Slide 1 / Objects can possess energy as: (a) endothermic energy (b) potential energy (c) kinetic energy. a only b only c only a and c b and c

Transcription

1 Slide 1 / 84 1 Objects can possess energy as: (a) endothermic energy (b) potential energy (c) kinetic energy A B C D E a only b only c only a and c b and c

2 Slide 2 / 84 2 The internal energy of a system A B C D E is the sum of the kinetic energy of all of its components is the sum of the rotational, vibrational, and translational energies of all of its components refers only to the energies of the nuclei of the atoms of the component molecules is the sum of the potential and kinetic energies of the components none of the above

3 Slide 3 / 84 3 Which one of the following conditions would always result in an increase in the internal energy of a system? A The system loses heat and does work on the surroundings. B The system gains heat and does work on the surroundings. C The system loses heat and has work done on it by the surroundings. D The system gains heat and has work done on it by the surroundings. E None of the above is correct.

4 Slide 4 / 84 4 The value of ΔE for a system that performs 111 kj of work on its surroundings and gains 89 kj of heat is kj. A -111 B -200 C 200 D -22 E 22

5 Slide 5 / 84 5 The value of ΔE for a system that performs 13 kj of work on its surroundings and loses 9 kj of heat is kj. A 22 B -22 C 4 D -4 E -13

6 Slide 6 / 84 6 Calculate the value of ΔE in joules for a system that loses 50 J of heat and has 150 J of work performed on it by the surroundings. A 50 B 100 C -100 D -200 E 200

7 Slide 7 / 84 7 The change in the internal energy of a system that absorbs 2,500 J of heat and that does 7,655 J of work on the surroundings is J. A 10,155 B 5,155 C -5,155 D -10,155 E 1.91 x107

8 Slide 8 / 84 8 The change in the internal energy of a system that releases 2,500 J of heat and that does 7,655 J of work on the surroundings is J. A -10,155 B -5,155 C -1.91x107 D 10,155 E 5,155

9 Slide 9 / 84 9 When a system, ΔE is always negative. A absorbs heat and does work B gives off heat and does work C absorbs heat and has work done on it D gives off heat and has work done on it E none of the above is always negative.

10 Slide 10 / Of the following, which one is a state function? A H B q C w D heat E none of the above

11 Slide 11 / Which one of the following is an endothermic process? A ice melting B water freezing C boiling soup D Hydrochloric acid and barium hydroxide are mixed at 25 C: the temperature increases. E Both A and C

12 Slide 12 / Which one of the following is an exothermic process? A ice melting B water evaporating C boiling soup D condensation of water vapor E Ammonium thiocyanate and barium hydroxide are mixed at 25 C: the temperature drops.

13 Slide 13 / A ΔH corresponds to an process. A negative, endothermic B negative, exothermic C positive, exothermic D zero, exothermic E zero, endothermic

14 Slide 14 / A ΔH corresponds to an process. A negative, endothermic B positive, exothermic C positive, endothermic D zero, exothermic E zero, endothermic zero, endothermic

15 Slide 15 / For an endothermic process is while ΔH for an exothermic process is. A zero, positive B zero, negative C positive, zero D negative, positive E positive, negative

16 Slide 16 / A chemical reaction that absorbs heat from the surroundings is said to be and has a ΔH. A endothermic, positive B endothermic, negative C exothermic, negative D exothermic, positive E exothermic, neutral

17 Slide 17 / The reaction 4Al(s) + 3O 2 (g) 2Al 2 O 3 (s) ΔH = kj is, and therefore heat is by the reaction. A endothermic, released B endothermic, absorbed C exothermic, released D exothermic, absorbed E thermoneutral, neither released nor absorbed

18 Slide 18 / The molar heat capacity of a compound with the formula C 2 H 6 SO is 88.0 J/mol-K. The specific heat of this substance is J/g-K. A 88.0 B 1.13 C 4.89 D 6.88x10 3 E -88.0

19 Slide 19 / A sample of aluminum metal absorbs 9.86 J of heat, and the temperature of the sample increases from 23.2 C to 30.5 C. Since the specific heat capacity of aluminum is 0.90 J/g-K, the mass of the sample is g. A 75 B 1.5 C 65 D 8.1 E 6.6

20 Slide 20 / The specific heat capacity of lead is 0.13 J/g-K. How much heat (in J) is required to raise the temperature of 15g of lead from 22 C to 37 C? A 2.0 B C 5.8 x10-4 D 29 E 0.13

21 Slide 21 / The temperature of a 15-g sample of lead metal increases from 22 C to 37 C upon the addition of 29.0 J of heat. The specific heat capacity of the lead is J/g-K. A 7.8 B 1.9 C 29 D 0.13 E -29

22 Slide 22 / The ΔH for the solution process when solid sodium hydroxide dissolves in water is 44.4 kj/mol. When a 13.9-g sample of NaOH dissolves in g of water in a coffee-cup calorimeter, the temperature increases from 23.0 C to C. Assume that the solution has the same specific heat as liquid water, i.e., 4.18 J/g-K. A 35.2 C B 24.0 C C 37.8 C D 37.0 C E 40.2 C

23 Slide 23 / An 8.29 g sample of calcium carbonate [CaCO 3 (s)] absorbs 50.3 J of heat, upon which the temperature of the sample increases from 21.1 C to 28.5 C. What is the specific heat of calcium carbonate? A 0.63 B 0.82 C 1.1 D 2.2 E 4.2

24 Slide 24 / A sample of iron absorbs 67.5 J of heat, upon which the temperature of the sample increases from 21.5 C to 28.5 C. If the specific heat of iron is J/g-K, what is the mass (in grams) of the sample? A 4.3 B 11 C 21 D 1100 E 1200

25 Slide 25 / A g sample of iron absorbs J of heat, upon which the temperature of the sample increases from 21.1 C to 39.0 C. What is the specific heat of iron? A B C D E 0.900

26 Slide 26 / When 45 g of an alloy at C is dropped into g of water at 25 C, the final temperature is 37 C. What is the specific heat of the alloy (J/g o C)? A 9.88 B 48.8 C D 1.77

27 Slide 27 / A 50.0-g sample of liquid water at 25.0 C is mixed with 29.0 g of water at 45.0 C. The final temperature of the water is. A 102 B 27.6 C 35.0 D 142 E 32.3

28 Slide 28 / A 6.50-g sample of copper metal at 25.0 C is heated by the addition of 84.0 J of energy. The final temperature of the copper is C. The specific heat of copper is 0.38 J/g-K. A 29.9 B 25.0 C 9.0 D 59.0 E 34.0

29 Slide 29 / How much heat is required to melt 1.5 moles of NaCl at its melting point (DHfus = 30 kj/mol) A 1.5 kj B 15 kj C 20 kj D 30 kj E 45 kj

30 Slide 30 / A substance releases 500 kj of heat as 25 mol of it condenses from a gas to a liquid. What is the heat of vaporization (DHvap) of this substance? A 20 kj/mol B 25 kj/mol C 475 kj/mol D 525 kj/mol

31 Slide 31 / If you supply 36 kj of heat, how many moles of ice a 0 o C can be melted, heated to its boiling point and completely boiled away? DHvap = 40.5 kj/mol; DHfus = 6.0 kj/mol; specific heat for water, C = kj/mol- o C

32 Slide 32 / Given the equation: H 2 O (l) H 2 O(g) DHrxn = 40.7 kj at 100 C Calculate the mass of liquid water (in grams) at 100 C that can converted to vapor by absorbing 2.40 kj of heat.

33 Slide 33 / Given the equation: H 2 O (l) H 2 O(g) DHrxn = 40.7 kj at 100 C Calculate the heat required to convert 3.00 grams of liquid water at 100 C to vapor.

34 Slide 34 / Based on the following information, which compound has the strongest intermolecular forces? Substance ΔHvap (kj/mol) Argon (Ar) 6.3 Benzene (C 6 H 6 ) 31.0 Ethanol (C 2 H 5 OH) 39.3 Water (H 2 O) 40.8 Methane (CH 4 ) 9.2 A Argon B Benzene C Ethanol D Water E Methane

35 Slide 35 / What amount of heat (in kj) is required to melt 35.0 g of ice at 0 o C? A 3.09 kj B 11.7 kj C 20.9 kj D 79.1 kj Specific heat of ice Specific heat of water Specific heat of steam Heat of fusion of water (Hfus) He at of vaporization of wate r (Hvap) 2.09 J/g- o C 4.18 J/g- o C 1.84 J/g- o C 6.01 kj/mol 40.7 kj/mol

36 Slide 36 / What amount of heat (in kj) is required to completely convert g of liquid water at 18 o C to steam at o C? A 6.51 kj B 6.94 kj C 430 kj D 559 kj Specific heat of ice Specific heat of water Specific heat of steam Heat of fusion of water (Hfus) He at of vaporization of wate r (Hvap) 2.09 J/g- o C 4.18 J/g- o C 1.84 J/g- o C 6.01 kj/mol 40.7 kj/mol

37 Slide 37 / The enthalpy change for converting 1.00 mol of ice at C to water at 70.0 C is kj. A B 6.41 C D 7154 E 9.40 Specific heat of ice Specific heat of water Specific heat of steam Heat of fusion of water (Hfus) He at of vaporization of wate r (Hvap) 2.09 J/g- o C 4.18 J/g- o C 1.84 J/g- o C 6.01 kj/mol 40.7 kj/mol

38 Slide 38 / The enthalpy change for converting 10.0 g of ice at C to water at 80.0 C is kj. A B 6.16 C 3870 D 7.21 E 9.88 Specific heat of ice Specific heat of water Specific heat of steam Heat of fusion of water (Hfus) He at of vaporization of wate r (Hvap) 2.09 J/g- o C 4.18 J/g- o C 1.84 J/g- o C 6.01 kj/mol 40.7 kj/mol

39 Slide 39 / The heat of fusion of water is 6.01 kj/mol. The heat capacity of liquid water is 75.3 J/mol-K The conversion of of ice at 0.00 C to liquid water at 22.0 C requires kj of heat. A 3.8 x10 2 B 21.3 C 17.2 D E Insufficient data given

40 Slide 40 / Which of the following statements is false? A Internal energy is a state function. B Enthalpy is an intensive property. C The enthalpy change for a reaction is equal in magnitude, but opposite in sign, to the enthalpy change for the reverse reaction. D The enthalpy change for a reaction depends on the state of the reactants and products. E The enthalpy of a reaction is equal to the heat of the reaction.

41 Slide 41 / The value of DH0 for the reaction below is -72 kj. kj of heat are released when 1.0 mol of HBr is formed in this reaction: H 2 (g) + Br 2 (g) 2HBr (g) A 144 B 72 C 0.44 D 36 E -72

42 Slide 42 / The value of DH0 for the reaction below is -126 kj. kj are released when 2.00 mol of NaOH is formed in the reaction? 2Na 2 O 2 (s) + 2H 2 O(l) 4NaOH (s) + O 2 (g) A 252 B 63 C 3.9 D 7.8 E -126

43 Slide 43 / The value of DH0 for the reaction below is -790 kj. The enthalpy change accompanying the reaction of 0.95 g of S is kj. 2S(s) + 3O2 (g) 2SO 3 (g) A 23 B -23 C -12 D 12 E -790

44 Slide 44 / The value of DH0 for the reaction below is kj. kj of heat are released in the combustion of 16.0 g of C 6 H 6 (l)? 2C 6 H 6 (l) + 15O 2 (g) 12CO 2 (g) + 6H 2 O(l) A 1.34 x 10 3 B 5.23 x 10 4 C 669 D 2.68 x10 3 E -6535

45 Slide 45 / The value of DH0 for the reaction below is -482 kj. Calculate the heat (kj) released to the surroundings when 12.0 g of CO (g) reacts completely. 2CO(g) + O 2 (g) 2CO 2 (g) A 2.89x10 3 B 207 C 103 D 65.7 E -482

46 Slide 46 / The value of DH0 for the reaction below is -336 kj. Calculate the heat (kj) released to the surroundings when 23.0 g of HCl is formed. CH 4 (g) +3Cl 2 (g) CHCl 3 (l) + 3HCl(g) A 177 B 2.57x10 3 C 70.7 D 211 E -336

47 Slide 47 / The value of DH0 for the reaction below is -186 kj. Calculate the heat (kj) released from the reaction of 25 g of Cl 2. H 2 (g) + Cl 2 (g) 2HCl (g) A 66 B 5.3 x 10 2 C 33 D 47 E -186

48 Slide 48 / The enthalpy change for the following reaction is kj: 2H 2 (g) + O 2 (g) 2H 2 O(g) Therefore, the enthalpy change for the following reaction is kj: 4H 2 (g) + 2O 2 (g) 4H 2 O(g) A B C 2.34x105 D E 967.2

49 Slide 49 / The value of DH for the reaction below is kj: CH 3 OH (l) CO(g) + 2H 2 (g) How many kj of heat are consumed when 15.5 g of CH 3 OH(l) decomposes as shown in the equation? A 0.48 B 62.0 C 1.3x10 2 D 32 E 8.3

50 Slide 50 / The value of DH0 for the reaction below is kj: CH 3 OH (l) CO(g) + 2H 2 (g) How many kj of heat are consumed when 5.10 g of H 2 (g) is formed as shown in the equation? A 162 B 62.0 C 128 D 653 E 326

51 Slide 51 / The value of DH0 for the reaction below is kj: CH 3 OH (l) CO(g) + 2H 2 (g) How many kj of heat are consumed when 5.10 g of CO (g) are formed? A B 162 C 8.31 D 23.3 E 62.0

52 Slide 52 / The value of DH0 for the reaction below is kj: CH 3 OH (l) CO(g) + 2H 2 (g) How many kj of heat are consumed when 5.75 g of CO(g) is formed? A 23.3 B 62.0 C 26.3 D 162 E 8.3

53 Slide 53 / The value of DH0 for the reaction below is kj: 2Ba(s) + O 2 (g) 2BaO (s) How many kj of heat are released when 5.75 g of Ba(s) reacts completely with oxygen to form BaO (s)? A 96.3 B 26.3 C 46.4 D 23.2 E 193

54 Slide 54 / The value of DH0 for this reaction is kj: 2Ba(s) + O 2 (g) 2BaO (s) How many kj of heat are released when 5.75 g of BaO (s) is produced? A 56.9 B 23.2 C 20.8 D 193 E 96.3

55 Slide 55 / The value of DH0 for the reaction below is kj: 2Ba(s) + O 2 (g) 2BaO (s) How many kj of heat are released when g of Ba(s) reacts completely with oxygen to form BaO(s)? A 20.8 B 63.5 C 114 D 70.3 E 35.1

56 Slide 56 / Which of the following is a statement of Hess's law? A B C D E If a reaction is carried out in a series of steps, the ΔH for the reaction will equal the sum of the enthalpy changes for the individual steps. If a reaction is carried out in a series of steps, the ΔH for the reaction will equal the product of the enthalpy changes for the individual steps. The ΔH for a process in the forward direction is equal in magnitude and opposite in sign to the ΔH for the process in the reverse direction. The ΔH for a process in the forward direction is equal to the ΔH for the process in the reverse direction. The ΔH of a reaction depends on the physical states of the reactants and products.

57 Slide 57 / ΔH for the reaction IF 5 (g) à IF 3 (g) + F 2 (g) is kj, give the data below. IF (g) + F 2 (g) à IF 3 (g) ) ΔH = -390 kj IF (g) + 2F 2 (g) à IF 5 (g) ΔH = -745 kj A +355 B C D +35 E -35

58 Slide 58 / Given the following reactions the enthalpy of the reaction of the nitrogen to produce nitric oxide N 2 (g) + O 2 (g)à 2NO (g) is kj. N 2 (g) + 2O 2 (g) à 2NO 2 (g) ΔH = 66.4 kj 2NO (g) + O 2 (g) à 2NO 2 (g) ΔH = kj A B C 47.8 D 90.3 E

59 Slide 59 / Given the following reactions the enthalpy of the reaction of nitrogen with oxygen to produce nitrogen dioxide N 2 (g) + 2O 2 (g) à 2NO 2 (g) is kj. (1) 2NO à N2 + O 2 ΔH = -180 kj (2) 2NO + O 2 à 2NO 2 ΔH = -112 kj A 68 B -68 C -292 D 292 E -146

60 Slide 60 / Given the following reactions the enthalpy of the reaction CaCO 3 (s) à CaO(s) + C (s) + O 2 (g) is kj. CaCO 3 (s) à CaO(s) + CO2(g) ΔH = kj C(s) + O 2 (g) à CO 2 (g) ΔH = kj A B C D E 7.01 x 10 4

61 Slide 61 / Given the following reactions the enthalpy for the decomposition of liquid water into gaseous hydrogen and oxygen 2H 2 O (l) à 2H 2 (g) + O 2 (g) is kj. H 2 O (l) à H 2 O (g) ΔH = kj 2H 2 (g) O 2 (g) à 2H 2 O (g) ΔH = kj A B C D E

62 Slide 62 / Given the following reactions the enthalpy for the decomposition of nitrogen dioxide into molecular nitrogen and oxygen 2NO 2 (g) à N 2 (g) + 2O 2 (g) is kj. N 2 (g) + O 2 (g) à 2NO(g) ΔH = kj 2NO (g) + O 2 (g) à 2NO 2 (g) ΔH = kj A 67.6 B C D E 45.5

63 Slide 63 / Given the following reactions the enthalpy of reaction for 4NO(g) à 2NO2 (g) + N2 (g) is kj. N 2 (g) + O 2 (g) à 2NO (g) ΔH = kj 2NO(g) +O 2 (g) à 2NO 2 (g) ΔH = kj A 67.6 B 45.5 C D E 293.8

64 Slide 64 / Given the following reactions the enthalpy of reaction for 2N 2 O(g) à 2NO(g) +N 2 (g) is kj. N 2 (g) + O 2 (g) à 2NO(g) ΔH = kj 2N 2 O(g) à O 2 (g) + 2N 2 (g) ΔH = kj A B C D 17.5 E

65 Slide 65 / Of the following, ΔH f 0 is not zero for. A B C D E O 2 (g) C (graphite) N 2 (g) F 2 (s) Cl 2 (g)

66 Slide 66 / In the reaction below, ΔH f 0 is zero for. Ni(s) + 2CO (g) +2PF 3 (g) à Ni(CO) 2 (PF 3 ) 2 (l) A Ni(s) B CO(g) C PF 3 (g) D Ni(CO) 2 (PF 3 ) 2 (l) E Both CO and PF 3

67 Slide 67 / For the species in the reaction below, ΔH f 0 is zero for. 2Co(s) + H 2 (g) + 8PF 3 (g) à 2HCo(PF 3 ) 4 (I) A B C Co(s) H 2 (g) PF 3 (g) D HCo(PF 3 ) 4 E Both Co(s) and H 2 (g)

68 Slide 68 / For which one of the following equations is ΔH 0 rxn equal to ΔH f 0 for the product? A B C Xe (g) + 2F 2 (g) à XeF 4 (g) CH 4 (g) +2Cl 2 (g) à CH 2 Cl 2 (l) + 2HCl(g) N 2 (g) + O 3 (g) à N 2 O 3 (g) D 2CO(g) +O 2 (g) à 2CO 2 E C(diamond) + O 2 (g) à CO 2 (g)

69 Slide 69 / For which of the following reactions is the value of ΔH0 rxn equal to ΔH f 0 for the product? A 2Ca(s) + O 2 (g) à 2CaO(s) B C 2 H 2 (g) + H 2 (g) à C 2 H 4 (g) C 2C(graphite) +O 2 (g) à 2CO (g) D 3Mg(s) + N 2 (g) à Mg 3 N 2 (s) E C(diamond) + O 2 (g) à CO 2 (g)

70 Slide 70 / For which of the following reactions is the value of ΔH0 rxn equal to ΔH 0 f for the product? A 2C(graphite) + 2H 2 (g) à C 2 H 4 (g) B N 2 (g) +O 2 (g) à 2NO(g) C 2H 2 (g) +O 2 (g) à 2H 2 O(l) D 2H 2 (g) + O 2 (g) à 2H 2 O(g) E H 2 O(l) +1/2 O 2 (g) à 2H 2 O(l)

71 Slide 71 / For which of the following reactions is the value of ΔH o rxn equal to ΔH f o for the product? A B C D E H 2 O(l) +1/2 O 2 (g) H 2 O 2 (l) N 2 (g) +O 2 (g) 2NO(g) 2H 2 (g) + O 2 (g) 2H 2 O(l) 2H 2 (g) + O 2 (g) 2H 2 O(g none of the above

72 Slide 72 / For which of the following reactions is the value of ΔH o rxn equal to ΔH f o for the product? A B C D E H 2 (g) + 1/2O 2 (g) H 2 O(l) H 2 (g) + O 2 (g) H 2 O 2 (l) 2C(graphite) + 2H 2 (g) C 2 H 4 (g) 1/2N 2 (g) + O 2 (g) NO 2 (g) All of the above

73 Slide 73 / The value of for the reaction below is -186 kj. H 2 (g) + Cl 2 (g) 2HCl(g) The value of ΔH o f for HCl (g) is kj/mol A -3.72x10 2 B -1.27x10 2 C D -186 E +186

74 Slide 74 / The value of for the following reaction is kj: 2Al(s) +3O 2 (g) Al 2 O 3 The value of ΔH f o for Al 2 O 3 is kj. A B C D E +3351

75 Slide 75 / Given the data in the table below, ΔH o rxn for this reaction is kj. Ca(OH) 2 + 2H 3 AsO 4 Ca(H 2 AsO 4 ) 2 + 2H 2 O A B C D E Substance ΔH 0 f (kj/mol) Ca(OH) H 3 AsO Ca(H 2 AsO 4 ) H 2 O

76 Slide 76 / Given the data in the table below, ΔH o rxn for this reaction is kj. 4NH 3 (g) + 5O 2 (g) 4NO(g) + 6H 2 O(l) A B -150 C D Substance ΔH 0 f (kj/mol) H 2 O(l) -286 NO (g) 90 NO 2 (g) 34 NO 3 (aq) -207 NH 3 (g) -46 E The ΔH f o of O 2 (g) is needed

77 Slide 77 / Given the data in the table below, H o rxn for this reaction is kj. C 2 H 5 OH(l) + O 2 (g) CH 3 CO 2 (l) + H 2 O(l) A B C D Substance C 2 H 4 (g) 523 C 2 H 5 OH(l) CH 3 CO 2 H(l) H 2 O(l) ΔH f 0 (kj /mol) E The value of H f o of O 2 (g) is required

78 Slide 78 / Given the data in the table below, ΔH o rxn for this reaction is kj. 3NO 2 +H 2 O (l) 2HNO 3 (aq) + NO(g) A 64 B 140 C -140 Substance ΔH 0 f (kj/mol) H 2 O(l) -286 NO (g) 90 NO 2 (g) 34 HNO 3 (aq) -207 NH 3 (g) -46 D -508 E -64

79 Slide 79 / Given the data in the table below, ΔH o rxn for this reaction is kj. IF 5 (g) + F 2 (g) IF 7 (g) A 1801 B Substance 0 ΔH f (kj /mol) IF(g) -95 IF 5 (g) -840 IF 7 (g) -941 C 121 D -121 E -101

80 Slide 80 / Given the data in the table below, ΔH o for the reaction is kj. 2CO (g) + O 2 2CO 2 (g) A B C Substance 0 ΔH f (kj /mol) CO(g) CO 2 (g) CaCO 3 (s) D E The ΔH f o of is needed

81 Slide 81 / The value of ΔH for the following reaction is kj. The value of ΔH o f for CaO(s) is kj/mol. CaCO 3 (s) CaO(s) + CO 2 (g) A B Substance 0 ΔH f (kj /mol) CO(g) CO 2 (g) CaCO 3 (s) C D E 177.8

82 Slide 82 / Given the data in the table below, ΔH o rxn for the reaction is kj. 2Ag 2 S(s) +O 2 (g) 2Ag 2 O(s) +2S(s) A -1.6 B +1.6 C -3.2 Substance 0 ΔH f (kj /mol) Ag 2 O(s) Ag 2 S(s) -326 H 2 S(g) H 2 O(l) -286 D +3.2 E The ΔH f o of S(s) and of O 2 (g) are needed.

83 Slide 83 / Given the data in the table below, ΔH o rxn for the reaction is kj. PCl 3 (g) +3HCl(g) 3Cl 2 (g) +PH 3 (g) A B C Substance 0 ΔH f (kj /mol) PCl 3 (g) HCl(g) PH 3 (g) 5.40 D E The ΔH f o of Cl 2 (g) is needed for the calculation.

84 Slide 84 / Given the data in the table below and ΔH o rxn for the reaction, ΔH o f of HCl(g) is kj/mol. SO 2 Cl 2 (g) +2H 2 O(l) H 2 SO 4 (l) + 2HCl(g) ΔH o f = -62 kj A -184 B 60 C -92 D 30 Substance ΔH f 0 (kj /mol) SO 2 (g) -297 SO 3 (g) -396 SO 2 Cl 2 (g) -364 H 2 SO 4 (l) -814 H 2 O(l) -286 E Insufficient data are given.