Supplementary Figure S1. Hole collection layer photovoltaic performance in perovskite solar cells. Current voltage curves measured under AM1.

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1 Supplementary Figure S1. Hole collection layer photovoltaic performance in perovskite solar cells. Current voltage curves measured under AM1.5 simulated sun light at 100mWcm -2 equivalent irradiance for inverted architecture devices incorporating V2O5 (black squares) and NiO (red circles) p-type hole collection layers.

2 PEDOT:PSS NiO V a) b) c) 2 O 5 d) e) f) Supplementary Figure S2. Perovskite film formation on p-type layers. Scanning electron microscopy (SEM) top view of perovskite films processed on a) and d) PEDOT:PSS, b) and e) NiO, c) and f) V2O5. Scale bars on the top row correspond to 25 µm and those on the bottom row correspond to 2.5 µm.

3 Supplementary Figure S3. Electron collection layer photovoltaic performance in perovskite solar cells. Current voltage curves measured under AM1.5 simulated sun light at 100mWcm -2 equivalent irradiance for inverted architecture devices incorporating a PC60BM and TiOx bilayer (top, red line), a PFN layer (middle, green line) and a PC60BM layer (bottom, blue) as electron collection layers.

4 Supplementary Figure S4. Typical power conversion efficiency (PCE) distribution for a batch of 40 devices.

5 Supplementary Figure S5. Light intensity dependence of the photovoltaic performance for an inverted device. JV curves were measured under AM1.5 simulated sun light for a range of light intensities (see legend for equivalent intensity in suns where 1 sun is 100mWcm -2 equivalent irradiance). The attenuation was achieved via metal mesh and measured with a KG5 filtered silicon reference cell.

6 10 minutes between first and last scan Supplementary Figure S6. Evolution of the current voltage curves for an inverted architecture device under constant illumination. Measurements were performed under AM1.5 simulated sun light at 100mWcm -2 equivalent irradiance, lighter curves correspond to more aging. 1 minute of full sunlight illumination was waited between scans.

7 Supplementary Figure S7. Perovskite film formation on PEDOT:PSS covered FTO and ITO. SEM top view of perovskite films processed under the same conditions on (left) FTO/PEDOT:PSS and (right) ITO/PEDOT:PSS. Scale bars correspond to 25 µm. Surface coverage for films grown on FTO/PEDOT:PSS in this image is approximately 90%, whereas those grown on ITO/PEDOT:PSS are approximately 80% as determined by the imaging software ImageJ.

8 Supplementary Figure S8. Phovoltaic performance of a regular device architecture incorporating an unsintered TiOx compact layer. Current-density voltage curve was measured under AM1.5 simulated sun light at 100mWcm -2 equivalent irradiance. The TiOx layer prepared in the same way as the TiOx layer in the inverted cells.

9 Supplementary Figure S9. Thickness dependence of perovskite films on PEDOT:PSS. Cross-sectional SEM images of perovskite films deposited on FTO/PEDOT:PSS spincoated at 2000 rpm with increasing precursor concentration from 10 wt% to 40wt%, with the furthest on the right at 1000 rpm and 40wt%. Scale bar represents 500 nm on all images. There are two layers discernible in the images, the bottom poly crystalline layer is the FTO coating and the top smooth layer is the perovskite film. The PEDOT:PSS is not apparent, since it is only a thin coating upon the FTO.

10 Supplementary Figure S10. Absorption spectrum for a series of thickness of the perovskite layer thickness. Layers were processed on PEDOT:PSS coated FTO glass. The measurements were performed with an integrating sphere, and are the single pass absorption through the films. In the devices, there are two passes due to the reflective Al electrode employed. 90% of the light which passes through the FTO, integrated between 350 to 750nm, is absorbed with a single pass through a 600 nm layer of the perovskite.

11 Supplementary Figure S11. Short circuit current density extracted from current-density voltage curves for a series of perovskite films of different thickness. Measurements were performed under AM1.5 simulated sun light at 100mWcm -2 equivalent irradiance.

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