CHEM Inorganic Chemistry for High School Teachers II (Spring 2014)

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1 CHEM Inorganic Chemistry for High School Teachers II (Spring 2014) 3 credit hours Online Format (January 13 May 8, 2014) Instructor: Christopher L. Exstrom Office: 405C Bruner Hall of Science Phone: (308) exstromc@unk.edu Required textbook: Inorganic Chemistry, 4 th ed. (Miessler and Tarr), ISBN Technical Requirements and Competencies. Course delivery will be made entirely through Blackboard. A broadband internet connection (DSL, cable, etc.) is recommended but the instructor will make every effort to keep the size of course documents down to accommodate those with dial-up internet connections. Course documents may be in Adobe PDF or Microsoft Office (Word, Excel, Powerpoint) formats. Links to downloadable free viewers will be provided. It is expected that you be able to download documents and open them in their appropriate programs. Exams will be taken on Blackboard. Familiarity with standard online form functions radio buttons, check boxes, fill-in blanks, etc. is required. Course Description. This is the second in a two-course sequence (CHEM ) on inorganic chemistry for high school teachers. CHEM 821 emphasizes more advanced topics in Inorganic Chemistry molecular orbital theory, the structure and properties of transition metal, and an introduction to inorganic materials and nanoparticles. Example demonstrations and laboratory exercises are given. The UNK Graduate Course Catalog indicates that this course may be offered for any number of credits between 1-4, with or without laboratory. This semester, CHEM 821 is offered for 3 credits without laboratory. Course Learning Structure. Welcome to the world of inorganic chemistry! Course content is divided between four modules: Module 1 Structures of (Textbook chapter 9 plus supplemental internet references) Module 2 Magnetic and Electric Properties of (Selected sections of textbook chapters 10 and 11 plus supplemental internet references) Module 3 Chemistry: Reactions and Mechanisms (Textbook chapter 12 plus supplemental internet references) Module 4 Molecular Orbital Theory and Modern Inorganic Materials (Selected sections of textbook chapter 5 plus supplemental internet references) Within each module, the following types of assignments must be completed: Readings from the textbook, instructor-generated supplemental handouts, and internet resources Homework Problems from instructor-generated handouts Discussion Board You will be required to contribute at least one response to each instructor-initiated thread pertaining to questions or issues within each module. The instructor will initiate one thread per module. A qualifying response must demonstrate a thorough analysis of the issue or question at hand in other words, something more thought out than yes or no. The instructor s role in discussion activities will primarily be that of a moderator, as threads will typically address openended issues and questions. Specific questions about the understanding of course material should be ed directly to the instructor.

2 Your grade will be based on the number of accumulated points as a percentage of the total possible number of points according to the distribution given below: GRADING DISTRIBUTION* Exams (4) 50% (12.5% each) Graded Homework (4) 20% (5% each) Original Lesson Plan Assignment 20% Discussion Board Responses (4) 10% (2.5% each) Exams. Four examinations of 1- to 2-hour lengths will be given. These will consist of a combination of multiplechoice, short answer and essay questions that may require you to properly apply several concepts simultaneously. Each exam will cover one module. There will be no cumulative final exam. Homework. You will receive assigned homework as handouts from the instructor. All problems will be graded. Original Lesson Plan Assignment (deadline: Friday, May 2, 5:00 p.m. CT topic proposal due on Monday, April 14, 5:00 p.m. CT). At the graduate level, one must develop the ability to create original instructional material from existing knowledge. As a term project, you are required to write an original 3-5 day lesson plan that introduces and/or reinforces one or more concepts from chapters 5, 9, 10, 11, and/or 12. Your writeup should include a lesson plan summary in the format that you would turn in to your principal or department head, detailed outlines (with full explanations of any example problems) of any lectures, full descriptions and teacher notes for any demonstrations, and complete handouts for any lab experiments (include a background section, procedural instructions for students, additional notes for teachers, and information on chemical hazards, safety, and storage considerations), homework assignments, and quizzes. A one-page topic proposal and plan outline must be turned in by April 14. Within a week, the instructor will evaluate the outline and return it with suggestions for the full assignment. Discussion Board Responses. Each response will be graded according to rubrics posted in Blackboard. Grading Scale. The following weighted percentage point scale will be the initial starting point: A (93-100), A- ( ), B+ ( ), B ( ), B- ( ), C+ ( ), C ( ), C- ( ), D+ ( ), D ( ), D- ( ), F (below 60). This scale may be moved downward at the instructors discretion. After the 2 nd and each succeeding exam, course grade estimates will be posted on Blackboard. DEADLINES. A table of deadlines for all assignments and exams is given on the last page of this syllabus. To keep the class flowing smoothly, these deadlines will be strictly adhered to. The following penalties will be applied to late work: Up to 24 hours late Between hours late Over 48 hours late 25% of possible points (or zero score for discussion board response) 50% of possible points (or zero score for discussion board response) Zero score (NOTE: These late times apply to business days only. Business days are defined as Monday-Friday except the following January 20 (MLK Day) and March (UNK Spring Break)

3 CHEM 821 Course Material Outline and Objectives Topic Area Textbook Coverage Broad Objectives Suggested Practice Problems (End of Chapter) Structure of EXAM #1 Chapter 9 Understand how ligands coordinate (or form dative bonds with) transition metal ions to form transition metal Know the formulas, charges, coordination modes, and abbreviations (if any) of the ligands in Tables 9.2, 9.3, and 9.4 (both editions). Understand how to determine the total number of valence electrons (metal d electrons + electrons contributed through ligand coordination) in transition metal Understand the molecular geometries (and identify example ) for 2-, 3-, 4-, 5-, 6-, and 8-coordinate Be able to determine all isomers for 6- coordinate of various ligand combinations (see Table 9.6, both editions) Understand and identify /, hydrate, ionization, coordination, and linkage isomers 12 (For each transition metal, determine its charge and number of valence d electrons.) Bonding in Chapter 10 (pp , , and ) Understand how formation equilibrium constants (sequential and total) reflect metalligand bond strength Understand how magnetic susceptibility is used to determine the number of unpaired electrons in a transition metal ion Understand crystal field theory and how it predicts the d-orbital energy splitting in octahedral, tetrahedral, and square planar Understand how high-spin and low-spin electronic configurations may arise in octahedral. Be able to calculate ligand field stabilization energies for octahedral and understand the coulombic and exchange energies involved. Understand the spectrochemical series of ligands and how they change the o energies in octahedral 1-3, 5-6, 19, 23

4 Electronic Spectroscopy of EXAM #2 Chapter 11 (pp and ) and supplementary handouts Understand how UV-vis spectra indicate the absorption of light wavelengths that result in the promotion of an electron from a lower energy orbital to a higher energy one. Understand Beer s Law and be able to convert between photon wavelength and wavenumber Understand the nature of d-d, metal-to-ligandcharge-transfer (MLCT), ligand-to-metalcharge-transfer (LMCT), and interligandcharge-transfer (ICT or LL CT) electronic transitions 8-9, 16-17, 20, 25, 27 Chemistry of EXAM #3 Chapter 12 (both editions) Understand ligand substitution reactions and associative and dissociation mechanisms Understand how ligand substitution reactions can affect the stereoisomerism of product Understand the nature of the trans effect in ligand substitution reactions of square planar Understand outer- and inner-sphere mechanisms for redox reactions Understand the nature of template reactions 1-2, 5-6, 10, 15 Molecular Orbital Theory Chapter 5 (pp and ) Know the shapes and phases of s, p, and d atomic orbitals Understand how s, p, and d orbitals may overlap to form bonding and antibonding molecular orbitals (MOs) Understand how to derive MO diagrams for homonuclear diatomic molecules ranging from H2 through Ne2 and determine bond orders Understand the trends in valence atomic orbital energies and their effects on the MO bonding of heteronuclear diatomic molecules and salts 2-5, 7-9 Modern Inorganic Materials EXAM #4 Supplementary Handouts provided Understand the dimensions of thin films and the properties of photovoltaic materials Understand the dimensions and scale of nanomaterials Understand quantum confinement effects and its relation to particle size and light absorption and emission Understand the three major carbon nanostructures 0-D fullerenes, graphene and nanotubes and their fundamental properties none

5 CHEM 821 (Spring 2014) Deadline Summary Date Friday, January 31 February 5-12 Friday, February 28 March 5-12 Monday, March 31 April 2-9 Monday, April 14 Friday, April 25 April 30-May 8 Friday, May 2 Event Module 1 discussion board (DB) forum response due Exam #1 access window Module 2 DB forum response due Exam #2 access window Module 3 DB forum response due Exam #3 access window Lesson Plan Assignment topic proposal due Module 4 DB forum response due Exam #4 access window Lesson Plan Assignment Due Exam windows begin at 8:00 a.m. CT on the first day and end at 11:00 p.m. CT on the last day. All other deadlines are at 5:00 p.m. CT unless otherwise noted. NOTE: For each module, homework problem deadlines are when you access that exam. Allow 48 hours (counting business days only) for feedback.

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