CHM 152 Practice Final
|
|
- Lillian Jennings
- 6 years ago
- Views:
Transcription
1 CM 152 Practice Final 1. Of the fllwing, the ne that wuld have the greatest entrpy (if cmpared at the same temperature) is, [a] 2 O (s) [b] 2 O (l) [c] 2 O (g) [d] All wuld have the same entrpy at the same temperature. [e] Mre infrmatin wuld be needed t make a selectin. 2. A prcess will be nnspntaneus at all temperatures if [a] the enthalpy change is and the entrpy change is +. [b] the enthalpy change is + and the entrpy change is +. [c] the enthalpy change is and the entrpy change is. [d] the enthalpy change is + and the entrpy change is. [e] all reactins will be spntaneus at sme temperature. 3. Given the fllwing standard state free energies f frmatin, G f (kj/ml) 2 O (l) NO 3 (l) 79.9 NO (g) 86.7 NO 2 (g) 51.8 Calculate G fr the reactin: 3NO 2 (g) + 2 O(l) 2NO 3 (l) + NO(g) [a] G = 8.7 kj [b] G = 192 kj [c] G = 414 kj [d] G = 192 kj [e] G = 155 kj 4. Cnsider a reactin fr which = 13.2 kj and S = 125 J/K. Calculate G rxn fr this reactin at a temperature f 95.0 K. [a] 25.1 kj [b] 13.3 kj [c] 13.1 kj [d] 11.9 kj [e] 1.33 kj 5. Cnsider the reactin, 2SO 2 (g) + O 2 g) 2SO 3 (g) G fr this reactin is 142 kj. Calculate the G fr this reactin at 25 C when the partial pressures f the gases are as fllws: P(SO 2 ) = atm, P(O 2 ) = atm, and P(SO 3 ) = atm. [a] 130 kj [b] 4.8 kj [c] 142 kj [d] 147 kj [e] 154 kj 6. The activatin energy f a reactin may be lwered by, [a] increasing the cncentratin f the reactants [b] increasing the temperature [c] adding a catalyst [d] answers b and c are bth crrect [e] answers a, b, and c are all crrect.
2 Cnsider the fllwing reactin and data fr questins 7 and 8. Exp# [NO] [ 2 ] Rate (ml/l s) M 0.20 M M 0.30 M M 0.20 M NO N O 7. If 2 were disappearing at the rate f ml/l s, N 2 wuld be appearing at the rate f, [a] ml/l s [b] 0.16 ml/l s [c] ml/l s [d] 0.24 ml/l s [e] The rate f N 2 appearance can nt be determined unless the temperature is knwn. 8. The rate law fr the reactin is, [a] rate = k[no] 2 [ 2 ] 2 [d] rate = k[no] 2 [ 2 ] [b] rate = k[no][ 2 ] 2 [e] nne f these are crrect. [c] rate = k[no][ 2 ] 9. The reactin 2NO 2NO + 2 is fund t bey the rate law, rate = k[no] 2. Of the fllwing three pstulated mechanisms, the ne(s) pssible is/are, 1) NO NO + (slw) 2) 2NO NO 2 + NO (slw) + NO NO 2 (fast) NO 2 NO + 2 (fast) NO 2 + NO 2NO + 2 (fast) 3) NO NO + (slw) NO + NO + 2 (fast) [a] 1 [b] 2 [c] 3 [d] 1 and 3 [e] 2 and At a certain temperature K c = fr the reactin: 2 (g) + F 2 (g) 2F(g) If 1.0 ml 2 and 1.0 ml F 2 are placed in a reactin vessel and allwed t react, then at equilibrium... [a] [F] will be much larger than [ 2 ] and [F 2 ]. [b] [F] will be much less than [ 2 ] and [F 2 ]. [c] [F] will be nearly equal t [ 2 ] and [F 2 ]. [d] the system will cntain nly 2 and F 2. [e] the system will cntain nly F. 11. The fllwing reactin cmes t equilibrium: 2 2 (g) + S 2 (g) 2 2 S(g) If the vlume f the reactin vessel is reduced, at cnstant temperature, the cncentratin f [a] 2 wuld increase. [b] 2 wuld decrease. [c] S 2 wuld increase. [d] 2 S wuld decrease. [e] 2, S 2 and 2 S wuld nt change. 2
3 12. Fr the equilibrium: 2N 2 O(g) + O 2 (g) 4NO(g), = +198 kj. Which f the fllwing changes will increase the amunt f N 2 O when the system reaches its new equilibrium state? [a] The temperature f the system is lwered. [b] The vlume f the cntainer is increased. [c] Sme O 2 is added. [d] e(g) is added withut changing the vlume. [e] Sme NO is remved. 13. Fr the reactin: 2 (g) + CO 2 (g) 2 O(g) + CO(g), the equilibrium cnstant, K p, is 4.40 at 2000 K. Calculate G fr this reactin. [a] 73.2 kj [b] 24.6 kj [c] 243 J [d] 243 J [e] 24.6 kj What is the K b value fr the carbnate in, CO 3? [a] K b = [d] K b = ( )( ) [b] K b = [c] K 11 b = [e] Nne f these are crrect Which f the fllwing wuld increase the K a fr acetic acid? [a] Decrease the p f the slutin. [b] Add sme sdium acetate. [c] Add sme sdium hydrxide. [d] Add sme water. [e] Nne f the abve, the K a is temperature dependent nly. 16. Which ne f the fllwing salts will frm a basic slutin n disslving in water? [a] Na [b] KO 4 [c] N 4 NO 3 [d] NaCN [e] Nne f these slutins are basic 17. Which is the cnjugate base f 2 PO 4? [a] 3 PO 4 [b] PO 4 [c] PO 4 2 [d] PO 4 3 [e] 2 PO The p f a slutin is The [O ] is: [a] [O ] = M [b] [O ] = M [c] [O ] = 5.50 M [d] [O ] = M [e] Nne f these is crrect. 19. What is the p f a M NO 3 slutin? [a] p = [b] p = 1.82 [c] p = 2.59 [d] p = [e] This cannt be answered withut mre infrmatin. 3
4 20. What is the p f a 0.10 M slutin f C 3 COONa? [a] p = 4.74 [b] p = 5.13 [c] p = 8.87 [d] p = 9.25 [e] Nne f these 21. Which f the fllwing is the mst acidic slutin? [a] 0.10 M C 3 COO and 0.10 M C 3 COONa [b] 0.10 M C 3 COO [c] 0.10 M NO 2 and 0.10 M NaNO 2 [d] 0.10 M NO 2 [e] 0.10 M C 3 COONa 22. Which f the fllwing mixtures is suitable fr making a buffer slutin with an ptimum p f ? [a] C 3 COONa/C 3 COO [b] N 3 /N 4 [c] NaO/O [d] NaNO 2 /NO 2 [e] Na/ 23. Which f the fllwing 0.10 M slutins cannt act as a gd buffer? [a] F & NaF [b] C 3 COO & C 3 COONa [c] NaCO 3 & Na 2 CO 3 [d] pure 2 O [e] All f these slutins are gd buffers. 24. What is the p f a slutin that is 0.41 M O and M NaO? [a] p = 0.39 [b] p = 3.94 [c] p = 6.58 [d] p = 7.49 [e] p = Fr which titratin will the p be basic at the equivalence pint? [a] with NaO [b] with N 3 [c] O with NaO [d] All f these titratins will be neutral at the equivalence pint. [e] A predictin cannt be made withut additinal infrmatin. 26. The p at the equivalence pint f an acid-base titratin may differ frm 7.00 because f [a] the indicatr used. [c] the initial p f the titrate. [e] the hydrlysis f the salt frmed. [b] the aut-inizatin f water. [d] the cncentratin f the titrant. 27. Chse the statement that describes the rle f B 3 and N 3 in the reactin: B + N B [a] B 3 is a Lewis base and N 3 is a Lewis acid. [b] Bth N 3 and B 3 are Lewis acids. [c] Bth N 3 and B 3 are Lewis bases. [d] B 3 is a Lewis acid and N 3 is a Lewis base. N 4
5 28. What is the p f the slutin resulting frm the additin f 10.0 ml f 0.10 M NaO t 50.0 ml f 0.10 M slutin? [a] p = 1.00 [b] p = 1.08 [c] p = 1.18 [d] p = 7.00 [e] Insufficient data t answer. 29. The mlar slubility f MgCO 3 is ml/l. What is K sp fr this cmpund? [a] [b] [c] [d] [e] The K sp f Ag 2 CrO 4 is The mlar slubility f Ag 2 CrO 4 in 0.10 M AgNO 3 slutin is: [a] M [b] M [c] M [d] M [e] M 31. Fr Pb 2, K sp = Will a precipitate f Pb 2 frm when 0.50 L f M Pb(NO 3 ) 2 is added t 0.50 L f M Na and why? [a] Yes, Q > K sp [b] N, Q < K sp [c] N, Q = K sp [d] Yes, Q < K sp [e] Mre infrmatin is needed t slve the prblem. Fr questins 32 and 33 cnsider the fllwing redx reactin, Zn + NO 3 acidic Zn 2+ + NO 32. In the balanced equatin in acidic slutin, the cefficient f 2 O is, [a] 1 2 O [b] 2 2 O [c] 3 2 O [d] 4 2 O [e] 5 2 O 33. The reducing agent is, [a] Zn [b] NO 3 [c] NO [d] + [e] 2 O 34. Referring t the Standard Reductin Ptential Table n this exam, the strngest xidizing agent listed belw is [a] Mn 2+ [b] Mn [c] O 3 [d] 2 [e] Ag Of the fllwing reactins, the spntaneus ne wuld be, [a] Mn 2+ + Fe Mn + Fe 2+ [b] 3Ag + NO Ag + + NO + 22 O [c] 3Sn Cr O 3Sn 2+ + Cr 2 O [d] all are spntaneus. [e] nne are spntaneus. 36. In a galvanic cell, the reactin ccurring at the cathde is [a] reductin [b] xidatin [c] hydrlysis [d] ismerizatin [e] acid-base 5
6 37. Use data frm the Table f Standard Reductin Ptentials t calculate the equilibrium cnstant fr the fllwing reactin at 25 C. 2 (g) + 2Br (aq) 2 (aq) + Br 2 (l) [a] K = [b] K = [c] K = [d] K = [e] K = The radiactive decay f 87 Kr prduces a beta particle and, [a] an alpha particle [b] a psitrn [c] + [d] 87 Br [e] 87 Rb 39. A first rder reactin has a rate cnstant f k = s 1 at 25 C. The half-life f the reactin is: [a] 1660 s [b] 576 s [c] 289 s [d] s [e] s 40. A certain radiactive element has a half-life f 10.0 minutes. If 2.00 grams f this element were present initially, the amunt f the element remaining after 8.30 minutes has elapsed wuld be: [a] 1.00 grams [b] 1.13 grams [c] 1.32 grams [d] 1.08 grams [e] grams 6
7 Ptentially Useful Infrmatin G = Σn G f (prducts) Σn G f (reactants) Rate = [cnc] t = Σn f (prducts) Σn f (reactants) Rate = k[a] x [B] y S = ΣnS (prducts) ΣnS (reactants) ln[a] t = kt + ln[a] 0 S univ = S sys + S surr [A] t ln = kt [A] 0 G = T S [A] ln 0 = [A] t kt G = RTlnK G = G + RTlnQ t 1 = 2 k R = J/ml K = L atm/ml K 1 1 = kt + [A] [A] 1 K = C t 1 = k[a] PV = nrt mlarity( M ) mles f slute = Lfslutin A quadratic equatin f the frm ax 2 + bx + c = 0, has the slutins: x x = t 2 0 ln k 0 Ea 1 = + T R k1 Ea 1 1 ln = k2 R T2 T 1 b± [prducts] K c = K y p = K c ( T) n [reactants] K w = [ 3 O + ][O ] = at 25 C p + po = 14 p = lg[ 3 O + ] po = lg[o ] K w = K a K b [base] p = pk a + lg [acid] G = nf F = 96,500 J/V ml Ecell Ecell = Ecathde Eande Ecell = RT ln K nf E = E RT ln Q nf b 2a 2 4ac Ecell = Exi + Ered ln A V E cell = ln K at 25 C n V E = E ln Q at 25 n 7
8 Acid Inizatin Cnstants (25 C) Acid Frmula K a pk a ydrfluric F Nitrus NO Benzic C 6 5 COO Acetic C 3 COO Carbnic 2 CO Bicarbnate in CO ypchlrus O Ammnium in + N ydrcyanic CN Standard Reductin Ptentials alf-reactin E (Vlts) Mg 2+ (aq) + 2 e Mg (s) 2.37 Mn 2+ (aq) + 2 e Mn (s) 1.18 Zn 2+ (aq) + 2 e Zn (s) 0.76 Cr 3+ (aq) + 3 e Cr (s) 0.74 Fe 2+ (aq) + 2 e Fe (s) (aq) + 2 e 2 (g) 0.00 Sn 4+ (aq) + 2 e Sn 2+ (aq) Fe 3+ (aq) + e Fe 2+ (aq) Ag + (aq) + e Ag (s) NO 3 (aq) + 4 (aq) + 3 e NO (g) O (l) Br 2 (l) + 2 e 2 Br (aq) Cr 2 O 7 (aq) + 14 (aq) + 6 e 2 Cr (aq) O (l) (l) + 2 e 2 (aq) O 3 (aq) + 12 (aq) + 10 e 2 (g) O (l) Ce 4+ (aq) + e Ce 3+ (aq) Answer Key 1) c 2) d 3) a 4) e 5) a 6) c 7) c 8) d 9) b 10) a 11) b 12) a 13) b 14) b 15) e 16) d 17) c 18) a 19) b 20) c 21) d 22) b 23) d 24) c 25) c 26) e 27) d 28) c 29) d 30) e 31) b 32) d 33) a 34) c 35) b 36) a 37) b 38) e 39) c 40) b 8
Tuesday, 5:10PM FORM A March 18,
Name Chemistry 153-080 (3150:153-080) EXAM II Multiple-Chice Prtin Instructins: Tuesday, 5:10PM FORM A March 18, 2003 120 1. Each student is respnsible fr fllwing instructins. Read this page carefully.
More informationCHEM 1032 FALL 2017 Practice Exam 4 1. Which of the following reactions is spontaneous under normal and standard conditions?
1 CHEM 1032 FALL 2017 Practice Exam 4 1. Which f the fllwing reactins is spntaneus under nrmal and standard cnditins? A. 2 NaCl(aq) 2 Na(s) + Cl2(g) B. CaBr2(aq) + 2 H2O(aq) Ca(OH)2(aq) + 2 HBr(aq) C.
More informationUniversity Chemistry Quiz /04/21 1. (10%) Consider the oxidation of ammonia:
University Chemistry Quiz 3 2015/04/21 1. (10%) Cnsider the xidatin f ammnia: 4NH 3 (g) + 3O 2 (g) 2N 2 (g) + 6H 2 O(l) (a) Calculate the ΔG fr the reactin. (b) If this reactin were used in a fuel cell,
More informationBIT Chapters = =
BIT Chapters 17-0 1. K w = [H + ][OH ] = 9.5 10 14 [H + ] = [OH ] =.1 10 7 ph = 6.51 The slutin is neither acidic nr basic because the cncentratin f the hydrnium in equals the cncentratin f the hydride
More informationFind this material useful? You can help our team to keep this site up and bring you even more content consider donating via the link on our site.
Find this material useful? Yu can help ur team t keep this site up and bring yu even mre cntent cnsider dnating via the link n ur site. Still having truble understanding the material? Check ut ur Tutring
More informationFind this material useful? You can help our team to keep this site up and bring you even more content consider donating via the link on our site.
Find this material useful? Yu can help ur team t keep this site up and bring yu even mre cntent cnsider dnating via the link n ur site. Still having truble understanding the material? Check ut ur Tutring
More informationSemester 2 AP Chemistry Unit 12
Cmmn In Effect and Buffers PwerPint The cmmn in effect The shift in equilibrium caused by the additin f a cmpund having an in in cmmn with the disslved substance The presence f the excess ins frm the disslved
More informationFind this material useful? You can help our team to keep this site up and bring you even more content consider donating via the link on our site.
Find this material useful? Yu can help ur team t keep this site up and bring yu even mre cntent cnsider dnating via the link n ur site. Still having truble understanding the material? Check ut ur Tutring
More informationFind this material useful? You can help our team to keep this site up and bring you even more content consider donating via the link on our site.
Find this material useful? Yu can help ur team t keep this site up and bring yu even mre cntent cnsider dnating via the link n ur site. Still having truble understanding the material? Check ut ur Tutring
More informationFind this material useful? You can help our team to keep this site up and bring you even more content consider donating via the link on our site.
Find this material useful? Yu can help ur team t keep this site up and bring yu even mre cntent cnsider dnating via the link n ur site. Still having truble understanding the material? Check ut ur Tutring
More informationChapter 19. Electrochemistry. Dr. Al Saadi. Electrochemistry
Chapter 19 lectrchemistry Part I Dr. Al Saadi 1 lectrchemistry What is electrchemistry? It is a branch f chemistry that studies chemical reactins called redx reactins which invlve electrn transfer. 19.1
More informationChapter 17 Free Energy and Thermodynamics
Chemistry: A Mlecular Apprach, 1 st Ed. Nivald Tr Chapter 17 Free Energy and Thermdynamics Ry Kennedy Massachusetts Bay Cmmunity Cllege Wellesley Hills, MA 2008, Prentice Hall First Law f Thermdynamics
More informationChem 112, Fall 05 (Weis/Garman) Exam 4A, December 14, 2005 (Print Clearly) +2 points
+2 pints Befre yu begin, make sure that yur exam has all 7 pages. There are 14 required prblems (7 pints each) and tw extra credit prblems (5 pints each). Stay fcused, stay calm. Wrk steadily thrugh yur
More informationCHAPTER PRACTICE PROBLEMS CHEMISTRY
Chemical Kinetics Name: Batch: Date: Rate f reactin. 4NH 3 (g) + 5O (g) à 4NO (g) + 6 H O (g) If the rate f frmatin f NO is 3.6 0 3 ml L s, calculate (i) the rate f disappearance f NH 3 (ii) rate f frmatin
More informationFind this material useful? You can help our team to keep this site up and bring you even more content consider donating via the link on our site.
Find this material useful? Yu can help ur team t eep this site up and bring yu even mre cntent cnsider dnating via the lin n ur site. Still having truble understanding the material? Chec ut ur Tutring
More informationChem 111 Summer 2013 Key III Whelan
Chem 111 Summer 2013 Key III Whelan Questin 1 6 Pints Classify each f the fllwing mlecules as plar r nnplar? a) NO + : c) CH 2 Cl 2 : b) XeF 4 : Questin 2 The hypthetical mlecule PY 3 Z 2 has the general
More informationAP CHEMISTRY CHAPTER 6 NOTES THERMOCHEMISTRY
AP CHEMISTRY CHAPTER 6 NOTES THERMOCHEMISTRY Energy- the capacity t d wrk r t prduce heat 1 st Law f Thermdynamics: Law f Cnservatin f Energy- energy can be cnverted frm ne frm t anther but it can be neither
More informationIn the half reaction I 2 2 I the iodine is (a) reduced (b) oxidized (c) neither of the above
6.3-110 In the half reactin I 2 2 I the idine is (a) reduced (b) xidized (c) neither f the abve 6.3-120 Vitamin C is an "antixidant". This is because it (a) xidizes readily (b) is an xidizing agent (c)
More informationThermodynamics and Equilibrium
Thermdynamics and Equilibrium Thermdynamics Thermdynamics is the study f the relatinship between heat and ther frms f energy in a chemical r physical prcess. We intrduced the thermdynamic prperty f enthalpy,
More informationIn the spaces provided, explain the meanings of the following terms. You may use an equation or diagram where appropriate.
CEM1405 2007-J-2 June 2007 In the spaces prvided, explain the meanings f the fllwing terms. Yu may use an equatin r diagram where apprpriate. 5 (a) hydrgen bnding An unusually strng diple-diple interactin
More informationUnit 14 Thermochemistry Notes
Name KEY Perid CRHS Academic Chemistry Unit 14 Thermchemistry Ntes Quiz Date Exam Date Lab Dates Ntes, Hmewrk, Exam Reviews and Their KEYS lcated n CRHS Academic Chemistry Website: https://cincchem.pbwrks.cm
More informationCHAPTER 6 / HARVEY A. CHEMICAL EQUILIBRIUM B. THERMODYNAMICS AND EQUILIBRIUM C. MANUPULATING EQUILIBRIUM CONSTANTS
CHPTER 6 / HRVEY. CHEMICL B. THERMODYNMICS ND C. MNUPULTING CONSTNTS D. CONSTNTS FOR CHEMICL RECTIONS 1. Precipitatin Reactins 2. cid-base Reactins 3. Cmplexatin Reactins 4. Oxidatin-Reductin Reactins
More informationCHEM Thermodynamics. Change in Gibbs Free Energy, G. Review. Gibbs Free Energy, G. Review
Review Accrding t the nd law f Thermdynamics, a prcess is spntaneus if S universe = S system + S surrundings > 0 Even thugh S system
More informationEntropy, Free Energy, and Equilibrium
Nv. 26 Chapter 19 Chemical Thermdynamics Entrpy, Free Energy, and Equilibrium Nv. 26 Spntaneus Physical and Chemical Prcesses Thermdynamics: cncerned with the questin: can a reactin ccur? A waterfall runs
More informationChapter 4 Thermodynamics and Equilibrium
Chapter Thermdynamics and Equilibrium Refer t the fllwing figures fr Exercises 1-6. Each represents the energies f fur mlecules at a given instant, and the dtted lines represent the allwed energies. Assume
More informationCHAPTER Read Chapter 17, sections 1,2,3. End of Chapter problems: 25
CHAPTER 17 1. Read Chapter 17, sectins 1,2,3. End f Chapter prblems: 25 2. Suppse yu are playing a game that uses tw dice. If yu cunt the dts n the dice, yu culd have anywhere frm 2 t 12. The ways f prducing
More informationCHEM 1413 Chapter 6 Homework Questions TEXTBOOK HOMEWORK
CHEM 1413 Chapter 6 Hmewrk Questins TEXTBOOK HOMEWORK 6.25 A 27.7-g sample f the radiatr clant ethylene glycl releases 688 J f heat. What was the initial temperature f the sample if the final temperature
More informationEdexcel IGCSE Chemistry. Topic 1: Principles of chemistry. Chemical formulae, equations and calculations. Notes.
Edexcel IGCSE Chemistry Tpic 1: Principles f chemistry Chemical frmulae, equatins and calculatins Ntes 1.25 write wrd equatins and balanced chemical equatins (including state symbls): fr reactins studied
More informationElectrochemistry. Reduction: the gaining of electrons. Reducing agent (reductant): species that donates electrons to reduce another reagent.
Electrchemistry Review: Reductin: the gaining f electrns Oxidatin: the lss f electrns Reducing agent (reductant): species that dnates electrns t reduce anther reagent. Oxidizing agent (xidant): species
More informationChapter 8 Reduction and oxidation
Chapter 8 Reductin and xidatin Redx reactins and xidatin states Reductin ptentials and Gibbs energy Nernst equatin Disprprtinatin Ptential diagrams Frst-Ebswrth diagrams Ellingham diagrams Oxidatin refers
More information19 Applications of Standard Electrode Potentials
9 Applicatins f Standard lectrde Ptentials ( Calculating thermdynamic cell ptentials ( Calculating equilibrium cnstants fr redx reactins ( Cnstructing redx titratin curves 9A Calculating Ptentials f lectrchemical
More informationCHEM 2400/2480. Lecture 19
Lecture 19 Metal In Indicatr - a cmpund whse clur changes when it binds t a metal in - t be useful, it must bind the metal less strngly than EDTA e.g. titratin f Mg 2+ with EDTA using erichrme black T
More informationChemistry 1A Fall 2000
Chemistry 1A Fall 2000 Midterm Exam III, versin B Nvember 14, 2000 (Clsed bk, 90 minutes, 155 pints) Name: SID: Sectin Number: T.A. Name: Exam infrmatin, extra directins, and useful hints t maximize yur
More informationChapters 29 and 35 Thermochemistry and Chemical Thermodynamics
Chapters 9 and 35 Thermchemistry and Chemical Thermdynamics 1 Cpyright (c) 011 by Michael A. Janusa, PhD. All rights reserved. Thermchemistry Thermchemistry is the study f the energy effects that accmpany
More informationLecture 16 Thermodynamics II
Lecture 16 Thermdynamics II Calrimetry Hess s Law Enthalpy r Frmatin Cpyright 2013, 2011, 2009, 2008 AP Chem Slutins. All rights reserved. Fur Methds fr Finding H 1) Calculate it using average bnd enthalpies
More informationUniversity of Waterloo DEPARTMENT OF CHEMISTRY CHEM 123 Test #2 Wednesday, March 11, 2009
University f Waterl DEPARTMENT OF CHEMISTRY CHEM 13 Test # Wednesday, March 11, 009 This is test versin 001. Fill in vals 001 fr the Card Number (r Test Master) n yur cmputer answer card. Name (Print in
More informationFind this material useful? You can help our team to keep this site up and bring you even more content consider donating via the link on our site.
Find this material useful? Yu can help ur team t keep this site up and bring yu even mre cntent cnsider dnating via the link n ur site. Still having truble understanding the material? Check ut ur Tutring
More informationREVIEW QUESTIONS Chapter 18. H = H (Products) - H (Reactants) H (Products) = (1 x -125) + (3 x -271) = -938 kj
Chemistry 102 ANSWER KEY REVIEW QUESTIONS Chapter 18 1. Calculate the heat reactin ( H ) in kj/ml r the reactin shwn belw, given the H values r each substance: NH (g) + F 2 (g) NF (g) + HF (g) H (kj/ml)
More informationReview Material for Exam #2
Review Material fr Eam # 1. a. Calculate the mlarity f a slutin made with 184.6 mg sample f ptassium dichrmate disslved in enugh water t give 500.0 ml f slutin. 1 g 184.6 mg K Cr O 1 mle K Cr O 7 7 1000
More information2004 AP CHEMISTRY FREE-RESPONSE QUESTIONS
2004 AP CHEMISTRY FREE-RESPONSE QUESTIONS 6. An electrchemical cell is cnstructed with an pen switch, as shwn in the diagram abve. A strip f Sn and a strip f an unknwn metal, X, are used as electrdes.
More informationChemistry 132 NT. Electrochemistry. Review
Chemistry 132 NT If yu g flying back thrugh time, and yu see smebdy else flying frward int the future, it s prbably best t avid eye cntact. Jack Handey 1 Chem 132 NT Electrchemistry Mdule 3 Vltaic Cells
More informationExamples: 1. How much heat is given off by a 50.0 g sample of copper when it cools from 80.0 to 50.0 C?
NOTES: Thermchemistry Part 1 - Heat HEAT- TEMPERATURE - Thermchemistry: the study f energy (in the frm f heat) changes that accmpany physical & chemical changes heat flws frm high t lw (ht cl) endthermic
More information2.303 [ OH ] [ H ] CT
CEE 680 25 Octber 2011 FIRST EXAM Clsed bk, ne page f ntes allwed. Answer all questins. Please state any additinal assumptins yu made, and shw all wrk. Yu are welcme t use a graphical methd f slutin if
More informationCHEMISTRY 16 HOUR EXAM IV KEY April 23, 1998 Dr. Finklea. 1. The anti-cancer drug cis-platin is the complex: cis-[pt(nh ) (Cl) ]. In this complex, the
CHEMISTRY 16 HOUR EXAM IV KEY April 23, 1998 Dr. Finklea Sme useful cnstants: ln(10) = 2.303, R = 8.314 J/ml@K, F = 96,00 cul/ml, 2.303RT/F = 0.0916 V at 2EC. Assume a temperature f 2EC unless tld therwise.
More informationA.P. CHEMISTRY. SOLUTIONS AND ACID BASE CHEMISTRY. p 1
A.P. CHEMISTRY. SOLUTIONS AND ACID BASE CHEMISTRY. p 1 (Nte: questins 1 t 14 are meant t be dne WITHOUT calculatrs!) 1.Which f the fllwing is prbably true fr a slid slute with a highly endthermic heat
More informationAdvanced Chemistry Practice Problems
Advanced Chemistry Practice Prblems Thermdynamics: Gibbs Free Energy 1. Questin: Is the reactin spntaneus when ΔG < 0? ΔG > 0? Answer: The reactin is spntaneus when ΔG < 0. 2. Questin: Fr a reactin with
More informationNUPOC STUDY GUIDE ANSWER KEY. Navy Recruiting Command
NUPOC SUDY GUIDE ANSWER KEY Navy Recruiting Cmmand CHEMISRY. ph represents the cncentratin f H ins in a slutin, [H ]. ph is a lg scale base and equal t lg[h ]. A ph f 7 is a neutral slutin. PH < 7 is acidic
More informationALE 21. Gibbs Free Energy. At what temperature does the spontaneity of a reaction change?
Name Chem 163 Sectin: Team Number: ALE 21. Gibbs Free Energy (Reference: 20.3 Silberberg 5 th editin) At what temperature des the spntaneity f a reactin change? The Mdel: The Definitin f Free Energy S
More informationThree Definitions of Acids/Bases Type Acid Base Problems with it Arrhenius Bronsted-Lowry Lewis. NH 3(aq) + H 2O(l)
CP NT Ch 19: Acid and Bases An Intrductin Prperties f Acids 1. taste 2. Can prduce H + ( ) ins ( ) 3. Change the clr f litmus frm t 4. Reacts with such as Zn and Mg t prduce gas. Ba(s) + H 2SO 4 BaSO 4(aq)
More informationSCH4U: End of Year Review
SCH4U: End f Year Review Unit 1: Energy and Rates 2 1) When 13.4 g f ammnium chlride disslve int 2.00x10 g f water the temperature changes frm 20.0 C t 15.3 C. Determine the mlar enthalpy f slutin f ammnium
More informationTHE ANSWER KEY TO THIS EXAM WILL BE POSTED ON BULLETIN BOARD #4 IN THE HALLWAY EAST OF ROOM 1002 GILMAN AND ON THE CHEM 167 WEBSITE.
PROF. JOHN VERKADE SPRING 2005 THIS EXAM CONSISTS OF 3 QUESTIONS ON 9 PAGES CHEM 67 HOUR EXAM II FEBRUARY 28, 2005 SEAT NO. NAME RECIT. INSTR. RECIT. SECT. GRADING PAGE Page 2 Page 3 Page 4 Page 5 Page
More informationThermodynamics Partial Outline of Topics
Thermdynamics Partial Outline f Tpics I. The secnd law f thermdynamics addresses the issue f spntaneity and invlves a functin called entrpy (S): If a prcess is spntaneus, then Suniverse > 0 (2 nd Law!)
More informationName:. Correct Questions = Wrong Questions =.. Unattempt Questions = Marks =
Name:. Crrect Questins = Wrng Questins =.. Unattempt Questins = Marks = 1. Which metal reacts mst vigrusly with water? (A) Al (B) Ca (C) Fe (D) K 2. Which are strng acids? I. HI II. HNO 3 III. H 2 SO 3
More informationChem 163 Section: Team Number: ALE 24. Voltaic Cells and Standard Cell Potentials. (Reference: 21.2 and 21.3 Silberberg 5 th edition)
Name Chem 163 Sectin: Team Number: ALE 24. Vltaic Cells and Standard Cell Ptentials (Reference: 21.2 and 21.3 Silberberg 5 th editin) What des a vltmeter reading tell us? The Mdel: Standard Reductin and
More informationLecture 4. The First Law of Thermodynamics
Lecture 4. The First Law f Thermdynamics THERMODYNAMICS: Basic Cncepts Thermdynamics: (frm the Greek therme, meaning "heat" and, dynamis, meaning "pwer") is the study f energy cnversin between heat and
More informationChapter 17: Thermodynamics: Spontaneous and Nonspontaneous Reactions and Processes
Chapter 17: hermdynamics: Spntaneus and Nnspntaneus Reactins and Prcesses Learning Objectives 17.1: Spntaneus Prcesses Cmparing and Cntrasting the hree Laws f hermdynamics (1 st Law: Chap. 5; 2 nd & 3
More informationHow can standard heats of formation be used to calculate the heat of a reaction?
Answer Key ALE 28. ess s Law and Standard Enthalpies Frmatin (Reerence: Chapter 6 - Silberberg 4 th editin) Imprtant!! Fr answers that invlve a calculatin yu must shw yur wrk neatly using dimensinal analysis
More informationWhen a substance heats up (absorbs heat) it is an endothermic reaction with a (+)q
Chemistry Ntes Lecture 15 [st] 3/6/09 IMPORTANT NOTES: -( We finished using the lecture slides frm lecture 14) -In class the challenge prblem was passed ut, it is due Tuesday at :00 P.M. SHARP, :01 is
More informationChemistry 114 First Hour Exam
Chemistry 114 First Hur Exam Please shw all wrk fr partial credit Name: (4 pints) 1. (12 pints) Espress is made by frcing very ht water under high pressure thrugh finely grund, cmpacted cffee. (Wikipedia)
More informationGOAL... ability to predict
THERMODYNAMICS Chapter 18, 11.5 Study f changes in energy and transfers f energy (system < = > surrundings) that accmpany chemical and physical prcesses. GOAL............................. ability t predict
More informationChem 116 POGIL Worksheet - Week 4 Properties of Solutions
Chem 116 POGIL Wrksheet - Week 4 Prperties f Slutins Key Questins 1. Identify the principal type f slute-slvent interactin that is respnsible fr frming the fllwing slutins: (a) KNO 3 in water; (b) Br 2
More informationAP Chemistry Assessment 2
AP Chemistry Assessment 2 DATE OF ADMINISTRATION: January 8 January 12 TOPICS COVERED: Fundatinal Tpics, Reactins, Gases, Thermchemistry, Atmic Structure, Peridicity, and Bnding. MULTIPLE CHOICE KEY AND
More information15.0 g Cr = 21.9 g Cr O g Cr 4 mol Cr mol Cr O
WYSE Academic Challenge Sectinal Chemistry Exam 2008 SOLUTION SET 1. Crrect answer: B. Use PV = nrt t get: PV = nrt 2. Crrect answer: A. (2.18 atm)(25.0 L) = n(0.08206 L atm/ml K)(23+273) n = 2.24 ml Assume
More information188 CHAPTER 6 THERMOCHEMISTRY
188 CHAPTER 6 THERMOCHEMISTRY 4. a. ΔE = q + w = J + 100. J = 77 J b. w = PΔV = 1.90 atm(.80 L 8.0 L) = 10.5 L atm ΔE = q + w = 50. J + 1060 = 1410 J c. w = PΔV = 1.00 atm(9.1 L11. L) = 17.9 L atm 101.
More informationChem 116 POGIL Worksheet - Week 3 - Solutions Intermolecular Forces, Liquids, Solids, and Solutions
Chem 116 POGIL Wrksheet - Week 3 - Slutins Intermlecular Frces, Liquids, Slids, and Slutins Key Questins 1. Is the average kinetic energy f mlecules greater r lesser than the energy f intermlecular frces
More informationChapter 9 Chemical Reactions NOTES
Chapter 9 Chemical Reactins NOTES Chemical Reactins Chemical reactin: Chemical change 4 Indicatrs f Chemical Change: (1) (2) (3) (4) Cnsist f reactants (starting materials) and prducts (substances frmed)
More informationChem 75 February 16, 2017 Exam 2 Solutions
1. (6 + 6 pints) Tw quick questins: (a) The Handbk f Chemistry and Physics tells us, crrectly, that CCl 4 bils nrmally at 76.7 C, but its mlar enthalpy f vaprizatin is listed in ne place as 34.6 kj ml
More informationSECTION I (Multiple Choice Questions)
ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI IIT JEE - 09 CRASH COURSE (MAIN) MARKS:90 TIME: 5 MIN. TOPIC: CHEMICAL & IONIC EQUILIBRIUM DATE:9//8 SECTION I (Multiple Chice Questins)
More informationAcids and Bases Lesson 3
Acids and Bases Lessn 3 The ph f a slutin is defined as the negative lgarithm, t the base ten, f the hydrnium in cncentratin. In a neutral slutin at 25 C, the hydrnium in and the hydrxide in cncentratins
More informationSPONTANEITY, ENTROPY, AND FREE ENERGY
CHAER 7 SONANEIY, ENROY, AND FREE ENERGY Questins. Living rganisms need an external surce f energy t carry ut these prcesses. Green plants use the energy frm sunlight t prduce glucse frm carbn dixide and
More informationCHAPTER 21 ELECTROCHEMISTRY: CHEMICAL CHANGE AND ELECTRICAL WORK
CHAPTR 1 LCTROCHMISTRY: CHMICAL CHANG AND LCTRICAL WORK 1.1 Oxidatin is the lss f electrns (resulting in a higher xidatin number), while reductin is the gain f electrns (resulting in a lwer xidatin number).
More informationhttps://goo.gl/eaqvfo SUMMER REV: Half-Life DUE DATE: JULY 2 nd
NAME: DUE DATE: JULY 2 nd AP Chemistry SUMMER REV: Half-Life Why? Every radiistpe has a characteristic rate f decay measured by its half-life. Half-lives can be as shrt as a fractin f a secnd r as lng
More informationFind this material useful? You can help our team to keep this site up and bring you even more content consider donating via the link on our site.
Find this material useful? Yu can help ur team t keep this site up and bring yu even mre cntent cnsider dnating via the link n ur site. Still having truble understanding the material? Check ut ur Tutring
More informationAccelerated Chemistry POGIL: Half-life
Name: Date: Perid: Accelerated Chemistry POGIL: Half-life Why? Every radiistpe has a characteristic rate f decay measured by its half-life. Half-lives can be as shrt as a fractin f a secnd r as lng as
More informationCHEM 116 Electrochemistry at Non-Standard Conditions, and Intro to Thermodynamics
CHEM 116 Electrchemistry at Nn-Standard Cnditins, and Intr t Thermdynamics Imprtant annuncement: If yu brrwed a clicker frm me this semester, return it t me at the end f next lecture r at the final exam
More informationUnit 11 Solutions- Guided Notes. What are alloys? What is the difference between heterogeneous and homogeneous mixtures?
Name: Perid: Unit 11 Slutins- Guided Ntes Mixtures: What is a mixture and give examples? What is a pure substance? What are allys? What is the difference between hetergeneus and hmgeneus mixtures? Slutins:
More informationCHEM 103 Calorimetry and Hess s Law
CHEM 103 Calrimetry and Hess s Law Lecture Ntes March 23, 2006 Prf. Sevian Annuncements Exam #2 is next Thursday, March 30 Study guide, practice exam, and practice exam answer key are already psted n the
More informationN 2 (g) + 3H 2 (g) 2NH 3 (g) o Three mole ratios can be derived from the balanced equation above: Example: Li(s) + O 2 (g) Li 2 O(s)
Chapter 9 - Stichimetry Sectin 9.1 Intrductin t Stichimetry Types f Stichimetry Prblems Given is in mles and unknwn is in mles. Given is in mles and unknwn is in mass (grams). Given is in mass and unknwn
More informationProcess Engineering Thermodynamics E (4 sp) Exam
Prcess Engineering Thermdynamics 42434 E (4 sp) Exam 9-3-29 ll supprt material is allwed except fr telecmmunicatin devices. 4 questins give max. 3 pints = 7½ + 7½ + 7½ + 7½ pints Belw 6 questins are given,
More information[ ] CEE October 2010 FIRST EXAM. Closed book, one page of notes allowed.
CEE 680 19 Octber 0 IRST EXAM Clsed bk, ne page f ntes alled. Anser all questins. Please state any additinal assumptins yu made, and sh all rk. Yu are elcme t use a graphical methd f slutin if it is apprpriate.
More informationFinals Study Guide. AP Chemistry. Spring Made by Ashley Thomas
Spring 2016 Finals Study Guide AP Chemistry Table f Cntents Sectin 1: Acids and Bases 1.1 Titratins 1.2 Indicatrs 1.3 Buffers 1.4 Slutin Preparatin Sectin 2: Calrimetry 2.1 Specific Heat 2.2 Metals Sectin
More informationA Chemical Reaction occurs when the of a substance changes.
Perid: Unit 8 Chemical Reactin- Guided Ntes Chemical Reactins A Chemical Reactin ccurs when the f a substance changes. Chemical Reactin: ne r mre substances are changed int ne r mre new substances by the
More informationThermochemistry. The study of energy changes that occur during chemical : at constant volume ΔU = q V. no at constant pressure ΔH = q P
Thermchemistry The study energy changes that ccur during chemical : at cnstant vlume ΔU = q V n at cnstant pressure = q P nly wrk Fr practical reasns mst measurements are made at cnstant, s thermchemistry
More information18:00-21:00, 15 April, 2016 (Total Score: 106 points)
Chemistry II Midterm Exam 18:00-21:00, 15 April, 2016 (Ttal Scre: 106 pints) R = 0.08206 atm L/ml K = 8.314 J/ ml K = 0.08314 bar L/ml K F = 96500 C/ml 1. Please answer the fllwing questins. (ttal 16%)
More informationUnit 13 Acids and Bases. Name: Period: TEST: Wednesday 4/27/16
Unit 13 Acids and Bases Name: Perid: TEST: Wednesday 4/27/16 1 Unit 13 Acids and Bases Calendar Mnday Tuesday Wednesday Thursday Friday APRIL 7th Slutins Test 8 th Vide: Acids & Bases Ntes #1 Acids and
More informationSTUDENT TIPS FOR USING THE CHEMISTRY REFERENCE TABLE
STUDENT TIPS FOR USING THE CHEMISTRY REFERENCE TABLE TABLE A: STANDARD TEMPERATURE AND PRESSURE This table gives the values fr Standard Temp. (in C & K) & Pressure (in kpa & atm). Standard Temperature
More informationCHE 105 EXAMINATION III November 11, 2010
CHE 105 EXAMINATION III Nvember 11, 2010 University f Kentucky Department f Chemistry READ THESE DIRECTIONS CAREFULLY BEFORE STARTING THE EXAMINATION! It is extremely imprtant that yu fill in the answer
More informationStrategy Write the two half-cell reactions and identify the oxidation and reduction reactions. Pt H2 (g) H + (aq)
Slutins manual fr Burrws et.al. Chemistry 3 Third editin 16 Electrchemistry Answers t wrked examples WE 16.1 Drawing a cell diagram (n p. 739 in Chemistry 3 ) Draw a cell diagram fr an electrchemical cell
More informationPart One: Heat Changes and Thermochemistry. This aspect of Thermodynamics was dealt with in Chapter 6. (Review)
CHAPTER 18: THERMODYNAMICS AND EQUILIBRIUM Part One: Heat Changes and Thermchemistry This aspect f Thermdynamics was dealt with in Chapter 6. (Review) A. Statement f First Law. (Sectin 18.1) 1. U ttal
More informationA. Lattice Enthalpies Combining equations for the first ionization energy and first electron affinity:
[15.1B Energy Cycles Lattice Enthalpy] pg. 1 f 5 CURRICULUM Representative equatins (eg M+(g) M+(aq)) can be used fr enthalpy/energy f hydratin, inizatin, atmizatin, electrn affinity, lattice, cvalent
More informationSYNTHESIS OF ASPIRIN SYNTHESIS PURIFICATION CHARACTERIZATION
SYNTHESIS F ASPIRIN SYNTHESIS PURIFICATIN CHARACTERIZATIN ASPIRIN: SME BACKGRUND PATENTED BY BAYER IN 1893 NE F THE LDEST DRUGS NE F THE MST CNSUMED DRUGS (PRDUCTIN IN THE US IS 10 MILLIN KG/YEAR) ASPIRIN:
More informationSession #22: Homework Solutions
Sessin #22: Hmewrk Slutins Prblem #1 (a) In the cntext f amrphus inrganic cmpunds, name tw netwrk frmers, tw netwrk mdifiers, and ne intermediate. (b) Sketch the variatin f mlar vlume with temperature
More informationHow can standard heats of formation be used to calculate the heat of a reaction?
Name Chem 161, Sectin: Grup Number: ALE 28. Hess s Law and Standard Enthalpies Frmatin (Reerence: Chapter 6 - Silberberg 5 th editin) Imprtant!! Fr answers that invlve a calculatin yu must shw yur wrk
More informationMore Tutorial at
Answer each questin in the space prvided; use back f page if extra space is needed. Answer questins s the grader can READILY understand yur wrk; nly wrk n the exam sheet will be cnsidered. Write answers,
More informationOKANAGAN UNIVERSITY COLLEGE FINAL EXAMINATION CHEMISTRY 121
Name (Print) Surname Given Names Student Number Centre OKANAGAN UNIVERSITY COLLEGE FINAL EXAMINATION CHEMISTRY 2 Professor: Nigel Eggers, Renee Van Poppelen, Stephen McNeil April 5, 2004 Duration: 3 hours
More information4 Fe + 3 O 2 2 Fe 2 O 3
UNIT 7: STOICHIOMETRY NOTES (chapter 9) INTRO TO STOICHIOMETRY Reactin Stichimetry: Stichimetry is simply a way t shw f smething this is. Relatinship between a given and an unknwn: GIVEN UNKNOWN Type 1
More informationUnit 10: Kinetics And Equilibrium
Name Unit 10: Kinetics And Equilibrium Skills 1. Understand thery f reactin kinetics 2. Understand factrs affecting reactin rate 3. Drawing and interpreting ptential energy diagrams 4. Distinguish between
More informationThermochemistry. Thermochemistry
Thermchemistry Petrucci, Harwd and Herring: Chapter 7 CHEM 1000A 3.0 Thermchemistry 1 Thermchemistry The study energy in chemical reactins A sub-discipline thermdynamics Thermdynamics studies the bulk
More informationlecture 5: Nucleophilic Substitution Reactions
lecture 5: Nuclephilic Substitutin Reactins Substitutin unimlecular (SN1): substitutin nuclephilic, unimlecular. It is first rder. The rate is dependent upn ne mlecule, that is the substrate, t frm the
More informationSpontaneous Processes, Entropy and the Second Law of Thermodynamics
Chemical Thermdynamics Spntaneus Prcesses, Entrpy and the Secnd Law f Thermdynamics Review Reactin Rates, Energies, and Equilibrium Althugh a reactin may be energetically favrable (i.e. prducts have lwer
More information