TASK 1 Writing formulas of ionic compounds. TASK 2 Writing formulas 1. TASK 3 Writing formulas 2. TASK 4 Writing balanced equations 1

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1 TASK 1 Writing formulas of ionic compounds 1 AgBr 2 Na 2CO 3 3 K 2O 4 Fe 2O 3 5 CrCl 3 6 Ca(OH) 2 7 Al(NO 3) 3 8 Na 2SO 4 9 PbO 10 Na 3PO 4 11 Zn(HCO 3) 2 12 (NH 4) 2SO 4 13 Ga(OH) 3 14 SrSe 15 RaSO 4 16 Na 3N TASK 2 Writing formulas 1 1 PbO 2 2 Cu 3 Na 4 NH 4Cl 5 NH 3 6 S 8 7 H 2SO 4 8 Ne 9 SiO 2 10 Si 11 Ba(OH) 2 12 SnCl 4 13 AgNO 3 14 I 2 15 Ni 16 H 2S 17 TiO 2 18 Pb 19 SrSO 4 20 Li TASK 3 Writing formulas 2 1 Ag 2CO 3 2 Au 3 PtF 2 4 HNO 3 5 NH 3 6 SiH 4 7 P 4 8 C 9 V 2O 5 10 Co(OH) 2 11 Ca(OH) 2 12 NH 4Cl 13 HCl 14 F 2 15 Si 16 Ca 3(PO 4) 2 17 Rb 18 GeO 2 19 MgAt 2 20 Ar TASK 4 Writing balanced equations 1 1 a Mg + 2 HNO 3 Mg(NO 3) 2 + H 2 b CuCl NaOH Cu(OH) NaCl c 2 SO 2 + O 2 2 SO 3 d C 4H ½ O 2 4 CO H 2O or 2 C 4H O 2 8 CO H 2O 2 a 4 Na + O 2 2 Na 2O b 2 Al + 3 Cl 2 2 AlCl 3 c Ca + 2 HCl CaCl 2 + H 2 d 2 NH 3 + H 2SO 4 (NH 4) 2SO Jul-12 Chemsheets AS 008 1

2 TASK 5 Writing balanced equations Al + 3 O 2 2 Al 2O 3 2 C 6H ½ O 2 6 CO H 2O or 2 C 6H O 2 12 CO H 2O 3 CH 3CH 2SH + 4½ O 2 2 CO 2 + SO H 2O or 2 CH 3CH 2SH + 9 O 2 4 CO SO H 2O 4 2 Li + 2 H 2O 2 LiOH + H 2 5 CaCO HNO 3 Ca(NO 3) 2 + H 2O + CO 2 6 Li 2CO 3 Li 2O + CO 2 7 NH 3 + HNO 3 NH 4NO 3 8 K 2O + H 2SO 4 K 2SO 4 + H 2O 9 Ca(OH) HCl CaCl H 2O 10 3 Zn + 2 H 3PO 4 Zn 3(PO 4) H NaHCO 3 + H 2SO 4 Na 2SO 4 + H 2O + CO KOH + H 2SO 4 K 2SO H 2O TASK 6 Ionic equations 1 HCl, LiOH, 1:1; H 2SO 4, NaHCO 3, 1:2; HNO 3, NH 3, 1:1; H 2SO 4, K 2CO 3, 1:1, HNO 3, Sr(OH) 2, 2:1 2 a H + + OH - H 2O b Ag + + I - AgI c 2 H + + CO 3 2- H 2O + CO 2 d Ca OH - Ca(OH) 2 e NH 3 + H + NH 4 + f H + + HCO 3 - H 2O + CO 2 g Ca 2+ + SO 4 2- CaSO 4 h Pb Cl - PbCl 2 i H + + OH - H 2O TASK 7 Significant figures & standard form 1 a b c d 6.00 e f a b c 13.7 d 30.0 e f a b c d 534 e f a 1.64 x 10-4 b 5.24 x 10-2 c 1.5 x 10-8 d 3.45 x 10 4 e 6.2 x 10-1 f 8.7 x a b 6.14 x 10-5 c 4.00 x 10 8 d 2400 e f 8.00 x 10-7 TASK 8 Moles 1 a 2.96 b 50.3 c d e a 355 g b 20.4 g c 1.08 g d g e 85.8 g 3 a 0.25 b 0.25 c a b 0.10 c a x g b x g c x g TASK 9 What equations mean 1 12 mol Na + 3 mol O 2 6 mol Na 2O; 0.1 mol Na mol O mol Na 2O 2 5 mol Al mol Cl 2 5 mol AlCl 3; 0.1 mol Al mol Cl mol AlCl mol C 4H mol O 2 2 mol CO mol H 2O; 20 mol C 4H mol O 2 80 mol CO mol H 2O mol NH mol O mol N mol H 2O; 10 mol NH mol O 2 5 mol N mol H 2O 07-Jul-12 Chemsheets AS 008 2

3 TASK 10 Reacting mass calculations g g g g g g g g g g g g g g 07-Jul-12 Chemsheets AS 008 3

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5 TASK 11 Reacting mass calculations 2 1 a 2 mol NH 3 b 6 mol NH 3 c 1.33 mol NH 3 d 1.0 mol NH 3 e 4 mol NH 3 2 a 3 mol SO 3 b 3 mol SO 3 c 0.04 mol SO 3 d 0.8 mol SO 3 e 2 mol SO g g g g g g g 07-Jul-12 Chemsheets AS 008 5

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7 CHALLENGE 1 1 NaHCO 3 = 3.51 g, Na 2CO g 2 CaCO 3 = 40.3%, MgCO 3 = 59.7% 3 C 4H % 07-Jul-12 Chemsheets AS 008 7

8 TASK 12 Percentage yield 1 a 120 g b 74.9% c reversible, product lost on isolation, other reactions take place 2 a g b 92.3% 3 a 510 g b 30.0% 4 a 25.2 g b 79.4% 5 a 529 g b 94.4% 6 a 330 g b 90.8% 7 a 2.40 g b 88.4% 07-Jul-12 Chemsheets AS 008 8

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10 TASK 13 Atom economy % 2 1.5% % % 5 100% % 7 a 320 g b 87.5% c 29.5% d % yield compares the amount produced compared to the amount you should get, atom economy is the proportion of the mass of all the products that is the desired product 07-Jul-12 Chemsheets AS

11 TASK 14 Ideal gas equation 1 a 473 K b Pa c 50 x 10-6 m 3 d 223 K e Pa f 3.2 x 10-3 m x 10-3 m Pa K m g m m K Pa 07-Jul-12 Chemsheets AS

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13 TASK 15 Reacting gas volumes 1 a O 2 2 dm 3, CO 2 1 dm 3 b O cm 3, CO 2 80 cm 3 c O cm 3, CO cm 3 d O cm 3, CO cm 3 q 2 20 cm 3 HBr left at end cm 3 O 2, 100 cm 3 CO 2, total 400 cm 3 gas at end 4 4 dm 3 O 2, 4 dm 3 H 2O, 4 dm 3 SO 2, total 12 dm 3 gas 07-Jul-12 Chemsheets AS

14 CHALLENGE : 3.11, 40.9 g 3 NS 4 C 2H ms -1 6 C 3H Jul-12 Chemsheets AS

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16 Calculations CHECK-UP 1 a Zn(NO 3) 2 b Pb c Cr 2O 3 d (NH 4) 2SO 4 e P 4 f N 2 g Ba(OH) 2 h Al 2(SO 4) 3 2 H 2SO 4, KOH, 1:2; HCl, KHCO 3, 1:1; HNO 3, NH 3, 1:1; HCl, ZnCO 3, 2:1 3 a H + + OH - H 2O b Ba 2+ + SO 2-4 BaSO 4 c H NH 3 NH 4 d H + + HCO - 3 H 2O + CO 2 4 a average mass of an atom, relative to 1/12 th mass of 12 C atom b it is the agreed standard c mixture of other isotopes 5 a H 2, NH 3 = b H 2, NH 3 = 3.33 c N 2, NH 3 = 20 d H 2, NH 3 = x 10-4 m x a volume of CO 2 = 57.1 cm 3, total = cm 3 b volume of CO 2 = 200 cm 3, total = 350 cm 3 c volume of CO 2 = cm 3, total = cm x 10-3 m m 3 11 a 40, 60 b 40, 20 c 5.84, g g 14 a 1250 g b 96% c reversible, product lost on isolation, other reactions d 100% 15 a 529 g b 94.5% c 52.9% a 0.05, 0.05, 1.22 x 10-3 m 3, 4.07 g b 1.30 g, 2.77 g 07-Jul-12 Chemsheets AS

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22 TASK 16 Solution calculations 1 a 0.1 b 250 c a 0.2 mol dm -3, 7.3 g dm -3 b 2.5 mol dm -3, g dm -3 c 2.1 mol dm -3, 84.0 g dm -3 3 a 0.05 dm 3 b dm mol dm -3, 4.61 g dm mol dm -3, 3.01 g dm dm mol dm -3, 71.0 g dm g dm A r = 39.1, K % 07-Jul-12 Chemsheets AS

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25 TASK 17 Back titration calculations % % mol, 4.22 g g g 07-Jul-12 Chemsheets AS

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27 CHALLENGE % 2 A Si 2OCl Jul-12 Chemsheets AS

28 TASK 18 Empirical & molecular formulas 1 a CH 3 b P 2O 3 c SO 2 d CH 2 e CH 2O f C 2H 7N g B 3H 5 h C 12H 22O 11 2 a N 2H 4 b C 4H 10 c C 5H 10 d PH 3 e C 6H 6 f C 3H 6 3 a 3:2 b 1:2 c 5:1 d 2:5 e 3:4 f 5:3 g 4:5 h 4:7 4 a CaBr 2 b Na 2S 2O 3 c C 2H 7N d CO 2 e NO 2 5 FeCl 3 6 K 2SO 4 7 P 2O 3, P 4O 6 8 CH 2O, C 2H 4O 2 9 C 5H 10O, C 5H 10O 10 x = 4, y = Jul-12 Chemsheets AS

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30 Calculation Allsorts 1 C 5H 11NO 2 C 11H 14O 2, C 11H 14O g g dm mol dm % % Al + 6 NH 4ClO 4 3 N H 2O + 6 HCl + 5 Al 2O Jul-12 Chemsheets AS

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AMOUNT OF SUBSTANCE. TASK 1 Writing formulas of ionic compounds. TASK 2 Writing formulas 1. TASK 3 Writing formulas 2

AMOUNT OF SUBSTANCE. TASK 1 Writing formulas of ionic compounds. TASK 2 Writing formulas 1. TASK 3 Writing formulas 2 AMOUNT OF SUBSTANCE TASK 1 Writing formulas of ionic compounds 1 AgBr 2 Na 2CO 3 3 K 2O 4 Fe 2O 3 5 CrCl 3 6 Ca(OH) 2 7 Al(NO 3) 3 8 Na 2SO 4 9 PbO 10 Na 3PO 4 11 Zn(HCO 3) 2 12 (NH 4) 2SO 4 13 Ga(OH)

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