Chap. 1 (Introduction), Chap. 2 (Components and Circuits)
|
|
- Bruce Esmond Porter
- 5 years ago
- Views:
Transcription
1 CHEM 455 The class describes the principles and applications of modern analytical instruments. Emphasis is placed upon the theoretical basis of each type of instrument, its optimal area of application, its sensitivity, its precision, and its limitations. Elementary integrated circuitry and treatment of analytical data are introduced. Outcomes Understanding the fundamental chemical and physical properties that are used in instrumentation Ability to evaluate and utilize data from instruments Limitation of experimental instrumentation Investigation of modern topics in analytical chemistry 1-1
2 Chap. 1 (Introduction), Chap. 2 (Components and Circuits) Methods of Analytical Chemistry Classical methods Separation of components * Precipitation, extraction, distillation Identification by properties Color, melting point, solubilities Amount determined by mass or titration Instrumental methods interaction with electrons or photons * Electronic or nuclear properties are identified Some properties based on bulk properties * Thermal analysis 1-2
3 Methods 1-3
4 Instruments Converts information in the sample to information expressed in an instrument Results are given in differing data domains Electrical and non-electrical 1-4
5 Components 1-5
6 Interdomain Conversions 1-6
7 Analog domains Electrical Domains Magnitude of electrical quantity Voltage, currant, power, charge * Correlation of two signals NMR, IR, DTA * Susceptible to noise 1-7
8 Time domains Time component of signals Duration of signal above a threshold Electrical domains * HI above and LO below Frequency and period 1-8
9 Electrical Domains Digital Domain 2 level scheme On, off; high, low * Each selection is a bit Bit is termed count digital data Numbers can be represented in binary 1 or 0 * 101 = 1x2 2 +0x2 1 +1x2 0 = 5 1-9
10 Detectors, Transducers, and Sensors Terms often interchanged Detector Device that identifies, records, or indicates change in variable Pressure, temperature, concentration, charge, radiation Chemical, mechanical, or electrical device Transducer Converts information from non-electrical to electrical domain Photomultipliers, photodiodes 1-10
11 Sensor Sensors monitor a specific chemical species Ion sensitive electrode Piezoelectric crystal Functionalization of surface Crystal oscillates at constant frequency in an electric circuit Change in mass can be detected 2 CF M F = A C is a constant, F is frequency, M is mass, and A is surface area * Also works in spectroscopy (photoacoustic) 1-11
12 Selection of Method Accuracy Sample size Concentration range Interference Matrix Number of samples 1-12
13 Criteria Precision Degree of mutual agreement Can be quantified Bias Difference in true sample measurement Bias=m-x t m is mean, x t is true measurement 1-13
14 Criteria Sensitivity Ability to distinguish analyte differences Based on linear calibration curve * S=mc+S bl S = signal, m = slope, c= concentration, S bl =blank signal Slope is calibration sensitivity Analytical senstivity g=m/s, s s s =standard deviation Detection limit Minimum analyte concentration that can be detected Approaches blank signal Generally blank plus 3 times blank standard deviation 1-14
15 Detection limit Criteria Equation used to convert S m to detection limit (c m ) Dynamic range c m = S m S m bl 1-15
16 Criteria Selectivity Impact of matrix on sample measurement Saturation of detector by matrix Similar chemical behavior * Group chemistry Physical properties * Mass similarity Can be defined by selectivity coefficient 0 and above * Can be greater than unity 1-16
17 Calibration Calibration curve Standard are measured and response recorded Need to consider matrix Can be nonlinear 1-17
18 Calibration Standard Addition Addition of standard directly to sample Multiple samples used to determine unknown concentration S1c svs cx = ( S2 S1) Vx c x =unknown concentration, S is response for sample (1) and sample plus standard (2), c s is concentration of added standard, V x is volume of unknown, V s is volume of added sample Internal Standard Standard added to all samples, blanks, and calibration 1-18
19 Chap 2 Electric components and circuits Instruments rely upon measurements in a circuit Based on electricity laws Ohms law * V=IR (V= potential difference in volts, R is resistance in ohms, and I is current in amperes Kirchhoff s law * Sum of current around a point is 0 Power Law * P=IV (P in watts) 1-19
20 Current Circuits Series Circuit R and V related based on fundamental laws V x =V(R x /R) Apply Kirchhoff s law and Ohm s law to find voltage at any point 1-20
21 Voltage divider In many circuits, it is necessary to obtain a voltage not available from the main power source can derive other voltages from the main power source voltage is less than the voltage from the main source use resistors in an appropriate configuration to reduce the voltage from the power source Potentiometers 1-21
22 A collection of series circuits Kirchhoff s and Ohm s law still apply More electrons flow through resistor with lower resistance Voltage for each section Parallel Circuit V=I x R x I t =V/R t 1 1 = R t R x x 1-22
23 Measurements Voltmeter Integrated circuit Power supply Display Uses analog to digital converter 1-23
24 AC circuits Current or potential fluctuates with time F=1/t (Hz) Cycles per second Waves can differ Sinusoidal, square wave, ramp, sawtooth Equations can describe fundamental properties Angular velocity ω = 2πf 1-24
25 Capacitors and Capacitance Conductors separated by dielectric substance Can store an electrical charge Capacitor accepts electrons and stores the charge Releases electrons Equipment can have charge when unplugged v r c 1-25
26 Band Gap and Semiconductor Distinguish between conductor and insulators based on band gap Thermal and photoexcitation Thermal promotes electron and creates hole Chemical excitation Inject impurities Dopants * i.e., P for Si, extra electron goes into conductive band Can apply Bohr model to describe single electron Replace e o with e (dielectric constant) and m e with effective mass 4 E = k m = 8ε e 0 e h
27 Chemical doping Dieletric constant for Si = 11.7, effective mass is 0.2 m e = 0.02 ev, measurement is ev Calculate Bohr radius r 1 =ae/m= 30 A Greater orbit Donor electron promoted to conduction band by thermal energy Ionized electron goes into conduction band * Level below conduction band is donor level Most electrons from P Electrons in band from P and governed by P 1-27
28 Dopants The value of semiconductors for solid state device fabrication lies in the fact that the number and type of conducting electric charge carriers [electrons are n-type (negative), holes are p-type (positive)] can be controlled through incorporation of appropriate dopant elements. Thus the substitutional incorporation of Group V elements (Sb, As, P) provides for shallow donor levels in the band gap at about 0.01 ev from the conduction band. The substitutional incorporation of Group III elements (B, Al) generates acceptor levels in the band gap at about 0.01 ev from the valence band. The two types of impurities are almost completely ionized at room temperature and give rise to extrinsic n-type and p-type conductivity the basis for the formation of junction devices such as diodes and transistors (fig. 8). Of increasing importance are compound III V ( adamantine) semiconductors, such as GaAs, InSb, InP and GaP (compounds of Group III and Group V elements). Together these compounds provide eight valence electrons and, by sp 3 hybridization, are able to form a diamond-like, covalent crystal structure with semiconductor properties. These compounds (GaAs, for example) exhibit electron mobilities which are higher than those of silicon and, therefore, are of considerable interest for advanced device technology. 1-28
29 1-29
30 N-type (negative) Doping Electron extrinsic semiconductor (extra e - ) Dope with subvalent impurity B in Si Removes electron from valance band * Creates hole that is mobile Apply Bohr model is hole Energy level are slightly about valence band Acceptor level (0.01 ev about valence band) * P- type 1-30
31 Semiconductor Make a p-n junction 1-31
32 1-32
33 Solids Ordered solids crystalline Irregular solids No long range order Amorphous (glass) Band gaps > 3 ev are transparent Shapes are based on packing 1-33
34 1-34
35 1-35
36 Digital Electronics and Microcomputers Analog and digital signals Use of binary numbers ADC and DAC Transducers to data Controlled by computer 1-36
37 Lecture Extra Bohr Atom Models of atoms Plum pudding Bohr atom Inclusion of quantum states Based on Rutherford atom Bohr atom for 1 electron system E total =1/2m e v 2 +q 1 q 2 /4pe o r q 2 =-e * Include proton and electron 1/2m e v 2 -Ze 2 /4pe o r 1-37
38 Bohr Atom Net force on the electron is zero 0=F dynamic +F coulombic 1/2m e v 2 /r+q 1 q 2 /4pe o r 2 Force is 1/r 2 Energy 1/r E 1/2m e v 2 /r-ze 2 /4pe o r 2 Z is charge on nucleus Quantize energy through angular momentum mvr=nh/2p, n=1,2,3. Can solve for r, E, v = Fdr 1-38
39 Bohr radius R=(e o h 2 /pm e e 2 )(n 2 /Z) Radius is quantized and goes at n 2 R=0.529 Å for Z=1, n=1 A o (Bohr radius) 1-39
40 Atomic Spectra Quantum numbers n=1,2,3,4 r=a o n 2 /Z for gases with 1 electron Energy E=-(m e e 4 /8e o2 h 2 )Z 2 /n 2 For ground state H E=2.18E-18 J/atom=k * Can determine J/mole 1312 kj/mole Energy goes as k/n 2 * System converges to limit 1-40
41 Energy n=infinity, r=infinity, E=0, unbound e - Ionization energy k is ionization energy Velocity v=nh/2pm e r Ionization energy Minimum energy required to remove electron from atom in gas phase Multiple ionization energies 1-41
42 Balmer states Gas H in tube Four lines in visible region Fit lines 1/l=(1/2 2-1/n 2 )R, R=1.1E-7 m -1 1/l=n (wavenumber) E=1/2m e v 2 =ev (V=Volts) At 1 V = 1.6E-19 J =ev K=13.6 ev 1-42
43 Matter energy interaction E incident =1/2mv 2 =qv E scattered DE =E incident -E scattered DE=kZ 2 (1/n 2 final-1/n 2 in ) =hn=hc/l De-excitation of electron results in photon emission Corresponds to line emission 1-43
Chemistry Instrumental Analysis Lecture 8. Chem 4631
Chemistry 4631 Instrumental Analysis Lecture 8 UV to IR Components of Optical Basic components of spectroscopic instruments: stable source of radiant energy transparent container to hold sample device
More informationLecture 1. OUTLINE Basic Semiconductor Physics. Reading: Chapter 2.1. Semiconductors Intrinsic (undoped) silicon Doping Carrier concentrations
Lecture 1 OUTLINE Basic Semiconductor Physics Semiconductors Intrinsic (undoped) silicon Doping Carrier concentrations Reading: Chapter 2.1 EE105 Fall 2007 Lecture 1, Slide 1 What is a Semiconductor? Low
More informationSignal to noise Source of noise Signal to noise enhancement
Chap. 5 (Signals and Noise), Chap. 6 (Spectroscopy introduction) Signal to noise Source of noise Signal to noise enhancement Signal has the information of the analyte Noise is the extraneous information
More informationELECTRONIC DEVICES AND CIRCUITS SUMMARY
ELECTRONIC DEVICES AND CIRCUITS SUMMARY Classification of Materials: Insulator: An insulator is a material that offers a very low level (or negligible) of conductivity when voltage is applied. Eg: Paper,
More informationElectronic Devices & Circuits
Electronic Devices & Circuits For Electronics & Communication Engineering By www.thegateacademy.com Syllabus Syllabus for Electronic Devices Energy Bands in Intrinsic and Extrinsic Silicon, Carrier Transport,
More informationChapter 1 Overview of Semiconductor Materials and Physics
Chapter 1 Overview of Semiconductor Materials and Physics Professor Paul K. Chu Conductivity / Resistivity of Insulators, Semiconductors, and Conductors Semiconductor Elements Period II III IV V VI 2 B
More informationEECS143 Microfabrication Technology
EECS143 Microfabrication Technology Professor Ali Javey Introduction to Materials Lecture 1 Evolution of Devices Yesterday s Transistor (1947) Today s Transistor (2006) Why Semiconductors? Conductors e.g
More informationKATIHAL FİZİĞİ MNT-510
KATIHAL FİZİĞİ MNT-510 YARIİLETKENLER Kaynaklar: Katıhal Fiziği, Prof. Dr. Mustafa Dikici, Seçkin Yayıncılık Katıhal Fiziği, Şakir Aydoğan, Nobel Yayıncılık, Physics for Computer Science Students: With
More informationEE 5344 Introduction to MEMS CHAPTER 5 Radiation Sensors
EE 5344 Introduction to MEMS CHAPTER 5 Radiation Sensors 5. Radiation Microsensors Radiation µ-sensors convert incident radiant signals into standard electrical out put signals. Radiant Signals Classification
More informationUnit IV Semiconductors Engineering Physics
Introduction A semiconductor is a material that has a resistivity lies between that of a conductor and an insulator. The conductivity of a semiconductor material can be varied under an external electrical
More informationGa and P Atoms to Covalent Solid GaP
Ga and P Atoms to Covalent Solid GaP Band Gaps in Binary Group III-V Semiconductors Mixed Semiconductors Affect of replacing some of the As with P in GaAs Band Gap (ev) (nm) GaAs 1.35 919 (IR) GaP 2.24
More informationHigher Physics. Electricity. Summary Notes. Monitoring and measuring a.c. Current, potential difference, power and resistance
Higher Physics Electricity Summary Notes Monitoring and measuring a.c. Current, potential difference, power and resistance Electrical sources and internal resistance Capacitors Conductors, semiconductors
More informationElectrical Properties
Electrical Properties Electrical Conduction R Ohm s law V = IR I l Area, A V where I is current (Ampere), V is voltage (Volts) and R is the resistance (Ohms or ) of the conductor Resistivity Resistivity,
More informationLecture 2. Semiconductor Physics. Sunday 4/10/2015 Semiconductor Physics 1-1
Lecture 2 Semiconductor Physics Sunday 4/10/2015 Semiconductor Physics 1-1 Outline Intrinsic bond model: electrons and holes Charge carrier generation and recombination Intrinsic semiconductor Doping:
More informationEE143 Fall 2016 Microfabrication Technologies. Evolution of Devices
EE143 Fall 2016 Microfabrication Technologies Prof. Ming C. Wu wu@eecs.berkeley.edu 511 Sutardja Dai Hall (SDH) 1-1 Evolution of Devices Yesterday s Transistor (1947) Today s Transistor (2006) 1-2 1 Why
More informationCME 300 Properties of Materials. ANSWERS: Homework 9 November 26, As atoms approach each other in the solid state the quantized energy states:
CME 300 Properties of Materials ANSWERS: Homework 9 November 26, 2011 As atoms approach each other in the solid state the quantized energy states: are split. This splitting is associated with the wave
More informationEECS130 Integrated Circuit Devices
EECS130 Integrated Circuit Devices Professor Ali Javey 8/30/2007 Semiconductor Fundamentals Lecture 2 Read: Chapters 1 and 2 Last Lecture: Energy Band Diagram Conduction band E c E g Band gap E v Valence
More informationEXTRINSIC SEMICONDUCTOR
EXTRINSIC SEMICONDUCTOR In an extrinsic semiconducting material, the charge carriers originate from impurity atoms added to the original material is called impurity [or] extrinsic semiconductor. This Semiconductor
More informationLecture 3b. Bonding Model and Dopants. Reading: (Cont d) Notes and Anderson 2 sections
Lecture 3b Bonding Model and Dopants Reading: (Cont d) Notes and Anderson 2 sections 2.3-2.7 The need for more control over carrier concentration Without help the total number of carriers (electrons and
More informationSemiconductor Detectors
Semiconductor Detectors Summary of Last Lecture Band structure in Solids: Conduction band Conduction band thermal conductivity: E g > 5 ev Valence band Insulator Charge carrier in conductor: e - Charge
More informationsmal band gap Saturday, April 9, 2011
small band gap upper (conduction) band empty small gap valence band filled 2s 2p 2s 2p hybrid (s+p)band 2p no gap 2s (depend on the crystallographic orientation) extrinsic semiconductor semi-metal electron
More informationReview of Optical Properties of Materials
Review of Optical Properties of Materials Review of optics Absorption in semiconductors: qualitative discussion Derivation of Optical Absorption Coefficient in Direct Semiconductors Photons When dealing
More informationCLASS 1 & 2 REVISION ON SEMICONDUCTOR PHYSICS. Reference: Electronic Devices by Floyd
CLASS 1 & 2 REVISION ON SEMICONDUCTOR PHYSICS Reference: Electronic Devices by Floyd 1 ELECTRONIC DEVICES Diodes, transistors and integrated circuits (IC) are typical devices in electronic circuits. All
More informationEngineering 2000 Chapter 8 Semiconductors. ENG2000: R.I. Hornsey Semi: 1
Engineering 2000 Chapter 8 Semiconductors ENG2000: R.I. Hornsey Semi: 1 Overview We need to know the electrical properties of Si To do this, we must also draw on some of the physical properties and we
More informationElectronics The basics of semiconductor physics
Electronics The basics of semiconductor physics Prof. Márta Rencz, Gergely Nagy BME DED September 16, 2013 The basic properties of semiconductors Semiconductors conductance is between that of conductors
More informationLecture 7: Extrinsic semiconductors - Fermi level
Lecture 7: Extrinsic semiconductors - Fermi level Contents 1 Dopant materials 1 2 E F in extrinsic semiconductors 5 3 Temperature dependence of carrier concentration 6 3.1 Low temperature regime (T < T
More informationSemiconductor Devices and Circuits Fall Midterm Exam. Instructor: Dr. Dietmar Knipp, Professor of Electrical Engineering. Name: Mat. -Nr.
Semiconductor Devices and Circuits Fall 2003 Midterm Exam Instructor: Dr. Dietmar Knipp, Professor of Electrical Engineering Name: Mat. -Nr.: Guidelines: Duration of the Midterm: 1 hour The exam is a closed
More informationJunction Diodes. Tim Sumner, Imperial College, Rm: 1009, x /18/2006
Junction Diodes Most elementary solid state junction electronic devices. They conduct in one direction (almost correct). Useful when one converts from AC to DC (rectifier). But today diodes have a wide
More informationIntroduction to Semiconductor Physics. Prof.P. Ravindran, Department of Physics, Central University of Tamil Nadu, India
Introduction to Semiconductor Physics 1 Prof.P. Ravindran, Department of Physics, Central University of Tamil Nadu, India http://folk.uio.no/ravi/cmp2013 Review of Semiconductor Physics Semiconductor fundamentals
More informationV = IR or R = V I. R = ρ l A
Metals and Semiconductors Ram Seshadri MRL 2031, x6129, seshadri@mrl.ucsb.edu Electrical resistance and Ohm s Law: If an electric current I (units of A, Ampère) flows through a conductor with resistance
More informationLecture 2. Introduction to semiconductors Structures and characteristics in semiconductors
Lecture 2 Introduction to semiconductors Structures and characteristics in semiconductors Semiconductor p-n junction Metal Oxide Silicon structure Semiconductor contact Literature Glen F. Knoll, Radiation
More informationSemiconductors. SEM and EDAX images of an integrated circuit. SEM EDAX: Si EDAX: Al. Institut für Werkstoffe der ElektrotechnikIWE
SEM and EDAX images of an integrated circuit SEM EDAX: Si EDAX: Al source: [Cal 99 / 605] M&D-.PPT, slide: 1, 12.02.02 Classification semiconductors electronic semiconductors mixed conductors ionic conductors
More informationDiamond. Covalent Insulators and Semiconductors. Silicon, Germanium, Gray Tin. Chem 462 September 24, 2004
Covalent Insulators and Chem 462 September 24, 2004 Diamond Pure sp 3 carbon All bonds staggered- ideal d(c-c) - 1.54 Å, like ethane Silicon, Germanium, Gray Tin Diamond structure Si and Ge: semiconductors
More informationLecture 2. Introduction to semiconductors Structures and characteristics in semiconductors
Lecture 2 Introduction to semiconductors Structures and characteristics in semiconductors Semiconductor p-n junction Metal Oxide Silicon structure Semiconductor contact Literature Glen F. Knoll, Radiation
More informationDesigning Information Devices and Systems II A. Sahai, J. Roychowdhury, K. Pister Discussion 1A
EECS 16B Spring 2019 Designing Information Devices and Systems II A. Sahai, J. Roychowdhury, K. Pister Discussion 1A 1 Semiconductor Physics Generally, semiconductors are crystalline solids bonded into
More informationESE 570: Digital Integrated Circuits and VLSI Fundamentals
ESE 570: Digital Integrated Circuits and VLSI Fundamentals Lec 4: January 23, 2018 MOS Transistor Theory, MOS Model Penn ESE 570 Spring 2018 Khanna Lecture Outline! CMOS Process Enhancements! Semiconductor
More information1 Name: Student number: DEPARTMENT OF PHYSICS AND PHYSICAL OCEANOGRAPHY MEMORIAL UNIVERSITY OF NEWFOUNDLAND. Fall :00-11:00
1 Name: DEPARTMENT OF PHYSICS AND PHYSICAL OCEANOGRAPHY MEMORIAL UNIVERSITY OF NEWFOUNDLAND Final Exam Physics 3000 December 11, 2012 Fall 2012 9:00-11:00 INSTRUCTIONS: 1. Answer all seven (7) questions.
More informationREVISED HIGHER PHYSICS REVISION BOOKLET ELECTRONS AND ENERGY
REVSED HGHER PHYSCS REVSON BOOKLET ELECTRONS AND ENERGY Kinross High School Monitoring and measuring a.c. Alternating current: Mains supply a.c.; batteries/cells supply d.c. Electrons moving back and forth,
More informationFREQUENTLY ASKED QUESTIONS February 21, 2017
FREQUENTLY ASKED QUESTIONS February 21, 2017 Content Questions How do you place a single arsenic atom with the ratio 1 in 100 million? Sounds difficult to get evenly spread throughout. Yes, techniques
More informationElectro - Principles I
Electro - Principles I Page 10-1 Atomic Theory It is necessary to know what goes on at the atomic level of a semiconductor so the characteristics of the semiconductor can be understood. In many cases a
More informationSemiconductor Device Physics
1 Semiconductor Device Physics Lecture 1 http://zitompul.wordpress.com 2 0 1 3 2 Semiconductor Device Physics Textbook: Semiconductor Device Fundamentals, Robert F. Pierret, International Edition, Addison
More informationn i exp E g 2kT lnn i E g 2kT
HOMEWORK #10 12.19 For intrinsic semiconductors, the intrinsic carrier concentration n i depends on temperature as follows: n i exp E g 2kT (28.35a) or taking natural logarithms, lnn i E g 2kT (12.35b)
More informationElectronic PRINCIPLES
MALVINO & BATES Electronic PRINCIPLES SEVENTH EDITION Chapter 2 Semiconductors Topics Covered in Chapter 2 Conductors Semiconductors Silicon crystals Intrinsic semiconductors Two types of flow Doping a
More informationDO PHYSICS ONLINE ELECTRIC CURRENT FROM IDEAS TO IMPLEMENTATION ATOMS TO TRANSISTORS ELECTRICAL PROPERTIES OF SOLIDS
DO PHYSICS ONLINE FROM IDEAS TO IMPLEMENTATION 9.4.3 ATOMS TO TRANSISTORS ELECTRICAL PROPERTIES OF SOLIDS ELECTRIC CURRENT Different substances vary considerably in their electrical properties. It is a
More informationEnergetic particles and their detection in situ (particle detectors) Part II. George Gloeckler
Energetic particles and their detection in situ (particle detectors) Part II George Gloeckler University of Michigan, Ann Arbor, MI University of Maryland, College Park, MD Simple particle detectors Gas-filled
More informationThe Semiconductor in Equilibrium
Lecture 6 Semiconductor physics IV The Semiconductor in Equilibrium Equilibrium, or thermal equilibrium No external forces such as voltages, electric fields. Magnetic fields, or temperature gradients are
More informationNote that it is traditional to draw the diagram for semiconductors rotated 90 degrees, i.e. the version on the right above.
5 Semiconductors The nearly free electron model applies equally in the case where the Fermi level lies within a small band gap (semiconductors), as it does when the Fermi level lies within a band (metal)
More informationUNIT - IV SEMICONDUCTORS AND MAGNETIC MATERIALS
1. What is intrinsic If a semiconductor is sufficiently pure, then it is known as intrinsic semiconductor. ex:: pure Ge, pure Si 2. Mention the expression for intrinsic carrier concentration of intrinsic
More informationMicroscopic Ohm s Law
Microscopic Ohm s Law Outline Semiconductor Review Electron Scattering and Effective Mass Microscopic Derivation of Ohm s Law 1 TRUE / FALSE 1. Judging from the filled bands, material A is an insulator.
More informationAtoms? All matters on earth made of atoms (made up of elements or combination of elements).
Chapter 1 Atoms? All matters on earth made of atoms (made up of elements or combination of elements). Atomic Structure Atom is the smallest particle of an element that can exist in a stable or independent
More informationIntroduction to Electronics and Semiconductor
Introduction to Electronics and Semiconductor 1 Chapter Objectives To study and understand basic electronics. To study and understand semiconductor principles. 2 Definition Electronics is the branch of
More informationEE301 Electronics I , Fall
EE301 Electronics I 2018-2019, Fall 1. Introduction to Microelectronics (1 Week/3 Hrs.) Introduction, Historical Background, Basic Consepts 2. Rewiev of Semiconductors (1 Week/3 Hrs.) Semiconductor materials
More informationSemiconductor Detectors are Ionization Chambers. Detection volume with electric field Energy deposited positive and negative charge pairs
1 V. Semiconductor Detectors V.1. Principles Semiconductor Detectors are Ionization Chambers Detection volume with electric field Energy deposited positive and negative charge pairs Charges move in field
More informationA semiconductor is an almost insulating material, in which by contamination (doping) positive or negative charge carriers can be introduced.
Semiconductor A semiconductor is an almost insulating material, in which by contamination (doping) positive or negative charge carriers can be introduced. Page 2 Semiconductor materials Page 3 Energy levels
More informationESE370: Circuit-Level Modeling, Design, and Optimization for Digital Systems
ESE370: Circuit-Level Modeling, Design, and Optimization for Digital Systems Lec 6: September 14, 2015 MOS Model You are Here: Transistor Edition! Previously: simple models (0 and 1 st order) " Comfortable
More informationLN 3 IDLE MIND SOLUTIONS
IDLE MIND SOLUTIONS 1. Let us first look in most general terms at the optical properties of solids with band gaps (E g ) of less than 4 ev, semiconductors by definition. The band gap energy (E g ) can
More informationESE 570: Digital Integrated Circuits and VLSI Fundamentals
ESE 570: Digital Integrated Circuits and VLSI Fundamentals Lec 4: January 29, 2019 MOS Transistor Theory, MOS Model Penn ESE 570 Spring 2019 Khanna Lecture Outline! CMOS Process Enhancements! Semiconductor
More informationClassification of Solids
Classification of Solids Classification by conductivity, which is related to the band structure: (Filled bands are shown dark; D(E) = Density of states) Class Electron Density Density of States D(E) Examples
More informationELECTRONIC I Lecture 1 Introduction to semiconductor. By Asst. Prof Dr. Jassim K. Hmood
ELECTRONIC I Lecture 1 Introduction to semiconductor By Asst. Prof Dr. Jassim K. Hmood SOLID-STATE ELECTRONIC MATERIALS Electronic materials generally can be divided into three categories: insulators,
More informationQualitative Picture of the Ideal Diode. G.R. Tynan UC San Diego MAE 119 Lecture Notes
Qualitative Picture of the Ideal Diode G.R. Tynan UC San Diego MAE 119 Lecture Notes Band Theory of Solids: From Single Attoms to Solid Crystals Isolated Li atom (conducting metal) Has well-defined, isolated
More informationITT Technical Institute ET215 Devices I Unit 1
ITT Technical Institute ET215 Devices I Unit 1 Chapter 1 Chapter 2, Sections 2.1-2.4 Chapter 1 Basic Concepts of Analog Circuits Recall ET115 & ET145 Ohms Law I = V/R If voltage across a resistor increases
More informationelectronics fundamentals
electronics fundamentals circuits, devices, and applications THOMAS L. FLOYD DAVID M. BUCHLA Lesson 1: Diodes and Applications Semiconductors Figure 1-1 The Bohr model of an atom showing electrons in orbits
More information12/10/09. Chapter 18: Electrical Properties. View of an Integrated Circuit. Electrical Conduction ISSUES TO ADDRESS...
Chapter 18: Electrical Properties ISSUES TO ADDRESS... How are electrical conductance and resistance characterized? What are the physical phenomena that distinguish? For metals, how is affected by and
More informationElectric Fields. Basic Concepts of Electricity. Ohm s Law. n An electric field applies a force to a charge. n Charges move if they are mobile
Basic Concepts of Electricity oltage E Current I Ohm s Law Resistance R E = I R Electric Fields An electric field applies a force to a charge Force on positive charge is in direction of electric field,
More informationResistance (R) Temperature (T)
CHAPTER 1 Physical Properties of Elements and Semiconductors 1.1 Introduction Semiconductors constitute a large class of substances which have resistivities lying between those of insulators and conductors.
More informationElectrical material properties
Electrical material properties U = I R Ohm s law R = ρ (l/a) ρ resistivity l length σ = 1/ρ σ conductivity A area σ = n q μ n conc. of charge carriers q their charge μ their mobility μ depends on T, defects,
More informationEE130: Integrated Circuit Devices
EE130: Integrated Circuit Devices (online at http://webcast.berkeley.edu) Instructor: Prof. Tsu-Jae King (tking@eecs.berkeley.edu) TA s: Marie Eyoum (meyoum@eecs.berkeley.edu) Alvaro Padilla (apadilla@eecs.berkeley.edu)
More informationCrystal Properties. MS415 Lec. 2. High performance, high current. ZnO. GaN
Crystal Properties Crystal Lattices: Periodic arrangement of atoms Repeated unit cells (solid-state) Stuffing atoms into unit cells Determine mechanical & electrical properties High performance, high current
More informationSemiconductors. Semiconductors also can collect and generate photons, so they are important in optoelectronic or photonic applications.
Semiconductors Semiconducting materials have electrical properties that fall between true conductors, (like metals) which are always highly conducting and insulators (like glass or plastic or common ceramics)
More informationESE 570: Digital Integrated Circuits and VLSI Fundamentals
ESE 570: Digital Integrated Circuits and VLSI Fundamentals Lec 4: January 24, 2017 MOS Transistor Theory, MOS Model Penn ESE 570 Spring 2017 Khanna Lecture Outline! Semiconductor Physics " Band gaps "
More informationISSUES TO ADDRESS...
Chapter 12: Electrical Properties School of Mechanical Engineering Choi, Hae-Jin Materials Science - Prof. Choi, Hae-Jin Chapter 12-1 ISSUES TO ADDRESS... How are electrical conductance and resistance
More informationCLASS 12th. Semiconductors
CLASS 12th Semiconductors 01. Distinction Between Metals, Insulators and Semi-Conductors Metals are good conductors of electricity, insulators do not conduct electricity, while the semiconductors have
More informationSemiconductor Physics Problems 2015
Semiconductor Physics Problems 2015 Page and figure numbers refer to Semiconductor Devices Physics and Technology, 3rd edition, by SM Sze and M-K Lee 1. The purest semiconductor crystals it is possible
More informationIntroduction to Engineering Materials ENGR2000. Dr.Coates
Introduction to Engineering Materials ENGR2000 Chapter 18: Electrical Properties Dr.Coates 18.2 Ohm s Law V = IR where R is the resistance of the material, V is the voltage and I is the current. l R A
More informationChapter 4: Bonding in Solids and Electronic Properties. Free electron theory
Chapter 4: Bonding in Solids and Electronic Properties Free electron theory Consider free electrons in a metal an electron gas. regards a metal as a box in which electrons are free to move. assumes nuclei
More informationConductivity and Semi-Conductors
Conductivity and Semi-Conductors J = current density = I/A E = Electric field intensity = V/l where l is the distance between two points Metals: Semiconductors: Many Polymers and Glasses 1 Electrical Conduction
More informationElectrical Resistance
Electrical Resistance I + V _ W Material with resistivity ρ t L Resistance R V I = L ρ Wt (Unit: ohms) where ρ is the electrical resistivity 1 Adding parts/billion to parts/thousand of dopants to pure
More informationEECS130 Integrated Circuit Devices
EECS130 Integrated Circuit Devices Professor Ali Javey 10/02/2007 MS Junctions, Lecture 2 MOS Cap, Lecture 1 Reading: finish chapter14, start chapter16 Announcements Professor Javey will hold his OH at
More informationAtmospheric Extinction
Atmospheric Extinction Calibrating stellar photometry requires correction for loss of light passing through the atmosphere. Atmospheric Rayleigh and aerosol scattering preferentially redirects blue light
More informationFree Electron Model for Metals
Free Electron Model for Metals Metals are very good at conducting both heat and electricity. A lattice of in a sea of electrons shared between all nuclei (moving freely between them): This is referred
More information3C3 Analogue Circuits
Department of Electronic & Electrical Engineering Trinity College Dublin, 2014 3C3 Analogue Circuits Prof J K Vij jvij@tcd.ie Lecture 1: Introduction/ Semiconductors & Doping 1 Course Outline (subject
More informationElectrical Forces arise from particles in atoms.
Electrostatics Electrical Forces arise from particles in atoms. The protons(+) in the nucleus attract the electrons and hold them in orbit Electrons(-)repel other electrons and protons repel other protons
More informationLecture 2. Introduction to semiconductors Structures and characteristics in semiconductors. Fabrication of semiconductor sensor
Lecture 2 Introduction to semiconductors Structures and characteristics in semiconductors Semiconductor p-n junction Metal Oxide Silicon structure Semiconductor contact Fabrication of semiconductor sensor
More informationLecture (02) PN Junctions and Diodes
Lecture (02) PN Junctions and Diodes By: Dr. Ahmed ElShafee ١ I Agenda N type, P type semiconductors N Type Semiconductor P Type Semiconductor PN junction Energy Diagrams of the PN Junction and Depletion
More informationELEC 4700 Assignment #2
ELEC 4700 Assignment #2 Question 1 (Kasop 4.2) Molecular Orbitals and Atomic Orbitals Consider a linear chain of four identical atoms representing a hypothetical molecule. Suppose that each atomic wavefunction
More informationTheory of Electrical Characterization of Semiconductors
Theory of Electrical Characterization of Semiconductors P. Stallinga Universidade do Algarve U.C.E.H. A.D.E.E.C. OptoElectronics SELOA Summer School May 2000, Bologna (It) Overview Devices: bulk Schottky
More informationChapter 37 Early Quantum Theory and Models of the Atom
Chapter 37 Early Quantum Theory and Models of the Atom Units of Chapter 37 37-7 Wave Nature of Matter 37-8 Electron Microscopes 37-9 Early Models of the Atom 37-10 Atomic Spectra: Key to the Structure
More informationMisan University College of Engineering Electrical Engineering Department. Exam: Final semester Date: 17/6/2017
Misan University College of Engineering Electrical Engineering Department Subject: Electronic I Class: 1 st stage Exam: Final semester Date: 17/6/2017 Examiner: Dr. Baqer. O. TH. Time: 3 hr. Note: Answer
More informationESE370: Circuit-Level Modeling, Design, and Optimization for Digital Systems
ESE370: Circuit-Level Modeling, Design, and Optimization for Digital Systems Lec 6: September 18, 2017 MOS Model You are Here: Transistor Edition! Previously: simple models (0 and 1 st order) " Comfortable
More informationElectron Energy, E E = 0. Free electron. 3s Band 2p Band Overlapping energy bands. 3p 3s 2p 2s. 2s Band. Electrons. 1s ATOM SOLID.
Electron Energy, E Free electron Vacuum level 3p 3s 2p 2s 2s Band 3s Band 2p Band Overlapping energy bands Electrons E = 0 1s ATOM 1s SOLID In a metal the various energy bands overlap to give a single
More informationCCD OPERATION. The BBD was an analog delay line, made up of capacitors such that an analog signal was moving along one step at each clock cycle.
CCDS Lesson 4 CCD OPERATION The predecessor of the CCD was a device called the BUCKET BRIGADE DEVICE developed at the Phillips Research Labs The BBD was an analog delay line, made up of capacitors such
More informationAppendix 1: List of symbols
Appendix 1: List of symbols Symbol Description MKS Units a Acceleration m/s 2 a 0 Bohr radius m A Area m 2 A* Richardson constant m/s A C Collector area m 2 A E Emitter area m 2 b Bimolecular recombination
More information! CMOS Process Enhancements. ! Semiconductor Physics. " Band gaps. " Field Effects. ! MOS Physics. " Cut-off. " Depletion.
ESE 570: Digital Integrated Circuits and VLSI Fundamentals Lec 4: January 3, 018 MOS Transistor Theory, MOS Model Lecture Outline! CMOS Process Enhancements! Semiconductor Physics " Band gaps " Field Effects!
More informationSemiconductor Physics fall 2012 problems
Semiconductor Physics fall 2012 problems 1. An n-type sample of silicon has a uniform density N D = 10 16 atoms cm -3 of arsenic, and a p-type silicon sample has N A = 10 15 atoms cm -3 of boron. For each
More informationModern Physics for Frommies IV The Universe - Small to Large Lecture 4
Fromm Institute for Lifelong Learning University of San Francisco Modern Physics for Frommies IV The Universe - Small to Large Lecture 4 3 February 06 Modern Physics IV Lecture 4 Agenda Administrative
More informationSection 12: Intro to Devices
Section 12: Intro to Devices Extensive reading materials on reserve, including Robert F. Pierret, Semiconductor Device Fundamentals EE143 Ali Javey Bond Model of Electrons and Holes Si Si Si Si Si Si Si
More informationMinimal Update of Solid State Physics
Minimal Update of Solid State Physics It is expected that participants are acquainted with basics of solid state physics. Therefore here we will refresh only those aspects, which are absolutely necessary
More informationCourse overview. Me: Dr Luke Wilson. The course: Physics and applications of semiconductors. Office: E17 open door policy
Course overview Me: Dr Luke Wilson Office: E17 open door policy email: luke.wilson@sheffield.ac.uk The course: Physics and applications of semiconductors 10 lectures aim is to allow time for at least one
More informationLecture 18: Semiconductors - continued (Kittel Ch. 8)
Lecture 18: Semiconductors - continued (Kittel Ch. 8) + a - Donors and acceptors J U,e e J q,e Transport of charge and energy h E J q,e J U,h Physics 460 F 2006 Lect 18 1 Outline More on concentrations
More informationESE370: Circuit-Level Modeling, Design, and Optimization for Digital Systems. Today MOS MOS. Capacitor. Idea
ESE370: Circuit-Level Modeling, Design, and Optimization for Digital Systems Day 9: September 26, 2011 MOS Model Today MOS Structure Basic Idea Semiconductor Physics Metals, insulators Silicon lattice
More information