ICP-Mass Spectrometer
|
|
|
- Luke Benedict Garrison
- 5 years ago
- Views:
Transcription
1 ICP-Mass Spectrometer
2 New Mass Spectrometers
3 The main issue: sequential vs. simultaneous Scanning, peak hopping are sequential Like viewing a photo through a peephole One pixel at a time Other parts of photo are invisible Even worse: viewing a movie through a peephole The most important parts always seem to be where you are NOT looking!
4 QuickTime and a decompressor are needed to see this picture.
5 Concept: Electronic Photoplate Truly simultaneous High spatial resolution Fast recording Direct integration Broad dynamic range Linear Stable; simple storage Immediate readout SSMS photoplate courtesy of D.W. Koppenaal
6
7 Mattauch-Herzog Mass Spectrograph Electrostatic Analyzer Ion Optics Magnetic Sector (1-10 KG) 80 cm Entrance Slit Extraction Optic Focal Plane Camera
8 QuickTime and a Cinepak decompressor are needed to see this picture.
9 New Multichannel Detector Faraday-strip detection One count per ion (no amplification) No thermionic emission No dynode statistics No dependence on ion mass Continuous integration and random access of m/z Nondestructive or destructive readout option Extended dynamic range; repetitive read
10 FPC-128 Multichannel Detector Time for one spectrum ms Reset FET 1000 ff Two gain levels Faraday Strip 45µ fingers 10 ff 1000 ff 0.16 V / e тidt OA Multiplexer 5µ spacing 10 ff 15.8 V / e 1 Vout = C x128
11 Data Acquisition DRO NDRO
12 Fingerboard
13 Fingerboard Channels
14 Put photo of ICP-ADAMS here FPC-128 Installed in MHMS FPC-128 Power Supplies
15 ICP-MHMS-FPC ICP FPC-128
16 Fixed Pattern Noise
17 Improved Resolution Operating Conditions Sample Intro. Laser Ablation Sample BNRM 44 (0.51% Mo) Integration Time 1 s MS Entrance Slit Width 100 µm 0.4 amu Resolution Peak Center Peak Width 0.12 FWHM R = 817
18 Simultaneous Isotope monitoring Mass Resolution 203 Pb, 206Pb, 207Pb, 208Pb 204 Tl, 205Tl µm wide pixels, 100 µm slit (old prototype detector with 32 pixels) 45 µm wide pixels, 100 µm slit (FPC 128) 45 µm wide pixels, 50 µm slit (FPC 128)
19 Limits of Detection (pptr) Element Li Be Mg Al V Cr Mn Fe Co Ni Cu Zn Ga As Se Sr FPC SEM Element Y Mo Ag Cd In Sn Sb Ba La Ce Ho W Ir Tl Bi U FPC SEM FPC 31-channel Focal-plane camera; SEM slit + single-channel electron multiplier
20 Elemental Analysis with the FPC Array Detector: Limits of Detection (ICP source) Bi Bi 203Tl 203 Tl Ir W W Ho Ho 193Ir 193 Limits of detection in the sub-part per trillion level for most elements Sn Sn Cd Cd Isotope 100Mo 100 Mo 8888Sr Sr 5555Mn Mn 5252Cr Cr V 4848Ti Ti 5151V Limits of detection (part pert trillion) Values determined using continuous sample introduction via an ultrasonic nebulizer 10 s integration time
21 Isotope Ratio Accuracy Isotope Ratio Accuracy (% Error)* Isotope Ratio FPC-128 FPC Ni/60Ni Sr/86Sr Mo/97Mo Cd/112Cd Sn/118Sn Sb/123Sb W/186W Ir/191Ir *No correction for mass bias
22 Isotope Ratio Accuracy Isotope Ratio Accuracy (% Error)* Isotope Ratio FPC-128 FPC Ni/60Ni Sr/86Sr Mo/97Mo Cd/112Cd Sn/118Sn Sb/123Sb W/186W Ir/191Ir *No correction for mass bias
23 Isotope Ratio Accuracy Isotope Ratio Accuracy (% Error)* Isotope Ratio FPC-128 FPC Ni/60Ni Sr/86Sr Mo/97Mo Cd/112Cd Sn/118Sn Sb/123Sb W/186W Ir/191Ir *No correction for mass bias
24 Isotope Ratio Accuracy Error Isotope Ratio Uncorrected Bias Corrected Sr/86Sr 14% 8% Mo/97Mo 11% 3% 4% 0.8% 120 5% 0.4% 121 5% 0.7% 4% 1% 3% 0.03% Cd/112Cd Sn/118Sn Sb/123Sb 184 W/186W 193 Ir/191Ir
25 Isotope-Ratio Precision
26 Isotope Ratio Precision 0.007% RSD, 3 minute integration
27 Elemental Analysis with the FPC Array Detector: Linear Dynamic Range Linearity over 7 orders 1pptr to 50 ppm Pixel full well capacity: ~105 charges (low gain) ~107 charges (high gain) Signal time
28 Where speed & simultaneous measurement really matter High-precision isotope ratios Optimal internal standardization Situations where the signal shape is critical Flow injection Electrothermal (carbon-furnace) vaporization Time-varying signals (e.g. LC, GC, CE) Modulation methods Fast transients (e.g. laser ablation)
29 Where speed & simultaneous measurement really matter High-precision isotope ratios Optimal internal standardization Situations where the signal shape is critical Flow injection Electrothermal (carbon-furnace) vaporization Time-varying signals (e.g. LC, GC, CE) Modulation methods Fast transients (e.g. laser ablation)
30 ETV-ICP-ADAMS
31 Electrothermal Vaporization Sample Introduction To ICP Cleaning Ar sweep gas I Temperature ( C) Ashing 1000 Drying 100 Vaporization Time (s)
32 Temporal Separation of Isobaric Interferences 1.5 ArO+ and Fe monitored at m/z = 56 during a full ETV cycle Signal Fe + Ar O Time (sec)
33 Elimination of Isobaric Overlaps Through Temperature Program Necessary m/z Resolving Power: ~330, μl injection, 10 ppb Cd and In solution Temperature Program Dry: 100 C, 90s Ash: 250 C, 10s Atomize: 1700 C, 4s Ramp: 250 C/s
34 ETV Limits of Detection (pptr) Isotope FPC SEM Isotope FPC SEM V Sn Cr Sb Mn Ba Co Ho Ni W Zn Ir Sr Tl Ag Bi Cd U s Integration Time FPC Focalplane camera SEM Single channel Secondary Electron Multiplier
35 ETV-ICP-ADAMS 1 ppm Sr and 10 ppb Y 2 s integration time All pixels at low gain (Pixels collecting 88Sr signals saturate at high gain) Signal for Y collected at high gain
36 Where speed & simultaneity really matter High-precision isotope ratios Optimal internal standardization Situations where the signal shape is critical Flow injection Electrothermal vaporization Time-varying signals (e.g. LC, GC, CE) Modulation methods Fast transients (e.g. laser ablation)
37 Laser Ablation ICP-ADAMS Setup Mattauch-Herzog Mass Spectrograph Cetac LSX-200 ICP He Sweep Gas Ar Make-up Gas
38 LA LODs Steady state, single shot Element Steady State (ng/g) Single Shot (fg) Element Steady State (ng/g) Single Shot (fg) B Sr Mn Ag Fe Au Co Tl Ni Pb 9 46 Cu Th Rb U
39 Laser Ablation ICP-ADAMS Shot-to-Shot Reproducibility Isotope %RSD Isotope %RSD 27 Al Cu Si Nb Cr Mo Mn Sn Fe W Ni Pb 12.2
40 Laser Ablation Precision Ultimate Precision: 0.02% RSD
41 Steel substrate NIST 1359B Copper on Brass 45um layer of Cu protective layer of Cr
42 NIST 1359B Copper on Brass 4-5nm depth resolution per pulse
43 Where speed & simultaneity really matter High-precision isotope ratios Optimal internal standardization Situations where the signal shape is critical Flow injection Electrothermal vaporization Time-varying signals (e.g. LC, GC, CE) Modulation methods Fast transients (e.g. in situ laser ablation)
44 Chromatography with ICPADAMS GC, LC, CE being pursued
45 Lanthanides by LC-ICP-ADAMS
OES - Optical Emission Spectrometer 2000
OES - Optical Emission Spectrometer 2000 OES-2000 is used to detect the presence of trace metals in an analyte. The analyte sample is introduced into the OES-2000 as an aerosol that is carried into the
ICP-3000 Inductively Coupled Plasma Optical Emission Spectrometer
Inductively Coupled Plasma Optical Emission Spectrometer Inductively Coupled Plasma Optical Emission Spectrometer Inductively Coupled Plasma Optical Emission Spectrometer is powerful simultaneous full
Direct Analysis of Trace Metal Impurities in High Purity Nitric Acid Using ICP-QQQ
Application Note Semiconductor Direct Analysis of Trace Metal Impurities in High Purity Nitric Acid Using ICP-QQQ Authors Kazuo Yamanaka and Kazuhiro Sakai Agilent Technologies, Tokyo, Japan Introduction
Element Cube Project (x2)
Element Cube Project (x2) Background: As a class, we will construct a three dimensional periodic table by each student selecting two elements in which you will need to create an element cube. Helpful Links
The Agilent 7700x ICP-MS Advantage for Drinking Water Analysis
The Agilent 77x ICP-MS Advantage for Drinking Water Analysis Application Note Environmental Authors Steve Wilbur Agilent Technologies, Inc. 338 146th Place SE, Suite 3, Bellevue Washington, 987 USA Introduction
February 20, Joe Cerniglia The International Group for Historic Aircraft Recovery (TIGHAR) Job Number: S0CHG688. Dear Joe:
February 20, 2012 Joe Cerniglia The International Group for Historic Aircraft Recovery (TIGHAR) Subject: ICP-MS Report Job Number: S0CHG688 Dear Joe: Please find enclosed the procedure report for the analysis
Overview of X-Ray Fluorescence Analysis
Overview of X-Ray Fluorescence Analysis AMPTEK, INC., Bedford, MA 01730 Ph: +1 781 275 2242 Fax: +1 781 275 3470 sales@amptek.com 1 What is X-Ray Fluorescence (XRF)? A physical process: Emission of characteristic
Partial Energy Level Diagrams
Partial Energy Level Diagrams 460 nm 323 nm 610 nm 330 nm 819 nm 404 nm 694 nm 671 nm 589 / 590 nm 767 / 769 nm Lithium Sodium Potassium Gas Mixtures Maximum Temperatures, C Air-Coal Gas 1825 Air-Propane
Determination of Impurities in Silica Wafers with the NexION 300S/350S ICP-MS
APPLICATION NOTE ICP - Mass Spectrometry Author Kenneth Ong PerkinElmer, Inc. Singapore Determination of Impurities in Silica Wafers with the NexION 300S/350S ICP-MS Introduction The control of impurity
The Periodic Table. Periodic Properties. Can you explain this graph? Valence Electrons. Valence Electrons. Paramagnetism
Periodic Properties Atomic & Ionic Radius Energy Electron Affinity We want to understand the variations in these properties in terms of electron configurations. The Periodic Table Elements in a column
Nucleus. Electron Cloud
Atomic Structure I. Picture of an Atom Nucleus Electron Cloud II. Subatomic particles Particle Symbol Charge Relative Mass (amu) protons p + +1 1.0073 neutrons n 0 1.0087 electrons e - -1 0.00054858 Compare
Introduction to GC/MS
Why Mass Spectrometry? Introduction to GC/MS A powerful analytical technique used to: 1.Identify unknown compounds 2. Quantify known materials down to trace levels 3. Elucidate the structure of molecules
Applications of ICP-MS for Trace Elemental Analysis in the Hydrocarbon Processing Industry
Applications of ICP-MS for Trace Elemental Analysis in the Hydrocarbon Processing Industry Fundamentals and Applications to the Petrochemical Industry Outline Some background and fundamentals of ICPMS
Fundamentals of the ICP-MS Technique and How to Resolve Issues for Pharmaceutical Materials (In 20 Minutes) Tim Shelbourn, Eli Lilly and Company
Fundamentals of the ICP-MS Technique and How to Resolve Issues for Pharmaceutical Materials (In 20 Minutes) Tim Shelbourn, Eli Lilly and Company Why ICP Mass Spectrometry? Ultra-trace multi-element analytical
(C) Pavel Sedach and Prep101 1
(C) Pavel Sedach and Prep101 1 (C) Pavel Sedach and Prep101 1 (C) Pavel Sedach and Prep101 2 (C) Pavel Sedach and Prep101 2 (C) Pavel Sedach and Prep101 3 (C) Pavel Sedach and Prep101 3 (C) Pavel Sedach
Sample Analysis Design PART III
Sample Analysis Design PART III Sample Analysis Design Generating high quality, validated results is the primary goal of elemental abundance determinations It is absolutely critical to plan an ICP-MS analysis
Trace Analyses in Metal Matrices Using the ELAN DRC II
www.perkinelmer.com Trace Analyses in Metal Matrices Using the ELAN DRC II Introduction Analyses of matrices containing high levels of metals present a challenge for ICP-MS. First, the concentrations of
Atoms and the Periodic Table
Atoms and the Periodic Table Parts of the Atom Proton Found in the nucleus Number of protons defines the element Charge +1, mass 1 Parts of the Atom Neutron Found in the nucleus Stabilizes the nucleus
Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry: acquiring basic skills and solid sample meausurements
Practicum Spectroscopy Fall 2010 LIM Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry: acquiring basic skills and solid sample meausurements Jorge Ferreiro, study degree Chemistry, 5 th semester,
Last 4 Digits of USC ID:
Chemistry 05 B Practice Exam Dr. Jessica Parr First Letter of last Name PLEASE PRINT YOUR NAME IN BLOCK LETTERS Name: Last 4 Digits of USC ID: Lab TA s Name: Question Points Score Grader 8 2 4 3 9 4 0
ORBITAL DIAGRAM - A graphical representation of the quantum number "map" of electrons around an atom.
178 (MAGNETIC) SPIN QUANTUM NUMBER: "spin down" or "spin up" - An ORBITAL (region with fixed "n", "l" and "ml" values) can hold TWO electrons. ORBITAL DIAGRAM - A graphical representation of the quantum
atomic absorption spectroscopy general can be portable and used in-situ preserves sample simpler and less expensive
Chapter 9: End-of-Chapter Solutions 1. The following comparison provides general trends, but both atomic absorption spectroscopy (AAS) and atomic absorption spectroscopy (AES) will have analyte-specific
THE STRUCTURE OF ATOMS. ATOMS Atoms consist of a number of fundamental particles, the most important ones are...
Atomic Structure THE STRUCTURE OF ATOMS ATOMS Atoms consist of a number of fundamental particles, the most important ones are... Mass / kg Charge / C Relative mass Relative Charge PROTON NEUTRON ELECTRON
ICP-MS. plasma 17OO. High Resolution Multi-Collector ICP-MS.
ICP-MS plasma 17OO High Resolution Multi-Collector ICP-MS www.nu-ins.com Plasma 1700 & Sapphire 1700 Plasma 1700: Large Geometry Multi-Collector Inductively Coupled Plasma Mass Spectrometer For more information
Thermo Scientific icap RQ ICP-MS: Typical limits of detection
TECHNICAL NOTE 43427 Thermo Scientific icap RQ ICP-MS: Typical limits of detection Author Tomoko Vincent Keywords BEC, interference removal, KED, LOD Introduction Inductively Coupled Plasma Mass Spectrometry
Key Analytical Issues: Sample Preparation, Interferences and Variability. Tim Shelbourn, Eli Lilly and Company
Key Analytical Issues: Sample Preparation, Interferences and Variability Tim Shelbourn, Eli Lilly and Company Presentation Outline Sample preparation objectives and challenges Some common interferences
Analysis Repeatability of Trace and Major Elements in a Water Sample
Analysis Repeatability of Trace and Major Elements in a Water Sample Agnès COSNIER HORIBA Scientific Longjumeau, France Keywords: environment Elements: Al, As, B, Ba, Ca, Cd, Co, Cr, Cu, Fe, Hg, K, Li,
Guide to the Extended Step-Pyramid Periodic Table
Guide to the Extended Step-Pyramid Periodic Table William B. Jensen Department of Chemistry University of Cincinnati Cincinnati, OH 452201-0172 The extended step-pyramid table recognizes that elements
High-Speed Environmental Analysis Using the Agilent 7500cx with Integrated Sample Introduction System Discrete Sampling (ISIS DS)
High-Speed Environmental Analysis Using the Agilent 7500cx with Integrated Sample Introduction System Discrete Sampling (ISIS DS) Application Note Environmental Authors Steve Wilbur Agilent Technologies,
5 questions, 3 points each, 15 points total possible. 26 Fe Cu Ni Co Pd Ag Ru 101.
Physical Chemistry II Lab CHEM 4644 spring 2017 final exam KEY 5 questions, 3 points each, 15 points total possible h = 6.626 10-34 J s c = 3.00 10 8 m/s 1 GHz = 10 9 s -1. B= h 8π 2 I ν= 1 2 π k μ 6 P
Effect of Sampling Depth on the Analyte Response in Laser Ablation Inductively Coupled Plasma Mass Spectrometry
JLMN-Journal of Laser Micro/Nanoengineering Vol., No., Effect of Sampling Depth on the Analyte Response in Laser Ablation Inductively Coupled Plasma Mass Spectrometry Zhongke WANG *, Bodo Hattendorf and
Direct Measurement of Metallic Impurities in 20% Ammonium Hydroxide by 7700s/7900 ICP-MS
Direct Measurement of Metallic Impurities in 20% Ammonium Hydroxide by 7700s/7900 ICP-MS Application Note Semiconductor Authors Junichi Takahashi Agilent Technologies Tokyo, Japan Abstract Ammonium hydroxide
Sample Analysis Design PART II
Sample Analysis Design PART II Sample Analysis Design Generating high quality, validated results is the primary goal of elemental abundance determinations It is absolutely critical to plan an ICP-MS analysis
Radiometric Dating (tap anywhere)
Radiometric Dating (tap anywhere) Protons Neutrons Electrons Elements on the periodic table are STABLE Elements can have radioactive versions of itself called ISOTOPES!! Page 1 in your ESRT has your list!
Use of a Novel Array Detector for the Direct Analysis of Solid Samples by Laser Ablation Inductively Coupled Plasma Sector-Field Mass Spectrometry
Use of a Novel Array Detector for the Direct Analysis of Solid Samples by Laser Ablation Inductively Coupled Plasma Sector-Field Mass Spectrometry James H. Barnes, IV, Gregory D. Schilling, and Gary M.
Determination of Chromium in Gelatin Capsules using an Agilent 7700x ICP-MS
Determination of Chromium in Gelatin Capsules using an Agilent 7700x ICP-MS Application note Pharmaceutical Authors Miao Jing, Yingping Ni, Yanping Wang and Zhixu Zhang Agilent Technologies, China Introduction
Multi-Element Analysis of Petroleum Crude Oils using an Agilent 7900 ICP-MS
Multi-Element Analysis of Petroleum Crude Oils using an Agilent 7900 ICP-MS Application note Energy and fuels Authors Jenny Nelson, Agilent Technologies, USA Ed McCurdy, Agilent Technologies, UK Introduction
Determination of trace elements in ultrapure semiconductor grade sulfuric acid using the Agilent 8900 ICP-QQQ in MS/MS mode
Determination of trace elements in ultrapure semiconductor grade sulfuric acid using the Agilent 8900 ICP-QQQ in MS/MS mode Application note Semiconductor Authors Michiko Yamanaka, Kazuo Yamanaka and Naoki
Supporting Information. Facile design of phase separation for microfluidic. droplet-based liquid phase microextraction as a front end to
Supporting Information Facile design of phase separation for microfluidic droplet-based liquid phase microextraction as a front end to electrothermal vaporization-icpms for the analysis of trace metals
HANDOUT SET GENERAL CHEMISTRY II
HANDOUT SET GENERAL CHEMISTRY II Periodic Table of the Elements 1 2 3 4 5 6 7 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 IA VIIIA 1 2 H He 1.00794 IIA IIIA IVA VA VIA VIIA 4.00262 3 Li 6.941 11 Na 22.9898
Topic 3: Periodicity OBJECTIVES FOR TODAY: Fall in love with the Periodic Table, Interpret trends in atomic radii, ionic radii, ionization energies &
Topic 3: Periodicity OBJECTIVES FOR TODAY: Fall in love with the Periodic Table, Interpret trends in atomic radii, ionic radii, ionization energies & electronegativity The Periodic Table What is the periodic
1.0 ACCREDITATION / REGISTRATION 2.0 PRODUCT DESCRIPTION 3.0 CERTIFIED VALUES AND UNCERTAINTIES. Assay Information:
1.0 ACCREDITATION / REGISTRATION INORGANIC VENTURES is accredited to ISO Guide 34, "General Requirements for the Competence of Reference Material Producers" and ISO/IEC 17025, "General Requirements for
Sample Analysis Design Polyatomic Interferences
Sample Analysis Design Polyatomic Interferences More serious than isobaric interferences Result from possible, short-lived combination of atomic species in the plasma or during ion transfer Common recombinants
ORBITAL DIAGRAM - A graphical representation of the quantum number "map" of electrons around an atom.
160 ORBITAL DIAGRAM - A graphical representation of the quantum number "map" of electrons around an atom. 4p 3d 4s 3p 3s 2p 2s 1s Each blank represents an ORBITAL, and can hold two electrons. The 4s subshell
-"l" also contributes ENERGY. Higher values for "l" mean the electron has higher energy.
175 - Giving the four parameters will uniquely identify an electron around an atom. No two electrons in the same atom can share all four. These parameters are called QUANTUM NUMBERS. PRINCIPAL QUANTUM
The exam must be written in ink. No calculators of any sort allowed. You have 2 hours to complete the exam. Periodic table 7 0
Email: The exam must be written in ink. No calculators of any sort allowed. You have 2 hours to complete the exam. CEM 610B Exam 3 Spring 2002 Instructor: Dr. Brian Pagenkopf Page Points 2 6 3 7 4 9 5
All chemical bonding is based on the following relationships of electrostatics: 2. Each period on the periodic table
UNIT VIII ATOMS AND THE PERIODIC TABLE 25 E. Chemical Bonding 1. An ELECTROSTATIC FORCE is All chemical bonding is based on the following relationships of electrostatics: The greater the distance between
610B Final Exam Cover Page
1 st Letter of Last Name NAME: 610B Final Exam Cover Page No notes or calculators of any sort allowed. You have 3 hours to complete the exam. CHEM 610B, 50995 Final Exam Fall 2003 Instructor: Dr. Brian
Fast Analysis of Water Samples Comparing Axially-and Radially- Viewed CCD Simultaneous ICP-OES
Fast Analysis of Water Samples Comparing Axially-and Radially- Viewed CCD Simultaneous ICP-OES Application Note Inductively Coupled Plasma-Optical Emission Spectrometers Author Tran T. Nham Introduction
PERIODIC TABLE OF THE ELEMENTS
Useful Constants and equations: K = o C + 273 Avogadro's number = 6.022 x 10 23 d = density = mass/volume R H = 2.178 x 10-18 J c = E = h = hc/ h = 6.626 x 10-34 J s c = 2.998 x 10 8 m/s E n = -R H Z 2
CHEMICAL COMPOUNDS MOLECULAR COMPOUNDS
48 CHEMICAL COMPOUNDS - Dalton's theory does not mention this, but there is more than one way for atoms to come together to make chemical compounds! - There are TWO common kinds of chemical compound, classified
Laser Spectroscopy on Bunched Radioactive Ion Beams
Laser Spectroscopy on Bunched Radioactive Ion Beams Jon Billowes University of Manchester Balkan School on Nuclear Physics, Bodrum 2004 Lecture 1. 1.1 Nuclear moments 1.2 Hyperfine interaction in free
CHEM 130 Exp. 8: Molecular Models
CHEM 130 Exp. 8: Molecular Models In this lab, we will learn and practice predicting molecular structures from molecular formulas. The Periodic Table of the Elements IA 1 H IIA IIIA IVA VA VIA VIIA 3 5
Grade 11 Science Practice Test
Grade 11 Science Practice Test Nebraska Department of Education 2012 Directions: On the following pages of your test booklet are multiple-choice questions for Session 1 of the Grade 11 Nebraska State Accountability
INSTRUCTIONS: CHEM Exam I. September 13, 1994 Lab Section
CHEM 1314.05 Exam I John I. Gelder September 13, 1994 Name TA's Name Lab Section Please sign your name below to give permission to post, by the last 4 digits of your student I.D. number, your course scores
Multi Analyte Custom Grade Solution. Aluminum, Potassium, Magnesium, ANALYTE CERTIFIED VALUE ANALYTE CERTIFIED VALUE
1.0 ACCREDITATION / REGISTRATION INORGANIC VENTURES is accredited to ISO Guide 34, "General Requirements for the Competence of Reference Material Producers" and ISO/IEC 17025, "General Requirements for
RITU and the GREAT Spectrometer
RITU and the GREAT Spectrometer Cath Scholey Department of Physics University of Jyväskylä 19 th March 2006 3rd TASCA Detector Group Meeting, GSI Darmstadt C. Scholey (JYFL, Finland) RITU and the GREAT
Ar Ar + e - INDUCTIVELY+COUPLED+ PLASMA+SPECTROMETRY+ What+is+Plasma?+ FuncDon+of+Plasma+
INDUCTIVELY+COUPLED+ PLASMA+SPECTROMETRY+ Applied'Analy+cal'and'Inorganic'Chemistry'Program' Department'of'Chemistry,'Faculty'of'Science' Mahidol'University' What+is+Plasma?+ Ar Ar + e - Plasma is an ionized
Unit 1 Part 2 Atomic Structure and The Periodic Table Introduction to the Periodic Table UNIT 1 ATOMIC STRUCTURE AND THE PERIODIC TABLE
UNIT 1 ATOMIC STRUCTURE AND THE PERIODIC TABLE PART 2 INTRODUCTION TO THE PERIODIC TABLE Contents 1. The Structure of the Periodic Table 2. Trends in the Periodic Table Key words: group, period, block,
Introduction to LIBS COMMUNITY USER WORKSHOP ON PLANETARY LIBS (CHEMCAM) DATA. Sam Clegg and the ChemCam team
Lunar and Planetary Science Conference, March 18 th, 2015 NASA/JPL-Caltech/MSSS COMMUNITY USER WORKSHOP ON PLANETARY LIBS (CHEMCAM) DATA Introduction to LIBS Sam Clegg and the ChemCam team Creating LIBS
History of the Periodic Table
SECTION 5.1 History of the Periodic Table By 60, more than 60 elements had been discovered. Chemists had to learn the properties of these elements as well as those of the many compounds that the elements
PHYSICAL SCIENCES GRADE : 10
PHYSICAL SCIENCES GRADE : 0 TIME : hour TOTAL : 75 INSTRUCTIONS AND INFORMATION. Write your full name on your answer book in the appropriate place. 2. The question paper consists of SEVEN questions. Answer
Analysis of Trace Metal Impurities in High Purity Hydrochloric Acid Using ICP-QQQ
Application Note Semiconductor Analysis of Trace Metal Impurities in High Purity Hydrochloric Acid Using ICP-QQQ Authors Kazuo Yamanaka and Kazuhiro Sakai Agilent Technologies, Japan Introduction Hydrochloric
BROOKLYN COLLEGE Department of Chemistry. Chemistry 1 Second Lecture Exam Nov. 27, Name Page 1 of 5
BROOKLYN COLLEGE Department of Chemistry Chemistry 1 Second Lecture Exam Nov. 27, 2002 Name Page 1 of 5 Circle the name of your lab instructor Kobrak, Zhou, Girotto, Hussey, Du Before you begin the exam,
CLASS TEST GRADE 11. PHYSICAL SCIENCES: CHEMISTRY Test 4: Matter and materials 1
CLASS TEST GRADE PHYSICAL SCIENCES: CHEMISTRY Test 4: Matter and materials MARKS: 45 TIME: hour INSTRUCTIONS AND INFORMATION. Answer ALL the questions. 2. You may use non-programmable calculators. 3. You
Environmental and Geological Applications of Instrumental Neutron Activation Analysis. Department Environmental, Earth, & Atmospheric Sciences
Environmental and Geological Applications of Instrumental Neutron Activation Analysis Department Environmental, Earth, & Atmospheric Sciences Instrumental Neutron Activation Analysis is an obsolete analytical
Example: Helium has an atomic number of 2. Every helium atom has two protons in its nucleus.
59 Atomic terms - ATOMIC NUMBER: The number of protons in the atomic nucleus. Each ELEMENT has the SAME NUMBER OF PROTONS in every nucleus. In neutral atoms, the number of ELECTRONS is also equal to the
2 (27) 3 (26) 4 (21) 5 (18) 6 (8) Total (200) Periodic Table
Chem 3311 Sammakia Fall 2009 Midterm 1 Student ID page points: 2 (27) 3 (26) 4 (21) 5 (18) 6 (8) Total (200) Periodic Table e Li Be B C N O F Ne Na Mg Al Si P S Cl Ar K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn
Rapid Analysis of High-Matrix Environmental Samples Using the Agilent 7500cx ICP-MS. Application. Author. Abstract. Introduction.
Rapid Analysis of High-Matrix Environmental Samples Using the Agilent 7500cx ICP-MS Application Environmental Author Steven Wilbur Agilent Technologies, Inc. 3380 146th Place, SE, Suite 300 Bellevue, WA
lectures accompanying the book: Solid State Physics: An Introduction, by Philip ofmann (2nd edition 2015, ISBN-10: 3527412824, ISBN-13: 978-3527412822, Wiley-VC Berlin. www.philiphofmann.net 1 Bonds between
COMPARATIVE STUDY OF PIGE, PIXE AND NAA ANALYTICAL TECHNIQUES FOR THE DETERMINATION OF MINOR ELEMENTS IN STEELS
COMPARATIVE STUDY OF PIGE, PIXE AND NAA ANALYTICAL TECHNIQUES FOR THE DETERMINATION OF MINOR ELEMENTS IN STEELS ANTOANETA ENE 1, I. V. POPESCU 2, T. BÃDICÃ 3, C. BEªLIU 4 1 Department of Physics, Faculty
Give the number of protons, neutrons and electrons in this atom of aluminium. Why is aluminium positioned in Group 3 of the periodic table? ...
Q1.An atom of aluminium has the symbol (a) Give the number of protons, neutrons and electrons in this atom of aluminium. Number of protons... Number of neutrons... Number of electrons... (3) (b) Why is
ICP/MS Multi-Element Standards
Standards Ultra Pure Matrix Special Packaging Traceability to National Reference Materials AccuStandard s ICP/MS Standards are formulated to meet the needs of this very special instrument. As matrix effect
Reporting Category 1: Matter and Energy
Name: Science Teacher: Reporting Category 1: Matter and Energy Atoms Fill in the missing information to summarize what you know about atomic structure. Name of Subatomic Particle Location within the Atom
Semiquantitative Screening of Pharmaceutical Antiviral Drugs using the Agilent 7500ce ICP-MS in Helium Collision Mode
Semiquantitative Screening of Pharmaceutical Antiviral Drugs using the Agilent 7500ce ICP-MS in Helium Collision Mode Application Note Pharmaceutical Authors Rebeca Santamaria-Fernandez, SheilaMerson,
CHEMICAL COMPOUNDS MOLECULAR COMPOUNDS
48 CHEMICAL COMPOUNDS - Dalton's theory does not mention this, but there is more than one way for atoms to come together to make chemical compounds! - There are TWO common kinds of chemical compound, classified
... but using electron configurations to describe how aluminum bromide forms is a bit cumbersome! Can we simplify the picture a bit?
193... but using electron configurations to describe how aluminum bromide forms is a bit cumbersome! Can we simplify the picture a bit? LEWIS NOTATION / ELECTRON-DOT NOTATION - Lewis notation represents
Earth Materials I Crystal Structures
Earth Materials I Crystal Structures Isotopes same atomic number, different numbers of neutrons, different atomic mass. Ta ble 1-1. Su mmar y of quantu m num bers Name Symbol Values Principal n 1, 2,
Chapter 12 The Atom & Periodic Table- part 2
Chapter 12 The Atom & Periodic Table- part 2 Electrons found outside the nucleus; negatively charged Protons found in the nucleus; positive charge equal in magnitude to the electron s negative charge Neutrons
Lewis dot structures for molecules
1 Lewis dot structures for molecules In the dot structure of a molecule, - SHARED valence electrons are shown with dashes - one per pair. - UNSHARED valence electrons ("lone pairs") are represented by
Chem Exam 1. September 26, Dr. Susan E. Bates. Name 9:00 OR 10:00
Chem 1711 Exam 1 September 26, 2013 Dr. Susan E. Bates Name 9:00 OR 10:00 N A = 6.022 x 10 23 mol 1 I A II A III B IV B V B VI B VII B VIII I B II B III A IV A V A VI A VII A inert gases 1 H 1.008 3 Li
Agilent Technologies at TIAFT 2013
Agilent Technologies at TIAFT 2013 Analytical approaches for the measurement of trace metals in forensic samples Funchal, Madeira September 2-6 CRIMINALISTIC TOXICOLOGY DNA INVESTIGATION DOCUMENT EXAMINATION
high temp ( K) Chapter 20: Atomic Spectroscopy
high temp (2000-6000K) Chapter 20: Atomic Spectroscopy 20-1. An Overview Most compounds Atoms in gas phase high temp (2000-6000K) (AES) (AAS) (AFS) sample Mass-to-charge (ICP-MS) Atomic Absorption experiment
Chapter 3: Elements and Compounds. 3.1 Elements
Chapter 3: Elements and Compounds 3.1 Elements An element is a fundamental substance that cannot be broken down by chemical or physical methods to simpler substances. The 118 known elements are nature
The Periodic Table of Elements
The Periodic Table of Elements 8 Uuo Uus Uuh (9) Uup (88) Uuq (89) Uut (8) Uub (8) Rg () 0 Ds (9) 09 Mt (8) 08 Hs (9) 0 h () 0 Sg () 0 Db () 0 Rf () 0 Lr () 88 Ra () 8 Fr () 8 Rn () 8 At (0) 8 Po (09)
Chemistry 431 Practice Final Exam Fall Hours
Chemistry 431 Practice Final Exam Fall 2018 3 Hours R =8.3144 J mol 1 K 1 R=.0821 L atm mol 1 K 1 R=.08314 L bar mol 1 K 1 k=1.381 10 23 J molecule 1 K 1 h=6.626 10 34 Js N A = 6.022 10 23 molecules mol
Chapter 8: An Introduction to Optical Atomic Spectrometry
Chapter 8: An Introduction to Optical Atomic Spectrometry Sample is atomized (gaseous atoms/ions) absorption or emission measured Optical Atomic Spectra Atomization Methods Sample Introduction Methods
9/20/2017. Elements are Pure Substances that cannot be broken down into simpler substances by chemical change (contain Only One Type of Atom)
CAPTER 6: TE PERIODIC TABLE Elements are Pure Substances that cannot be broken down into simpler substances by chemical change (contain Only One Type of Atom) The Periodic Table (Mendeleev) In 1872, Dmitri
Trace Metal Dynamic Extraction from Five Pumps in Hydrochloric Acid. Submitted to: Reto Schoeb Levitronix GmbH. Submitted by:
CT Associates, Inc. 72 Shady Oak Road, Eden Prairie, MN 55344-356 Telephone: (952) 470-066 Fax: (952) 942-0293 Website: http://www.ctassociatesinc.com Trace Metal Dynamic Extraction from Five Pumps in
U.S. EPA SW-846 Method 6010C using the Prodigy High Dispersion ICP
Prodigy ICP Application Note: 1035 U.S. EPA SW-846 Method 6010C using the Prodigy High Dispersion ICP Introduction This Application Note describes the capability of the Teledyne Leeman Labs Prodigy High
Made the FIRST periodic table
Made the FIRST periodic table 1869 Mendeleev organized the periodic table based on the similar properties and relativities of certain elements Later, Henri Moseley organized the elements by increasing
INTRODUCTION TO MEASUREMENTS
INTRODUCTION TO MEASUREMENTS Introduction: In the first three experiments you will learn how to use equipment that to measure length, mass, and volume. You will apply the rules about significant figures
Secondary Support Pack. be introduced to some of the different elements within the periodic table;
Secondary Support Pack INTRODUCTION The periodic table of the elements is central to chemistry as we know it today and the study of it is a key part of every student s chemical education. By playing the
CHEM 10113, Quiz 5 October 26, 2011
CHEM 10113, Quiz 5 October 26, 2011 Name (please print) All equations must be balanced and show phases for full credit. Significant figures count, show charges as appropriate, and please box your answers!
What monitoring techniques are appropriate and effective for detecting CO2 migration in groundwater: isotope-based monitoring Philippe Négrel
What monitoring techniques are appropriate and effective for detecting CO2 migration in groundwater: isotope-based monitoring Philippe Négrel Acting in complicity with Pauline Humez. Results from Pauline
Solutions and Ions. Pure Substances
Class #4 Solutions and Ions CHEM 107 L.S. Brown Texas A&M University Pure Substances Pure substance: described completely by a single chemical formula Fixed composition 1 Mixtures Combination of 2 or more
Ion-beam techniques. Ion beam. Electrostatic Accelerators. Van de Graaff accelerator Pelletron Tandem Van de Graaff
Ion-beam techniques RBS Target nucleus Ion beam STIM RBS: Rutherford backscattering ERD: Elastic recoil detection PIXE: Particle induced x-ray emission PIGE: Particle induced gamma emission NRA: Nuclear
8. Relax and do well.
CHEM 1515 Exam II John II. Gelder October 14, 1993 Name TA's Name Lab Section INSTRUCTIONS: 1. This examination consists of a total of 8 different pages. The last two pages include a periodic table, a
02/05/09 Last 4 Digits of USC ID: Dr. Jessica Parr
Chemistry 05 B First Letter of PLEASE PRINT YOUR NAME IN BLOCK LETTERS Exam last Name Name: 02/05/09 Last 4 Digits of USC ID: Dr. Jessica Parr Lab TA s Name: Question Points Score Grader 2 2 9 3 9 4 2
Atomic weight: This is a decimal number, but for radioactive elements it is replaced with a number in parenthesis.
47 Blocks on the periodic table 11 Sodium 22.99 Atomic number: This is always a whole number. The periodic table is arranged by atomic number! Element symbol: A one or two letter abbreviation for the name