Supporting Information
|
|
- Erin Rose
- 6 years ago
- Views:
Transcription
1 Supporting Information Hypercrosslinked Organic Microporous Polymers Based on Alternative Copolymerization of Bismaleimide Hui Gao, Lei Ding, Wenqing Li, Guifeng Ma, Hua Bai and Lei Li *, College of Materials, Xiamen University, Xiamen, , P. R. China Department of Chemical and Biochemical Engineering, College of Chemistry and Chemical Engineering, National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, Xiamen University, Xiamen , P. R. China Tel: Fax:
2 Experimental section Materials N,N'-4,4'-diphenylmethane-bismaleimide (BDM), N,N'-(4-Methyl-1, 3-phenylene) bismalemide (BMP) were provided by Institute of Chemistry, Chinese Academy of Sciences. N,N'-1,4-phenylenedimaleimide (p-pdm) was obtained from Tokyo Chemical Industry. N,N'-1,3-phenylenedimaleimide (m-pdm), styrene (St) and divinylbenzene (DVB) were purchased from J&K Scientific Co. Ltd. 2,2'-azobisisobutyronitrile (AIBN) was purchased from Tianjin Guangfu Fine Chemical Research Institute. Magnesium sulfate (MgSO 4 ) and N,N-Dimethylformamide (DMF) were obtained from Sinopharm Chemical Reagent Co. Ltd. DMF was predried with MgSO 4 and subsequently distilled prior to be used as solvent. Preparation of the bismaleimide-based HOMPs Typically, a solution of BDM ( g, 2 mmol), DVB ( g, 2 mmol), and AIBN ( g, 0.02mmol) were dissolved in 10 ml DFM in a 25 ml round-bottom flask equipped with a condenser and a argon gas inlet. The solution was stirred at room temperature and deoxygenated by argon bubbling for 0.5 h, and then kept at 80 o C for 24 h. The resulting solids were separated by filter-suction and extracted in a Soxhlet extractor by THF for 12 h to further remove the unreacted monomer. Finally the
3 obtained powder was dried under reduced pressure at 80 C for 24 h. Characterization The chain structures of the polymers were characterized by 13 C cross-polarization magic angle spinning (CP/MAS) NMR spectra (WB 400 MHz BRUKER AV III spectrometer). Measurements were made with a 4 mm MAS probe spinning at 12 khz. The incorporation of the DVB/St and bismaleimide comonomers were confirmed by a Fourier transform infrared (FTIR) spectrometer (NICOLET is10). The morphology of samples was observed by scanning electron microscopy (SEM) (SU-70, Hitachi) under an electron beam with an accelerating voltage of 10 kv and a working distance of 15 mm.elemental analysis was performed by an Elementar Vario EL III elemental analyzer. The thermogravimetric analysis (TGA) of the copolymers was conducted by a thermal analyzer (Q500 V6.7 Build 203), under N 2 atmosphere with a heating rate of 10 o C min 1. Nitrogen adsorption/desorption isotherms at 77.3 K were obtained using a Micromeritics TriStar II 3020 static volumetric analyzer. Prior to adsorption measurements, the samples were degassed for 12 h at 100 ºC ensuring that the residual pressure fell below 10 mbar. The Brunauer-Emmett-Teller surface area was calculated within the relative pressure range 0.05 to 0.2. Total volume was calculated at P/P 0 = The CO 2 adsorption isotherms were measured at 273 K and 298 K using
4 Micromeritics TriStar II 3020 static volumetric analyzer. The N 2 adsorption isotherms were measured at 273 K up to 1.0 bar. The H 2 adsorption isotherms were measured using a Micromeritics ASAP 2020 static volumetric analyzer at 77.3 K up to 1.0 bar. Kinetics of hydrogen adsorption for the HOMPs was determined on dosing the first aliquot of hydrogen using a Micromeritics ASAP 2020 M surface areas and porosity analyzer and the standard calculation routines in its software named ROA (rate of adsorption). Kinetics of carbon dioxide adsorption for the HOMPs was determined on dosing the first aliquot of carbon dioxide using a Micromeritics ASAP 2020 M surface areas and porosity analyzer and the standard calculation routines in its software named ROA (rate of adsorption). Measurement of organic vapor adsorption Organic vapor adsorption was measured by a home-made device 1. In a typical adsorption of benzene experiment, a certain amount of HOMPs were weighed and loaded in a small metallic basket, and then the basket was hung by a quartz spring in a stainless steel tube charged with saturated vapor of benzene, and the height of the basket was measured immediately through the telescopic cathetometer. After an hour, height was measured again. Adsorption capacity value was thus calculated (the height difference of the ending number and the original number
5 multiplies the coefficient of the quartz spring, and then the obtained value divide the weight of HOMPs). The other organic vapor adsorption experiment was done following the same procedure.
6 Table S1 The amount of raw materials in each experiment. a Samples Bismaleimide BDM/g BMP/g m-pdm/g P-PDM /g St/g DVB/g a The amount of AIBN is fixed at 1 mol % of biamaleimide in all experiments.
7 Table S2 Elemental Analysis of Polymers samples Theoretical (wt %) Experimental (wt %) C H N C H N BDM-St BMI-St m-pdm-st p-pdm-st BDM-DVB BMI-DVB m-pdm-dvb p-pdm-dvb
8 Figure S1 The SEM micrograph of the BDM-DVB.
9 Statistics Graph (1 measurem ents) 40 Number (%) Size (d.nm ) Mean with +/-1 Standard Deviation error bar Figure S2. The size distribution of BDM-DVB measured by dynamical light scattering.
10 Figure S3 The FTIR spectra of BDM, BMP, m-pdm and p-pdm.
11 Figure S4. Differential (top) and number fraction (bottom) pore size distribution of BDM-DVB (a, b) and m-pdm-dvb (c, d) measured by mercury intrusion porosimetry.
12 Figure S5 Nitrogen adsorption/desorption isotherms for BDM-DVB before (blue) and after (red) being immersed 1 M HCl (red) for 12 h.
13 Figure S6 TGA curve of the BDM-DVB, BMP-DVB, m-pdm-dvb and p-pdm-dvb.
14 1.0 Normalized adsorption amount Time (s) Figure S7 Kinetics of carbon dioxide adsorption for p-pdm-dvb at 273 K/0.133 bar.
15 Figure S8 Adsorption isotherms of CO 2 and N 2 at 273 K for p-pdm-dvb.
16 Figure S9 Adsorption selectivity of CO 2 over N 2 for p-pdm-dvb derived from the initial slope method at 273 K.
17 1.0 Normalized adsorption amount Time (s) Figure S10 Kinetics of hydrogen adsorption for p-pdm-dvb at 77.3 K/0.06 bar.
18 Figure S11 Nitrogen adsorption/desorption isotherms for activated carbon.
19 Figure S12 Nitrogen adsorption/desorption isotherms for pure poly(divinylbenzene).
20 Figure S13 CO 2 adsorption and desorption isotherms at 273 K for pure poly(divinylbenzene).
21 Reference [1] Gong, Y.; Wang, H.; Chen, Y.; Hu, X.; Ibrahim, A.-R.; Tanyi, A.-R.; Hong, Y.; Su, Y.; Li, J., Ind. Eng. Chem. Res. 2013, 52,
Electronic Supplementary Information
Electronic Supplementary Information The directing effect of linking unit on building microporous architecture in tetraphenyladmantane-based poly(schiffbase) networks Guiyang Li, Biao Zhang, Jun Yan and
More informationElectronic Supplementary Information. Noninvasive Functionalization of Polymers of Intrinsic Microporosity for Enhanced CO 2 Capture
Electronic Supplementary Information Noninvasive Functionalization of Polymers of Intrinsic Microporosity for Enhanced CO 2 Capture Hasmukh A. Patel and Cafer T. Yavuz* Oxide and Organic Nanomaterials
More informationSupporting Information
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2016 Supporting Information Polystyrene Sulfonate Threaded in MIL-101Cr(III) as Stable and
More informationElectronic supplementary information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 Electronic supplementary information Heterogeneous nucleation and growth of highly crystalline
More informationSupporting Information
Copyright WILEY-VCH Verlag GmbH & Co. KGaA, 69469 Weinheim, Germany, 2012. Supporting Information for Adv. Mater., DOI: 10.1002/adma.201202447 Hypercrosslinked Aromatic Heterocyclic Microporous Polymers:
More informationSupporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 214 Supporting Information Lei Liu, ab Yijie Xia, b Jie Zhang* b a) China Center for Modernization
More informationElectronic Supporting Information
Electronic Supporting Information for the manuscript Tunable Absorption and Emission Wavelength in Conjugated Microporous Polymers by Copolymerization by Jessica Brandt, a Johannes Schmidt, b Arne Thomas,
More informationSupporting Information. Metalated mesoporous poly(triphenylphosphine) with azo-functionality: efficient catalysts for CO 2 conversion
Supporting Information Metalated mesoporous poly(triphenylphosphine) with azo-functionality: efficient catalysts for C 2 conversion Zhenzhen Yang, Bo Yu, Hongye Zhang, Yanfei Zhao, Yu Chen, Zhishuang Ma,
More informationSupporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Supporting Information Title: A sulfonated polyaniline with high density and high rate Na-storage
More informationSupporting Information. Rapid synthesis of metal-organic frameworks MIL-101(Cr) without the addition of solvent and hydrofluoric acid
Supporting Information Rapid synthesis of metal-organic frameworks MIL-11(Cr) without the addition of solvent and hydrofluoric acid Kunyue Leng a, Yinyong Sun a *, Xiaolin Li a, Shun Sun a, Wei Xu b a
More informationSupporting Information for
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C. This journal is The Royal Society of Chemistry 2014 Supporting Information for Application of thermal azide-alkyne cycloaddition
More informationSupplementary Information. Rational Design of Soluble and Clickable Polymers Prepared by. Conventional Free Radical Polymerization of
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2017 Supplementary Information Rational Design of Soluble and Clickable Polymers Prepared by
More informationSupporting Information for: Three-Dimensional Cuprous Oxide Microtube Lattices with High Catalytic
Supporting Information for: Three-Dimensional Cuprous Oxide Microtube Lattices with High Catalytic Activity Templated by Bacterial Cellulose Nanofibers Guigao Liu, Fang He*, Xiaoqing Li, Sihui Wang, Lijun
More informationSupporting Information. Nanoscale Kirkendall Growth of Silicalite-1 Zeolite Mesocrystals with. Controlled Mesoporosity and Size
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Supporting Information Nanoscale Kirkendall Growth of Silicalite-1 Zeolite Mesocrystals with Controlled
More informationRapid, Efficient Phase Pure Synthesis of Ca 2 AlNO 3 Layered Double Hydroxide
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2015 Supporting Information Rapid, Efficient Phase Pure Synthesis of Ca 2 AlNO
More informationElectronic Supporting Information for
Electronic Supporting Information for An efficient long fluorescence lifetime polymer-based sensor based on europium complex as chromophore for the specific detection of F -, CH 3 COO - -, and H 2 PO 4
More informationMetal-organic frameworks (MOFs) as precursors towards TiO x /C. composites for photodegradation of organic dye
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supplementary Information Metal-organic frameworks (MOFs) as precursors towards TiO x /C composites
More informationSynthesis of nano-sized anatase TiO 2 with reactive {001} facets using lamellar protonated titanate as precursor
Supporting Information Synthesis of nano-sized anatase TiO 2 with reactive {001} facets using lamellar protonated titanate as precursor Liuan Gu, Jingyu Wang *, Hao Cheng, Yunchen Du and Xijiang Han* Department
More informationSupporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Information Nanoparticle-to-vesicle and nanoparticle-to-toroid transitions of ph-sensitive
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information Experimental section Materials Sodium
More informationElectronic Supplementary Information (ESI)
Electronic Supplementary material (ESI) for Nanoscale Electronic Supplementary Information (ESI) Synthesis of Nanostructured Materials by Using Metal-Cyanide Coordination Polymers and Their Lithium Storage
More informationSupporting Information
Supporting Information For the manuscript Catalyst-free Preparation of Melamine-based Microporous Polymer Networks through Schiff Base Chemistry by Matthias Georg Schwab, + Birgit Faßbender, + Hans Wolfgang
More informationConstruction of Superior Visible-Light-Driven Photocatalyst. Platform-Electron Withdrawing Unit Triadic Structure. Covalent Organic Framework
Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2017 Construction of Superior Visible-Light-Driven Photocatalyst Based on C 3 N 4 Active
More informationExceptional Organic Solvents Uptake by Disulfide linked Polymeric. Networks
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information Exceptional Organic Solvents Uptake by Disulfide linked
More informationSupporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 204 Supporting Information Efficient CO 2 Capture by a Task-Specific Porous Organic Polymer Bifunctionalized
More informationSupporting Information
Supporting Information UCST or LCST? Composition-Dependent Thermoresponsive Behavior of Poly(N-Acryloylglycinamide-co-Diacetone Acrylamide) Wenhui Sun, Zesheng An*, Peiyi Wu * Experimental Materials Glycinamide
More informationVersatile Preparation of Monodisperse Poly (furfuryl alcohol) and Carbon. Hollow Spheres in a Simple Microfluidic Device
Electronic supplementary information (ESI) Versatile Preparation of Monodisperse Poly (furfuryl alcohol) and Carbon Hollow Spheres in a Simple Microfluidic Device Yichang Pan, Minhua Ju, Chongqing Wang,
More informationFabrication of COF-MOF Composite Membranes and Their Highly. Selective Separation of H 2 /CO 2
[Supporting Information] Fabrication of COF-MOF Composite Membranes and Their Highly Selective Separation of H 2 /CO 2 Jingru Fu, a Saikat Das, a Guolong Xing, a Teng Ben, a * Valentin Valtchev a,b and
More informationSupporting Information
Supporting Information Solid Polymer Electrolytes Based on Functionalized Tannic Acids from Natural Resources for All-Solid-State Lithium- Ion Batteries Jimin Shim, [a] Ki Yoon Bae, [b] Hee Joong Kim,
More informationSUPPLEMENTARY INFORMATION
DOI: 10.1038/NCHEM.2633 Mechanically controlled radical polymerization initiated by ultrasound Hemakesh Mohapatra, Maya Kleiman, Aaron P. Esser-Kahn Contents 1. Materials and methods 2 2. Procedure for
More informationA triazine-based covalent organic polymer for efficient CO 2 adsorption
Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2015 Supporting Information A triazine-based covalent organic polymer for efficient CO
More informationCovalent-Organic Frameworks: Potential Host Materials for Sulfur Impregnation in Lithium-Sulfur Batteries
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2014 Covalent-Organic Frameworks: Potential Host Materials for Sulfur Impregnation
More informationAn Anionic Metal Organic Framework For Adsorption and. Separation of Light Hydrocarbons
Supporting Information for An Anionic Metal Organic Framework For Adsorption and Separation of Light Hydrocarbons Jia Li, Hong-Ru Fu, Jian Zhang, Lan-Sun Zheng, and Jun Tao* State Key Laboratory of Physical
More informationSupplementary Information for
Supplementary Information for Microwave-Assisted Solvothermal Synthesis of Zirconium Oxide Based Metal-Organic Frameworks Weibin Liang and Deanna M. D Alessandro* School of Chemistry, The University of
More informationSupporting Information
Supporting Information Efficient Temperature Sensing Platform Based on Fluorescent Block Copolymer Functionalized Graphene Oxide Hyunseung Yang, Kwanyeol Paek, and Bumjoon J. Kim * : These authors contributed
More informationapplied as UV protective films
Nanocomposite gels via in-situ photoinitiation and disassembly of TiO 2 -Clay composites with polymers applied as UV protective films Chuanan Liao, Qing Wu, Teng Su, Da Zhang, Qingsheng Wu and Qigang Wang*
More informationSupporting Information
Supporting Information Anion Conductive Triblock Copolymer Membranes with Flexible Multication Side Chain Chen Xiao Lin a,b, Hong Yue Wu a, Ling Li a, Xiu Qin Wang a, Qiu Gen Zhang a, Ai Mei Zhu a, Qing
More informationSupporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Supporting Information Novel Nanoporous Ferrocenyl Framework for Clean Energy Application Qingquan
More informationScheme 1: Reaction scheme for the synthesis of p(an-co-mma) copolymer
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 Design and Development of Poly (acrylonitrile-co-methyl methacrylate) Copolymer to Improve
More informationSupporting Information
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 2017 Supporting Information Visible-Light-Driven Conversion of CO 2 from Air to CO Using an Ionic
More informationSupporting Information
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2018 Supporting Information 2-Methylimidazole-Assisted Synthesis of Two-Dimensional MOF-5 Catalyst
More informationHaving a High Mg/Al Molar Ratio
SUPPORTING INFORMATION High-Temperature CO 2 Sorption on Hydrotalcite Having a High Mg/Al Molar Ratio Suji Kim, Sang Goo Jeon, and Ki Bong Lee*, Department of Chemical and Biological Engineering, Korea
More informationAdsorption of Methylene Blue on Mesoporous SBA 15 in Ethanol water Solution with Different Proportions
2015 2 nd International Conference on Material Engineering and Application (ICMEA 2015) ISBN: 978-1-60595-323-6 Adsorption of Methylene Blue on Mesoporous SBA 15 in Ethanol water Solution with Different
More informationTuning Porosity and Activity of Microporous Polymer Network Organocatalysts by Co-Polymerisation
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Information Tuning Porosity and Activity of Microporous Polymer Network Organocatalysts
More informationSupporting Information. Table of content
Supporting Information Nitrogen-Rich Triptycene-Based Porous Polymer for Gas Storage and Iodine Enrichment Hui Ma, Jing-Jing Chen, Liangxiao Tan, Jian-Hua Bu,*, Yanhong Zhu,*, Bien Tan, Chun Zhang*, Key
More informationNovel Supercapacitor Materials Including OLED emitters
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2015 Supporting Information Novel
More informationSupporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 ucleophilic addition of amines, alcohols, and thiophenol with epoxide/olefin using highly efficient
More informationSupporting Information
Supporting Information Azo Polymer Janus Particles and Their Photoinduced Symmetry-Breaking Deformation Xinran Zhou, Yi Du, Xiaogong Wang* Department of Chemical Engineering, Laboratory of Advanced Materials
More informationTrisulfur Radical Anion as the Key Intermediate for the. Synthesis of Thiophene via the Interaction between Elemental.
Trisulfur Radical Anion as the Key Intermediate for the Synthesis of Thiophene via the Interaction between Elemental Sulfur and NaOtBu Guoting Zhang, a Hong Yi, a Hong Chen, a Changliang Bian a Chao Liu
More informationEthers in a Porous Metal-Organic Framework
Supporting Information Enhanced Isosteric Heat of H 2 Adsorption by Inclusion of Crown Ethers in a Porous Metal-Organic Framework Hye Jeong Park and Myunghyun Paik Suh* Department of Chemistry, Seoul National
More informationSelective aerobic oxidation of biomass-derived HMF to 2,5- diformylfuran using a MOF-derived magnetic hollow Fe-Co
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 2016 Selective aerobic oxidation of biomass-derived HMF to 2,5- diformylfuran using a MOF-derived
More informationSBA-15-functionalized sulfonic acid confined acidic ionic liquid: a powerful and water-tolerant catalyst for solvent-free esterifications
SBA-15-functionalized sulfonic acid confined acidic ionic liquid: a powerful and water-tolerant catalyst for solvent-free esterifications Babak Karimi* a, Majid Vafaeezadeh a a Department of Chemistry,
More informationEasy synthesis of hollow core, bimodal mesoporous shell carbon nanospheres and their. application in supercapacitor
Electronic Electronic Supplementary Information Easy synthesis of hollow core, bimodal mesoporous shell carbon nanospheres and their application in supercapacitor Bo You, Jun Yang,* Yingqiang Sun and Qingde
More informationSupple. KBr. C N) cm (s, p-phenenylene
Supple ementary Information Supplementary Figures Supplementary Figure S1. FTIR spectra of azo-cops. The spectra were recorded as KBr pellets. 3400 (s, free N H), 32000 (s, hydrogen bonded N H), 1610 (s,
More informationSupporting Information
Supporting Information Chitosan Aerogels: Transparent, Flexible Thermal Insulators Satoru Takeshita* and Satoshi Yoda Detailed experimental procedure Materials: Chitosan (deacetylation rate: > 80%, viscosity:
More informationBabak Karimi* and Majid Vafaeezadeh
Electronic upplementary Material (EI) for RC Advances This journal is The Royal ociety of Chemistry 2013 BA-15 functionalized sulfonic acid confined hydrophobic and acidic ionic liquid: a highly efficient
More informationElectronic Supplementary Information (ESI)
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information (ESI) Enhancing stability and porosity of penetrated
More informationShape Assisted Fabrication of Fluorescent Cages of Squarate based Metal-Organic Coordination Frameworks
Supporting Information Shape Assisted Fabrication of Fluorescent Cages of Squarate based Metal-Organic Coordination Frameworks Kolleboyina Jayaramulu, a Katla Sai Krishna, a Subi J. George, b Muthuswamy
More informationSupporting Information
Supporting Information Photocatalytic Suzuki Coupling Reaction using Conjugated Microporous Polymer with Immobilized Palladium Nanoparticles under Visible Light Zi Jun Wang, Saman Ghasimi, Katharina Landfester
More informationNanoporous Organosilica Membrane for Water Desalination
Electronic Supplementary Information Nanoporous Organosilica Membrane for Water Desalination Yen Thien Chua a, Chun Xiang Cynthia Lin a, Freddy Kleitz b, Xiu Song Zhao a, Simon Smart a* a The University
More informationSupplementary Information
Supplementary Information Fabrication of Novel Rattle-Type Magnetic Mesoporous carbon Microspheres for Removal of Microcystins Xinghua Zhang and Long Jiang* Beijing National Laboratory for Molecular Science
More informationSupplementary Information T. Ebert, a A. Wollbrink, b A. Seifert, a R. John, a and S. Spange a
Electronic Supplementary Material (ESI for Polymer Chemistry. This journal is The Royal Society of Chemistry Please do 216 not adjust margins ARTICLE Supplementary Information T. Ebert, a A. Wollbrink,
More informationAutonomous Fluorescence Regulation in Responsive Polymer Systems Driven by a Chemical Oscillating Reaction **
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2016 Electronic Supporting Information Autonomous Fluorescence Regulation in Responsive Polymer
More informationSupporting Information
Copyright WILEY-VCH Verlag GmbH & Co. KGaA, 69469 Weinheim, Germany, 2013. Supporting Information for Adv. Mater., DOI: 10.1002/adma. 201304284 Metal-Organic Frameworks Reactivate Deceased Diatoms to be
More informationStabilizing vitamin D 3 by conformationally selective co-crystallization
Supporting Information for Stabilizing vitamin D 3 by conformationally selective co-crystallization Jian-Rong Wang, Chun Zhou, Xueping Yu and Xuefeng Mei* Pharmaceutical Analytical & Solid-State Chemistry
More informationElectronic Supplementary Information (ESI)
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information (ESI) Rational Design and Synthesis of a Porous, Task-Specific
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information Micro- and mesoporous poly(schiff-base)s
More informationA Highly Efficient Double-Hierarchical Sulfur Host for Advanced Lithium-Sulfur Batteries
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2017 Supporting Information A Highly Efficient Double-Hierarchical Sulfur Host for Advanced
More informationSupporting Information
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 217 Supporting Information Experimental Section Materials. Dicyandiamide(DCDA, C 2 H 4 N 4,
More informationDouble-decker-shaped Silsesquioxane Having
Supporting Information Hydrosilylation Polymerization of Double-decker-shaped Silsesquioxane Having Hydrosilane with Diynes Makoto Seino, Teruaki Hayakawa, Yoshihito Ishida, and Masa-aki Kakimoto* Department
More informationSupracolloidal Polymer Chains of Diblock Copolymer Micelles
Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2014 Supporting Information Supracolloidal Polymer Chains of Diblock Copolymer Micelles
More informationSupporting Information for
Supporting Information for Microporous Organic Network Hollow Spheres: Useful Templates for Nanoparticulate Co 3 O 4 Hollow Oxidation Catalysts Narae Kang, Ji Hoon Park, Mingshi Jin, Nojin Park, Sang Moon
More informationElectronic Supporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Electronic Supporting Information Amine-functionalized metal-organic framework as a sensing platform
More informationSupporting Information
Electronic Supplementary Material (ESI) for Catalysis Science & Technology. This journal is The Royal Society of Chemistry 206 Supporting Information N-heterocyclic carbene based MOFs catalyst for Sonogashira
More informationSupplementary Information
Supplementary Information Hollow Microporous Organic Capsules Buyi Li, Xinjia Yang, Lingling Xia, Muhammad Irfan Majeed and Bien Tan* Both Buyi Li and Xinjia Yang contributed equally to this work School
More informationSupplementary Information. Large Scale Graphene Production by RF-cCVD Method
Supplementary Information Large Scale Graphene Production by RF-cCVD Method Enkeleda Dervishi, *a,b Zhongrui Li, b Fumiya Watanabe, b Abhijit Biswas, c Yang Xu, b Alexandru R. Biris, d Viney Saini, a,b
More informationA Conjugated Polyelectrolyte-Based New Strategy. for In Situ Detection of Carbon Dioxide
Supporting Information A Conjugated Polyelectrolyte-Based New Strategy for In Situ Detection of Carbon Dioxide Yibing Fan, Chengfen Xing, *, Hongbo Yuan, Ran Chai, Linfei Zhao, and Yong Zhan Key Laboratory
More informationSUPPORTING INFORMATION
SUPPORTING INFORMATION Polymerization-induced Self-Assembly of Homopolymer and Diblock copolymer: A Facile Approach for preparing Polymer Nano-objects with Higher Order Morphologies Jianbo Tan *a,b, Chundong
More informationA soft-templated method to synthesize sintering-resistant Au/mesoporous-silica core-shell nanocatalysts with sub-5 nm single-core
A soft-templated method to synthesize sintering-resistant Au/mesoporous-silica core-shell nanocatalysts with sub-5 nm single-core Chunzheng Wu, ab Zi-Yian Lim, a Chen Zhou, a Wei Guo Wang, a Shenghu Zhou,
More informationSupporting Information
Supporting Information A strategy toward constructing bifunctionalized MF catalyst: post-synthesized modification of MFs on organic ligands and coordinatively unsaturated metal sites Baiyan Li, Yiming
More informationSynthesis of hydrophilic monomer, 1,4-dibromo-2,5-di[4-(2,2- dimethylpropoxysulfonyl)phenyl]butoxybenzene (Scheme 1).
Supporting Information Materials. Hydroquinone, potassium carbonate, pyridine, tetrahydrofuran (THF for organic synthesis) were purchased from Wako Pure Chemical Industries Ltd and used as received. Chlorosulfuric
More informationSupporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Information A Highly stable Metal- and Nitrogen-doped Nanocomposite derived from Zn/Ni-ZIF-8
More informationA supramolecular approach for fabrication of photo- responsive block-controllable supramolecular polymers
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2014 Supporting Information A supramolecular approach for fabrication of photo- responsive
More informationBulk graphdiyne powder applied for highly efficient lithium storage
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Bulk graphdiyne powder applied for highly efficient lithium storage Shengliang Zhang, ab Huibiao
More informationMaterials and Instrumentation. Preparation of ferrofluid [1] Preparation of polymer magnetic nanoparticles. Preparation of NHC ligand [2]
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 204 Materials and Instrumentation. All the reagents and solvents were purchased from Sinopharm
More informationSupporting Information
Supporting Information Hydrogen Storage in the Dehydrated Prussian Blue Analogues M 3 [Co(CN) 6 ] 2 (M = Mn, Fe, Co, Ni, Cu, Zn) Steven S. Kaye and Jeffrey R. Long* Dept. of Chemistry, University of California,
More informationEfficient Molybdenum (VI) Modified Zr-MOF Catalyst for
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Efficient Molybdenum (VI) Modified Zr-MOF Catalyst for Epoxidation of Olefins Jia Tang, a Wenjun
More informationUltrasmall Sn nanoparticles embedded in nitrogen-doped porous carbon as high-performance anode for lithium-ion batteries
Supporting Information Ultrasmall Sn nanoparticles embedded in nitrogen-doped porous carbon as high-performance anode for lithium-ion batteries Zhiqiang Zhu, Shiwen Wang, Jing Du, Qi Jin, Tianran Zhang,
More informationSupporting Information for
Supporting Information for AmPhos Pd-Catalyzed Suzuki-Miyaura Catalyst-Transfer Condensation Polymerization: Narrower Dispersity by Mixing the Catalyst and Base Prior to Polymerization Kentaro Kosaka,
More informationCharacterization of partially reduced graphene oxide as room
Supporting Information Characterization of partially reduced graphene oxide as room temperature sensor for H 2 Le-Sheng Zhang a, Wei D. Wang b, Xian-Qing Liang c, Wang-Sheng Chu d, Wei-Guo Song a *, Wei
More informationCooperative Template-Directed Assembly of Mesoporous Metal-Organic Frameworks
Supporting Information Cooperative Template-Directed Assembly of Mesoporous Metal-Organic Frameworks Lin-Bing Sun, Jian-Rong Li, Jinhee Park, and Hong-Cai Zhou* Department of Chemistry, Texas A&M University,
More informationSupplementary Information
Supplementary Information Facile preparation of superhydrophobic coating by spraying a fluorinated acrylic random copolymer micelle solution Hui Li, a,b Yunhui Zhao a and Xiaoyan Yuan* a a School of Materials
More informationSupplementary Information
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2014 Supplementary Information A honeycomb-like porous carbon derived from pomelo peel for use in high-performance
More informationThermal Conductivity of Covalent Organic Frameworks as a Function of Their Pore Size
Thermal Conductivity of Covalent Organic Frameworks as a Function of Their Pore Size Sunny K. S. Freitas a ; Raquel S. Borges b ; Claudia Merlini c, Guilherme M. O. Barra d, Pierre M. Esteves a, * a. Instituto
More informationFacile synthesis of polymer and carbon spheres decorated with highly dispersed metal nanoparticles
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 1 Facile synthesis of polymer and carbon spheres decorated with highly dispersed metal nanoparticles
More informationSupporting Information. CdS/mesoporous ZnS core/shell particles for efficient and stable photocatalytic hydrogen evolution under visible light
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2014 Supporting Information CdS/mesoporous ZnS core/shell particles for efficient
More informationTemplate-Free Synthesis of Beta Zeolite Membranes on Porous α-al 2 O 3 Supports
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information for Template-Free Synthesis of Beta Zeolite Membranes on Porous
More informationElectronic Supplementary Information. Enhanced Photocatalytic/photoelectrocatalytic Activities
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information Electrospun BiVO 4 Nanobelts with Tailored Structures
More information1. Materials All chemicals and solvents were purchased from Sigma Aldrich or SAMCHUN and used without further purification.
1. Materials All chemicals and solvents were purchased from Sigma Aldrich or SAMCHUN and used without further purification. 2. Experimental procedures Benzo[1,2-c:3,4-c':5,6-c'']trifuran, 1: The synthesis
More informationLigand-free coupling of phenols and alcohols with aryl halides by a recyclable heterogeneous copper catalyst
Supporting Information Ligand-free coupling of phenols and alcohols with aryl halides by a recyclable heterogeneous copper catalyst Man Wang, Bizhen Yuan, Tongmei Ma, Huanfeng Jiang and Yingwei Li* School
More information