The general solution of Schrödinger equation in three dimensions (if V does not depend on time) are solutions of time-independent Schrödinger equation

Transcription

1 Lecture 27st Page 1 Lecture 27 L27.P1 Review Schrödinger equation The general solution of Schrödinger equation in three dimensions (if V does not depend on time) is where functions are solutions of time-independent Schrödinger equation If potential V is spherically symmetric, i.e. only depends on distance to the origin r, then the separable solutions are spherical harmonics where and are solutions of radial equation Hydrogen-like atom energy levels:

2 Lecture 27st Page 2 L27.P2 Identical particles Bosons and fermions In classical mechanics, you can always identify which particle is which. In quantum mechanics, you simply can't say which electron is which as you can not put any labels on them to tell them apart. There are two possible ways to deal with indistinguishable particles, i.e. to construct two-particle wave function from single particle wave functions and that is non committal to which particle is in which state: Symmetric Antisymmetric Therefore, quantum mechanics allows for two kinds of identical particles: bosons (for the "+" sign) and fermions (for the "-" sign). N-particle states are constructed in the same way, antisymmteric state for fermions (which can be easily written as Slater determinant) and symmetric state for bosons; the normalization factor is. In our non-relativistic quantum mechanics we accept the following statement as an axiom: All particles with integer spin are bosons, all particles with half-integer spin are fermions. Note that it is total wave function that has to be antisymmetric. Therefore, for example if spatial wave function for the electrons is symmetric, then the corresponding spin state has to be antisymmteric. Note: make sure that you can add angular momenta and know what are singlet and triplet states. From the above, two identical fermions can not occupy the same state. It is called Pauli exclusion principle.

3 Lecture 27st Page 3 Perturbation theory L27.P3 General formalism of the problem: Suppose that we solved the time-independent Schrödinger equation for some potential and obtained a complete set of orthonormal eigenfunctions and corresponding eigenvalues. This is the problem that we completely understand and know solutions for. We mark all these solutions and the Hamiltonian with " " label. Now we slightly perturb the potential: The problem of the perturbation theory is to find eigenvalues and eigenfunctions of the perturbed potential, i.e. to solve approximately the following equation: using the known solutions of the problem Nondegenerate perturbation theory We expand our solution as follows in terms of perturbation H' The first-order correction to the energy is given by: First-order correction to the wave function is given by Note that as long as m n, the denominator can not be zero as long as energy levels are nondegenerate. If the energy levels are degenerate, we need degenerate perturbation theory ( consider later).

4 Lecture 27st Page 4 The second-order correction to the energy is L27.P4 Degenerate perturbation theory Suppose now that the states energy. are degenerate, i.e. have the same How to calculate first-order energy correction E 1? In the case of n-fold degeneracy, E 1 are eigenvalues of n x n matrix Variational method The variational principle let you get an upper bound for the ground state energy when you can not directly solve the Schrödinger's equation. How does it work? (1) Pick any normalized function. (2) The ground state energy Egs is 3) Some choices of the trial function will get your Egs that is close to actual value. If you picked a function with a parameter, minimize the resulting expression for. Substitute resulting value of the parameter into to get lowest upper bound on Egs.

5 Lecture 27st Page 5 L27.P5 WKB approximation This method allows to obtain approximate solutions to the time-independent Schrödinger equation in one dimension and is particularly useful in calculating tunneling rates through potential barriers and bound state energies. "Classical" region, E > V General solution is the combination of these two. If E < V (non-classical region), then p is imaginary but we can still write Transmission probability: over non-classical region Formulas above are derived with the assumption that the potential is slowly varying in comparison with the wavelength λ (or 1/κ for E<V). This is not the case for the turning points, where "classical" region connects with "non classical" region. In this case WKB approximation breaks down. Note: make sure that you know how to apply connection formulas to derive quantization conditions 0 for potential with two vertical walls at x1 and x2 for potential with one vertical wall at x1 for potential with no vertical walls. turning points

6 Lecture 27st Page 6 Scattering L27.P6 Differential (scattering) cross-section: Total cross section is defined as the integral of D( ) over all solid angles: Quantum scattering theory Our problem: incident plane wave traveling in Z direction encounters a scattering potential that produces outgoing spherical wave: Particle energy Therefore, the solutions of the Schrödinger equation have the general form: scattering amplitude

7 Lecture 27st Page 7 Partial wave analysis L27.P7 For spherically symmetric potential, the scattering amplitude may be calculated using partial wave analysis formula The partial wave amplitudes are found by solving the Schrödinger equation for the area where V 0 and using the boundary conditions. Substituting the expression for the partial wave scattering amplitude (1) into the formula for the differential cross section and integrating over all solid angles yields simple expression for the total scattering cross-section: Scattering amplitude in Born approximation. As before, the differential and total cross sections are given by (1) Low-energy scattering (2) Spherically symmetric potential.

8 Lecture 27st Page 8 L27.P8 Notes on the exam preparation & exam taking: 1. Make sure that you know, understand and can use all formulas and concepts from this lecture. 2. Make sure that you can solve on your own and without looking into any notes any problem done in class in Lectures or from homeworks (if integrals are complicated, use Maple, Matematica, etc.) 3. During exam, look through all the problems first. Start with the one you know best and the one that is shortest to write a solution for. 4. Make sure that you read the problem very carefully and understand what is being asked. If you are unsure, ask me. 5. To save time, make sure you are not repeating the same calculations. For example, if you need to do several similar integrals, make sure that you are not redoing the ones you have already done. If you are out of time and you have not finished, write an outline of what you would do to finish the problem if you had time.

9 Lecture 27st Page 9 P1 Practice final Problem 1 Three imaginary "spinless" fermions are confined into a one-dimensional box of length L. The confinement potential is V = We assume that there is no interaction between the fermions. What is the ground state? Find its energy and write the corresponding wave function(s). Is it degenerate?

10 Lecture 27st Page 10 Problem 2 Consider a quantum system with just three linearly independent states. Suppose the Hamiltonian, in matrix form is where c is a constant, c «1. Calculate first-order and second-order corrections to the energies.

11 Lecture 27st Page 11 P2

12 Lecture 27st Page 12 Problem 3 A particle of mass m is in a one-dimensional potential given by for x 0, where K is a positive constant, and with infinite potential barrier at x=0. Using the trial wave function make the best estimate of the ground state energy.

13 Lecture 27st Page 13 Problem 4 Use WKB approximation to find the energy levels of "half-harmonic oscillator": otherwise Solution

14 Lecture 27st Page 14 Problem 5. Use low-energy scattering in Born approximation to calculate differential and total cross sections for low-energy soft-sphere scattering,

15 Lecture 27st Page 15 Possibly useful formulas Solutions for one-dimensional infinite square well of width a:

16 Lecture 27st Page 16 Connection formulas when potential slopes upward: If the potential slopes downward, the connection formulas are: