MANUFACTURING OF MICROPOROUS CERAMIC MEMBRANES FOR ENVIRONMENTAL APPLICATIONS I. CO 2 -free power plants II. Fuel cells
|
|
- Jasper Bennett
- 6 years ago
- Views:
Transcription
1 Mitglied der Helmholtz-Gemeinschaft Innovation for Sustainable Production i-sup 2008 Congrescentrum Oud Sint-Jan, Brugge April 2008 MANUFACTURING OF MICROPOROUS CERAMIC MEMBRANES FOR ENVIRONMENTAL APPLICATIONS I. CO 2 -free power plants II. Fuel cells Tim Van Gestel, Wilhelm A. Meulenberg, Hans Peter Buchkremer Forschungszentrum Jülich GmbH Institute of Energy Research Materials Synthesis and Processing (IEF-1) D Jülich
2 Membrane research topics in IEF-1 Focus on energy-related applications : 1 Development of porous and dense membranes for application in CO 2 -free power plants dense membranes for O 2 /N 2 separation microporous membranes for CO 2 /H 2 separation 2 Development of porous and dense membranes for application in advanced Solid Oxide Fuel Cells (SOFC s) porous anode and cathode layers dense electrolyte membrane Institute of Energy Research IEF-1 Van Gestel, Meulenberg, Buchkremer, Brugge
3 Microporous membranes for CO 2 separation Example: Metal-supported Membranes for H 2 /CO 2 -Separation Separation membrane Detail: H 2 CO 2 Pore size ~ 0.5 nm 3. Interlayer 2. Interlayer 1. Interlayer (metallic) Pore size 3-10 nm metallic substrate * bar = 200 nm Gas Molecule H 2 CO 2 N 2 d kin in nm 0,29 0,33 0,36 * bar = 10 µm Institute of Energy Research IEF-1 Van Gestel, Meulenberg, Buchkremer, Brugge
4 Microporous membranes for CO 2 separation Example: Multilayer-Membrane on ceramic ZrO 2 substrate 3% Y 2 microporous toplayer (Pore size < 1 nm) Sol-Gel Method: γ-al 2 mesoporous layer (Pore size ~ 5 nm) Nano-Particle sol Particle size ~ 6 nm Sol-Gel Method: Colloidal Particle Sol Particle size ~ 30 nm 8Y 2 macroporous layer (Pore size ~ 100 nm) 8Y 2 substrate (Pore size ~ 1 µm) * bar = 10 µm Suspension Method: Particle size ~ 350 nm - Vacuum slip-casting - Dip-coating - Screen-printing Powder Method: Warm-pressing Institute of Energy Research IEF-1 Van Gestel, Meulenberg, Buchkremer, Brugge
5 Microporous membranes for CO 2 separation Substrate preparation - Warmpressing Warmpressing 8Y 2 Substrate + Sintering (1200 ºC) Large-scale Support: Preparation with Standard IEF-1 Technology for Solid Oxide Fuel Cells SOFC s (25 x 25 cm) Lab-scale Support for R & D: Polishing with diamant particles for improving Surface roughness (4 x 4 cm) Particle size: 3-5 µm Average Pore size: ~ 1 µm pore volume (mm³/g) Pore size distribution Substrate (Firing 1200 C, Hg-porosimetry) 0,0 0,5 1,0 1,5 2,0 2,5 3,0 pore size (mm) Institute of Energy Research IEF-1 Van Gestel, Meulenberg, Buchkremer, Brugge
6 Macroporous Interlayer Suspension coating 8Y 2 macroporous layer 8Y 2 substrate 8Y 2 macroporous layer * bar = 100 µm * bar = 1 µm abundance Particle size distribution Coating liquid (8Y 2 Suspension, Tosoh corp.) pore volume (mm³/g) Pore size distribution Membrane material (Firing 1100 C, Hg-porosimetry) particle size (nm) pore size (nm) Institute of Energy Research IEF-1 Van Gestel, Meulenberg, Buchkremer, Brugge
7 Mesoporous interlayer Sol-gel coating 8Y 2 mesoporous layer 8Y 2 mesoporous layer 8Y 2 macroporous layer 8Y 2 substrate 8Y 2 macroporous layer * bar = 10 µm * bar = 1 µm abundance Particle size distribution Coating liquid (Colloidal 8Y 2 Sol) pore volume (cm³/g) 0,30 0,25 0,20 0,15 0,10 0,05 Pore size distribution Membrane material (Firing 500 C, N 2 -ads./desorption) particle size (nm) 0, pore size (nm) Institute of Energy Research IEF-1 Van Gestel, Meulenberg, Buchkremer, Brugge
8 Microporous toplayer Sol-Gel Coating 8Y 2 microporous layer 8Y 2 microporous layer 8Y 2 mesoporous layer 8Y 2 double mesoporous layer 8Y 2 mesoporous layer 8Y 2 macroporous layer * bar = 1 µm * bar = 200 nm Particle size distribution Coating liquid (8Y 2 Nano-Particle Sol) 0,030 0,025 Pore size distribution Membrane material (Firing 450 C, N 2 -ads./desorption) pore volume (cm³/g) 0,020 0,015 0,010 0,005 0, pore size (nm) Institute of Energy Research IEF-1 Van Gestel, Meulenberg, Buchkremer, Brugge
9 Microporous toplayer Sol-Gel Coating 8Y 2 microporous double-layer 8Y 2 mesoporous double-layer * bar = 1 µm * bar = 200 nm Institute of Energy Research IEF-1 Van Gestel, Meulenberg, Buchkremer, Brugge
10 Microporous toplayer Sol-Gel Coating 8Y 2 microporous double-layer 8Y 2 mesoporous double-layer 8Y 2 macroporous layer * bar = 1 µm Institute of Energy Research IEF-1 Van Gestel, Meulenberg, Buchkremer, Brugge
11 Overview subsequent membrane coating steps Particle size 8Y 2 Suspension Particle size Colloidal 8Y 2 Sol Particle size Polymeric 8Y 2 Nano-Sol average particle size 350 nm average particle size 40 nm average particle size 6 nm abundance abundance particle size (nm) particle size (nm) macroporous layer mesoporous layer microporous layer * bar = 1 µm Pore size ~ 90 nm (1200ºC) Phase structure: Cubic * bar = 200 nm Pore size ~ 6-7 nm (500ºC) Phase structure: Cubic * bar = 200 nm Pore size ~ 1 nm (450ºC) Phase structure: Cubic Institute of Energy Research IEF-1 Van Gestel, Meulenberg, Buchkremer, Brugge
12 Membrane research topics in IEF-1 Focus on energy-related applications : 1 Development of porous and dense membranes for application in CO 2 -free power plants dense membranes for O 2 /N 2 separation microporous membranes for CO 2 /H 2 separation 2 Development of porous and dense membranes for application in advanced Solid Oxide Fuel Cells (SOFC s) porous anode and cathode layers dense electrolyte membrane Institute of Energy Research IEF-1 Van Gestel, Meulenberg, Buchkremer, Brugge
13 Standard FZ-Jülich SOFC (La,Sr)Mn cathode (La,Sr)Mn /8Y 2 cathode layer 8Y 2 electrolyte layer NiO/8Y 2 anode layer * bar = 10 µm NiO/8Y 2 substrate Planar configuration ( 20 cm x 20 cm) Anode supported concept with thin-film electrolyte I = ~ 1.5 A/cm 2 at 800ºC and 0.7 V (single cell); ~ 1.1 A/cm 2 (stack) Demonstrated 60-cell stack with 13 kw; in progress 20 kw system Institute of Energy Research IEF-1 Van Gestel, Meulenberg, Buchkremer, Brugge
14 Novel membranes for advanced SOFC s dense 8Y 2 electrolyte membrane on porous NiO/8Y 2 substrate * bar = 10 µm Conventional preparation method: (1) Deposition of macroporous membrane starting from ZrO 2 powder suspension (2) Sintering of macroporous membrane at high temperature (1400 C, 5h) Proposed alternative preparation method: (1) Deposition of membrane starting from ZrO 2 nano-particles (e.g. Coating with ultra-fine suspension or sol) (2) Sintering at lower temperature (objective < 1100 C) (3) Possibility to apply steel substrate, reduction of production cost Institute of Energy Research IEF-1 Van Gestel, Meulenberg, Buchkremer, Brugge
15 Novel membranes for advanced SOFC s Coating with ultra-fine suspension 8Y 2 mesoporous electrolyte membrane made from ultra-fine suspension (particle size = 80 nm) Surface 8Y 2 layer 8Y 2 /NiO anode layer 8Y 2 /NiO substrate * bar = 10 µm Institute of Energy Research IEF-1 Van Gestel, Meulenberg, Buchkremer, Brugge
16 Novel membranes for advanced SOFC s Coating with ultra-fine suspension 8Y 2 mesoporous membrane made from ultrafine suspension (particle size = 80 nm) Surface 8Y 2 layer 8Y 2 membrane layer made from colloidal and polymer sol 8Y 2 /NiO anode layer * bar = 2 µm Institute of Energy Research IEF-1 Van Gestel, Meulenberg, Buchkremer, Brugge
17 Novel membranes for advanced SOFC s Coating with ultra-fine suspension 8Y 2 mesoporous membrane made from ultrafine suspension (particle size = 80 nm) 8Y 2 membrane layer made fromsurface colloidal 8Yand 2 -ZrO polymer 2 layer sol anode layer substrate Application of developed mesoporous and microporous membrane coating technology for making thin and continuous electrolyte layers on standard SOFC substrate with a coarse structure * bar = 10 µm Institute of Energy Research IEF-1 Van Gestel, Meulenberg, Buchkremer, Brugge
18 Novel membranes for advanced SOFC s Coating with ultra-fine suspension Surface 8Y 2 layer after firing at 600 C 8Y 2 layer anode layer * bar = 1 µm Coating with ultra-fine suspension and sol * bar = 200 nm Surface 8Y 2 layer after firing at 600 C * bar = 1 µm * bar = 200 nm Institute of Energy Research IEF-1 Van Gestel, Meulenberg, Buchkremer, Brugge
19 Novel membranes for advanced SOFC s Coating with ultra-fine suspension (+ firing 1300 C) Surface 8Y 2 layer after firing at 1300 C Standard 1400 C * bar = 10 µm Coating with ultra-fine suspension and sol (+ firing 1300 C) * bar = 2 µm Surface 8Y 2 layer after firing at 1300 C Standard 1400 C * bar = 10 µm * bar = 2 µm Institute of Energy Research IEF-1 Van Gestel, Meulenberg, Buchkremer, Brugge
20 Novel membranes for advanced SOFC s 8Y 2 dense electrolyte membrane layer (1300 C) 8Y 2 /NiO anode layer * bar = 1 µm Institute of Energy Research IEF-1 Van Gestel, Meulenberg, Buchkremer, Brugge
21 Novel membranes for advanced SOFC s 8Y 2 dense electrolyte membrane layer (1300 C) anode layer substrate Application of developed mesoporous and microporous membrane coating technology for making thin and continuous electrolyte layers on standard SOFC substrate with a coarse structure * bar = 10 µm Institute of Energy Research IEF-1 Van Gestel, Meulenberg, Buchkremer, Brugge
22 Novel membranes for advanced SOFC s 8Y 2 dense electrolyte membrane layer (1200 C) anode layer substrate Standard firing 1400 C previous example 1300 C * bar = 10 µm this example 1200 C Institute of Energy Research IEF-1 Van Gestel, Meulenberg, Buchkremer, Brugge
23 Novel membranes for advanced SOFC s 8Y 2 dense electrolyte membrane layer (1200 C) anode layer substrate Institute of Energy Research IEF-1 Van Gestel, Meulenberg, Buchkremer, Brugge
24 Novel membranes for advanced SOFC s Surface Coating with 8Y 2 Oultra-fine 3 /NiO suspension anode layer (on standard SOFC substrate) Coating with ultra-fine suspension and sol Institute of Energy Research IEF-1 Van Gestel, Meulenberg, Buchkremer, Brugge
25 Novel membranes for advanced SOFC s Surface 8Y 2 porous membrane after firing at 600 C Coating with ultra-fine suspension Coating with ultra-fine suspension and sol Institute of Energy Research IEF-1 Van Gestel, Meulenberg, Buchkremer, Brugge
26 Novel membranes for advanced SOFC s Coating with ultra-fine suspension Surface 8Y 2 membrane after firing at 1200 C Coating with ultra-fine suspension and sol Institute of Energy Research IEF-1 Van Gestel, Meulenberg, Buchkremer, Brugge
27 Novel membranes for advanced SOFC s Detail 8Y 2 membrane after firing at 1200 C Coating with ultra-fine suspension Coating with ultra-fine suspension and sol Institute of Energy Research IEF-1 Van Gestel, Meulenberg, Buchkremer, Brugge
28 State of the art - Conclusion Current gas separation membranes aremadeof SiO 2 materials, having an insufficient (hydro)thermal stability for application in power plant streams Current solid oxide fuel cells are made by unwanted high-temperature sinter treatments In this work : Manufacturing of novel nano-structured ZrO 2 membranes Widely accepted material for long-term operation in gas separation Densification material at a lower temperature for SOFC manufacturing In progress : Optimization of the membrane pore size (target: high H 2 /CO 2 selectivity) Manufacturing SOFC s for current density characterization Institute of Energy Research IEF-1 Van Gestel, Meulenberg, Buchkremer, Brugge
29 Acknowledgement : Funding by Helmholtz Association of German Research Centers Helmholtz Alliance MEM-BRAIN SEM images made by Dr. Doris Sebold IEF-1 Institute of Energy Research IEF-1 Van Gestel, Meulenberg, Buchkremer, Brugge
Materials development for inorganic membrane layers at ECN
Materials development for inorganic membrane layers at ECN B.C. Bonekamp Presented at XXV EMS Summerschool, Leuven, Belgium, September ECN-M--09-062 May Materials Development for Inorganic Membrane Layers
More informationElectrophoretic Deposition. - process in which particles, suspended in a liquid medium, migrate in an electric field and deposit on an electrode
Electrophoretic Deposition - process in which particles, suspended in a liquid medium, migrate in an electric field and deposit on an electrode no redox differs from electrolytic in several ways deposit
More informationPorous silicon as base material of MEMS-compatible fuel cell components
Porous silicon as base material of MEMS-compatible fuel cell components José Geraldo Alves Brito Neto Tokyo University of Science - Faculty of Science and Technology Department of Mechanical Engineering
More informationPhysical properties of porous membranes. Membranes D f S BET [m 2 /g] d peak [nm]
The Sol-Gel Preparation and Characterization of Nanoporous Silica Membrane with Controlled Pore Size T. Fujii, T. Izumi, Dept. of Food Sci., Niigata Univ. of Pharm. & Appl. Life Sci., Niitsu, Niigata 956-8603,
More informationSynthesis of Zeolite Composite Membranes for CO2 Separation
Synthesis of Zeolite Composite Membranes for CO2 Separation April. 10. 2003 Sang Hoon Hyun, Dong Wook Shin, Young Eun Lee, Moon Hee Han*, and Churl Hee Cho* School of Materials Science & Engineering Yonsei
More informationThe goal of this project is to enhance the power density and lowtemperature efficiency of solid oxide fuel cells (SOFC) manufactured by atomic layer
Stanford University Michael Shandalov1, Shriram Ramanathan2, Changhyun Ko2 and Paul McIntyre1 1Department of Materials Science and Engineering, Stanford University 2Division of Engineering and Applied
More informationBatteries (Electrochemical Power Sources)
Batteries (Electrochemical Power Sources) 1. Primary (single-discharge) batteries. => finite quantity of the reactants 2. Secondary or rechargeable batteries => regeneration of the original reactants by
More informationSupplementary Information. Experimental Methods
Extremely thin Pd-silica mixed-matrix membranes with nano-dispersion for improved hydrogen permeability Masakoto Kanezashi, Mitsunori Sano, Tomohisa Yoshioka, and Toshinori Tsuru Department of Chemical
More informationCEITEC/Central European Institute of Technology BUT
GENERAL PRESENTATION Complete denomination: Brno University of Technology, Central European Institute of Technology Location (city, country): Brno, Czech Republic Technicka 10, 61600 Brno, CR Director:
More informationIntroduction to Reflectometry and Small Angle Scattering under Grazing Incidence
Mitglied der Helmholtz-Gemeinschaft Introduction to Reflectometry and Small Angle Scattering under Grazing Incidence E. Kentzinger Jülich Center for Neutron Science and Peter Grünberg Institut Jülich Research
More informationHydrothermal Stability Analysis of Carbonised Template Molecular Sieve Silica Membranes
Refereed Proceedings Separations Technology VI: New Perspectives on Very Large-Scale Operations Engineering Conferences International Year 2004 Hydrothermal Stability Analysis of Carbonised Template Molecular
More informationFUNDAMENTALS OF INORGANIC MEMBRANE SCIENCE AND TECHNOLOGY
Membrane Science and Technology Series, 4 FUNDAMENTALS OF INORGANIC MEMBRANE SCIENCE AND TECHNOLOGY Edited by A.J. Burggraaf Laboratory of Inorganic Materials Science, Faculty of Chemical Technology, University
More informationTechnologies and Approaches of CO 2 Capture
Southwest Regional Partnership Project Technologies and Approaches of CO 2 Capture Liangxiong Li, Brian McPherson, Robert Lee Petroleum Recovery Research Center New Mexico Institute of Mining and Technology,
More informationRepetition: Ion Plating
Repetition: Ion Plating Substrate HV (bis ca. 1kV) Optional ionization system Source Ionized filling gas Source material, ionized or neutral Repetition: Ion Plating Ion Species Separated ion source Ions
More informationGold nanothorns macroporous silicon hybrid structure: a simple and ultrasensitive platform for SERS
Supporting Information Gold nanothorns macroporous silicon hybrid structure: a simple and ultrasensitive platform for SERS Kamran Khajehpour,* a Tim Williams, b,c Laure Bourgeois b,d and Sam Adeloju a
More informationnot to be confused with using the materials to template nanostructures
Zeolites as Templates: continued Synthesis: Most zeolite syntheses are performed by using template-synthesis not to be confused with using the materials to template nanostructures templates are often surfactants
More informationNano-Composites for Next-Generation Electrochemical Devices
Nano-Composites for Next-Generation Electrochemical Devices Dr. Jason D. Nicholas Chemical Engineering & Materials Science Dept. Michigan State University, East Lansing, MI http://www.egr.msu.edu/nicholasgroup/index.html
More informationElectrolytes for Fuel Cells
Electrolytes for Fuel Cells Tom Zawodzinski Materials Science and Technology Division Los Alamos National Laboratory Air-Breather Fuel Cell Stack Systems Laptop Demo DCH/Enable Prototype Small Battery
More informationMembrane Performance Forecast
Membrane Performance Forecast Interested in Membranes? Liquid Selectivity in s ea cr Zeta potential analysis with SurPASS 3 from Anton Paar opens up new possibilities in the characterization of membranes
More informationSolutions for Assignment-6
Solutions for Assignment-6 Q1. What is the aim of thin film deposition? [1] (a) To maintain surface uniformity (b) To reduce the amount (or mass) of light absorbing materials (c) To decrease the weight
More informationEffect of dipping number on the fabricated silica ceramic membranes via sol dip-coating method
7, Issue 1 (2017) 19-24 Journal of Advanced Research in Applied Sciences and Engineering Technology Journal homepage: www.akademiabaru.com/araset.html ISSN: 2462-1943 Effect of dipping number on the fabricated
More informationAdvanced Analytical Chemistry Lecture 12. Chem 4631
Advanced Analytical Chemistry Lecture 12 Chem 4631 What is a fuel cell? An electro-chemical energy conversion device A factory that takes fuel as input and produces electricity as output. O 2 (g) H 2 (g)
More informationNanotechnology Fabrication Methods.
Nanotechnology Fabrication Methods. 10 / 05 / 2016 1 Summary: 1.Introduction to Nanotechnology:...3 2.Nanotechnology Fabrication Methods:...5 2.1.Top-down Methods:...7 2.2.Bottom-up Methods:...16 3.Conclusions:...19
More informationAalborg Universitet. Transport phenomena in gas-selective silica membranes Boffa, Vittorio. Creative Commons License Unspecified
Aalborg Universitet Transport phenomena in gas-selective silica membranes Boffa, Vittorio Creative Commons License Unspecified Publication date: 2016 Link to publication from Aalborg University Citation
More informationNano-sized ceria abrasive for advanced polishing applications in IC manufacturing
Nano-sized ceria abrasive for advanced polishing applications in IC manufacturing Joke De Messemaeker, Stijn Put, Daniël Nelis, Dirk Van Genechten, Paul Lippens, Yves Van Rompaey and Yvan Strauven Umicore
More informationSYNTHESIS OF INORGANIC MATERIALS AND NANOMATERIALS. Pr. Charles Kappenstein LACCO, Laboratoire de Catalyse en Chimie Organique, Poitiers, France
SYNTHESIS OF INORGANIC MATERIALS AND NANOMATERIALS Pr. Charles Kappenstein LACCO, Laboratoire de Catalyse en Chimie Organique, Poitiers, France Outline IV - FORMATION OF SOLIDS FROM SOLUTIONS 1) Glass
More informationHydrothermal stability of a new hybrid membrane in dehydration applications
Hydrothermal stability of a new hybrid membrane in dehydration applications Jaap Vente Approach Four way competences: Materials research System development Process design Implementation facilitation Five
More informationGeneration of Hydrogen Peroxide In ORR Over Low Loadings of Pt/C Catalysts
Generation of Hydrogen Peroxide In ORR Over Low Loadings of Pt/C Catalysts Raja Swaidan The Cooper Union Advisor: Dr. Branko N. Popov Electrochemical Engineering 26 July 2007 Overview of Research Studied
More informationCharacterization of microporous silica-based membranes by calorimetric analysis Boffa, Vittorio; Yue, Yuanzheng
Aalborg Universitet Characterization of microporous silica-based membranes by calorimetric analysis Boffa, Vittorio; Yue, Yuanzheng Published in: 6th Black Sea Conference on Analytical Chemistry - Book
More informationAdsorption Processes. Ali Ahmadpour Chemical Eng. Dept. Ferdowsi University of Mashhad
Adsorption Processes Ali Ahmadpour Chemical Eng. Dept. Ferdowsi University of Mashhad Contents Introduction Principles of adsorption Types of adsorption Definitions Brief history Adsorption isotherms Mechanism
More informationToshinori Tsuru, Hiroaki Shintani, Tomohisa Yoshioka, Masashi Asaeda
9/26/2006 (1/15) A bimodal catalytic membrane having a hydrogen-permselective silica layer on a bimodal catalytic support: Preparation and application to the steam reforming of methane Toshinori Tsuru,
More informationIntroduction Fuel Cells Repetition
Introduction Fuel Cells Repetition Fuel cell applications PEMFC PowerCell AB, (S1-S3) PEMFC,1-100 kw Toyota Mirai a Fuel Cell Car A look inside The hydrogen tank 1. Inside Layer of polymer closest to the
More informationExperimental details. General
Experimental details General TiO 2 P25 was purchased from Degussa; methyl methacrylate (MMA, 99%), 2,2 -azobis(2- methylpropionamidine) dihydrochloride (97%), titanium (IV) isopropoxide (97%), concentrated
More informationNetwork of Excellence
Network of Excellence IN SItu study and DEvelopment of processes involving nano PORous Solids Priority 3 NMP research area3.4.1.1 www. pores.gr Goals of the inside-pores The goal of the INSIDE-PORES is
More informationA1308. Combined experimental and modeling study of interaction between LSCF and CGO in SOFC cathodes
A1308 Combined experimental and modeling study of interaction between LSCF and CGO in SOFC cathodes Rémi Costa (1), Roberto Spotorno (1), Claudia Repetto (1), Zeynep Ilhan (1,2) and Vitaliy Yurkiv (1,2)
More informationPolarization analysis and microstructural characterization of SOFC anode and electrolyte supported cells
Polarization analysis and microstructural characterization of SOFC anode and electrolyte supported cells Lanzini A., Leone P., Santarelli M., Asinari P., Calì M. Dipartimento di Energetica. Politecnico
More informationDevelopment of Innovative Gas Separation Membranes through Sub- Nanoscale Material Control
Development of Innovative Gas Separation Membranes through Sub- Nanoscale Material Control Investigators Research Institute of Innovative Technology for the Earth (RITE) Yuichi Fujioka Group Leader, Chief
More informationSol-Gel Methods. Hydrolysis Condensation Gelation Ageing Drying Densification
Sol-Gel Methods Sol-gel process: Hydrolysis Condensation Gelation Ageing Drying Densification Powders: microcrystalline, nanocrystalline, amorphous Monoliths, Coatings, Films, Fibers Aerogels Glasses,
More informationPhysics and Chemistry of Interfaces
Hans Jürgen Butt, Karlheinz Graf, and Michael Kappl Physics and Chemistry of Interfaces Second, Revised and Enlarged Edition WILEY- VCH WILEY-VCH Verlag GmbH & Co. KGaA Contents Preface XI 1 Introduction
More informationCHAPTER 5 SURFACE TOPOGRAPHY STUDIES ON ELECTROPHORETICALLY DEPOSITED CHITOSAN ON POLYCAPROLACTONE MICRO FIBROUS SUBSTRATES
89 CHAPTER 5 SURFACE TOPOGRAPHY STUDIES ON ELECTROPHORETICALLY DEPOSITED CHITOSAN ON POLYCAPROLACTONE MICRO FIBROUS SUBSTRATES 5.1 INTRODUCTION Synthetic bio polymers such as PCL, poly (glycolic acid)
More informationAdvanced characterization: the key factor for standardization at nm-scale. Olha Sereda
Advanced characterization: the key factor for standardization at nm-scale Olha Sereda osr@csem.ch about CSEM Our mission Development and transfer of microtechnologies to the industrial sector in order
More informationGas Permeation Study Using Porous Ceramic Membranes
Energy and Environment Research; Vol. 4, No. 3; 2014 ISSN 1927-0569 E-ISSN 1927-0577 Published by Canadian Center of Science and Education Gas Permeation Study Using Porous Ceramic Membranes Mohammed N.
More informationChapter - 8. Summary and Conclusion
Chapter - 8 Summary and Conclusion The present research explains the synthesis process of two transition metal oxide semiconductors SnO 2 and V 2 O 5 thin films with different morphologies and studies
More informationSEPARATION BY BARRIER
SEPARATION BY BARRIER SEPARATION BY BARRIER Phase 1 Feed Barrier Phase 2 Separation by barrier uses a barrier which restricts and/or enhances the movement of certain chemical species with respect to other
More informationSolution-processable graphene nanomeshes with controlled
Supporting online materials for Solution-processable graphene nanomeshes with controlled pore structures Xiluan Wang, 1 Liying Jiao, 1 Kaixuan Sheng, 1 Chun Li, 1 Liming Dai 2, * & Gaoquan Shi 1, * 1 Department
More informationSynthesis and Characterization of high-performance ceramic materials for hightemperature
Synthesis and Characterization of high-performance ceramic materials for hightemperature CO 2 capture and hydrogen production. Location: Institute for Energy Technology (IFE), Kjeller, Norway Department
More informationPreparation of Colloidal Sols and Gels
Preparation of Colloidal Sols and Gels Objective This laboratory examines the preparation of silica suspensions and gels by the sol-gel processing of silicate solution under hydrolytic conditions using
More informationApplication of Hierarchical Titanate and Titania nanotubes in Dye Sensitized Solar Cells Dmitry V. Bavykin and Frank C. Walsh
Application of Hierarchical Titanate and Titania nanotubes in Dye Sensitized Solar Cells Dmitry V. Bavykin and Frank C. Walsh Energy Technology and Materials Engineering Research Groups School of Engineering
More informationSynthesis of uranium oxides by Complex Sol-Gel Processes (CSGP)
Synthesis of uranium oxides by Complex Sol-Gel Processes (CSGP) A.Deptula, M.Brykala, W.Lada, T.Olczak, D.Wawszczak Institute of Nuclear Chemistry and Technology Sol-Gel Laboratory Warsaw, Poland G.Modolo,
More informationCharacterisation of mesopores - ortho-positronium lifetime measurement as a porosimetry technique
Characterisation of mesopores - ortho-positronium lifetime measurement as a porosimetry technique S. Thraenert 1, E. M. Hassan 1, D. Enke 2, R. Krause-Rehberg 1 Martin-Luther-Universität Halle-Wittenberg
More informationInstitut für Energie und Umwelttechnik e.v.
Institut für Energie und Umwelttechnik e.v. Continuous synthesis of highly-specific nanopowder on the pilot-plant scale Tim Hülser Successful R&I 2015, Düsseldorf Duisburg, North-Rhine-Westphalia, Germany
More informationTowards selective test protocols for accelerated in situ degradation of PEM electrolysis cell components
Towards selective test protocols for accelerated in situ degradation of PEM electrolysis cell components 1 st International Conference on Electrolysis - Copenhagen Thomas Lickert, Claudia Schwarz, Patricia
More informationAll-Chemical-Solution Coated Conductors at Deutsche Nanoschicht GmbH
chemistry meets energy All-Chemical-Solution Coated Conductors at Deutsche Nanoschicht GmbH Michael Baecker; Martina Falter; Ron Feenstra; Brygida Wojtyniak; Jan Bennewitz; Jan Kunert; Mark O. Rikel Deutsche
More informationGENERAL ENGINEERING AND RESEARCH. Nano Capsule CMP Slurries: Enabling Localized Control of Chemical Exposure
GENERAL ENGINEERING AND RESEARCH National Science Foundation SBIR Phase II Nano Capsule CMP Slurries: Enabling Localized Control of Chemical Exposure Robin V. Ihnfeldt, Ph.D. July 11, 2016 Outline Introduction
More informationSynthesis of a Zeolite Column with a Monolithic Microhoneycomb Structure Using the Ice Template Method
Synthesis of a Zeolite Column with a Monolithic Microhoneycomb Structure Using the Ice Template Method Shin R. Mukai, Shinya Murata, Kazufusa Onodera and Izumi Yamada *1 Graduate School of Engineering,
More informationSUPPORTING INFORMATION. Preparation of colloidal photonic crystal containing CuO nanoparticles with. tunable structural colors
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 215 SUPPORTING INFORMATION Preparation of colloidal photonic crystal containing CuO nanoparticles
More informationSupports, Zeolites, Mesoporous Materials - Chapter 9
Supports, Zeolites, Mesoporous Materials - Chapter 9 Krijn P. de Jong Inorganic Chemistry and Catalysis Utrecht University NIOK CAIA Course, Schiermonnikoog, December 4 th, 2009 1 Overview of lecture Introduction
More informationFabrication Methods: Chapter 4. Often two methods are typical. Top Down Bottom up. Begins with atoms or molecules. Begins with bulk materials
Fabrication Methods: Chapter 4 Often two methods are typical Top Down Bottom up Begins with bulk materials Begins with atoms or molecules Reduced in size to nano By thermal, physical Chemical, electrochemical
More informationMicrostructured Porous Silica Obtained via Colloidal Crystal Templates
Paper No. 203e Microstructured Porous Silica Obtained via Colloidal Crystal Templates O. D. Velev, T. A. Jede, R. F. Lobo and A. M. Lenhoff Department of Chemical Engineering, University of Delaware, Newark
More informationAnodic alumina supported dual-layer microporous silica membranes
Journal of Membrane Science 287 (2007) 157 161 Rapid communication Anodic alumina supported dual-layer microporous silica membranes G. Xomeritakis a,, N.G. Liu a,1, Z. Chen a, Y.-B. Jiang a,b,r.köhn a,2,
More informationDirect Energy Conversion: Fuel Cells
Direct Energy Conversion: Fuel Cells References and Sources: Direct Energy Conversion by Stanley W. Angrist, Allyn and Beacon, 1982. Fuel Cell Systems, Explained by James Larminie and Andrew Dicks, Wiley,
More informationNanocontainers with controlled permeability for feedback active coatings
Nanocontainers with controlled permeability for feedback active coatings Contents: 1. Self-healing coatings based on nanocontainers for corrosion protection: - with ph-triggered release, - triggered by
More informationTrapping Lithium into Hollow Silica Microspheres. with a Carbon Nanotube Core for Dendrite-Free
Supporting Information Trapping Lithium into Hollow Silica Microspheres with a Carbon Nanotube Core for Dendrite-Free Lithium Metal Anodes Tong-Tong Zuo,, Ya-Xia Yin,, Shu-Hua Wang, Peng-Fei Wang,, Xinan
More informationVariable capacitor energy harvesting based on polymer dielectric and composite electrode
2.8.215 Variable capacitor energy harvesting based on polymer dielectric and composite electrode Robert Hahn 1*, Yuja Yang 1, Uwe Maaß 1, Leopold Georgi 2, Jörg Bauer 1, and K.- D. Lang 2 1 Fraunhofer
More informationIntroduction to Solid Oxide Fuel Cells. Solid Oxide Fuel Cell (SOFC)
Introduction to Solid Oxide Fuel Cells Basics Electrochemistry Microstructure Effects Stacks Solid Oxide Fuel Cell (SOFC) CATHODE: (La,Sr)(Mn)O 3 (LSM) LSM-YSZ ELECTROLYTE: ANODE: Y-doped ZrO 2 (YSZ) Ni-YSZ
More informatione - Galvanic Cell 1. Voltage Sources 1.1 Polymer Electrolyte Membrane (PEM) Fuel Cell
Galvanic cells convert different forms of energy (chemical fuel, sunlight, mechanical pressure, etc.) into electrical energy and heat. In this lecture, we are interested in some examples of galvanic cells.
More informationDesign and Fabrication of Hierarchically Porous Carbon with a Template-free Method
Supplementary information Design and Fabrication of Hierarchically Porous Carbon with a Template-free Method Yutong Gong, Zhongzhe Wei, Jing Wang, Pengfei Zhang, Haoran Li and Yong Wang * Carbon Nano Materials
More informationOne-Dimensional Nanomaterials for Energy and Electronics Applications
#1/28 One-Dimensional Nanomaterials for Energy and Electronics Applications Latika Menon Advanced Nanomaterials Laboratory Department of Physics l.menon@neu.edu 617-373-4530 617-373-4530 Menon Laboratories,
More informationMATERIALS FOR SUPERCAPACITORS ELECTRODES: PREFORMANCE AND NEW TRENDS
MATERIALS FOR SUPERCAPACITORS ELECTRODES: PREFORMANCE AND NEW TRENDS Bologna, May 23 th 2017 M. Federica De Riccardis SSPT-PROMAS-MATAS OUTLINE Basic concepts EDLC and PC Porosity Electrode materials Carbon
More informationCERAMIC MATERIALS I. Asst. Prof. Dr. Ayşe KALEMTAŞ. Office Hours: Wenesday, 09:30-10:30 am.
CERAMIC MATERIALS I Office Hours: Wenesday, 09:30-10:30 am. akalemtas@mu.edu.tr, akalemtas@gmail.com, Phone: 211 19 17 Metallurgical and Materials Engineering Department Liquid Phase Synthesis Fine Ceramic
More informationDetermination and Assessment of the Rheological Properties of Pastes for Screen Printing Ceramics
ANNUAL TRANSACTIONS OF THE NORDIC RHEOLOGY SOCIETY, VOL. 17, 2009 Determination and Assessment of the Rheological Properties of Pastes for Screen Printing Ceramics John W. Phair 1 and Andreas F-J. Kaiser
More informationSuperhydrophobic Surfaces
Superhydrophobic Surfaces Glen McHale and Mike Newton School of Biomedical & Natural Sciences Nottingham Trent University, UK Email: glen.mchale@ntu.ac.uk The Laboratory Themes & Expertise Wetting of surfaces
More informationCarbon Molecular Sieves and Spherical Graphitized Polymer Carbons for Sample Preparation Processes and Bulk Scale Purification Processes
Carbon Molecular Sieves and Spherical Graphitized Polymer Carbons for Sample Preparation Processes and Bulk Scale Purification Processes William R. Betz, Michael J. Keeler, Jay M. Jones, Wendy S. Roe,
More informationSHORT ANSWER QUESTIONS UNIT I: POLYMERS AND BUILDING MATERIALS
SHORT ANSWER QUESTIONS UNIT I: POLYMERS AND BUILDING MATERIALS 1. Define polymer. Give one example. 2. What is monomer? Give one example. 3. What is polymerization? 4. What is degree of polymerization?
More informationCarbon nanotubes and conducting polymer composites
University of Wollongong Thesis Collections University of Wollongong Thesis Collection University of Wollongong Year 4 Carbon nanotubes and conducting polymer composites May Tahhan University of Wollongong
More informationNano-silica production by a sustainable process; application in building materials.
Nano-silica production by a sustainable process; application in building materials. A. LÁZARO AND H. J. H. BROUWERS Department of Architecture, Building and Planning Unit of Building Physics and Systems,
More informationGRAPHENE/CARBON BLACK COUNTER ELECTRODE FOR PEROVSKITE SOLAR CELL. Nutsuda Bunyoo, Nuttapol Pootrakulchote*
GRAPHENE/CARBON BLACK COUNTER ELECTRODE FOR PEROVSKITE SOLAR CELL Nutsuda Bunyoo, Nuttapol Pootrakulchote* Department of Chemical Technology, Faculty of Science, Chulalongkorn University Center of Excellence
More informationDevelopment of Innovative Gas Separation Membranes Through Sub-Nanoscale Materials Control
GCEP Research Symposium 2006 Wednesday, September 20, 2006 Carbon Mitigation, Capture, and Separation Development of Innovative Gas Separation Membranes Through Sub-Nanoscale Materials Control Yuichi Fujioka,
More informationELECTROCHROMIC RADIATORS FOR MICROSPACECRAFT THERMAL CONTROL
ELECTROCHROMIC RADIATORS FOR MICROSPACECRAFT THERMAL CONTROL Anthony Paris Kevin Anderson Jet Propulsion Laboratory Prasanna Chandrasekhar, Brian Zay, Terrance McQueeney Ashwin-Ushas Corporation, Inc.,
More informationProperties and synthesis of ultra-thin SOFC structures Jingyu Shi, Frank M. Zalar, and Henk Verweij Department of Materials Science & Engineering,
Properties and synthesis of ultra-thin SOFC structures Jingyu Shi, Frank M. Zalar, and Henk Verweij Department of Materials Science & Engineering, Ohio State University, 241 College Road, Columbus OH 4321-1178,
More informationPreparation of DielectAcs HR Mirrors from Colloidal Oxide Suspensions Containing Organic Polymer Binders
UCRL-JC-115940 Preparation of DielectAcs HR Mirrors from Colloidal Oxide Suspensions Containing Organic Polymer Binders I. M. Thomas This paper was prepared for submittal to the SPIE International Symposia
More informationResolving Questions of Biological Interface Chemistry with TOF-SIMS and FIB-TOF Tomography
Resolving Questions of Biological Interface Chemistry with TOF-SIMS and FIB-TOF Tomography Gregory L. Fisher, John S. Hammond & Scott R. Bryan, Physical Electronics With acknowledgements to: Prof. Reinhard
More informationProton-Conducting Nanocomposites and Hybrid Polymers
Proton-onducting Nanocomposites and Hybrid Polymers Y.D. Premchand 1, M.L. Di Vona 2, and P. Knauth 1 1 Introduction This chapter is about proton-conducting nanocomposites and hybrid polymers. Before beginning
More informationBlock Copolymer Based Hybrid Nanostructured Materials As Key Elements In Green Nanotechnology
The 7 th Korea-U.S. Nano Forum Block Copolymer Based Hybrid Nanostructured Materials As Key Elements In Green Nanotechnology Dong Ha Kim Department of Chemistry and Nano Science, Ewha Womans University
More informationDevelopment of active inks for organic photovoltaics: state-of-the-art and perspectives
Development of active inks for organic photovoltaics: state-of-the-art and perspectives Jörg Ackermann Centre Interdisciplinaire de Nanoscience de Marseille (CINAM) CNRS - UPR 3118, MARSEILLE - France
More informationMicro/nano and precision manufacturing technologies and applications
The 4th China-American Frontiers of Engineering Symposium Micro/nano and precision manufacturing technologies and applications Dazhi Wang School of Mechanical Engineering Dalian University of Technology
More informationDOWNLOAD OR READ : NANOSTRUCTURED MATERIALS PROCESSING PROPERTIES AND APPLICATIONS 2ND ENLARGED EDITION PDF EBOOK EPUB MOBI
DOWNLOAD OR READ : NANOSTRUCTURED MATERIALS PROCESSING PROPERTIES AND APPLICATIONS 2ND ENLARGED EDITION PDF EBOOK EPUB MOBI Page 1 Page 2 nanostructured materials processing properties and applications
More informationMetallurgical and Materials Engineering Department MME 2509 Materials Processing Laboratory SOL-GEL DIP COATING
Metallurgical and Materials Engineering Department MME 2509 Materials Processing Laboratory SOL-GEL DIP COATING Assist. Prof. Dr. Tolga TAVŞANOĞLU 1. Sol-gel Process Sol-gel process is used for production
More informationOMICS Group International is an amalgamation of Open Access publications
About OMICS Group OMICS Group International is an amalgamation of Open Access publications and worldwide international science conferences and events. Established in the year 2007 with the sole aim of
More informationRECENT DEVELOPMENT IN THE ZEOLITE MEMBRANE SYNTHESIS
RECENT DEVELOPMENT IN THE ZEOLITE MEMBRANE SYNTHESIS L. GÓRA, J.C. JANSEN, A.W.C. van den BERG and Th. MASCHMEYER Laboratory for Applied Organic Chemistry and Catalysis, DelftChemTech, Delft University
More informationDevelopment of Bifunctional Electrodes for Closed-loop Fuel Cell Applications. Pfaffenwaldring 6, Stuttgart, Germany
Development of Bifunctional Electrodes for Closed-loop Fuel Cell Applications S. Altmann a,b, T. Kaz b, K. A. Friedrich a,b a Institute of Thermodynamics and Thermal Engineering, University Stuttgart,
More informationPlasma Route to Nanosciences and Nanotechnology Frontiers
J. Plasma Fusion Res. SERIES, Vol. 8 (2009) Plasma Route to Nanosciences and Nanotechnology Frontiers M.P.SRIVASTAVA Department of Physics and Astrophysics, University of Delhi, Delhi -110007, INDIA (Received:
More informationSupplemental Information. Carbon Monoxide Gas Diffusion Electrolysis. that Produces Concentrated C 2 Products. with High Single-Pass Conversion
JOUL, Volume 3 Supplemental Information Carbon Monoxide Gas Diffusion Electrolysis that Produces Concentrated C 2 Products with High Single-Pass Conversion Donald S. Ripatti, Thomas R. Veltman, and Matthew
More informationOn Continuum Models for Heat Transfer in Small Scale Porous Materials Professor Jinliang Yuan
On Continuum Models for Heat Transfer in Small Scale Porous Materials Professor Jinliang Yuan August 30, 2013 Department of Energy Sciences Lund University, Sweden Jinliang.yuan@energy.lth.se Why porous
More informationHydrogen permeation using nanostructured silica membranes
Sustainable Development and Planning VII 447 Hydrogen permeation using nanostructured silica membranes M. N. Kajama, N. C. Nwogu & E. Gobina Centre for Process Integration and Membrane Technology (CPIMT),
More informationImpedance spectroscopy of symmetric cells for SOFC research
Impedance spectroscopy of symmetric cells for SOFC research Shany Hershkovitz, Sioma Baltianski and Yoed Tsur Department of Chemical Engineering Technion, 32000 Haifa, Israel Outline A short update on
More informationFacilitated transport of thiophenes through Ag 2 O-filled PDMS membranes
Facilitated transport of thiophenes through PDMS membranes Rongbin Qi, Yujun Wang, Jiding Li *, Shenlin Zhu State Key Laboratory of Chemical Engineering, Department of Chemical Engineering, Tsinghua University.
More informationJulien Schmitt, postdoc in the Physical Chemistry department. Internship 2010: Study of the SAXS scattering pattern of mesoporous materials
Before starting Julien Schmitt, postdoc in the Physical Chemistry department Internship 2010: Study of the SAXS scattering pattern of mesoporous materials PhD 2011-2014: Self-assembly mechanism of mesoporous
More informationUV-LED Module Design with Maximum Power Density
UV-LED Module Design with Maximum Power Density Manfred Scholdt 1, Christian Herbold 1, Marc Schneider 2, Cornelius Neumann 1 1 e 2 Institute for Data Processing and Electronics e (LTI) KIT Universität
More informationREDUCED GRAPHITE OXIDE-INDIUM TIN OXIDE COMPOSITES FOR TRANSPARENT ELECTRODE USING SOLUTION PROCESS
18 TH INTERNATIONAL CONFERENCE ON COMPOSITE MATERIALS REDUCED GRAPHITE OXIDE-INDIUM TIN OXIDE COMPOSITES FOR TRANSPARENT ELECTRODE USING SOLUTION PROCESS K. S. Choi, Y. Park, K-.C. Kwon, J. Kim, C. K.
More information