AIMALYTICAL CHEMISTRY
|
|
|
- Laurence Armstrong
- 5 years ago
- Views:
Transcription
1 Fundamentals of AIMALYTICAL CHEMISTRY Seventh Edition Douglas A. Skoog Stanford University Donald M. West San Jose State University F. James Holler University ;of Kentucky W r SAUNDERS COLLEGE PUBLISHING Harcourt Brace College Publishers Fort Worth Philadelphia San Diego New York Orlando Austin San Antonio Toronto Montreal London Sydney Tokyo
2 Contents i Introduction 1 1A Role of Analytical Chemistry in the Sciences 7 1B Classification of Quantitative Methods of Analysis 2 1C Steps in a Typical Quantitative Analysis 3 Errors in Chemical Analyses 11 2A Definition of Terms 12 2B Systematic Errors 16 2C Questions and Problems 20 4 Random Errors in Analyses 21 3A The Nature of Random Errors 21 3B The Statistical Treatment of Random Error 25 3C The Standard Deviation of Computed Results 33 3D Methods for Reporting Computed Data 39 3E Questions and Problems 44 Application of Statistics to Data Treatment and Evaluation 4A Confidence Limits 47 4B Statistical Aids to Hypothesis Testing 51 4C Detection of Gross Errors 57 4D Estimation of Detection Limits 59 4E The Least-Squares Method for Deriving Calibration Plots 4F Quality Assurance and Control Charts 65 4G Questions and Problems 68 Gravimetrie Methods of Analysis 71 5A Gravimetrie Calculations 73 5B Properties of Precipitates and Precipitating Agents 82 5C Drying and Ignition of Precipitates 92 5D Application of Gravimetrie Methods 93 5E Questions and Problems 97
3 xii Contents Titrimetric Methods of Analysis 700 6A Some General Aspects of Volumetrie Titrimetry 100 6B Standard Solutions 702 6C Volumetrie Caiculations 103 6D Gravimetrie Titrimetry E Questions and Problems Aqueous-Solution Chemistry 722 7A The Chemical Composition ofaqueous Solutions 722 7B Chemical Equilibrium 126 7C Questions and Problems 746 Effect of Electrolytes on lonic Equilibria 148 8A Thermodynamic Versus Concentration-Based Equilibrium Consta nts 748 8B Activity Coefficients 757 8C Questions and Problems 758 Application of Equilibrium Caiculations to Complex Systems 159 9A A Systematic Method for Solving Multiple-Equilibrium Problems 760 9B The Calculation of Solubility by the Systematic Method 764 9C Separation of Ions by Control of the Concentration of the Precipitating Agent 783 9D Questions and Problems Theory of Neutralization Titrations A Solutions and Indicators for Acid/Base Titrations B Titration Curves C Titration Curves for Strong Acids and Strong Bases D Buffer Solutions E Titration Curves for Weak Acids F Titration Curves for Weak Bases G The Composition of Buffer Solutions as a Function of ph H Common Types of Acid/Base Indicators Questions and Problems 227.J!.J1L Titration Curves for Complex Acid/Base Systems A Mixtures of Strong and Weak Acids or Strong and Weak Bases 224 IIB Polyfunctional Acids C Polyfunctional Bases D Buffer Solutions Involving Polyprotic Acids 229
4 Contents xiii 11E Caiculation of the ph of Solutions of Amphiprotic Salts F Titration Curves for Polyfunctional Acids G Titration Curves for Polyfunctional Bases H Titration Curves for Amphiprotic Species The Composition of Solutions of a Polyprotic Acid as a Function of ph J Questions and Problems Z 1 '"J Applications of Neutralization Titrations A Reagents for Neutralization Titrations B Typical Applications of Neutralization Titrations C Questions and Problems 262 Precipitation Titrimetry A Titration Curves B End Points for Argentometric Titrations C Applications of Standard Silver Nitrate Solutions D Questions and Problems 275 Complex-Formation Titrations A Complex-Formation Reactions B Titrations with Aminocarboxylic Acids C Titrations with Inorganic Complexing Agents D Questions and Problems 507 -&. mb*f An Introduction to Electrochemistry A Oxidation/Reduction Reactions B Electrochemical Cells C Electrode Potentials D Questions and Problems 327 Applications of Standard Electrode Potentials A The Thermodynamic Potential of Electrochemical Cells B Calculations of Redox Equilibrium Constants C Redox Titration Curves D Oxidation/Reduction Indicators E Potentiometrie End Points F Questions and Problems 358 Applications of Oxidation/Reduction Titrations A Auxiliary Oxidizing and Reducing Reagents B Application of Standard Reductants 362
5 xiv Contents 17C Applications of Standard Oxidants D Some Specialized Oxidants E Questions and Problems Theory of Potentiometry A General Principles B Reference Electrodes C Liquid-Junction Potentials D Indicator Electrodes E Questions and Problems 470 Applications of Potentiometry A Instruments for Measuring Cell Potentials B Direct Potentiometrie Measurements C Potentiometrie Titrations D The Determination of Equilibrium Constants from Electrode Potential Measurements E Questions and Problems 429 Electrogravimetric and Coulometric Methods A The Effect of Current on the Potential of Electrochemical Cells B The Potential Selectivity of Electrolytic Methods C Electrogravimetric Methods ofanalysis D Coulometric Methods of Analysis E Questions and Problems 457 Voltammetry A Excitation Signals in Voltammetry B Linear-Scan Voltammetry C Pulse Polarographic and Voltammetric Methods D Stripping Methods E Voltammetry with Ultramicroelectrodes F Questions and Problems 495 An Introduction to Spectrochemical Methods A General Properties of Electromagnetic Radiation B The Electromagnetic Spectrum C Absorption of Radiation D Emission of Electromagnetic Radiation E Questions and Problems 524
6 Contents xv Instruments for Optical Spectrometry A Instrument Components B Optical Instrument Designs C Questions and Problems 555 Molecular Absorption Spectroscopy A Ultraviolet and Visible Molecular Absorption Spectroscopy B Automated Photometrie and Spectrophotometric Methods C Infrared Absorption Spectroscopy D Questions and Problems 598 Molecular Fluorescence Spectroscopy A Theory of Molecular Fluorescence B Effect of Concentration on Fluorescence Intensity C Fluorescence Instruments D Applications of Fluorescence Methods E Questions and Problems 609 Atomic Spectroscopy Based on Ultraviolet and Visible Radiation A Sources of Atomic Spectra B Atomic Spectroscopy Based upon Flame Atomization C Atomic Spectroscopy with Electrothermal Atomizers D Atomic Emission Methods Based on Plasma Sources E Questions and Problems 635 Kinetic Methods of Analysis 'A Rates of Chemical Reactions: Rate Laws B The Determination of Reaction Rates C Applications of Kinetic Methods D Questions and Problems 658 An Introduction to Chromatographie Methods A A General Description of Chromatography B Migration Rates of Solutes C Band Broadening and Column Efficiency D Column Resolution E Applications of Chromatography F Questions and Problems 684 Gas-Liquid Chromatography A Instruments for Gas-Liquid Chromatography B Gas-Chromatographie Columns and the Stationary Phase 693
7 xvi Contents 29C Applications of Gas-Liquid Chromatography D Gas-Solid Chromatography E Questions and Problems High-Performance Liquid Chromatography A Instruments B High-Performance Partition Chromatography C High-Performance Adsorption Chromatography D High-Performance Ion-Exchange Chromatography E High-Performance Size-Exclusion Chromatography F Comparison of High-Performance Liquid Chromatography with Gas- Liquid Chromatography G Supercritical-Fluid Chromatography H Planar Chromatography Questions and Problems 724 The Analysis of Real Samples 725 %&*^r.jl 32 31A Choice of Method for the Analysis of Real Samples B The Accuracy Obtainable in the Analysis of Complex Materials 732 Preparing Samples for Analysis A Sampling B Moisture in Samples C The Determination of Water in Samples D Questions and Problems 748 Decomposing and Dissolving the Sample 749 sw^ m*j 33A Sources of Errors in Decompositipn and Dissolution B Decomposing Samples by Inorganic Acids in Open Vessels C Microwave Decompositions D Combustion Methods for Decomposing Organic Samples E Decomposition of Inorganic Materials by Fluxes F Questions and Problems 759 "**% A \/t =s&..j Eliminating Interferences A The Nature of the Separation Process B Separation by Precipitation C Separation by Extraction D Application of Extraction Procedures E Ion-Exchange Separations F The Separation of Inorganic Species by Distillation G Questions and Problems 776
8 Contents xvii 1^ 1 I 36 The Chemicals, Apparatus, and Unit Operations of Analytical Chemistry A The Selection and Handling of Reagents and Other Chemicals B The Cleaning and Marking of Laboratory Ware C The Evaporation of Liquids D The Measurement of Mass E The Equipment and Manipulations Associated with Weighing F Weight Titrations G The Equipment and Manipulations for Filtration and Ignition H The Measurement of Volume The Calibration of Volumetrie Ware J The Laboratory Notebook K Safety in the Laboratory 870 Selected Methods of Analysis A Gravimetrie Methods of Analysis B Neutralization Titrations C Precipitation Titrations D Complex-Formation Titrations with EDTA E Titrations with Potassium Permanganate F Titration with lodine G Titrations with Sodium Thiosulfate H Titrations with Potassium Bromate Potentiometrie Methods J Electrogravimetric Methods K Coulometric Titrations L Voltammetry M Methods Based on the Absorption of Radiation N Molecular Fluorescence Atomic Spectroscopy P Applications of Ion-Exchange Resins Q Gas-Liquid Chromatography 868 Glossary G-7 A P P E N D I X j Selected References to the Literature of Analytical Chemistry A- A P P E N D I X 2 Solubility Product Constants A-6 3 A P P E N D I X o Dissociation Constants for Acids A-8
9 xviii Contents A P P E N D I X A Stepwise Formation Constants A-10 A P P E N D I X c Some Standard and Formal Electrode Potentials A-12 A P P E N D I X /r Designations Carried by Ashless Filter Papers A-16 A P P E N D I X -i Designations and Porosities for Filtering Crucibles A-17 A P P E N D I X Q Use of Exponential Numbers and Logarithms A-18 A P P E N D I X Q Volumetrie Caiculations Using Normality and Equivalent Weight A-23 A P P E N D I X Q Compounds Recommended for the Preparation of Standard Solutions of Common Elements A-32 A P P E N D I X i Propagation of Measurement Uncertainties A-34 Answers to Selected Questions and Problems A-40 Index 1-1
BOROUGH OF MANHATTAN COMMUNITY COLLEGE City University of New York Department of Science
on the specific course section and instructor. Different sections of the same course may require different Web Page. Modifications of the grading system presented here will be communicated by the instructors
Electrochemistry in Nonaqueous Solutions
К. Izutsu Electrochemistry in Nonaqueous Solutions WILEY-VCH Contents Preface V Part I Fundamentals of Chemistry in Non-Aqueous Solutions: Electrochemical Aspects 1 Properties of Solvents and Solvent Classification
Principles and Applications of Electrochemistry
Principles and Applications of Electrochemistry Fourth edition D. R. CROW Professor of Electrochemistry and Dean of Research University of Wolverhampton BLACKIE ACADEMIC & PROFESSIONAL An Imprint of Chapman
Introduction to Pharmaceutical Chemical Analysis
Introduction to Pharmaceutical Chemical Analysis Hansen, Steen ISBN-13: 9780470661222 Table of Contents Preface xv 1 Introduction to Pharmaceutical Analysis 1 1.1 Applications and Definitions 1 1.2 The
ANALYTICAL TECHNIQUES
ANALYTICAL TECHNIQUES DEGREE IN PHARMACY University of Alcalá Academic Year 2017/2018 2 nd Year - Annual COURSE DESCRIPTION Name of the course: Analytical Techniques Code: 570011 Degree: Department and
Exploring Chemical Analysis
Exploring Chemical Analysis Daniel C. Harris Michelson Laboratory China Lake, California W. H. Freeman and Company New York What Am I Doing in This Course? XVIII Preface Chapter 1 1-1 1-2 1-3 1-4 1-5 2-2
Chemistry PhD Qualifying Exam Paper 1 Syllabus
Chemistry PhD Qualifying Exam Paper 1 Syllabus Preface This document comprises all topics relevant for Paper 1 of the Ph.D. Qualifying Exam in Chemistry at Eastern Mediterranean University, in accordance
Analytical Topics to Consider in preparation for the MFAT/GRE
Analytical Topics to Consider in preparation for the MFAT/GRE 1. Solutions and Measurement: (CHEM 222) Describe the steps in a chemical analysis Know the meaning and use of the following solution concentrations.
School of Chemistry UNIVERSITY OF KWAZULU-NATAL, WESTVILLE CAMPUS JUNE 2009 EXAMINATION CHEM340: INSTRUMENTAL ANALYSIS.
School of Chemistry UNIVERSITY OF KWAZULU-NATAL, WESTVILLE CAMPUS JUNE 2009 EXAMINATION CHEM340: INSTRUMENTAL ANALYSIS DURATION: 3 HOURS TOTAL MARKS: 100 Internal Examiners: Professor A Kindness Dr T Msagati
EXPERIMENTS IN PHYSICAL CHEMISTRY
EXPERIMENTS IN PHYSICAL CHEMISTRY SIXTH EDITION DAVID P. SHOEMAKER CARL W. GARLAND JOSEPH W. NIBLER The Late Emeritus Professor of Chemistry Professor of Chemistry Professor of Chemistry Oregon State University
CONTENTS PART 1 - MINERALOGICAL ANALYSIS. CHAPTER 1 Water Content and Loss on Ignition. CHAPTER 2 Particle Size Analysis
CONTENTS PART 1 - MINERALOGICAL ANALYSIS CHAPTER 1 Water Content and Loss on Ignition 1.1 Introduction...3 1.2 Water Content at 105 C (H 2 O )...6 1.2.1 Principle...6 1.2.2 Materials...6 1.2.3 Sample...6
PhET Interactive Chemistry Simulations Aligned to an Example General Chemistry Curriculum
PhET Interactive Chemistry Simulations Aligned to an Example General Chemistry Curriculum Alignment is based on the topics and subtopics addressed by each sim. Sims that directly address the topic area
INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY
INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY Edited by AKBAR MONTASER George Washington University Washington, D.C. 20052, USA WILEY-VCH New York Chichester Weinheim Brisbane Singapore Toronto CONTENTS
CHEM 540 ADVANCED ANALYTICAL CHEMISTRY
CHEM 540 ADVANCED ANALYTICAL CHEMISTRY CHEM 540 KFUPM CHEM 540, Advanced Analytical Chemistry CHEMISTRY DEPT. Credit hours: 3 Fall 2006/2007 ( Term 061) DR A.M.Y. JABER Room 261F, Tel 2611 Office hours
Spanish Fork High School Unit Topics and I Can Statements AP Chemistry
Spanish Fork High School 2014-15 Unit Topics and I Can Statements AP Chemistry Properties of Elements I can describe how mass spectroscopy works and use analysis of elements to calculate the atomic mass
Contents. 1 Matter: Its Properties and Measurement 1. 2 Atoms and the Atomic Theory Chemical Compounds Chemical Reactions 111
Ed: Pls provide art About the Authors Preface xvii xvi 1 Matter: Its Properties and Measurement 1 1-1 The Scientific Method 2 1-2 Properties of Matter 4 1-3 Classification of Matter 5 1-4 Measurement of
Q!JANTITATIVE CHEMICAL ANALYSIS
Q!JANTITATIVE CHEMICAL ANALYSIS This page intentionally left blank QUANTITATIVE CHEMICAL ANALYSIS Na Li Peking University, China john J. Hefferren Peking University, China Et University of Kansas, USA
Instrumental Chemical Analysis
L1 Page1 Instrumental Chemical Analysis Dr. Ahmad Najjar Philadelphia University Faculty of Pharmacy Department of Pharmaceutical Sciences 2 nd semester, 2016/2017 L1 Page2 Course Syllabus Course title:
Topics for the Lecture Quizzes:
Lecture Policy 5.310 Laboratory Chemistry has three components: 1) the safety lectures and safety quiz 2) the experiments carried out in the laboratory and associated quizzes/ reports 3) the classroom
BASICS OF ANALYTICAL CHEMISTRY AND CHEMICAL EQUILIBRIA
BASICS OF ANALYTICAL CHEMISTRY AND CHEMICAL EQUILIBRIA BASICS OF ANALYTICAL CHEMISTRY AND CHEMICAL EQUILIBRIA BRIAN M. TISSUE Virginia Tech Department of Chemistry Blacksburg, VA Cover Design: Wiley Cover
Spectrometric Titrations
Jürgen Polster Heinrich Lachmann Spectrometric Titrations Analysis of Chemical Equilibria VCH Contents Part I The Theoretical and Methodological Basis of Spectrometric Titration 1 Basic Principles and
8. Draw Lewis structures and determine molecular geometry based on VSEPR Theory
Chemistry Grade 12 Outcomes 1 Quantum Chemistry and Atomic Structure Unit I 1. Perform calculations on wavelength, frequency and energy. 2. Have an understanding of the electromagnetic spectrum. 3. Relate
AP CHEMISTRY COURSE SYLLABUS FIRST SEMESTER. Supplies: notebook, lab notebook (will be supplied), graph paper, calculator
AP CHEMISTRY COURSE SYLLABUS FIRST SEMESTER Instructor: Ken MacGillivray - kenneth.macgillivray@nhcs.net Textbook: Chemistry-Zumdahl, 9th edition, 2014. ISBN: 978-1-133-61109-7 Supplies: notebook, lab
ANALYTICAL TECHNIQUES
ANALYTICAL TECHNIQUES (Aprobada en CD el 18-06-2018) DEGREE IN PHARMACY University of Alcalá Academic Year 2018/2019 2 nd Year - Annual COURSE DESCRIPTION Name of the course: Analytical Techniques Code:
CHEM 1310: Review. List of major topics
CHEM 1310: Review List of major topics Chapter 1: Atomic Nature of Matter Atomic theory of matter Atomic masses Moles Elemental analysis Volume & density Chapter 2: Stoichiometry Balancing equations Limiting
Preface... (v) Acknowledgement... (vii) Introduction Chapter 1 Acids and Bases... 21
CONTENTS Preface... (v) Acknowledgement... (vii) Introduction... 1 Chapter 1 Acids and Bases... 21 Experiment 1.1 To Prepare 1M HCl and Standardize it and Perform Assay of Sodium Hydrogen Carbonate...
Chemistry 301 Test #1
Name: KEY Pledge: I have neither given nor received aid on this test Chemistry 301 Test #1 Point Total: 100 pts possible 8 pts 1. In 2-4 sentences, explain the fundamental basis of quantitative analysis
CHROMATOGRAPHY. The term "chromatography" is derived from the original use of this method for separating yellow and green plant pigments.
CHROMATOGRAPHY The term "chromatography" is derived from the original use of this method for separating yellow and green plant pigments. THEORY OF CHROMATOGRAPHY: Separation of two sample components in
Principles of Electrochemistry Second Edition
Principles of Electrochemistry Second Edition Jiri Koryta Institute of Physiology, Czechoslovak Academy of Sciences, Prague HKJin Dvorak Department of Physical Chemistry, Faculty of Science, Charles University,
Student Achievement. Chemistry 12
Student Achievement Chemistry 12 Key Elements: Reaction Kinetics Estimated Time: 14 16 hours By the end of this course, students will be able to explain the significance of reaction rates, demonstrate
Exploring Chemical Analysis
Exploring Chemical Analysis FIFTH EDITION Daniel C. Harris Michelson Laboratory China Lake, California IS W. H. Freeman and Company New York twitertfii Preface xi 3-5 Introducing Spreadsheets 68 Chapter
FUNDAMENTALS OF ELECTRO- ANALYTICAL CHEMISTRY
FUNDAMENTALS OF ELECTRO- ANALYTICAL CHEMISTRY Paul Monk Manchester Metropolitan University, Manchester, UK JOHN WILEY & SONS LTD Chichester New York Weinheim Brisbane Toronto Singapore Contents Series
Thinkwell s Homeschool AP Chemistry Course Lesson Plan: 34 weeks
Thinkwell s Homeschool AP Chemistry Course Lesson Plan: 34 weeks Welcome to Thinkwell s Homeschool AP Chemistry! We re thrilled that you ve decided to make us part of your homeschool curriculum. This lesson
Fundamentals of Macroscopic Chemical Analysis (CHEM 255) Spring 2013 Course Syllabus, Policies, and Procedures
Fundamentals of Macroscopic Chemical Analysis (CHEM 255) Spring 2013 Course Syllabus, Policies, and Procedures Prerequisites: Completed CHEM 125 Instructor: Fazal, M. Abul Office: Ardolf Science Center,
Glossary of Common Laboratory Terms
Accuracy A measure of how close a measured value is to the true value. Assessed by means of percent recovery of spikes and standards. Aerobic Atmospheric or dissolved oxygen is available. Aliquot A measured
VALLIAMMAI ENGINEERING COLLEGE SRM Nagar, Kattankulathur
VALLIAMMAI ENGINEERING COLLEGE SRM Nagar, Kattankulathur 603 203 DEPARTMENT OF ELECTRONICS AND INSTRUMENTATION ENGINEERING QUESTION BANK V SEMESTER EI6501 Analytical Instruments Regulation 2013 Academic
Course Code: CHEM4441 Course Title: Analytical Chemistry II
College of Science Department of Chemistry Course Code: CHEM4441 Course Title: Analytical Chemistry II General Inmation Number of Credits: 3. Instructional Format: hours Lectures + 3 hours lab Contact
MULTIVARIABLE CALCULUS, LINEAR ALGEBRA, AND DIFFERENTIAL EQUATIONS
T H I R D E D I T I O N MULTIVARIABLE CALCULUS, LINEAR ALGEBRA, AND DIFFERENTIAL EQUATIONS STANLEY I. GROSSMAN University of Montana and University College London SAUNDERS COLLEGE PUBLISHING HARCOURT BRACE
UNIT 1: CHEMISTRY FOUNDATIONS
Advanced Placement AP Chemistry builds students' understanding of the nature and reactivity of matter. After studying chemical reactions and electrochemistry, students move on to understand how the chemical
Experiment UPHPLC: Separation and Quantification of Components in Diet Soft Drinks
Experiment UPHPLC: Separation and Quantification of Components in Diet Soft Drinks bjective: The purpose of this experiment is to quantify the caffeine content of a diet soda sample using Ultra-High Performance
x Contents 3 The Stationary Phase in Thin-Layer Chromatography Activating and Deactivating Stationary Phases Snyder s Adsorption M
Contents 1 History of Planar Chromatography... 1 1.1 History of Paper Chromatography (PC)... 1 1.2 History of Thin-Layer Chromatography... 7 1.3 The History of Quantitative Planar Chromatography... 8 References.....
GENERAL, ORGANIC AND BIOLOGICAL CHEMISTRY. JOHN R. AMEND Montana State University. BRADFORD P. MUNDY Colby College
GENERAL, ORGANIC AND BIOLOGICAL CHEMISTRY JOHN R. AMEND Montana State University BRADFORD P. MUNDY Colby College MELVIN T. ARMOLD Adams State College # Saunders Golden Sunburst Series SAUNDERS COLLEGE
AP Chemistry
AP Chemistry 2013 2014 Patrick Hemmingsen Telephone 816.892.1456 patrick.hemmingsen@raypec.org Course Description: The AP Chemistry course is designed to be the equivalent of the general chemistry course
COURSE DELIVERY PLAN - THEORY Page 1 of 6
COURSE DELIVERY PLAN - THEORY Page 1 of 6 Department of Applied Chemistry B.Tech: Chemical Engineering Regulation: 2013 Sub. Code / Sub. Name : CH6501 / Instrumental Methods of Analysis Unit: I LP: Sub
Chemical Laboratory Techniques
Unit 23: Chemical Laboratory Techniques Unit code: H/601/0355 QCF level: 4 Credit value: 15 Aim This unit gives learners the opportunity to practise and become proficient in a range of practical skills
Elements, Compounds Mixtures Physical and Chemical Changes
Elements, Compounds Mixtures Physical and Chemical Changes Fundamentals of Chemistry 1 Classification of Matter Matter is any substance having distinct physical characteristics and chemical properties.
UNIT 3 CHEMISTRY. Fundamental Principles in Chemistry
UNIT 3 CHEMISTRY NOTE: This list has been compiled based on the topics covered in the 2016 Master Class program. Once all of the 2017 Chemistry program materials have been finalised, this summary will
(If submission is not a book, cite appropriate location(s))
Arkansas Science Curriculum Framework, Strand 1-Physical Systems (Grades 9-12) CONTENT STANDARD 1 Students will demonstrate an understanding of physical systems as a process of inquiry. PS.1.1. PS.1.2.
B L U E V A L L E Y D I S T R I C T C U R R I C U L U M Science AP Chemistry
B L U E V A L L E Y D I S T R I C T C U R R I C U L U M Science AP Chemistry ORGANIZING THEME/TOPIC UNIT 1: ATOMIC STRUCTURE Atomic Theory Electron configuration Periodic Trends Big Idea 1: The chemical
General Information. 1. Course Description. 2. Course Objectives
College of Science Department of Chemistry Course Code: CHEM 334 Course Title: Analytical Chemistry I General Information Number of Credits: 3 Instructional Format: hours Lectures + 3 hours Lab Contact
Pearson Education Limited Edinburgh Gate Harlow Essex CM20 2JE England and Associated Companies throughout the world
Pearson Education Limited Edinburgh Gate Harlow Essex CM20 2JE England and Associated Companies throughout the world Visit us on the World Wide Web at: www.pearsoned.co.uk Pearson Education Limited 2014
Proposed Content for the Project (Scope and Sequence)
Proposed Content for the Project (Scope and Sequence) The scope and sequence of the proposed project is not unusual. It follows the path of many available general chemistry texts. What we feel is innovative
1) How are experiments designed and analyzed. 2) How are chemical formulas used? 1) How do you write and balance chemical equations
GBCS Curriculum Guide GRADE: 11-12 Topic Pacing Unit Standards SUBJECT: AP Chemistry General Chemistry Review 1 Week Unit 1 CR1 AP At minimum, six of the required 16 labs are conducted in a guided-inquiry
Miami Dade College CHM Second Semester General Chemistry
Miami Dade College CHM 1046 - Second Semester General Chemistry Course Description: CHM 1046 is the second semester of a two-semester general chemistry course for science, premedical science and engineering
Chemistry 265 December Exam 2011 Smith-Palmer
1 Chemistry 265 December Exam 2011 Smith-Palmer NAME: [1] 1. Define an anode [1] Define a cathode [2] What is the E o for the following reaction: Ag + + Cu Ag (s) + Cu 2+ Ag + + e - Ag (s) E o = 0.799
EXPERIMENT 7. Determination of Sodium by Flame Atomic-Emission Spectroscopy
EXPERIMENT 7 Determination of Sodium by Flame Atomic-Emission Spectroscopy USE ONLY DEIONIZED WATER (NOT DISTILLED WATER!) THROUGHOUT THE ENTIRE EXPERIMENT Distilled water actually has too much sodium
CHEMISTRY Scientific Inquiry
Chemistry Overview The standards for chemistry establish scientific inquiry skills and core content for all chemistry courses in South Carolina schools. In chemistry, students acquire a fundamental knowledge
Classifying Chemical Reactions
1 Classifying Chemical Reactions Analyzing and Predicting Products Introduction The power of chemical reactions to transform our lives is visible all around us-in our cars, even in our bodies. Chemists
AP Chemistry. Syllabus and Essential Outcomes. Overview: Resources: Student Generated Resources:
AP Chemistry Syllabus and Essential Outcomes Overview: The AP Chemistry course is designed to prepare students for the AP Chemistry Exam. It is the equivalent of the general chemistry course usually taken
AP CHEMISTRY Pacing Guide
AP CHEMISTRY Pacing Guide Course Description: AP CHEMISTRY (one term guide) EOC AP/IB VOCATS Teacher-made final exam Day Date SCS Objectives Essential Questions Content Tasks/Strategies 1 2 3 Objective
Big Idea 1: Structure of Matter Learning Objective Check List
Big Idea 1: Structure of Matter Learning Objective Check List Structure of Matter Mole Concept: Empirical Formula, Percent Composition, Stoichiometry Learning objective 1.1 The student can justify the
Acid and Base. Properties of Umass Boston
Acid and Base Dissociation of diprotic acid For the solution of H 2 L H 2 L HL H a = 4.69 x 0-3 HL L - H a2 =.79 x 0-0 Assumption: since a >> a2 so the dissociation of HL is insignificant comparing with
2101 Atomic Spectroscopy
2101 Atomic Spectroscopy Atomic identification Atomic spectroscopy refers to the absorption and emission of ultraviolet to visible light by atoms and monoatomic ions. It is best used to analyze metals.
Naming salts. Metal Acid Salt. Sodium hydroxide reacts with Hydrochloric acid to make Sodium chloride
Naming salts A salt is any compound formed by the neutralisation of an acid by a base. The name of a salt has two parts. The first part comes from the metal, metal oxide or metal carbonate. The second
CHAPTER - 2 EXPERIMENTAL TECHNIQUE. Potassium permanganate has been used for. oxidation of many systems. Oxidations by permanganate
42 CHAPTER - 2 EXPERIMENTAL TECHNIQUE Potassium permanganate has been used for oxidation of many systems. Oxidations by permanganate generally takes place very fast because it is a strong oxidising agent.
TEACHER CERTIFICATION STUDY GUIDE. Table of Contents ATOMIC STRUCTURE AND THE PROPERTIES OF MATTER
Table of Contents SUBAREA I. ATOMIC STRUCTURE AND THE PROPERTIES OF MATTER COMPETENCY 1.0 UNDERSTAND THE VARIOUS MODELS OF ATOMIC STRUCTURE, THE PRINCIPLES OF QUANTUM THEORY, AND THE PROPERTIES AND INTERACTIONS
April 23, 2015 Lab 1 - Gravimetric Analysis of a Metal Carbonate
Lab 1 - Gravimetric Analysis of a Metal Carbonate Purpose - to determine the identity of the cation in X 2 CO 3 by gravimetric analysis Lab Highlights Include: SLOW gravity filtration Primary Experimental
Page 2. Q1.A student investigated food dyes using paper chromatography. This is the method used.
Q1.A student investigated food dyes using paper chromatography. This is the method used. 1. Put a spot of food colouring X on the start line. 2. Put spots of four separate dyes, A, B, C and D, on the start
Luminescence transitions. Fluorescence spectroscopy
Luminescence transitions Fluorescence spectroscopy Advantages: High sensitivity (single molecule detection!) Measuring increment in signal against a dark (zero) background Emission is proportional to excitation
Chemistry 12 - Learning Outcomes
Chemistry 12 - Learning Outcomes A: Chapt 1. Reaction Kinetics - (Introduction) A1. give examples of reactions proceeding at different rates A2. describe rate in terms of some quantity (produced or consumed)
atomic absorption spectroscopy general can be portable and used in-situ preserves sample simpler and less expensive
Chapter 9: End-of-Chapter Solutions 1. The following comparison provides general trends, but both atomic absorption spectroscopy (AAS) and atomic absorption spectroscopy (AES) will have analyte-specific
Chapter 4 Reactions in Aqueous Solutions. Copyright McGraw-Hill
Chapter 4 Reactions in Aqueous Solutions Copyright McGraw-Hill 2009 1 4.1 General Properties of Aqueous Solutions Solution - a homogeneous mixture Solute: the component that is dissolved Solvent: the component
Physical Changes and Chemical Reactions
Physical Changes and Chemical Reactions Gezahegn Chaka, Ph.D., and Sudha Madhugiri, Ph.D., Collin College Department of Chemistry Objectives Introduction To observe physical and chemical changes. To identify
Advanced Chemistry in Creation, 2 nd Edition Table of Contents
Advanced Chemistry in Creation, 2 nd Edition Table of Contents MODULE #1: Units, Chemical Equations, and Stoichiometry Revisited... 1 Introduction... 1 Units Revisited... 1 A New Look at Chemical Equations...
Redox Titration. Properties of Umass Boston
Redox Titration Redox Titration Ce 4+ + Fe 2+ Ce 3+ + Fe 3+ Redox titration is based on the redox reaction (oxidation-reduction) between analyte and titrant. Position of the end point Determine the end
Contents. Publisher s Foreword. Glossary of Symbols and Abbreviations
Publisher s Foreword Glossary of Symbols and Abbreviations v xiii 1 Equilibrium Electrochemistry and the Nernst Equation 1 1.1 Cell Thermodynamics....................... 1 1.2 The Nernst Equation........................
Atmospheric Analysis Gases. Sampling and analysis of gaseous compounds
Atmospheric Analysis Gases Sampling and analysis of gaseous compounds Introduction - External environment (ambient air) ; global warming, acid rain, introduction of pollutants, etc - Internal environment
Voltammetry. Voltammetry and Polarograph. Chapter 23. Polarographic curves -- Voltammograms
Chapter 23 Voltammetry Voltammetry and Polarograph Electrochemistry techniques based on current (i) measurement as function of voltage (E appl ) Voltammetry Usually when the working electrode is solid,
CHAPTER THREE: MATTER, PROPERTY, AND CHANGE
CHAPTER THREE: MATTER, PROPERTY, AND CHANGE CLASSIFICATION OF MATTER! A sample of matter can be a gas, a liquid, or a solid. These three forms of matter are called the states of matter. STATES OF MATTER!
31. Applications of the chromatographic methods in drug analysis
31. Applications of the chromatographic methods in drug analysis 31. 1. Depending on the processes that underlie the chromatographic separation, the following methods exist: A. adsorption chromatography
All Questions are to be attempted 1- Redox Titration (35 Marks)
SOHAG UNIVERSITY FACULTY OF PHARMACY PHARM. ANAL. CHEM. DEPT. Pharm. Anal. Chem-2 Second Year Students May, 31, 2016 TIME ALLOWED: TWO HOURS Total marks: 90 All Questions are to be attempted 1- Redox Titration
CHEMISTRY CONTENT SKILLS CHART
I. NATURE OF CHEMISTRY A. Safety B. Fundamental quantitative relationships 1. Metric system a. Prefixes b. Difference between base units and derived units 2. Significant figures 3. Scientific notation
Questions on Instrumental Methods of Analysis
Questions on Instrumental Methods of Analysis 1. Which one of the following techniques can be used for the detection in a liquid chromatograph? a. Ultraviolet absorbance or refractive index measurement.
CHAPTER GENERAL CONCEPTS READING from text HOMEWORK from text OTHER ASSIGNMENTS LABORATORIES. R1: Sections 1,2 Set 1: CR 15; PP 1
MONTPELIER HIGH SCHOOL teacher: Toni Ceckler / Room 220, phone: 225-8182, email: toni@mpsvt.org CHEMISTRY 2018-2019 GENERAL SYLLABUS Text: Chemistry: Connections to Our Changing World (Prentice Hall, 2000)
Required Materials For complete material(s) information, refer to
Butler Community College Science, Technology, Engineering, and Math Division Robert Carlson Revised Fall 2017 Implemented Spring 2018 COURSE OUTLINE College Chemistry 2 Course Description CH 115. College
Identify the bonding types molecular, covalent network, ionic, and metallic - in various solids (11.8)
Intermolecular Forces, Liquids, and Solids (Chapter 11) Very brief review of Lewis structures and molecular geometry Draw Lewis structures for and determine polarity of molecules through sp 3 8.45 8.64,
Instrumental methods of analysis
Instrumental methods of analysis By Dr Hisham Ezzat Abdellatef Prof. of Analytical Chemistry Background: Analytical Chemistry: The Science of Chemical Measurements. Analyte: The compound or chemical species
Chemistry 6 12 Section 03
Chemistry 6 12 Section 03 1 Knowledge of the nature of matter 1. Differentiate between pure substances, homogeneous mixtures, and heterogeneous mixtures. 2. Determine the effects of changes in temperature,
5. SEPARATION OF MIXTURES, PURIFICATION OF SOLIDS Objectives
Name: Date:.. 5. SEPARATION OF MIXTURES, PURIFICATION OF SOLIDS Objectives Introduction to basic chemical laboratory operations: grinding, dissolving, decanting, centrifuging, filtration, crystallization.
General Education Competencies Satisfied:
Course Name: General Chemistry I Course Number: CHE* E121 Credits: 4 Catalog description: A study of the fundamental principles, theories and laws of chemistry. Topics include atomic theory and the structure
MATTER. Chemistry is the study of matter and the changes that matter undergoes. Matter is anything that has mass and takes up space.
MATTER Chemistry is the study of matter and the changes that matter undergoes. Matter is anything that has mass and takes up space. Properties of Matter Physical Properties Can be observed without changing
Course Details. Analytical Techniques Based on Optical Spectroscopy. Course Details. Textbook. SCCH 211: Analytical Chemistry I
SCCH 211: Analytical Chemistry I Analytical Techniques Based on Optical Spectroscopy Course Details September 22 October 10 September 22 November 7 November 17 December 1 Topic Period Introduction to Spectrometric
Ch. 9 Atomic Absorption & Atomic Fluorescence Spectrometry
Ch. 9 Atomic Absorption & Atomic Fluorescence Spectrometry 9.1 9A. Atomization Most fundamental for both techniques. Typical types 1. flame - burner type 2. Electrothermal graphite furnace 3. Specialized
ANALYTICAL CHEMISTRY. Introduction to Titration
ANALYTICAL CHEMISTRY by Wan Norfazilah Wan Ismail Faculty of Industrial Sciences & Technology norfazilah@ump.edu.my Chapter Description Expected Outcomes Describe the principles of equilibria involved
Techniques for Volumetric Analysis
Techniques for Volumetric Analysis Volumetric analysis involves measuring the volumes of two solutions that react together. The basic principles are as follows. The solution to be analysed contains an
Mechanisms of retention in HPLC
Mechanisms of retention in HPLC María Celia García-Álvarez-Coque Department of Analytical Chemistry University of Valencia Valencia, Spain https://sites.google.com/site/fuschrom/ 1 Part 3 Mechanisms of
About the Authors Preface Student's Guide to Using this Text Matter-Its Properties and Measurement The Scientific Method Properties of Matter
About the Authors Preface Student's Guide to Using this Text Matter-Its Properties and Measurement The Scientific Method Properties of Matter Classification of Matter Measurement of Matter: SI (Metric)
JEFFERSON COLLEGE COURSE SYLLABUS CHM112 GENERAL CHEMISTRY II. 5 Credit Hours. Prepared by: Richard A. Pierce. Revised Date: August 2009 by Sean Birke
JEFFERSON COLLEGE COURSE SYLLABUS CHM112 GENERAL CHEMISTRY II 5 Credit Hours Prepared by: Richard A. Pierce Revised Date: August 2009 by Sean Birke Arts & Science Education Dr. Mindy Selsor, Dean CHM112
Angelina College Science and Mathematics Chemistry 1412: General Chemistry II (Lecture and Laboratory) General Syllabus
Angelina College Science and Mathematics Chemistry 1412: General Chemistry II (Lecture and Laboratory) General Syllabus I. Basic Course Information A. Course Description 1. Four hours credit. A continuation
An Introduction to Chemical Kinetics
An Introduction to Chemical Kinetics Michel Soustelle WWILEY Table of Contents Preface xvii PART 1. BASIC CONCEPTS OF CHEMICAL KINETICS 1 Chapter 1. Chemical Reaction and Kinetic Quantities 3 1.1. The