Jawab soalan mengikut arahan yang diberikan dalam setiap bahagian. Questions should be answered according to the instructions given in each section.
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1 UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE PEPERIKSAAN IJAZAH SARJANA MUDA SAINS DENGAN PENDIDIKAN EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE WITH EDUCATION SESI AKADEMIK 2016/2017 : SEMESTER 1 ACADEMIC SESSION 2016/2017 : SEMESTER 1 SCES2210/SIC2001 : KIMIA TAKORGANIK II INORGANIC CHEMISTRY II Dis 2016/Jan 2017 Dec 2016/Jan 2017 MASA : 3 jam TIME : 3 hours ARAHAN KEPADA CALON : INSTRUCTIONS TO CANDIDATES : Kertas soalan ini mengandungi Bahagian A, B dan C. This paper consists of Section A, B and C. Jawab soalan mengikut arahan yang diberikan dalam setiap bahagian. Questions should be answered according to the instructions given in each section. (Kertas soalan ini mengandungi 7 soalan dalam 6 halaman yang dicetak) (This question paper consists of 7 questions on 6 printed pages)
2 BAHAGIAN A (34 MARKAH) SECTION A (34 MARKS) Jawab SEMUA soalan. Answer ALL questions. 1. Satu ion kompleks terbentuk daripada satu ion Fe 3+, dua ion CN - dan empat ion NO 2 -. A complex ion is formed from one Fe 3+, two CN - and four NO 2 - ions. (a) Apakah formula struktur dan nama ion kompleks itu? What is the structural formula and name of the complex ion? Kenalpasti jenis pengisomeran dan lukis stuktur isomer yang hadir bagi kompleks ion tersebut. Identify the type of isomerism and draw the isomer structures exhibited by the complex ion. (3 markah/marks) (c) Lukiskan diagram orbital molekul dan kira CFSE bagi ion kompleks tersebut. Draw the molecular orbital diagram and calculate the CFSE for the complex ion. (10 markah/marks) 2. Berdasarkan Teori Medan Hablur, bincangkan mengapa [MnO 4 ] - adalah berwarna gelap. Based on Crystal Field Theory, discuss why [MnO 4 ] - is deeply coloured. 3. (a) Deduksikan simbol ungkapan bagi ion Mn 2+ bebas pada keadaan asas. Deduce the term symbol for the free Mn 2+ ion in the ground state. 2/6
3 Guna gambar rajah Tanabe-Sugano yang sesuai untuk menentukan bilangan puncak spin dibenarkan yang dijangkakan dalam spektrum elektronik suatu larutan akueus ion [Co(H 2 O) 6 ] 2+, dan kenal pasti peralihan yang menghasilkan setiap puncak itu. Use a suitable Tanabe-Sugano diagram to determine the number of spin-allowed peaks expected in the electronic spectrum of an aqueous solution of [Co(H 2 O) 6 ] 2+ ion, and identify the electronic transition responsible for each peak. (10 markah/marks) BAHAGIAN B (33 MARKAH) SECTION B (33 MARKS) Jawab SEMUA soalan. Answer ALL questions. 4. (a) Senaraikan semua unsur simetri bagi ion kompleks [PdCl 4 ] 2-. List all of the symmetry elements for [PdCl 4 ] 2- complex ion. Dengan menggunakan metana sebagai contoh, tunjukkan kaitan S n dengan unsur simetri putaran dan pantulan. By using methane as an example, show the relation between S n with rotation and reflection symmetry elements. (c) Terangkan mengapa [MnCl(CO) 5 ] tidak berada dalam kumpulan titik yang sama dengan [Mn(CO) 6 ]. Explain why [MnCl(CO) 5 ] is not in the same point group with [Mn(CO) 6 ]. (8 markah/marks) (d) Apakah perwakilan tak terturunkan bagi orbital d z 2 dalam ion [Fe(H 2 O) 6 ] 2+? Terangkan jawapan anda. What is the irreducible representation for a d z 2 orbital in [Fe(H 2 O) 6 ] 2+ ion? Explain your answer. 3/6
4 (e) Tentukan bilangan puncak yang dijangka diperhatikan dalam spectrum inframerah bagi molekul NH 3. Jelaskan jawapan anda. Determine the number of peaks expected in the infrared spectrum of NH 3. Explain your answer. (10 markah/marks) Jawab SEMUA soalan dalam bahagian ini. Answer ALL questions in this section. 5. (a) Terangkan ayat berikut: Explain the following statement: BAHAGIAN C (33 MARKAH) SECTION C (33 MARKS) (i) Dalam beberapa hal, zink bukan logam peralihan biasa. Berikan 2 sebabnya. In some respect, zinc is not a typical transition metal. Give 2 reasons. (ii) Kompleks logam peralihan biasanya berwarna-warni. Berikan 3 sebabnya. Transition metal complexes are normally colorful. Give 3 reasons. (3 markah/marks) (iii) Ion FeO 4 2- yang berwarna merah adalah paling stabil dalam larutan alkali tetapi bila dalam larutan neutral atau asid penguraian kepada Fe (III) adalah pesat. The deep red FeO 4 2- ions are most stable in alkali but in neutral or acid solution decomposition to Fe(III) is rapid. (iv) Bagaimanakah logam kromium tulen diekstrak daripada bijihnya? How is pure chromium metal extracted from its ore? 4/6
5 6. (a) Terangkan mengapa V(CO) 6 dijangka tidak stabil? Sebatian jenis ini mungkin akan menjalani pendimeran untuk mengatasi ketakstabilan nya. Berikan satu penjelasan mengapa sebatian divanadium yang tidak ditemui. Explain why V(CO) 6 is expected to be unstable? Compound of this type will probably undergo dimerization to overcome its unstability. Propose an explanation why the divanadium compound is not observed. Apakah keadaan pengoksidaan yang paling stabil untuk mangan? Terangkan mengapa? What is the most stable oxidation state for manganese? Explain why? (c) Bagaimanakah proses parkerizing dijalankan? How is parkerizing process carried out? (d) Mengapakah Mn 2+ mempunyai warna kurang sengit berbanding Fe 3+? Why Mn 2+ has less intense color than Fe 3+? (e) Bagaimanakah nikel Raney dihasilkan? Berikan satu contoh bagaimana ia digunakan. How is Raney nickel produced? Give an example of how it is used. 7. (a) Namakan DUA sumber untuk lantanida dan terangkan secara ringkas bagaimana lantanida diekstrak daripada bijihnya? Name TWO common sources of lanthanides and explain briefly how the lanthanides extracted from their ores? Bandingkan perbezaan kimia lantanida dan aktinida. Compare the differences of lanthanides and actinides chemistry. 5/6
6 TAMAT END 6/6
Jawab soalan mengikut arahan yang diberikan dalam setiap bahagian. Questions should be answered according to the instructions given in each section.
UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE PEPERIKSAAN IJAZAH SARJANA MUDA SAINS DENGAN PENDIDIKAN EXAMINATION FOR THE
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UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE PEPERIKSAAN IJAZAH SARJANA MUDA SAINS DENGAN PENDIDIKAN EXAMINATION FOR THE
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UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE PEPERIKSAAN IJAZAH SARJANA MUDA SAINS DENGAN PENDIDIKAN EXAMINATION FOR THE
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UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE PEPERIKSAAN IJAZAH SARJANA MUDA SAINS DENGAN PENDIDIKAN EXAMINATION FOR THE
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UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE PEPERIKSAAN IJAZAH SARJANA MUDA SAINS DENGAN PENDIDIKAN EXAMINATION FOR THE
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UNIVERSITI MALAYA UNIVERSITY F MALAYA PEPERIKSAAN IJAZA SARJANA MUDA SAINS EXAMINATIN FR TE DEGREE F BACELR F SCIENCE PEPERIKSAAN IJAZA SARJANA MUDA SAINS DENGAN PENDIDIKAN EXAMINATIN FR TE DEGREE F BACELR
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UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE PEPERIKSAAN IJAZAH SARJANA MUDA SAINS DENGAN PENDIDIKAN EXAMINATION FOR THE
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UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE PEPERIKSAAN IJAZAH SARJANA MUDA SAINS DENGAN PENDIDIKAN EXAMINATION FOR THE
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UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE PEPERIKSAAN IJAZAH SARJANA MUDA SAINS DENGAN PENDIDIKAN EXAMINATION FOR THE
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