7. Non-LTE basic concepts
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1 7. Non-LTE basic concepts LTE vs NLTE occupation numbers rate equation transition probabilities: collisional and radiative examples: hot stars, A supergiants 10/13/2003
2 Spring 2016 LTE LTE vs NLTE each volume element separately in thermodynamic equilibrium at temperature T(r) 1. f(v) dv = Maxwellian with T = T(r) 2. Saha: (n p n e )/n 1 = T 3/2 exp(-hν 1 /kt) 3. Boltzmann: n i / n 1 = g i / g 1 exp(-hν 1i /kt) However: volume elements not closed systems, interactions by photons è LTE non-valid if absorption of photons disrupts equilibrium
3 Equilibrium: LTE vs NLTE Processes: radiative photoionization, photoexcitation establish equilibrium if radiation field is Planckian and isotropic valid in innermost atmosphere however, if radiation field is non-planckian these processes drive occupation numbers away from equilibrium, if they dominate collisional collisions between electrons and ions (atoms) establish equilibrium if velocity field is Maxwellian valid in stellar atmosphere Detailed balance: the rate of each process is balanced by inverse process
4 Spring 2016 LTE vs NLTE NLTE if rate of photon absorptions >> rate of electron collisions I ν (T)» T α, α > 1» n e T 1/2 LTE valid: low temperatures & high densities non-valid: high temperatures & low densities
5 Spring 2016 LTE vs NLTE in hot stars Kudritzki 1978
6 Spring 2016 NLTE 1. f(v) dv remains Maxwellian 2. Boltzmann Saha replaced by dn i / dt = 0 (statistical equilibrium) for a given level i the rate of transitions out = rate of transitions in rate out = rate in i n i X j6=i P ij = X j6=i n j P ji rate equations P i,j transition probabilities
7 Calculation of occupation numbers NLTE 1. f(v) dv remains Maxwellian 2. Boltzmann Saha replaced by dn i / dt = 0 (statistical equilibrium) for a given level i the rate of transitions out = rate of transitions in RATE EQUATIONS lines ionization lines recombination Transition probabilities radiative absorption emission collisional
8 Occupation numbers can prove that if C ij À R ij or J ν à B ν (T): n i à n i (LTE) We obtain a system of linear equations for n i : Where matrix A contains terms: combine with equation of transfer: non-linear system of integro-differential equations
9 Spring 2016 complex atomic models for O-stars (Pauldrach et al., 2001)
10 Occupation numbers Iteration required: radiative processes depend on radiation field radiation field depends on opacities opacities depend on occupation numbers requires database of atomic quantities: energy levels, transitions, cross sections levels per ion 3-5 ionization stages per species» 30 species è fast algorithm to calculate radiative transfer required
11 Transition probabilities: collisions probability of collision between atom/ion (cross section σ) and colliding particles in time dt: ~σ v dt v collision cylinder: all particles in that volume collide with target atom rate of collisions = flux of colliding particles relative to atom/ion (n coll v) cross section σ. for excitations: σ coll from complex quantum mechanical calculations and similarly for de-excitation
12 Transition probabilities: collisions in a hot plasma free electrons dominate: n coll = n e v th = < v > = (2kT/m) 1/2 is largest for electrons (v th, e ' 43 v th, p ) f(v) dv is Maxwellian in stellar atmospheres established by fast belastic e-e collisions. One can show that under these circumstances the collisional transition probabilities for excitation and de-excitation are related by
13 Transition probabilities: collisions for bound-free transitions: collisional recombination (very inefficient 3-particle process) = collisional ionization (important at high T) In LTE:
14 Transition probabilities: collisions Approximations for C ji line transition i à j Ω ji = collision strength for forbidden transitions: Ω ji ' 1 for allowed transitions: Ω ji = (g i / g j ) f ij λ ij Γ(E ij /kt) max (g, exp(e ij /kt) E 1 (E ij /kt) g = 0.7 for nl -> nl =0.3 for nl à n l
15 Transition probabilities: collisions for ionizations = 0.1 for Z=1 = 0.2 for Z=2 = 0.3 for Z=3 photoionization cross section at ionization edge
16 Transition probabilities: radiative processes Line transitions absorption i à j (i < j) probability for absorption integrating over x and dω (dω = 2π dµ ) emission (i > j)
17 Transition probabilities: radiative processes Bound-free photo-ionization i à k σ v for photons photo-recombination k à i
18 LTE vs NLTE in hot stars Kudritzki 1979
19 LTE vs NLTE in hot stars Kudritzki 1979 difference between NLTE and LTE in Hγ line profile for an O-star model with Teff = 45000K and log g = 4.5
20 LTE vs NLTE in hot stars Kudritzki 1979 difference between NLTE and LTE Hγ equivalent width as a function of log g for T eff = 45,000 K NLTE and LTE temperature stratifications for two different Helium abundances at T eff = 45,000 K, log g = 5
21 LTE vs NLTE: departure coefficients - hydrogen β Orionis (B8 Ia) T eff = 12,000 K log g = 1.75 (Przybilla 2003)
22 Rome 2005 N I N II Nitrogen atomic models Przybilla, Butler, Kudritzki 2003
23 LTE vs NLTE: departure coefficients - nitrogen
24 LTE vs NLTE: line fits nitrogen lines
25 log {n i /n i LTE } FeII Przybilla, Butler, Kudritzki, Becker, A&A, 2005
26 Brackett lines LTE vs NLTE: line fits hydrogen lines in IR
27 J-band spectroscopy of red supergiants Cosmic abundance probes out to 70 Mpc distance α Her Davies, Kudritzki, Figer, 2010 MNRAS, 407,1203
28 Red supergiants, NLTE model atom for TiI! Bergemann, Kudritzki et al., 2012
29 TiII Bergemann, Kudritzki et al., 2012 TiI
30 Red supergiants, IR lines and connected transitions for TiI! Bergemann, Kudritzki et al., 2012
31 Red supergiants, IR lines fine structure levels for TiI! Bergemann, Kudritzki et al., 2012
32 Red supergiants, IR lines departure coefficient for TiI! Bergemann, Kudritzki et al., 2012
33 Red supergiants, IR lines for TiI: NLTE vs. LTE! Bergemann, Kudritzki et al., 2012 NLTE LTE
34 Red supergiants, IR lines NLTE abundance corrections for TiI! D(NLTE-LTE) = log{n(ti)/n(h)}nlte log{n(ti)/n(h)}lte! Bergemann, Kudritzki et al., 2012
35 AWAP 05/19/05 complex atomic models for O-stars (Pauldrach et al., 2001)
36 Pauldrach, 2003, Reviews in Modern Astronomy, Vol. 16 AWAP 05/19/05 consistent treatment of expanding atmospheres along with spectrum synthesis techniques allow the determination of stellar parameters, wind parameters, and abundances
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