Multifunctional alginate-sulfonate-silica sphere-shaped adsorbent particles for the recovery of indium(iii) from secondary resources
|
|
- Bartholomew Arnold
- 5 years ago
- Views:
Transcription
1 Multifunctional alginate-sulfonate-silica sphere-shaped adsorbent particles for the recovery of indium(iii) from secondary resources Joris Roosen, ab Steven Mullens b and Koen Binnemans a a KU Leuven, Department of Chemistry, Celestijnenlaan 200F, P.O. Box 2404, B-3001 Heverlee, Belgium. b VITO, Sustainable Materials Management, Boeretang 200, B-2400 Mol, Belgium. SUPPORTING INFORMATION S1
2 Table S1: Reported wavelengths and view mode (AX/RAD) for ICP measurements Cd Zn Co Ni Fe Al In Ga Ge λ (nm) view mode RAD RAD RAD RAD RAD RAD AX AX AX Rheological data of sodium alginate solutions with different alginate concentrations were fitted with the Ostwald de Waele (power-law) model, which is based on equation (S1): 1 µ = K γ n 1 (S1) with, µ [Pa s] is the apparent viscosity, γ [s -1 ] is the shear rate, K [Pa s n ] and n [dimensionless] are the flow consistency index and the flow behavior index, respectively. The empirical parameters derived from fitting the Ostwald de Waele model to the experimental data give information on the flow behavior and the consistency of the solution (Table S2). The sodium alginate solutions showed shear-thinning behavior: the higher the shear rate, the lower the apparent viscosity. Additionally, a higher sodium alginate concentration resulted in an upward shift of the viscosity curve, as expected. Solutions with different viscosities may be used to obtain droplets with different diameters, due to a changing surface tension. S2
3 Viscosity (mpa.s) % (wt/vol) 1.5% (wt/vol) 1.0% (wt/vol) Shear rate (s -1 ) Figure S1: Ostwald de Waele viscosity fits at 25 C for solutions of sodium alginate (1.0% (wt/vol), 1.5% (wt/vol) and 2.0% (wt/vol)), after 24 h of settling. Table S2: Ostwald de Waele model parameters at room temperature for solutions of sodium alginate (1.0% (wt/vol), 1.5% (wt/vol) and 2.0% (wt/vol) after 24h of settling Sodium alginate concentration %(wt/vol) K n Viscosity at γ = 1000 s -1 (mpa s) The Feret ratio (S2) quantifies the degree of circularity: 2 Feret ratio = d D (S2) Here, d is the minimum Feret diameter and D the maximum Feret diameter. A Feret diameter is defined as the distance between two parallel tangential lines of a spheroid. 2 A S3
4 Feret ratio of 1 indicates a perfectly spherical particle. A measure for the width of the particle size distribution is the d 90 /d 10 value, defined by the ratio between the 90% largest and 10% smallest spheres. The closer this ratio approaches a value of 1, the higher the monodispersity. Upon drying of the wet (gel) beads, shrinkage was observed. The shrinkage factor (S3) can be defined as: Shrinkage factor = d av,wet d av,dried d av,wet 100% (S3) Here d av,wet is the average diameter of the wet (gel) spheres and d av,dried the average diameter of the spheres that were (irreversibly) dried by supercritical CO 2. Diameters were calculated as equivalent projected circle values. The equivalent projected circle is the diameter of a circle that has the same projected area as the actual particle. 2. A Feret ratio higher than 0.90 quantitatively confirmed the high circularity of the three batches of ASS spheres. So did the d 90 /d 10 value, which was very close to 1 for each batch, meaning that the spheres were nearly monodisperse. Uniform, spherical particles have the advantage that they allow very close packing of the solid phase in a chromatography column, thus maximizing (ion) exchange with the (aqueous) mobile phase and avoiding preferential percolation pathways. Table S1: Compressive strength of alginate-silica-sulfonate (ASS) particles Maximal compressive force (N) gel spheres dried spheres ASS 2.2 mm 0.05 ( 0.01) > 100 ASS 2.8 mm 0.08 ( 0.01) > 100 ASS 3.5 mm 0.20 ( 0.02) 24 (± 4) S4
5 Table S4: Pseudo-second-order kinetic model parameters for ASS spheres with different particle sizes Particle diameter k (mm) q e (mmol g -1 ) R² Table S5: Comparison of different adsorbent materials regarding adsorption amount from dilute metal solutions of In(III) as the element studied here and Nd(III) as a representative element for the REEs Sorbent material Metal Concentration Alginate-sulfonate-silica (ASS) spheres (mmol L -1 ) ph q e (mmol g -1 ) Reference In(III) present work Alginate-TMOS spheres In(III) present work Alginate-TMOS spheres Nd(III) [3] DTPA-functionalized chitosan-silica Nd(III) [4] Lewatit TP207 resin In(III) [5] DETA-functionalized chitosan nanoparticles Nd(III) [6] P-functionalized silica Nd(III) [7] S5
6 Figure S2: Raman spectrum of alginate spheres (in isopropanol) after functionalization with (3- mercaptopropyl) trimethoxysilane. Figure S3: Raman spectrum of alginate-sulfonate-silica spheres (dry) after oxidation with H 2 O 2. S6
7 (a) (b) (c) (d) (e) (f) Figure S4: Element mappings on cross-sectional images of ASS spheres with a diameter of 2.8 mm, (a) = C, (b) = Ca, (c) = Si, (d) = S, (e) = O, (f) = CBS reference. S7
8 Figure S5: N 2 adsorption-desorption isotherms at 77K of ASS spheres with a diameter of 2.2 mm. Figure S6: TGA traces of ASS spheres of 2.2 mm (green), 2.8 mm (red) and 3.5 mm (blue). S8
9 In(III) adsorption amount (mmol g -1 ) Temperature ( C) Figure S7: In(III) adsorption amount on ASS spheres with a diameter of 2.8 mm as a function of the reaction temperature. (1) Chhabra, R. P.; Richardson, J. F., Non-Newtonian Flow and Applied Rheology: Engineering Applications. 2 ed.; Elsevier: Oxford, UK, 2008; p 536. (2) Yu, W.; Hancock, B. C., Evaluation of dynamic image analysis for characterizing pharmaceutical excipient particles. Int. J. Pharm. 2008, 361, (3) Roosen, J.; Pype, J.; Binnemans, K.; Mullens, S., Shaping of Alginate Silica Hybrid Materials into Microspheres through Vibrating-Nozzle Technology and Their Use for the Recovery of Neodymium from Aqueous Solutions. Ind. Eng. Chem. Res. 2015, 54, (4) Roosen, J.; Spooren, J.; Binnemans, K., Adsorption performance of functionalized chitosansilica hybrid materials toward rare earths. J. Mater. Chem. A 2014, 2, (5) Lee, S.-K.; Lee, U. H., Adsorption and desorption property of iminodiacetate resin (Lewatit TP207) for indium recovery. J. Ind. Eng. Chem. 2016, 40, (6) Galhoum, A. A.; Mahfouz, M. G.; Abdel-Rehem, S. T.; Gomaa, N. A.; Atia, A. A.; Vincent, T.; Guibal, E., Diethylenetriamine-functionalized chitosan magnetic nano-based particles for the sorption of rare earth metal ions [Nd(III), Dy(III) and Yb(III)]. Cellulose 2015, 22, (7) Park, H.-J.; Tavlarides, L. L., Adsorption of Neodymium(III) from Aqueous Solutions Using a Phosphorus Functionalized Adsorbent. Ind. Eng. Chem. Res. 2010, 49, S9
Environment Protection Engineering REMOVAL OF HEAVY METAL IONS: COPPER, ZINC AND CHROMIUM FROM WATER ON CHITOSAN BEADS
Environment Protection Engineering Vol. 3 No. 3 4 KATARZYNA JAROS*, WŁADYSŁAW KAMIŃSKI*, JADWIGA ALBIŃSKA**, URSZULA NOWAK* REMOVAL OF HEAVY METAL IONS: COPPER, ZINC AND CHROMIUM FROM WATER ON CHITOSAN
More informationEfficient removal of heavy metal ions with EDTA. functionalized chitosan/polyacrylamide double network
Supporting Information Efficient removal of heavy metal ions with EDTA functionalized chitosan/polyacrylamide double network hydrogel Jianhong Ma a,b, Guiyin Zhou c, Lin Chu c, Yutang Liu a,b, *, Chengbin
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Supporting Information Cyclic Molecule Aerogels: A Robust Cyclodextrin
More informationAdsorption Performance of Functionalized Chitosan-Silica Hybrid Materials toward Rare Earths
Adsorption Performance of Functionalized Chitosan-Silica Hybrid Materials toward Rare Earths Joris Roosen, a,b Jeroen Spooren b and Koen Binnemans a * a KU Leuven, Department of Chemistry, Celestijnenlaan
More informationCarbon Dots Modified Mesoporous Organosilica as an Adsorbent for the. Removal of 2, 4-Dichlorophenol and Heavy Metal Ions
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information (ESI) for Journal of Materials Chemistry
More informationColloidal Suspension Rheology Chapter 1 Study Questions
Colloidal Suspension Rheology Chapter 1 Study Questions 1. What forces act on a single colloidal particle suspended in a flowing fluid? Discuss the dependence of these forces on particle radius. 2. What
More informationInfluence of Nonionic Surfactant Concentration on Physical Characteristics of Resorcinol-Formaldehyde Carbon Cryogel Microspheres
Influence of Nonionic Surfactant Concentration on Physical Characteristics of Resorcinol-Formaldehyde Carbon Cryogel Microspheres Seong-Ick Kim, Takuji Yamamoto, Akira Endo, Takao Ohmori, and Masaru Nakaiwa
More informationSelective Recovery of Indium from Acid Sulfate Media with Solvent Impregnated Resin of Bis(4-cyclohexylcyclohexyl)phosphoric Acid as an Extractant
Ion Exchange Letters 2 (2009) 22-26 iel.vscht.cz Selective Recovery of Indium from Acid Sulfate Media with Solvent Impregnated Resin of Bis(4-cyclohexylcyclohexyl)phosphoric Acid as an Extractant T. Nakamura,
More informationMOF-76: From Luminescent Probe to Highly Efficient U VI Sorption Material
MOF-76: From Luminescent Probe to Highly Efficient U VI Sorption Material Weiting Yang, a Zhi-Qiang Bai, b Wei-Qun Shi*, b Li-Yong Yuan, b Tao Tian, a Zhi-Fang Chai*, c Hao Wang, a and Zhong-Ming Sun*
More informationSupporting information A Porous Zr-cluster-based Cationic Metal-Organic Framework for Highly Efficient Cr 2 O 7
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Supporting information A Porous Zr-cluster-based Cationic Metal-Organic Framework for Highly Efficient
More informationApplication of Fe 2 O 3 nanoparticles in Heavy Metal Removal
Application of Fe 2 O 3 nanoparticles in Heavy Metal Removal 5.1 Introduction Different contaminants are released to water bodies due to the rapid industrialization of human society, including heavy metal
More informationSupplementary material to On the rheology of pendular gels and morphological developments in paste- like ternary systems based on capillary attraction
Electronic Supplementary Material (ESI) for Soft Matter. This journal is The Royal Society of Chemistry 214 Supplementary material to On the rheology of pendular gels and morphological developments in
More informationEVALUATION OF THE PERFORMANCE OF SOME CHEMICAL INHIBITORS ON CORROSION INHIBITION OF COPPER IN ACID MEDIA
EVALUATION OF THE PERFORMANCE OF SOME CHEMICAL INHIBITORS ON CORROSION INHIBITION OF COPPER IN ACID MEDIA Dr. Aprael S. Yaro University of Baghdad College of Engineering Chemical Eng. Department Anees
More informationParticle Size and Shape Analysis in PHARMACEUTICAL INDUSTRY.
Particle Size and Shape Analysis in PHARMACEUTICAL INDUSTRY Generalities Many analytical methods exist for the characterization of products manufactured in the pharmaceutical industry. Measuring the size
More informationSupplementary Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 Supplementary Information Enhanced Adsorption of Cu(II) Ions on the Chitosan Microspheres Functionalized
More informationKatarzyna Zielińska, Alexandre G. Chostenko, Stanisław Truszkowski
ADSORPTION OF CADMIUM IONS ON CHITOSAN MEMBRANES: KINETICS AND EQUILIBRIUM STUDIES Katarzyna Zielińska, Alexandre G. Chostenko, Stanisław Truszkowski Chair of Nuclear and Radiation Chemistry Faculty of
More information1 Supplemetary information. 3 Immobilization of hydrous iron oxides into porous alginate beads for. 4 arsenic removal from water
Electronic Supplementary Material (ESI) for Environmental Science: Water Research & Technology. This journal is The Royal Society of Chemistry 2018 1 Supplemetary information 2 3 Immobilization of hydrous
More informationExtraction of Rare Earth Elements using Composites
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2018 Supplementary Information Extraction of Rare Earth Elements using Magnetite@MOF
More informationPyrolytic Temperature Dependent and Ash Catalyzed Formation of Sludge Char. Xiao-Qing Liu, Hong-Sheng Ding, Yuan-Ying Wang, Wu-Jun Liu, Hong Jiang*
Pyrolytic Temperature Dependent and Ash Catalyzed Formation of Sludge Char with Ultra-High Adsorption to 1-Naphthol Xiao-Qing Liu, Hong-Sheng Ding, Yuan-Ying Wang, Wu-Jun Liu, Hong Jiang* CAS Key Laboratory
More informationSupplementary Information
Supplementary Information Fabrication of Novel Rattle-Type Magnetic Mesoporous carbon Microspheres for Removal of Microcystins Xinghua Zhang and Long Jiang* Beijing National Laboratory for Molecular Science
More informationMagnetic cellulose-chitosan hydrogels prepared from ionic liquids as reusable adsorbent for removal of heavy metal ions
Magnetic cellulose-chitosan hydrogels prepared from ionic liquids as reusable adsorbent for removal of heavy metal ions Zhen Liu, Haisong Wang*, Chao Liu, Yijun Jiang, Guang Yu, Xindong Mu* and Xiaoyan
More informationRemoval of Colloidal Particles Utilizing Gelation Reaction of Sodium Alginate
Korean J. Chem. Eng., 17(5), 574-578 (2000) Removal of Colloidal Particles Utilizing Gelation Reaction of Sodium Alginate Masashi Iwata Department of Industrial Chemistry, Suzuka National College of Technology,
More informationAgilent s New Weak Anion Exchange (WAX) Solid Phase Extraction Cartridges: SampliQ WAX
Agilent s New Weak Anion Exchange (WAX) Solid Phase Extraction Cartridges: SampliQ WAX Technical Note Agilent s SampliQ WAX provides Applications for strongly acidic, acidic and neutral compounds Excellent
More informationSize-controlled Synthesis of sub-10 nm Citrate-stabilized Gold. Nanoparticles and Related Optical Properties.
Supporting information for: Size-controlled Synthesis of sub-10 nm Citrate-stabilized Gold Nanoparticles and Related Optical Properties. Jordi Piella, Neus G. Bastús and Victor Puntes Table of Contents
More informationPharmaceutics I صيدالنيات 1. Unit 6
Pharmaceutics I صيدالنيات 1 Unit 6 1 Rheology of suspensions Rheology, the study of flow, addresses the viscosity characteristics of powders, fluids, and semisolids. Materials are divided into two general
More informationPREFACE About the Author
Contents / vii CONTENTS PREFACE About the Author CONTENTS v vi vii INTRODUCTION Sorption and Biosorption Share the Methodology 1 1. POTENTIAL OF BIOSORPTION 5 1.1 METALS: ENVIRONMENTAL THREAT 5 1.2 BIOSORPTION
More informationPreparation of alginate chitosan hybrid gel beads and adsorption of divalent metal ions
Chemosphere 55 (2004) 135 140 Short Communication Preparation of alginate chitosan hybrid gel beads and adsorption of divalent metal ions Takeshi Gotoh a, *, Keiei Matsushima b, Ken-Ichi Kikuchi a a Department
More informationMaterials Chemistry A
Journal of Materials Chemistry A PAPER Cite this: J. Mater. Chem. A, 2014,2, 1530 Adsorption and chromatographic separation of rare earths with EDTA- and DTPA-functionalized chitosan biopolymers Joris
More informationScreening of Algae Material as a Filter for Heavy Metals in Drinking Water
1 Screening of Algae Material as a Filter for Heavy Metals in Drinking Water 2 ABSTRACT Calcium alginate beads generated from alginic acid sodium salt from brown algae were 3 used to explore the adsorption
More informationA high-efficient monoclinic BiVO 4 adsorbent for selective capture toxic selenite
Supporting Online Materials for A high-efficient monoclinic BiVO 4 adsorbent for selective capture toxic selenite Huan Ouyang, Yuanyuan Sun*, and Jianqiang Yu* Collaborative Innovation Center for Marine
More informationDegradation of Bisphenol A by Peroxymonosulfate Catalytically Activated with. Gui-Xiang Huang, Chu-Ya Wang, Chuan-Wang Yang, Pu-Can Guo, Han-Qing Yu*
Supporting Information for Degradation of Bisphenol A by Peroxymonosulfate Catalytically Activated with Mn 1.8 Fe 1.2 O 4 Nanospheres: Synergism between Mn and Fe Gui-Xiang Huang, Chu-Ya Wang, Chuan-Wang
More informationThe principals of rheology In pharmaceutical technology
The principals of rheology In pharmaceutical technology Dr. Aleksandar Széchenyi University of Pécs Gyógyszertechnológiai és Biofarmáciai Intézet Institute of Pharmaceutical Technology and Biopharmacy
More informationDouble Mesoporous Silica Shelled Spherical/Ellipsoidal Nanostructures: Synthesis and Hydrophilic/Hydrophobic Anticancer Drug Delivery
Supporting information for Supplementary Material (ESI) for Journal of Materials Chemistry Double Mesoporous Silica Shelled Spherical/Ellipsoidal Nanostructures: Synthesis and Hydrophilic/Hydrophobic Anticancer
More informationTitanium mesh based fully flexible highly efficient quantum dots sensitized solar cells
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Supplementary Information (SI) Titanium mesh based fully flexible highly
More informationTreatment of Heavy Metals in Contaminated Soils Around an Abandoned Mine Using Magnetically Modified Alginic Acid and XYZ
Treatment of Heavy Metals in Contaminated Soils Around an Abandoned Mine Using Magnetically Modified Alginic Acid and XYZ Choong Jeon and Sung Ho Yeom Department of Environmental & Applied Chemical Engineering,
More informationBabak Karimi* and Majid Vafaeezadeh
Electronic upplementary Material (EI) for RC Advances This journal is The Royal ociety of Chemistry 2013 BA-15 functionalized sulfonic acid confined hydrophobic and acidic ionic liquid: a highly efficient
More informationPharmaceutics I. Unit 6 Rheology of suspensions
Pharmaceutics I اينالديصيدلينيات 1 Unit 6 Rheology of suspensions 1 Rheology, the science of the flow or deformation of matter (liquid or soft solid) under the effect of an applied force. It addresses
More informationSupporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting Information Au nanoparticles supported on magnetically separable Fe 2 O 3 - graphene
More informationEthers in a Porous Metal-Organic Framework
Supporting Information Enhanced Isosteric Heat of H 2 Adsorption by Inclusion of Crown Ethers in a Porous Metal-Organic Framework Hye Jeong Park and Myunghyun Paik Suh* Department of Chemistry, Seoul National
More informationPesticide sorption and diffusion in natural clay loam aggregates
Pesticide sorption and diffusion in natural clay loam aggregates Wendy van Beinum, Sabine Beulke, Colin Brown Cranfield University, Silsoe Central Science Laboratory, York Funded by BBSRC Time-dependent
More informationPotential Alternative Utilization of Manganese Nodules
UNIVERSITY OF CHEMISTRY AND TECHNOLOGY PRAGUE Potential Alternative Utilization of Manganese Nodules Ng. Hong VU Utilization of leaching residues as sorbents Reductive leaching: - 90 o C, l/s= 10:1, ~
More informationAcid-base Polymeric Engineered Foams for Adsorption of Micro-Oil Droplets from Industrial Effluents
Supporting Information for Acid-base Polymeric Engineered Foams for Adsorption of Micro-Oil Droplets from Industrial Effluents Pavani Cherukupally,, Edgar J. Acosta, Juan P. Hinestroza, Amy M. Bilton,
More informationSupporting Information
Supporting Information Ultrafast and Efficient Extraction of Uranium from Seawater Using an Amidoxime Appended Metal-Organic Framework Long Chen, Zhuanling Bai, Lin Zhu, Linjuan Zhang, # Yawen Cai, Yuxiang
More informationGFC Analysis of Water-Soluble Polymers with TSKgel PW-type Columns. Contents
No.035 GFC Analysis of Water-Soluble Polymers with TSKgel PW-type Columns Contents Page 1. Introduction 2. Separation ranges for each grade of TSKgel PW-type column 3. GFC apparatus for water-soluble systems
More informationHierarchical Nanocomposite by Integrating Reduced Graphene Oxide and Amorphous Carbon with Ultrafine MgO Nanocrystallites for Enhanced CO 2 Capture
Supporting Information Hierarchical Nanocomposite by Integrating Reduced Graphene Oxide and Amorphous Carbon with Ultrafine MgO Nanocrystallites for Enhanced CO 2 Capture Ping Li, and Hua Chun Zeng* Department
More informationA General Synthesis of Discrete Mesoporous Carbon Microspheres through a Confined Self- Assembly Process in Inverse Opals
A General Synthesis of Discrete Mesoporous Carbon Microspheres through a Confined Self- Assembly Process in Inverse Opals Zhenkun Sun,, Yong Liu, Bin Li, Jing Wei, Minghong Wang, Qin Yue, Yonghui Deng,
More informationSupporting Information. Adsorption of Cu(II), Zn(II), and Pb(II) from aqueous single. and binary metal solutions by regenerated cellulose and
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2018 Supporting Information Adsorption of Cu(II), Zn(II), and Pb(II) from aqueous single and binary
More informationModern Chemical Enhanced Oil Recovery
Modern Chemical Enhanced Oil Recovery Theory and Practice James J. Sheng, Ph. D. AMSTERDAM BOSTON «HEIDELBERG LONDON ELSEVIER NEW YORK OXFORD PARIS SAN DIEGO SAN FRANCISCO SINGAPORE SYDNEY TOKYO Gulf Professional
More informationVersatile inorganic organic hybrid WO x ethylenediamine nanowires: Synthesis, mechanism and application in heavy metal ion adsorption and catalysis
Electronic Supplementary Material Versatile inorganic organic hybrid WO x ethylenediamine nanowires: Synthesis, mechanism and application in heavy metal ion adsorption and catalysis Wei Li 1,2, Fang Xia
More informationPhysical adsorption of PVOH to adjust the rheological profile of NFC
Physical adsorption of PVOH to adjust the rheological profile of NFC Lars Järnström and Kristýna Hlisnikovská, Karlstad University SUNPAP Workshop 5.10.2011 Outline Introduction Experimental part Results
More informationHighly stable and AC electric field-activated electrorheological fluid. based on mesoporous silica-coated graphene nanosheets
Supplementary Information for: Highly stable and AC electric field-activated electrorheological fluid based on mesoporous silica-coated graphene nanosheets Jianbo Yin *, Runtian Chang, Yan Kai and Xiaopeng
More informationHydrophobic Silica Aerogels Solvent Removal From Water
Hydrophobic Silica Aerogels Solvent Removal From Water Zoran NOVAK, Suzana #ERN#I#, Željko KNEZ* University of Maribor, Faculty of Chemistry and Chemical Engineering, Smetanova 17, SI-2000 Maribor, Slovenia
More informationQuantification of ligand packing density on gold nanoparticles using ICP-OES
Analytical and Bioanalytical Chemistry Electronic Supplementary Material Quantification of ligand packing density on gold nanoparticles using ICP-OES Sherrie Elzey, De-Hao Tsai, Savelas A. Rabb, Lee L.
More informationSilver-Decorated Hafnium Metal-Organic Framework for. Ethylene/Ethane Separation
Supporting Information Silver-Decorated Hafnium Metal-Organic Framework for Ethylene/Ethane Separation Yuxiang Wang, Zhigang Hu, Youdong Cheng, and Dan Zhao * Department of Chemical & Biomolecular Engineering,
More informationRECOVERY OF INDIUM FROM SPENT FLAT PANEL DISPLAY WITH SOLVENT-IMPREGNATED RESINS. K. Inoue, M. Nishiura, H. Kawakita, K.Ohto, and H.
RECOVERY OF INDIUM FROM SPENT FLAT PANEL DISPLAY WITH SOLVENT-IMPREGNATED RESINS K. Inoue, M. Nishiura, H. Kawakita, K.Ohto, and H. Harada Department of Applied Chemistry, Saga University, Honjo 1, Saga
More informationXiaoping Wangab. Electronic Supplementary Material (ESI) for Journal of Materials Chemistry This journal is The Royal Society of Chemistry 2012
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry Supplementary Information of Highly Efficient Dye Adsorption and Removal: Functional Hybrid of Reduced Graphene Oxide Fe 3 O 4
More informationCharacteristics of Spherical Activated Carbon contained Titanium Oxide
Characteristics of Spherical Activated Carbon contained Titanium Oxide Jeong-Kwon Suh 1, Joon-Jae Lee 1, Ji-Sook Hong 1, Young-Seak Lee 2 and Jung-Min Lee 1 1 Korea research Institute of Chemical Technology
More informationSupporting Information. Golf ball-shaped PLGA microparticles with internal pores fabricated by simple O/W emulsion
Supplementary Material (ESI) for Chemical Communications Supporting Information Golf ball-shaped PLGA microparticles with internal pores fabricated by simple O/W emulsion Mi Ri Kim, a Seungwoo Lee, b Jung-Ki
More informationRheology of strongly sedimenting magnetite suspensions
ANNUAL TRANSACTIONS OF THE NORDIC RHEOLOGY SOCIETY, VOL. 13, 05 Rheology of strongly sedimenting magnetite suspensions Jan Gustafsson1, Martti Toivakka1, and Kari K. Koskinen2 1 Laboratory of Paper Coating
More informationCHAPTER 4. SYNTHESIS, CHARACTERIZATION OF TiO 2 NANOTUBES AND THEIR APPLICATION IN DYE SENSITIZED SOLAR CELL
93 CHAPTER 4 SYNTHESIS, CHARACTERIZATION OF TiO 2 NANOTUBES AND THEIR APPLICATION IN DYE SENSITIZED SOLAR CELL 4.1 INTRODUCTION TiO 2 -derived nanotubes are expected to be applicable for several applications,
More informationSupporting Information. Sol gel Coating of Inorganic Nanostructures with Resorcinol Formaldehyde Resin
Supporting Information Sol gel Coating of Inorganic Nanostructures with Resorcinol Formaldehyde Resin Na Li, a,b Qiao Zhang, b Jian Liu, c Jibong Joo, b Austin Lee, b Yang Gan,* a Yadong Yin *b a School
More informationAnalysis of Droplet Coalescence in Emulsions Subjected to Acoustic Fields
Analysis of Droplet Coalescence in Emulsions Subjected to Acoustic Fields Gautam D. Pangu and Donald L. Feke, Department of Chemical Engineering, Case Western Reserve University, Cleveland, OH 4416 USA
More informationCFD Study of the Turbulent Forced Convective Heat Transfer of Non-Newtonian Nanofluid
Reduction of Parasitic Currents in Simulation of Droplet Secondary Breakup with Density Ratio Higher than 60 by InterDyMFoam Iranian Journal of Chemical Engineering Vol. 11, No. 2 (Spring 2014), IAChE
More informationSupporting Information
Supporting Information MoSe2 embedded CNT-Reduced Graphene Oxide (rgo) Composite Microsphere with Superior Sodium Ion Storage and Electrocatalytic Hydrogen Evolution Performances Gi Dae Park, Jung Hyun
More informationEnhanced Acidic and Catalytic Properties of Modified Sulfonic Acid Resins. D R Brown, H E Cross and P F Siril
Enhanced Acidic and Catalytic Properties of Modified Sulfonic Acid Resins D R Brown, E Cross and P F Siril Department of Chemical and Biological Chemistry, University of uddersfield 1 omogeneous Acid
More informationA theoretical approach to evaluate the release rate of. acetaminophen from erosive wax matrix dosage forms
1 2 A theoretical approach to evaluate the release rate of acetaminophen from erosive wax matrix dosage forms 3 4 Yasuyoshi Agata, Yasunori Iwao, Kai Shiino, Atsuo Miyagishima, Shigeru Itai* 5 6 7 8 9
More informationI. Multiple choice: ( ) (2.5 points each, total: 75 points) 1. Which among the following represent a set of isotopes Atomic nuclei containing:
I. Multiple choice: ( ) (2.5 points each, total: 75 points) 1. Which among the following represent a set of isotopes Atomic nuclei containing: I. 20 protons and 20 neutrons. II. 21 protons and 19 neutrons.
More informationSupporting Information
Copyright WILEY-VCH Verlag GmbH & Co. KGaA, 69469 Weinheim, Germany, 2018. Supporting Information for Small, DOI: 10.1002/smll.201801523 Ultrasensitive Surface-Enhanced Raman Spectroscopy Detection Based
More informationGeneral conclusions and the scope of future work. Chapter -10
General conclusions and the scope of future work Chapter -10 General conclusion and 157 General Conclusions and the scope of future work 10.1 Introduction The first step in the preparation of silica aerogels
More informationPreparation and characterisation of a sorbent suitable for technetium separation from environmental matrices
Preparation and characterisation of a sorbent suitable for technetium separation from environmental matrices A. Bartosova, P. Rajec, M. Reich Faculty of Natural Sciences, Department of Nuclear chemistry,
More informationApplication of Phosphorus-Containing Ion Exchangers for the Recovery and Separation of Uranium and Transuranic Elements
Application of Phosphorus-Containing Ion Exchangers for the Recovery and Separation of Uranium and Transuranic Elements - 11490 Vladimir M.Gelis, Vitaly V.Milyutin, Evgeny A.Kozlitin, Natalya A.Nekrasova,
More informationSupporting Information
Supporting Information Clay Based Nanocomposites as Recyclable Adsorbent toward Hg(II) Capture: Experimental and Theoretical Understanding Sankar Das, Arnab Samanta, Gautam Gangopadhyay and Subhra Jana
More informationLuke Chimuka. School of Chemistry, University of Witwatersrand
Preparation, characterization and application of NaHCO 3 leached bulk U(VI) imprinted polymers endowed with γ-mps coated magnetite in contaminated water Luke Chimuka School of Chemistry, University of
More informationFormation of valine microcrystals through rapid antisolvent precipitation
Formation of valine microcrystals through rapid antisolvent precipitation Miroslav Variny a, Sandra Alvarez de Miguel b, Barry D. Moore c, Jan Sefcik b a Department of Chemical and Biochemical Engineering,
More informationSupporting Information
Supporting Information Hydrogen Storage in the Dehydrated Prussian Blue Analogues M 3 [Co(CN) 6 ] 2 (M = Mn, Fe, Co, Ni, Cu, Zn) Steven S. Kaye and Jeffrey R. Long* Dept. of Chemistry, University of California,
More informationJahresbericht 2003 der Arbeitsgruppe Experimentalphysik Prof. Dr. Michael Farle
Self-assembly of Fe x Pt 1-x nanoparticles. M. Ulmeanu, B. Stahlmecke, H. Zähres and M. Farle Institut für Physik, Universität Duisburg-Essen, Lotharstr. 1, 47048 Duisburg Future magnetic storage media
More informationAvailable online at ScienceDirect. Energy Procedia 89 (2016 )
Available online at www.sciencedirect.com ScienceDirect Energy Procedia 89 (2016 ) 366 372 CoE on Sustainable Energy System (Thai-Japan), Faculty of Engineering, Rajamangala University of Technology Thanyaburi
More informationChromatography. What is Chromatography?
Chromatography What is Chromatography? Chromatography is a technique for separating mixtures into their components in order to analyze, identify, purify, and/or quantify the mixture or components. Mixture
More informationMagnetic Particles for Phosphorus Adsorption in Simulated Phosphate Solution
215 4th International Conference on Informatics, Environment, Energy and Applications Volume 82 of IPCBEE (215) DOI: 1.7763/IPCBEE. 215.V82.28 Magnetic Particles for Phosphorus Adsorption in Simulated
More informationMeasurement techniques
Measurement techniques 1 GPC GPC = gel permeation chromatography GPC a type of size exclusion chromatography (SEC), that separates analytes on the basis of size. The column used for GPC is filled with
More informationEndcapping Treatment of Inner Surfaces of a Hexagonal Mesoporous Silica
Journal of Adhesion Science and Technology 26 (2012) 2135 2141 brill.nl/jast Endcapping Treatment of Inner Surfaces of a Hexagonal Mesoporous Silica Weiyi Lu a, Aijie Han b, Taewan Kim c, Brian J. Chow
More informationSupporting Information High Activity and Selectivity of Ag/SiO 2 Catalyst for Hydrogenation of Dimethyloxalate
Supporting Information High Activity and Selectivity of Ag/SiO 2 Catalyst for Hydrogenation of Dimethyloxalate An-Yuan Yin, Xiao-Yang Guo, Wei-Lin Dai*, Kang-Nian Fan Shanghai Key Laboratory of Molecular
More informationSupporting Information. Facile design of phase separation for microfluidic. droplet-based liquid phase microextraction as a front end to
Supporting Information Facile design of phase separation for microfluidic droplet-based liquid phase microextraction as a front end to electrothermal vaporization-icpms for the analysis of trace metals
More informationA soft-templated method to synthesize sintering-resistant Au/mesoporous-silica core-shell nanocatalysts with sub-5 nm single-core
A soft-templated method to synthesize sintering-resistant Au/mesoporous-silica core-shell nanocatalysts with sub-5 nm single-core Chunzheng Wu, ab Zi-Yian Lim, a Chen Zhou, a Wei Guo Wang, a Shenghu Zhou,
More informationSupporting Information
Supporting Information Eco-friendly Composite of Fe 3 O 4 -Reduced Grapene Oxide Particles for Efficient Enzyme Immobilization Sanjay K. S. Patel a,, Seung Ho Choi b,, Yun Chan Kang b,*, Jung-Kul Lee a,*
More informationSynthesis of magnetic nanoparticles via the sol-gel technique
Materials Science-Poland, Vol. 23, No. 1, 2005 Synthesis of magnetic nanoparticles via the sol-gel technique RÓŻA KORNAK 1, DANIEL NIŽŇANSKỲ 2, KRYSTYNA HAIMANN 1 WŁODZIMIERZ TYLUS 3, KRZYSZTOF MARUSZEWSKI
More informationSynthesis of a Zeolite Column with a Monolithic Microhoneycomb Structure Using the Ice Template Method
Synthesis of a Zeolite Column with a Monolithic Microhoneycomb Structure Using the Ice Template Method Shin R. Mukai, Shinya Murata, Kazufusa Onodera and Izumi Yamada *1 Graduate School of Engineering,
More informationSuspension Stability; Why Particle Size, Zeta Potential and Rheology are Important
ANNUAL TRANSACTIONS OF THE NORDIC RHEOLOGY SOCIETY, VOL. 20, 2012 Suspension Stability; Why Particle Size, Zeta Potential and Rheology are Important Mats Larsson 1, Adrian Hill 2, and John Duffy 2 1 Malvern
More informationSupporting Information for
Supporting Information for Microporous Organic Network Hollow Spheres: Useful Templates for Nanoparticulate Co 3 O 4 Hollow Oxidation Catalysts Narae Kang, Ji Hoon Park, Mingshi Jin, Nojin Park, Sang Moon
More informationMicrostructure and strength change of hardened cement paste under drying process
Microstructure and strength change of hardened cement paste under drying process Ippei MARUYAMA 1, Yukiko NISHIOKA 1, and Go IGARASHI 1 1 Nagoya University * ES-bldg 546, Nagoya Univ., Furo, Chikusa, Nagoya,
More informationAdsorption Equilibria. Ali Ahmadpour Chemical Eng. Dept. Ferdowsi University of Mashhad
Adsorption Equilibria Ali Ahmadpour Chemical Eng. Dept. Ferdowsi University of Mashhad Contents Introduction Adsorption isotherm models Langmuir isotherm Volmer isotherm Fowler-Guggenheim isotherm Hill-deBoer
More informationSupplementary Data. Size-controlled synthesis of MIL-101(Cr) nanoparticles with. enhanced selectivity for CO 2 over N 2
Supplementary Data Size-controlled synthesis of MIL-11(Cr) nanoparticles with enhanced selectivity for CO 2 over N 2 Dongmei Jiang, Andrew D. Burrows* and Karen J. Edler Department of Chemistry, University
More informationSupplementary Figure 1 XPS, Raman and TGA characterizations on GO and freeze-dried HGF and GF. (a) XPS survey spectra and (b) C1s spectra.
Supplementary Figure 1 XPS, Raman and TGA characterizations on GO and freeze-dried HGF and GF. (a) XPS survey spectra and (b) C1s spectra. (c) Raman spectra. (d) TGA curves. All results confirm efficient
More informationUse of Organo-Montmorillonite Nanoclay as an Environmentally Friendly Adsorbent for Removal of Hexavalent Chromium
International Proceedings of Chemical, Biological and Environmental Engineering, Vl. 11 (217) DOI: 1.7763/IPCBEE. 217. V11. 19 Use of Organo-Montmorillonite Nanoclay as an Environmentally Friendly Adsorbent
More informationARSENIC SPECIATION AND IDENTIFICATION ON ACTIVE IRON ADSORBENT SITES BY XAFS TECHNOLOGY
ARSENIC SPECIATION AND IDENTIFICATION ON ACTIVE IRON ADSORBENT SITES BY XAFS TECHNOLOGY Dilshad Masih, Ken-ichi Aika and Yasuo Izumi (Tokyo Institute of Technology, Midori-ku, Yokohama 226-8502, Japan)
More informationRelative Viscosity of Non-Newtonian Concentrated Emulsions of Noncolloidal Droplets
Ind. Eng. Chem. Res. 2000, 39, 4933-4943 4933 Relative Viscosity of Non-Newtonian Concentrated Emulsions of Noncolloidal Droplets Rajinder Pal* Department of Chemical Engineering, University of Waterloo,
More informationSupporting Information for the manuscript. Metastable interwoven mesoporous metal-organic frameworks
S1 Supporting Information for the manuscript Metastable interwoven mesoporous metal-organic frameworks Yabing He, ab Zhiyong Guo, b Shengchang Xiang, c Zhangjing Zhang, c Wei Zhou, d,e Frank R. Fronczek,
More informationSupplementary Information. ZIF-8 Immobilized Ni(0) Nanoparticles: Highly Effective Catalysts for Hydrogen Generation from Hydrolysis of Ammonia Borane
Supplementary Information ZIF-8 Immobilized Ni() Nanoparticles: Highly Effective Catalysts for Hydrogen Generation from Hydrolysis of Ammonia Borane Pei-Zhou Li, a,b Kengo Aranishi, a and Qiang Xu* a,b
More informationDepartment of Chemistry, College of Science, Rikkyo (St.Paulls) University. phosphorus in mussel, tea-leaves, sargasso and rice flour (NIES CRM) with
P r e l i m i n a r y s t u d y o f m a t r i x effect on t h e s i m u l t a n e o u s d e t e r m i n a t i o n of silica and phosphate w i t h on-line c o l u m n F I A s p e c t r o p h o t o m e t
More informationFe/C CATALYSTS FOR HETEROGENEOUS FENTON TREATMENT OF PHENOL IN AQUEOUS PHASE
Fe/C CATALYSTS FOR HETEROGENEOUS FENTON TREATMENT OF PHENOL IN AQUEOUS PHASE Zazo, J.A. 1, Casas, J.A. 1, Bahamonde, A., Gilarranz, M.A. 1, Mohedano, A.F. 1, Rodriguez, J.J 1. 1 Area de Ingeniería Química,
More information