Houston Community College System EXAM # 3A. Chemistry 1412

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1 Houston Community College System EXAM # 3A Chemistry 1412

2 CHEM 1412 Sample EXAM # 3A (19, 23, and 24) Name: Score: Part I-Please DO NOT circle. Write the correct answer in space provided. 1. Which energy conversion below takes place in a galvanic cell? A) electrical to chemical B) chemical to electrical C) mechanical to chemical D) electrical to mechanical 2. Consider a galvanic cell based on the reaction below, what is the coefficient of Fe 3+ in the balanced equation in acidic solution? Fe 2+ + Cr2O7 2 Fe 3+ + Cr 3+ A) 1 B) 2 C) 3 D) none of these 3. How many electrons are transferred in the following reaction? 2ClO3 + 12H I 5I2 + Cl2 + 6H2O A) 10 B) 12 C) 5 D) Which of the following is true for the cell shown here? Zn(s) Zn 2+ (aq) Cr 3+ (aq) Cr(s) A) the electrons flow from cathode to the anode B) the electrons flow from the zinc to the chromium C) the electrons flow from the chromium to the zinc D) the zinc is reduced 5. Which of the following reactions is possible at the anode of a galvanic cell? A) Zn Zn 2+ +2e B) Zn e Zn C) Zn 2+ + Cu Zn + Cu 2+ D) Zn + Cu 2+ Zn 2+ + Cu 6. The standard reduction potentials for the following half reactions are given as follows; Cr e Cr(s) Br2(aq) + 2e 2Br - E 0 = V E 0 = V what is the E 0 for this cell? A) 1.82 V B) 0.36 V C) 4.75 V D) 1.79 V 7. A voltaic cell has an E 0 value of V. The reaction : A) is not spontaneous B) has K =1 C) has a negative G 0 D) has G 0 = 0 8. In the following nuclear equation, identify the missing particle Ca He H A) Ti B) Sc C) Ti D) Ar

9. Which of the following represents positron? A) 1 1 H B) 0-1 e C) 0 +1 e D) 4 2 He 10.Which of the following is a product of alpha decay of 238 92 U?

3 9. Which of the following represents positron? A) 1 1 H B) 0-1 e C) 0 +1 e D) 4 2 He 10.Which of the following is a product of alpha decay of U? A) Th B) Np C) Pa D) U 11. An unstable isotope of rhenium, 191 Re, has a half-life of 9.8 minutes and is a beta producer. What is the other product of this reaction? A) 191 Os B) 191 W C) 190 W D) 190 Os 12. Which of the following process increases the atomic number by 1? A) gamma-ray production B) electron capture C) beta particle production D) positron production 13. Which of the following balanced equation is labeled incorrectly? A) Beta decay, U Np e B) Alpha Bombardment, Na He Al n C) Electron capture, 7 4 Be + 0-1e 7 3 Li D) All are correctly labeled 14. Which of the following pairs is incorrect? A) ethane (C2H6 ) B) hexane (C6H14) C) decane (C10H22) D) heptane (C7H14) 15. Which of the following is general formula for alkene with n-carbon atoms? A) CnHn B) CnH2n+2 C) CnH2n D) CnH2n Warfarin is used to prevent blood clots from forming or growing larger in your blood and blood vessels. How many different functional groups are in Warfarin? A) 3 B) 4 C) 5 D) 6

4 17. What is the correct IUPAC name for the following compound; Cl H 3 C C C Cl A) cis-2-chloro-3-chloro--2-butene B) 2,3-dichloro-1-methyl-propene C) trans-2,3-dichloro-2-butene D) 1-chloro-2-methyl-propene 18. Name the following: CH C - C C - H H A) 1-hexyne B) 2-ethynylbutane C) 3-methyl-1-pentyne D)3-methyl-4-pentyne 19. Name the following: CH CH - CH 2 - CH 2 - CH - A) 2,4-diethylpentane B) 2,5-dimethylheptane C) 2-ethyl-5-methylheptane D) 3,6-dimethylheptane 20. Which of the following is correct condensed formula for isopropanol? - CH 2 - CH 2 OH - CH - - C - CH 2 OH CH 2 CHOH OH CH 2 CH 2 A) B) C) D)

5 Part II-Essay questions(please show all your work for complete credit) 21. The following reaction occurs in basic solution: MnO2 + HO2 MnO4 + H2O a) write a balanced equation b) identify the species which is oxidized c) identify which species is oxidizing agent 22. Refer to the following half-reactions below; MnO4 + 8H + + 5e Mn H2O Cr2O H + + 5e 2Cr H2O E o = 1.51 V E o = 1.33 V a) when current is allowed to flow, which species is oxidized? b) what is the value of cell potential, E o? c) what is the G o for the cell that utilized this reaction? d) calculate the value of equilibrium constant at 25 0 C for this reaction? 23. If a constant current of 5.0 amperes is passed through a cell containing Cr 3+ for 1.0 hour, how many grams of Cr will plate out on to the cathode? ( the atomic mass of Cr is and 1 Faraday = coulombs) 24. The half-life of Sr-90 1s 28.1 years. How long will it take a 10.0 g sample of Sr-90 to decompose to 0.10 g? 25. A radioactive element has a half-life of 1.0 hr. How many hours will it take for the number of atoms present to decay (decreased or reduced ) by 6.25% of the initial value? 26. One of the hopes for solving the world s energy problem is to make use of the fusion reaction: 2 1 H H 4 2 He n + energy ( ) ( ) ( ) ( ) amu amu amu amu how much energy is released when one mole of deuterium is fused with one mole of tritium according to the above reaction? The speed of light is x10 8 m/s and 1 a.m.u =6.022x10 23 g. 27. A student gave a molecule the following name; 3-methyl-4- isopropylpentane. However, the professor pointed out that, although the molecule could be correctly drawn from this name, the name did not follow systematic (IUPAC) rules. What is the correct (IUPAC) name of the molecule?

6 28. Identify the following reactions as addition (A), substitution (S), or oxidation (O). a) - CH 2 - CH = CH 2 + H 2 O - CH 2 - CHOH - H + b) 2 - CHOH - + 9O 2 6 CO H 2 O 29. Identify the classification of the following compounds; - CH - CH 2 - CHO O - CH 2 - COOH CH 2 OCH 2 - CH 2 - C Complete the following reactions; (write the major products) COOH a) + CH 2 OH H + b) - CH Cl 2 light c) - CH 2 - C = CH 2 + H 2 Ni(s) d) - CH 2 OH + - CH 2 - CH -OH H + e) - CH 2 - CH = CH 2 + HBr ether Bonus question- ( 10 points) - Please write all your work. 1. How many isomers are there with the formula C3H5Br? Include both structural and geometrical isomers. Please draw at least five isomers and name each.

7 CHEM 1412 EXAM # 3A KEY ( 19, 23, and 24) Part I.(2 points each) 1. B 2. D Fe 2+ Fe 3+ + e, Cr2O H + +6e 2Cr 3+ +7H2O 6Fe 2+ 6Fe 3+ +6e 6Fe 2+ + Cr2O H + 6Fe Cr 3+ +7H2O 3. A 10 I 5I2 + 10e 4. B Electrons flow from anode to cathode. Zn Zn e (oxidation half)-anode Cr 3+ +3e Cr (reduction half)-cathode 5. A Oxidation occurs in anode.( loss of electron) Zn Zn 2+ +2e 6. A E 0 red (Cr 3+ ) = 0.73 V (smaller) E 0 ox =+0.73 V E 0 red (Br2) = V (larger) E 0 cell = (+0.73V) + (+1.09V) = +1.82V 7. C E 0 = 1.00 V > zero ( positive), spontaneous and G 0 < 0.0 ( negative) 8. B 9. C 10. A 11. A 12. C 13. D 14. D ( C7H14 is heptene and C7H16 is heptane) 15. C 16. C 17. C 18. C 19. B 20. B Part II. ( 6 points each) 21. MnO2 + HO2 MnO4 + H2O ( basic solution) MnO2 MnO4 HO2 H2O MnO2 + 2H2O MnO4 + 4H + HO2 +3H + 2H2O 2(MnO2 + 2H2O MnO4 +4H + +3e ) 3(HO2 + 3H + +2e 2H2O) ( MnO2 is oxidized, reducing agent ) ( HO2 - is reduced, oxidizing agent ) Balance equation in basic solution: 2MnO2 + 3HO2 2 MnO4 - + H2O + OH - ( basic solution) 22. MnO4 + 8H + +5e Mn H2O E 0 = 1.51 V (larger), reduced best Cr2O H + + 5e 2 Cr H2O E 0 = 1.33 V (smaller), oxidized best E 0 ox= 1.33 V E 0 cell = (+1.55 V) + ( 1.33 V) = V, G 0 = -nfe 0 cell = (5e )(96500)(+0.18) = 8.70x10 4 J K = invlog( ne 0 /.0592) = invlog ( 5x0.18/.0952) = 1.60x M It (5.0)(1.0)(3600sec) m Cr = x = x = 3.23 g, Cr will plate out in cathode n F 3e t =3.32(t1/2) log N0/Nt = 3.32(28.1) log (10.0/0.10) t =186 yrs

8 25. nt = = 93.75% remaining t = 3.32 (t1/2) log N0/Nt 3.3(1.0) log (100/93.75) t = hrs 26. m = ( ) ( ) m = a.m.u E = m ( 1.49x10 10 J/amu) = ( amu)(1.50x10 10 J/amu) = x10-12 J/atom ( x10 12 J/atom)x (6.02x10 23 atoms/mol) = 1.32x10 12 J/mol 27. CH3- CH - CH - CH2 -CH3 CH3- CH CH3 2,3,4- trimethylhexane CH3 28. a) Addition ( hydration) b) Oxidation (combustion) 29. Aldehyde, Carboxylic acid, Ether, Ketone 30. COO-CH 2 a) b) - CHCl - + HCl c) - CH 2 - CH- d) - CH 2 O - CH - CH 2 - e) - CH 2 - CHBr - Bonus question C3H5Br possible isomers; Br C = C H H cis -1- bromo- 1-propene CH 2 Br - CH = CH 2 3-Bromo-1-propene H C = C Br H trans -1- bromo- 1-propene CH 2 CHBr CH 2 Bromocyclopropane - CBr = CH 2 2-Bromo-1-propene

9 Houston Community College System EXAM # 3B Chemistry 1412

10 CHEM 1412 Sample EXAM # 3B (19, 23, and 24) Name: Score: PART I (3 points each) Please write your correct answer next to each question number. DO NOT CIRCLE 1. The loss of electron in a reaction is called. a) reduction b) oxidation c) deposition d) none of these 2. What substance is oxidized in the following reaction? Cr2O7 2 + S2O H + 2Cr S4O H2O a) Cr2O7 2 b) S2O3 2 c) H + d) Cr What is the coefficient of the permanganate ion, MnO4 -, when the following equation is balanced? MnO4 + Br Mn 2+ + Br2 (acidic solution) a) 1 b) 2 c) 3 d) 4 4. The electrode at which oxidation occurs is called the a) oxidizing agent b) cathode c) reducing agent d) anode 5. What is the sign of the cathode in a galvanic (voltaic) cell? a) + b) c) 0 d) all of these 6. The half reaction occurring at the anode in the voltaic cell reaction 3 MnO H Fe 3 Mn Fe H2O is, a) MnO4 + 8H + + 5e Mn H2O b) Fe Fe e c) Fe Fe e - d) Fe 2+ Fe 3+ + e 7. The standard reduction potentials for Cr 2+ (aq) and Sn 2+ (aq) are 0.91 V and 0.14 V, respectively. Which element, chromium or tin, should be oxidized more readily? a) Cr b) Sn c) They will behave exactly the same d) Cannot be determine 8. The standard reduction potentials in V for Pb 2+ and Ag + are 0.13 and respectively. Calculate E o cell for a cell in which the overall reaction is Pb + 2Ag + 2Ag + Pb 2+ a) 0.93 V b) 0.27 V c) 1.95 V d) 1.26 V

11 9. If Ecell for the above reaction is 0.13 V. What is the value of G (in kj) for the reaction? a) 25 kj b) 15 kj c) 52 kj d) 62 kj 10. One of the differences between the voltaic cell and an electrolytic cell is that in an electrolytic cell a) an electric current is produced by a chemical reaction. b) electrons flow toward the anode c) a nonspontaneous reaction is forced to occur. d) O2 gas is produced at the cathode. 11. The value of E o cell for the following reaction is 1.10 V. What is the value of Ecell for this reaction when the concentration of Cu 2+ is 1.0 x10 5 M and the concentration of Zn 2+ is 1.0M? Zn + Cu 2+ Cu + Zn 2+ a) 1.50 V b) 1.35 V c) 0.95 V d) 0.56 V 12. How many grams of copper metal can be obtained by passing a current of 7.50 amps through a solution of CuSO4 for 15 minutes? a) 2.22 g b) 3.61 g c) 5.14 g d) 24.0 g 13. What nuclide is produced if Krypton-81 undergoes beta decay? a) Krypton-82 b) bromine-79 c) Kr-81 d) Rb By what process does thorium-230 decay to radium-226? a) positron emission b) alpha emission c) beta emission d) electron capture 15. The alpha decay of what isotope of what element produces lead-206? a) polonium-210 b) thallium-204 c) radon-222 d) bismuth In the nuclear transmutation, 8O 16 (p, α) 7N 13, what is the emitted particle? a) an alpha particle b) a beta particle c) a gamma particle d) a proton 17. What order process is radioactive decay? a) zero order b) first order c) second order d) third order 18. An ancient wooden artifact, said to be over 5000 years old, was found to have a carbon- 14 content 78% of that found in living trees. The half-life of carbon-14 is 5730 years. What is the actual age of the wooden artifact? a) 350 yr b) 1260 yr c) 2050 yr d) 5210 yr

12 19. The half-life for the beta-decay of cesium-137 is 30 years. How many years must pass to reduce a 500 mg sample of cesium-137 to one-millionth of its initial amount? a) 54 yr b) 153 yr c) 227 yr d) 598 yr 20. I -131 has a half-life of 8.04 days. Assuming you start with a 5.00 mg sample of I-131, how much will remain after one year? a) mg b) 4.46 x 10-8 mg c) 1.06 x mg d) 2.74 mg PART II (8 points each) Please show all your work. 21. Balance the following equation in basic solution and determine the oxidizing and reducing agent. Zn + MnO4 - Zn(OH)2 + MnO2 22. How many minutes will it take to plate out 5.00 g of Fe from an Fe(NO3)3 solution by a current of 1.50 A? (atomic weight: Fe = 55.85) 23. From the listed standard electrode potentials, what is E o and equilibrium constant for the following cell? ( Fe 2+ (aq) Fe 3+ (aq) Ag+ (aq) Ag (s) Fe 3+ (aq) + 1e - Fe 2+ (aq) Ag + (aq) + 1e - Ag (s) E o = V E o = V 24. Identify the following functional groups as alcohol, aldehyde,. I) R-COOH II) CO III) CHO IV) COO

13 25. Give the proper IUPAC names or structures for the followings: CH2 CH3 I) CH3 CH2 CH CH3 II) H3C Cl C = C H H III) 1,3-dimethylcyclopentane IV) 1-chloro-2,2-dimethylpentane Bonus Question (10 points)- show all your work for the full credit. Please write FIVE possible isomers for the following compounds and name each. C4H6Br2

14 PART I CHEM 1412 EXAM # 3B KEY ( 19, 23, and 24) 1. B oxidation is loss of electrons and reduction is gain of electrons 2. B Cr 2 O H e - 2 Cr 3+ +7H 2 O ( reduction half, Cr 2 O 7 2- is reduced and S 2 O 3 2- is oxidized)) 3. B 2 (MnO H e - Mn H 2 O) 1 (2 Br - Br e - ) add-up 2 MnO Br H + 2 Mn 2+ + Br H 2 O 4. D oxidation occurs in anode and reduction occurs in cathode. 5. A anode( + )oxidation, cathode (- ) reduction 6. B oxidation occurs in anode, Fe(s) Fe 3+ (aq) + 3 e - 7. A Since E o red (Sn 2+ ) = V and is greater than E o red (Cr 2+ ) = V ; Sn 2+ reduced the best and Cr 2+ oxidizes more rapidly 8. A Pb(s) Pb 2+ (aq) + 2 e- E o ox = V 2 Ag + (aq) + 2 e - 2 Ag (s) E o red = V E o cell = V > spontaneous reaction 9. A G = -nfe = - (2 e-)(96500)(0.13) = J / 1000 = -25 kj 10. C 11. C E cell = E o cell - (0.0592/n) log [Zn 2+ ]/[Cu 2+ ] = = (0.0592/2) log [1M]/ [1.0x10-5 M] = 0.95 V 12. A m Cu = (M/n) ( It /F) = ( 64/2)( 15x60 x7.50/ 96500) = 2.22 g 13. D 36 Kr 81-1 e o + 37 Rb B 90 Th Ra He 4 ( alpha emission) 15. A 84 Po He Pb A Oxygen and proton are reactants. Alpha,, and nitrogen are produced ( emission) 17. B since t 1/2 = /k, radioactive decay is first-order reaction 18. C t = 3.32 (t 1/2 ) log (N o /N t ) = 3.32 (5730)log ( 100/78) = 2050 years 19. D t = 3.32 (t 1/2 ) log (N o /N t ) = 3.32 (30) log ( 500/ 500x10-6 ) = 3.32(30) log (10 6 ) = 598 years 20. C t = 3.32 (t 1/2 ) log (N o /N t ) (1 yearx365days) = 3.32(8.04days)log (5.00/ N t ) log (5.00/X) = /X = antilog( ) = 4.72x10 13 X = Nt = 5.00/4.72x10 13 = 1.06x10-13 mg

15 PART II 21. Zn + MnO 4 - Zn(OH) 2 + MnO 2 (acidic solution) - 2 (MnO H e - - MnO H 2 O ) (MnO 4 reduced and oxidizing agent) 3 ( Zn + 2 H 2 O Zn (OH) H e - ) ( Zn oxidized and reducing agent) 3 Zn + 2 MnO H 2 O + 2 H + 3 Zn (OH) MnO 2 ( acidic solution) 3 Zn + 2 MnO H 2 O 3 Zn (OH) MnO OH - ( basic solution) Sum of products coefficients = = m Fe = (M/n) ( It /F) 5.00 g = ( 55.85/3)( 1.50x time /96500) time = (3)(5.00)(96500) / (1.50)(55.85) time = seconds / 3600 = time = 288 min 23. Fe 2+ (aq) Fe 3+ (aq) + 1 e -, E o ox = V Ag + (aq) +1 e - Ag (s), E o red = V E o cell = V > 0 spontaneous reaction log k = ( ne o cell /0.0591) = ( 1 e - x 0.03 / ) = k = antilog ( ) k = I) R-COOH (carboxylic acid) II) - CO - ( ketone) III) - CHO ( aldehyde) IV) -COO- (ester) 25. I) 3 -methylpentane II) cis-1- chloro-1-propene III) IV) - CH 2 - CH 2 - C - CH 2 - Cl BONUS QUESTION ( there are other possible isomers) -CH 2 -CH = C Br 2 1,1-dibromo-1-butene -CH 2 Br C = C H Br cis- 1,2-dibromo-1- butene -CH 2 Br C = C Br H -CH Br-CH = CH Br CH 2 Br-CH 2 -CH = CH Br trans-1,2 -dibromo-1- butene 1,3-dibromo-1-butene 1,4-dibromo-1-butene

CHEM 1412 Practice Exam 3, Chapters 18, 19 & 24 Chang

CHEM 1412 Practice Exam 3, Chapters 18, 19 & 24 Chang F = 96485 J/V mol = 96485 C/mol of e Ecell = E cell (0.0592/n) log(q) = E cell (0.0257/n) ln(q) G = n F E cell G = RT ln(keq) lnnt = kt + lnno Amp