4) protons experience a net magnetic field strength that is smaller than the applied magnetic field.
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1 1) Which of the following CANNOT be probed by an spectrometer? See sect 16.1 Chapter 16: 1 A) nucleus with odd number of protons & odd number of neutrons B) nucleus with odd number of protons &even number of neutrons C) nucleus with even number of protons & odd number of neutrons D) nucleus with even number of protons & even number of neutrons E) none of these 2) How many nuclear spin states are possible for the 1 H nucleus? A) 1 B) 2 C) 4 D) 5 E) none of these 3) Which of the following electromagnetic radiation is used in spectroscopy? A) UV B) IR C) visible D) γ rays E) radio wave 4) protons experience a net magnetic field strength that is smaller than the applied magnetic field. A) Deshielded B) Shielded C) Paramagnetic D) Diamagnetic E) none of these 5) protons experience a net magnetic field strength that is higher than the protons. A) Deshielded, shielded B) Shielded, deshielded C) Paramagnetic, diamagnetic D) Shielded, diamagnetic E) none of these
2 Chapter 16: 2 6) Which of the following is true about the relationship between the energy gap (ΔE) between the spin states for a 1 H nucleus and the strength of the external magnetic field? A) they are inversely proportional B) they are directly proportional C) there is no relationship D) the magnetic field is slightly less E) none of these 7) Which of the following is true about the number of different signals in a 1 H spectrum? Section: 16.3 A) it indicates the number of neighboring protons B) it indicates the electronic environment of neighboring protons C) it indicates the number of different kinds of protons D) it indicates the electronic environment of absorbing protons E) it indicates the number of protons in the signal 8) Which of the following is true about the location of signals in a 1H spectrum? Section: 16.3 A) it indicates the number of neighboring protons B) it indicates the electronic environment of neighboring protons C) it indicates the number of different protons D) it indicates the electronic environment of absorbing protons E) it indicates the number of protons in the signal 9) Which of the following is true about the area under each signal in a 1 H spectrum? Section: 16.3 A) it indicates the number of neighboring protons B) it indicates the electronic environment of neighboring protons C) it indicates the number of different protons D) it indicates the electronic environment of absorbing protons E) it indicates the relative number of protons in the signal
3 1) Which of the following is true about the shape (multiplicity) of the signal in a 1 H spectrum? Section: 16.3 A) it indicates the number of neighboring protons B) it indicates the electronic environment of neighboring protons C) it indicates the number of different protons D) it indicates the electronic environment of absorbing protons E) it indicates the number of protons in the signal Chapter 16: 3 11) Which of the following type of protons are chemically non equivalent? Section: 16.4 A) homotopic B) enantiotopic C) diastereotopic D) A and B E) B and C 12) Which of the following type of protons are chemically equivalent? Section: 16.4 A) homotopic B) enantiotopic C) diastereotopic D) A and B E) B and C 13) Which of the following is the maximum multiplicity observed for H b protons. Assume that J ab and J bc values are different. a a b c O d A) 9 B) 12 C) 21 D) 24 E) none of these
4 Chapter 16: 4 14) Which of the following is the maximum multiplicity observed for H c protons. Assume that J cd and J cb values are DIFFERENT. H c N d a b A) 5 B) 6 C) 8 D) 12 E) none of these 15) Which of the following is the maximum multiplicity observed for H c protons. Assume that J cd and J cb values are the SAME. H c N d a b A) 5 B) 6 C) 8 D) 12 E) none of these 16) H b and H d should be placed in 2 of the three boxes below. An X should be drawn in the remaining box
5 Chapter 16: 5 17) Identify the indicated sets of protons as (U)nrelated, (H)omotopic, (E)nantiotopic or (D)iastereotopic H OH H H H H 18) How many kinds of nonequivalent carbons (C) and protons (H) are present in the following? That is, how many unique 1 H and 13 C signals will you observed in an spectrum for each.
6 continued Chapter 16: 6 19) MATCH a term to each description below. Place the letter of the term in the Box. A) TMS (tetramethylsilane) B) downfield (or low field) C) upfield (or high field) D) chemical shift E) MHz F) delta (δ) When looking at an chart the right hand part of the chart is... The exact place on the chart at which a nucleus absorbs is called its... A calibration standard that was commonly used to mark the ppm for 1 H and 13 C is... The charts are calibrated using an arbitrary X axis scale denoting parts per million that is divided into units.
7 Chapter 16: 7 2) Identify the chemically non-equivalent and equivalent hydrogens by writing the letters in the boxes, starting with the letter 'A'. In the following example, protons 'A' and 'H' are equivalent but are not equivalent to 'J', and so on. Note, not every box has to be filled. HERE IS AN EXAMPLE. X in box(es) not used A,H I J K,L X ) How many different kinds of non-equivalent CARBONS are there in the following? 22) Predict the splitting patterns in the 1 H or all of the unique protons indicated in the molecules
8 Chapter 16: 8 23) The relative proton chemical shifts of the labeled hydrogens are shown in the 1 H. The integration of the peak areas is shown in the spectrum. 1 H 3 The most shielded is A,B,C,or D? The most deshielded is A,B,C,or D? ) Fill in Table below with number of adjacent hydrogens and the splitting patterns you would expect for each proton in the molecules below. Splitting: S = singlet; D = doublet; T = triplet; Q = quartet; QU = quintet; SX = sextet; SP = septet; DD = doublet of doublet Proton Number of Adjacent Protons that Couple Splitting (use capital letters above) Proton Number of Adjacent Protons that Couple Splitting (use capital letters) A G B H C I D J E K F L M
9 Chapter 16: 9 25) Calculate the degrees of unsaturation for the formula (C 5 H 1 O) TABLES ATTACHED, if you need them. Logical labeling/work that supports your answer should appear within spectra. 13C 1H 3H, singlet 2H, triplet 2H, sextet 3H, triplet IR data 26) Structure here. Structure MUST BE PLACED Here (show work for credit)
10 Chapter 16: 1 27) Calculate the degrees of unsaturation for the formula (C 4 H 1 O) TABLES ATTACHED, if you need them. Logical labeling/work that supports your answer should appear within spectra. 13C 1H 3H, doublet 3H, triplet 1H, sextet 1H, broad singlet 2H, quintet 5 IR data ) Structure here. Structure MUST BE PLACED Here (show work for credit)
11 Chapter 16: 11 29) Calculate the degrees of unsaturation for the formula (C 4 H 9 NO) TABLES ATTACHED, if you need them. 13C 1H IR data ) Structure here. Structure MUST BE PLACED Here (show work for credit)
12 Chapter 16: 12 31) Which of the following display a signal in the DEPT-9 13 C spectroscopy? A) CH 3 B) CH 2 C) CH D) C E) none of these 32) Which of the following displays a negative signal in the DEPT C spectroscopy? A) CH 3 B) CH 2 C) CH D) C E) none of these 33) Which of the following does NOT display a signal in the DEPT C spectroscopy? A) CH 3 B) CH 2 C) CH D) C E) none of these
13 Chapter 16: 13 Many will feel lost WITHOUT a Table of chemical shift values, but you do not need a table. The following problems are designed to test deductive reasoning. 34) The following compounds show a single line in their 1 H spectra. Write the letter assigned to each spectrum next to the corresponding compound. (4 pts)
14 35) Place the number next to the indicated protons in the boxes in the 1 H spectrum? Chapter 16: 14 I II III IV OH ) Place the number next to the indicated protons in the boxes in the 1 H spectrum?
15 NOTE: protons attached to N and O generally don't couple to nearest neighboring protons Chapter 16: 15
16 37) Match the following 1 H spectra to compounds 1 5 below H O O O O O O O O O H III IV V I II H H O Chapter 16: 16 Ans Here Ans Here
17 43) Match the following 1 H spectra to compounds 1 4 below Chapter 16: 19 I II III IV singlet singlet Ans Here singlet singlet doublet triplet Ans Here
18 Chapter 16: 24 52) Calculate the degree of unsaturation for the formula (C 4 H 9 Br) 1 H C ) Structure here.
19 Chapter 16: 25 54) Calculate the degree of unsaturation for the formula (C 11 H 14 O) IR 1 H 5H, mutiplet 2H, singlet 3H, triplet 2H, sextet 2H, triplet 13C ) Structure here.
20 Chapter 16: 26 56) Calculate the degree of unsaturation for the formula (C 7 H 14 O 2 ) IR 1 H 6H, doublet 1H, septet 2H, sextet 2H, triplet 3H, triplet 13C ) Structure here.
21 Chapter 16: 27 58) Calculate the degree of unsaturation for the formula (C 9 H 12 O) IR 1 H triplet 3 doublet 2 2 doublet 1 exchanges with D 2 O triplet 2 2 sextet 13C ) Structure here.
22 Chapter 16: 28 6) Calculate the degree of unsaturation for the formula (C 5 H 7 NO 2 ) IR 1 H 2H, singlet 3H, triplet 2H, quartet 13C 61) Structure here.
23 Chapter 16: 31 66) Calculate the degree of unsaturation for the formula (C 1 H 14 ) IR A compound with molecular formula C1H14 displays the following IR, 1H, 13C spectra. Propose a structure for this compound. 1 H 3H, doublet 5H, multiplet 3H, triplet 1H, pentet 2H, pentet 13 C 67) Structure here.
24 Chapter 16: 32 68) Calculate the degree of unsaturation for the formula (C 8 H 11 N) IR 1 H 5H, multiplet 2H (exchange with D of D 2 O) 3H, doublet 1H, quartet 13 C ) Structure here.
25 Chapter 16: 33 7) Calculate the degree of unsaturation for the formula (C 8 H 14 O 3 ) IR 1 H 4H, hextet 4H, triplet 6H, triplet 13 C SDBS Hint: Think Symmetry ) Structure here.
26 Chapter 16: 34 72) Calculate the degree of unsaturation for the formula (C 7 H 14 O 2 ) IR 1 H 6H, doublet 2H, triplet 3H, triplet 1H, septet 2H, sextet 13 C 18 73) Structure here
27 Chapter 16: 35 74) Calculate the degree of unsaturation for the formula (C 6 H 15 N) IR 1 H 1H (exchange with D of D 2 O) 4H, triplet 6H, triplet 4H, sextet MS m/z 72 DRAW STRUCTURE OF m/z 72 for Extra Credit m/z C Hint: Think Symmetry 75) Structure here.
28 Chapter 16: 36
4) protons experience a net magnetic field strength that is smaller than the applied magnetic field.
1) Which of the following CANNOT be probed by an spectrometer? See sect 16.1 Chapter 16: 1 A) nucleus with odd number of protons & odd number of neutrons B) nucleus with odd number of protons &even number
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