Quantum Mechanics CHEM/ENCH 313
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1 Quantum Mechanics CHEM/ENCH 313 Instructor: Soran Jahangiri Instructor Contact Information Office: Chernoff Hall, Room 313 Office Hours: Monday 2:30PM - 3:30PM, Tuesday 10:30AM - 11:30AM TA: Sangeeth D. Kallullathil TA Contact Information: sdk4@queensu.ca Office: Chernoff Hall, Room 314 Lectures Times and Place Monday 1:30PM - 2:30PM McLaughlin RM315 Wednesday 12:30PM - 1:30PM McLaughlin RM315 Friday 11:30AM - 12:30PM McLaughlin RM315 Tutorial Time and Place Wednesday 10:30AM - 11:30AM Dunning RM12 Intended Student Learning Outcomes At the end of CHEM/ENCH 313, students will be able to Describe the historical development of quantum mechanics. Explain the postulates and general principles of quantum mechanics. Solve the Schrödinger equation for systems such as the particle in a box, harmonic oscillator, rigid rotor, and the Hydrogen atom. Apply the variational method and perturbation theory to multi-electron systems. Apply quantum mechanics to describe the electronic structure of molecules and calculate molecular properties. Provide a quantum-mechanical description for chemical concepts such as atomic and molecular orbitals, chemical bonds, and atomic charges. Course Outline Chapter 1: Fundamental Concepts and Background 1.1. The wave-particle duality 1.2. Blackbody radiation and the photoelectric effect 1.3. The double-slit experiment and de Broglie waves 1.4. Partial differential equations 1
2 Chapter 2: The Postulates of Quantum Mechanics 2.1. Wave functions in quantum mechanics 2.2. Operators in quantum mechanics 2.3. The Schrödinger equation 2.4. Evaluation of properties in quantum mechanics Chapter 3: The Particle in a Box 3.1. The particle in a one-dimensional box 3.2. Wave functions and energy levels of the particle in a box 3.3. The Heisenberg uncertainty principle 3.4. The particle in a two- and three-dimensional box Chapter 4: The Harmonic Oscillator 4.1. One-dimensional harmonic oscillator 4.2. Harmonic oscillator wave functions and energy levels 4.3. Tunneling in quantum mechanics 4.4. Vibration of a diatomic molecule Chapter 5: The Rigid Rotor 5.1. One-particle orbital angular momentum 5.2. Spherical coordinates 5.3. Wave function and energy levels of a rigid rotor 5.4. Rotation of a diatomic molecule Chapter 6: The Hydrogen Atom 6.1. The Schrödinger equation for the Hydrogen atom 6.2. Spherical harmonics and atomic orbitals 6.3. Energy levels of the Hydrogen atom and quantum numbers 6.4. Electron spin and spin-orbit coupling Chapter 7: Many-Electron Atoms 7.1. The Schrödinger equation for the Helium atom 7.2. The variational method 7.3. The Pauli exclusion principle 7.4. The Hartree-Fock method Chapter 8: Molecular Electronic Structure 8.1. The Born-Oppenheimer approximation 8.2. Basis functions and molecular orbitals 8.3. Electron correlation and perturbation theory 8.4. Chemical bonds and atomic charges Textbooks/Readings Reference book: Quantum Chemistry, Ira N. Levine, 7 th edition Additional reading: Quantum Chemistry, Donald A. McQuarrie, 2 nd edition Both books are available in the library. 2
3 Grading Scheme 3 Assignments Assignment 1 due: October 5 (5 %) Assignment 2 due: November 2 (10 %) Assignment 3 due: November 30 (10 %) 2 Quizzes Quiz 1: October 19, in class (15 %) Quiz 2: November 16, in class (15 %) Final exam (45 %) Grading Method All components of this course will receive numerical percentage marks. The final grade you receive for the course will be derived by converting your numerical course average to a letter grade according to Queen s Official Grade Conversion Scale: Queen s Official Grade Conversion Scale Numerical Course Grade Average (Range) A A A B B B C C C D D D F 49 and below Copyright of Course Materials Materials generated by instructors of this course, including assignments and quizzes, are copyrighted and may not be shared with anyone other than students registered in this course. Statement of the Location and Timing of Final Examinations As noted in Academic Regulation 8.2.1, the final examination in any class offered in a term or session (including Summer Term) must be written on the campus on which it was taken, at the end of the appropriate term or session at the time scheduled by the Examinations Office. The exam period is listed in the key dates prior to the start of the academic year in the Faculty of Arts and Science Academic Calendar and on the Office of the University Registrar s webpage. A detailed exam schedule for the Fall Term is posted before the Thanksgiving holiday; for the Winter Term it is posted the Friday before Reading Week, and for the Summer Term the window of dates is noted on the Arts and Science Online 3
4 syllabus prior to the start of the course. Students should delay finalizing any travel plans until after the examination schedule has been posted. Exams will not be moved or deferred to accommodate employment, travel/holiday plans or flight reservations. Academic Integrity Queen s students, faculty, administrators and staff all have responsibilities for supporting and upholding the fundamental values of academic integrity. Academic integrity is constituted by the five core fundamental values of honesty, trust, fairness, respect and responsibility (see and by the quality of courage. These values and qualities are central to the building, nurturing and sustaining of an academic community in which all members of the community will thrive. Adherence to the values expressed through academic integrity forms a foundation for the "freedom of inquiry and exchange of ideas" essential to the intellectual life of the University. Students are responsible for familiarizing themselves with and adhering to the regulations concerning academic integrity. General information on academic integrity is available at Integrity@Queen's University, along with Faculty or School specific information. Departures from academic integrity include, but are not limited to, plagiarism, use of unauthorized materials, facilitation, forgery and falsification. Actions which contravene the regulation on academic integrity carry sanctions that can range from a warning, to loss of grades on an assignment, to failure of a course, to requirement to withdraw from the university. Calculator Policy As noted in Academic Regulation 9.2, Calculators acceptable for use during quizzes, tests and examinations are intended to support the basic calculating functions required by most Arts and Science courses. For this purpose, the only approved and permitted calculator for Arts and Science courses and exams is the Cassio 991 series. This calculator sells for around $25 at the Queen's Campus Bookstore, Staples and other popular suppliers of school and office supplies. Turnitin Statement This course makes use of Turnitin, a third-party application that helps maintain standards of excellence in academic integrity. Normally, students will be required to submit their course assignments to through onq to Turnitin. In doing so, students work will be included as source documents in the Turnitin reference database, where they will be used solely for the purpose of detecting plagiarism. Turnitin is a suite of tools that provide instructors with information about the authenticity of submitted work and facilitates the process of grading. Turnitin compares submitted files against its extensive database of content, and produces a similarity report and a similarity score for each assignment. A similarity score is the percentage of a document that is similar to content held within the database. Turnitin does not determine if an instance of plagiarism has occurred. Instead, it gives instructors the information they need to determine the authenticity of work as a part of a larger process. Please read Turnitin s Privacy Pledge, Privacy Policy, and Terms of Service, which governs users relationship with Turnitin. Also, please note that Turnitin uses cookies and other tracking technologies; however, in its service contract with Queen s Turnitin has agreed that neither Turnitin nor its third-party partners will use data collected through cookies or other tracking technologies for marketing or advertising purposes. For further information about how you can exercise control over cookies, see Turnitin s Privacy Policy: Turnitin may provide other services that are not connected to the purpose for which Queen s University has engaged Turnitin. Your independent use of Turnitin s other services is subject solely to Turnitin s Terms of Service and Privacy Policy, and Queen s University has no liability for any independent interaction you choose to have with Turnitin. 4
5 Accommodations Statement Queen's University is committed to achieving full accessibility for persons with disabilities. Part of this commitment includes arranging academic accommodations for students with disabilities to ensure they have an equitable opportunity to participate in all of their academic activities. If you are a student with a disability and think you may need accommodations, you are strongly encouraged to contact Student Wellness Services (SWS) and register as early as possible. For more information, including important deadlines, please visit the Student Wellness website at: Academic Considerations for Students in Extenuating Circumstances The Senate Policy on Academic Consideration for Students in Extenuating Circumstances ( ndtrustees/academic%20considerations%20for%20extenuating%20circumstances%20policy%20final.p df) was approved in April, Queen s University is committed to providing academic consideration to students experiencing extenuating circumstances that are beyond their control and which have a direct and substantial impact on their ability to meet essential academic requirements. Each Faculty has developed a protocol to provide a consistent and equitable approach in dealing with requests for academic consideration for students facing extenuating circumstances. Arts and Science undergraduate students can find the Faculty of Arts and Science protocol and the portal where they submit a request at: 5
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