Carbon Compounds. Chemical Bonding Part 1b

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1 Carbon Compounds Chemical Bonding Part 1b

2 Board Notes Introduction to VSEPR

3 Organic Formulas Various Representations " dimethyl ether C 2 H 6 O " propyl alcohol C 3 H 8 O

4 3D representations " Wedges and dotted lines can be used to represent the 3D aspect structures.

5 Bond-line formulas (Skeletal Structures) " Each vertex represents a carbon atom. " Hydrogen atoms attached to carbons are generally not shown. " H s may be shown in cases where a reaction will involve a specific H atom. " The symbol for all other atoms are shown. " Single, double, and triple bonds between C s and other atoms are shown with the appropriate number of lines. " Unless a formal charge is indicated, each carbon is assumed to have enough H s to complete an octet. " A lone pair on C is always shown if present. " Lone pairs on other atoms may or may not be shown. " Typically, lone pairs ARE shown for N and O " Often, lone pairs are not shown on halogens, S, and P. " Formal charges are always shown.

6 Formal Charge

7 7

8 Structural (Constitutional) Isomers " Structural isomers are compounds that have the same formula, but a different arrangement of bonds in molecules of the compounds. " Example: C 2 H 6 O Ethanol & Dimethyl Ether

9 Propyl and isopropyl alcohols structural isomers " propyl alchohol C 3 H 8 O " isopropyl alchohol C 3 H 8 O

10 Lewis Dot Structures Single Central Atom General rules for covalent compounds and polyatomic ions with a SINGLE central atom. 1. Find the Total number of valence electrons: Add up valence electrons for all atoms. For each negative (-) charge, add one electron. For each positive (+) charge, subtract one electron. 2. Put the least electronegative atom in the center (but not Hydrogen). 3. Put other atoms around central atom and connect with a single bond.

11 Lewis Dot Structures Single Central Atom 4. Fill octets on outer atoms as lone pairs. 5. If any electrons are unused, put those remaining electrons on the central atom as lone pairs. 6. If needed, move lone pairs from outer atoms to bond with the central atom to form an octet on the central atom. This will make double or triple bonds. 7. Minimize (or properly distribute) formal charge by changing lone pairs to bonds. Only violate the octet if allowed.

12 Oxoanions, Oxyacids, and Carboxylic Acids " Board Write electron dot structures for an oxoanion, its corresponding acid, and acetic acid.

13 Quantum Mechanics & Bonding " Schrödinger & others working in the early 20 th century recognized that electrons can be treated mathematically as waves. " Schrödinger developed an equation for a wave function, psi (Ψ) that mathematically describes an electron based on its energy level in an atom. " Psi-squared (Ψ 2 ) provides the probability of finding an electron in a given region of space. " From a physical standpoint, Ψ 2 can be used to create an electron probability map describing the region of space where an electron in a given orbital can be found some percentage of the time (usually 90-95%).

14 QM Electron Probability Maps s orbitals

15 QM Electron Probability Maps p orbitals

16

17

18 Atomic Orbitals " An atomic orbital describes a region of space where up to two electrons in an atom are likely to be found. " Because atomic orbitals arise from the wave-like motion of electrons, we can apply wave properties to describe them. " Like a wave, AO s have + and regions and nodes.

19 Atomic Orbitals " Consider a transverse wave (as on a lake): " Regions of the wave are above (+) or below ( ) the level of the lake. " At some points, the wave is equal to the average level this point is a node.

20 s and p orbitals shapes, + / regions, and nodes " At a nodal surface or plane, the probability of finding an electron is zero. " The positive or negative sign on a particular lobe of an orbital does not in any way describe the motion or charge of an electron, but is merely a mathematical construct related to its wave function. " The signs becomes more important when orbitals combine.

21 Carbon: Atomic Orbitals (AO) " Carbon has an electron configuration of 1s 2 2s 2 2p 2 " The electron orbital diagram (Aufbau) arranges the electrons as follows: " This diagram follows the three rules of orbital filling: " Aufbau Principle " Pauli Exclusion Principle " Hund s Rule

22 Hybridization " When s & p orbitals combine, they form hybrid orbitals. " The resulting orbitals have shapes that reflects the shape of both original orbital wave functions.

23 VSEPR Theory Valence Shell Electron Pair Repulsion Theory: " Each electron region around a central atom has its own hybrid orbital. " Single, double, & triple bonds and lone pairs are all treated the same in VSEPR theory. " Because orbitals are filled with negatively charged particles - electrons, the regions repel one another. " The regions arrange in space to minimize these interactions resulting in predictable shapes.

24 Electron Dot Structure Total # of ELECTRON Regions # of BONDING Regions # of LONE PAIRS Hybridization Electron Arrangement SHAPE Bond Angle(s) Sketch

25 2 electron regions - sp hybridization " Consider BeH 2 DRAW. " Draw the Lewis dot structure. " Both of the valence electrons from Be form bonds. " However, in the electron configuration and in the Aufbau diagram for Be, we see that both of the valence electrons are already paired: Be = 1s 2 2s 2 2 nd E level: s p p p

26 2 electron regions - sp hybridization " In order for Be to form two covalent bonds, it must have two unpaired electrons. " One electron must be promoted to the 2p sublevel. 2 nd E level: s p p p " However, an s orbital & p orbital will not allow for the linear shape experimentally observed for the BeH 2 molecule. " The s & p orbitals hybridize to create two equivalent sp orbitals that can take on a linear arrangement: Hybridized 2 nd E level: sp sp p p

27 Mixing of Atomic Orbitals - sp hybridization

28 BeH 2 Molecule Be Hybridized 2 nd E level: 1s orbital from one H atom sp sp s s p p 1s orbital from a second H atom Be sp hybrid orbitals H Be H H 1s orbital BeH 2 is a LINEAR molecule.

29 3 electron regions - sp 2 hybridization " Consider BH 3 " Draw the electron dot structure. " In BH 3, boron needs 3 unpaired electrons to make three bonds to hydrogens. " However, in the electron configuration and in the Aufbau diagram for Be, we again see that two of the valence electrons are already paired. DRAW. " Experimental evidence shows 3 equivalent bonds and a planar molecule with120º bond angles.

30 3 electron regions - sp 2 hybridization B = 1s 2 2s 2 2p 1 2 nd E level: s p p p

31 sp 2 hybridization & BH 3 orbital overlap diagram " One electron will be promoted from the 2s to the 2p sublevel. " The 2s orbital and two of the three 2p orbitals will hybridize to make 3 equivalent sp 2 orbitals. DRAW. " The three hybrid orbitals assume a TRIGONAL PLANAR arrangement. " The sp 2 orbitals overlap with the 1s orbitals of 3 hydrogens to create sigma bonds. DRAW. " BH 3 is a TRIGONAL PLANAR molecule.

32 sp 2 hybridization & BH 3 orbital overlap diagram B hybridized 2 nd E level: sp 2 sp 2 sp 2 p H 1s orbital B sp 2 orbitals Sigma Bond

33 Consider: NO 2-3 electron regions: 2 bonds & 1 lone pairs

34 sp 3 hybridization in CH 4 " The Lewis dot structure demonstrates predicts methane has 4 C-H bonds. " Experimental evidence shows that all four bonds are identical. " Four identical orbitals are needed for carbon to make four identical bonds to the hydrogens. " The one 2s and three 2p orbitals of the 2 nd energy level hybridize to make four degenerate (same energy) sp 3 hybrid orbitals.

35 sp 3 hybridization in CH 4 native atomic orbitals: hybridized orbitals: 1. Promotion 2. Hybridization s p p p sp 3 sp 3 sp 3 sp 3

36 Hybridization sp3

37 VSEPR & sp 3 Hybridization

38 Bonding in Methane: sp 3 hybridization & orbital overlap Orbital Overlap Diagram:

39 Methane

40 VSEPR 4 electron regions - sp 3 hybridization " VSEPR Valence Shell Electron Pair Repulsion " 4 electron regions (from the 4 hybrid orbitals) à TETRAHEDRAL electron arrangement " SHAPES (based on bonds & lone pairs):

41 Hybridization & VSEPR - General " One hybrid orbital is needed for each electron region whether it is a single, double, or triple bond. " 2 electron regions: sp " 5 electron regions: sp 3 d " 3 electron regions: sp 2 " 6 electron regions: sp 3 d 2 " 4 electron regions: sp 3

42 VSEPR Summary 2, 3, 4 e - regions

43 VSEPR Summary 5 & 6 electron regions

44 Organic Molecules Interpreting VSEPR, Hybridization, & Bonding " Board Interpret a complex organic molecule.

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