Ph.D. 03/10 Chemistry Pasadena, CA California Institute of Technology (Caltech), Pasadena, CA

Transcription

1 BIOGRAPHICAL SKETCH Provide the following information for the Senior/key personnel and other significant contributors in the order listed on Form Page 2. Follow this format for each person. DO NOT EXCEED FOUR PAGES. NAME Surratt, Jason D. era COMMONS USER NAME (credential, e.g., agency login) JASON_SURRATT POSITION TITLE Assistant Professor EDUCATION/TRAINING (Begin with baccalaureate or other initial professional education, such as nursing, include postdoctoral training and residency training if applicable.) DEGREE INSTITUTION AND LOCATION MM/YY FIELD OF STUDY (if applicable) North Carolina State University, Raleigh, NC B.A. 05/03 Chemistry North Carolina State University, Raleigh, NC B.S. 05/03 Meteorology California Institute of Technology (Caltech), Ph.D. 03/10 Chemistry Pasadena, CA California Institute of Technology (Caltech), Pasadena, CA Postdoctoral 06/10 Chemistry A. Personal Statement My research utilizes advanced mass spectrometry and chromatographic techniques to understand as deeply as possible the atmospheric chemistry that occurs in both the gas and particulate phases, with special focus on the chemistry leading to the formation of organic aerosol. Since numerical models currently underestimate the amount of organic aerosol mass observed in fine aerosol collected from several locations, which indicates that significant sources of organic aerosol are not yet identified or well characterized, my research involves the chemically characterization of both smog chamber-generated and ambient aerosol in order to more adequately describe sources and sinks of aerosols in the Earth s atmosphere. By using this approach, in collaboration with others, which includes the U.S. EPA, European colleagues, and the Electric Research Power Institute (EPRI), I have helped to elucidate the chemical pathways leading to organic aerosol formation from the atmospheric oxidation of isoprene, which is the most abundant non-methane hydrocarbon emitted annually into the Earth s atmosphere that was previously thought not to be a significant source of aerosol. My detailed chemical measurements are also coupled with toxicological, risk assessment, and global and regional climate modeling data in order to more fully assess the impact of fine aerosols on human health and global climate change. B. Positions and Honors Positions and Employment Graduate Research Assistant, California Institute of Technology, Pasadena, CA 2010 Post Doctoral Research Fellow, California Institute of Technology, Pasadena, CA Assistant Professor, Department of Environmental Sciences and Engineering, UNC School of Public Health present Associate Professor, Department of Environmental Sciences and Engineering, UNC School of Public Health Other Experience and Professional Memberships 2006 present Member of the American Association for Aerosol Research (AAAR) 2006 present Member of the American Geophysical Union (AGU) 2006 present Member of the American Chemical Society (ACS) 2006 present Reviewer for Scientific Journals: Environmental Science and Technology, Atmospheric Chemistry and Physics, Nature Geosciences, Atmospheric Environment, Analytical Chemistry, Journal of Geophysical Research-Atmospheres, Geophysical Research Letters, Journal of Environmental Monitoring, Journal of Physical Chemistry A, and Physical Chemistry Chemical Physics. Honors EPA Science to Achieve Results (STAR) Graduate Fellowship 2011 Atmospheric Chemistry Colloquium for Emerging Senior Scientists (ACCESS)

2 2012 Walter A. Rosenblith New Investigator Award from Health Effects Institute (HEI) 2013 EPA Early Career Award 2013 AAAR Sheldon K. Friedlander Award 2013 Environmental Science & Technology (ES&T) Excellence in Review Award 2013 Camille & Henry Dreyfus Environmental Chemistry Mentor C. Selected Peer-reviewed Publications (Selected from 80 peer-reviewed publications) Most relevant to the current application 1. Riedel TP, Lin YH, Budisulistiorini SH, Gaston CJ, Thornton JA, Zhang Z, Vizuete WG, Gold A, Surratt JD (2015) Heterogeneous Reactions of Isoprene-Derived Epoxides: Reaction Probabilities and Molar SOA Yield Estimates, Environ Sci Technol Lett, 2 (2), Lin YH, Budisulistiorini SH, Chu K, Siejack RA, Zhang H, Riva M, Zhang Z, Gold A, Kautzman KE, Surratt JD (2014) Light-Absorbing Oligomer Formation in Secondary Organic Aerosol from Reactive Uptake of Isoprene Epoxydiols. Environ Sci Technol, 48 (20), Budisulistiorini SH, Canagaratna MR, Croteau PL, Baumann K, Edgerton ES, Kollman MS, Ng NL, Verma, V, Shaw SL, Knipping EM, Worsnop DR, Jayne JT, Weber RJ, Surratt JD (2014) Intercomparison of an Aerosol Chemical Speciation Monitor (ACSM) with Ambient Fine Aerosol Measurements in Downtown Atlanta, Georgia. Atmos Meas Tech, 7 (7), Budisulistiorini SH, Canagaratna MR, Croteau PL, Marth WJ, Baumann K, Edgerton ES, Shaw SL, Knipping EM, Worsnop DR, Jayne JT, Gold A, Surratt JD. Real-time continuous characterization of secondary organic aerosol derived from isoprene epoxydiols in downtown Atlanta, Georgia, using the Aerodyne Aerosol Chemical Speciation Monitor. Environ Sci Technol. 2013; 47(11): PMID: Lin YH, Zhang H, Pye HO, Zhang Z, Marth WJ, Park S, Arashiro M, Cui T, Budisulistiorini SH, Sexton KG, Vizuete W, Xie Y, Luecken DJ, Piletic IR, Edney EO, Bartolotti LJ, Gold A, Surratt JD. Epoxide as a precursor to secondary organic aerosol formation from isoprene photooxidation in the presence of nitrogen oxides. Proc Natl Acad Sci U S A. 2013; 110(17): PMCID: PMC Lin YH, Zhang Z, Docherty KS, Zhang H, Budisulistiorini SH, Rubitschun CL, Shaw SL, Knipping EM, Edgerton ES, Kleindienst TE, Gold A, Surratt JD. Isoprene epoxydiols as precursors to secondary organic aerosol formation: acid-catalyzed reactive uptake studies with authentic compounds. Environ Sci Technol. 2012; 46(1): PMCID: PMC Lin YH, Knipping EM, Edgerton ES, Shaw SL, Surratt, JD*. Investigating the Influences of SO 2 and NH 3 Levels on Isoprene-Derived Secondary Organic Aerosol Formation Using Conditional Sampling Approaches. Atmospheric Chemistry & Physics Discussions. 2013; 13(2): Article does not have PMID or PMCID. 8. Zhang H, Lin YH, Zhang Z, Zhang X, Shaw SL, Knipping EM, Weber RJ, Gold A, Kamens RM, Surratt JD*. Secondary Organic Aerosol Formation from Methacrolein Photooxidation: Roles of NO x Level, Relative Humidity, and Aerosol Acidity. Environmental Chemistry. 2012; 9(3): Article does not have PMID or PMCID. 9. Zhang H, Surratt, JD*, Lin YH, Bapat J, Kamens RM. Effect of Relative Humidity on SOA Formation from Isoprene/NO Photooxidation: Enhancement of 2-Methylglyceric Acid and its Corresponding Oligoesters under Dry Conditions. Atmospheric Chemistry & Physics. 2011; 11(13): Article does not have PMID or PMCID. 10. Surratt JD, Chan AW, Eddingsaas NC, Chan M, Loza CL, Kwan AJ, Hersey SP, Flagan RC, Wennberg PO, Seinfeld JH. Reactive intermediates revealed in secondary organic aerosol formation from isoprene. Proc Natl Acad Sci U S A. 2010; 107(15): PMCID: PMC Surratt JD, Gómez-González Y, Chan AW, Vermeylen R, Shahgholi M, Kleindienst TE, Edney EO, Offenberg JH, Lewandowski M, Jaoui M, Maenhaut W, Claeys M, Flagan RC, Seinfeld JH. Organosulfate formation in biogenic secondary organic aerosol. J Phys Chem A. 2008; 112(36): PMID: Surratt JD, Murphy SM, Kroll JH, Ng NL, Hildebrandt L, Sorooshian A, Szmigielski R, Vermeylen R, Maenhaut W, Claeys M, Flagan RC, Seinfeld JH. Chemical composition of secondary organic aerosol formed from the photooxidation of isoprene. J Phys Chem A. 2006; 110(31): PMID:

3 D. Research Support Ongoing Research Support EP-P37771/C16950 Surratt (PI) 10/01/10 06/30/16 Field Deployment of the Aerodyne Aerosol Chemical Speciation Monitor (ACSM) in the Southeastern USA In the present work, we propose to deploy the Aerodyne ACSM over a 5-year period at selected sites located within the SEARCH network for purposes of evaluating the utility of this instrument for unattended long-term monitoring of fine PM. In addition to the ACSM, we will have complimentary measurements of OC/EC mass concentrations, as well as additional measurements of inorganic species, CO, O3, NOx, SO2, and VOC mixing ratios RFA11-2/13-1 Surratt (PI) 03/01/03 02/28/16 Health Effects Institute (HEI) Walter A. Rosenblith New Investigator Award Understanding the Health Effects of Isoprene-Derived Particulate Matter Enhanced by Anthropogenic Pollutants We propose to test the hypothesis that isoprene-derived PM induces toxicity and biological effects and in human lung cells. RD Surratt (PI) 04/02/13 03/31/16 US Environmental Protection Agency (EPA) - Early Career Award Impacts of Anthropogenic Emissions in the Southeastern U.S. on Heterogeneous Chemistry of Isoprene- Derived Epoxides Leading to Secondary Organic Aerosol Formation The underlying hypothesis of this study is that anthropogenic emissions enhance isoprene SOA formation through the heterogeneous chemistry of isoprene-derived epoxides, possibly leading to light-absorbing SOA in the southeastern U.S. The specific objectives to evaluate this hypothesis include: (1) Leveraging our ongoing Look Rock, TN, field site during the community-led Southern Oxidant & Aerosol Study (SOAS) in summer 2013 to evaluate how isoprene SOA formation chemistry varies between regional and urban influenced air masses; (2) Evaluate the effects of relative humidity, aerosol acidity, and seed aerosol type on the heterogeneous chemistry of isoprene-derived epoxides leading to SOA and how this might yield light-absorbing aerosol constituents (i.e., brown carbon); (3) Evaluate gaseous yields of epoxides from isoprene oxidation under varying initial levels of nitric oxide. NA130AR Surratt (PI) 08/01/13 07/31/16 Department of Commerce (DOC) Organic Nitrogen in Atmospheric Aerosols: Concentrations, Chemical Composition, and Properties The work proposed here involves the determination of the identities, amounts, and key properties of PON in organic aerosol, over a wide geographical and temporal range. Coverage of such a range will be achieved by analyzing previously-collected, archived filter samples from a number of locations worldwide, including those associated with NOAA campaigns. Sites vary greatly in terms of anthropogenic influence, ranging from an urban/polluted area (CalNex 2010, Pasadena CA), to suburban/rural areas influenced by urban outflow or biomass burning (NEAQS 2004; Chapel Hill, NC; BEACHON-RoMBAS 2011, Manitou Forest, CO; SOAS 2013, Look Rock, TN), to a very remote site (Cape Grim, Australia). A Surratt (PI) 02/1/14 01/31/16 Camille and Henry Dreyfus Foundation Heterogeneous Chemistry of Isoprene-Derived Epoxides Leads to Secondary Organic Aerosol Formation Isoprene is the single largest source of secondary organic aerosol (SOA) in Earth s atmosphere; however, in the southeastern U.S., where isoprene combines with anthropogenic emissions, existing models underestimate

4 observations. We combine organic synthesis and mass spectrometry to parameterize how anthropogenic pollutants enhance isoprene SOA in both laboratory and field studies. UTA Surratt (Co-PI) 5/28/14-6/30/15 University of Texas at Austin Update and Evaluation of Model Algorithms Needed to Predict Particulate Matter from Isoprene We will conduct a series of experiments at UNC to quantitatively measure the reactive uptake of the two predominant isoprene-derived epoxides to particles of different inorganic compositions. By providing these fundamental measurements, we will be able to more directly evaluate the aerosol-phase processes added to the model. This work will produce a fully updated gas- and aerosol-phase box model (Morpho) and a model evaluation of isoprene SOA formation against existing UNC outdoor smog chamber experiments. This project will also deliver performance data needed to bound uncertainties in key parameters used by CAMx to predict isoprene derived SOA. Role: Co-PI CHE Surratt (PI) 11/15/14-10/31/17 National Science Foundation (NSF) Collaborative Research: Quantifying Secondary Organic Aerosol Formation from the Reactive Uptake of Isoprene-derived Epoxides to Submicron Aerosol Particles This collaborative project will measure the reactive uptake kinetics of the two predominant isoprene-derived epoxides to submicron particles of different inorganic and organic compositions over a range of timescales. We will also quantify tracer compounds for epoxide multiphase chemistry and assess the volatility distribution and light-absorbing properties of the initial reaction products and those resulting from dark and photochemical aging of the SOA over hours Completed Research Support EP-P42280/C18445 Surratt (PI) 01/01/12 09/30/12 Chemical Characterization of SOA Collected from the SPHERES Program We propose to chemically characterize SOA produced from the the Secondary Particulate Health Effects Research (SPHERES) program. SPHERES was established to define the composition and resulting relative health hazard of SOA synthesized under varying reaction conditions and SOA precursors. EP-P37881/C16990 Surratt (PI) 10/01/10 06/30/11 Field Deployment of a Scanning Mobility Particle Sizer (SMPS) System in the SEARCH Network We propose to purchase and deploy a TSI, Inc., Scanning Mobility Particle Sizer (SMPS) system over a 5-year period at selected sites located within the SEARCH network for purposes of unattended long-term real-time monitoring of fine PM; more specifically, this instrument will provide real-time measurements of aerosol number concentrations (and thus aerosol mass concentrations) of fine PM. EP-P37901/C17000 Surratt (PI) 01/01/11 03/31/12 PM 2.5 Conditional Sampling In the proposed work, two high-volume PM2.5 samplers will be operated at the Yorkville, GA site, a rural site located within the SEARCH network that is downwind of a major coal-burning power plant, under a conditional sampling protocol that is based on certain environmental conditions (i.e., mixing ratios of SO2 and NH3) Surratt (PI) 02/06/13 12/31/13 University of Texas Austin

5 Generation of Exposed Lung Cells Tissues to Various Environmental Conditions In this study, A549 lung cells will be exposed to ozone, a complex gas mixture, and a complex gas mixture with real diesel exhaust, and the RNA extracted from these cells immediately after exposure will be characterized with respect to oxidative damage. Specifically, 8-oxoguanine (8-OG) levels will be measured by ELISA and mass spectrometry as a benchmark for total oxidative damage to cellular RNAs. It is hypothesized that levels of 8-OG will rise with exposure to increasingly complex urban air mixtures.