(Kertas soalan ini mengandungi 6 soalan dalam 7 halaman yang bercetak) (This question paper consists of 6 questions on 7 printed pages)
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1 UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE SESI AKADEMIK 2016/2017 ACADEMIC SESSION 2016/2017 : SEMESTER I : SEMESTER I SCES3363 : TOPIK-TOPIK KHAS KIMIA SPECIAL TOPICS IN CHEMISTRY Dis 2016/Jan 2017 Dec 2016/Jan 2017 Masa: 2 jam Time: 2 hours ARAHAN KEPADA CALON: INSTRUCTIONS TO CANDIDATES: Kertas soalan ini mengandungi Bahagian A dan B. This paper consists of Section A and B. Jawab soalan mengikut arahan yang diberikan di dalam setiap bahagian. Question should be answered according to the instructions given in each section. (Kertas soalan ini mengandungi 6 soalan dalam 7 halaman yang bercetak) (This question paper consists of 6 questions on 7 printed pages)
2 BAHAGIAN A (50 MARKAH) SECTION A (50 MARKS) Jawab SEMUA soalan di Seksyen A. Answer ALL questions in Section A. 1. (a) Takrifkan haptasiti, η. Define hapticity, η. Dengan menggunakan logam dan ligan berikut yang sesuai: By using suitable metals and ligands below: 24Cr; 26Fe; 27Co; 42Mo; 44Ru PPh 3 ; benzene, cyclooctadiene (COD); cyclooctatetraene (COT); pentamethylcyclopentadienyl (Cp*) (i) Lukiskan struktur kompleks logam yang menunjukkan koordinasi η 1 ; η 4 dan η 6. Draw the structures of metal complexes that have η 1, η 4 and η 6 coordinations. (ii) Untuk setiap kompleks di (i), buktikan ia mematuhi aturan 18- elektron. For each complex in (i), show that the 18-electron rule is obeyed. (12 markah/marks) (c) Namakan TIGA (3) unsur nadir-bumi yang terdapat dalam telefon pintar and jelaskan fungsinya di dalam peranti ini. Name THREE (3) rare-earth elements present in a typical smartphone and describe their functions or roles in the gadget. 2. (a) Fosforus adalah salah satu unsur yang penting dan penuh dengan pelbagai misteri. Jelaskan sejarah penemuannya dan beberapa kegunaannya pada ketika itu. Phosphorus is a very important element and its discovery was full of mysteries. Describe a historical background on its discovery and its uses at that period. (6 markah/marks) 2/7
3 Posfa-alkuna adalah suatu ligan yang sangat vesatil. Tunjukkan kedudukan yang mungkin untuk ligan ini terkoordinat dengan pusat logam. Phospha-alkyne, t BuC P is a very versatile ligands. Indicate the possible coordination sites for this ligand to bind towards metal centres. Show with examples FOUR (4) phospha-alkynes metal complexes that showed different modes of coordination towards transition metal complexes. (9 markah/marks) 3. (a) Tulis satu nota ringkas tentang kegunaan logam atau kompleks logam untuk SATU dari bidang-bidang berikut: Write a brief note on the use of metals or their complexes in ONE of the following fields: (i) (ii) perubatan; dan medicine; and agen anti-bakteria. anti-bacterial agents. Kenalpasti logam atau kompleks logam khusus yang digunakan dan fungsinya di bidang-bidang ini. Indicate the specific metals or their complexes that were used and their specific applications in those fields. (9 markah/marks) Apakah unsur X dan Y pada sebatian berikut: What are elements X and Y in the following compounds: Sebatian/Compound A 3/7
4 Sebatian/Compound B Apakah kegunaan utama Sebatian A dan B di bidang perubatan? What are the main uses of Compound A and B in medicine? (6 markah/marks) 4/7
5 BAHAGIAN B (50 MARKAH) SECTION B (50 MARKS) Jawab SEMUA soalan. Answer ALL questions. 4. (a) (i) Mengapakah sebatian azo (Ph-N=N-Ph) yang mempunyai satu ikatan N=N- antara dua gelang benzena adalah sebatian berwarna? Why azo compounds (Ph-N=N-Ph) containing a -N=N- bridge between two benzene rings are coloured compound? (ii) Metil jingga adalah sejenis sebatian azo dan wujud dalam dua bentuk (A dan B) satu bentuk adalah sebatian berwarna merah dan satu lagi adalah berwarna kuning. Tentukan warna sebatian A dan B. Jelaskan. Methyl orange is an azo compound and comes in two forms (A and B). One form compound is red and the other is yellow. Assign the colour of compounds A and B. Justify. (iii) Alizarian dan Indigo adalah pewarna semulajadi. Lukis stuktur kimia bagi kedua sabatian ini. Alizarin and Indigo are natural dyes. Draw the chemical structures for both the compounds. 5/7
6 Lukis struktur kimia bagi DUA ubatan sulfa dan beri aktiviti biologinya. Draw the chemical structure for TWO sulfa drugs and assign their biological activities. (8 markah/marks) 5. Tentukan bahan uji semua tindak balas dan hasil (C-G) bagi tindak balas di bawah. Give all the reagents, reactant and products (C-G) of the following reactions: (a) (c) (d) (10 markah/marks) 6/7
7 6. Amina aromatik seperti 4-kloroanalina adalah sebatian perantara di dalam penghasilan pewarna azo. Aromatic amines such as 4-chloroaniline are intermediates in the manufacture of azo dyes. (a) Cadangkan satu penyedian 4-kloroanalina dari benzene. Propose the preparation of 4-chloroaniline from benzene. (6 markah/marks) 4-kloroanalina boleh ditukarkan kepada ion diazonium. Beri reagen yang digunakan dalam tindak balas dan lukis struktur ion diazonium. 4-chloroaniline can be converted into a diazonium ion. State the reagents used in the reaction and draw the structure of the diazonium ion. (c) Ion diazonium boleh bertindak balas dengan fenol dalam larutan alkali akueus untuk membentuk pewarna azo. The diazonium ion can be reacted with phenol in aqueous alkali to form an azo dye. (i) Lukis struktur kimia pewarna azo. Draw the chemical structure of the azo dye. (2 markah/marks) (ii) Cadangkan mekanisme tindak balas. Propose the reaction mechanism. (5 markah/marks) (d) Apakah hasil reduksi bagi ion 4-klorofil diazonium di bawah penggunaan reagen Sn/HCI? What is the reduction product of 4-chlorophenyl diazonium ion using Sn/HCl reagent? (3 markah/marks) TAMAT END 7/7
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UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE PEPERIKSAAN IJAZAH SARJANA MUDA SAINS DENGAN PENDIDIKAN EXAMINATION FOR THE
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UNIVERSITI MALAYA UNIVERSITY F MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATIN FR THE DEGREE F BACHELR F SCIENCE SESI AKADEMIK 2016/2017 ACADEMIC SESSIN 2016/2017 : SEMESTER I : SEMESTER I SCES3336
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UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE PEPERIKSAAN IJAZAH SARJANA MUDA SAINS DENGAN PENDIDIKAN EXAMINATION FOR THE
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UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE PEPERIKSAAN IJAZAH SARJANA MUDA SAINS DENGAN PENDIDIKAN EXAMINATION FOR THE
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UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE PEPERIKSAAN IJAZAH SARJANA MUDA SAINS DENGAN PENDIDIKAN EXAMINATION FOR THE
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UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE PEPERIKSAAN IJAZAH SARJANA MUDA SAINS DENGAN PENDIDIKAN EXAMINATION FOR THE
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UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE SESI AKADEMIK 2010/2011 : SEMESTER 1 ACADEMIC SESSION 2010/2011 : SEMESTER
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UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE SESI AKADEMIK 2015/2016 : SEMESTER 2 ACADEMIC SESSION 2015/2016 : SEMESTER
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UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE PEPERIKSAAN IJAZAH SARJANA MUDA SAINS DENGAN PENDIDIKAN EXAMINATION FOR THE
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UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE PEPERIKSAAN IJAZAH SARJANA MUDA SAINS DENGAN PENDIDIKAN EXAMINATION FOR THE
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UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE PEPERIKSAAN IJAZAH SARJANA MUDA SAINS DENGAN PENDIDIKAN EXAMINATION FOR THE
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UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE SESI AKADEMIK 2015/2016 ACADEMIC SESSION 2015/2016 : SEMESTER II : SEMESTER
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UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE PEPERIKSAAN IJAZAH SARJANA MUDA SAINS DENGAN PENDIDIKAN EXAMINATION FOR THE
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