Supplementary Figure 1 IR Spectroscopy. 1Cu 1Ni Supplementary Figure 2 UV/Vis Spectroscopy. 1Cu 1Ni

Size: px
Start display at page:

Download "Supplementary Figure 1 IR Spectroscopy. 1Cu 1Ni Supplementary Figure 2 UV/Vis Spectroscopy. 1Cu 1Ni"

Transcription

1 Supplementary Figure 1 IR Spectroscopy. IR spectra of 1Cu and 1Ni as well as of the starting compounds, recorded as KBr-pellets on a Bruker Alpha FTIR spectrometer. Supplementary Figure 2 UV/Vis Spectroscopy. UV/Vis spectra of 1Cu and 1Ni recorded in acetonitrile solution at room temperature on a Perkin-Elmer Lambda 2 spectrometer. 1

2 Supplementary Figure 3 Susceptibility temperature product as a function of temperature for 1Cu. The measurement was performed on a teflon-wrapped pressed powder sample in an applied field of 1000 Oe with a Quantum Design MPMS XL7 SQUID magnetometer. The data were corrected for the diamagnetic contribution by using Pascal's constants. 1,0 Brillouin functions 1.8 K 2 K 3 K 5 K 7 K 10 K M / B 0,5 0, H / koe Supplementary Figure 4 Magnetization as a function of field for 1Cu. The measurement was performed on a teflon-wrapped pressed powder sample at various temperatures as indicated in the Figure with a Quantum Design MPMS XL7 SQUID magnetometer. The data were corrected for the diamagnetic contribution by using Pascal's constants. Solid red lines are fits to the Brillouin function with S = ½ and g =

3 a b Intensity (arb. u.) Intensity (arb. u.) Magnetic field (mt) Supplementary Figure 5 CW X-band EPR spectra of 1Cu 1.5%. Experimental CW X-Band EPR spectra (blue solid lines) and easy spin simulations (red dashed lines). The spectra were recorded on a finely ground powder sample of 1Cu 1.5% in evacuated sample tubes at 9.47 GHz on a Bruker EMX spectrometer in Stuttgart. a, Spectrum at 5 K and fit with parameters g = ± 0.002, g = ± 0.001, A = 496 ± 5 MHz, A = 119 ± 5 MHz. b, Spectrum at room temperature and fit with parameters g = ± 0.002, g = ± 0.001, A = 480 ± 5 MHz, A = 115 ± 5 MHz. 3

4 a b c d Intensity (arb. u.) e f Magnetic field (mt) Magnetic field (mt) Supplementary Figure 6 Pulsed Q-band EPR spectra of 1Cu 0.001%. Electron spin echo detected field-swept spectra recorded on 1Cu 0.001% (blue solid lines) and easy spin simulations (red dashed lines) using the parameters g = ± 0.010, g = ± 0.005, A = 500 ± 5 MHz, A = 118 ± 5 MHz. The measurements were performed on a Bruker Elexsys E580 in Frankfurt. Temperatures up to 275 K were achieved with an Oxford Instruments CF935 continuous flow cryostat (cryogenic liquid: He), room temperature measurements were done at approximately 294 K. a, Spectrum recorded at 7 K and GHz. b, Spectrum recorded at 15 K and GHz. c, Spectrum recorded at 50 K and 33.8 GHz. d, Spectrum recorded at 120 K and GHz. e, Spectrum recorded at 200 K and GHz. f, Spectrum recorded at room temperature and GHz. 4

5 Supplementary Figure 7 Hahn echo decay curves of 1Cu 0.001%. Normalized echo intensity as a function of delay time 2τ (Hahn echo sequence) recorded on a powder sample of 1Cu 0.001% at different temperatures. Black solid lines are stretched exponential fits resulting in the coherence times reported in Supplementary Table 1. The measurements were performed at 34 GHz on a Bruker Elexsys E580 in Frankfurt. Temperatures up to 275 K were achieved with an Oxford Instruments CF935 continuous flow cryostat (cryogenic liquid: He), room temperature measurements were done at approximately 294 K. 5

6 Intensity / arb. u. 0,3 0,2 0,1 0,0 1,16 1,20 1,24 1,28 Magnetic Field / T a / arb. units I*I 1 0 I / arb. units 1,0 0,8 0,6 0,4 0,2 0, b / s 15 c T / ms Supplementary Figure 8 Pulsed EPR on 1Cu 1.5%. The measurements were performed at 35 GHz on a homebuilt pulsed Q-band EPR spectrometer in Stuttgart. a, echo detected EPR spectrum recorded at 7 K; b, Hahn echo decay curve at 7 K together with stretched exponential fit, where T M = 3.97 μs, and x = 1.43; c, inversion recovery curve together with a biexponential fit at 7 K, where T 1,f = 2.5 ms and T 1,s = 41 ms. 6

7 Supplementary Figure 9 Nutation measurement of 1Cu 0.001%. Nutation measurement on a powder sample of 1Cu 0.001% at 15 K and different applied powers were performed at 34 GHz on a Bruker Elexsys E580 in Frankfurt. Pulse sequence: nutation pulse - τ nut - π/2 - τ fix - π - τ fix - echo with τ nut = 400 ns, τ fix = 140 ns. 7

8 Supplementary Figure 10 Inversion recovery traces of 1Cu 0.001%. Normalized echo intensity as a function of delay time T (inversion recovery sequence) at different temperatures. Black solid lines are biexponential (for 7-25 K) or monoexponential (for T > 25 K) fit functions resulting in the spin lattice relaxation times reported in Supplementary Table 2. The measurements were performed at 34 GHz on a Bruker Elexsys E580 in Frankfurt. Temperatures up to 275 K were achieved with an Oxford Instruments CF935 continuous flow cryostat (cryogenic liquid: He), room temperature measurements were done at approximately 294 K. 8

9 Intensity / arb. u. 0,05 0,04 0,03 0,02 0,01 0,00 1,16 1,20 1,24 1,28 Magnetic Field / mt a Echo Intensity / arb. u. 1,0 7 K b 50 K 150 K 0, / s 1,5 1,0 0,5 0,0-0,5-1, T / s c Supplementary Figure 11 Pulsed EPR on 1Cu 0.01% D. The measurements were performed at 35 GHz on a homebuilt pulsed Q-band EPR spectrometer in Stuttgart. a, echo detected EPR spectrum recorded at 7 K; b, Hahn echo decay curves together with fit functions at different temperatures; c, inversion recovery curves together with fit functions at different temperatures. Fit functions are bi- (7 K) or monoexponentials (50, 100 K) for both relaxation times and their results are reported in Supplementary Table 3. 9

10 Supplementary Table 1 Coherence times T M and stretch factors for 1Cu 0.001%. Parameters were extracted from fitting Hahn echo decay curves of Supplementary Figure 7 with stretched exponentials. T / K T M / μs x ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± rt ± ± Supplementary Table 2 Spin lattice relaxation times T 1 (fast and slow components) for Cu 0.001%. Parameters were extracted from fitting Inversion recovery traces of Supplementary Figure 10 with biexponential (for 7-25 K) or monoexponential (for T > 25 K) fit functions. T / K T 1,f / μs T 1,s / μs rt

11 Supplementary Table 3 Spin lattice relaxation times T 1 and spin-spin relaxation times T M (fast and slow components in both cases) for Cu 0.01% D. Parameters were extracted from fitting Inversion recovery traces and Hahn echo decays shown in Supplementary Figure 11 with biexponential (for 7 K) or monoexponential (for 50, 100 K) fit functions. T / K T 1,f / μs T 1,s / μs T M,f / μs T M,s / μs 7 7 ± ± ± ± ± ± ± ± 0.2 Supplemetary Methods Synthesis and Analysis All reagents and solvents were used as purchased from commercial sources. Bis-(tetraphenylphosphonium)-bis-(maleonitriledithiolato)cuprate, (PPh 4 ) 2 [Cu(mnt) 2 ] (1Cu): Sodium maleonitriledithiolate (279 mg, 1.5 mmol) was dissolved in 5 ml ethanol and 2 ml demineralized water. Subsequently copper chloride dihydrate (128 mg, 0.75 mmol), dissolved in 5 ml ethanol, and tetraphenylphosphonium bromide (629 mg, 1.50 mmol), dissolved in 15 ml ethanol were added under stirring. The brown product precipitated immediately and was separated from the solution after 5 min by vacuum filtration. Washing of the product with 3 x 5 ml ethanol and drying for 20 h under reduced pressure gave a yield of 576 mg (75.01 % based on Cu). Elemental analysis: found (calcd) for C 59 H 40 CuN 4 P 2 S 4 in %: C: (65.77), H: 3.90 (3.94), N: 5.48 (5.48), S: (12.54). UV/VIS (MeCN): λ max in nm: 478, 430, 369, 348, 317, 275. IR (KBr-pellet): in cm -1 and assignment in brackets: 2195 (ν C N ), 1459 (ν C=C ). Bis-(tetraphenylphosphonium)-bis-(maleonitriledithiolato)nickelate (PPh 4 ) 2 [Ni(mnt) 2 ] (1Ni): The same procedure as described for 1Cu was executed with nickel chloride hexahydrate (178 mg, 0.75 mmol) instead of copper chloride dihydrate. The red compound was isolated with a yield of 614 mg (80.4 % based on Ni). Elemental analysis: found (calcd) for C 59 H 40 NiN 4 P 2 S 4 : C: (66.08), H: 3.94 (3.96), N: 5.46 (5.50), S: (12.60). UV/VIS (MeCN): λ max in nm: 474, 379, 315, 270. IR (KBr-pellet): in cm -1 and assignment in brackets: 2196 (ν C N ), 1479 (ν C=C ). Perdeuterotetraphenylphosphonium bromide PPh 4 Br -d 20 : In a pressure cylinder, deuterated triphenylphosphine ( g, 3.6 mmol) was combined with anhydrous nickel(ii)bromide ( g, 1.8 mmol) and deuterated phenylbromide (0.76 ml, 7.2 mmol). The pressure cylinder was sealed and heated to 180 C for three hours. After cooling, 50 ml of demineralized water was added to the blue-green solid. After stirring for 15 min at 75 C, a watery blue solution and a fawn precipitate formed. The mixture was cooled in an ice bath and extracted with 3 x 50 ml of diethylether. The organic phase of the ether extraction was discarded and the aqueous phase was extracted with 3 x 50 ml chloroform. Subsequently, the solvent of the organic phase was removed and the resulting white solid was dried under reduced pressure. 13 C NMR (500MHz): (t), (td), (td), , ppm. 11

12 Bis-(perdeuterotetraphenylphosphonium)-bis-(maleonitriledithiolato)cuprate (PPh 4 -d 20 ) 2 [Cu(mnt) 2 ] (1CuD): The deuterated compound was synthesized following the same procedure as described for its protonated analogue, except that PPh 4 Br was replaced by d 20 -PPh 4 Br. UV/VIS in DCM: λ max in nm: 482, 388, 373, 328, 323, 287, 276, 268. IR (KBrpellet): in cm -1 and assignment in brackets: 2195 (ν C N ), 1459 (ν C=C ). Bis-(perdeuterotetraphenylphosphonium)-bis-(maleonitriledithiolato)nickelate (PPh 4 -d 20 ) 2 [Ni(mnt) 2 ] (1NiD): The deuterated complex was synthesized following the same procedure as given for its protonated analogue above, where PPh 4 Br was replaced by d 20 - PPh 4 Br. UV/VIS in DCM: λ max in nm: 481, 384, 318, 272, 229. IR (KBr-pellet): in cm -1 and assignment in brackets: 2195 (ν C N ), 1479 (ν C=C ). Doped powder: % of 1Cu in 1Ni (1Cu 0.001% ): Doped powders 1Cu 0.001% were obtained by dissolving compounds 1Cu and 1Ni in the molar ratio : in a minimum volume of acetone, which was subsequently evaporated under reduced pressure. The resulting powders were dried in vacuo and finely ground. Doped powder: 0.01 % of 1CuD in 1NiD (1Cu 0.01% D): Doped powders 1Cu 0.01% D wereobtained similarly to 1Cu 0.001% from 1CuD and 1NiD. Doped single crystal: 1.5 % of 1Cu in 1Ni (1Cu 1.5% ): X-ray quality single crystals were obtained by dissolving compounds 1Cu and 1Ni in the molar ratio 98.5 : 1.5 in a minimum volume of acetone, which was subsequently diluted with the same amount of methanol. Crystals were collected after one week of slow solvent evaporation under ambient conditions. Results of X-ray analysis of 1Cu 1.5% : monoclinic, a = (10), b = (13), c = (12) Å, β = (5), V = (4) Å 3, T = 110 K, space group P2 1 /n, Z = 4, reflections collected, 7183 unique, final R 1 = , wr 2 [I > 2σ(I)] = , GOF =

Room Temperature Quantum Coherence and Rabi Oscillations in Vanadyl Phthalocyanine: Toward Multifunctional Molecular Spin Qubits

Room Temperature Quantum Coherence and Rabi Oscillations in Vanadyl Phthalocyanine: Toward Multifunctional Molecular Spin Qubits Room Temperature Quantum Coherence and Rabi Oscillations in Vanadyl Phthalocyanine: Toward Multifunctional Molecular Spin Qubits Matteo Atzori, Lorenzo Tesi, Elena Morra, Mario Chiesa, Lorenzo Sorace,

More information

Rare double spin canting antiferromagnetic behaviours in a. [Co 24 ] cluster

Rare double spin canting antiferromagnetic behaviours in a. [Co 24 ] cluster Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2016 Rare double spin canting antiferromagnetic behaviours in a [Co 24 ] cluster Guang-Ming Liang, Qing-Ling

More information

Red Color CPL Emission of Chiral 1,2-DACH-based Polymers via. Chiral Transfer of the Conjugated Chain Backbone Structure

Red Color CPL Emission of Chiral 1,2-DACH-based Polymers via. Chiral Transfer of the Conjugated Chain Backbone Structure Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2015 Red Color CPL Emission of Chiral 1,2-DACH-based Polymers via Chiral Transfer of the Conjugated

More information

Spin Transition and Structural Transformation in a

Spin Transition and Structural Transformation in a Supporting Information for Spin Transition and Structural Transformation in a Mononuclear Cobalt(II) Complex Ying Guo, Xiu-Long Yang, Rong-Jia Wei, Lan-Sun Zheng, and Jun Tao* State Key Laboratory of Physical

More information

Supporting Information

Supporting Information Supporting Information A Diiron Amido-Imido Complex [(Cp*Fe) 2 (µ 2 -NHPh)(µ 2 -NPh)]: Synthesis and a Net Hydrogen Atom Abstraction Reaction to Form a Bis(imido) Complex Shin Takemoto, Shin-ichiro Ogura,

More information

A versatile electronic hole in one-electron oxidized Ni II bissalicylidene

A versatile electronic hole in one-electron oxidized Ni II bissalicylidene Electronic Supplementary Information for manuscript: A versatile electronic hole in one-electron oxidized Ni II bissalicylidene phenylenediamine complexes Olaf Rotthaus, Olivier Jarjayes,* Carlos Perez

More information

An Efficient Total Synthesis and Absolute Configuration. Determination of Varitriol

An Efficient Total Synthesis and Absolute Configuration. Determination of Varitriol An Efficient Total Synthesis and Absolute Configuration Determination of Varitriol Ryan T. Clemens and Michael P. Jennings * Department of Chemistry, University of Alabama, 500 Campus Dr. Tuscaloosa, AL

More information

Supporting Information

Supporting Information Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 214 Supporting Information Lei Liu, ab Yijie Xia, b Jie Zhang* b a) China Center for Modernization

More information

Supporting Information. Sandmeyer Cyanation of Arenediazonium Tetrafluoroborate Using Acetonitrile as Cyanide Source

Supporting Information. Sandmeyer Cyanation of Arenediazonium Tetrafluoroborate Using Acetonitrile as Cyanide Source Electronic Supplementary Material (ESI) for Organic Chemistry Frontiers. This journal is the Partner Organisations 2015 Supporting Information Sandmeyer Cyanation of Arenediazonium Tetrafluoroborate Using

More information

Reduction-free synthesis of stable acetylide cobalamins. Table of Contents. General information. Preparation of compound 1

Reduction-free synthesis of stable acetylide cobalamins. Table of Contents. General information. Preparation of compound 1 Electronic Supporting Information Reduction-free synthesis of stable acetylide cobalamins Mikołaj Chromiński, a Agnieszka Lewalska a and Dorota Gryko* a Table of Contents General information Numbering

More information

Supporting Information. Ze-Min Zhang, Lu-Yi Pan, Wei-Quan Lin, Ji-Dong Leng, Fu-Sheng Guo, Yan-Cong Chen, Jun-Liang Liu, and Ming-Liang Tong*

Supporting Information. Ze-Min Zhang, Lu-Yi Pan, Wei-Quan Lin, Ji-Dong Leng, Fu-Sheng Guo, Yan-Cong Chen, Jun-Liang Liu, and Ming-Liang Tong* Supporting Information Wheel-shaped nanoscale 3d-4f {Co II 16Ln III 24} clusters (Ln = Dy and Gd) Ze-Min Zhang, Lu-Yi Pan, Wei-Quan Lin, Ji-Dong Leng, Fu-Sheng Guo, Yan-Cong Chen, Jun-Liang Liu, and Ming-Liang

More information

Hydrogen Bonded Dimer Stacking Induced Emission of Amino-Benzoic Acid Compounds

Hydrogen Bonded Dimer Stacking Induced Emission of Amino-Benzoic Acid Compounds Electronic Supplementary Information (ESI) Hydrogen Bonded Dimer Stacking Induced Emission of Amino-Benzoic Acid Compounds Tianlei Zhou, Feng Li, Yan Fan, Weifeng Song, Xiaoyue Mu, Hongyu Zhang* and Yue

More information

Halogen halogen interactions in diiodo-xylenes

Halogen halogen interactions in diiodo-xylenes Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information (ESI) for CrystEngComm. This journal is The Royal Society

More information

Mn 12 Single-Molecule Magnet Aggregates as Magnetic Resonance Imaging Contrast Agents

Mn 12 Single-Molecule Magnet Aggregates as Magnetic Resonance Imaging Contrast Agents Electronic Supplementary Information Mn 12 Single-Molecule Magnet Aggregates as Magnetic Resonance Imaging Contrast Agents Yinglin Wang, a Wen Li, a Shengyan Zhou, b Daliang Kong, b Haishan Yang, b and

More information

From Double-Shelled Grids to Supramolecular Frameworks

From Double-Shelled Grids to Supramolecular Frameworks Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 From Double-Shelled Grids to Supramolecular Frameworks Jianfeng Wu, Mei Guo, Xiao-Lei Li, Lang

More information

Supporting Information for

Supporting Information for Supporting Information for Nickel(I)-mediated transformations of carbon dioxide in closed synthetic cycles: reductive cleavage and coupling of CO 2 generating Ni I CO, Ni II CO 3 and Ni II C 2 O 4 Ni II

More information

Light irradiation experiments with coumarin [1]

Light irradiation experiments with coumarin [1] Materials and instruments All the chemicals were purchased from commercial suppliers and used as received. Thin-layer chromatography (TLC) analysis was carried out on pre-coated silica plates. Column chromatography

More information

Zero-field slow magnetic relaxation in a uranium(iii) complex with a radical ligand

Zero-field slow magnetic relaxation in a uranium(iii) complex with a radical ligand Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Information for: Zero-field slow magnetic relaxation in a uranium(iii) complex with

More information

Aggregation-induced emission enhancement based on 11,11,12,12,-tetracyano-9,10-anthraquinodimethane

Aggregation-induced emission enhancement based on 11,11,12,12,-tetracyano-9,10-anthraquinodimethane Electronic Supplementary Information (ESI) Aggregation-induced emission enhancement based on 11,11,12,12,-tetracyano-9,10-anthraquinodimethane Jie Liu, ab Qing Meng, a Xiaotao Zhang, a Xiuqiang Lu, a Ping

More information

Supporting Information

Supporting Information Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2015 A rare case of a dye co-crystal showing better dyeing performance Hui-Fen Qian, Yin-Ge Wang,

More information

One-dimensional organization of free radicals via halogen bonding. Supporting information

One-dimensional organization of free radicals via halogen bonding. Supporting information One-dimensional organization of free radicals via halogen bonding Guillermo Mínguez Espallargas,* a Alejandro Recuenco, a Francisco M. Romero, a Lee Brammer, b and Stefano Libri. b a Instituto de Ciencia

More information

1G (bottom) with the phase-transition temperatures in C and associated enthalpy changes (in

1G (bottom) with the phase-transition temperatures in C and associated enthalpy changes (in Supplementary Figure 1. Optical properties of 1 in various solvents. UV/Vis (left axis) and fluorescence spectra (right axis, ex = 420 nm) of 1 in hexane (blue lines), toluene (green lines), THF (yellow

More information

Magnetic Metal-Organic Framework Exhibiting Quick and. Selective Solvatochromic Behavior Along With The Reversible

Magnetic Metal-Organic Framework Exhibiting Quick and. Selective Solvatochromic Behavior Along With The Reversible Magnetic Metal-Organic Framework Exhibiting Quick and Selective Solvatochromic Behavior Along With The Reversible Crystal-to-Amorphous-to-Crystal Transformation Peng Hu,, Lei Yin,, Angelo Kirchon,, Jiangli

More information

Supporting Information

Supporting Information Supporting Information Highly Selective Colorimetric Chemosensor for Co 2+ Debabrata Maity and T. Govindaraju* Bioorganic Chemistry Laboratory, New Chemistry Unit, Jawaharlal Nehru Centre for Advanced

More information

Supporting Information

Supporting Information Supporting Information Total Synthesis of (±)-Grandilodine B Chunyu Wang, Zhonglei Wang, Xiaoni Xie, Xiaotong Yao, Guang Li, and Liansuo Zu* School of Pharmaceutical Sciences, Tsinghua University, Beijing,

More information

Silver-catalyzed decarboxylative acylfluorination of styrenes in aqueous media

Silver-catalyzed decarboxylative acylfluorination of styrenes in aqueous media Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Information Silver-catalyzed decarboxylative acylfluorination of styrenes in aqueous

More information

O-Allylation of phenols with allylic acetates in aqueous medium using a magnetically separable catalytic system

O-Allylation of phenols with allylic acetates in aqueous medium using a magnetically separable catalytic system Supporting information for -Allylation of phenols with allylic acetates in aqueous medium using a magnetically separable catalytic system Amit Saha, John Leazer* and Rajender S. Varma* Sustainable Technology

More information

Simple Solution-Phase Syntheses of Tetrahalodiboranes(4) and their Labile Dimethylsulfide Adducts

Simple Solution-Phase Syntheses of Tetrahalodiboranes(4) and their Labile Dimethylsulfide Adducts Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2017 Supporting Information for: Simple Solution-Phase Syntheses of Tetrahalodiboranes(4) and their

More information

Supplementary Information

Supplementary Information Supplementary Information C aryl -C alkyl bond formation from Cu(ClO 4 ) 2 -mediated oxidative cross coupling reaction between arenes and alkyllithium reagents through structurally well-defined Ar-Cu(III)

More information

Supporting Information

Supporting Information Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C. This journal is The Royal Society of Chemistry 2018 Supporting Information A difunctional metal organic framework with Lewis

More information

Supporting information

Supporting information Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2017 Template-directed synthesis

More information

Supplementary Material (ESI) for CrystEngComm. An ideal metal-organic rhombic dodecahedron for highly efficient

Supplementary Material (ESI) for CrystEngComm. An ideal metal-organic rhombic dodecahedron for highly efficient Supplementary Material (ESI) for CrystEngComm An ideal metal-organic rhombic dodecahedron for highly efficient adsorption of dyes in an aqueous solution Yuan-Chun He, Jin Yang,* Wei-Qiu Kan, and Jian-Fang

More information

Electronic Supporting Information

Electronic Supporting Information Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Electronic Supporting Information for Mechanochemical reactions studied by in situ Raman spectroscopy:

More information

An unprecedented 2D 3D metal-organic polyrotaxane. framework constructed from cadmium and flexible star-like

An unprecedented 2D 3D metal-organic polyrotaxane. framework constructed from cadmium and flexible star-like Electronic Supplementary Information An unprecedented 2D 3D metal-organic polyrotaxane framework constructed from cadmium and flexible star-like ligand Hua Wu, a,b Hai-Yan Liu, a Ying-Ying Liu, a Jin Yang,*

More information

Effect of Conjugation and Aromaticity of 3,6 Di-substituted Carbazole On Triplet Energy

Effect of Conjugation and Aromaticity of 3,6 Di-substituted Carbazole On Triplet Energy Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2018 Electronic Supporting Information (ESI) for Effect of Conjugation and Aromaticity of 3,6 Di-substituted

More information

Magnetic nanoparticle-supported proline as a recyclable and recoverable ligand for the CuI catalyzed arylation of nitrogen nucleophiles

Magnetic nanoparticle-supported proline as a recyclable and recoverable ligand for the CuI catalyzed arylation of nitrogen nucleophiles Magnetic nanoparticle-supported proline as a recyclable and recoverable ligand for the CuI catalyzed arylation of nitrogen nucleophiles Gagan Chouhan, Dashan Wang and Howard Alper* Centre for Catalysis

More information

An Anionic Metal Organic Framework For Adsorption and. Separation of Light Hydrocarbons

An Anionic Metal Organic Framework For Adsorption and. Separation of Light Hydrocarbons Supporting Information for An Anionic Metal Organic Framework For Adsorption and Separation of Light Hydrocarbons Jia Li, Hong-Ru Fu, Jian Zhang, Lan-Sun Zheng, and Jun Tao* State Key Laboratory of Physical

More information

Supporting Information

Supporting Information Supporting Information Wiley-VCH 2007 69451 Weinheim, Germany Crystal-to-Crystal Transformation between Three Cu(I) Coordination Polymers and Structural Evidence for Luminescence Thermochromism Tae Ho

More information

Supporting Information

Supporting Information Supporting Information One Pot Synthesis of 1,3- Bis(phosphinomethyl)arene PCP/PNP Pincer Ligands and Their Nickel Complexes Wei-Chun Shih and Oleg V. Ozerov* Department of Chemistry, Texas A&M University,

More information

Supporting Information

Supporting Information Supporting Information Synthesis of a new class of ribose functionalized dinucleotide cap analogues for biophysical studies on interaction of cap-binding proteins with the 5 end of mrna. Karolina Piecyk,

More information

Yujuan Zhou, Kecheng Jie and Feihe Huang*

Yujuan Zhou, Kecheng Jie and Feihe Huang* Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2017 A redox-responsive selenium-containing pillar[5]arene-based macrocyclic amphiphile: synthesis,

More information

Hydrophobic Ionic Liquids with Strongly Coordinating Anions

Hydrophobic Ionic Liquids with Strongly Coordinating Anions Supporting material Hydrophobic Ionic Liquids with Strongly Coordinating Anions Hasan Mehdi, Koen Binnemans*, Kristof Van Hecke, Luc Van Meervelt, Peter Nockemann* Experimental details: General techniques.

More information

Supporting Information Double Interpenetration in a Chiral Three-Dimensional Magnet with a (10,3)-a Structure

Supporting Information Double Interpenetration in a Chiral Three-Dimensional Magnet with a (10,3)-a Structure Supporting Information Double Interpenetration in a Chiral Three-Dimensional Magnet with a (10,3)-a Structure Thais Grancha, Marta Mon, Francesc Lloret, Jesús Ferrando-Soria,* Yves Journaux, Jorge Pasán,

More information

A supramolecular approach for fabrication of photo- responsive block-controllable supramolecular polymers

A supramolecular approach for fabrication of photo- responsive block-controllable supramolecular polymers Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2014 Supporting Information A supramolecular approach for fabrication of photo- responsive

More information

Molecular Imaging of Labile Iron(II) Pools in Living Cells with a Turn-on Fluorescent Probe

Molecular Imaging of Labile Iron(II) Pools in Living Cells with a Turn-on Fluorescent Probe Supporting Information for Molecular Imaging of Labile Iron(II) Pools in Living Cells with a Turn-on Fluorescent Probe Ho Yu Au-Yeung, Jefferson Chan, Teera Chantarojsiri and Christopher J. Chang* Departments

More information

Chemical Communication RSC Publishing

Chemical Communication RSC Publishing Chemical Communication RSC Publishing Supporting Information 1 Table of Contents Experimental Section and Physical Measurements Figure S1. Cyclic Voltammogram of 1 in THF at 22 C. Figure S2. Cyclic Voltammogram

More information

Supporting Information

Supporting Information Supporting Information Wiley-VCH 2008 69451 Weinheim, Germany Iridium-Catalyzed Dehydrocoupling of Primary Amine-Borane Adducts: A Route to High Molecular Weight Polyaminoboranes, Boron-Nitrogen Analogues

More information

Supporting Information

Supporting Information Supporting Information Heteroligand o-semiquinonato-formazanato cobalt complexes Natalia A. Protasenko, Andrey I. Poddel sky,*, Artem S. Bogomyakov, Georgy K. Fukin, Vladimir K. Cherkasov G.A. Razuvaev

More information

p-tert-butylthiacalix[4]arene-surpported High-nuclearity {Co 24 M 8 } (M = Mo or W) Nanospheres and the Hybrids with Keggin Polyoxometalates

p-tert-butylthiacalix[4]arene-surpported High-nuclearity {Co 24 M 8 } (M = Mo or W) Nanospheres and the Hybrids with Keggin Polyoxometalates Supporting Information p-tert-butylthiacalix[4]arene-surpported High-nuclearity {Co 24 M 8 } (M = Mo or W) Nanospheres and the Hybrids with Keggin Polyoxometalates Yanfeng Bi, a,b Shangchao Du a,b and

More information

Active Trifluoromethylating Agents from Well-defined Copper(I)-CF 3 Complexes

Active Trifluoromethylating Agents from Well-defined Copper(I)-CF 3 Complexes Supplementary Information Active Trifluoromethylating Agents from Well-defined Copper(I)-CF 3 Complexes Galyna Dubinina, Hideki Furutachi, and David A. Vicic * Department of Chemistry, University of Hawaii,

More information

Synthesis of Secondary and Tertiary Amine- Containing MOFs: C-N Bond Cleavage during MOF Synthesis

Synthesis of Secondary and Tertiary Amine- Containing MOFs: C-N Bond Cleavage during MOF Synthesis Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2015 Supporting Information Synthesis of Secondary and Tertiary Amine- Containing MFs: C-N Bond

More information

The First Asymmetric Total Syntheses and. Determination of Absolute Configurations of. Xestodecalactones B and C

The First Asymmetric Total Syntheses and. Determination of Absolute Configurations of. Xestodecalactones B and C Supporting Information The First Asymmetric Total Syntheses and Determination of Absolute Configurations of Xestodecalactones B and C Qiren Liang, Jiyong Zhang, Weiguo Quan, Yongquan Sun, Xuegong She*,,

More information

Phosphirenium-Borate Zwitterion: Formation in the 1,1-Carboboration Reaction of Phosphinylalkynes. Supporting Information

Phosphirenium-Borate Zwitterion: Formation in the 1,1-Carboboration Reaction of Phosphinylalkynes. Supporting Information Phosphirenium-Borate Zwitterion: Formation in the 1,1-Carboboration Reaction of Phosphinylalkynes Olga Ekkert, Gerald Kehr, Roland Fröhlich and Gerhard Erker Supporting Information Experimental Section

More information

Supporting Information

Supporting Information Supporting Information Wiley-VCH 2006 69451 Weinheim, Germany Sandwich Complexes Containing Bent Palladium ains Yasuki Tatsumi, Katsunori Shirato, Tetsuro Murahashi,* Sensuke Ogoshi and Hideo Kurosawa*

More information

Supporting Information. (1S,8aS)-octahydroindolizidin-1-ol.

Supporting Information. (1S,8aS)-octahydroindolizidin-1-ol. SI-1 Supporting Information Non-Racemic Bicyclic Lactam Lactones Via Regio- and cis-diastereocontrolled C H insertion. Asymmetric Synthesis of (8S,8aS)-octahydroindolizidin-8-ol and (1S,8aS)-octahydroindolizidin-1-ol.

More information

Electronic Supplementary Information. Reversible, Solid State Capture of Carbon Dioxide by Hydroxylated Amidines. Myungsook Kim, and Ji-Woong Park*

Electronic Supplementary Information. Reversible, Solid State Capture of Carbon Dioxide by Hydroxylated Amidines. Myungsook Kim, and Ji-Woong Park* Electronic Supplementary Information Reversible, Solid State Capture of Carbon Dioxide by Hydroxylated Amidines Myungsook Kim, and Ji-Woong Park* Department of Materials Science and Engineering, Gwangju

More information

Appendix A. Supplementary Information. Design, synthesis and photophysical properties of 8-hydroxyquinoline-functionalized

Appendix A. Supplementary Information. Design, synthesis and photophysical properties of 8-hydroxyquinoline-functionalized Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Appendix A Supplementary Information Design, synthesis and photophysical properties of 8-hydroxyquinoline-functionalized

More information

Supplementary Materials

Supplementary Materials Supplementary Materials First synthesis of a new fullerene oximes bis(9-[hydroxo]-1-[1'-hydroxymino-2'-oxo-2'-alkyl-ethyl])1,9-dihydro-[с60-ih][5,6]fullerenes via reaction of C60 with ketones and NaNO2

More information

Synthesis of two novel indolo[3,2-b]carbazole derivatives with aggregation-enhanced emission property

Synthesis of two novel indolo[3,2-b]carbazole derivatives with aggregation-enhanced emission property Supporting Information for: Synthesis of two novel indolo[3,2-b]carbazole derivatives with aggregation-enhanced emission property Wen-Bin Jia, Hao-Wei Wang, Long-Mei Yang, Hong-Bo Lu, Lin Kong, Yu-Peng

More information

Highly Luminescent -Conjugated Dithienometalloles: Photophysical Properties and Application to Organic Light-Emitting Diodes

Highly Luminescent -Conjugated Dithienometalloles: Photophysical Properties and Application to Organic Light-Emitting Diodes Electronic Supplementary Information (ESI) Highly Luminescent -Conjugated Dithienometalloles: Photophysical Properties and Application to Organic Light-Emitting Diodes Ryosuke Kondo, a Takuma Yasuda,*

More information

Functional nickel complexes of N-heterocyclic carbene ligands in pre-organized and supported thin film materials

Functional nickel complexes of N-heterocyclic carbene ligands in pre-organized and supported thin film materials Supporting Information Functional nickel complexes of N-heterocyclic carbene ligands in pre-organized and supported thin film materials Xinjiao Wang, a Marek Sobota, b Florian T. U. Kohler, c Bruno Morain,

More information

Synthesis of 2 ) Structures by Small Molecule-Assisted Nucleation for Plasmon-Enhanced Photocatalytic Activity

Synthesis of 2 ) Structures by Small Molecule-Assisted Nucleation for Plasmon-Enhanced Photocatalytic Activity Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information Synthesis of Au@UiO-66(NH 2 ) Structures by Small Molecule-Assisted

More information

Supporting Information For:

Supporting Information For: Supporting Information For: Peptidic α-ketocarboxylic Acids and Sulfonamides as Inhibitors of Protein Tyrosine Phosphatases Yen Ting Chen, Jian Xie, and Christopher T. Seto* Department of Chemistry, Brown

More information

Supporting Information

Supporting Information Supporting Information Wiley-VCH 2012 69451 Weinheim, Germany Substitution of Two Fluorine Atoms in a Trifluoromethyl Group: Regioselective Synthesis of 3-Fluoropyrazoles** Kohei Fuchibe, Masaki Takahashi,

More information

Sequential dynamic structuralisation by in situ production of

Sequential dynamic structuralisation by in situ production of Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information Sequential dynamic structuralisation by in situ production

More information

Supporting Information

Supporting Information Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2018 Supporting Information Content Synthesis of compounds 2a, 2b in Scheme

More information

Electronic Supporting Information for

Electronic Supporting Information for Electronic Supporting Information for An efficient long fluorescence lifetime polymer-based sensor based on europium complex as chromophore for the specific detection of F -, CH 3 COO - -, and H 2 PO 4

More information

Chia-Shing Wu, Huai-An Lu, Chiao-Pei Chen, Tzung-Fang Guo and Yun Chen*

Chia-Shing Wu, Huai-An Lu, Chiao-Pei Chen, Tzung-Fang Guo and Yun Chen* Electronic Supplementary Material (ESI) for rganic & Biomolecular Chemistry Supporting Information Water/alcohol soluble electron injection material containing azacrown ether groups: Synthesis, characterization

More information

ph-responsive assembly and disassembly of a supramolecular cryptand-based pseudorotaxane driven by π-π stacking interaction

ph-responsive assembly and disassembly of a supramolecular cryptand-based pseudorotaxane driven by π-π stacking interaction ph-responsive assembly and disassembly of a supramolecular cryptand-based pseudorotaxane driven by π-π stacking interaction Xuzhou Yan, Mingming Zhang, Peifa Wei, Bo Zheng, Xiaodong Chi, Xiaofan Ji, and

More information

Supporting Information

Supporting Information Supporting Information Exploring the detection of metal ions by tailoring the coordination mode of V-shaped thienylpyridyl ligand in three MOFs Li-Juan Han,, Wei Yan, Shu-Guang Chen, Zhen-Zhen Shi, and

More information

SUPPORTING INFORMATION. Fathi Elwrfalli, Yannick J. Esvan, Craig M. Robertson and Christophe Aïssa

SUPPORTING INFORMATION. Fathi Elwrfalli, Yannick J. Esvan, Craig M. Robertson and Christophe Aïssa Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 SUPPORTING INFORMATION S1 Fathi Elwrfalli, Yannick J. Esvan, Craig M. Robertson and Christophe

More information

Supporting Information

Supporting Information Supporting Information Incorporation of a Sugar Unit into a C C N Pincer Pd Complex Using Click Chemistry and Its Dynamic Behavior in Solution and Catalytic Ability toward the Suzuki Miyaura Coupling in

More information

Supporting Information for

Supporting Information for Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2017 Supporting Information for

More information

Supplementary Material:

Supplementary Material: Supplementary Material: Water soluble amphiphilic gold nanoparticles with structured ligand shells Oktay Uzun, Ying Hu, Ayush Verma, Suelin Chen, Andrea Centrone, and Francesco Stellacci* Department of

More information

Transformations: New Approach to Sampagine derivatives. and Polycyclic Aromatic Amides

Transformations: New Approach to Sampagine derivatives. and Polycyclic Aromatic Amides -1- An Unexpected Rearrangement which Disassembles Alkyne Moiety Through Formal Nitrogen Atom Insertion between Two Acetylenic Carbons and Related Cascade Transformations: New Approach to Sampagine derivatives

More information

Tuning Porosity and Activity of Microporous Polymer Network Organocatalysts by Co-Polymerisation

Tuning Porosity and Activity of Microporous Polymer Network Organocatalysts by Co-Polymerisation Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Information Tuning Porosity and Activity of Microporous Polymer Network Organocatalysts

More information

Carbon powder modification. Preparation of NS1, NS2, NS3 and NS4.

Carbon powder modification. Preparation of NS1, NS2, NS3 and NS4. SUPPORTING INFORMATION EXPERIMENTAL SECTION Reagents. Carbon powder (Norit-S50) was purchased from Norit, 4-aminobenzene sulfonic acid (99%), lithium perchlorate (99%, potassium ferricyanide (99%) and

More information

Supporting Information. Integration of accessible secondary metal sites into MOFs for H 2 S removal

Supporting Information. Integration of accessible secondary metal sites into MOFs for H 2 S removal Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers. This journal is the Partner Organisations 2014 Supporting Information Integration of accessible secondary metal sites into MOFs

More information

Electronic Supplementary Information

Electronic Supplementary Information Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 S1 Electronic Supplementary Information Flash Carboxylation: Fast Lithiation - Carboxylation

More information

A Third Generation Breathing MOF with Selective, Stepwise, Reversible and Hysteretic Adsorption properties

A Third Generation Breathing MOF with Selective, Stepwise, Reversible and Hysteretic Adsorption properties Supporting information for A Third Generation Breathing MOF with Selective, Stepwise, Reversible and Hysteretic Adsorption properties Suresh Sanda, Srinivasulu Parshamoni and SanjitKonar* Department of

More information

Sulfuric Acid-Catalyzed Conversion of Alkynes to Ketones in an Ionic Liquid Medium under Mild Reaction Conditions

Sulfuric Acid-Catalyzed Conversion of Alkynes to Ketones in an Ionic Liquid Medium under Mild Reaction Conditions Sulfuric Acid-Catalyzed Conversion of Alkynes to Ketones in an Ionic Liquid Medium under Mild Reaction Conditions Wing-Leung Wong, Kam-Piu Ho, Lawrence Yoon Suk Lee, Kin-Ming Lam, Zhong-Yuan Zhou, Tak

More information

[Ag-Ag] 2+ Unit-Encapsulated Trimetallic Cages: One-pot Syntheses and Modulation of Argentophilic Interactions by the Uncoordinated Substituents

[Ag-Ag] 2+ Unit-Encapsulated Trimetallic Cages: One-pot Syntheses and Modulation of Argentophilic Interactions by the Uncoordinated Substituents [Ag-Ag] 2+ Unit-Encapsulated Trimetallic Cages: One-pot Syntheses and Modulation of Argentophilic Interactions by the Uncoordinated Substituents Guo-Xia Jin,,a Gui-Ying Zhu,,a Yan-Yan Sun, c Qing-Xiu Shi,

More information

Supporting Information for

Supporting Information for Electronic Supplementary Material (ES) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2016 Supporting nformation for BODPY-Containing

More information

A water-stable zwitterionic dysprosium carboxylate metal organic. framework: a sensing platform for Ebolavirus RNA sequences

A water-stable zwitterionic dysprosium carboxylate metal organic. framework: a sensing platform for Ebolavirus RNA sequences Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 A water-stable zwitterionic dysprosium carboxylate metal organic framework: a sensing platform

More information

How to build and race a fast nanocar Synthesis Information

How to build and race a fast nanocar Synthesis Information How to build and race a fast nanocar Synthesis Information Grant Simpson, Victor Garcia-Lopez, Phillip Petemeier, Leonhard Grill*, and James M. Tour*, Department of Physical Chemistry, University of Graz,

More information

Supporting Information for Synthesis of C(3) Benzofuran Derived Bis-Aryl Quaternary Centers: Approaches to Diazonamide A

Supporting Information for Synthesis of C(3) Benzofuran Derived Bis-Aryl Quaternary Centers: Approaches to Diazonamide A Fuerst et al. Synthesis of C(3) Benzofuran Derived Bis-Aryl Quaternary Centers: Approaches to Diazonamide A S1 Supporting Information for Synthesis of C(3) Benzofuran Derived Bis-Aryl Quaternary Centers:

More information

Highly efficient P-N nickel(ii) complexes for the dimerisation of ethylene

Highly efficient P-N nickel(ii) complexes for the dimerisation of ethylene Highly efficient P-N nickel(ii) complexes for the dimerisation of ethylene Antoine Buchard, Audrey Auffrant, Christian Klemps, Laurence Vu-Do, Leïla Boubekeur, Xavier F. Le Goff and Pascal Le Floch* Laboratoire

More information

Synthesis of Glaucogenin D, a Structurally Unique. Disecopregnane Steroid with Potential Antiviral Activity

Synthesis of Glaucogenin D, a Structurally Unique. Disecopregnane Steroid with Potential Antiviral Activity Supporting Information for Synthesis of Glaucogenin D, a Structurally Unique Disecopregnane Steroid with Potential Antiviral Activity Jinghan Gui,* Hailong Tian, and Weisheng Tian* Key Laboratory of Synthetic

More information

Electronic Supplementary Information

Electronic Supplementary Information Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information Micro- and mesoporous poly(schiff-base)s

More information

Electronic Supporting Information

Electronic Supporting Information Electronic Supporting Information Solid-State Coexistence of {Zr 12 } and {Zr 6 } Zirconium Oxocarboxylate Clusters Iurie L. Malaestean, Meliha Kutluca Alıcı, Claire Besson, Arkady Ellern and Paul Kögerler*

More information

An Unusual High Thermal Stable 2D 3D Polycatenated. Fe(II) Metal-Organic Framework Showing. Guest-Dependent Spin-Crossover Behavior and High

An Unusual High Thermal Stable 2D 3D Polycatenated. Fe(II) Metal-Organic Framework Showing. Guest-Dependent Spin-Crossover Behavior and High Supporting Information for Crystal Growth & Design An Unusual High Thermal Stable 2D 3D Polycatenated Fe(II) Metal-Organic Framework Showing Guest-Dependent Spin-Crossover Behavior and High Spin-Transition

More information

Supporting Information

Supporting Information Supporting Information An Extremely Active and General Catalyst for Suzuki Coupling Reactions of Unreactive Aryl Chlorides Dong-Hwan Lee and Myung-Jong Jin* School of Chemical Science and Engineering,

More information

Electronic Supplementary Information (ESI) for

Electronic Supplementary Information (ESI) for Electronic Supplementary Information (ESI) for When Cu 4 I 4 cubane meets Cu 3 (pyrazolate) 3 triangle: dynamic interplay between two classical luminophores functioning in a reversibly thermochromic coordination

More information

Reversible Single-Crystal to Single-Crystal Transformation. Modification of Structures and Properties

Reversible Single-Crystal to Single-Crystal Transformation. Modification of Structures and Properties Supplementary Material Reversible Single-Crystal to Single-Crystal Transformation upon Anion Exchange Induced Cu 2+ I - Weak Interactions and Modification of Structures and Properties Junhong Fu, Huijun

More information

Electronic Supplementary Information (12 pages)

Electronic Supplementary Information (12 pages) Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 A C 2 -responsive pillar[5]arene: synthesis and self-assembly in water Kecheng Jie, Yong Yao, Xiaodong

More information

Supporting Information

Supporting Information Supporting Information An L-proline Functionalized Metallo-organic Triangle as Size-Selective Homogeneous Catalyst for Asymmertry Catalyzing Aldol Reactions Xiao Wu, Cheng He, Xiang Wu, Siyi Qu and Chunying

More information

Electronic Supplementary Information (ESI)

Electronic Supplementary Information (ESI) Electronic Supplementary Information (ESI) S1 Experimental Section: Materials and methods: All commercially available chemicals were used as supplied without further purification. The Q[5] was synthesized

More information

Electronic Supplementary Information

Electronic Supplementary Information Electronic Supplementary Information The directing effect of linking unit on building microporous architecture in tetraphenyladmantane-based poly(schiffbase) networks Guiyang Li, Biao Zhang, Jun Yan and

More information

Supporting Information

Supporting Information Remarkably Variable Reaction Modes of Frustrated Lewis Pairs with Non-Conjugated Terminal Diacetylenes Chao Chen, Roland Fröhlich, Gerald Kehr, Gerhard Erker Organisch-Chemisches Institut, Westfälische

More information

Supporting information. Cooperatively Enhanced Ion Pair Binding with a Hybrid Receptor

Supporting information. Cooperatively Enhanced Ion Pair Binding with a Hybrid Receptor Supporting information Cooperatively Enhanced Ion Pair Binding with a Hybrid Receptor Toni Mäkelä, a Elina Kalenius a and Kari Rissanen a* a University of Jyvaskyla, Department of Chemistry, Nanoscience

More information