYNES CHAP 9 ASSIGN
HEM 241 ALKYNES HAP 9 ASSIGN 1. What is the IUPA name of the following compound A. 5-propyl-3-heptyne B. 5-isopropyl-3-heptyne. 5-ethyl-3-octyne D. 4-ethyl-5-octyne 2. What is the correct IUPA name for
More informationAlcohols. Contents. Structure. structure
Page 1 of 9 Alcohols Contents structure Physical Properties Classification of Alcohols Nomenclature of Alcohols Preparation of Alcohols Oxidation of Alcohols oxidation of aldehydes Structure Alcohols can
More informationPractice Multiple-Choice Questions for Ending Chem 21 and/or Starting Chem 22
Practice Multiple-Choice Questions for Ending Chem 21 and/or Starting Chem 22 Includes information from chapters 5-10 of the third edition of Klein s Organic Chemistry text. 1. Which of the following compounds
More informationCHAPTER 3 ALKENES, ALKYNES & CONJUGATE DIENES
CHEM 244 PRINCIPLES OF ORGANIC CHEMISTRY I FOR CHEMICAL ENGINEERING STUDENTS, COLLEGE OF ENGINEERING PRE-REQUISITES COURSE; CHEM 101 CREDIT HOURS; 2 (2+0) Dr. Mohamed El-Newehy Chemistry Department, College
More informationHomework - Review of Chem 2310
omework - Review of Chem 2310 ame 1. Fill in the following partial Periodic Table of Table of Elements. Do as much as you can from memory. 2. Using the Table above, circle the more electronegative atom
More informationLevel 2 Chemistry, 2014
91165 911650 2SUPERVISOR S Level 2 Chemistry, 2014 91165 Demonstrate understanding of the properties of selected organic compounds 2.00 pm Tuesday 11 November 2014 Credits: Four Achievement Achievement
More informationCh 17 Alcohols and Phenols
Ch 17 Alcohols and Phenols Alcohols are compounds with a hydroxyl group (OH) attached to an sp 3 C. Phenols are compounds with a hydroxyl group (OH) attached to an aromatic sp 2 C. Classification of Alcohols
More informationChapter 7. Alkenes: Reactions and Synthesis
Chapter 7. Alkenes: Reactions and Synthesis 1 Synthesis of Alkenes: Elimination Reactions 1. Dehydrohalogenation of alkyl halides. loss of requires CH 2 CH 2 Cl Zaitsev s Rule: CH 2 C 2. Dehydration of
More informationInternational School of Johannesburg. Diploma Chemistry. Organic Chemistry (HL) Revision Questions. D. ( HNCH 2 CH 2 NHCOCH 2 NH ) (Total 1 mark)
International School of Johannesburg Diploma Chemistry Organic Chemistry (HL) Revision Questions 1. The compounds H 2 NCH 2 CH 2 NH 2 and HOOCCH 2 COOH react to form a polymer. What is the structure of
More informationLearning Guide for Chapter 14 - Alcohols (I)
Learning Guide for Chapter 14 - Alcohols (I) I. Introduction to Alcohols and Thiols II. Acid/base Behavior of Alcohols, Phenols, and Thiols III. Nomenclature of Alcohols IV. Synthesis of Alcohols Previous
More informationFinal Exam CHM1321-B. Date: July 4th Length: 3 hrs Last Name:
Pavillon d Iorio all Final Exam CM1321-B Date: July 4th Length: 3 hrs Last Name: Professor Sandro Gambarotta Name: First Student # Seat # - Instructions: ( all information that will be useful) Examples:
More informationCHAPTER 20: MORE ABOUT OXIDATION REDUCTION REACTIONS Oxidation Reduction Reactions of Organic Compounds: An Overview
CHAPTER 20: MORE ABOUT OXIDATION REDUCTION REACTIONS In an oxidation-reduction reaction (redox reaction), one species loses electrons and one gains electrons. The species that loses electrons is oxidized,
More information6 Synthesis of Alcohols
6 Synthesis of Alcohols 6.1 Synthesis of Saturated Alcohols Hydroboration-oxidation is now a standard method for anti-markovnikov s cishydration [1] of alkenes from the less hindered side of the double
More informationPage 2. Q1.Consider the five cyclic compounds, A, B, C, D and E. The infrared spectra of compounds A, B, C and D are shown below.
Q1.Consider the five cyclic compounds, A, B, C, D and E. (a) The infrared spectra of compounds A, B, C and D are shown below. Write the correct letter, A, B, C or D, in the box next to each spectrum. You
More informationUnit 5: Organic Chemistry
Unit 5: Organic Chemistry Organic chemistry: discipline in chemistry focussing strictly on the study of hydrocarbons compounds made up of carbon & hydrogen Organic compounds can contain other elements
More informationChapter 8 Alkenes and Alkynes II: Addition Reactions. Alkenes are electron rich. Additions to Alkenes
Additions to Alkenes hapter 8 Alkenes and Alkynes II: Addition eactions Generally the reaction is exothermic because one π and one σ bond are converted to two σ bonds Alkenes are electron rich The carbocation
More informationpent-2-ene CH 3CH = CHCH 2CH 3 3-methylbut-1-ene (CH 3) 2CHCH = CH 2 2-methylbut-2-ene (CH 3) 2C = CHCH 3 2-methylbut-1-ene H 2C = C(CH 3)CH 2CH 3
Q1.The following table gives the names and structures of some structural isomers with the molecular formula C 5H 10. Name of isomer Structure 1 pent-2-ene CH 3CH = CHCH 2CH 3 2 cyclopentane 3 4 5 3-methylbut-1-ene
More informationCHEM 2312 practice final. Version - II
EM 2312 practice final Version - II The following standardized final examination covers the entire introductory year of organic chemistry (EM 2311 and 2312 at Georgia Tech). The exam consists of 70 multiple
More information(Neither an oxidation or reduction: Addition or loss of H +, H 2 O, HX).
eactions of Alcohols Alcohols are versatile organic compounds since they undergo a wide variety of transformations the majority of which are either oxidation or reduction type reactions. xidation is a
More informationEXPERIMENT 8 Reactions of Hydrocarbons
EXPERIMENT 8 Reactions of Hydrocarbons Properties and Identification of Hydrocarbons Purpose: a) To identify saturated and unsaturated hydrocarbons using properties and reactions. b) Study substitution
More informationUnit - 11 ALCOHOLS, PHENOLS AND ETHERS 1. Write IUPAC names of the following compounds : (ix) C 6 H 5 OC 3 H 7 (x) O Cl 2. Write the structures of the compounds whose names are given below : (i) 3, 5-dimethoxyhexane-1,
More informationChapter 17: Alcohols and Phenols. Based on McMurry s Organic Chemistry, 7 th edition
Chapter 17: Alcohols and Phenols Based on McMurry s Organic Chemistry, 7 th edition Alcohols and Phenols Alcohols contain an OH group connected to a a saturated C (sp 3 ) They are important solvents and
More informationCHE 325 ORGANOMETALLIC COMPOUNDS CHAP 15 ASSIGN. , would be? CH 3 CHOCH 2 CH 2 OH CH 3 CHCH 2 CH 2 OH A B C D E
HE 325 RGNMETLLI MPUNDS HP 15 SSIGN 1. The final product, D, in the following reaction sequence, H 2 H 2 HH P 3 Mg ether B H 3 D, would be? HH 2 H 2 H HH 2 H 2 HH 2 H 2 H HH 2 HH 2 B D E 2. What is the
More informationCHE 275 NUCLEOPHILIC SUBSTITUTUION CHAP 8 ASSIGN. 1. Which best depicts the partial charges on methyl bromide and sodium methoxide?
CHE 275 NUCLEPHILIC SUBSTITUTUIN CHAP 8 ASSIGN 1. Which best depicts the partial charges on methyl bromide and sodium methoxide? 2. Which of the following would be the best (most reactive) nucleophile
More informationTest Bank for Organic Chemistry 8th Edition by Wade
Test Bank for Organic Chemistry 8th Edition by Wade Link download full: https://testbankservice.com/download/test-bankfororganic-chemistry-8th-edition-by-wade/ Organic Chemistry 8th Edition Test Bank Wade
More informationPractice Packet Unit 11: Organic Chemistry
Regents Chemistry: Mr. Palermo Practice Packet Unit 11: Organic Chemistry www.mrpalermo.com 1 LESSON 1: Introduction to Organic Chemistry 1. How many times does carbon bond and why? 2. A student investigated
More information11.5 PREPARATION AND OXIDATIVE CLEAVAGE OF GLYCOLS
11.5 PEPAATIN AND XIDATIVE EAVAGE F GY 50 These reactions also provide methods for the formation of carbon carbon bonds. eactions that form carbon carbon bonds are especially important in organic chemistry
More informationALDEHYDES AND KETONES
ALDEHYDES AND KETONES IN WEEK 1, A STUDENT SHOULD BE ABLE TO: 1. Give the IUPAC name given the structure, and draw the structure given the name, of aldehydes and ketones. Also, draw the structure given
More informationCHEM Exam 2 ANSWER KEY
CEM 3311-200 Exam 2 ANSWER KEY ctober 23, 2012 Time: 2 ours Please copy and sign the onor Pledge on the scantron sheet in the space below the double lines. I pledge that n my honor, as a University of
More informationI. Multiple Choice Questions (Type-I)
Unit 13 HYDROCARBONS I. Multiple Choice Questions (Type-I) 1. Arrange the following in decreasing order of their boiling points. (A) n butane (B) 2 methylbutane (C) n-pentane (D) 2,2 dimethylpropane A
More informationAlcohols, Phenols, and Thiols
7 Alcohols, Phenols, and Thiols hapter Summary The functional group of alcohols and phenols is the hydroxyl group. In alcohols, this group is connected to an aliphatic carbon, whereas in phenols, it is
More information9. Which compound is an alcohol? A) methanol C) butane B) ethyne D) propanal
1. Given the structural formulas for two organic compounds: The differences in their physical and chemical properties are primarily due to their different A) number of hydrogen atoms B) number of carbon
More informationChemistry 2541, Fall 2017 Midterm Exam 3 (100 points)
Important notes: Chemistry 2541, Fall 2017 Midterm Exam 3 (100 points) - Please use the provided Scantron form for your answers; you can keep the sheet with the questions and can use it as scratch paper
More informationChemistry 210 Organic Chemistry I Fall Semester 2000 Dr. Rainer Glaser
Chemistry 210 Organic Chemistry I Fall Semester 2000 Dr. Rainer Glaser Examination #3 Alkenes and Alkynes. Structure, Synthesis and Reactions. Friday, November 17, 2000, 9:00-9:50 Name: Question 1. Alkenes
More informationLearning Guide for Chapter 12 - Alkenes (II)
Learning Guide for Chapter 12 - Alkenes (II) I. Addition reactions of alkenes Introduction to addition reactions Catalytic hydrogenation of alkenes Hydroxylation of alkenes Epoxidation of alkenes Cyclopropanation
More information15.1: Hydrocarbon Reactions
15.1: Hydrocarbon Reactions Halogenation An alkane will react with a halogen to produce a halalkane and the corresponding hydrogen halide. The catalyst is ultraviolet radiation. Reaction 1 methane chlorine
More informationSynthesis and Structure of Alcohols Alcohols can be considered organic analogues of water.
Synthesis and Structure of Alcohols Alcohols can be considered organic analogues of water. Alcohols are usually classified as primary, secondary and tertiary. Alcohols with the hydroxyl bound directly
More informationChapter 3. Alkenes And Alkynes
Chapter 3 Alkenes And Alkynes Alkenes ydrocarbons containing double bonds C C double bond the functional group center of reactivity Molecular Formula of Alkene Acyclic alkene: C n 2n Cyclic alkene: C n
More informationFinal Exam Professor R. Hoenigman
I pledge to uphold the CU onor Code: CEM 3311-100 Spring 2007 Final Exam Professor R. oenigman Signature Name (printed) Last four digits of your student ID number Recitation TA Recitation number, day,
More informationChem 30A Winter Mon March 21st
Last Name First Name MI Student ID Number: Total Score / 200 Chem 30A Winter 2005 FINAL (180 Min) Mon March 21st Course Grade ***DO NOT OPEN THIS EXAM UNTIL INSTRUCTED TO DO SO*** ONLY ANSWERS WRITTEN
More informationAlcohol Synthesis. Dr. Sapna Gupta
Alcohol Synthesis Dr. Sapna Gupta Synthesis of Alcohols Alcohols can be synthesized from several functional groups. Nucleophilic substitution of O - on alkyl halide ydration of alkenes water in acid solution
More information2/26/18. Practice Questions. Practice Questions B F. How many steps are there in this reaction?
Practice Questions Practice Questions D B F C E A G How many steps are there in this reaction? 1 Practice Questions D B F C E A G What is the highest-energy transitions state? Practice Questions D B F
More informationThis is a long exam. Most students will not finish each problem. Carefully select your problems to work on.
Chemistry 51 Exam 1, Spring 2008 =============================================== This is a closed book exam. The exam lasts 75 minutes. All answers must appear on the answer sheet. Only the answer sheet
More informationCHEM 241 ALCOHOLS AND ALKYL HALIDES CHAP 5 ASSIGN
CEM 241 ALCOOLS AND ALKYL ALIDES CAP 5 ASSIGN 1. What is the IUPAC name of the compound below? A. 3-isobutyl-2-hexanol B. 2-methyl-5-propyl-6-heptanol C. 2-methyl-5-(1-hydroxyethyl)octane D. 6-methyl-3-propyl-2-heptanol
More informationAlcohols Classification
Alcohols Alcohols are compounds of the general formula ROH, where R is any alkyl or substituted alkyl group. The group may be primary, secondary, or tertiary; it may be open-chain or cyclic; it may contain
More information