NAME: Modern Physics: Physics 305, Section 1

Size: px
Start display at page:

Download "NAME: Modern Physics: Physics 305, Section 1"

Transcription

1 1 Modern Physics: Physics 305, Section 1 NAME: Homework 8: Spin, Magnetic Dipole Moments, and the Spin-Orbit Effect: Homeworks are due as posted on the course web site. They are NOT handed in. The student reports that it is completed and receives one point for this. Solutions are already posted, but students are only permitted to look at the solutions after completion. The solutions are intended to be (but not necessarily are) super-perfect and go beyond a complete answer expected on a test. 014 qmult easy deducto-memory: spin defined Extra keywords: mathematical physics 1. Let s play Jeopardy! For $100, the answer is: It is the intrinsic angular momentum of a fundamental (or fundamental-for-most-purposes) particle. It is invariant and its quantum number s is always an integer or half-integer. What is, Alex? a) rotation b) quantum number c) magnetic moment d) orbital angular momentum e) spin SUGGESTED ANSWER: (e) Wrong answers: a) Well no, but not a bad guess. Redaction: Jeffery, 008jan qmult easy deducto-memory: Goudsmit and Uhlenbeck, spin. Let s play Jeopardy! For $100, the answer is: Goudsmit and Ulhenbeck. a) Who are the original proposers of electron spin in 195, Alex? b) Who performed the Stern-Gerlach experiment, Alex? c) Who are Wolfgang Pauli s evil triplet brothers, Alex? d) What are two delightful Dutch cheeses, Alex? e) What were Rosencrantz and Gildenstern s first names, Alex? SUGGESTED ANSWER: (a) See Le-185 and ER-76. Actually Compton hinted at the idea in 191, but didn t follow up on it. b) Now wouldn t you think Stern & Gerlach performed the Stern-Gerlach experiment? CDL- 897 calls it the Stern-Gerlach experiment. e) Rosencrantz and Gildenstern were real people: members of the Danish embassy to England in 159. Frederick (Fred) Rosenkrantz later met up with Johannes Kepler and thus provides the missing link between Kepler and Shakespeare. Rosenkrantz died tragically in a duel trying to stop it, not fight it but Shakespeare and Stoppard have made him immortal. 014 qmult easy memory: spin magnitude 3. A spin s particle s angular momentum vector magnitude (in the vector model picture) is a) s(s + 1)h. b) sh c) s(s 1)h d) sh e) s(s + 1)h SUGGESTED ANSWER: (a) Wrong answers: e) This is the magnitude squared or the eigenvalue of the S op spin operator. Redaction: Jeffery, 008jan qmult easy memory: eigenvalues of spin 1/ particle

2 4. The eigenvalues of a component of the spin of a spin 1/ particle are always: a) ±h. b) ± h 3. c) ± h 4. d) ± h 5. e) ± h. SUGGESTED ANSWER: (e) 014 qmult easy memory: eigenvalues of spin s particle 5. The quantum numbers for the component of the spin of a spin s particle are always: a) ±1. b) s, s 1, s,..., s + 1, s. c) ± 1. d) ±. e) ±1 4. SUGGESTED ANSWER: (b) c) This is only correct for electrons. 014 qmult easy deducto-memory: spin and environment 6. Is the spin (not spin component) of an electron dependent on the electron s environment? a) Always. b) No. Spin is an intrinsic, unchanging property of a particle. c) In atomic systems, no, but when free, yes. d) Both yes and no. e) It depends on a recount in Palm Beach. SUGGESTED ANSWER: (b) e) Only for those who recall the American presidential election of qmult easy memory: space and spin operators commute 7. A spatial operator and a spin operator commute: never. b) sometimes. c) always. d) always and never. e) to the office. SUGGESTED ANSWER: (c) e) I don t think this could reasonably be interpreted as a right answer. 014 qmult easy memory: Bohr magneton 8. What is µ b = eh m e = (6) 10 4 J/T = (79) 10 5 ev/t? a) The nuclear magneton, the characteristic magnetic moment of nuclear systems. b) The Bohr magneton, the characteristic magnetic moment of electronic systems. c) The intrinsic magnetic dipole moment of an electron. d) The coefficient of sliding friction. e) The zero-point energy of an electron. SUGGESTED ANSWER: (b)

3 3 a) The subscript b and the values should tell you this must be wrong. c) No. For magnitude of the intrinsic magnetic dipole moment is g 3/ times the Bohr magneton (ER-74). 014 qmult easy memory: g factor 9. The g factor in quantum mechanics is the dimensionless factor for some system that multiplied by the appropriate magneton (e.g., Bohr magneton for electron systems) times the angular momentum of the system divided by h gives the magnetic moment of the system. For example for the electron, the intrinsic magnetic moment operator associated with intrinsic spin is given by µ op = gµ b Sop h, where µ b is the Bohr magneton and S op is the spin vector operator. What is g for the intrinsic magnetic moment operator of an electron to modern accuracy? a) 1. b). c) (15). d) 1/137. e) 137. SUGGESTED ANSWER: (c) Wrong answers: b) This is what Dirac s relativistic quantum theory gives. Modern quantum electrodynamics gives to g to about 1 in 10 1 (Wikipedia: 008apr30: Precision tests of QED). Redaction: Jeffery, 008jan qmult easy memory: magnetic moment precession Extra keywords: The precession is also called Larmor precession (En-114) 10. An object in a uniform magnetic field with magnetic moment due to the object s angular momentum will both classically and quantum mechanically: a) Lancy progress. b) Lorenzo regress. c) London recess. d) Larmor precess. e) Lamermoor transgress. SUGGESTED ANSWER: (d) e) That too. 018 qmult easy memory: spin-orbit interaction, hydrogenic atom Extra keywords: spin-orbit interaction, hydrogenic atom 11. What is the main internal perturbation preventing the spinless hydrogenic eigenstates from being the actual ones? a) The Stark effect. b) The Zeeman effect. c) The Stern-Gerlach effect. d) The spin-orbit interaction. e) The Goldhaber interaction. SUGGESTED ANSWER: (d) b) The spin-orbit interaction isn t usually considered as a Zeeman effect although the physics is related: they are both magnetic interactions. The Zeeman effect is usually reserved for the effect of external magnetic fields and the expression for the interaction lacks the characteristic L S factor of the spin-orbit interaction. e) The Goldhabers are great old particle guys: Gerson and Maurice. 018 qfull easy math: fine-structure energy levels

4 4 1. The hydrogen atom energy level energies corrected for the fine structure perturbations (i.e., the relativistic and spin-orbit perturbations) is E(n, l, ±1/, j) = E Ryd n m m e [1 + α n ( n j + 1/ 3 )] 4 where n is the principal quantum number, l is the orbital angular momentum quantum number, ±1/ is allowed variations of j from l, j (the total angular momentum quantum number) is a redundant parameter since j = max(l ± 1/, 1/) (but it is a convenient one), E Ryd = 1 m ec α is the Rydberg energy, m e is the electron mass, α 1/137 is the fine structure constant, and m = m em p m e + m p is the reduced mass with m p being the proton mass. The bracketed perturbation correction term is α ( n n j + 1/ 3 ) 4 which is of order α 10 4 times smaller than the unperturbed energy. Show that the perturbation term is always negative and reduces the energy from the unperturbed energy: i.e., show that in all cases. SUGGESTED ANSWER: n j + 1/ 3 4 > 0 The correction term for a given n is smallest for largest the maximum possible j which is j max = n = n 1, where we have used the fact that the largest l for a given n is n 1 and that j is largest for the +1/ case. Let us assume the inequality n j + 1/ 3 4 > 0 and use j max in it and show that that leads to a correct result. Behold: n j max + 1/ 3 4 > 0, n n 3 4 > 0, > 0, 1 4 > 0, which is obviously correct. Reversing the steps verifies that the inequality is valid for j max, and therefore it is valid for all j. We have proven the inequality, and thus that the fine-structure perturbation always causes a reduction from the energy of a given energy level. Fortran-95 Code Redaction: Jeffery, 008jan01,

5 5 Equation Sheet for Modern Physics These equation sheets are intended for students writing tests or reviewing material. Therefore they are neither intended to be complete nor completely explicit. There are fewer symbols than variables, and so some symbols must be used for different things: context must distinguish. The equations are mnemonic. Students are expected to understand how to interpret and use them. 1 Constants c = m/s m/s m/s 1 lyr/yr 1 ft/ns e = (40) C E Rydberg = (34)eV g e = (electron g-factor) h = (33) J s = (10) ev s hc = evå 10 4 ev Å h = (53) J s = (16) ev s k = (4) 10 3 J/K = (15) 10 4 ev/k 10 4 ev/k m e = (45) kg = (13)MeV m p = (83) 10 7 kg = (3), MeV α = e /(4πǫ 0 hc) = (50) 10 3 = 1/ (94) 1/137 λ C = h/(m e c) = (33) 10 1 m = (33)Å µ B = (79) 10 5 ev/t Geometrical Formulae C cir = πr A cir = πr A sph = 4πr V sph = 4 3 πr3 3 Trigonometry x r = cosθ y r = sinθ y x = tanθ cos θ + sin θ = 1 sin(a + b) = sin(a)cos(b) + cos(a)sin(b) cos(a + b) = cos(a)cos(b) sin(a)sin(b) cos θ = 1 [1 + cos(θ)] sin θ = 1 [1 cos(θ)] sin(θ) = sin(θ)cos(θ) cos(a)cos(b) = 1 [cos(a b) + cos(a + b)] sin(a)sin(b) = 1 [cos(a b) cos(a + b)] sin(a)cos(b) = 1 [sin(a b) + sin(a + b)] 4 Blackbody Radiation

6 6 B ν = hν3 c 1 [e hν/(kt) 1] B λ = hc λ 5 1 [e hc/(ktλ) 1] B λ dλ = B ν dν νλ = c dν dλ = c λ E = hν = hc λ p = h λ F = σt 4 σ = π5 15 k 4 c h 3 = (40) 10 8 W/m /K 4 λ max T = constant = hc kx max x max B λ,wien = hc λ 5 e hc/(ktλ) B λ,rayleigh Jeans = ckt λ 4 k = π λ = π c ν = ω c k i = π L n i standing wave BCs k i = π L n i periodic BCs ln(z!) n(k)dk = k π dk = π ( ) ν dν = n(ν)dν c ( z + 1 ) ln(z) z + 1 ln(π) + 1 1z 1 360z z 5... ln(n!) N ln(n) N ρ(e)de = e E/(kT) kt de P(n) = (1 e α )e nα α = hν kt y x = 1 y v t f(x vt) f(kx ωt) 5 Photons KE = hν w λ = λ scat λ inc = λ C (1 cosθ) l = 1 nσ ρ = e s/l l s m = l m m! 6 Matter Waves

7 7 λ = h p p = h k x p h E t h Ψ(x, t) = φ(k)ψ k (x, t)dk φ(k) = v g = dω = h k 0 dk m = p 0 m = v clas,0 k0 Ψ(x, 0) e ikx π dk 7 Non-Relativistic Quantum Mechanics H = h m x + V T = h m x HΨ = h Ψ m x + V Ψ = ih Ψ t ρ = Ψ Ψ ρ dx = Ψ Ψ dx Aφ i = a i φ i f(x) = i c i φ i b φ i φ j dx = δ ij c j = b a a φ jf(x)dx [A, B] = AB BA P i = c i A = Ψ AΨ dx = i c i a i Hψ = Eψ Ψ(x, t) = ψ(x)e iωt p op φ = h i φ x = pφ φ = eikx π ψ x = m (V E)ψ h Ψ Ψ x Ψ = Ψ(x) r Ψ = Ψ( r) k Ψ = Ψ(k) Ψ i Ψ j = Ψ j Ψ i φ i Ψ = c i 1 op = i φ i φ i Ψ = i φ i φ i Ψ = i c i φ i 1 op = dx x x Ψ i Ψ j = dx Ψ i x x Ψ j A ij = φ i A φ j Pf(x) = f( x) P df(x) dx = df( x) d( x) = df( x) dx Pf e/o (x) = ±f e/o (x) P df e/o(x) dx = df e/o(x) dx 8 Spherical Harmonics

8 8 Y 0,0 = 1 ( ) 1/ ( ) 1/ 3 3 Y 1,0 = cos(θ) Y 1,±1 = sin(θ)e ±iφ 4π 4π 8π L Y lm = l(l + 1)h Y lm L z Y lm = mh Y lm m l m = l, l + 1,...,l 1, l s p d f g h i... 9 Hydrogenic Atom ψ nlm = R nl (r)y lm (θ, φ) l n 1 l = 0, 1,,..., n 1 a z = a 0 Z ( me m reduced ) a 0 = h m e cα = λ C πα m reduced = m 1m m 1 + m R 10 = a 3/ Z e r/az R 0 = 1 ( a 3/ Z 1 1 r a Z ) e r/(az) R 1 = 1 a 3/ r Z e r/(az) 4 a Z R nl = { ( na Z ) } 3 1/ (n l 1)! n[(n + l)!] 3 e ρ/ ρ l L l+1 n+l (ρ) ρ = r nr Z ( ) q d L q (x) = e x ( e x x q) Rodrigues s formula for the Laguerre polynomials dx ( ) j d L j q (x) = L q (x) Associated Laguerre polynomials dx r nlm = a Z [ 3n l(l + 1) ] Nodes = (n 1) l not counting zero or infinity E n = 1 m ec α Z m reduced Z m reduced n = E Ryd m e n Z m reduced m e n m e ev 10 Spin, Magnetic Dipole Moment, Spin-Orbit Interaction Sop = 3 ( ) h 01 s = 1 s(s + 1) = 3 4 S = s(s + 1)h = 3 h

9 9 S z,op = h ( ) m s = ± 1 χ + = ( ) 1 0 χ = ( ) 0 1 µ b = eh m e = (6) 10 4 J/T = (79) 10 5 ev/t µ nuclear = eh m p = (13) 10 7 J/T = (45) 10 8 ev/t µ l = g l µ b L h µ l = g l µ b l(l + 1) µ l,z = g l µ b L z h µ l,z = g l µ b m l τ = µ B PE = µ B F = ( µ B) Fz = j µ j B j z ω = g lµ b h B J = L + S J = j(j + 1)h j = l s, l s + 1,...,l + s triangle rule J z = m j h m j = j, j + 1,...,j 1, j E(n, l, ±1/, j) = E Ryd n m m e [1 + α n ( n j + 1/ 3 )] 4 11 Special Relativity c = m/s m/s m/s 1 lyr/yr 1 ft/ns β = v c γ = 1 1 β γ(β << 1) = β τ = ct Galilean Transformations x = x βτ y = y z = z τ = τ β obj = β obj β Lorentz Transformations x = γ(x βτ) y = y z = z τ = γ(τ βx) β obj = β obj β 1 ββ obj l = l proper 1 β τ proper = τ 1 β m = γm 0 p = mv = γm 0 cβ E 0 = m 0 c E = γe 0 = γm 0 c = mc

10 10 E = mc E = (pc) + (m 0 c ) KE = E E 0 = (pc) + (m 0 c ) m 0 c = (γ 1)m 0 c f = f proper 1 β 1 + β for source and detector separating f(β << 1) = f proper ( 1 β + 1 β ) f trans = f proper 1 β f trans (β << 1) = f proper ( 1 1 β ) τ = βx + γ 1 τ for lines of constant τ τ = x γ 1 x β for lines of constant x x = x intersection γ = x x scale 1 β 1 + β τ = τ intersection = τ τ 1 β scale γ 1 + β θ Mink = tan 1 (β)

a) quantum mechanics b) special relativity c) general relativity d) Newtonian physics e) Maxwellian electromagnetism

a) quantum mechanics b) special relativity c) general relativity d) Newtonian physics e) Maxwellian electromagnetism 1 Modern Physics: Physics 305, Section 1 NAME: Homework 3: Photons Homeworks are due as posted on the course web site. They are NOT handed in. The student reports that it is completed and receives one

More information

Ψ Ψ dx. be a finite, non-zero number. If this is the case, then one can normalize Ψ by multiplying it by a constant such that one obtains 1 =

Ψ Ψ dx. be a finite, non-zero number. If this is the case, then one can normalize Ψ by multiplying it by a constant such that one obtains 1 = 1 Modern Physics: Physics 305, Section 1 NAME: Homework 4: Matter Waves Homeworks are due as posted on the course web site. They are NOT handed in. The student reports that it is completed and receives

More information

Modern Physics 305: 2nd Exam 2008 April 23 Wednesday Instructions: There are 10 multiple-choice questions each worth 2 marks for a total

Modern Physics 305: 2nd Exam 2008 April 23 Wednesday Instructions: There are 10 multiple-choice questions each worth 2 marks for a total 1 Modern Physics 305: nd Exam 008 April 3 Wednesday NAME: Instructions: There are 10 multiple-choice questions each worth marks for a total of 0 marks altogether. Choose the BEST answer, completion, etc.,

More information

Answer Table for the Multiple-Choice Questions

Answer Table for the Multiple-Choice Questions 1 Modern Physics: Physics 305, Section 1 NAME: Homework 5: Non-Relativistic Quantum Mechanics Homeworks are due as posted on the course web site. They are NOT handed in. The student reports that it is

More information

4/21/2010. Schrödinger Equation For Hydrogen Atom. Spherical Coordinates CHAPTER 8

4/21/2010. Schrödinger Equation For Hydrogen Atom. Spherical Coordinates CHAPTER 8 CHAPTER 8 Hydrogen Atom 8.1 Spherical Coordinates 8.2 Schrödinger's Equation in Spherical Coordinate 8.3 Separation of Variables 8.4 Three Quantum Numbers 8.5 Hydrogen Atom Wave Function 8.6 Electron Spin

More information

Physics 2203, 2011: Equation sheet for second midterm. General properties of Schrödinger s Equation: Quantum Mechanics. Ψ + UΨ = i t.

Physics 2203, 2011: Equation sheet for second midterm. General properties of Schrödinger s Equation: Quantum Mechanics. Ψ + UΨ = i t. General properties of Schrödinger s Equation: Quantum Mechanics Schrödinger Equation (time dependent) m Standing wave Ψ(x,t) = Ψ(x)e iωt Schrödinger Equation (time independent) Ψ x m Ψ x Ψ + UΨ = i t +UΨ

More information

C/CS/Phys C191 Particle-in-a-box, Spin 10/02/08 Fall 2008 Lecture 11

C/CS/Phys C191 Particle-in-a-box, Spin 10/02/08 Fall 2008 Lecture 11 C/CS/Phys C191 Particle-in-a-box, Spin 10/0/08 Fall 008 Lecture 11 Last time we saw that the time dependent Schr. eqn. can be decomposed into two equations, one in time (t) and one in space (x): space

More information

Please read the following instructions:

Please read the following instructions: MIDTERM #1 PHYS 33 (MODERN PHYSICS II) DATE/TIME: February 11, 016 (8:30 a.m. - 9:45 a.m.) PLACE: RB 306 Only non-programmable calculators are allowed. Name: ID: Please read the following instructions:

More information

6.1 Nondegenerate Perturbation Theory

6.1 Nondegenerate Perturbation Theory 6.1 Nondegenerate Perturbation Theory Analytic solutions to the Schrödinger equation have not been found for many interesting systems. Fortunately, it is often possible to find expressions which are analytic

More information

One-electron Atom. (in spherical coordinates), where Y lm. are spherical harmonics, we arrive at the following Schrödinger equation:

One-electron Atom. (in spherical coordinates), where Y lm. are spherical harmonics, we arrive at the following Schrödinger equation: One-electron Atom The atomic orbitals of hydrogen-like atoms are solutions to the Schrödinger equation in a spherically symmetric potential. In this case, the potential term is the potential given by Coulomb's

More information

The Hydrogen Atom. Thornton and Rex, Ch. 7

The Hydrogen Atom. Thornton and Rex, Ch. 7 The Hydrogen Atom Thornton and Rex, Ch. 7 Applying Schrodinger s Eqn to the Hydrogen Atom The potential: -1 e 2 V(r) = 4p e0 r Use spherical polar coordinates (with y(x,y,z) => y(r,q,f) ): 1 y 1 y ( r

More information

The Hydrogen Atom. Dr. Sabry El-Taher 1. e 4. U U r

The Hydrogen Atom. Dr. Sabry El-Taher 1. e 4. U U r The Hydrogen Atom Atom is a 3D object, and the electron motion is three-dimensional. We ll start with the simplest case - The hydrogen atom. An electron and a proton (nucleus) are bound by the central-symmetric

More information

(relativistic effects kinetic energy & spin-orbit coupling) 3. Hyperfine structure: ) (spin-spin coupling of e & p + magnetic moments) 4.

(relativistic effects kinetic energy & spin-orbit coupling) 3. Hyperfine structure: ) (spin-spin coupling of e & p + magnetic moments) 4. 4 Time-ind. Perturbation Theory II We said we solved the Hydrogen atom exactly, but we lied. There are a number of physical effects our solution of the Hamiltonian H = p /m e /r left out. We already said

More information

2.4. Quantum Mechanical description of hydrogen atom

2.4. Quantum Mechanical description of hydrogen atom 2.4. Quantum Mechanical description of hydrogen atom Atomic units Quantity Atomic unit SI Conversion Ang. mom. h [J s] h = 1, 05459 10 34 Js Mass m e [kg] m e = 9, 1094 10 31 kg Charge e [C] e = 1, 6022

More information

1.6. Quantum mechanical description of the hydrogen atom

1.6. Quantum mechanical description of the hydrogen atom 29.6. Quantum mechanical description of the hydrogen atom.6.. Hamiltonian for the hydrogen atom Atomic units To avoid dealing with very small numbers, let us introduce the so called atomic units : Quantity

More information

PHYSICS 250 May 4, Final Exam - Solutions

PHYSICS 250 May 4, Final Exam - Solutions Name: PHYSICS 250 May 4, 999 Final Exam - Solutions Instructions: Work all problems. You may use a calculator and two pages of notes you may have prepared. There are problems of varying length and difficulty.

More information

The 3 dimensional Schrödinger Equation

The 3 dimensional Schrödinger Equation Chapter 6 The 3 dimensional Schrödinger Equation 6.1 Angular Momentum To study how angular momentum is represented in quantum mechanics we start by reviewing the classical vector of orbital angular momentum

More information

Final Exam Tuesday, May 8, 2012 Starting at 8:30 a.m., Hoyt Hall Duration: 2h 30m

Final Exam Tuesday, May 8, 2012 Starting at 8:30 a.m., Hoyt Hall Duration: 2h 30m Final Exam Tuesday, May 8, 2012 Starting at 8:30 a.m., Hoyt Hall. ------------------- Duration: 2h 30m Chapter 39 Quantum Mechanics of Atoms Units of Chapter 39 39-1 Quantum-Mechanical View of Atoms 39-2

More information

Physics and Chemistry of the Interstellar Medium

Physics and Chemistry of the Interstellar Medium 0. Physics and Chemistry of the Interstellar Medium Pierre Hily-Blant Master2 Lecture, LAOG pierre.hilyblant@obs.ujf-grenoble.fr, Office 53 2012-2013 Pierre Hily-Blant (Master2) The ISM 2012-2013 1 / 220

More information

Chemistry 120A 2nd Midterm. 1. (36 pts) For this question, recall the energy levels of the Hydrogenic Hamiltonian (1-electron):

Chemistry 120A 2nd Midterm. 1. (36 pts) For this question, recall the energy levels of the Hydrogenic Hamiltonian (1-electron): April 6th, 24 Chemistry 2A 2nd Midterm. (36 pts) For this question, recall the energy levels of the Hydrogenic Hamiltonian (-electron): E n = m e Z 2 e 4 /2 2 n 2 = E Z 2 /n 2, n =, 2, 3,... where Ze is

More information

Preliminary Quantum Questions

Preliminary Quantum Questions Preliminary Quantum Questions Thomas Ouldridge October 01 1. Certain quantities that appear in the theory of hydrogen have wider application in atomic physics: the Bohr radius a 0, the Rydberg constant

More information

charges q r p = q 2mc 2mc L (1.4) ptles µ e = g e

charges q r p = q 2mc 2mc L (1.4) ptles µ e = g e APAS 5110. Atomic and Molecular Processes. Fall 2013. 1. Magnetic Moment Classically, the magnetic moment µ of a system of charges q at positions r moving with velocities v is µ = 1 qr v. (1.1) 2c charges

More information

Quantum Physics III (8.06) Spring 2007 FINAL EXAMINATION Monday May 21, 9:00 am You have 3 hours.

Quantum Physics III (8.06) Spring 2007 FINAL EXAMINATION Monday May 21, 9:00 am You have 3 hours. Quantum Physics III (8.06) Spring 2007 FINAL EXAMINATION Monday May 21, 9:00 am You have 3 hours. There are 10 problems, totalling 180 points. Do all problems. Answer all problems in the white books provided.

More information

20 The Hydrogen Atom. Ze2 r R (20.1) H( r, R) = h2 2m 2 r h2 2M 2 R

20 The Hydrogen Atom. Ze2 r R (20.1) H( r, R) = h2 2m 2 r h2 2M 2 R 20 The Hydrogen Atom 1. We want to solve the time independent Schrödinger Equation for the hydrogen atom. 2. There are two particles in the system, an electron and a nucleus, and so we can write the Hamiltonian

More information

The Hydrogen Atom. Chapter 18. P. J. Grandinetti. Nov 6, Chem P. J. Grandinetti (Chem. 4300) The Hydrogen Atom Nov 6, / 41

The Hydrogen Atom. Chapter 18. P. J. Grandinetti. Nov 6, Chem P. J. Grandinetti (Chem. 4300) The Hydrogen Atom Nov 6, / 41 The Hydrogen Atom Chapter 18 P. J. Grandinetti Chem. 4300 Nov 6, 2017 P. J. Grandinetti (Chem. 4300) The Hydrogen Atom Nov 6, 2017 1 / 41 The Hydrogen Atom Hydrogen atom is simplest atomic system where

More information

Final Exam Practice Solutions

Final Exam Practice Solutions Physics 390 Final Exam Practice Solutions These are a few problems comparable to those you will see on the exam. They were picked from previous exams. I will provide a sheet with useful constants and equations

More information

Introduction to Quantum Physics and Models of Hydrogen Atom

Introduction to Quantum Physics and Models of Hydrogen Atom Introduction to Quantum Physics and Models of Hydrogen Atom Tien-Tsan Shieh Department of Applied Math National Chiao-Tung University November 7, 2012 Physics and Models of Hydrogen November Atom 7, 2012

More information

H atom solution. 1 Introduction 2. 2 Coordinate system 2. 3 Variable separation 4

H atom solution. 1 Introduction 2. 2 Coordinate system 2. 3 Variable separation 4 H atom solution Contents 1 Introduction 2 2 Coordinate system 2 3 Variable separation 4 4 Wavefunction solutions 6 4.1 Solution for Φ........................... 6 4.2 Solution for Θ...........................

More information

8.05 Quantum Physics II, Fall 2011 FINAL EXAM Thursday December 22, 9:00 am -12:00 You have 3 hours.

8.05 Quantum Physics II, Fall 2011 FINAL EXAM Thursday December 22, 9:00 am -12:00 You have 3 hours. 8.05 Quantum Physics II, Fall 0 FINAL EXAM Thursday December, 9:00 am -:00 You have 3 hours. Answer all problems in the white books provided. Write YOUR NAME and YOUR SECTION on your white books. There

More information

PHY4604 Introduction to Quantum Mechanics Fall 2004 Final Exam SOLUTIONS December 17, 2004, 7:30 a.m.- 9:30 a.m.

PHY4604 Introduction to Quantum Mechanics Fall 2004 Final Exam SOLUTIONS December 17, 2004, 7:30 a.m.- 9:30 a.m. PHY464 Introduction to Quantum Mechanics Fall 4 Final Eam SOLUTIONS December 7, 4, 7:3 a.m.- 9:3 a.m. No other materials allowed. If you can t do one part of a problem, solve subsequent parts in terms

More information

Angular momentum and spin

Angular momentum and spin Luleå tekniska universitet Avdelningen för Fysik, 007 Hans Weber Angular momentum and spin Angular momentum is a measure of how much rotation there is in particle or in a rigid body. In quantum mechanics

More information

Atomic Systems (PART I)

Atomic Systems (PART I) Atomic Systems (PART I) Lecturer: Location: Recommended Text: Dr. D.J. Miller Room 535, Kelvin Building d.miller@physics.gla.ac.uk Joseph Black C407 (except 15/1/10 which is in Kelvin 312) Physics of Atoms

More information

Semi-Classical Theory of Radiative Transitions

Semi-Classical Theory of Radiative Transitions Semi-Classical Theory of Radiative Transitions Massimo Ricotti ricotti@astro.umd.edu University of Maryland Semi-Classical Theory of Radiative Transitions p.1/13 Atomic Structure (recap) Time-dependent

More information

Examination Radiation Physics - 8N120 5 November 2014, 13:30-16:30

Examination Radiation Physics - 8N120 5 November 2014, 13:30-16:30 Examination Radiation Physics - 8N120 5 November 2014, 13:30-16:30 Four general remarks: This exam consists of 8 assignments on a total of 3 pages. There is a table on page 4 listing the maximum number

More information

Dirac Equation. Chapter 1

Dirac Equation. Chapter 1 Chapter Dirac Equation This course will be devoted principally to an exposition of the dynamics of Abelian and non-abelian gauge theories. These form the basis of the Standard Model, that is, the theory

More information

We now turn to our first quantum mechanical problems that represent real, as

We now turn to our first quantum mechanical problems that represent real, as 84 Lectures 16-17 We now turn to our first quantum mechanical problems that represent real, as opposed to idealized, systems. These problems are the structures of atoms. We will begin first with hydrogen-like

More information

Physics 115C Homework 2

Physics 115C Homework 2 Physics 5C Homework Problem Our full Hamiltonian is H = p m + mω x +βx 4 = H +H where the unperturbed Hamiltonian is our usual and the perturbation is H = p m + mω x H = βx 4 Assuming β is small, the perturbation

More information

Energy Level Energy Level Diagrams for Diagrams for Simple Hydrogen Model

Energy Level Energy Level Diagrams for Diagrams for Simple Hydrogen Model Quantum Mechanics and Atomic Physics Lecture 20: Real Hydrogen Atom /Identical particles http://www.physics.rutgers.edu/ugrad/361 physics edu/ugrad/361 Prof. Sean Oh Last time Hydrogen atom: electron in

More information

Phys 622 Problems Chapter 5

Phys 622 Problems Chapter 5 1 Phys 622 Problems Chapter 5 Problem 1 The correct basis set of perturbation theory Consider the relativistic correction to the electron-nucleus interaction H LS = α L S, also known as the spin-orbit

More information

Chapter Electron Spin. * Fine structure:many spectral lines consist of two separate. lines that are very close to each other.

Chapter Electron Spin. * Fine structure:many spectral lines consist of two separate. lines that are very close to each other. Chapter 7 7. Electron Spin * Fine structure:many spectral lines consist of two separate lines that are very close to each other. ex. H atom, first line of Balmer series n = 3 n = => 656.3nm in reality,

More information

Physics 342: Modern Physics

Physics 342: Modern Physics Physics 342: Modern Physics Final Exam (Practice) Relativity: 1) Two LEDs at each end of a meter stick oriented along the x -axis flash simultaneously in their rest frame A. The meter stick is traveling

More information

1.4 Solution of the Hydrogen Atom

1.4 Solution of the Hydrogen Atom The phase of α can freely be chosen to be real so that α = h (l m)(l + m + 1). Then L + l m = h (l m)(l + m + 1) l m + 1 (1.24) L l m = h (l + m)(l m + 1) l m 1 (1.25) Since m is bounded, it follow that

More information

L z L L. Think of it as also affecting the angle

L z L L. Think of it as also affecting the angle Quantum Mechanics and Atomic Physics Lecture 19: Quantized Angular Momentum and Electron Spin http://www.physics.rutgers.edu/ugrad/361 h / d/361 Prof. Sean Oh Last time Raising/Lowering angular momentum

More information

1 Measurement and expectation values

1 Measurement and expectation values C/CS/Phys 191 Measurement and expectation values, Intro to Spin 2/15/05 Spring 2005 Lecture 9 1 Measurement and expectation values Last time we discussed how useful it is to work in the basis of energy

More information

Quantum Theory of Angular Momentum and Atomic Structure

Quantum Theory of Angular Momentum and Atomic Structure Quantum Theory of Angular Momentum and Atomic Structure VBS/MRC Angular Momentum 0 Motivation...the questions Whence the periodic table? Concepts in Materials Science I VBS/MRC Angular Momentum 1 Motivation...the

More information

Physics 342 Lecture 22. The Hydrogen Atom. Lecture 22. Physics 342 Quantum Mechanics I

Physics 342 Lecture 22. The Hydrogen Atom. Lecture 22. Physics 342 Quantum Mechanics I Physics 342 Lecture 22 The Hydrogen Atom Lecture 22 Physics 342 Quantum Mechanics I Friday, March 28th, 2008 We now begin our discussion of the Hydrogen atom. Operationally, this is just another choice

More information

Physics of Condensed Matter I

Physics of Condensed Matter I Physics of Condensed Matter I 1100-4INZ`PC Faculty of Physics UW Jacek.Szczytko@fuw.edu.pl Summary of the lecture 1. Quantum mechanics 2. Optical transitions 3. Lasers 4. Optics 5. Molecules 6. Properties

More information

Magnetic Moments and Spin

Magnetic Moments and Spin Magnetic Moments and Spin Still have several Homeworks to hand back Finish up comments about hydrogen atom and start on magnetic moment + spin. Eleventh Homework Set is due today and the last one has been

More information

Final Exam - Solutions PHYS/ECE Fall 2011

Final Exam - Solutions PHYS/ECE Fall 2011 Final Exam - Solutions PHYS/ECE 34 - Fall 211 Problem 1 Cosmic Rays The telescope array project in Millard County, UT can detect cosmic rays with energies up to E 1 2 ev. The cosmic rays are of unknown

More information

Physics 115C Homework 3

Physics 115C Homework 3 Physics 115C Homework 3 Problem 1 In this problem, it will be convenient to introduce the Einstein summation convention. Note that we can write S = i S i i where the sum is over i = x,y,z. In the Einstein

More information

Chapter 6. Quantum Theory of the Hydrogen Atom

Chapter 6. Quantum Theory of the Hydrogen Atom Chapter 6 Quantum Theory of the Hydrogen Atom 1 6.1 Schrodinger s Equation for the Hydrogen Atom Symmetry suggests spherical polar coordinates Fig. 6.1 (a) Spherical polar coordinates. (b) A line of constant

More information

ψ s a ˆn a s b ˆn b ψ Hint: Because the state is spherically symmetric the answer can depend only on the angle between the two directions.

ψ s a ˆn a s b ˆn b ψ Hint: Because the state is spherically symmetric the answer can depend only on the angle between the two directions. 1. Quantum Mechanics (Fall 2004) Two spin-half particles are in a state with total spin zero. Let ˆn a and ˆn b be unit vectors in two arbitrary directions. Calculate the expectation value of the product

More information

Total Angular Momentum for Hydrogen

Total Angular Momentum for Hydrogen Physics 4 Lecture 7 Total Angular Momentum for Hydrogen Lecture 7 Physics 4 Quantum Mechanics I Friday, April th, 008 We have the Hydrogen Hamiltonian for central potential φ(r), we can write: H r = p

More information

Goal: find Lorentz-violating corrections to the spectrum of hydrogen including nonminimal effects

Goal: find Lorentz-violating corrections to the spectrum of hydrogen including nonminimal effects Goal: find Lorentz-violating corrections to the spectrum of hydrogen including nonminimal effects Method: Rayleigh-Schrödinger Perturbation Theory Step 1: Find the eigenvectors ψ n and eigenvalues ε n

More information

Vector Spaces for Quantum Mechanics J. P. Leahy January 30, 2012

Vector Spaces for Quantum Mechanics J. P. Leahy January 30, 2012 PHYS 20602 Handout 1 Vector Spaces for Quantum Mechanics J. P. Leahy January 30, 2012 Handout Contents Examples Classes Examples for Lectures 1 to 4 (with hints at end) Definitions of groups and vector

More information

16.1. PROBLEM SET I 197

16.1. PROBLEM SET I 197 6.. PROBLEM SET I 97 Answers: Problem set I. a In one dimension, the current operator is specified by ĵ = m ψ ˆpψ + ψˆpψ. Applied to the left hand side of the system outside the region of the potential,

More information

8.1 The hydrogen atom solutions

8.1 The hydrogen atom solutions 8.1 The hydrogen atom solutions Slides: Video 8.1.1 Separating for the radial equation Text reference: Quantum Mechanics for Scientists and Engineers Section 10.4 (up to Solution of the hydrogen radial

More information

Angular Momentum Quantization: Physical Manifestations and Chemical Consequences

Angular Momentum Quantization: Physical Manifestations and Chemical Consequences Angular Momentum Quantization: Physical Manifestations and Chemical Consequences Michael Fowler, University of Virginia 7/7/07 The Stern-Gerlach Experiment We ve established that for the hydrogen atom,

More information

The Bohr Magneton and Bohr's second and third biggest mistakes

The Bohr Magneton and Bohr's second and third biggest mistakes The Bohr Magneton and Bohr's second and third biggest mistakes by Miles Mathis Abstract: I will show several problems with the derivation of the Bohr Magneton. Using that analysis, I will look again at

More information

The Central Force Problem: Hydrogen Atom

The Central Force Problem: Hydrogen Atom The Central Force Problem: Hydrogen Atom B. Ramachandran Separation of Variables The Schrödinger equation for an atomic system with Z protons in the nucleus and one electron outside is h µ Ze ψ = Eψ, r

More information

Space-Time Symmetries

Space-Time Symmetries Space-Time Symmetries Outline Translation and rotation Parity Charge Conjugation Positronium T violation J. Brau Physics 661, Space-Time Symmetries 1 Conservation Rules Interaction Conserved quantity strong

More information

Introduction to Quantum Mechanics PVK - Solutions. Nicolas Lanzetti

Introduction to Quantum Mechanics PVK - Solutions. Nicolas Lanzetti Introduction to Quantum Mechanics PVK - Solutions Nicolas Lanzetti lnicolas@student.ethz.ch 1 Contents 1 The Wave Function and the Schrödinger Equation 3 1.1 Quick Checks......................................

More information

Physics 139B Solutions to Homework Set 4 Fall 2009

Physics 139B Solutions to Homework Set 4 Fall 2009 Physics 139B Solutions to Homework Set 4 Fall 9 1. Liboff, problem 1.16 on page 594 595. Consider an atom whose electrons are L S coupled so that the good quantum numbers are j l s m j and eigenstates

More information

[variable] = units (or dimension) of variable.

[variable] = units (or dimension) of variable. Dimensional Analysis Zoe Wyatt wyatt.zoe@gmail.com with help from Emanuel Malek Understanding units usually makes physics much easier to understand. It also gives a good method of checking if an answer

More information

Chm 331 Fall 2015, Exercise Set 4 NMR Review Problems

Chm 331 Fall 2015, Exercise Set 4 NMR Review Problems Chm 331 Fall 015, Exercise Set 4 NMR Review Problems Mr. Linck Version.0. Compiled December 1, 015 at 11:04:44 4.1 Diagonal Matrix Elements for the nmr H 0 Find the diagonal matrix elements for H 0 (the

More information

CHAPTER 8 The Quantum Theory of Motion

CHAPTER 8 The Quantum Theory of Motion I. Translational motion. CHAPTER 8 The Quantum Theory of Motion A. Single particle in free space, 1-D. 1. Schrodinger eqn H ψ = Eψ! 2 2m d 2 dx 2 ψ = Eψ ; no boundary conditions 2. General solution: ψ

More information

Indiana University PHYSICS P301 Final Exam 15 December 2004

Indiana University PHYSICS P301 Final Exam 15 December 2004 Indiana University PHYSICS P30 Final Exam 5 December 004 This is a closed-book examination. You may not refer to lecture notes, textbooks, or any other course materials. You may use a calculator, but solely

More information

Sommerfeld (1920) noted energy levels of Li deduced from spectroscopy looked like H, with slight adjustment of principal quantum number:

Sommerfeld (1920) noted energy levels of Li deduced from spectroscopy looked like H, with slight adjustment of principal quantum number: Spin. Historical Spectroscopy of Alkali atoms First expt. to suggest need for electron spin: observation of splitting of expected spectral lines for alkali atoms: i.e. expect one line based on analogy

More information

1 r 2 sin 2 θ. This must be the case as we can see by the following argument + L2

1 r 2 sin 2 θ. This must be the case as we can see by the following argument + L2 PHYS 4 3. The momentum operator in three dimensions is p = i Therefore the momentum-squared operator is [ p 2 = 2 2 = 2 r 2 ) + r 2 r r r 2 sin θ We notice that this can be written as sin θ ) + θ θ r 2

More information

Topics Covered: Motion in a central potential, spherical harmonic oscillator, hydrogen atom, orbital electric and magnetic dipole moments

Topics Covered: Motion in a central potential, spherical harmonic oscillator, hydrogen atom, orbital electric and magnetic dipole moments PHYS85 Quantum Mechanics I, Fall 9 HOMEWORK ASSIGNMENT Topics Covered: Motion in a central potential, spherical harmonic oscillator, hydrogen atom, orbital electric and magnetic dipole moments. [ pts]

More information

5.111 Lecture Summary #6

5.111 Lecture Summary #6 5.111 Lecture Summary #6 Readings for today: Section 1.9 (1.8 in 3 rd ed) Atomic Orbitals. Read for Lecture #7: Section 1.10 (1.9 in 3 rd ed) Electron Spin, Section 1.11 (1.10 in 3 rd ed) The Electronic

More information

Let us go back to what you knew in high school, or even earlier...

Let us go back to what you knew in high school, or even earlier... Lecture I Quantum-Mechanical Way of Thinking To cultivate QM way of thinking, we will not start with the fascinating historical approach, but instead begin with one of the most important expt, that sends

More information

Quantum Mechanics FKA081/FIM400 Final Exam 28 October 2015

Quantum Mechanics FKA081/FIM400 Final Exam 28 October 2015 Quantum Mechanics FKA081/FIM400 Final Exam 28 October 2015 Next review time for the exam: December 2nd between 14:00-16:00 in my room. (This info is also available on the course homepage.) Examinator:

More information

Select/Special Topics in Atomic Physics Prof. P.C. Deshmukh Department Of Physics Indian Institute of Technology, Madras

Select/Special Topics in Atomic Physics Prof. P.C. Deshmukh Department Of Physics Indian Institute of Technology, Madras Select/Special Topics in Atomic Physics Prof. P.C. Deshmukh Department Of Physics Indian Institute of Technology, Madras Lecture - 37 Stark - Zeeman Spectroscopy Well, let us continue our discussion on

More information

2013 CAP Prize Examination

2013 CAP Prize Examination Canadian Association of Physicists SUPPORTING PHYSICS RESEARCH AND EDUCATION IN CANADA 2013 CAP Prize Examination Compiled by the Department of Physics & Engineering Physics, University of Saskatchewan

More information

1 Recall what is Spin

1 Recall what is Spin C/CS/Phys C191 Spin measurement, initialization, manipulation by precession10/07/08 Fall 2008 Lecture 10 1 Recall what is Spin Elementary particles and composite particles carry an intrinsic angular momentum

More information

Physics GRE: Atomic Physics. G. J. Loges 1. University of Rochester Dept. of Physics & Astronomy. xkcd.com/658/

Physics GRE: Atomic Physics. G. J. Loges 1. University of Rochester Dept. of Physics & Astronomy. xkcd.com/658/ Physics GRE: Atomic Physics G. J. Loges 1 University of Rochester Dept. of Physics & Astronomy xkcd.com/658/ 1 c Gregory Loges, 2016 Contents 1 Bohr Model 1 2 Atomic Structure 1 3 Selection Rules 2 4 Blackbody

More information

Introduction to Quantum Mechanics (Prelude to Nuclear Shell Model) Heisenberg Uncertainty Principle In the microscopic world,

Introduction to Quantum Mechanics (Prelude to Nuclear Shell Model) Heisenberg Uncertainty Principle In the microscopic world, Introduction to Quantum Mechanics (Prelude to Nuclear Shell Model) Heisenberg Uncertainty Principle In the microscopic world, x p h π If you try to specify/measure the exact position of a particle you

More information

ONE AND MANY ELECTRON ATOMS Chapter 15

ONE AND MANY ELECTRON ATOMS Chapter 15 See Week 8 lecture notes. This is exactly the same as the Hamiltonian for nonrigid rotation. In Week 8 lecture notes it was shown that this is the operator for Lˆ 2, the square of the angular momentum.

More information

The experiment consists of studying the deflection of a beam of neutral ground state paramagnetic atoms (silver) in inhomogeneous magnetic field:

The experiment consists of studying the deflection of a beam of neutral ground state paramagnetic atoms (silver) in inhomogeneous magnetic field: SPIN 1/2 PARTICLE Stern-Gerlach experiment The experiment consists of studying the deflection of a beam of neutral ground state paramagnetic atoms (silver) in inhomogeneous magnetic field: A silver atom

More information

Chem 6, 10 Section Spring Exam 2 Solutions

Chem 6, 10 Section Spring Exam 2 Solutions Exam 2 Solutions 1. (4 + 6 + 5 points) Dartmouth s FM radio station, WDCR, broadcasts by emitting from its antenna photons of frequency 99.3 MHz (99.3 10 6 Hz). (a) What is the energy of a single WDCR

More information

Examination Radiation Physics - 8N120, 2 November

Examination Radiation Physics - 8N120, 2 November Examination Radiation Physics - 8N0, November 0-4.00-7.00 Four general remarks: This exam consists of 6 assignments on a total of pages. There is a table on page listing the maximum number of that can

More information

Lecture 4 Quantum mechanics in more than one-dimension

Lecture 4 Quantum mechanics in more than one-dimension Lecture 4 Quantum mechanics in more than one-dimension Background Previously, we have addressed quantum mechanics of 1d systems and explored bound and unbound (scattering) states. Although general concepts

More information

Magnetism, Angular Momentum, and Spin

Magnetism, Angular Momentum, and Spin Magnetism, Angular Momentum, and Spin Chapter 19 P. J. Grandinetti Chem. 4300 Nov 13, 2017 P. J. Grandinetti (Chem. 4300) Magnetism, Ang. Mom., & Spin Nov 13, 2017 1 / 62 In 1820 Hans Christian Ørsted

More information

PH 451/551 Quantum Mechanics Capstone Winter 201x

PH 451/551 Quantum Mechanics Capstone Winter 201x These are the questions from the W7 exam presented as practice problems. The equation sheet is PH 45/55 Quantum Mechanics Capstone Winter x TOTAL POINTS: xx Weniger 6, time There are xx questions, for

More information

Attempts at relativistic QM

Attempts at relativistic QM Attempts at relativistic QM based on S-1 A proper description of particle physics should incorporate both quantum mechanics and special relativity. However historically combining quantum mechanics and

More information

The Hydrogen atom. Chapter The Schrödinger Equation. 2.2 Angular momentum

The Hydrogen atom. Chapter The Schrödinger Equation. 2.2 Angular momentum Chapter 2 The Hydrogen atom In the previous chapter we gave a quick overview of the Bohr model, which is only really valid in the semiclassical limit. cf. section 1.7.) We now begin our task in earnest

More information

7. The Hydrogen Atom in Wave Mechanics

7. The Hydrogen Atom in Wave Mechanics 7. The Hydrogen Atom in Wave Mechanics In this chapter we shall discuss : The Schrödinger equation in spherical coordinates Spherical harmonics Radial probability densities The hydrogen atom wavefunctions

More information

Physics 129, Fall 2010; Prof. D. Budker

Physics 129, Fall 2010; Prof. D. Budker Physics 129, Fall 2010; Prof. D. Budker Some introductory thoughts Reductionists science Identical particles are truly so (bosons, fermions) We will be using (relativistic) QM where initial conditions

More information

P3317 HW from Lecture 15 and Recitation 8

P3317 HW from Lecture 15 and Recitation 8 P3317 HW from Lecture 15 and Recitation 8 Due Oct 23, 218 Problem 1. Variational Energy of Helium Here we will estimate the ground state energy of Helium. Helium has two electrons circling around a nucleus

More information

Lectures 21 and 22: Hydrogen Atom. 1 The Hydrogen Atom 1. 2 Hydrogen atom spectrum 4

Lectures 21 and 22: Hydrogen Atom. 1 The Hydrogen Atom 1. 2 Hydrogen atom spectrum 4 Lectures and : Hydrogen Atom B. Zwiebach May 4, 06 Contents The Hydrogen Atom Hydrogen atom spectrum 4 The Hydrogen Atom Our goal here is to show that the two-body quantum mechanical problem of the hydrogen

More information

PH 253 Final Exam: Solution

PH 253 Final Exam: Solution PH 53 Final Exam: Solution 1. A particle of mass m is confined to a one-dimensional box of width L, that is, the potential energy of the particle is infinite everywhere except in the interval 0

More information

CHAPTER 28 Quantum Mechanics of Atoms Units

CHAPTER 28 Quantum Mechanics of Atoms Units CHAPTER 28 Quantum Mechanics of Atoms Units Quantum Mechanics A New Theory The Wave Function and Its Interpretation; the Double-Slit Experiment The Heisenberg Uncertainty Principle Philosophic Implications;

More information

Outline Spherical symmetry Free particle Coulomb problem Keywords and References. Central potentials. Sourendu Gupta. TIFR, Mumbai, India

Outline Spherical symmetry Free particle Coulomb problem Keywords and References. Central potentials. Sourendu Gupta. TIFR, Mumbai, India Central potentials Sourendu Gupta TIFR, Mumbai, India Quantum Mechanics 1 2013 3 October, 2013 Outline 1 Outline 2 Rotationally invariant potentials 3 The free particle 4 The Coulomb problem 5 Keywords

More information

ACCESS TO SCIENCE, ENGINEERING AND AGRICULTURE: MATHEMATICS 1 MATH00030 SEMESTER / Trigonometry

ACCESS TO SCIENCE, ENGINEERING AND AGRICULTURE: MATHEMATICS 1 MATH00030 SEMESTER / Trigonometry ACCESS TO SCIENCE, ENGINEERING AND AGRICULTURE: MATHEMATICS 1 MATH0000 SEMESTER 1 017/018 DR. ANTHONY BROWN 5. Trigonometry 5.1. Parity and Co-Function Identities. In Section 4.6 of Chapter 4 we looked

More information

The Postulates of Quantum Mechanics Common operators in QM: Potential Energy. Often depends on position operator: Kinetic Energy 1-D case: 3-D case

The Postulates of Quantum Mechanics Common operators in QM: Potential Energy. Often depends on position operator: Kinetic Energy 1-D case: 3-D case The Postulates of Quantum Mechanics Common operators in QM: Potential Energy Often depends on position operator: Kinetic Energy 1-D case: 3-D case Time Total energy = Hamiltonian To find out about the

More information

Units, limits, and symmetries

Units, limits, and symmetries Units, limits, and symmetries When solving physics problems it s easy to get overwhelmed by the complexity of some of the concepts and equations. It s important to have ways to navigate through these complexities

More information

Quantum Physics 2006/07

Quantum Physics 2006/07 Quantum Physics 6/7 Lecture 7: More on the Dirac Equation In the last lecture we showed that the Dirac equation for a free particle i h t ψr, t = i hc α + β mc ψr, t has plane wave solutions ψr, t = exp

More information

IV. Electronic Spectroscopy, Angular Momentum, and Magnetic Resonance

IV. Electronic Spectroscopy, Angular Momentum, and Magnetic Resonance IV. Electronic Spectroscopy, Angular Momentum, and Magnetic Resonance The foundation of electronic spectroscopy is the exact solution of the time-independent Schrodinger equation for the hydrogen atom.

More information

The Spin (continued). February 8, 2012

The Spin (continued). February 8, 2012 The Spin continued. Magnetic moment of an electron Particle wave functions including spin Stern-Gerlach experiment February 8, 2012 1 Magnetic moment of an electron. The coordinates of a particle include

More information