Nernst effect. Makariy A. Tanatar 590B. September 30, Nernst effect

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1 Nernst effect 590B Makariy A. Tanatar September 30, 2009 Nernst effect

2 Nernst-Ettingshausen effect (1 st NE) 1 E N y B dt dx Nernst-Ettingshausen effect (2 nd NE) Walther Hermann Nernst dt dy PI x B Z Graz 1887 Ludwig Boltzman and coworkers Thesis 1887: Electromotive forces produced by magnetism in heated metal plates Third law of thermodynamics (Nobel prize 1920) Nernst glower Bernstein-Siemens-Nernst electric piano N Albert von Ettingshausen E B

3 Hall effect B V H R H IB d -V H q + F L V D E H E +V H I Transverse voltage Longitudinal current Magnetic field

4 Nernst effect or 1 st Nernst-Ettingshausen effect T+ T q + -V T N E N B Q= T N E y B Z dt / dx F L +V N Transverse voltage Longitudinal heat current Magnetic field

5 Ettingshausen effect or 2 nd Nernst-Ettingshausen effect B T P BI d I 2 d T q + F L I d-sample thickness - thermal conductivity ρ- electrical resistivity T- T Transverse thermal gradient Longitudinal electrical current Magnetic field Can be used for thermoelectric cooling

6 -V S T+ T Closer look Hall effect: Lorenz force B Nernst effect Flowing charges in B E S q + F L Weak field MR q V- + F L gradt - V D + -V N + E N + +V N E H E + B V+ T Q +V S I NE Steady state: no charge flow! E s compensates gradt force N=0? We met this situation before. Where? Magnetoresistance, cyclotron orbit curvature is compensated by Hall voltage to first degree effect is zero Nernst effect is second order effect DISTRIBUTION of velocities of carriers, qe s compensates average v D, but not hotter and colder than average In SIMPLE metals for good scattering N is negligibly small

7 Nernst effect in gold ~0.1 nv/kt

8 Bad scattering Anisotropy notably increases Nernst effect Rapid rise on approaching SC Tc YBCO Increased N~5nV/KT!

9 Measurement of Nernst effect Typical numbers Metals Good scattering??? Anisotropic scattering 5 nv/kt Ideologically similar to Thermopower measurements V<10 nv Semiconductors n~ m -3 V~1-100 μv Very demanding measurements from thermal stability and electrical noise point of view

10 Measurements Nernst signal is defined as odd part of Sxy in field S xy =S nonequipotential +S MR +S N Measurements in positive and negative fields, Sxy(H)-Sxy(-H)=2S N Fixed temperature +H to H sweep Time consuming Strict requirements for T-drift, Sxy( T)<<Sxy(H)

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12 Why bother measuring Nernst effect? Additional insight into multiple carrier conductors Anomalous scattering, easy to detect sharp features in Exotic scattering in magnetic systems ( ) K. Behnia

13 Nernst effect in superconductors N is big in the mixed state of SC Flux quanta respond to grad T by thermal diffusion generate Seebeck and Nernst voltages

14 Nernst effect in superconductors Same big in high-tc cuprates But in a broader T-range

15 Claims: Nernst effect is too big for a metal Superconducting vortices above Tc Preformed pairs scenario

16 Can Nernst effect be big otherwise? To have big MR you need V H =0 B q F L + V D V D E -q - I Q. What should we have =0 to get big Nernst effect? A. S =0 Compensation of different carrier types No compensation for cyclotron orbit curvature When S=0 there is no restoring force and there is always a current of two carrier types in the same direction

17 T+ T Ambipolar Nernst effect B q -q + V - D F L -V N +V N F L V D T Q One carrier type: Nernst is second order effect Two carrier types: Nernst effect is FIRST order effect Contrary to Hall effect Contributions of +q and q Sum up in ambipolar Nernst effect Q. What is the difference?

18 Nernst effect Ge: big Semiconductors First observation Krylova TV, Mochan IV, J. Tech. Phys. (USSR) 25, 2119 (1955) N is very big in narrow gap semiconductors 100 V/KT Number of unknowns=number of equations To solve transport completely you want to measure Single carrier type: resistivity +Hall Second carrier type: +Seebeck +Nernst

19 Not negligible even in metallic systems!

20 Nernst effect is big when weak field MR is big: Compensation+ high mobility Bi metal 200% MR in 2T at room temperature

21 K. Behnia group

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23 Reading: General J. M. Ziman Principles of the theory of solids Nernst effect in superconductors, review R. P. Huebener, Supercond. Sci. Technology 8, 189 (1995). Nernst effect in exotic materials K. Behnia, virtual lecture at hvar05.ifs.hr/workshop/work_lectures.html Review articles on physics of thermal and thermoelectric phenomena N. Hussey Adv. Phys. 51, 1685 (2002). K. Behnia, D. Jaccard, J. Flouquet, JPCM 16, 5187 (2003)