GROWMARK, INC 2200 Sout h Ave nue, P. O. Box 587, Counc i l Bl uf f s, I A

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Letitia Gloria Merritt
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1 UPDATED: J ul y 8, 2004 MATERIAL SAFETY DATA SHEET GROWMARK, INC 2200 Sout h Ave nue, P. O. Box 587, Counc i l Bl uf f s, I A EMERGENCY TELEPHONE NUMBER: 1- ( 800) ****************** I. PRODUCT IDENTIFICATION ****************** Pr oduc t Na me : Uni t e d Se l e c t 450 A/ S 10w30 Che mi c a l Na me : Lubr i c a t i ng Oi l Che mi c a l Fa mi l y: Pe t r ol e um Hydr oc a r bon Tr a de Na me s : Uni t e d, Hyde, Nour s e, Tr a c t o, En- O- Co ( Enoc o) ********* II. TYPICAL CHEMICAL AND PHYSICAL PROPERTIES ********* Va por Pr e s s ur e ( MM HG) : Ni l Va por De ns i t y ( Ai r =1) Ni l Sol ubi l i t y ( i n wa t e r ) : Ni l Me l t i ng Poi nt : NA Spe c i f i c Gr a vi t y ( H2O=1) : Boi l i ng Poi nt F( C) : Gr e a t e r t ha n 680 F ( 360 C) Eva por a t i on Ra t e : Sl owe r t ha n n- But yl Ac e t a t e Appe a r a nc e a nd Odor Ambe r Li qui d, Sl i ght Hydr oc a r bon Odor ***************** III. HAZARDOUS COMPONENTS ********************* COMPONENT CAS Wt - % ACGI H TLV OSHA PEL STEL Hi ghl y Re f i ne d Pe t r ol e um Oi l mg/ M 3 5 mg/ M 3 10 mg/ M 3 Zi nc di a l kyl di t hi ophos pha t e No l i mi t s e s t a bl i s he d ************* IV. FIRE AND EXPLOSION HAZARD DATA ************** Fl a mma bi l i t y Cl a s s : NFPA 704=1 NFPA 30=I I I - B Combus t i bl e Fl a s h Poi nt F ( C) 370 F( 188 C) F ( 235 C) ( COC) LEL: n/ a v EXTI NGUI SHI NG MEDI A: Ac c or di ng t o t he NFPA gui de, us e wa t e r f og. Foa m. Dr y c he mi c a l or CO 2. Do not us e a di r e c t s t r e a m of wa t e r. Pr oduc t wi l l f l oa t a nd c a n be r e i gni t e d on t he s ur f a c e of wa t e r. Us e wa t e r t o c ool c ont a i ne r s SPECI AL FI RE FI GHTI NG PROCEDURES AND PRECAUTI ONS: Ma t e r i a l wi l l not bur n unl e s s pr e he a t e d. Do not e nt e r c onf i ne d f i r e - s pa c e wi t hout pr ope r pr ot e c t i ve e qui pme nt i nc l udi ng a pos i t i ve - pr e s s ur e NI OSH a ppr ove d s e l f - c ont a i ne d br e a t hi ng a ppa r a t us. Us e wa t e r t o ke e p f i r e e xpos e d c ont a i ne r s c ool. ********************** V. REACTIVITY DATA ********************* 1

2 St a bi l i t y ( t he r ma l, l i ght, e t c. ) : St a bl e Ha z a r dous pol yme r i z a t i on: wi l l not oc c ur I nc ompa t a bi l i t y ( ma t e r i a l s t o a voi d) : s t r ong oxi di z e r s Condi t i ons t o a voi d: e xt r e me he a t Ha z a r dous de c ompos i t i on pr oduc t s : c a r bon monoxi de ******************** VI. HEALTH HAZARD DATA ******************* EYE CONTACT: Lubr i c a t i ng oi l s a r e ge ne r a l l y c ons i de r e d no mor e t ha n mi ni ma l l y i r r i t a t i ng t o t he e ye s. SKI N CONTACT: Br i e f c ont a c t i s not i r r i t a t i ng. Lubr i c a t i ng oi l s a r e ge ne r a l l y c ons i de r e d no mor e t ha n mi l dl y i r r i t a t i ng t o t he s ki n. Be c a us e of i t s de f a t t i ng pr ope r t i e s, pr ol onge d a nd r e pe a t e d c ont a c t ma y a ggr a va t e a n e xi s t i ng or r e s ul t i n va r i ous s ki n di s or de r s ( de r ma t i t i s, f ol l i c ul i t i s, e t c. ) I NHALATI ON: I nha l a t i on of va por or oi l mi s t ( ge ne r a t e d a t hi gh t e mpe r a t ur e s ) ma y r e s ul t i n mi l d i r r i t a t i on of t he uppe r r e s pi r a t or y t r a c t, i nc l udi ng i r r i t a t i on of t he nos e a nd t hr oa t, he a da c he, na us e a a nd dr ows i ne s s. I NGESTI ON: No a dve r s e e f f e c t s e xpe c t e d. I f mor e t ha n s e ve r a l mout hf ul s a r e s wa l l owe d, a bdomi na l di s c omf or t, na us e a a nd di a r r he a ma y oc c ur. *********** VII. EMERGENCY AND FIRST AID PROCEDURES *********** EYE CONTACT: Fl us h wi t h wa t e r f or 15 mi nut e s whi l e hol di ng e ye l i ds ope n. oc c ur s, s e e k me di c a l a t t e nt i on. I f i r r i t a t i on SKI N CONTACT: Re move c ont a mi na t e d c l ot hi ng a nd wi pe of f e xc e s s. Wa s h wi t h pl e nt y of s oa p a nd wa t e r or a wa t e r l e s s ha nd c l e a ne r f ol l owe d by s oa p a nd wa t e r. I f i r r i t a t i on oc c ur s, s e e k me di c a l a t t e nt i on. I NHALATI ON: Re move vi c t i m t o f r e s h a i r. I f br e a t hi ng i s di f f i c ul t, pr ovi de r e s pi r a t or y s uppor t, a nd s e e k me di c a l a t t e nt i on. I NGESTI ON: Do not i nduc e vomi t i ng. Dr i nk wa t e r. I f unc omf or t a bl e, s e e k me di c a l a t t e nt i on. ******* VIII. ENVIRONMENTAL PROTECTION and ACCIDENTAL RELEASE ******** SPI LL OR LEAK PROCEDURE: St op s our c e of l e a k i f pos s i bl e. Di ke a nd c ont a i n s pi l l. Re move wi t h va c uum t r uc ks or pump t o s t or a ge s a l va ge ve s s e l s. Soa k up r e s i due wi t h a bs or be nt s uc h a s c l a y, s a nd, e t c. Di s pos e of i n a c c or da nc e wi t h c ur r e nt a ppl i c a bl e l a ws a nd r e gul a t i ons. ******************* IX. EMPLOYEE PROTECTION ******************* EYE / FACE PROTECTI ON: Che mi c a l t ype goggl e s or f a c e s hi e l d i s r e c omme nde d t o pr e ve nt e ye c ont a c t. 2

3 RESPI RATORY PROTECTI ON: No s pe c i a l r e qui r e me nt s unde r or di na r y c ondi t i ons of us e a nd wi t h a de qua t e ve nt i l a t i on. I f c onc e nt r a t i on e xc e e ds oc c upa t i ona l e xpos ur e l i mi t s ( s e c t i on I I I. ) Us e a NI OSH a ppr ove d r e s pi r a t or. PROTECTI VE CLOTHI NG: Nor ma l i ndus t r i a l e ye pr ot e c t i on, gl ove s, a nd ot he r pr ot e c t i ve c l ot hi ng a s r e qui r e d t o mi ni mi z e c ont a c t wi t h e ye s a nd s ki n. 3

4 ******************* IX. EMPLOYEE PROTECTION (Cont d) ******************* VENTI LATI ON: Ade qua t e t o me e t c ompone nt oc c upa t i ona l e xpos ur e l i mi t s. EXPOSURE LI MI T FOR TOTAL PRODUCT: None e s t a bl i s he d f or t hi s pr oduc t. ******************* X. TOXICOLOGICAL INFORMATION ******************* Me di a n Le t ha l Dos e ( LD50 LC 50) ( Spe c i e s ) Or a l : be l i e ve d t o be >5 g/ kg ( r a t ) ; pr a c t i c a l l y non- t oxi c I nha l a t i on: N. D. De r ma l : be l i e ve d t o be >5 g/ kg ( r a bbi t ) ; no a ppr e c i a bl e e f f e c t I r r i t a t i on I nde x, e s t i ma t e of I r r i t a t i on ( Spe c i e s ) Ski n: be l i e ve d t o be <0. 5 / 8. 0 ( r a bbi t ) ; no a ppr e c i a bl e e f f e c t Eye s : be l i e ve d t o be < 15 / 110 ( r a bbi t ) ; no a ppr e c i a bl e e f f e c t Se ns i t i z a t i on: N. D. Ot he r : Thi s pr oduc t a nd i t s c ompone nt s a r e not c l a s s i f i e d a s c a r c i noge ns by t he I nt e r na t i ona l Age nc y f or Re s e a r c h on Ca nc e r ( I ARC) or OSHA. Us e d ga s ol i ne mot or oi l s ha ve be e n s hown t o c a us e s ki n c a nc e r whe n r e pe a t e dl y a ppl i e d t o mous e s ki n wi t hout a ny e f f or t t o r e move t he ma t e r i a l be t we e n a ppl i c a t i ons. The r e i s no e vi de nc e of a c a us a l r e l a t i ons hi p be t we e n s ki n c a nc e r i n huma ns a nd e xpos ur e t o us e d mot or oi l. ******************* XI. DISPOSAL CONSIDERATIONS ******************* Wa s t e Di s pos a l Me t hods : Thi s pr oduc t ha s be e n e va l ua t e d f or RCRA c ha r a c t e r i s t i c s a nd doe s not me e t t he c r i t e r i a of a ha z a r dous wa s t e i f di s c a r de d i n i t s pur c ha s e d f or m. Unde r RCRA, i t i s t he r e s pons i bi l i t y of t he us e r of t he pr oduc t t o de t e r mi ne a t t he t i me of di s pos a l, whe t he r t he pr oduc t me e t s RCRA c r i t e r i a f or ha z a r dous wa s t e. Thi s i s be c a us e pr oduc t us e s, t r a ns f or ma t i ons, mi xt ur e s, pr oc e s s e s, e t c. ma y r e nde r t he r e s ul t i ng ma t e r i a l s ha z a r dous. Re ma r ks : Re c yc l e a l l us e d oi l s. Re c yc l i ng us e d oi l s ma y pr ovi de e xe mpt i ons r e l a t e d t o ha z a r dous wa s t e r e gul a t i ons. ******************* XII. TRANSPORTATION INFORMATION ******************* D. O. T. Cl a s s i f i c a t i on: Not Ha z a r dous by D. O. T. Re gul a t i ons D. O. T. Pr ope r Shi ppi ng Na me : Not Appl i c a bl e Thi s pr oduc t i s c ons i de r e d a n oi l unde r 49CFR ( DOT) Pa r t 130. I f s hi ppe d by r a i l or hi ghwa y i n a t a nk wi t h a c a pa c i t y of 3, 500 ga l l ons or mor e, i t i s s ubj e c t t o t he r e qui r e me nt s of Pa r t 130. ******************* XIII. OTHER INFORMATION ******************* The i nf or ma t i on c ont a i ne d he r e i n i s ba s e d upon da t a a va i l a bl e t o us a nd i s be l i e ve d t o be a c c ur a t e. Howe ve r, we ma ke no wa r r a nt y, e xpr e s s or i mpl i e d, r e ga r di ng t he a c c ur a c y of t he s e da t a or t he r e s ul t s t o be obt a i ne d f r om t he us e t he r e of. We a s s ume no r e s pons i bi l i t y f or i nj ur y f r om t he us e of t he pr oduc t de s c r i be d he r e i n. 4

5 I nqui r i e s r e ga r di ng MSDS s houl d be di r e c t e d t o: Mc Col l i s t e r & Co. Ma na ge r, Pr oduc t I nf or ma t i on a nd Sa f e t y P. O. Box 587 Counc i l Bl uf f s, I A

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