A Compactly Fused π Conjugated Tetrathiafulvalene Perylenediimide Donor Acceptor Dyad
|
|
- Augustus Bennett
- 5 years ago
- Views:
Transcription
1 Supporting Information for: A Compactly Fused π Conjugated Tetrathiafulvalene Perylenediimide Donor Acceptor Dyad Michael Jaggi, a Carmen Blum, a Nathalie Dupont, b Jakob Grilj, b Shi-Xia Liu, *,a Jürg Hauser, a Andreas Hauser, b Silvio Decurtins a a Departement für Chemie und Biochemie, Universität Bern, Freiestrasse 3, CH-3012 Bern, Switzerland. b Département de chimie physique, Université de Genève, 30 quai Ernest-Ansermet, CH-1211 Genève 4, Switzerland. address: liu@iac.unibe.ch Table of Contents Experimental section Procedure for preparation of compound 1 S2 S3 1 H NMR Spectrum of compound 1 S4 Crystal packing of 1 Selected molecular orbitals for 1 Electronic absorption spectra of 1 upon electrochemical oxidation Decay curves in transient absorption upon pulsed irradiation at 400 nm S5 S6 S7 S7 S1
2 Experimental section Materials The compounds N-(1-octylnonyl)perylene-3,4,9,10-tetracarboxylic acid 3,4-anhydride-9,10- imide 2 7 and 5,6-diamino-2-(4,5-bis(propylthio)-1,3-dithio-2-ylidene)benzo[d]-1,3-dithiole 3 3e were prepared according to the literature procedures. All other chemicals and solvents were purchased from commercial sources and were used without further purification. Physical measurements 1 H NMR spectrum was measured at 400 MHz at 50 C. Chemical shifts δ were calibrated against TMS as an internal standard. FT-IR data were collected on a Perkin-Elmer Spectrum One spectrometer. UV-vis spectra were recorded on a Perkin-Elmer Lambda 900 spectrometer. Elemental analyses were performed on an Carlo Erba EA 1110 CHNS apparatus. Cyclic voltammetry was conducted on a VA-Stand 663 electrochemical analyzer. An Ag/AgCl electrode containing 2 M LiCl (in ethanol) served as reference electrode, a glassy carbon electrode as counter electrode, and a Pt tip as working electrode. Cyclic voltammetric measurements were performed at room temperature under N 2 in CH 2 Cl 2 ( M) with 0.1 M n-bu 4 NPF 6 as supporting electrolyte. Mass spectrum was recorded on a FTMS 4.7T BioAPEX II for MALDI ionisation method. S2
3 Preparation of 1 A mixture of N-(1-octylnonyl)perylene-3,4,9,10-tetracarboxylic acid 3,4-anhydride-9,10- imide 2 (280 mg, 445 µmol), 5,6-diamino-2-(4,5-bis(propylthio)-1,3-dithio-2- ylidene)benzo[d]-1,3-dithiole 3 (117 mg, 270 µmol) and imidazole (700 mg, 10.3mmol) in pyridine (30 ml) was refluxed for 21 h at 135 C under N 2. After evaporation of pyridine, the purple residue was subjected to column chromatography on silica gel (CHCl 3 then 9:1 CHCl 3 :MeOH) to yield the crude product. This material was rechromatographed eluting initially with 8:2 CHCl 3 :CH 2 Cl 2, then with pure CHCl 3 and finally with 9:1 CHCl 3 :MeOH to afford analytically pure compound 1 as a deep-purple solid. Yield 54% (150 mg, 146 µmol). T > 223 C (dec.). Anal. Calc. for C 57 H 59 N 3 O 3 S 6 : C, 66.69; H, 5.79; N, 4.1. Found: C, 66.71; H, 5.97; N, 3.9%. 1 H NMR (CDCl 3, 50 C) δ 8.76 (d, J = 8.24 Hz, 2H), 8.58 (m, 6H), 8.22 (s, 1H), 7.50 (s, 1H), 5.11 (br, 1H), 2.70 (t, 4H), 2.17 (br, 2H), 1.83 (br, 2H), 1.59 (m, 4H), 1.19 (m, 24H), 0.95 (dt, 6H), 0.77 (t, 6H). Selected IR data (cm -1, KBr pellet): 3436 (br), 2922 (s), 2851 (m), 1693 (s), 1655 (s), 1591 (s), 1501 (w), 1437 (m), 1353 (m), 1340 (s), 1238 (m), 805 (m), 738 (m). MS (MALDI-TOF, DCTB as matrix, positive) calcd. for C 57 H 59 N 3 O 3 S , found Single crystals suitable for X-ray analysis were obtained by slow evaporation of a CH 2 Cl 2 solution (~150 µg/ml) of 1. S3
4 S4 1 H NMR Spectrum of 1 in CDCl (ppm) (ppm)
5 Figure S1. Crystal packing of 1 showing the hydrogen bondings (dashed lines) within the dimers. S5
6 The DFT method was employed with the B3LYP functional and the TZVP (valence triplezeta plus polarization) basis set. The calculations were done with the TURBOMOLE V5.10 program package. The ground-state molecular geometry of 1 was constrained to have C s symmetry. Figure S2. Selected molecular orbitals for 1. Ref Ref: (a) Treutler, O.; Ahlrichs, R. J. Chem. Phys. 1995, 102, 346. (b) Bauernschmitt, R.; Ahlrichs, R. Chem. Phys. Lett. 1996, 256, 454. (c) Bauernschmitt, R.; Häser, M.; Treutler, O.; Ahlrichs, R. Chem. Phys. Lett. 1997, 264, 573. S6
7 Figure S3. Electronic absorption spectra of 1 upon electrochemical (V = 0.8 V vs. Ag/AgCl) oxidation. Figure S4. Decay curves in transient absorption upon pulsed irradiation at 400 nm, detected at different wavelengths. The decay is non-exponential with a first time constant of 1 ps and a second time constant of 10 ps. S7
Supporting Information
S1 Supporting Information Synthesis, Characterization, and Photophysical properties of a melamine-mediated hydrogenbonded phthalocyanine-perylenediimide assembly Ángel J. Jiménez,, Rafael Krick Calderón,
More informationElectronic Supplementary Information
Electronic Supplementary Information A new class of organic donor-acceptor molecules with large third-order optical nonlinearities Tsuyoshi Michinobu, a Joshua C. May, b Jin H. Lim, b Corinne Boudon, c
More informationA versatile electronic hole in one-electron oxidized Ni II bissalicylidene
Electronic Supplementary Information for manuscript: A versatile electronic hole in one-electron oxidized Ni II bissalicylidene phenylenediamine complexes Olaf Rotthaus, Olivier Jarjayes,* Carlos Perez
More informationThe all-photochemical Synthesis an. OGP (10-14) Precursor
SUPPORTING INFORMATION The all-photochemical Synthesis an OGP (10-14) Precursor Jean-Luc Débieux, Christian G. Bochet* Department of Chemistry, University of Fribourg, 9 Chemin du Musée, CH-1700 Fribourg,
More informationPrabhat Gautam, Bhausaheb Dhokale, Shaikh M. Mobin and Rajneesh Misra*
Supporting Information Ferrocenyl BODIPYs: Synthesis, Structure and Properties Prabhat Gautam, Bhausaheb Dhokale, Shaikh M. Mobin and Rajneesh Misra* Department of Chemistry, Indian Institute of Technology
More informationSupplementary Information
Supplementary Information C aryl -C alkyl bond formation from Cu(ClO 4 ) 2 -mediated oxidative cross coupling reaction between arenes and alkyllithium reagents through structurally well-defined Ar-Cu(III)
More informationRed Color CPL Emission of Chiral 1,2-DACH-based Polymers via. Chiral Transfer of the Conjugated Chain Backbone Structure
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2015 Red Color CPL Emission of Chiral 1,2-DACH-based Polymers via Chiral Transfer of the Conjugated
More informationHai-Bin Yang, Xing Fan, Yin Wei,* Min Shi*
Electronic Supplementary Material (ESI) for Organic Chemistry Frontiers. This journal is the Partner Organisations 2015 Solvent-controlled Nucleophilic Trifloromethylthiolation of Morita- Baylis-Hillman
More information[Ag-Ag] 2+ Unit-Encapsulated Trimetallic Cages: One-pot Syntheses and Modulation of Argentophilic Interactions by the Uncoordinated Substituents
[Ag-Ag] 2+ Unit-Encapsulated Trimetallic Cages: One-pot Syntheses and Modulation of Argentophilic Interactions by the Uncoordinated Substituents Guo-Xia Jin,,a Gui-Ying Zhu,,a Yan-Yan Sun, c Qing-Xiu Shi,
More informationSupporting Information. Copyright Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2008
upporting Information Copyright Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, 2008 1 Mono- and Bis-Tetrathiafulvalene-1,3,5-Triazines as Covalently Linked Donor-Acceptor ystems: tructural, pectroscopic
More informationSupporting Information for. an Equatorial Diadduct: Evidence for an Electrophilic Carbanion
Supporting Information for Controlled Synthesis of C 70 Equatorial Multiadducts with Mixed Addends from an Equatorial Diadduct: Evidence for an Electrophilic Carbanion Shu-Hui Li, Zong-Jun Li,* Wei-Wei
More informationNTCDA-TTF First Axial Fusion: Emergent Panchromatic, NIR Optical, Multi-state Redox and High Optical Contrast Photooxidation
NTCDA-TTF First Axial Fusion: Emergent Panchromatic, NIR Optical, Multi-state Redox and High Optical Contrast Photooxidation Deepak Asthana, a M. R. Ajayakumar, a Rajendra Prasad Pant b and Pritam Mukhopadhyay*
More informationHigh-performance Single-crystal Field Effect Transistors of Pyreno[4,5-a]coronene
Electronic Supplementary Information High-performance Single-crystal Field Effect Transistors of Pyreno[4,5-a]coronene Experimental details Synthesis of pyreno[4,5-a]coronene: In 1960 E. Clar et.al 1 and
More informationElectronic Supplementary Information (ESI)
Electronic Supplementary Information (ESI) A thin-layered chromatography plate prepared from naphthalimide-based receptor immobilized SiO 2 nanoparticles as a portable chemosensor and adsorbent for Pb
More informationCo(I)-Mediated Removal of Addends on the C60 Cage and Formation of Monovalent Cobalt Complex CpCo(CO)(η 2 -C60)
Supporting Information Co(I)-Mediated Removal of Addends on the C60 Cage and Formation of Monovalent Cobalt Complex CpCo(CO)(η 2 -C60) Yoshifumi Hashikawa, Michihisa Murata, Atsushi Wakamiya, and Yasujiro
More informationAn isolated seven-coordinate Ru(IV) dimer complex with [HOHOH] bridging. ligand as an intermediate for catalytic water oxidation
Supporting Information An isolated seven-coordinate Ru(IV) dimer complex with [HOHOH] bridging ligand as an intermediate for catalytic water oxidation Lele Duan, Andreas Fisher, Yunhua Xu, and Licheng
More informationSupporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting Information Rh 2 (Ac) 4 -Catalyzed 2,3-Migration of -rrocenecarboxyl -Diazocarbonyl
More informationNew tris- and pentakis-fused donors containing extended. tetrathiafulvalenes: New positive electrode materials for
Supporting Information for New tris- and pentakis-fused donors containing extended tetrathiafulvalenes: New positive electrode materials for rechargeable batteries Shintaro Iwamoto 1,2, Yuu Inatomi 1,3,
More informationPhotostability of a dyad of magnesium porphyrin and fullerene and its application to photocurrent conversion
Supplementary Information Photostability of a dyad of magnesium porphyrin and fullerene and its application to photocurrent conversion Takahiko Ichiki, Yutaka Matsuo,* and Eiichi akamura* Department of
More informationStereoselective Synthesis of (-) Acanthoic Acid
1 Stereoselective Synthesis of (-) Acanthoic Acid Taotao Ling, Bryan A. Kramer, Michael A. Palladino, and Emmanuel A. Theodorakis* Department of Chemistry and Biochemistry, University of California, San
More informationDomino reactions of 2-methyl chromones containing an electron withdrawing group with chromone-fused dienes
Domino reactions of 2-methyl chromones containing an electron withdrawing group with chromone-fused dienes Jian Gong, Fuchun Xie, Wenming Ren, Hong Chen and Youhong Hu* State Key Laboratory of Drug Research,
More informationSupporting Information
Supporting Information (Tetrahedron. Lett.) Cavitands with Inwardly and Outwardly Directed Functional Groups Mao Kanaura a, Kouhei Ito a, Michael P. Schramm b, Dariush Ajami c, and Tetsuo Iwasawa a * a
More informationYujuan Zhou, Kecheng Jie and Feihe Huang*
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2017 A redox-responsive selenium-containing pillar[5]arene-based macrocyclic amphiphile: synthesis,
More informationSYNTHESIS AND ANTIBACTERIAL EVALUATION OF NOVEL 3,6- DISUBSTITUTED COUMARIN DERIVATIVES
SYNTHESIS AND ANTIBACTERIAL EVALUATION OF NOVEL 3,6- DISUBSTITUTED COUMARIN DERIVATIVES 1 Ravibabu Velpula, 1 Ramesh Gondru, 2 Yashodhara Velivela and 1 Rajitha Bavantula* 1 Department of Chemistry, National
More informationAggregation-induced emission enhancement based on 11,11,12,12,-tetracyano-9,10-anthraquinodimethane
Electronic Supplementary Information (ESI) Aggregation-induced emission enhancement based on 11,11,12,12,-tetracyano-9,10-anthraquinodimethane Jie Liu, ab Qing Meng, a Xiaotao Zhang, a Xiuqiang Lu, a Ping
More informationInfluence of anellation in N-heterocyclic carbenes: Detection of novel quinoxalineanellated NHC by trapping as transition metal complexes
Influence of anellation in N-heterocyclic carbenes: Detection of novel quinoxalineanellated NHC by trapping as transition metal complexes Shanmuganathan Saravanakumar, a Markus K. Kindermann, a Joachim
More informationWell-organized Supramolecular Self-Assembly of a Novel Acene Diimide Derivatives
Well-organized Supramolecular Self-Assembly of a Novel Acene Diimide Derivatives Sheshanath V. Bhosale, a, * Mohammad Al Kobaisi, a Rajesh S. Bhosale b and Sidhanath V. Bhosale b a Supramolecular Chemistry
More informationSupporting Information. for. Angew. Chem. Int. Ed. Z Wiley-VCH 2003
Supporting Information for Angew. Chem. Int. Ed. Z53001 Wiley-VCH 2003 69451 Weinheim, Germany 1 Ordered Self-Assembly and Electronic Behavior of C 60 -Anthrylphenylacetylene Hybrid ** Seok Ho Kang 1,
More informationFacile Multistep Synthesis of Isotruxene and Isotruxenone
Facile Multistep Synthesis of Isotruxene and Isotruxenone Jye-Shane Yang*, Hsin-Hau Huang, and Shih-Hsun Lin Department of Chemistry, National Taiwan University, Taipei, Taiwan 10617 jsyang@ntu.edu.tw
More informationMultistep Electron Transfer Systems Based. on Silicon Phthalocyanine, [60]Fullerene and. Trinitrofluorenone
Supporting Information Multistep Electron Transfer Systems Based on Silicon Phthalocyanine, [60]Fullerene and Trinitrofluorenone Luis Martín-Gomis, a Kei hkubo, b Fernando Fernández-Lázaro, a Shunichi
More informationNear Infrared Electrochromism in Electropolymerized Films of Biscyclometallated Ruthenium Complex Bridged by 1,2,4,5-Tetra(2-pyridyl)benzene
Supporting Information for: ear Infrared Electrochromism in Electropolymerized Films of Biscyclometallated Ruthenium Complex Bridged by 1,2,4,5-Tetra(2-pyridyl)benzene Chang-Jiang Yao, Yu-Wu Zhong,, *
More informationAntiparallel double-stranded BODIPY porphyrin dyad assembled by a self-complementary B F Zn interaction
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2017 Supporting Information for Antiparallel double-stranded BODIPY porphyrin dyad assembled by a self-complementary
More informationCatalyst-Free Reaction of Ethynyl-π-Extended Electron Acceptors with Amines
Catalyst-Free Reaction of Ethynyl-π-Extended Electron Acceptors with Amines Atsuro Takai* and Masayuki Takeuchi* 2018 The Chemical Society of Japan Table of Contents S1. Synthesis and Characterization
More informationSupporting Information for. Immobilizing Tetraphenylethylene into Fused Metallacycles: Shape Effects on Fluorescence Emission
Supporting Information for Immobilizing Tetraphenylethylene into Fused Metallacycles: Shape Effects on Fluorescence Emission Zhixuan Zhou, Xuzhou Yan,,,, Manik Lal Saha,,, Mingming Zhang, Ming Wang,, Xiaopeng
More informationOne polymer for all: Benzotriazole Containing Donor-Acceptor Type Polymer as a Multi-Purpose Material
One polymer for all: Benzotriazole Containing Donor-Acceptor Type Polymer as a Multi-Purpose Material Abidin Balan a, Derya Baran a, Gorkem Gunbas a,b, Asuman Durmus a,b, Funda Ozyurt a and Levent Toppare
More informationSynthesis of Glaucogenin D, a Structurally Unique. Disecopregnane Steroid with Potential Antiviral Activity
Supporting Information for Synthesis of Glaucogenin D, a Structurally Unique Disecopregnane Steroid with Potential Antiviral Activity Jinghan Gui,* Hailong Tian, and Weisheng Tian* Key Laboratory of Synthetic
More informationSupplementary Material. Synthesis of novel C-2 substituted imidazoline derivatives having the norbornene/dibenzobarrelene skeletons
Supplementary Material Synthesis of novel C-2 substituted imidazoline derivatives having the norbornene/dibenzobarrelene skeletons İrfan Çapan a and Süleyman Servi b a Gazi University, Technical Sciences
More informationEfficient Syntheses of the Keto-carotenoids Canthaxanthin, Astaxanthin, and Astacene
Efficient Syntheses of the Keto-carotenoids Canthaxanthin, Astaxanthin, and Astacene Seyoung Choi and Sangho Koo* Department of Chemistry, Myong Ji University, Yongin, Kyunggi-Do, 449-728, Korea. E-mail:
More informationElectronic Supporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Electronic Supporting Information A fast and selective probe for detection of CN - and F -
More informationSUPPORTING INFORMATION
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 2017 1 SUPPORTING INFORMATION Synthesis of urea derivatives via reductive carbon dioxide fixation
More informationSUPPORTING INFORMATION
Synthesis and Biological Evaluation of Direct Thrombin Inhibitors Bearing 4-(Piperidin-1- yl)pyridine at the P1 Position with Potent Anticoagulant Activity Modesto de Candia, Filomena Fiorella,,# Gianfranco
More informationSupplementary Materials
Supplementary Materials ORTHOGOALLY POSITIOED DIAMIO PYRROLE- AD IMIDAZOLE- COTAIIG POLYAMIDES: SYTHESIS OF 1-(3-SUBSTITUTED-PROPYL)-4- ITROPYRROLE-2-CARBOXYLIC ACID AD 1-(3-CHLOROPROPYL)-4- ITROIMIDAZOLE-2-CARBOXYLIC
More informationSupporting Information
Supporting Information Electrochemical generation of silver scetylides from terminal alkynes with a Ag anode and integration into sequential Pd-catalysed coupling with arylboronic acids Koichi Mitsudo,*
More informationSupplementary Figure S1 X-ray crystallographic structure of (C)-(-)-6. (a) ORTEP drawing of (C)-(-)-6 at probability ellipsoids of 50%: tope view.
Supplementary Figure S1 X-ray crystallographic structure of (C)-(-)-6. (a) ORTEP drawing of (C)-(-)-6 at probability ellipsoids of 50%: tope view. (b) Side view. All hydrogen atoms are omitted for clarity.
More informationSupporting Information
Supporting Information Selective Synthesis of [6]-, [8]-, and [10]Cycloparaphenylenes Eiichi Kayahara, 1,2 Takahiro Iwamoto, 1 Toshiyasu Suzuki, 2,3 and Shigeru Yamago* 1,2 1 Institute for Chemical Research,
More informationSyntheses and Structures of Mono-, Di- and Tetranuclear Rhodium or Iridium Complexes of Thiacalix[4]arene Derivatives
Supplementary Information Syntheses and Structures of Mono-, Di- and Tetranuclear Rhodium or Iridium Complexes of Thiacalix[4]arene Derivatives Kenji Hirata, Toshiaki Suzuki, Ai Noya, Izuru Takei and Masanobu
More informationA Sumanene-based Aryne, Sumanyne
A Sumanene-based Aryne, Sumanyne Niti Ngamsomprasert, Yumi Yakiyama, and Hidehiro Sakurai* Division of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871
More informationAn unexpected highly selective mononuclear zinc complex for adenosine diphosphate (ADP)
This journal is The Royal Society of Chemistry 213 Supplementary Information for An unexpected highly selective mononuclear zinc complex for adenosine diphosphate (ADP) Lei Shi, Ping Hu, Yanliang Ren and
More informationSupporting Information for
Supporting Information for Friedel Crafts-type reaction of pyrene with diethyl 1- (isothiocyanato)alkylphosphonates. Efficient synthesis of highly fluorescent diethyl 1-(pyrene-1- carboxamido)alkylphosphonates
More informationSupplementary Information
Supplementary Information Luminescence on-off switching via reversible interconversion between inter- and intramolecular aurophilic interactions Semi Han, a Yu Young Yoon, a Ok-Sang Jung b and Young-A
More informationSupporting Information
Supporting Information Synthesis of H-Indazoles from Imidates and Nitrosobenzenes via Synergistic Rhodium/Copper Catalysis Qiang Wang and Xingwei Li* Dalian Institute of Chemical Physics, Chinese Academy
More informationFacile Synthesis of Flavonoid 7-O-Glycosides
Facile Synthesis of Flavonoid 7-O-Glycosides Ming Li, a Xiuwen Han, a Biao Yu b * a State Key Laboratory of Catalyst, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
More informationSupporting Information
Supporting Information Photoinduced Processes of Subphthalocyanine Diazobenzene Fullerene Triad as an Efficient Excited Energy Transfer System Jong-Hyung Kim, 1 Mohamed E. El-Khouly,* 2,3 Yasuyuki Araki,
More informationFormal Total Synthesis of Optically Active Ingenol via Ring-Closing Olefin Metathesis
Formal Total Synthesis of Optically Active Ingenol via Ring-Closing Olefin Metathesis Kazushi Watanabe, Yuto Suzuki, Kenta Aoki, Akira Sakakura, Kiyotake Suenaga, and Hideo Kigoshi* Department of Chemistry,
More informationSynthesis of fluorophosphonylated acyclic nucleotide analogues via Copper (I)- catalyzed Huisgen 1-3 dipolar cycloaddition
Synthesis of fluorophosphonylated acyclic nucleotide analogues via Copper (I)- catalyzed Huisgen 1-3 dipolar cycloaddition Sonia Amel Diab, Antje Hienzch, Cyril Lebargy, Stéphante Guillarme, Emmanuel fund
More informationLight-Controlled Switching of a Non- Photoresponsive Molecular Shuttle
Supporting Information Light-Controlled Switching of a Non- Photoresponsive Molecular Shuttle Liu-Pan Yang, a,b Fei Jia, a Jie-Shun Cui, a Song-Bo Lu, a and Wei Jiang* a a Department of Chemistry, South
More informationSynthesis of two novel indolo[3,2-b]carbazole derivatives with aggregation-enhanced emission property
Supporting Information for: Synthesis of two novel indolo[3,2-b]carbazole derivatives with aggregation-enhanced emission property Wen-Bin Jia, Hao-Wei Wang, Long-Mei Yang, Hong-Bo Lu, Lin Kong, Yu-Peng
More informationElectronic Supplementary Information (12 pages)
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 A C 2 -responsive pillar[5]arene: synthesis and self-assembly in water Kecheng Jie, Yong Yao, Xiaodong
More informationSupporting Information
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 217 Electronic Supplementary Material
More informationSupporting Information. Enantioselective Organocatalyzed Henry Reaction with Fluoromethyl Ketones
Supporting Information Enantioselective Organocatalyzed Henry Reaction with Fluoromethyl Ketones Marco Bandini,* Riccardo Sinisi, Achille Umani-Ronchi* Dipartimento di Chimica Organica G. Ciamician, Università
More informationSupporting Information. Rhodium, iridium and nickel complexes with a. 1,3,5-triphenylbenzene tris-mic ligand. Study of
Supporting Information for Rhodium, iridium and nickel complexes with a 1,3,5-triphenylbenzene tris-mic ligand. Study of the electronic properties and catalytic activities Carmen Mejuto 1, Beatriz Royo
More informationSUPPORTING INFORMATION
SUPPORTING INFORMATION Synthesis of Functionalized Thia Analogues of Phlorins and Covalently Linked Phlorin-Porphyrin Dyads Iti Gupta a, Roland Fröhlich b and Mangalampalli Ravikanth *a a Department of
More informationSUPPORTING INFORMATION
Current Density (ma/cm 2 ) Current Density (ma/cm 2 ) SUPPORTING INFORMATION New Electron Acceptor Derived from Fluorene: Synthesis and its Photovoltaic Properties P. Nagarjuna, Anirban Bagui, Jianhui
More informationSupporting Information
S1 Microwave-Assisted Synthesis of Isonitriles: A General Simple Methodology Andrea Porcheddu,* Giampaolo Giacomelli, and Margherita Salaris Dipartimento di Chimica, Università degli Studi di Sassari,
More informationElectronic Supplementary Material
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Material A Novel Functionalized Pillar[5]arene: Synthesis, Assembly
More informationSupporting Information
Supporting Information Carbon Nanodots: Supramolecular Electron Donor Acceptor Hybrids Featuring Perylenediimides** Volker Strauss, Johannes T. Margraf, Konstantin Dirian, Zois Syrgiannis, Maurizio Prato,
More informationA fluorescent ph probe for acidic organelle in living cells
Electronic Supplementary Material (ESI) for rganic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2017 Supporting Information for A fluorescent ph probe for acidic organelle in
More informationIntensely luminescent gold(i) phosphinopyridyl clusters: visualization of unsupported aurophilic interactions in solution
Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2017 Supplementary Information Intensely luminescent gold(i) phosphinopyridyl clusters:
More informationEnantioselectivity switch in copper-catalyzed conjugate addition. reaction under influence of a chiral N-heterocyclic carbene-silver complex
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 Supplementary Information Enantioselectivity switch in copper-catalyzed conjugate addition
More informationSupporting Information
Supporting Information An Extremely Active and General Catalyst for Suzuki Coupling Reactions of Unreactive Aryl Chlorides Dong-Hwan Lee and Myung-Jong Jin* School of Chemical Science and Engineering,
More informationSupporting Information
Supporting Information Tetrathiafulvalene Diindolylquinoxaline: A Dual Signaling Anion Receptor with Phosphate Selectivity Christopher Bejger, Jung Su Park, Eric S. Silver, and Jonathan L. Sessler* 1.
More informationSupporting Information
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2014 Supporting Information 3D Cross-Correlative Matrix Temperature Detection and Non-Invasive
More informationA colorimetric and fluorescent turn-on sensor for pyrophosphate. anion based on dicyanomethylene-4h-chromene framework
Electronic Supplementary Information (ESI) A colorimetric and fluorescent turn-on sensor for pyrophosphate anion based on dicyanomethylene-4h-chromene framework Xiaomei Huang, Zhiqian Guo, Weihong Zhu*,
More informationRare double spin canting antiferromagnetic behaviours in a. [Co 24 ] cluster
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2016 Rare double spin canting antiferromagnetic behaviours in a [Co 24 ] cluster Guang-Ming Liang, Qing-Ling
More informationSupporting Information. DBU-Mediated Metal-Free Oxidative Cyanation of α-amino. Carbonyl Compounds: Using Molecular Oxygen as the Oxidant
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2015 Supporting Information DBU-Mediated Metal-Free Oxidative Cyanation of α-amino
More informationDual role of Allylsamarium Bromide as Grignard Reagent and a. Single Electron Transfer Reagent in the One-Pot Synthesis of.
Dual role of Allylsamarium Bromide as Grignard Reagent and a Single Electron Transfer Reagent in the One-Pot Synthesis of Terminal Olefins Ying Li, Yuanyuan Hu and Songlin Zhang* Key Laboratory of Organic
More informationSupporting Information
Supporting Information Enantioselective Synthesis of 3-Alkynyl-3-Hydroxyindolin-2-ones by Copper-Catalyzed Asymmetric Addition of Terminal Alkynes to Isatins Ning Xu, Da-Wei Gu, Jing Zi, Xin-Yan Wu, and
More informationSupporting Information. for. Angew. Chem. Int. Ed. Z Wiley-VCH 2003
Supporting Information for Angew. Chem. Int. Ed. Z50567 Wiley-VCH 2003 69451 Weinheim, Germany Metallacarborane-Based Nanostructures: A Carbon-Wired Planar Octagon** Haijun Yao, Michal Sabat, and Russell
More informationSupporting Information. Corporation, 1-1 Kurosakishiroishi, Yahatanishi-ku, Kitakyushu , Japan
Supporting Information Facile Fullerene Modification: FeCl 3 -mediated Quantitative Conversion of C 60 to Polyarylated Fullerenes Containing Pentaaryl(chloro)[60]fullerenes Masahiko Hashiguchi,*,1 Kazuhiro
More informationSupplementary Figure 1. Mass spectrum (top) and 1 H NMR spectrum (bottom, in CDCl 3 ) of [ppy 2 IrNH] + PF 6 -.
Supplementary Figure 1. Mass spectrum (top) and 1 H NMR spectrum (bottom, in CDCl 3 ) of [ppy 2 IrNH] + PF 6 -. 1 Supplementary Figure 2. Mass spectrum (top) and 1 H NMR spectrum (bottom, in CDCl 3 ) of
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics. This journal is the Owner Societies 2017 Electronic Supplementary Information Effect of Fluorine Position and Content on
More informationSupporting Information
Supporting Information Towards Singlet Oxygen Delivery at a Measured Rate: A Selfreporting Photosensitizer Sundus Erbas-Cakmak #, Engin U. Akkaya # * # UNAM-National Nanotechnology Research Center, Bilkent
More informationSupporting Information
Supporting Information Wiley-VCH 2007 69451 Weinheim, Germany Crystal-to-Crystal Transformation between Three Cu(I) Coordination Polymers and Structural Evidence for Luminescence Thermochromism Tae Ho
More informationElectronic Supplementary Material (ESI) for Chemical Communications This journal is The Royal Society of Chemistry 2012
Ring Expansion of Alkynyl Cyclopropanes to Highly substituted Cyclobutenes via a N-Sulfonyl-1,2,3-Triazole Intermediate Renhe Liu, Min Zhang, Gabrielle Winston-Mcerson, and Weiping Tang* School of armacy,
More informationStraightforward Synthesis of Enantiopure (R)- and (S)-trifluoroalaninol
S1 Supplementary Material (ESI) for Organic & Biomolecular Chemistry This journal is (c) The Royal Society of Chemistry 2010 Straightforward Synthesis of Enantiopure (R)- and (S)-trifluoroalaninol Julien
More informationSupporting Information. Table of Contents. 1. General Notes Experimental Details 3-12
Supporting Information Table of Contents page 1. General Notes 2 2. Experimental Details 3-12 3. NMR Support for Timing of Claisen/Diels-Alder/Claisen 13 4. 1 H and 13 C NMR 14-37 General Notes All reagents
More informationElaborately Tuning Intramolecular Electron Transfer Through Varying Oligoacene Linkers in the Bis(diarylamino) Systems
Electronic Supplementary Information (ESI) Elaborately Tuning Intramolecular Electron Transfer Through Varying Oligoacene Linkers in the Bis(diarylamino) Systems Jing Zhang 1,+, Zhao Chen 2,+, Lan Yang
More informationA TTFV pyrene-based copolymer: synthesis, redox properties, and aggregation behaviour
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 A TTFV pyrene-based copolymer: synthesis, redox properties, and aggregation behaviour Eyad
More informationUnexpected Fluorescence Quenching in a Perylenetetracarboxylate Diimide. Trimer
Supporting information for: Unexpected Fluorescence Quenching in a Perylenetetracarboxylate Diimide Trimer Yanfeng Wang, Hailong Chen, Haixia Wu, Xiyou Li,* Yuxiang Weng,* Department of Chemistry, Shandong
More informationSupporting Information
Supporting Information Wiley-VCH 2008 69451 Weinheim, Germany Iridium-Catalyzed Dehydrocoupling of Primary Amine-Borane Adducts: A Route to High Molecular Weight Polyaminoboranes, Boron-Nitrogen Analogues
More informationSupporting Information Reagents. Physical methods. Synthesis of ligands and nickel complexes.
Supporting Information for Catalytic Water Oxidation by A Bio-inspired Nickel Complex with Redox Active Ligand Dong Wang* and Charlie O. Bruner Department of Chemistry and Biochemistry and Center for Biomolecular
More informationSilver-catalyzed decarboxylative acylfluorination of styrenes in aqueous media
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Information Silver-catalyzed decarboxylative acylfluorination of styrenes in aqueous
More informationSupporting Information
Supporting Information New Hexaphosphane Ligands 1,3,5-C 6 H 3 {p-c 6 H 4 N(PX 2 ) 2 } 3 [X = Cl, F, C 6 H 3 OMe(C 3 H 5 )]: Synthesis, Derivatization and, Palladium(II) and Platinum(II) Complexes Sowmya
More informationYields refer to analytically pure samples. Isomer ratios were determined by suitable
Supporting Information Sustainable Radical Reduction through Catalytic Hydrogen Atom Transfer Andreas Gansäuer,* Chun-An Fan, Frederik Piestert Kekulé-Institut für Organische Chemie und Biochemie der Universität
More informationO-Allylation of phenols with allylic acetates in aqueous medium using a magnetically separable catalytic system
Supporting information for -Allylation of phenols with allylic acetates in aqueous medium using a magnetically separable catalytic system Amit Saha, John Leazer* and Rajender S. Varma* Sustainable Technology
More informationHalogen halogen interactions in diiodo-xylenes
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information (ESI) for CrystEngComm. This journal is The Royal Society
More informationStructural Elucidation of Sumanene and Generation of its Benzylic Anions
Structural Elucidation of Sumanene and Generation of its Benzylic Anions idehiro Sakurai, Taro Daiko, iroyuki Sakane, Toru Amaya, and Toshikazu irao Department of Applied Chemistry, Graduate School of
More informationSupporting Information for
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2017 Supporting Information for
More informationSupporting Information for
Page of 0 0 0 0 Submitted to The Journal of Organic Chemistry S Supporting Information for Syntheses and Spectral Properties of Functionalized, Water-soluble BODIPY Derivatives Lingling Li, Junyan Han,
More informationSupporting Information
Supporting Information Organocatalytic Enantioselective Formal Synthesis of Bromopyrrole Alkaloids via Aza-Michael Addition Su-Jeong Lee, Seok-Ho Youn and Chang-Woo Cho* Department of Chemistry, Kyungpook
More information