Department of Materials Science and Engineering, Research Institute of Advanced
|
|
- Reynard Morris
- 5 years ago
- Views:
Transcription
1 Supporting Information High Energy Organic Cathode for Sodium Rechargeable Batteries Haegyeom Kim 1, Ji Eon Kwon 2, Byungju Lee 1, Jihyun Hong 1, Minah Lee 3, Soo Young Park 2*, and Kisuk Kang 1,4 * 1. Department of Materials Science and Engineering, Research Institute of Advanced Materials (RIAM), Seoul National University, 1 Gwanak Road, Seoul , Republic of Korea 2. Center for Supramolecular Optoelectronic Materials (CSOM), Department of Materials Science and Engineering, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul , Republic of Korea. 3. Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology (KAIST), 335 Science Road, Daejeon , Republic of Korea 4. Center for Nanoparticle Research, Institute for Basic Science (IBS), Seoul National University, Seoul , Republic of Korea * Corresponding Author. (S. Y. Park) Tel.: Fax.: address: parksy@snu.ac.kr
2 (K. Kang) Tel.: Fax.: address: 1. Experiments 1.1. Synthesis of C 6 Cl 4 O 2 /CMK composite The C 6 Cl 4 O 2 /CMK composite was prepared by a simple solution impregnation method. CMK-3 (100 mg) was added to 5 ml DMF solution containing C 6 Cl 4 O 2 (150 mg). Then, the solvent of mixture was slowly removed by spontaneous evaporation under ambient condition. The composite powder was carefully collected and the remnant solvent was fully removed under vacuum Calculation details We conducted geometry optimization and energy calculation of the molecules using density functional theory (DFT) calculation tool, Gaussian 09 quantum chemistry package. 1 All calculations were conducted with spin-unrestricted DFT, based on Becke-Lee-Yang-Parr (B3LYP) hybrid exchange-correlation functional 2-4 and the 6-311G(d,p) basis set. 5-7 Effect of the solvent was considered by using the polarizable continuum model (PCM). Dielectric constant = 70 was applied to model the electrolyte used in the experiment (EC:PC:DMC=45:45:10).
3 1.3. Characterization The molecular structure of the samples was analyzed with fourier transform infrared spectroscopy (FTIR, Hyperion 3000, Bruker, USA ). Thermogravimetric (TGA, Q-5000 IR, TA Instruments, USA) analysis was used to determine the content of C 6 Cl 4 O 2 in the composite. The morphology of the samples was verified using field-emission scanning electron microscopy (FE-SEM, SUPRA 55VP, Carl Zeiss, Germany). UV/Vis absorbance spectra of the samples were obtained using a V/650 spectrophotometer (Jasco Inc., Japan) in the range of nm Electrochemical measurements Electrodes were prepared by mixing the active material (C 6 Cl 4 O 2, 40 wt%) with poly (tetrafluoroethylene) binder (PTFE, 20 wt%) and conductive carbon black (Super-P, 40 wt%). Test cells were assembled in a glove box into a two-electrode configuration with a Na metal counter electrode. A separator of grade GF/F (Whatman, USA) was used. 1 M NaClO 4 electrolyte in a 45:45:10 mixture of ethylene carbonate, propylene carbonate, and dimethyl carbonate (Techno Semichem) was used. Electrochemical profiles were obtained using a multichannel potentio-galvanostat (WonATech).
4 2. Supporting Figures Figure S1. HOMO structure of C 6 F 4 O 2 and C 6 Cl 4 O 2 after accepting two electrons.
5 Figure S2. Typical charge/discharge profile of C 6 F 4 O 2.
6 Figure S3. Typical discharge profiles of C 6 Cl 4 O 2 electrodes in Na cells (upper) and Li cells (lower).
7 Figure S4. Ex situ XPS analysis of C 6 F 4 O 2. XPS peaks of a. Na 1s, b. O 1s, and c. Cl 2p during Na insertion and extraction. (black: before cycling, red: after discharge, blue: after charge)
8 Stored in the electrolyte Fresh powder Intensity (a. u.) Wavenumber (cm -1 ) Figure S5. Chemical stability of C 6 Cl 4 O 2 in the surrounding electrolyte. FTIR vibrations of C 6 Cl 4 O 2 powder were monitored after 24 hours storage in the electrolyte.
9 Figure S6. a. Photo image of (i) the fresh electrolyte and (ii) the electrolyte storing C 6 Cl 4 O 2 for 12 hours. b. FTIR spectra of the fresh electrolyte, the electrolyte storing C 6 Cl 4 O 2 for 12 hours, and C 6 Cl 4 O 2 power.
10 Figure S7. FTIR spectra of C 6 Cl 4 O 2 /CMK, C 6 Cl 4 O 2, and CMK. The molecular structure of C 6 Cl 4 O 2 was maintained after incorporation into the CMK matrix.
11 Figure S8. XPS analyses of a. O1s and b. Cl2p of C 6 Cl 4 O 2 /CMK composite (red) and C 6 Cl 4 O 2 (black). The general shapes of O 1s and Cl 2p peaks of C 6 Cl 4 O 2 molecules were not altered after confinement in carbon matrix. However, the peak positions were slightly shifted to higher binding energy, which indicates the change in the number of π-electrons of C 6 Cl 4 O 2 molecules. The up-shifts of binding energy results from the π-π interactions between carbon matrix and C 6 Cl 4 O 2 molecules. The strong π-π interactions in combination with physical confinement could partially suppress the dissolution of active molecules in the electrolyte.
12 Weight (%) ~42 % Temperature ( o C) Figure S9. Thermogravimetric (TGA) curve of C 6 Cl 5 O 2 /CMK. The C 6 Cl 4 O 2 content of the composite was ~42 wt% as determined by TGA analyses.
13 Figure S10. SEM images of a. C 6 Cl 4 O 2 power and b. C 6 Cl 4 O 2 /CMK composite. The C 6 Cl 4 O 2 was integrated into the CMK matrix without segregation. While micron-sized C 6 Cl 4 O 2 particles were observed in the initial mixture of C 6 Cl 4 O 2 and CMK, no such particles were observed in the composite material.
14 Figure S11. SEM image of C 6 Cl 4 O 2 /CMK. e. and f. EDS mapping images of O and Cl, respectively.
15 4 Voltage (V vs. Na) Capacity (mah g -1 ) Figure S12. Charge/discharge profile of CMK electrode.
16 Table S1. LUMO energy calculated at with/without applying implicit solvation model. The adoption of implicit solvation model upshifts LUMO levels of molecules by 0.1 ev in X=Br case, by 0.1~0.2 ev in X=Cl case and by 0.2~0.4 ev in X=F case, probably because elements with higher electronegativity are stabilized in environment of highly polar solvents. References 1. Frisch, M. Gaussian 09 revision D. 01, Lee, T.; Yang, W.; and Parr, R. Development of Colle-Salvetti correlation-energy formula into a functional of the electron density. Phys. Rev. B, 1988, 37, Stephens, P. J.; Devlin, F. J.; Chabalowski, C. F.; Frisch, M. J. Ab initio calculation of vibrational absorption and circular dichroism spectra using density functional force fields. J. Phys. Chem., 1994, 98, Becke, A. D. Density functional thermochemistry. III. The role of exact exchange. J. Chem. Phys., 1993, 98, Liang, Y.; Zhang, P.; Chen, J. Function-oriented design of conjugated carbonyl compound electrodes for high energy lithium batteries. Chem. Sci. 2013, 4, Burkhardt, S. E.; Bois, J.; Tarascon, J. M.; Henning, R. G.; Abruna, H. D. Li-Carboxylate Anode Structure-Property Relationships from Molecular Modeling. Chem. Mater. 2013, 25, Wang, H.; Sun, Z.; Zhang, Y.; Liang, M.; Jia, D.; Xue, S. Charge Transport Limitations of Redox Mediators in Dye-Sensitized Solar Cells: Investigation Based on a Quasi-Linear Model. J. Phys. Chem. C 2014, 118, 60
for Magnesium-Ion Batteries
[Supporting Information] Cointercalation of Mg 2+ Ions into Graphite for Magnesium-Ion Batteries Dong Min Kim, Sung Chul Jung, Seongmin Ha, Youngjin Kim, Yuwon Park, Ji Heon Ryu ǂ, Young Kyu Han*,, Kyu
More informationSodium Intercalation Chemistry in Graphite
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2015 Supplementary information Sodium Intercalation Chemistry in Graphite Haegyeom
More informationUltrasmall Sn nanoparticles embedded in nitrogen-doped porous carbon as high-performance anode for lithium-ion batteries
Supporting Information Ultrasmall Sn nanoparticles embedded in nitrogen-doped porous carbon as high-performance anode for lithium-ion batteries Zhiqiang Zhu, Shiwen Wang, Jing Du, Qi Jin, Tianran Zhang,
More informationSelf-rearrangement of silicon nanoparticles. high-energy and long-life lithium-ion batteries
Supporting Information Self-rearrangement of silicon nanoparticles embedded in micron carbon sphere framework for high-energy and long-life lithium-ion batteries Min-Gi Jeong,, Hoang Long Du, Mobinul Islam,,
More informationSupporting Information
Supporting Information A Novel Potassium-Ion Hybrid Capacitor Based on an Anode of K 2 Ti 6 O 13 Micro-Scaffolds Shengyang Dong,, Zhifei Li, Zhenyu Xing, Xianyong Wu, Xiulei Ji*, and Xiaogang Zhang*, Jiangsu
More informationMulti-electron redox phenazine for ready-to-charge organic batteries
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 2017 Supplementary Information Multi-electron redox phenazine for ready-to-charge organic batteries
More informationA Scalable Synthesis of Few-layer MoS2. Incorporated into Hierarchical Porous Carbon. Nanosheets for High-performance Li and Na Ion
Supporting Information A Scalable Synthesis of Few-layer MoS2 Incorporated into Hierarchical Porous Carbon Nanosheets for High-performance Li and Na Ion Battery Anodes Seung-Keun Park, a,b Jeongyeon Lee,
More informationSUPPLEMENTARY INFORMATION
ARTICLE NUMBER: 16066 DOI: 10.1038/NENERGY.2016.66 Rational design of redox mediators for advanced Li-O 2 batteries Hee-Dae Lim, 1, Byungju Lee, 1, Yongping Zheng, 2 Jihyun Hong, 1 Jinsoo Kim, 1 Hyeokjo
More informationHKUST-Shenzhen Research Institute, No. 9 Yuexing 1st RD, South Area, Hi-tech Park, Nanshan, Shenzhen , China
Electronic Supporting Information Aggregation-Induced Emission and Photocyclization of Poly(hexaphenyl-1,3-butadiene)s Synthesized from 1+2 Polycoupling of Internal Alkynes and Arylboronic Acids Yajing
More informationSupporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Supporting Information Title: A sulfonated polyaniline with high density and high rate Na-storage
More informationDual redox catalysts for oxygen reduction and evolution reactions: towards a redox flow Li-O 2 battery
Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2015 Supporting Information Dual redox catalysts for oxygen reduction and evolution reactions:
More informationAn inorganic-organic hybrid supramolecular nanotube as high-performance anode for lithium ion batteries
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2018 An inorganic-organic hybrid supramolecular nanotube as high-performance anode for lithium
More informationSupporting Information
Supporting Information Facet-Selective Deposition of FeO x on α-moo 3 Nanobelts for Lithium Storage Yao Yao, 1 Nuo Xu, 2 Doudou Guan, 1 Jiantao Li, 1 Zechao Zhuang, 1 Liang Zhou,*,1 Changwei Shi 1, Xue
More informationSupplementary Materials for
advances.sciencemag.org/cgi/content/full/2/1/e1501038/dc1 Supplementary Materials for Environmentally-friendly aqueous Li (or Na)-ion battery with fast electrode kinetics and super-long life Xiaoli Dong,
More informationSupplemental Information. Lightweight Metallic MgB 2 Mediates. Polysulfide Redox and Promises High- Energy-Density Lithium-Sulfur Batteries
JOUL, Volume 3 Supplemental Information Lightweight Metallic MgB 2 Mediates Polysulfide Redox and Promises High- Energy-Density Lithium-Sulfur Batteries Quan Pang, Chun Yuen Kwok, Dipan Kundu, Xiao Liang,
More informationElectronic Supplementary Information. Facile Synthesis of Germanium-Graphene Nanocomposites. and Their Application as Anode Material for Lithium Ion
Supplementary Material (ESI) for CrystEngCommunity This journal is (c) The Royal Society of Chemistry 2011 Electronic Supplementary Information Facile Synthesis of Germanium-Graphene Nanocomposites and
More informationFacile synthesis of yolk-shell structured Si-C nanocomposites as anode for lithium-ion battery 1. Experimental 1.1 Chemicals
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Facile synthesis of yolk-shell structured Si-C nanocomposites as anode for lithium-ion battery
More informationSupplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2018 Supplementary Information Three-Dimensional Hollow Sphere of Tetragonal-Spinel
More informationTrace Solvent as a Predominant Factor to Tune Dipeptide. Self-Assembly
Trace Solvent as a Predominant Factor to Tune Dipeptide Self-Assembly Juan Wang,, Kai Liu,,, Linyin Yan,, Anhe Wang, Shuo Bai, and Xuehai Yan *,, National Key Laboratory of Biochemical Engineering, Institute
More informationSupporting Information s for
Supporting Information s for # Self-assembling of DNA-templated Au Nanoparticles into Nanowires and their enhanced SERS and Catalytic Applications Subrata Kundu* and M. Jayachandran Electrochemical Materials
More informationSupporting Information
Copyright WILEY-VCH Verlag GmbH & Co. KGaA, 69469 Weinheim, Germany, 213. Supporting Information for Adv. Energy Mater., DOI: 1.12/aenm.2131565 Reduction of Graphene Oxide by Hydrogen Sulfide: A Promising
More informationSchool of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, , Singapore. b
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Dopamine-Mo VI complexation-assisted large-scale aqueous synthesis of single-layer MoS 2 /carbon
More informationSupporting Information High-performance sodium battery with 9,10-anthraquinone/CMK-3 cathode and ether-based electrolyte
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Supporting Information High-performance sodium battery with 9,10-anthraquinone/CMK-3 cathode and
More informationSupporting Information
Copyright WILEY-VCH Verlag GmbH & Co. KGaA, 69469 Weinheim, Germany, 2016. Supporting Information for Adv. Mater., DOI: 10.1002/adma.201604015 High Performance Graphene/Ni 2 P Hybrid Anodes for Lithium
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 214 Electronic Supplementary Information Ultrathin and High-Ordered CoO Nanosheet
More informationSupporting Information An Interlaced Silver Vanadium Oxide-Graphene Hybrid with High Structural Stability for Use in Lithium Ion Batteries
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Information An Interlaced Silver Vanadium Oxide-Graphene Hybrid with High Structural
More informationGraphene oxide hydrogel at solid/liquid interface
Electronic Supplementary Information Graphene oxide hydrogel at solid/liquid interface Jiao-Jing Shao, Si-Da Wu, Shao-Bo Zhang, Wei Lv, Fang-Yuan Su and Quan-Hong Yang * Key Laboratory for Green Chemical
More informationELECTRONIC SUPPLEMENTARY INFORMATION. Synthesis and Dye Sensitized Solar Cell Applications of Bodipy Derivatives with Bisdimethylfluorenyl
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2015 ELECTRONIC SUPPLEMENTARY INFORMATION
More informationBulk graphdiyne powder applied for highly efficient lithium storage
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Bulk graphdiyne powder applied for highly efficient lithium storage Shengliang Zhang, ab Huibiao
More informationTwo Dimensional Graphene/SnS 2 Hybrids with Superior Rate Capability for Lithium ion Storage
Electronic Supplementary Information Two Dimensional Graphene/SnS 2 Hybrids with Superior Rate Capability for Lithium ion Storage Bin Luo, a Yan Fang, a Bin Wang, a Jisheng Zhou, b Huaihe Song, b and Linjie
More informationElectronic Supplementary Information (ESI)
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information (ESI) LiTi 2 (PO 4 ) 3 /reduced graphene oxide nanocomposite
More informationElectronic Supplementary Information. Three-Dimensional Carbon Foam/N-doped 2. Hybrid Nanostructures as Effective Electrocatalysts for
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information Three-Dimensional Carbon Foam/N-doped
More informationElectronic Supplementary Information (ESI)
Electronic Supplementary material (ESI) for Nanoscale Electronic Supplementary Information (ESI) Synthesis of Nanostructured Materials by Using Metal-Cyanide Coordination Polymers and Their Lithium Storage
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2018 Supporting Information Na3V2(PO4)2F3-SWCNT: A High Voltage Cathode for
More informationNitrogen-doped Activated Carbon for High Energy Hybridtype Supercapacitor
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2015 SUPPORTING INFORMATION Nitrogen-doped Activated Carbon for High Energy Hybridtype
More informationHigh Voltage Magnesium-ion Battery Enabled by Nanocluster Mg3Bi2
Supporting Information High Voltage Magnesium-ion Battery Enabled by Nanocluster Mg3Bi2 Alloy Anode in Noncorrosive Electrolyte Yi-Hong Tan,, Wei-Tang Yao,*, Tianwen Zhang, Tao Ma, Lei-Lei Lu, Fei Zhou,
More information[Supporting information]
[Supporting information] Proof of ionic transport in interparticles of LiMPO 4 electrodes Kyu T. Lee, Wang H. Kan, Linda F. Nazar *. University of Waterloo, Department of Chemistry, Waterloo, Ontario,
More informationHighly stable and flexible Li-ion battery anodes based on TiO 2 coated
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2015 Supporting Information for Highly stable and flexible Li-ion battery anodes
More informationHigh Tap Density Secondary Silicon Particle. Anodes by Scalable Mechanical Pressing for
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information: High Tap Density Secondary Silicon
More informationSupporting Information for. Aqueous Mg-ion Battery Based on Polyimide Anode and Prussian. Blue Cathode
Supporting Information for Aqueous Mg-ion Battery Based on Polyimide Anode and Prussian Blue Cathode L. Chen, J. L. Bao, X. Dong, D. G. Truhlar, Y. Wang,* C. Wang, Y. Xia * Department of Chemistry and
More informationSupporting Information
Supporting Information Polyoxometalate-based crystalline tubular microreactor: redox-active inorganic-organic hybrid materials producing gold nanoparticles and catalytic properties Dong-Ying Du, Jun-Sheng
More informationInexpensive Colloidal SnSb Nanoalloys as Efficient Anode Materials for Lithium- and Sodium-Ion Batteries
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Supplementary Information for Inexpensive Colloidal SnSb Nanoalloys as
More informationLithium-ion Batteries Based on Vertically-Aligned Carbon Nanotubes and Ionic Liquid
Electronic Supplementary Information Lithium-ion Batteries Based on Vertically-Aligned Carbon Nanotubes and Ionic Liquid Electrolytes Wen Lu, * Adam Goering, Liangti Qu, and Liming Dai * 1. Synthesis of
More informationCovalent-Organic Frameworks: Potential Host Materials for Sulfur Impregnation in Lithium-Sulfur Batteries
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2014 Covalent-Organic Frameworks: Potential Host Materials for Sulfur Impregnation
More informationUltrathin V 2 O 5 Nanosheet Cathodes: Realizing Ultrafast Reversible Lithium Storage
Supplementary Information for Ultrathin V 2 O 5 Nanosheet Cathodes: Realizing Ultrafast Reversible Lithium Storage Xianhong Rui, ab Ziyang Lu, a Hong Yu, a Dan Yang, a Huey Hoon Hng, a Tuti Mariana Lim,*
More informationSupporting Information. Electrocatalytic polysulfide-traps for controlling redox shuttle process of Li-S battery
Supporting Information Electrocatalytic polysulfide-traps for controlling redox shuttle process of Li-S battery Hesham Al Salem, Ganguli Babu, Chitturi V. Rao and Leela Mohana Reddy Arava * Department
More informationPhenyl-Rich Silicone Oil as a Precursor for SiOC Anode Materials in Long- Cycle and High-Rate Lithium Ion Batteries
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Supporting Information Phenyl-Rich Silicone Oil as a Precursor for SiOC
More informationSupporting Information. Bi-functional Catalyst with Enhanced Activity and Cycle Stability for. Rechargeable Lithium Oxygen Batteries
Supporting Information Hierarchical Mesoporous/Macroporous Perovskite La 0.5 Sr 0.5 CoO 3-x Nanotubes: a Bi-functional Catalyst with Enhanced Activity and Cycle Stability for Rechargeable Lithium Oxygen
More informationFunctionalization of reduced graphene oxides by redox-active ionic liquids for energy storage
Supplementary Material (ESI) for Chemical Communications Functionalization of reduced graphene oxides by redox-active ionic liquids for energy storage Sung Dae Cho, a Jin Kyu Im, b Han-Ki Kim, c Hoon Sik
More informationPlasma-functionalized carbon-layered separators for improved performance of
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2019 Electronic Supplementary Material (ESI) for Journal of Materials Chemistry
More informationSupplementary Figure 1 Supplementary Figure 2
Supplementary Figure 1 XRD pattern of pure 3D PGC framework. The pure 3D PGC was obtained by immersing NaCl Na 2 S@GC in water to remove the NaCl and Na 2 S. The broad reflection peak in the range of 15
More informationSupporting information. Alkali Metal Ion Templated Transition Metal Formate. Framework Materials: Synthesis, Crystal Structures,
Supporting information Alkali Metal Ion Templated Transition Metal Formate Framework Materials: Synthesis, Crystal Structures, Ion Migration and Magnetism Espen Eikeland, 1 Nina Lock, 2 Mette Filsø, 1
More informationT he global energy paradigm is rapidly transforming from fossil fuels to sustainable energy resources, including
OPEN SUBJECT AREAS: MATERIALS FOR ENERGY AND CATALYSIS ELECTROCHEMISTRY GRAPHENE All-graphene-battery: bridging the gap between supercapacitors and lithium ion batteries Haegyeom Kim 1, Kyu-Young Park
More informationSupporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2016 Supporting Information Synthesis and Application of Hexagonal Perovskite BaNiO 3 with Quadrivalent
More informationTransparent and ultra-bendable all-solid-state supercapacitors without percolation problems
Electronic Supplementary Information: Transparent and ultra-bendable all-solid-state supercapacitors without percolation problems Inho Nam, Soomin Park, Gil-Pyo Kim, Junsu Park and Jongheop Yi* World Class
More informationAn Ideal Electrode Material, 3D Surface-Microporous Graphene for Supercapacitors with Ultrahigh Areal Capacitance
Supporting Information An Ideal Electrode Material, 3D Surface-Microporous Graphene for Supercapacitors with Ultrahigh Areal Capacitance Liang Chang, 1 Dario J. Stacchiola 2 and Yun Hang Hu 1, * 1. Department
More informationSupporting Information
Supporting Information Nanoconfined Iron Oxychloride Material as a High-Performance Cathode for Rechargeable Chloride Ion Batteries Tingting Yu, Qiang Li, Xiangyu Zhao,*,, Hui Xia, Liqun Ma, Jinlan Wang,
More informationElectronic Supplementary Material. Methods. Synthesis of reference samples in Figure 1(b) Nano Res.
Electronic Supplementary Material Shaped Pt Ni nanocrystals with an ultrathin Pt-enriched shell derived from one-pot hydrothermal synthesis as active electrocatalysts for oxygen reduction Jun Gu 1,, Guangxu
More informationHysteresis-free low-temperature-processed planar perovskite solar cells with 19.1% efficiency
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2016 Supplementary Information Hysteresis-free low-temperature-processed planar
More informationElectronic Supplementary Information
Electronic Supplementary Information Stable cycling of lithium sulfide cathodes through strong affinity with a bifunctional binder Zhi Wei Seh, Qianfan Zhang, Weiyang Li, Guangyuan Zheng, Hongbin Yao,
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2018 Supporting Information Directly anchoring 2D NiCo metal-organic frameworks
More informationElectronic Supplementary Information
Copyright Royal Society of Chemistry 2013 Electronic Supplementary Information for J. Mater. Chem. A, DOI: 10.1039/x0xx00000x ((will be completed by the editorial staff)) Improved Cycle Lives of LiMn 2
More informationDFT-TDDFT Computational Study of Three Different Chlorophyllous as Dye sensitized solar cells (DSSCs)
DFT-TDDFT Computational Study of Three Different Chlorophyllous as Dye sensitized solar cells (DSSCs) Rahmatollah Rahimi 1, *, Mahboube Rabbani 1, Rahim Rahimi 2, Morteza Moghimi Waskasi 1 Rahimi_rah@iust.ac.ir
More informationSupporting Information
Supporting Information Dynamic Crosslinking of Polymeric Binders Based on Host- Guest Interactions for Silicon Anodes in Lithium Ion Batteries Tae-woo Kwon,, You Kyeong Jeong,, Erhan Deniz, Siham Y. AlQaradawi,
More informationFabrication of a One-dimensional Tube-in-tube Polypyrrole/Tin oxide Structure for Highly Sensitive DMMP Sensor Applications
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information (ESI) for Fabrication of a One-dimensional
More informationCarboxymethyl cellulose-templated synthesis of hierarchically structured metal oxides
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information Carboxymethyl cellulose-templated synthesis of hierarchically
More informationLayered Sb 2 Te 3 and its nanocomposite: A new and outstanding electrode material for superior rechargeable Li-ion batteries
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Supplementary Information: Layered Sb 2 Te 3 and its nanocomposite: A new
More informationSupporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting Information Au nanoparticles supported on magnetically separable Fe 2 O 3 - graphene
More informationMetal Organic Framework-Derived Metal Oxide Embedded in Nitrogen-Doped Graphene Network for High-Performance Lithium-Ion Batteries
Supporting Information for Metal Organic Framework-Derived Metal Oxide Embedded in Nitrogen-Doped Graphene Network for High-Performance Lithium-Ion Batteries Zhu-Yin Sui, Pei-Ying Zhang,, Meng-Ying Xu,
More informationSupporting Information
Supporting Information Heterostructured Bi 2 S 3 -Bi 2 O 3 Nanosheets with a Built-In Electric Field for Improved Sodium Storage Wen Luo, a,b Feng Li, a Qidong Li, a Xuanpeng Wang, a Wei Yang, a Liang
More informationEnergy Storage. Light-emitting. Nano-Carbons. H 2 Energy. CNT synthesis. Graphene synthesis Top-down. Solar H 2 generation
Nano-Carbon battery Graphene synthesis Top-down CNT synthesis CVD reactor hydrocarbon gas Catalyst CNTs Chemical Modification COO O NO 2 COO COO COO Bottom-up O O NO NO 2 2 COO COO Nano-Carbons 20 nm Light-emitting
More informationSupplementary Information. Unusual High Oxygen Reduction Performance in All-Carbon Electrocatalysts
Supplementary Information Unusual High Oxygen Reduction Performance in All-Carbon Electrocatalysts Wei Wei 1, 4,, Ying Tao 1, 4,, Wei Lv 2,, Fang-Yuan Su 2, Lei Ke 2, Jia Li 2, Da-Wei Wang 3, *, Baohua
More informationSupporting Information
Supporting Information Iron Telluride Decorated Reduced Graphene Oxide Hybrid Microspheres as Anode Materials with Improved Na-Ion Storage Properties Jung Sang Cho 1, Seung Yeon Lee 1, Jung-Kul Lee 2,
More informationElectronic Supplementary Information
Electronic Supplementary Information Designed Copper-amine Complex as an Efficient Template for One-pot Synthesis of Cu-SSZ-13 Zeolite with Excellent Activity for Selective Catalytic Reduction of NOx by
More informationAn Advanced Anode Material for Sodium Ion. Batteries
Layered-Structure SbPO 4 /Reduced Graphene Oxide: An Advanced Anode Material for Sodium Ion Batteries Jun Pan, Shulin Chen, # Qiang Fu, Yuanwei Sun, # Yuchen Zhang, Na Lin, Peng Gao,* # Jian Yang,* and
More informationElectronic Supplementary Information (ESI)
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information (ESI) Synthesis of 1T-MoSe 2 ultrathin
More informationSupporting Information. Polyaniline-MnO 2 nanotubes hybrid nanocomposite as supercapacitor electrode material in acidic electrolyte
Supporting Information Polyaniline-MnO 2 nanotubes hybrid nanocomposite as supercapacitor electrode material in acidic electrolyte Jaidev, R Imran Jafri, Ashish Kumar Mishra, Sundara Ramaprabhu* Alternative
More informationGRAPHENE EFFECT ON EFFICIENCY OF TiO 2 -BASED DYE SENSITIZED SOLAR CELLS (DSSC)
Communications in Physics, Vol. 26, No. 1 (2016), pp. 43-49 DOI:10.15625/0868-3166/26/1/7961 GRAPHENE EFFECT ON EFFICIENCY OF TiO 2 -BASED DYE SENSITIZED SOLAR CELLS (DSSC) NGUYEN THAI HA, PHAM DUY LONG,
More informationSupplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Supplementary Information Ultrasmall Sn Nanodots Embedded inside N-Doped
More informationSn-Based Nanocomposite for Li-Ion Battery Anode with High Energy Density, Rate Capability, and Reversibility
SUPPORTING INFORMATION Sn-Based Nanocomposite for Li-Ion Battery Anode with High Energy Density, Rate Capability, and Reversibility Min-Gu Park a,b, Dong-Hun Lee a, Heechul Jung c, Jeong-Hee Choi d and
More informationHydrothermally Activated Graphene Fiber Fabrics for Textile. Electrodes of Supercapacitors
Supporting Information for Hydrothermally Activated Graphene Fiber Fabrics for Textile Electrodes of Supercapacitors Zheng Li, Tieqi Huang, Weiwei Gao*, Zhen Xu, Dan Chang, Chunxiao Zhang, and Chao Gao*
More informationSupporting Information. Facile electrospinning formation of carbon-confined metal oxide cube-intube. nanostructures for stable lithium storage
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2017 Supporting Information Facile electrospinning formation of carbon-confined metal oxide cube-intube
More informationSupporting Information
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2015 Supporting Information Pyrite FeS 2 for High-rate and Long-life Rechargeable
More informationSupporting Information
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2016 Supporting Information Enhanced Catalytic Activity and Magnetization of Encapsulated
More informationAll materials were purchased from Sigma-Aldrich unless specified otherwise. PCBA
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Experimental section 1. Materials All materials were purchased from Sigma-Aldrich
More informationSupporting Information
Supporting Information MoSe2 embedded CNT-Reduced Graphene Oxide (rgo) Composite Microsphere with Superior Sodium Ion Storage and Electrocatalytic Hydrogen Evolution Performances Gi Dae Park, Jung Hyun
More informationSupporting Information
Supporting Information The Design of Hierarchical Ternary Hybrid for Fiber-Shaped Asymmetric Supercapacitor with High Volumetric Energy Density Xunliang Cheng, Jing Zhang, Jing Ren, Ning Liu, Peining Chen,
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Supporting Information On-site Evolution of Ultrafine ZnO nanoparticles
More informationHigh-Performance Silicon Battery Anodes Enabled by
Supporting Information for: High-Performance Silicon Battery Anodes Enabled by Engineering Graphene Assemblies Min Zhou,, Xianglong Li, *, Bin Wang, Yunbo Zhang, Jing Ning, Zhichang Xiao, Xinghao Zhang,
More informationActivation of Sodium Storage Sites in Prussian Blue Analogues via Surface Etching
Supporting Information Activation of Sodium Storage Sites in Prussian Blue Analogues via Surface Etching Wenhao Ren, Mingsheng Qin, Zixuan Zhu, Mengyu Yan, Qi Li,*, Lei Zhang, Dongna Liu, and Liqiang Mai*,,
More informationMicroporous carbon nanosheets with redox-active. heteroatoms for pseudocapacitive charge storage
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2015 SUPPORTING INFORMATION Microporous carbon nanosheets with redox-active heteroatoms for pseudocapacitive
More informationSupporting information. A Metal-Organic Framework-Derived Porous Cobalt Manganese Oxide Bifunctional
Supporting information A MetalOrganic FrameworkDerived Porous Cobalt Manganese Oxide Bifunctional Electrocatalyst for Hybrid NaAir/Seawater Batteries Mari Abirami a,, Soo Min Hwang a,, *, Juchan Yang a,
More informationEnhancing potassium-ion battery performance by defect and. interlayer engineering
Electronic Supplementary Material (ESI) for Nanoscale Horizons. This journal is The Royal Society of Chemistry 2018 Electronic Supplementary Information for Enhancing potassium-ion battery performance
More informationSynthesis of Oxidized Graphene Anchored Porous. Manganese Sulfide Nanocrystal via the Nanoscale Kirkendall Effect. for supercapacitor
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2015 Synthesis of Oxidized Graphene Anchored Porous Manganese Sulfide Nanocrystal
More informationElectronic Supplementary Information. Concentrated Electrolytes Stabilize Bismuth-Potassium Batteries
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2018 Electronic Supplementary Information Concentrated Electrolytes Stabilize Bismuth-Potassium
More informationMg, Zn) as High Voltage Layered Cathodes for
Supporting Information for Honeycomb-Ordered Na 3 Ni 1.5 M 0.5 BiO 6 (M = Ni, Cu, Mg, Zn) as High Voltage Layered Cathodes for Sodium-Ion Batteries Peng-Fei Wang, a,d, Yu-Jie Guo, a,d, Hui Duan, a,d Tong-Tong
More informationSupporting Information (SI) for
Supporting Information (SI) for Highly sensitive and selective fluorescent probe for ascorbic acid with a broad detection range through dual-quenching and bimodal action of nitronyl-nitroxide Haerim Nam,
More informationA novel electrolyte system without Grignard reagent for rechargeable magnisium battery
Electronic Supplementary Information A novel electrolyte system without Grignard reagent for rechargeable magnisium battery Fei-fei Wang, a,b Yong-sheng Guo, a,b Jun Yang,* a,b Yanna Nuli, a,b Shin-ichi
More informationSaltwater as the energy source for low-cost, safe rechargeable. batteries
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information Saltwater as the energy source for
More informationSupporting Information of
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Supporting Information of Synthesis of Hard Carbons from Argan Shell for
More information