Chem 112, Fall 05 (Weis/Garman) Exam 4A, December 14, 2005 (Print Clearly) +2 points
|
|
- Mildred Gibson
- 6 years ago
- Views:
Transcription
1 +2 pints Befre yu begin, make sure that yur exam has all 7 pages. There are 14 required prblems (7 pints each) and tw extra credit prblems (5 pints each). Stay fcused, stay calm. Wrk steadily thrugh yur exam. YOU MUST: Put yur name and student ID n the bubble sheet crrectly. Put all yur answers n the bubble sheet; nthing n this exam will be used fr grading. Sign the statement n the last page f the exam. Turn in bth the exam and bubble sheet when yu are dne. Gd Luck! Physical Cnstants: R = kj/(k ml) F = kj/(ml ev) N = 6.02 x F = 96,485 C/(ml e) Useful quatins: Binmial Distributin: (p + q) n ΔS = q rev /T q rev = ΔH sys ΔS sys = Σ S(prducts) Σ S(reactants) ΔS univ = ΔS surr + ΔS sys ΔG sys = ΔH sys - TΔS sys ΔG rxn = Σ ΔG f (prducts) Σ ΔG f (reactants) ΔG = ΔG + (RT)lnQ ΔG = -(RT)lnK w max = -ΔG sys page 1
2 Useful quatins (cnt d): = cathde - ande (1/2 reactins are expressed as reductins) = (RT/nF)lnQ = (reductin ½ rxn) + (xidatin ½ rxn) At T = K, = (( V)/n)lnQ w max = nf ΔG = -nf = (RT/nF)lnK Current (amperes, A) = [electric charge (culmbs, C)]/[time (secnds, s)] lectric charge (culmbs, C) = [n (mles f electrns transferred)] x [F (culmbs/mle e - )] TABLS f DATA All the Necessary Data are Presented with the Prblem page 2
3 1. Which f the fllwing linear alkane mlecules is likely t have the largest standard entrpy? A. CH 4 B. CH 3 CH 3 C. CH 3 CH 2 CH 3 D. CH 3 CH 2 CH 2 CH 3. CH 3 CH 2 CH 2 CH 2 CH 3 2. All f the fllwing statements cncerning entrpy are true XCPT A. entrpy values fr substances are greater than r equal t zer. B. entrpy is a thermdynamic state functin. C. entrpy is zer fr elements under standard cnditins. D. a psitive change in entrpy dentes a change tward greater disrder. 3. Which reactin is likely t have a negative change in entrpy? A. 2 NH 3 (g) N 2 (g) + 3 H 2 (g) B. CaCO 3 (s) CaO(s) + CO 2 (g) C. N 2 O 4 (g) 2 NO 2 (g) D. 2 CO(g) 2 C(s) + O 2 (g) 4. The disslutin f ammnium nitrate (NH 4 NO 3 ) ccurs spntaneusly in water at 25 C. As it disslves, the temperature f the water decreases. What are the signs f ΔH, ΔS, and ΔG fr this prcess? A. ΔH > 0, ΔS < 0, ΔG > 0 B. ΔH > 0, ΔS > 0, ΔG < 0 C. ΔH > 0, ΔS > 0, ΔG > 0 D. ΔH < 0, ΔS < 0, ΔG < 0 page 3
4 5. What is the crrect equilibrium cnstant expressin fr the balanced reactin shwn belw? C 3 H 8 (g) + 5O 2 (g) 3CO 2 (g) + 4H 2 O(l) A. B. C. D. 6. At what temperatures will a reactin be spntaneus if ΔH = +158 kj and ΔS = +411 J/K? A. All temperatures belw 384 K B. All temperatures abve 384 K C. Temperatures between 158 K and 411 K D. The reactin will be spntaneus at any temperature.. The reactin will never be spntaneus. 7. Calculate ΔG fr the fllwing reactin at 425 C, at which temperature K eq = 56. H 2 (g) + I 2 (g) 2 HI(g) (R = J/K ml) A kj B kj C kj D kj kj page 4
5 8. In the reductin f HClO 4 t Cl - (HClO 4 Cl - ), the xidatin state f Cl changes by A. -7 B. +7 C. -8 D Write a balanced half-reactin fr the reductin f ClO 3 - (aq) t Cl 2 (g) in an acidic slutin. A. 2 ClO - 3 (aq) + 6 H + (aq) + 10 e - Cl 2 (g) + 6 OH - (aq) B. 2 ClO - 3 (aq) + 12 H + (aq) + 5 e - Cl 2 (g) + 6 H 2 O(l) C. 2 ClO - 3 (aq) + 10 e - Cl 2 (g) + 6 H 2 O(l) + 3 O 2 (g) D. 2 ClO - 3 (aq) + 12 H + (aq) + 10 e - Cl 2 (g) + 6 H 2 O(l). nne f these are balanced 10. Use the standard reductin ptentials belw t determine which element r in is the best reducing agent. Pd 2+ (aq) + 2 e - Pd(s) = V Sn 2+ (aq) + 2 e - Sn(s) = V Cr 2+ (aq) + 2 e - Cr(s) = V A. Pd 2+ B. Cr(s) C. Sn 2+ D. Cr 2+. Pd(s) 11. Which f the fllwing statements abut the reactin is crrect? (Cr e - Cr, = V) (Cd e - Cd, = V) 3Cd 2+ (aq) + 2Cr(s) 3Cd(s) + 2Cr 3+ (aq) A. < 0 B. ΔG < 0 C. 6 mles f electrns are transferred in the reactin D. A and C. B and C page 5
6 12. In an electrchemical... A. the xidatin prcess ccurs at the ande. B. the reductin prcess ccurs at the cathde. C. the salt bridge enables electrical cnnectin thrugh the by making a physical cnnectin between the ande and cathde cmpartments. D. All f the abve.. Just A and B. 13. Given the fllwing tw half-reactins, determine which f the verall reactins is spntaneus and calculate its standard ptential. Al 3+ (aq) + 3 e - Al(s) = V Cu 2+ (aq) + 2e - Cu(s) = V A. 2 Al 3+ (aq) + 3 Cu(s) 2 Al(s) + 3 Cu 2+ (aq) B. 2 Al 3+ (aq) + 3 Cu(s) 2 Al(s) + 3 Cu 2+ (aq) C. 2 Al(s) + 3 Cu 2+ (aq) 2 Al 3+ (aq) + 3 Cu(s) D. 2 Al(s) + 3 Cu 2+ (aq) 2 Al 3+ (aq) + 3 Cu(s) = V = V = V = V 14. Calculate fr the fllwing electrchemical reactin at 298 K where Sn 2+ (aq) + 2AgI(s) Sn 4+ (aq) + 2I - (aq) + Ag(s) [Sn 2+ ] = 0.50 M [Sn 4+ ] = 0.50 M [I - ] = 0.15 M AgI(s) + e - Ag(s) + I - (aq) = V Sn 4+ (aq) + 2 e - Sn 2+ (aq) = V A V B V C V D V V page 6
7 XTRA CRDIT (5 pints each) 15. Citric Acid (Cit) binds reversibly t Citric Acid binding prtein (CBP) with an equilibrium cnstant f 2.96 x The enthalpy f binding is kj ml -1. What is the entrpy f binding at 25 C? CBP + Cit CBP:Cit A J/K B J/K C J/K D J/K 16. T generate 1 kilgram (1000 grams) f Al frm Al 2 O 3 in an electrlytic in 1 hur, what is the electrical current (in amperes) that must be supplied t the? A x 10 7 B x 10 6 C D. 990 Please sign the fllwing statement at the cmpletin f the exam. I, (print name) pledge nt t discuss this test with anyne wh has nt it the tests until are graded and returned. page 7
CHEM 1032 FALL 2017 Practice Exam 4 1. Which of the following reactions is spontaneous under normal and standard conditions?
1 CHEM 1032 FALL 2017 Practice Exam 4 1. Which f the fllwing reactins is spntaneus under nrmal and standard cnditins? A. 2 NaCl(aq) 2 Na(s) + Cl2(g) B. CaBr2(aq) + 2 H2O(aq) Ca(OH)2(aq) + 2 HBr(aq) C.
More informationFind this material useful? You can help our team to keep this site up and bring you even more content consider donating via the link on our site.
Find this material useful? Yu can help ur team t keep this site up and bring yu even mre cntent cnsider dnating via the link n ur site. Still having truble understanding the material? Check ut ur Tutring
More informationREVIEW QUESTIONS Chapter 18. H = H (Products) - H (Reactants) H (Products) = (1 x -125) + (3 x -271) = -938 kj
Chemistry 102 ANSWER KEY REVIEW QUESTIONS Chapter 18 1. Calculate the heat reactin ( H ) in kj/ml r the reactin shwn belw, given the H values r each substance: NH (g) + F 2 (g) NF (g) + HF (g) H (kj/ml)
More informationPart One: Heat Changes and Thermochemistry. This aspect of Thermodynamics was dealt with in Chapter 6. (Review)
CHAPTER 18: THERMODYNAMICS AND EQUILIBRIUM Part One: Heat Changes and Thermchemistry This aspect f Thermdynamics was dealt with in Chapter 6. (Review) A. Statement f First Law. (Sectin 18.1) 1. U ttal
More informationFind this material useful? You can help our team to keep this site up and bring you even more content consider donating via the link on our site.
Find this material useful? Yu can help ur team t keep this site up and bring yu even mre cntent cnsider dnating via the link n ur site. Still having truble understanding the material? Check ut ur Tutring
More informationCHEM Thermodynamics. Change in Gibbs Free Energy, G. Review. Gibbs Free Energy, G. Review
Review Accrding t the nd law f Thermdynamics, a prcess is spntaneus if S universe = S system + S surrundings > 0 Even thugh S system
More informationChapter 17 Free Energy and Thermodynamics
Chemistry: A Mlecular Apprach, 1 st Ed. Nivald Tr Chapter 17 Free Energy and Thermdynamics Ry Kennedy Massachusetts Bay Cmmunity Cllege Wellesley Hills, MA 2008, Prentice Hall First Law f Thermdynamics
More informationChapter 19. Electrochemistry. Dr. Al Saadi. Electrochemistry
Chapter 19 lectrchemistry Part I Dr. Al Saadi 1 lectrchemistry What is electrchemistry? It is a branch f chemistry that studies chemical reactins called redx reactins which invlve electrn transfer. 19.1
More informationCHM 152 Practice Final
CM 152 Practice Final 1. Of the fllwing, the ne that wuld have the greatest entrpy (if cmpared at the same temperature) is, [a] 2 O (s) [b] 2 O (l) [c] 2 O (g) [d] All wuld have the same entrpy at the
More informationCHEM 116 Electrochemistry at Non-Standard Conditions, and Intro to Thermodynamics
CHEM 116 Electrchemistry at Nn-Standard Cnditins, and Intr t Thermdynamics Imprtant annuncement: If yu brrwed a clicker frm me this semester, return it t me at the end f next lecture r at the final exam
More informationUniversity Chemistry Quiz /04/21 1. (10%) Consider the oxidation of ammonia:
University Chemistry Quiz 3 2015/04/21 1. (10%) Cnsider the xidatin f ammnia: 4NH 3 (g) + 3O 2 (g) 2N 2 (g) + 6H 2 O(l) (a) Calculate the ΔG fr the reactin. (b) If this reactin were used in a fuel cell,
More informationChapters 29 and 35 Thermochemistry and Chemical Thermodynamics
Chapters 9 and 35 Thermchemistry and Chemical Thermdynamics 1 Cpyright (c) 011 by Michael A. Janusa, PhD. All rights reserved. Thermchemistry Thermchemistry is the study f the energy effects that accmpany
More informationEntropy, Free Energy, and Equilibrium
Nv. 26 Chapter 19 Chemical Thermdynamics Entrpy, Free Energy, and Equilibrium Nv. 26 Spntaneus Physical and Chemical Prcesses Thermdynamics: cncerned with the questin: can a reactin ccur? A waterfall runs
More informationThermodynamics and Equilibrium
Thermdynamics and Equilibrium Thermdynamics Thermdynamics is the study f the relatinship between heat and ther frms f energy in a chemical r physical prcess. We intrduced the thermdynamic prperty f enthalpy,
More informationFind this material useful? You can help our team to keep this site up and bring you even more content consider donating via the link on our site.
Find this material useful? Yu can help ur team t keep this site up and bring yu even mre cntent cnsider dnating via the link n ur site. Still having truble understanding the material? Check ut ur Tutring
More informationFind this material useful? You can help our team to keep this site up and bring you even more content consider donating via the link on our site.
Find this material useful? Yu can help ur team t keep this site up and bring yu even mre cntent cnsider dnating via the link n ur site. Still having truble understanding the material? Check ut ur Tutring
More informationIn the half reaction I 2 2 I the iodine is (a) reduced (b) oxidized (c) neither of the above
6.3-110 In the half reactin I 2 2 I the idine is (a) reduced (b) xidized (c) neither f the abve 6.3-120 Vitamin C is an "antixidant". This is because it (a) xidizes readily (b) is an xidizing agent (c)
More informationTuesday, 5:10PM FORM A March 18,
Name Chemistry 153-080 (3150:153-080) EXAM II Multiple-Chice Prtin Instructins: Tuesday, 5:10PM FORM A March 18, 2003 120 1. Each student is respnsible fr fllwing instructins. Read this page carefully.
More informationChem 163 Section: Team Number: ALE 24. Voltaic Cells and Standard Cell Potentials. (Reference: 21.2 and 21.3 Silberberg 5 th edition)
Name Chem 163 Sectin: Team Number: ALE 24. Vltaic Cells and Standard Cell Ptentials (Reference: 21.2 and 21.3 Silberberg 5 th editin) What des a vltmeter reading tell us? The Mdel: Standard Reductin and
More informationElectrochemistry. Reduction: the gaining of electrons. Reducing agent (reductant): species that donates electrons to reduce another reagent.
Electrchemistry Review: Reductin: the gaining f electrns Oxidatin: the lss f electrns Reducing agent (reductant): species that dnates electrns t reduce anther reagent. Oxidizing agent (xidant): species
More informationChapter 8 Reduction and oxidation
Chapter 8 Reductin and xidatin Redx reactins and xidatin states Reductin ptentials and Gibbs energy Nernst equatin Disprprtinatin Ptential diagrams Frst-Ebswrth diagrams Ellingham diagrams Oxidatin refers
More informationExamples: 1. How much heat is given off by a 50.0 g sample of copper when it cools from 80.0 to 50.0 C?
NOTES: Thermchemistry Part 1 - Heat HEAT- TEMPERATURE - Thermchemistry: the study f energy (in the frm f heat) changes that accmpany physical & chemical changes heat flws frm high t lw (ht cl) endthermic
More informationChemistry 1A Fall 2000
Chemistry 1A Fall 2000 Midterm Exam III, versin B Nvember 14, 2000 (Clsed bk, 90 minutes, 155 pints) Name: SID: Sectin Number: T.A. Name: Exam infrmatin, extra directins, and useful hints t maximize yur
More informationUnit 14 Thermochemistry Notes
Name KEY Perid CRHS Academic Chemistry Unit 14 Thermchemistry Ntes Quiz Date Exam Date Lab Dates Ntes, Hmewrk, Exam Reviews and Their KEYS lcated n CRHS Academic Chemistry Website: https://cincchem.pbwrks.cm
More informationCHAPTER 6 / HARVEY A. CHEMICAL EQUILIBRIUM B. THERMODYNAMICS AND EQUILIBRIUM C. MANUPULATING EQUILIBRIUM CONSTANTS
CHPTER 6 / HRVEY. CHEMICL B. THERMODYNMICS ND C. MNUPULTING CONSTNTS D. CONSTNTS FOR CHEMICL RECTIONS 1. Precipitatin Reactins 2. cid-base Reactins 3. Cmplexatin Reactins 4. Oxidatin-Reductin Reactins
More informationChem 112, Fall 05 (Garman/Weis) Final Exam A, 12/20/2005 (Print Clearly) +2 points
+2 points Before you begin, make sure that your exam has all 10 pages. There are 24 required problems worth 4 points apiece, unless otherwise noted, and two 4-point extra credit problems. Stay focused,
More informationGOAL... ability to predict
THERMODYNAMICS Chapter 18, 11.5 Study f changes in energy and transfers f energy (system < = > surrundings) that accmpany chemical and physical prcesses. GOAL............................. ability t predict
More informationChapter 17: Thermodynamics: Spontaneous and Nonspontaneous Reactions and Processes
Chapter 17: hermdynamics: Spntaneus and Nnspntaneus Reactins and Prcesses Learning Objectives 17.1: Spntaneus Prcesses Cmparing and Cntrasting the hree Laws f hermdynamics (1 st Law: Chap. 5; 2 nd & 3
More informationChapter 4 Thermodynamics and Equilibrium
Chapter Thermdynamics and Equilibrium Refer t the fllwing figures fr Exercises 1-6. Each represents the energies f fur mlecules at a given instant, and the dtted lines represent the allwed energies. Assume
More informationThermodynamics Partial Outline of Topics
Thermdynamics Partial Outline f Tpics I. The secnd law f thermdynamics addresses the issue f spntaneity and invlves a functin called entrpy (S): If a prcess is spntaneus, then Suniverse > 0 (2 nd Law!)
More information2004 AP CHEMISTRY FREE-RESPONSE QUESTIONS
2004 AP CHEMISTRY FREE-RESPONSE QUESTIONS 6. An electrchemical cell is cnstructed with an pen switch, as shwn in the diagram abve. A strip f Sn and a strip f an unknwn metal, X, are used as electrdes.
More informationCHEMISTRY 16 HOUR EXAM IV KEY April 23, 1998 Dr. Finklea. 1. The anti-cancer drug cis-platin is the complex: cis-[pt(nh ) (Cl) ]. In this complex, the
CHEMISTRY 16 HOUR EXAM IV KEY April 23, 1998 Dr. Finklea Sme useful cnstants: ln(10) = 2.303, R = 8.314 J/ml@K, F = 96,00 cul/ml, 2.303RT/F = 0.0916 V at 2EC. Assume a temperature f 2EC unless tld therwise.
More informationCHAPTER Read Chapter 17, sections 1,2,3. End of Chapter problems: 25
CHAPTER 17 1. Read Chapter 17, sectins 1,2,3. End f Chapter prblems: 25 2. Suppse yu are playing a game that uses tw dice. If yu cunt the dts n the dice, yu culd have anywhere frm 2 t 12. The ways f prducing
More informationAP CHEMISTRY CHAPTER 6 NOTES THERMOCHEMISTRY
AP CHEMISTRY CHAPTER 6 NOTES THERMOCHEMISTRY Energy- the capacity t d wrk r t prduce heat 1 st Law f Thermdynamics: Law f Cnservatin f Energy- energy can be cnverted frm ne frm t anther but it can be neither
More informationChemistry 132 NT. Electrochemistry. Review
Chemistry 132 NT If yu g flying back thrugh time, and yu see smebdy else flying frward int the future, it s prbably best t avid eye cntact. Jack Handey 1 Chem 132 NT Electrchemistry Mdule 3 Vltaic Cells
More informationWhen a substance heats up (absorbs heat) it is an endothermic reaction with a (+)q
Chemistry Ntes Lecture 15 [st] 3/6/09 IMPORTANT NOTES: -( We finished using the lecture slides frm lecture 14) -In class the challenge prblem was passed ut, it is due Tuesday at :00 P.M. SHARP, :01 is
More informationAdvanced Chemistry Practice Problems
Advanced Chemistry Practice Prblems Thermdynamics: Gibbs Free Energy 1. Questin: Is the reactin spntaneus when ΔG < 0? ΔG > 0? Answer: The reactin is spntaneus when ΔG < 0. 2. Questin: Fr a reactin with
More informationBIT Chapters = =
BIT Chapters 17-0 1. K w = [H + ][OH ] = 9.5 10 14 [H + ] = [OH ] =.1 10 7 ph = 6.51 The slutin is neither acidic nr basic because the cncentratin f the hydrnium in equals the cncentratin f the hydride
More informationFind this material useful? You can help our team to keep this site up and bring you even more content consider donating via the link on our site.
Find this material useful? Yu can help ur team t keep this site up and bring yu even mre cntent cnsider dnating via the link n ur site. Still having truble understanding the material? Check ut ur Tutring
More informationMore Tutorial at
Answer each questin in the space prvided; use back f page if extra space is needed. Answer questins s the grader can READILY understand yur wrk; nly wrk n the exam sheet will be cnsidered. Write answers,
More informationChemistry 114 First Hour Exam
Chemistry 114 First Hur Exam Please shw all wrk fr partial credit Name: (4 pints) 1. (12 pints) Espress is made by frcing very ht water under high pressure thrugh finely grund, cmpacted cffee. (Wikipedia)
More informationLecture 16 Thermodynamics II
Lecture 16 Thermdynamics II Calrimetry Hess s Law Enthalpy r Frmatin Cpyright 2013, 2011, 2009, 2008 AP Chem Slutins. All rights reserved. Fur Methds fr Finding H 1) Calculate it using average bnd enthalpies
More informationCHEM 2400/2480. Lecture 19
Lecture 19 Metal In Indicatr - a cmpund whse clur changes when it binds t a metal in - t be useful, it must bind the metal less strngly than EDTA e.g. titratin f Mg 2+ with EDTA using erichrme black T
More informationCHEM-443, Fall 2013, Section 010 Midterm 2 November 4, 2013
CHEM-443, Fall 2013, Sectin 010 Student Name Midterm 2 Nvember 4, 2013 Directins: Please answer each questin t the best f yur ability. Make sure yur respnse is legible, precise, includes relevant dimensinal
More informationHow can standard heats of formation be used to calculate the heat of a reaction?
Answer Key ALE 28. ess s Law and Standard Enthalpies Frmatin (Reerence: Chapter 6 - Silberberg 4 th editin) Imprtant!! Fr answers that invlve a calculatin yu must shw yur wrk neatly using dimensinal analysis
More information188 CHAPTER 6 THERMOCHEMISTRY
188 CHAPTER 6 THERMOCHEMISTRY 4. a. ΔE = q + w = J + 100. J = 77 J b. w = PΔV = 1.90 atm(.80 L 8.0 L) = 10.5 L atm ΔE = q + w = 50. J + 1060 = 1410 J c. w = PΔV = 1.00 atm(9.1 L11. L) = 17.9 L atm 101.
More informationTHE ANSWER KEY TO THIS EXAM WILL BE POSTED ON BULLETIN BOARD #4 IN THE HALLWAY EAST OF ROOM 1002 GILMAN AND ON THE CHEM 167 WEBSITE.
PROF. JOHN VERKADE SPRING 2005 THIS EXAM CONSISTS OF 3 QUESTIONS ON 9 PAGES CHEM 67 HOUR EXAM II FEBRUARY 28, 2005 SEAT NO. NAME RECIT. INSTR. RECIT. SECT. GRADING PAGE Page 2 Page 3 Page 4 Page 5 Page
More informationHow can standard heats of formation be used to calculate the heat of a reaction?
Name Chem 161, Sectin: Grup Number: ALE 28. Hess s Law and Standard Enthalpies Frmatin (Reerence: Chapter 6 - Silberberg 5 th editin) Imprtant!! Fr answers that invlve a calculatin yu must shw yur wrk
More informationCHE 105 EXAMINATION III November 11, 2010
CHE 105 EXAMINATION III Nvember 11, 2010 University f Kentucky Department f Chemistry READ THESE DIRECTIONS CAREFULLY BEFORE STARTING THE EXAMINATION! It is extremely imprtant that yu fill in the answer
More informationSecond Law of Thermodynamics
Second Law of Thermodynamics First Law: the total energy of the universe is a constant Second Law: The entropy of the universe increases in a spontaneous process, and remains unchanged in a process at
More informationElectrochemistry. Half-Reactions 1. Balancing Oxidation Reduction Reactions in Acidic and Basic Solutions
Electrchemistry Half-Reactins 1. Balancing Oxidatin Reductin Reactins in Acidic and Basic Slutins Vltaic Cells 2. Cnstructin f Vltaic Cells 3. Ntatin fr Vltaic Cells 4. Cell Ptential 5. Standard Cell Ptentials
More informationCHEM 103 Calorimetry and Hess s Law
CHEM 103 Calrimetry and Hess s Law Lecture Ntes March 23, 2006 Prf. Sevian Annuncements Exam #2 is next Thursday, March 30 Study guide, practice exam, and practice exam answer key are already psted n the
More informationFind this material useful? You can help our team to keep this site up and bring you even more content consider donating via the link on our site.
Find this material useful? Yu can help ur team t keep this site up and bring yu even mre cntent cnsider dnating via the link n ur site. Still having truble understanding the material? Check ut ur Tutring
More informationWhat factors influence how far a reaction goes and how fast it gets there?
. What s in a slutin? Hw far des a reactin g? 2. What factrs influence hw far a reactin ges and hw fast it gets there? 3. Hw d atmic and mlecular structure influence bserved prperties f substances? Big
More informationALE 21. Gibbs Free Energy. At what temperature does the spontaneity of a reaction change?
Name Chem 163 Sectin: Team Number: ALE 21. Gibbs Free Energy (Reference: 20.3 Silberberg 5 th editin) At what temperature des the spntaneity f a reactin change? The Mdel: The Definitin f Free Energy S
More informationUniversity of Waterloo DEPARTMENT OF CHEMISTRY CHEM 123 Test #2 Wednesday, March 11, 2009
University f Waterl DEPARTMENT OF CHEMISTRY CHEM 13 Test # Wednesday, March 11, 009 This is test versin 001. Fill in vals 001 fr the Card Number (r Test Master) n yur cmputer answer card. Name (Print in
More informationElectrochemistry. Learning Objectives. Half-Reactions 1. Balancing Oxidation Reduction Reactions in Acidic and Basic Solutions
Electrchemistry 1 Learning Objectives Electrchemistry Balancing Oxidatin Reductin Reactins in Acidic and Basic Slutins a. Learn the steps fr balancing xidatin reductin reactins using the half-reactin methd.
More informationFind this material useful? You can help our team to keep this site up and bring you even more content consider donating via the link on our site.
Find this material useful? Yu can help ur team t eep this site up and bring yu even mre cntent cnsider dnating via the lin n ur site. Still having truble understanding the material? Chec ut ur Tutring
More informationSpontaneous Processes, Entropy and the Second Law of Thermodynamics
Chemical Thermdynamics Spntaneus Prcesses, Entrpy and the Secnd Law f Thermdynamics Review Reactin Rates, Energies, and Equilibrium Althugh a reactin may be energetically favrable (i.e. prducts have lwer
More informationChemistry 112, Fall 2006, Section 1 (Garman and Heuck) Final Exam A (100 points) 19 Dec 2006
Chemistry 112, Fall 2006, Section 1 (Garman and Heuck) (100 points) 19 Dec 2006 Name: YOU MUST: Put your name and student ID on the bubble sheet correctly. Put the exam version on the bubble sheet on the
More informationA.P. CHEMISTRY. SOLUTIONS AND ACID BASE CHEMISTRY. p 1
A.P. CHEMISTRY. SOLUTIONS AND ACID BASE CHEMISTRY. p 1 (Nte: questins 1 t 14 are meant t be dne WITHOUT calculatrs!) 1.Which f the fllwing is prbably true fr a slid slute with a highly endthermic heat
More informationChem 75 February 16, 2017 Exam 2 Solutions
1. (6 + 6 pints) Tw quick questins: (a) The Handbk f Chemistry and Physics tells us, crrectly, that CCl 4 bils nrmally at 76.7 C, but its mlar enthalpy f vaprizatin is listed in ne place as 34.6 kj ml
More informationCHEM 1032 PRACTICE EXAM IV CLASS SPRING 2017
1 CHEM 1032 PRACTICE EXAM IV CLASS SPRING 2017 (You may need a periodic table. Useful information is on the last page). 1. Which of the following is a non-spontaneous reaction under standard conditions?
More informationCHAPTER 21 ELECTROCHEMISTRY: CHEMICAL CHANGE AND ELECTRICAL WORK
CHAPTR 1 LCTROCHMISTRY: CHMICAL CHANG AND LCTRICAL WORK 1.1 Oxidatin is the lss f electrns (resulting in a higher xidatin number), while reductin is the gain f electrns (resulting in a lwer xidatin number).
More informationCHEM 1001 Problem Set #3: Entropy and Free Energy
CHEM 1001 Prblem Set #3: Entry and Free Energy 19.7 (a) Negative; A liquid (mderate entry) cmbines with a slid t frm anther slid. (b)psitive; One mle f high entry gas frms where n gas was resent befre.
More informationChem 111 Summer 2013 Key III Whelan
Chem 111 Summer 2013 Key III Whelan Questin 1 6 Pints Classify each f the fllwing mlecules as plar r nnplar? a) NO + : c) CH 2 Cl 2 : b) XeF 4 : Questin 2 The hypthetical mlecule PY 3 Z 2 has the general
More informationFind this material useful? You can help our team to keep this site up and bring you even more content consider donating via the link on our site.
Find this material useful? Yu can help ur team t keep this site up and bring yu even mre cntent cnsider dnating via the link n ur site. Still having truble understanding the material? Check ut ur Tutring
More informationEntropy and Gibbs energy
14 Entrpy and Gibbs energy Answers t wrked examples WE 14.1 Predicting the sign f an entrpy change (n p. 658 in Chemistry 3 ) What will be the sign f the value f S fr: (a) crystallizatin f salt frm a slutin;
More informationCH 223 Sample Exam Exam II Name: Lab Section:
Exam II Name: Lab Section: Part I: Multiple Choice Questions (100 Points) Use a scantron sheet for Part I. There is only one best answer for each question. 1. Which of the following equations is the solubility
More informationCHM 2046 Practice Final Exam
CHM 2046 Practice Final Exam IMPORTANT: Bubble in A, B or C as the test form code at the top right of your answer sheet AND also bubble in your Section Number and UFID on the left side of your answer sheet.
More informationStrategy Write the two half-cell reactions and identify the oxidation and reduction reactions. Pt H2 (g) H + (aq)
Slutins manual fr Burrws et.al. Chemistry 3 Third editin 16 Electrchemistry Answers t wrked examples WE 16.1 Drawing a cell diagram (n p. 739 in Chemistry 3 ) Draw a cell diagram fr an electrchemical cell
More informationMaking and Experimenting with Voltaic Cells. I. Basic Concepts and Definitions (some ideas discussed in class are omitted here)
Making xperimenting with Vltaic Cells I. Basic Cncepts Definitins (sme ideas discussed in class are mitted here) A. Directin f electrn flw psitiveness f electrdes. If ne electrde is mre psitive than anther,
More informationIn the spaces provided, explain the meanings of the following terms. You may use an equation or diagram where appropriate.
CEM1405 2007-J-2 June 2007 In the spaces prvided, explain the meanings f the fllwing terms. Yu may use an equatin r diagram where apprpriate. 5 (a) hydrgen bnding An unusually strng diple-diple interactin
More informationTypes of Energy COMMON MISCONCEPTIONS CHEMICAL REACTIONS INVOLVE ENERGY
CHEMICAL REACTIONS INVOLVE ENERGY The study energy and its transrmatins is knwn as thermdynamics. The discussin thermdynamics invlve the cncepts energy, wrk, and heat. Types Energy Ptential energy is stred
More informationLecture 14 Chapter 16, Sections 3-4 Equilibrium. Nifty K eq math Q and K eq Connection with G Le Chatelier
Lecture 14 Chater 16, Sectins 3-4 Equilibrium Nifty K math Q and K Cnnectin with G Le Chatelier Remember In general fr a reactin like aa + bb dd + ee K [ ] d D [ E] e [ ] a A [ ] b B K s can be cmbined
More informationSolutions to the Extra Problems for Chapter 14
Slutins t the Extra Prblems r Chapter 1 1. The H -670. T use bnd energies, we have t igure ut what bnds are being brken and what bnds are being made, s we need t make Lewis structures r everything: + +
More informationLecture 4. The First Law of Thermodynamics
Lecture 4. The First Law f Thermdynamics THERMODYNAMICS: Basic Cncepts Thermdynamics: (frm the Greek therme, meaning "heat" and, dynamis, meaning "pwer") is the study f energy cnversin between heat and
More information5.0 minutes. The temperature rose from
QUESTION 1 The table belw describes features cmmn t a slutin calrimeter and a bmb calrimeter as well as differences. Features f Bth the Slutin and Bmb alrimeters W X Features f the Bmb alrimeter Only Y
More informationSupporting information
Electrnic Supplementary Material (ESI) fr Physical Chemistry Chemical Physics This jurnal is The wner Scieties 01 ydrgen perxide electrchemistry n platinum: twards understanding the xygen reductin reactin
More informationCHM 152 Exam 4 Review Ch KEY
CHM 152 Exam 4 Review Ch. 18 19 KEY 1. Predict whether the entropy change will be positive or negative for the following: a. H 2 O (g) H 2 O (l) S - b. C 6 H 12 O 6 (s) 2C 2 H 5 OH(l) + 2CO 2 (g) S +_
More informationThermochemistry. Thermochemistry
Thermchemistry Petrucci, Harwd and Herring: Chapter 7 CHEM 1000A 3.0 Thermchemistry 1 Thermchemistry The study energy in chemical reactins A sub-discipline thermdynamics Thermdynamics studies the bulk
More informationChemical Thermodynamics
Chemical Thermdynamics Objectives 1. Be capable f stating the First, Secnd, and Third Laws f Thermdynamics and als be capable f applying them t slve prblems. 2. Understand what the parameter entrpy means.
More informationFind this material useful? You can help our team to keep this site up and bring you even more content consider donating via the link on our site.
Find this material useful? You can help our team to keep this site up and bring you even more content consider donating via the link on our site. Still having trouble understanding the material? Check
More informationElectrochemical Reactions
Electrchemical Reactins The first chemical prcess t prduce electricity was described in 1800 by the Italian scientist Alessandr Vlta, a frmer high schl teacher. Acting n the hypthesis that tw dissimilar
More informationSCH4U: End of Year Review
SCH4U: End f Year Review Unit 1: Energy and Rates 2 1) When 13.4 g f ammnium chlride disslve int 2.00x10 g f water the temperature changes frm 20.0 C t 15.3 C. Determine the mlar enthalpy f slutin f ammnium
More informationSPONTANEITY, ENTROPY, AND FREE ENERGY
CHAER 7 SONANEIY, ENROY, AND FREE ENERGY Questins. Living rganisms need an external surce f energy t carry ut these prcesses. Green plants use the energy frm sunlight t prduce glucse frm carbn dixide and
More informationThree charges, all with a charge of 10 C are situated as shown (each grid line is separated by 1 meter).
Three charges, all with a charge f 0 are situated as shwn (each grid line is separated by meter). ) What is the net wrk needed t assemble this charge distributin? a) +0.5 J b) +0.8 J c) 0 J d) -0.8 J e)
More information2.303 [ OH ] [ H ] CT
CEE 680 25 Octber 2011 FIRST EXAM Clsed bk, ne page f ntes allwed. Answer all questins. Please state any additinal assumptins yu made, and shw all wrk. Yu are welcme t use a graphical methd f slutin if
More informationN 2 (g) + 3H 2 (g) 2NH 3 (g) o Three mole ratios can be derived from the balanced equation above: Example: Li(s) + O 2 (g) Li 2 O(s)
Chapter 9 - Stichimetry Sectin 9.1 Intrductin t Stichimetry Types f Stichimetry Prblems Given is in mles and unknwn is in mles. Given is in mles and unknwn is in mass (grams). Given is in mass and unknwn
More informationAP Chemistry Assessment 2
AP Chemistry Assessment 2 DATE OF ADMINISTRATION: January 8 January 12 TOPICS COVERED: Fundatinal Tpics, Reactins, Gases, Thermchemistry, Atmic Structure, Peridicity, and Bnding. MULTIPLE CHOICE KEY AND
More informationThermodynamics 1/16/2013. Thermodynamics
Thermdynamics http://www.chem.purdue.edu/gchelp/hwtslveit/hwtslveit.html 1 Thermdynamics Study f energy changes and flw f energy Answers several fundamental questins: Is it pssible fr reactin t ccur? Will
More informationEnergies of Phase Changes (Some review from Chapter 6, Some New)
. What s in a slutin? Hw far des a reactin g? 2. What factrs influence hw far a reactin ges and hw fast it gets there? 3. Hw d atmic and mlecular structure influence bserved prperties f substances? A Macrscpic
More informationNUPOC STUDY GUIDE ANSWER KEY. Navy Recruiting Command
NUPOC SUDY GUIDE ANSWER KEY Navy Recruiting Cmmand CHEMISRY. ph represents the cncentratin f H ins in a slutin, [H ]. ph is a lg scale base and equal t lg[h ]. A ph f 7 is a neutral slutin. PH < 7 is acidic
More information19 Applications of Standard Electrode Potentials
9 Applicatins f Standard lectrde Ptentials ( Calculating thermdynamic cell ptentials ( Calculating equilibrium cnstants fr redx reactins ( Cnstructing redx titratin curves 9A Calculating Ptentials f lectrchemical
More informationChem 115 POGIL Worksheet - Week 8 Thermochemistry (Continued), Electromagnetic Radiation, and Line Spectra
Chem 115 POGIL Wrksheet - Week 8 Thermchemistry (Cntinued), Electrmagnetic Radiatin, and Line Spectra Why? As we saw last week, enthalpy and internal energy are state functins, which means that the sum
More informationLecture 12: Chemical reaction equilibria
3.012 Fundamentals f Materials Science Fall 2005 Lecture 12: 10.19.05 Chemical reactin equilibria Tday: LAST TIME...2 EQUATING CHEMICAL POTENTIALS DURING REACTIONS...3 The extent f reactin...3 The simplest
More informationHess Law - Enthalpy of Formation of Solid NH 4 Cl
Hess Law - Enthalpy f Frmatin f Slid NH 4 l NAME: OURSE: PERIOD: Prelab 1. Write and balance net inic equatins fr Reactin 2 and Reactin 3. Reactin 2: Reactin 3: 2. Shw that the alebraic sum f the balanced
More informationBonus Final Exam 3. 1 Calculate the heat of reaction,δh 0 rxn, for the following reaction as written at 298 K: g 2H 2 CH 4. g CF 4.
Bonus Final Exam 3 1 Calculate the heat of reaction,δh rxn, for the following reaction as written at 298 K: CH 4 2F 2 CF 4 2H 2 substance CH 4 CF 4 ΔH f kj/mol 75 68 (A) ΔH rxn 23 kj (B) ΔH rxn 914 kj
More informationCHAPTER 3 INEQUALITIES. Copyright -The Institute of Chartered Accountants of India
CHAPTER 3 INEQUALITIES Cpyright -The Institute f Chartered Accuntants f India INEQUALITIES LEARNING OBJECTIVES One f the widely used decisin making prblems, nwadays, is t decide n the ptimal mix f scarce
More information18:00-21:00, 15 April, 2016 (Total Score: 106 points)
Chemistry II Midterm Exam 18:00-21:00, 15 April, 2016 (Ttal Scre: 106 pints) R = 0.08206 atm L/ml K = 8.314 J/ ml K = 0.08314 bar L/ml K F = 96500 C/ml 1. Please answer the fllwing questins. (ttal 16%)
More information