PV = nrt where R = universal gas constant
|
|
- Nelson Thomas
- 6 years ago
- Views:
Transcription
1 Ideal Gas Law Dd Deduced dfrom Combination of Gas Relationships: V 1/P, Boyle's Law V, Charles's Law V n, Avogadro'sLaw Therefore, V nt/p or PV nt PV = nrt where R = universal gas constant The empirical Equation of State for an Ideal Gas
2 Ideal Gas Equation of State
3 Ideal Gas Law PV = nrt where R = universal gas constant R = PV/nT R = atm L mol 1 K 1 R = atm dm 3 mol 1 K 1 R = J mol 1 K 1 (SI unit) Standard molar volume = 22.4 L mol 1 at 0 C and 1 atm Real gases approach ideal gas behavior at low P & high T
4 ConcepTest #1 One mole of ice is similar in volume to A. The Lambert Glacier B. The iceberg that sank the Titanic C. The ice of the CU skating rink D. An ice cube in a cold drink E. A snowflake
5 ConcepTest #1 One mole of ice is similar in volume to A. The Lambert Glacier B. The iceberg that sank the Titanic C. The ice of the CU skating rink D. An ice cube in a cold drink E. A snowflake
6 ConcepTest #2 A steel vessel contains 1 mole of gas at 100K. 2 moles of gas are added and the temperature is increased to 200K. How does the pressure change? A. P increases by a factor of 4 B. P decreases by a factor of 4 C. P increases by a factor of 6 D. P decreases by a factor of 6 E. P does not change
7 ConcepTest #2 A steel vessel contains 1 mole of gas at 100K. 2 moles of gas are added and the temperature is increased to 200K. How does the pressure change? A. P increases by a factor of 4 B. P decreases by a factor of 4 C. P increases by a factor of 6 D. P decreases by a factor of 6 E. P does not change
8 ConcepTest #3 An ideal gas is compressed at constant temperature. Which picture below best describes how the volume V of the gas behaves as the pressure P is increased? A V B V P P C V D V P P
9 Dalton slaw Definition: Partial pressure P i is the pressure exerted by one component of a gas mixture (at total pressure P t ) P i = x i P t where x i is the mole fraction (x i = n i /n total ) Dalton s Law: P t = P 1 +P 2 +P P i The total pressure is equal to the sum of the partial pressures that each individual component gas would exert if it were alone
10 ConcepTest #4 A mixture of gases contains 4 g of He and 4 g of H 2. The total pressure is 300 Pa. What is the partial pressure of helium? A. 100 Pa B. 150 Pa C. 200 Pa D. 250 Pa
11 ConcepTest #4 A mixture of gases contains 4 g of He and 4 g of H 2. The total pressure is 300 Pa. What is the partial pressure of helium? A. 100 Pa B. 150 Pa C. 200 Pa D. 250 Pa
12 Graham s Law of Effusion Effusion is the movement of gases through small passages (e.g., passing through a plug of fine sand) where essentially all collisions are between gas and sand This feels like something where the faster you go, the faster you get through the maze, so we might expect an effusion rate velocity. Graham observed that for gases A and B Rate(A)/Rate(B) = [M(B)/M(A)] 1/2 The rate of effusion of a gas is inversely proportional to the square root of its molar mass (M)
13 Real Gases Compressibility, Z Z PV PV nrt RT Z = 1 Ideal Gas behavior Z < 1 PV less than expected Attractive forces Z > 1 PV greater than expected Repulsive forces Z Ar 1 Ideal Gas P
14 Real Gases data! Compressibility Z PV nrt
15 Boyle Temperature, T B Temperature of greatest extent of near-ideal behavior. We can determine T B analytically. Z T, P P df dt lim p 0 f T 0 at T T, the Boyle temperature t B
16 Real Gases CO 2 Look at 20 C isotherm. A B C Compression At C, liquid condensation begins D liquid- vapor mixture at P vap (20 C) E last vapor condenses F Steep rise in pressure A liquid or solid is much less compressible than a gas For T >T there is a single phase For T >T c, there is a single phase, with no liquid formed.
17 van der Waals equation of state Physically-motivated y y corrections to Ideal Gas EoS. For a real gas, both attractive and repulsive intermolecular forces are present. Empirical terms were developed to help account for both. 1. Repulsive forces: make pressure higher than ideal gas Excluded volume P nrt V nb Volume of one molecule of radius r is V m = 4/3 r 3 Closest approach of two molecules with radius r is 2r.
18 ConcepTest #5 nrt Excluded volume P V nb The volume of one molecule of radius r is V m = 4/3 r 3 The closest approach of two molecules l with radius r is 2r. What is the excluded volume for the two molecules? A. 2V m B. 4V m C. 8V m D. 16 V m
19 van der Waals equation of state Physically-motivated y y corrections to Ideal Gas EoS. For a real gas, both attractive and repulsive intermolecular forces are present. Empirical terms were developed to help account for both. 1. Repulsive forces: make pressure higher than ideal gas nrt Excluded volume P V nb Volume of one molecule of radius r is V m = 4/3 r 3 Closest approach of two molecules with radius r is 2r. The excluded volume V exc is 2 3 V m = 8V m for two molecules. b 4V N So we estimate that m A
20 van der Waals equation of state Physically-motivated y y corrections to Ideal Gas EoS. For a real gas, both attractive and repulsive intermolecular forces are present. Empirical terms were developed to help account for both. 2. Attractive forces: make pressure lower than ideal gas Pressure depends wall collisions, both on frequency and their force. Both scale as n/v, so we expect a pressure correction of the form a(n/v) 2, giving the van der Waals Equation of State 2 nrt an RT a P V nb V V b V 2 2
21 3D van der Waals eqn of state T= T/Tc
22 van der Waals Isotherms near T c v d W loops are not physical. Why? Patch up with Maxwell construction van der Waals Isotherms, T/T c
23 van der Waals Isotherms near T c Look at one of the van der Waals isotherms at a temperature re of 0.9 T c 1.5 G A D compress the gas at constant T, F G compress the liquid phase (steep and not very compressible) D F vapor condensing (gas and liquid coexist) These are stable states Reduced Pre essure, P r F C B g, l D T r = 0.9 A F C super cooled liquid D B superheated gas These are metastable t states tt Reduced d Volume, V r Metastable example: C B a non physical artifact of VdW Use a very clean glass. Add water and heat (patched up with Maxwell construction) for a while with a microwave oven (superheat) eat) Add a drop of sand or perhaps touch with a spoon.
24 Real Gases van der Waals EoS P an2 2 V nb nrt V Condensation Supercritical Fluid Solid Liquid fluid with T>T c, P>P c We can use vdw EoS to approximate features. E.g., P C V T C C a 2 27b 3 bn 8a 27bR P Triple point T SCF Critical point Gas T c P c
25 Critical Constants of Real Gases Notice that Z c is essentially 0.3 for all gases, while the other critical properties can be very different from each other. There is a lesson to learn here. We might think about looking at T and P in terms of reduced parameters: P r = P/P c and V r = V/V c
26 Critical Constants of Real Gases T r = T/T c
27 Next Steps... We have not invoked any molecular properties. It is as though the various gases were just different, structureless fluids. We will now change that!
van der Waals Isotherms near T c
van der Waals Isotherms near T c v d W loops are not physical. Why? Patch up with Maxwell construction van der Waals Isotherms, T/T c van der Waals Isotherms near T c Look at one of the van der Waals isotherms
More informationLecture Presentation. Chapter 10. Gases. John D. Bookstaver St. Charles Community College Cottleville, MO Pearson Education, Inc.
Lecture Presentation Chapter 10 John D. Bookstaver St. Charles Community College Cottleville, MO Characteristics of Unlike liquids and solids, gases Expand to fill their containers. Are highly compressible.
More informationChapter 1. The Properties of Gases Fall Semester Physical Chemistry 1 (CHM2201)
Chapter 1. The Properties of Gases 2011 Fall Semester Physical Chemistry 1 (CHM2201) Contents The Perfect Gas 1.1 The states of gases 1.2 The gas laws Real Gases 1.3 Molecular interactions 1.4 The van
More informationAP Chemistry Ch 5 Gases
AP Chemistry Ch 5 Gases Barometer - invented by Evangelista Torricelli in 1643; uses the height of a column of mercury to measure gas pressure (especially atmospheric) Manometer- a device for measuring
More informationChapter Elements That Exist as Gases at 25 C, 1 atm. 5.2 Pressure basic physics. Gas Properties
5.1 Elements That Exist as Gases at 25 C, 1 atm Chapter 5 The Gaseous State YOU READ AND BE RESPONSIBLE FOR THIS SECTION! Gaseous compounds include CH 4, NO, NO 2, H 2 S, NH 3, HCl, etc. Gas Properties
More informationUNIT 10.
UNIT 10 Pressure: F/A http://chemlab.truman.edu/chem130labs/calorimetryfiles/thermobackground.asp There are four variable needed to define the physical state of a gas. They are: o Temperature o Pressure
More informationThe Kinetic-Molecular Theory of Gases
The Kinetic-Molecular Theory of Gases kinetic-molecular theory of gases Originated with Ludwig Boltzman and James Clerk Maxwell in the 19th century Explains gas behavior on the basis of the motion of individual
More informationPart One: The Gas Laws. gases (low density, easy to compress)
CHAPTER FIVE: THE GASEOUS STATE Part One: The Gas Laws A. Introduction. 1. Comparison of three states of matter: fluids (flow freely) solids condensed states liquids (high density, hard to compress) gases
More informationGases. Characteristics of Gases. Unlike liquids and solids, gases
Gases Characteristics of Gases Unlike liquids and solids, gases expand to fill their containers; are highly compressible; have extremely low densities. 1 Pressure Pressure is the amount of force applied
More information1. What is the value of the quantity PV for one mole of an ideal gas at 25.0 C and one atm?
Real Gases Thought Question: How does the volume of one mole of methane gas (CH4) at 300 Torr and 298 K compare to the volume of one mole of an ideal gas at 300 Torr and 298 K? a) the volume of methane
More informationGASES (Chapter 5) Temperature and Pressure, that is, 273 K and 1.00 atm or 760 Torr ) will occupy
I. Ideal gases. A. Ideal gas law review. GASES (Chapter 5) 1. PV = nrt Ideal gases obey this equation under all conditions. It is a combination ofa. Boyle's Law: P 1/V at constant n and T b. Charles's
More informationImperfect Gases. NC State University
Chemistry 431 Lecture 3 Imperfect Gases NC State University The Compression Factor One way to represent the relationship between ideal and real gases is to plot the deviation from ideality as the gas is
More informationLecture Presentation. Chapter 10. Gases. James F. Kirby Quinnipiac University Hamden, CT Pearson Education, Inc.
Lecture Presentation Chapter 10 James F. Kirby Quinnipiac University Hamden, CT Characteristics of Physical properties of gases are all similar. Composed mainly of nonmetallic elements with simple formulas
More informationGases. Chapter 5. Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
Gases Chapter 5 Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display. 1 Elements that exist as gases at 25 0 C and 1 atmosphere 2 3 Physical Characteristics of Gases
More informationChapter 10. Gases. Chemistry, The Central Science, 11th edition Theodore L. Brown; H. Eugene LeMay, Jr.; and Bruce E. Bursten
Chemistry, The Central Science, 11th edition Theodore L. Brown; H. Eugene LeMay, Jr.; and Bruce E. Bursten Chapter 10 John Bookstaver St. Charles Community College Cottleville, MO Characteristics of Unlike
More informationChapter 10. Gases. Chemistry, The Central Science, 10th edition Theodore L. Brown; H. Eugene LeMay, Jr.; and Bruce E. Bursten
Chemistry, The Central Science, 10th edition Theodore L. Brown; H. Eugene LeMay, Jr.; and Bruce E. Bursten Chapter 10 John Bookstaver St. Charles Community College St. Peters, MO 2006, Prentice Hall, Inc.
More informationReal Gases. Sections (Atkins 6th Ed.), (Atkins 7-9th Eds.)
Real Gases Sections 1.4-1.6 (Atkins 6th Ed.), 1.3-1.5 (Atkins 7-9th Eds.) Molecular Interactions Compression factor Virial coefficients Condensation Critical Constants Van der Waals Equation Corresponding
More informationChapter 10. Chapter 10 Gases
Chapter 10 Gases Earth is surrounded by a layer of gaseous molecules - the atmosphere - extending out to about 50 km. 10.1 Characteristics of Gases Gases low density; compressible volume and shape of container
More informationGases. A gas. Difference between gas and vapor: Why Study Gases?
Gases Chapter 5 Gases A gas Uniformly fills any container. Is easily compressed. Mixes completely with any other gas. Exerts pressure on its surroundings. Difference between gas and vapor: A gas is a substance
More informationExample Problems: 1.) What is the partial pressure of: Total moles = 13.2 moles 5.0 mol A 7.0 mol B 1.2 mol C Total Pressure = 3.
5.6 Dalton s Law of Partial Pressures Dalton s Law of Partial Pressure; The total pressure of a gas is the sum of all its parts. P total = P 1 + P + P 3 + P n Pressures are directly related to moles: n
More informationGas Laws. Gas Properties. Gas Properties. Gas Properties Gases and the Kinetic Molecular Theory Pressure Gas Laws
Gas Laws Gas Properties Gases and the Kinetic Molecular Theory Pressure Gas Laws Gas Properties 1) Gases have mass - the density of the gas is very low in comparison to solids and liquids, which make it
More informationGases and Kinetic Theory
Gases and Kinetic Theory Chemistry 35 Fall 2000 Gases One of the four states of matter Simplest to understand both physically and chemically Gas Properties Low density Fluid Can be defined by their: 1.
More informationQuick Review 1. Properties of gases. 2. Methods of measuring pressure of gases. 3. Boyle s Law, Charles Law, Avogadro s Law. 4. Ideal gas law.
Quick Review 1. Properties of gases. 2. Methods of measuring pressure of gases. 3. Boyle s Law, Charles Law, Avogadro s Law. 4. Ideal gas law. 5. Dalton s law of partial pressures. Kinetic Molecular Theory
More informationChapter 10. Gases. The Gas Laws
Page 1 of 12 10.1 Characteristics of Gases. Chapter 10. Gases. All substances have three phases; solid, liquid and gas. Substances that are liquids or solids under ordinary conditions may also exist as
More informationGases. T boil, K. 11 gaseous elements. Rare gases. He, Ne, Ar, Kr, Xe, Rn Diatomic gaseous elements H 2, N 2, O 2, F 2, Cl 2
Gases Gas T boil, K Rare gases 11 gaseous elements He, Ne, Ar, Kr, Xe, Rn 165 Rn 211 N 2 O 2 77 F 2 90 85 Diatomic gaseous elements Cl 2 238 H 2, N 2, O 2, F 2, Cl 2 H 2 He Ne Ar Kr Xe 20 4.4 27 87 120
More informationKINETIC MOLECULAR DESCRIPTION OF THE STATES OF MATTER
KINETIC MOLECULAR DESCRIPTION OF THE STATES OF MATTER CHAPTER 9 The Gaseous State CHAPTER 10 Solids, Liquids, and Phase Transitions CHAPTER 11 Solutions 392 Gas Liquid Solid 9 THE GASEOUS STATE 9.1 The
More informationThe Kinetic-Molecular Theory of Gases
The Kinetic-Molecular Theory of Gases kinetic-molecular theory of gases Originated with Ludwig Boltzman and James Clerk Maxwell in the 19th century Explains gas behavior on the basis of the motion of individual
More informationRate of Heating and Cooling
Rate of Heating and Cooling 35 T [ o C] Example: Heating and cooling of Water E 30 Cooling S 25 Heating exponential decay 20 0 100 200 300 400 t [sec] Newton s Law of Cooling T S > T E : System S cools
More informationChapter 5 The Gaseous State
Chapter 5 The Gaseous State Contents and Concepts Gas Laws We will investigate the quantitative relationships that describe the behavior of gases. 1. Gas Pressure and Its Measurement 2. Empirical Gas Laws
More informationGases: Their Properties & Behavior. Chapter 09 Slide 1
9 Gases: Their Properties & Behavior Chapter 09 Slide 1 Gas Pressure 01 Chapter 09 Slide 2 Gas Pressure 02 Units of pressure: atmosphere (atm) Pa (N/m 2, 101,325 Pa = 1 atm) Torr (760 Torr = 1 atm) bar
More informationChapter 11 Gases 1 Copyright McGraw-Hill 2009
Chapter 11 Gases Copyright McGraw-Hill 2009 1 11.1 Properties of Gases The properties of a gas are almost independent of its identity. (Gas molecules behave as if no other molecules are present.) Compressible
More informationPressure. Pressure Units. Molecular Speed and Energy. Molecular Speed and Energy
Pressure is defined as force per unit area. Pressure Pressure is measured with a device called a barometer. A mercury barometer uses the weight of a column of Hg to determine the pressure of gas pushing
More informationAdiabatic Expansion/Compression
Adiabatic Expansion/Compression Calculate the cooling in a the reversible adiabatic expansion of an ideal gas. P P 1, 1, T 1 A du q w First Law: Since the process is adiabatic, q = 0. Also w = -p ex d
More informationChapter 10. Gases THREE STATES OF MATTER. Chapter 10 Problems 6/29/2012. Problems 16, 19, 26, 33, 39,49, 57, 61
Chemistry, The Central Science, 11th edition Theodore L. Brown; H. Eugene LeMay, Jr.; and Bruce E. Bursten Chapter 10 John Bookstaver St. Charles Community College Cottleville, MO Chapter 10 Problems Problems
More informationChemistry 11. Unit 11 Ideal Gas Law (Special Topic)
Chemistry 11 Unit 11 Ideal Gas Law (Special Topic) 2 1. States of substances It has been studied in Unit 3 that there exist 3 states of matter in nature: gas, liquid and solid. (Technically there is the
More informationOUTLINE. States of Matter, Forces of Attraction Phase Changes Gases The Ideal Gas Law Gas Stoichiometry
UNIT 6 GASES OUTLINE States of Matter, Forces of Attraction Phase Changes Gases The Ideal Gas Law Gas Stoichiometry STATES OF MATTER Remember that all matter exists in three physical states: Solid Liquid
More informationGases. Which elements exist as gases at ordinary temperature and pressure? Gases: Have simple molecular formulas. Chapter 10 part 1: Ideal Gases
Chapter 10 part 1: Ideal Gases Read: BLB 10.1 5 HW: BLB 10.2,19a,b, 23, 26, 30, 39, 41, 45, 49 Sup 10:1 6 Know: What is pressure? Gases Which elements exist as gases at ordinary temperature and pressure?
More informationMixture of gases. Mix 5 moles of CO 2 V = 40L 2 moles of N 2 T = 0 C 1 mole of Cl 2 What is P? Mary J. Bojan Chem 110
Mixture of gases Mix 5 moles of CO 2 V = 40L 2 moles of N 2 T = 0 C 1 mole of Cl 2 What is P? 1 Partial Pressure Partial pressure: the pressure a gas would have if it was the only gas in the container.
More informationChapter 10. Gases. Characteristics of Gases. Units of Pressure. Pressure. Manometer. Units of Pressure 27/07/2014 P = F A
7/07/014 Chemistry, The Central Science, 11th edition Theodore L. Brown; H. Eugene LeMay, Jr.; and Bruce E. Bursten Characteristics of Chapter 10 Unlike liquids and solids, gases expand to fill their containers;
More informationChemistry, The Central Science, 10th edition Theodore L. Brown; H. Eugene LeMay, Jr.; and Bruce E. Bursten. Chapter 10. Gases.
Chemistry, The Central Science, 10th edition Theodore L. Brown; H. Eugene LeMay, Jr.; and Bruce E. Bursten Chapter 10 Characteristics of Unlike liquids and solids, they Expand to fill their containers.
More informationSummary of Gas Laws V T. Boyle s Law (T and n constant) Charles Law (p and n constant) Combined Gas Law (n constant) 1 =
Summary of Gas Laws Boyle s Law (T and n constant) p 1 V 1 = p 2 V 2 Charles Law (p and n constant) V 1 = T 1 V T 2 2 Combined Gas Law (n constant) pv 1 T 1 1 = pv 2 T 2 2 1 Ideal Gas Equation pv = nrt
More informationFig Note the three different types of systems based on the type of boundary between system and surroundings.
CHAPTER 1 LECTURE NOTES System, Surroundings, and States Fig. 1.4 Note the three different types of systems based on the type of boundary between system and surroundings. Intensive and Extensive Properties
More informationStates of Matter Lesson 3.6 CHEMISTRY 2 HONORS. Jeff Venables Northwestern High School
States of Matter Lesson 3.6 CHEMISTRY HONORS Molecular Effusion and Diffusion As kinetic energy increases, the velocity of the gas molecules increases. Average kinetic energy of a gas is related to its
More informationChapter 5 Gases and the Kinetic-Molecular Theory
Chapter 5 Gases and the Kinetic-Molecular Theory Name (Formula) Methane (CH 4 ) Ammonia (NH 3 ) Chlorine (Cl 2 ) Oxygen (O 2 ) Ethylene (C 2 H 4 ) Origin and Use natural deposits; domestic fuel from N
More informationGases. Measuring Temperature Fahrenheit ( o F): Exceptions to the Ideal Gas Law. Kinetic Molecular Theory
Ideal gas: a gas in which all collisions between atoms or molecules are perfectly elastic (no energy lost) there are no intermolecular attractive forces Think of an ideal gas as a collection of perfectly
More informationLecture Presentation. Chapter 10. Gases. James F. Kirby Quinnipiac University Hamden, CT Pearson Education
Lecture Presentation Chapter 10 2015 Pearson Education James F. Kirby Quinnipiac University Hamden, CT Characteristics of Physical properties of gases are all similar. Composed mainly of nonmetallic elements
More informationChapter 10 Notes: Gases
Chapter 10 Notes: Gases Watch Bozeman Videos & other videos on my website for additional help: Big Idea 2: Gases 10.1 Characteristics of Gases Read p. 398-401. Answer the Study Guide questions 1. Earth
More informationGeneral Properties of Gases
Page III-9-1 / Chapter Nine Lecture Notes Gases and Their Properties Chapter 9 Importance of Gases Chemistry 222 Professor Michael Russell Airbags fill with N 2 gas in an accident. Gas is generated by
More informationA Gas Uniformly fills any container. Easily compressed. Mixes completely with any other gas. Exerts pressure on its surroundings.
Chapter 5 Gases Chapter 5 A Gas Uniformly fills any container. Easily compressed. Mixes completely with any other gas. Exerts pressure on its surroundings. Copyright Cengage Learning. All rights reserved
More informationGaseous States of Matter
Gaseous States of Matter Semester-1 : ICY-101: CHEMISTRY-I, Unit III Dr. Tapta Kanchan Roy Assistant Professor Department of Chemistry & Chemical Sciences Central University of Jammu 1 The simplest state
More informationThis should serve a s a study guide as you go on to do the problems in Sapling and take the quizzes and exams.
CHM 111 Chapter 9 Worksheet and Study Guide Purpose: This is a guide for your as you work through the chapter. The major topics are provided so that you can write notes on each topic and work the corresponding
More informationGases and Kinetic Molecular Theory
1 Gases and Kinetic Molecular Theory 1 CHAPTER GOALS 1. Comparison of Solids, Liquids, and Gases. Composition of the Atmosphere and Some Common Properties of Gases 3. Pressure 4. Boyle s Law: The Volume-Pressure
More informationProperties of Gases. 5 important gas properties:
Gases Chapter 12 Properties of Gases 5 important gas properties: 1) Gases have an indefinite shape 2) Gases have low densities 3) Gases can compress 4) Gases can expand 5) Gases mix completely with other
More informationTOPIC 2. Topic 2. States of Matter (I) - Gases. 1
Chemistry TOPIC 2 States of Matter (I) - Gases Topic 2. States of Matter (I) - Gases. 1 Contents 1. Introduction 2. Pressure measurement 3. The Ideal Gas equation 4. Efusion and Diffusion 5. Kinetic Molecular
More informationStandard T & P (STP) At STP, 1 mol of any ideal gas occupies 22.4 L. The standard temperature and pressure for gases is:
Standard T & P (STP) The standard temperature and pressure for gases is: At STP, 1 mol of any ideal gas occupies 22.4 L T = 273 K (0 o C) P = 1 atm = 101.325 kpa = 1.01325 bar 22.4 L Using STP in problems
More informationLBS 172 Exam 1 Review
Chapter 12- Gases LBS 172 Exam 1 Review I. What is a gas? a. Properties i. Non-definite volume, fills container, can flow, spread out, can be compressed b. Air is a gas composed of many gases i. Relatively
More informationWhy study gases? A Gas 10/17/2017. An understanding of real world phenomena. An understanding of how science works.
Kinetic Theory and the Behavior of Ideal & Real Gases Why study gases? n understanding of real world phenomena. n understanding of how science works. Gas Uniformly fills any container. Mixes completely
More informationChapter 5. The Properties of Gases. Gases and Their Properties. Why Study Gases? Gas Pressure. some very common elements exist in a gaseous state
Chapter 5 Gases and Their Properties Why Study Gases? some very common elements exist in a gaseous state our gaseous atmosphere provides one means of transferring energy and material throughout the globe
More information10/15/2015. Why study gases? An understanding of real world phenomena. An understanding of how science works.
0/5/05 Kinetic Theory and the Behavior of Ideal & Real Gases Why study gases? An understanding of real world phenomena. An understanding of how science works. 0/5/05 A Gas fills any container. completely
More informationC H E M 1 CHEM 101-GENERAL CHEMISTRY CHAPTER 5 GASES INSTR : FİLİZ ALSHANABLEH
C H E M 1 CHEM 101-GENERAL CHEMISTRY CHAPTER 5 GASES 0 1 INSTR : FİLİZ ALSHANABLEH CHAPTER 5 GASES Properties of Gases Pressure History and Application of the Gas Laws Partial Pressure Stoichiometry of
More informationChapter 5 The Gaseous State
Chapter 5 The Gaseous State Contents and Concepts Gas Laws We will investigate the quantitative relationships that describe the behavior of gases. 1. Gas Pressure and Its Measurement 2. Empirical Gas Laws
More informationChapter 7. Gases, liquids, and solids. Water coexisting in three states H 2 O (g) in air H 2 O (l) ocean H 2 O (s) iceberg
Chapter 7 Gases, liquids, and solids Water coexisting in three states H 2 O (g) in air H 2 O (l) ocean H 2 O (s) iceberg What s crack a lackin? Kinetic-molecular theory of gases Physical states and the
More informationB 2, C 2, N 2. O 2, F 2, Ne 2. Energy order of the p 2p and s 2p orbitals changes across the period.
Chapter 11 Gases Energy order of the p p and s p orbitals changes across the period. Due to lower nuclear charge of B, C & N there is no s-p orbitals interaction Due to high nuclear charge of O, F& Ne
More informationStates of Matter. The Solid State. Particles are tightly packed, very close together (strong cohesive forces) Low kinetic energy (energy of motion)
States of Matter The Solid State Particles are tightly packed, very close together (strong cohesive forces) Low kinetic energy (energy of motion) Fixed shape and volume Crystalline or amorphous structure
More informationReal Gases 1. The value of compressibility factor for one mole of a gas under critical states is 1) 3/8 2) 2/3 3) 8/27 4) 27/8 2. an der Waal s equation for one mole of CO2 gas at low pressure will be
More informationChapter Ten- Gases. STUDY GUIDE AP Chemistry
STUDY GUIDE AP Chemistry Chapter Ten- Gases Lecture Notes 10.1 Characteristics of Gases All substances have three phases: solid, liquid and gas. Substances that are liquids or solids under ordinary conditions
More informationChapter 6: The States of Matter
Spencer L. Seager Michael R. Slabaugh www.cengage.com/chemistry/seager Chapter 6: The States of Matter PHYSICAL PROPERTIES OF MATTER All three states of matter have certain properties that help distinguish
More informationChapter 5. The Gas Laws
Chapter 5 The Gas Laws 1 Pressure Force per unit area. Gas molecules fill container. Molecules move around and hit sides. Collisions are the force. Container has the area. Measured with a barometer. 2
More informationSome Fundamental Definitions:
Lecture 2. The GAS LAWS Some Fundamental Definitions: SYSTEM: the part of the universe being the subject of study 1 Some Fundamental Definitions: State of the System: condition of a system at any given
More information1 Points to Remember Subject: Chemistry Class: XI Chapter: States of matter Top concepts 1. Intermolecular forces are the forces of attraction and repulsion between interacting particles (atoms and molecules).
More informationGases. Chapter 5. Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
Gases Chapter 5 1 Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Elements that exist as gases at 250C and 1 atmosphere 2 3 Physical Characteristics of Gases
More informationis more suitable for a quantitative description of the deviation from ideal gas behaviour.
Real and ideal gases (1) Gases which obey gas laws or ideal gas equation ( PV nrt ) at all temperatures and pressures are called ideal or perfect gases. Almost all gases deviate from the ideal behaviour
More informationAlthough different gasses may differ widely in their chemical properties, they share many physical properties
IV. Gases (text Chapter 9) A. Overview of Chapter 9 B. Properties of gases 1. Ideal gas law 2. Dalton s law of partial pressures, etc. C. Kinetic Theory 1. Particulate model of gases. 2. Temperature and
More informationCHAPTER 12 GASES AND KINETIC-MOLECULAR THEORY
. Pressure CHAPER GASES AND KINEIC-MOLECULAR HEORY. Boyle s Law: he -P Relationship 3. Charles Law: he - Relationship 4. Standard &P 5. he Combined Gas Law Equation 6. Avogadro s Law and the Standard Molar
More information(b) The measurement of pressure
(b) The measurement of pressure The pressure of the atmosphere is measured with a barometer. The original version of a barometer was invented by Torricelli, a student of Galileo. The barometer was an inverted
More information7/16/2012. Characteristics of Gases. Chapter Five: Pressure is equal to force/unit area. Manometer. Gas Law Variables. Pressure-Volume Relationship
7/6/0 Chapter Five: GASES Characteristics of Gases Uniformly fills any container. Mixes completely with any other gas. Exerts pressure on its surroundings. When subjected to pressure, its volume decreases.
More information10/16/2018. Why study gases? An understanding of real world phenomena. An understanding of how science works.
10/16/018 Kinetic Theory and the Behavior of Ideal & Real Gases Why study gases? An understanding of real world phenomena. An understanding of how science works. 1 10/16/018 A Gas Uniformly fills any container.
More informationComparison of Solids, Liquids, and Gases
CHAPTER 8 GASES Comparison of Solids, Liquids, and Gases The density of gases is much less than that of solids or liquids. Densities (g/ml) Solid Liquid Gas H O 0.97 0.998 0.000588 CCl 4.70.59 0.00503
More informationLecture 2 PROPERTIES OF GASES
Lecture 2 PROPERTIES OF GASES Reference: Principles of General Chemistry, Silberberg Chapter 6 SOME FUNDAMENTAL DEFINITIONS: SYSTEM: the part of the universe being the subject of study 1 SOME FUNDAMENTAL
More informationChapter 3 PROPERTIES OF PURE SUBSTANCES
Thermodynamics: An Engineering Approach Seventh Edition in SI Units Yunus A. Cengel, Michael A. Boles McGraw-Hill, 2011 Chapter 3 PROPERTIES OF PURE SUBSTANCES Copyright The McGraw-Hill Companies, Inc.
More informationWarm-Up. 1)Convert the following pressures to pressures in standard atmospheres:
Warm-Up 1)Convert the following pressures to pressures in standard atmospheres: A. 151.98 kpa B. 456 torr Conversions 1 atm=101.3 kpa= 760 mm Hg= 760 torr Standard temp. & pressure = 1 atm & 0 C (STP)
More informationClass XI Chapter 5 States of Matter Chemistry
Question 5.1: What will be the minimum pressure required to compress 500 dm 3 of air at 1 bar to 200 dm 3 at 30 C? Initial pressure, p 1 = 1 bar Initial volume, V 1 = 500 dm 3 Final volume, V 2 = 200 dm
More information"Mathematics is a language in which one cannot express unprecise or nebulous thoughts." - Henri Poincaire
CHM 3400 Problem Set 1 Due date: Tuesday, September 2 nd Do all of the following problems. Show your work. (NOTE: Conversion factors between different pressure units are given in Table 0.1 of Atkins. Values
More informationD g << D R < D s. Chapter 10 Gases & Kinetic Molecular Theory. I) Gases, Liquids, Solids Gases Liquids Solids. Particles far apart
Chapter 10 Gases & Kinetic Molecular Theory I) Gases, Liquids, Solids Gases Liquids Solids Particles far apart Particles touching Particles closely packed very compressible slightly comp. Incomp. D g
More informationIMPORTANT CONCEPTS. 5.1 Pressure Units for pressure STP. 5.6 Kinetic Molecular Theory. 5.3 Ideal Gas Law. 5.4 Gas Stoichiometry Gas density Molar mass
TOPICS 1. Intermolecular Forces 2. Properties of Gases 3. Pressure 4. Gas Laws Boyle, Charles, Lussac 5. Ideal Gas Law 6. Gas Stoichiometry 7. Partial Pressure 8. Kinetic Molecular Theory 9. Effusion &
More informationS OF MATTER TER. Unit. I. Multiple Choice Questions (Type-I)
Unit 5 STATE TES TE S OF MATTER MA TER I. Multiple Choice Questions (Type-I) 1. A person living in Shimla observed that cooking food without using pressure cooker takes more time. The reason for this observation
More informationCh 6 Gases 6 GASES. Property of gases. pressure = force/area
6 GASES Gases are one of the three states of matter, and while this state is indispensable for chemistry's study of matter, this chapter mainly considers the relationships between volume, temperature and
More informationChapter 10 Gases. Measurement of pressure: Barometer Manometer Units. Relationship of pressure and volume (Boyle s Law)
Chapter 10 Gases Conditions of ideal gases: Ideal gases have no attractive forces between the molecules. the atoms volume taken into account when looking at the volume a gas occupies. Low pressure and
More informationCHEM1100 Summary Notes Module 2
CHEM1100 Summary Notes Module 2 Lecture 14 Introduction to Kinetic Theory & Ideal Gases What are Boyle s and Charles Laws? Boyle s Law the pressure of a given mass of an ideal gas is inversely proportional
More informationChapter 10 Gases Characteristics of Gases Elements that exist as gases: Noble gases, O 2, N 2,H 2, F 2 and Cl 2. (For compounds see table 10.
Chapter 10 Gases 10.1 Characteristics of Gases Elements that exist as gases: Noble gases, O 2, N 2,H 2, F 2 and Cl 2. (For compounds see table 10.1) Unlike liquids and solids, gases expand to fill their
More informationAirbags fill with N 2 gas in an accident. Gas is generated by the decomposition of. 2 NaN 3 ---> > 2 Na + 3 N 2
1 2 Airbags fill with N 2 gas in an accident. Gas is generated by the decomposition of sodium azide,, NaN 3. 2 NaN 3 ---> > 2 Na + 3 N 2 3 4 There is a lot of free space in a gas. Gases can be expanded
More informationWhat we will learn about now
Chapter 4: Gases What we will learn about now We will learn how volume, pressure, temperature are related. You probably know much of this qualitatively, but we ll learn it quantitatively as well with the
More informationCHEM 116 Phase Changes and Phase Diagrams
CHEM 116 Phase Changes and Phase Diagrams Lecture 4 Prof. Sevian Please turn in extra credit assignments at the very beginning of class. Today s agenda Finish chapter 10 Partial pressures Vapor pressure
More information5.60 Thermodynamics & Kinetics Spring 2008
MIT OpenCourseWare http://ocw.mit.edu 5.60 Thermodynamics & Kinetics Spring 2008 For information about citing these materials or our Terms of Use, visit: http://ocw.mit.edu/terms. 5.60 Spring 2008 Lecture
More informationCHEMISTRY Matter and Change. Chapter 12: States of Matter
CHEMISTRY Matter and Change Chapter 12: States of Matter CHAPTER 12 States of Matter Section 12.1 Section 12.2 Section 12.3 Section 12.4 Gases Forces of Attraction Liquids and Solids Phase Changes Click
More informationIdeal Gas Behavior. NC State University
Chemistry 331 Lecture 6 Ideal Gas Behavior NC State University Macroscopic variables P, T Pressure is a force per unit area (P= F/A) The force arises from the change in momentum as particles hit an object
More informationChapter 5 Gases. Chapter 5: Phenomena. Properties of Gases. Properties of Gases. Pressure. Pressure
Chapter 5: Phenomena Phenomena: To determine the properties of gases scientists recorded various observations/measurements about different gases. Analyze the table below looking for patterns between the
More informationGases. Chapter 5. Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
Gases Chapter 5 Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display. 1 Elements that exist as gases at 25 0 C and 1 atmosphere 2 3 Physical Characteristics of Gases
More informationPhases of matter and phase diagrams
Phases of matter and phase diagrams Transition to Supercritical CO2 Water Ice Vapor Pressure and Boiling Point Liquids boil when the external pressure equals the vapor pressure. Temperature of boiling
More informationChapter 5: Phenomena. Chapter 5: Gases. Molar Mass. Volume (L) Amount (mol) Pressure (atm) Temperature ( C) Odor
Chapter 5: Phenomena Phenomena: To determine the properties of gases scientists recorded various observations/measurements about different gases. Analyze the table below looking for patterns between the
More information