i"hvsleai! SCIENCES LIBRARY THESIS

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2 ihvsleai! SCIENCES LIBRARY THESIS on d,

3 or on in ij l::n 1 1 1:1 ) er d no ' z co no 116 ( 1 ot i t t v 1 c cr c t'> /,

4 e.) t t ( 1 c or c e j it 1 tj O-Il 1 1'1 t t 4) f:} c::- l v t o- t :Lt lo t t o:u 1

5 con io:n chlc.n i 11 n. to AZnCJL>. ' tine, G. 1 t i zlno ( '!' \w t., t; 1 (J ( c c on 1JB 1.18 :ions little to i

6 t'llfj t fj if not.i.l reli for, 'l 1 he t:l on wcu1 to on f e lu11 tb, IJO tcxn ulu Gt)l 1i ouo Oilt: Le 11 i11 ter, o cl is one, ti on ernnot b un Jne ion of t tlv to ( i :for 1 1 1

7 y 4- fl., A.D X 1-lq

8 - D - AD -t- DC. in e chl d, all no zinc ori. c if z CX.C8tlfl, to :form nc tem becnrne ex 1> nc clll in CJC xture V(.;tt i:n e c 'in or of e elsmtu;te (} t, if we (1-x) no c nc o.cj t, A rc c of ne Xi y e to ;roficl:l t 1 co j te J. v :i :ce 1., uc hr C3 i,j-.l i

9 - (j - e t (i.,e., o) ( i e ) of (i.e. ) lj \ ZnO) e tt i on +C it to f c I \, in + + ( + ( + t cl ene c CJ:i'L

10 - / t i 'Lion i r j l L of o vo i 1 i 1 L (Jrt.,., Jon. 1 t. t out :i :L 1.1 t c j r i on

11 8 on, 11 on b b 1 ' if' d i s i e t., J. 1 o eet f.1l:tt n it i i 11 i (_,, f_), nc ut ) ]nc

12 d 1 1 :}7 n It 5 r/!i '{ G., 1 n t4 3 1 If I J.,. 1 e Vtte ( 1.D.).

13 1 # II II!l 1 t '1'1 f? q f 8,1 1 II 1 n.,1 't. ;J!I ( ch i ili 1 t nt j :ir

14 1 ' (\ ;,? 3 rc -,_ ' w f' i} 1 r} 1 1 l., -.,,: o 1 i( L cro \ P1 in f nc i li

15

16 it D e ton i c OfJ tion curve on ( ' ' l It ( 1 c c (l t l 1 t Ofl

17 icn. l in one, it th f oil on GdTltC'F.lt :cn.n

18 14. 1 te:c cleliyer l) till., I on 'I i) t 'C no (t', tl:l:l c foj.' d ::; 11 i,)llf} i lll1jo.f:1 e :l Uli1 n no on ne ton sij:vcr t j 'C: t t b 1 ( 11'7

19 c 1 one ) :ee tion c '. t u 1 j. id Z 1Ce to ;) c.c t:it o:n e :f 1

20 eolo1n t ton lj. j t on 1Jot t or t J

21 i in i ome t:i.@) in olu 1 fi u n!j e J (l :i. n 1 r oi nc t, if seve re no

22 1J t 1 e to t O!!lt;.; - 5, i on 11 t j 1 f.; '

23 19. to 11 j t, er. so <1 e on in ti fhj d out.,. in tt 1 i t bot ion we o1n c.i fl () {J C <):C., t. 1 'i of lu. )on as of il on,

24 on ion ehl L \!

25 rce>ulta fro.m Den 5. y ' l ] 1 1,..9,.1 n?1g 1 1 t: ' 't._j'o., 91Z1 1 11'7 ) h.j.,., ;; '7 OOc.i!.); 1 ' 1,. (' 4,? -) t,! ;J.rr;r:,, ;.)it 11 JC1 1 c Pt 1., ' '7 '77 '-'--'''- 1'--' --'--''' T-,c!F--_.,-_, -=-, :; I I,J. ') o:; t) 1. $., 6 ; ft ) /i '7 :5(A?fjz l) <:r;., 6 fj J ;; 1!l_,-:;.' , 4 5.,1 \) lt:/1,Q IJ.Ll (1 rl {j,,,,. P} c ) j )?-_f.,1 1, ' ::J 1 1 (} ---' ---

26 oc, n J-j X y 1 1,. 'r/ 4., fl P\., '''II ' ' 5 l It 1 -' 1.o7a 1., )::t, v ,. 4 1., ( 14 '7?,.119 '!.,.!., f 1..,1 1;.?. a , Y1 i 5 1., 1 r t).,1'13 8,. f).. L, , 1., 4,. 1.,1 f3.,''19rlo It 1 1., '7.,.1 ') '' 'Ill

27 16,. 1 '{ V '7 65.,1.,1.,1 1 1, ib 1 1 ilyf '! t,.1_. J?,.1 r t ;;.,167 ( ]_7..,? G,. f> 1 '7., 1?; 6., '.?,.1?'1 1'7 l., n li () 1,. ---R 3 t}. [). '11.ll>? 17 G.,? 1.,l 1.,1'77,},..

28 j_ x: y 1.,, >.,31B., vo 4 g.,11, '/ 1 1 1,. 6.,1 ll \.l?l '( b. '' G n t:.j '' ' -' I ll- J. '79 1.j 1,. ;:. 7 1,. _q_ '!? u,:)\ Jlf.,()' r (.':, G, 4? '{ ' ; (5 :- ' -,t ' '7 e

29 }[O X y 1 1., 9,. 1 7., 1., 1 1!;)., '1 (!, 1.?,. ' 1 1 1,.119.,1 t1.,1. I '' l.r. 1 7.,1 ' 1.,:.,1 f) 1,.,, l), ;.j ,. 1 'lt 1 l,.j, 1,.?1 1 ''1 1,.9 <!!

30 y 1'7. 1 6, ,1'71 9,.4 t-.?,.,.,9'7'7 v , 1 1.,9 * o 1!l! 1

31 8 on, a wet so ti for t r cone en-, two coraon :for '1 or 8, waa3 i or<3 poj c n.ot tion or 4.} re it e of 1 :l. :t on

32

33 c 1 5 e to of y to 1 or on 1 1 j (l i J it on curve ot { lv) were c lines, exo t ace for in or = 1, y = t c not t J. are e ous in the ec on mo ott J

34 exes X::: o ' c on e in 1 so ons on ( 1 on t l 1 Ii ot s i tion l1cl fsurve on th

35 Y r' _ ' ngi z,o., 8 C.. lf1.p svre 'ZnO - H.,.,O ' HC/

36

37 t;ion 1 t:i oli J:c t on on. c {) :Lt t cu1 tt ' 1 er uf

38

39 .;) 1 '1,. :) l.::.s.,7 a 1? f' t-' r.j.u 1! 1.; e!jr r(., (} l C;.,. ''.,.l.?. (I f;<,.7 1, '7 5.,7 :- ),. '{,! 7 ' Ill', II u.,? , ::.> 7 *r; 1-6,) I').,1 '' b.,6 Ill.,1,, {; 1ft-' 1,.1 e-.j 1,1?.,_3.9 1 'l,4 4

40 er 1 1.9, 1 1 tt L1 1? g.,v 1,G 1,. l6., 4 I lit' ' ' '? 1?.,. 1.,1 G.,?. f) () 'J I) LJ lit lj..9 1 l 'I.,6?,5 l 1 t; :2i7. i-3,.6 i't ' 1

41

42

43 e 1'l<e e for c fo na t for. HO Vll t'or 5 Q d. F u, F ' t t or n f c i i t.o a Ennen td i:1 no in A.'.!. 1

44 -!- r,., '. I''' r -- I, _-r+ t - -t- - i r -; T - h r-- 'r-o-t-!!- -''a t- '' t-'1-t- -to j 4 t + - ' _ - t-.,_ t t : ; -- -H-I - :!... - i i ! 'j_ ' I - I. 'iit' r-. 1- ' n i. i - rt-r r-r--i 1 t-' 'J:'-+ - I I.' ' t -t- ---> ' - i ' ' I -t_;._ - -I ' t I ' I ----t---- '. t t , J. r +---: i 1- - I J -.L -._ - -p f - '1-1-1->----l-! - ' t-+--' I --- t. -- -f i- - - I h , --7' : r-----,._,_.,l _._._,_, t i r l L,_! I 1 ' : 1- I'. - t... :-, : - j I t L: t - l_-_ 1 i.:. I... t.. ' 1'! I! L ! - --' t j. : e. I J_ [: i: ;: : t ;_:.:::.:. i. :_: I_: ;::.',..:=::-'.:-=i. I I +- t- +-,.1 ' + - j - - t- -!-. r I t..-+ t... l I. ;. -- L-!-,. -.,.. t-. t +.,_. - 1' J_ t- --- r t ' i r.;. ' f ----r _. _j_,_, )--t,._.,_.,_, t_ f'-t--f !-4-'7-. - ' i - -. _, : l ' -..! L. L -.. t l. '!. ----'-. -.,. -. I.,, f i.. l' l '. I. -,. - I,_. r---., ; <- -l! L L_. L:.t. i.!. L trt -- -t to--+ -'!' _. t-..,.. _. 1 4,, I... J r., --' r t-- -- ' 1- ' 'I - T ! I 1 -,.. ['- I... 1._,_ r t- _ ,.. : - --:--:--:-4--==J-i-:_:_=r_:_ ;.: : :7:: L :;:: r. _:_=-=:=-=:=--: 1-. : : :. :..--:: : : :-i. -, _.:_:-:: :-;1--r ;_, l.. l f. ;-- '1 i. --. h r Tf - - i I ---! :_J_+,.-. J._, - - J- r- -r _,_- --L_, :! :+l- _t. ---!]-;-i.::w.,r' L-i I ;-I --1 I' r---r - h--t- + I ::=--=:::_, -: :-:_:t - t :: t --t : :-:- - -:- :.: L.:. ;- Jll.._II.:-.j-. -;-- - t ;-1 t -. L._,;_ 1- : _. :-, ;----. t r----:----! 1... I t. I--. i- -'1 --, - r- -:- - -r-t 1 l - - :r- T r---i- -1-T r r r--r-- r : : r = : -!. t = I = ; :-: -.,_,--t f. 1 : r i--.,-- '. 1-- t ii.lj. l l. ;:;T: -: [, i -;4.-: ;:r; : :y=;:r= L-1 - ;j t! _, I J -H- -1--l-- _,_,. -.. L -- - l -. i I. : - :-::-=! t t: :.:-.:! I i, ' t- r r - -,_. ----!l r- ::---: i.... :::-1.:.:::.1,_: : :; :_: - ;.:-; 1 -: 1 r r -- 1 t :.i f E : ;-:-c:: :r- : -i I i. I f-. :.! : J,1!- 1-. ' ; 1!. I t I ' I. - - l t : L +. - _, ' :_:_.::+:_:_ : ,.j =t..!1- -,i_ it, I., ' i ' j I ' ±: -... :; = - 1 t r l r : =tf J -+ t -. f. : - :- r----: r : :-- ---_-:::-1: : t :._:_: J.:-:l t.- : -!. t. L : :: t I ; - I. i T. 1 t. t I ; - t : : I t t - :l:=i: 1::, t 't.1!,.:1 - l : : - 1 : : I - I :... ' : :.! :.:-:: l - 1:- r-- T i t 8 \::::; >- :;. p : t I M -s J. ::z: f cs.

45 J)e'c:.iry I c- 1 ll T - -- t I I t -! I TT'lTnr r.,, :-:- -=- l : : l ;: : j j,.rm= - l. I J I I I I I I I I r : - r - -:- t t - r i r 1-;- 1- r- t r 1 --' 1 ' i : _r_:_ 1 + t- t 1 -r t t + t.1- li 1 I l.,_ t ' I 4 1 I 1- ; I :.l, -j- -t ; : ; j ; : i l, L. I, j I I ]! - --._.-T;.-.t- -r: ' ' ' I I ;. : I I J I I I ' I I -t --r t 1 + -, - - I. -. '! f 1 1 T ' ' I ) ' I ' t t i ; i 1 ; r : i - i i t i : 1- ; '1 I : r i i I l ;! ; I : l 1 ' I rri : iji ; t li'tiiil 1 i::.i', in:i 1 1 ''i --n : r -. -r 1 i - ' - : jj - r i : r i : i : r 1 1 r i r r l i i 1 1, r l: r- Iii h l 1 1 l--- i- i w., -- : ; i i. I :. f j t.. : ' - '. ' t I>. I t- - - Iii i r r 7 1 i-!.- \ r.,- i. r : f! I ; j. -- -i-1-; -:_f--1 : t_: ::::--=t =-rj I+' r. F.- -:1.-!.J J. i ; 1 i i i.. i ; : : ;! ; ' ' i 1 - t-f--:- l - -: r i : t t l 1 t r! f j 1 :,_,_ ' 1, t i I i t, r i 'I I i 1.,_L t-:.l t 1 r _, ; i i t- i-1' '!,..... n I. 'I I : : f i, -. Ll' ,_J_, -'. I i -.J_ 1 i ; 1 i ; i.. r -t - ; J 1 i d. 'IT r'-; -!. ' l ' i. I - :.,. ' T ' ' ' ' _;! ; I :.. -t -! H-1-:; 1 H i i L! f i f- 1!. i. :. i j f j. I,- - '.,-+-! 'T ,.!1-±--!.l-.-l-L J' j'i! tr!.!.+ r,, i..' 't1 l I. I l I I I !. -,_.. 1 I I. I _ i,,. ' I ' I I. J ' ' I. - f,_,-j_, l I -,,,,.,, :. ;. I,, : ;, l -r--i-r. f :,. - f t i i 1 j. ll i - -, t ; I I 3 I I- ' I. -. r- j,,_.-!- ---.! - r '----, I.,. >- i + ' T. -'1 T -- T. l I ' ' T J ; I. 1 r t - f-1 1,. I... h ; - - I n- - I - i - -i t - r 1 1 : r i. i - -! - J :----j I. l..... i I f. : I ' ;. 1 '!. ' ' t j l p l!-!-: -. -! t l ' ' ; ' :. _ j! - t '!! i J l.!!! ; I! - W-1 ' ' ±...., I,.,.,.1. '.. I ; '1 -I. I. '. _-1 1 J. I : I I - ' 1!,), T ;. I -- L. ' l lr r r L. L.!.1 l I I! I : :!' I I 1 l ' I. : --H+ I I t. : i i I j. ' : : ' I.... t!' 4 t I I - --i- -- -,_ t l. t t.. I + I -..,. r -. : l 1 i ' ; - ' t 1 : j l H- 1 : ', i I r _ : ;! : 1 ; r ' ) t-r-r--.-,,. +-. l-;.,. -1--H-- - t--:.,._ --,- r ,. -.,! j ' 1 <I 1-.t.. ' - t-., t t ' t --! j., 1--! - + j.l.! - I i t 1., '! t o l 1 I I t 1 T - t i I \- :!-- - T - l i ' 'i- 'I. ;. ' : ' _,.-'-+--4-r- r , _I ,._. --' -l _ t.!,. t jl.:l. jtl j,.. J ;. _;. -. I.; I..... I i : : ;.. ' 1- ' : i. ; l '.. ' ' --m-. r ' 1 r i i i.., I I 1,! I 't t- l! f. l I _ I ; 1.,.. t. l 1 : t. I r 1 : 9 T',I. L -1-. ' 1 t ;_ - ;_, t ;- t. I. ' ; :. II '1 '. I. ' I : l :. '.,. I t ' l t I : I 1' l : ' I ' I ' I :!. 1 ; ' r-t L. 1! T I j ; t 1 ' ; I 1 j ' : 1 ',. - t=_ 1.:J :.l i 1 : i'!h 1 'j f - j 1 ii 1r :' : t. t,. - r., I I.. ' - :.++. i ' I..,,.! l t r,. J - _ -. - r-t--r J j j' :t i ---:-,--, -- 1-;--.-t t,. _;_ 'rr +- '!- I. I l. I -,. J. 1 t J, t ' :! ' '. I 1. J ;.;, -.;. t.,.! I, '--! -. '! i. ;!. I' L ' ; I.. '. t!! '. i..... I. ; +. l t. ;_ I.:_;. i t } j 4 1 f,. ' +- i 1- -r-:,.-. ; --:i.ol : _, r :-- i -... T - i r,.!' r. I. I '. :. 1 i. - ;. i'' rl :. '. - I T 1 I.. t--:- t. f 1 i r r 1 : ;, f 1 ---'. _._- -+- I I - _..-_ , i- -- t -. fm,,. '--'-r :, r i ; r-: t : i -t, f '. r - i r - ; - -t. -i 1 _w --± _ t.l.,,_ 1 - l -Lr ;.,.,!! ; 1, 1 i 1, t 1 i..! , - r. L.bii. I J.. J±i. i llr' r,. r l +! l + l!, '., ;! ; I l ;. i.. 1' LJ H, -t,!.!.!.l!.-t l t ;,!j,.!l l! I II :!-.!.. J 2. I+ r; Jlt> (11 tl,, ( bt> u;u \.DD -t.o 1.4 d.ro.m<;, 'Z.CI. r--e\ IOO r '!. ')Co ri*. EII

46 el B are es on tallic and etea,.cdo. is beryllium sium it :rnust not be no ahlori of curve., to ion curvec At the s.l)jlutions were ti ties of solutions are in lx. Vlll, ti in black e s of ot zinc oxide solutions were and to one ' th a in tion the so

47 but a a me fo IJOint 9., re the ;),me manner a curve ( 1) was ob lity oxide Driot 1 e to ons er 1 1 oxide 5,.6 dis so i solut!on to oool no to a.mount of was tated 6 tion At. oc. e curve roee to a h to rat the BO ion cttrve eae a aeooncl curves of After i more on in on the ent. ints of be o no pres ll 1 rom that 11 error ther no on error the zinc the chlori is e (11). same curve

48 1 grm >7 ;::; 1, ,.?, , ll , ,,.7 1., ,/7 1. F A 3.,15 1,.5 11? , 5? ,9 1 1:2., 3.,39 1.,646 l}n 4.,4 2 1., 5

49 1 5. 1,. ' , v., 1,.77 1 h 1 1 lo7 JP l-;-j 1 J 1., 3.,4 l 7 2,.9 1., 'I 4 1 :53 1 '794 2,.3 l.,b 4,. 1., rf i ),., 9'71 o 5.,1

50 1 er i Zn 't,/ 1, , 2 9 -n F;!'; )? , , , G , , ,. 3.,4

51 C.ro. Zr. Cl,_ p.,. t oo ra. H-. t\g. lx.

52 r , ,.--- ',_ I 1,. o. * - -. r 4 _i. 1-! ;...- r-,_ I 1 I :--: : t- t '. - I -.. j ' - f-- lo I., l. _ t::: =t: -. ::.:., '7!- ---.L. r r+-r- -i.... t.. r----y ' I I 1_-: : ::::::::::: : -1 =.. :. I r 1 -;t= -l: i. :. : i r - ---r.::: f ' I I-: I. i_[' -- t1_. =r. t-±-r.-:-+ :-:,.-. o i :.1 T t : t : :_: T :. R : :-r : t:.. t-- L:._ r-:--! : - : t ::: ;' : t - i. -r - t L ! 'j I c_ t-:.: : : J ',. - -i.._. -L.. I I , -._ I : - '. ' 1! t.!! r-- '( r J I - --._,,_,,_ ' I i. t - --J-!.. L ' - l. ' E ' Ci. -u N Ci). t h L l.. i - L l l ,---- r I i. il J.j),) r. '. l.l t- 'i : 1 -L. -- I : 1-- I f L. ' - :f. T -. I. r... : :. :=-t--:-: ---- i -; -:)'\ : j. f I -l _, --r i ' : :+ := : L -. - I. i ;,T j., I I I. I ----,--- t I., t j i - :: : J : :.: ; : : : --j l-l--- t- c N IJ l t. -. i I t d J. r-. _,_r:-: ',_._ ' t, r ---r--- - T..,. <l Q c :r ojo E _, c '?! 1.! lo. \\ ) \j c t:4 2,/' E Cl. \.S

53 4, libri c studi nc so ems e of' nevv a o cone on was f to tione xnore co was cone in e oolu.tioll.b a con ons,. 6., e f re.

54 tions nc in chl solu-

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