Supplementary Figure 1 IR Spectroscopy. 1Cu 1Ni Supplementary Figure 2 UV/Vis Spectroscopy. 1Cu 1Ni

Save this PDF as:
 WORD  PNG  TXT  JPG

Size: px
Start display at page:

Download "Supplementary Figure 1 IR Spectroscopy. 1Cu 1Ni Supplementary Figure 2 UV/Vis Spectroscopy. 1Cu 1Ni"

Transcription

1 Supplementary Figure 1 IR Spectroscopy. IR spectra of 1Cu and 1Ni as well as of the starting compounds, recorded as KBr-pellets on a Bruker Alpha FTIR spectrometer. Supplementary Figure 2 UV/Vis Spectroscopy. UV/Vis spectra of 1Cu and 1Ni recorded in acetonitrile solution at room temperature on a Perkin-Elmer Lambda 2 spectrometer. 1

2 Supplementary Figure 3 Susceptibility temperature product as a function of temperature for 1Cu. The measurement was performed on a teflon-wrapped pressed powder sample in an applied field of 1000 Oe with a Quantum Design MPMS XL7 SQUID magnetometer. The data were corrected for the diamagnetic contribution by using Pascal's constants. 1,0 Brillouin functions 1.8 K 2 K 3 K 5 K 7 K 10 K M / B 0,5 0, H / koe Supplementary Figure 4 Magnetization as a function of field for 1Cu. The measurement was performed on a teflon-wrapped pressed powder sample at various temperatures as indicated in the Figure with a Quantum Design MPMS XL7 SQUID magnetometer. The data were corrected for the diamagnetic contribution by using Pascal's constants. Solid red lines are fits to the Brillouin function with S = ½ and g =

3 a b Intensity (arb. u.) Intensity (arb. u.) Magnetic field (mt) Supplementary Figure 5 CW X-band EPR spectra of 1Cu 1.5%. Experimental CW X-Band EPR spectra (blue solid lines) and easy spin simulations (red dashed lines). The spectra were recorded on a finely ground powder sample of 1Cu 1.5% in evacuated sample tubes at 9.47 GHz on a Bruker EMX spectrometer in Stuttgart. a, Spectrum at 5 K and fit with parameters g = ± 0.002, g = ± 0.001, A = 496 ± 5 MHz, A = 119 ± 5 MHz. b, Spectrum at room temperature and fit with parameters g = ± 0.002, g = ± 0.001, A = 480 ± 5 MHz, A = 115 ± 5 MHz. 3

4 a b c d Intensity (arb. u.) e f Magnetic field (mt) Magnetic field (mt) Supplementary Figure 6 Pulsed Q-band EPR spectra of 1Cu 0.001%. Electron spin echo detected field-swept spectra recorded on 1Cu 0.001% (blue solid lines) and easy spin simulations (red dashed lines) using the parameters g = ± 0.010, g = ± 0.005, A = 500 ± 5 MHz, A = 118 ± 5 MHz. The measurements were performed on a Bruker Elexsys E580 in Frankfurt. Temperatures up to 275 K were achieved with an Oxford Instruments CF935 continuous flow cryostat (cryogenic liquid: He), room temperature measurements were done at approximately 294 K. a, Spectrum recorded at 7 K and GHz. b, Spectrum recorded at 15 K and GHz. c, Spectrum recorded at 50 K and 33.8 GHz. d, Spectrum recorded at 120 K and GHz. e, Spectrum recorded at 200 K and GHz. f, Spectrum recorded at room temperature and GHz. 4

5 Supplementary Figure 7 Hahn echo decay curves of 1Cu 0.001%. Normalized echo intensity as a function of delay time 2τ (Hahn echo sequence) recorded on a powder sample of 1Cu 0.001% at different temperatures. Black solid lines are stretched exponential fits resulting in the coherence times reported in Supplementary Table 1. The measurements were performed at 34 GHz on a Bruker Elexsys E580 in Frankfurt. Temperatures up to 275 K were achieved with an Oxford Instruments CF935 continuous flow cryostat (cryogenic liquid: He), room temperature measurements were done at approximately 294 K. 5

6 Intensity / arb. u. 0,3 0,2 0,1 0,0 1,16 1,20 1,24 1,28 Magnetic Field / T a / arb. units I*I 1 0 I / arb. units 1,0 0,8 0,6 0,4 0,2 0, b / s 15 c T / ms Supplementary Figure 8 Pulsed EPR on 1Cu 1.5%. The measurements were performed at 35 GHz on a homebuilt pulsed Q-band EPR spectrometer in Stuttgart. a, echo detected EPR spectrum recorded at 7 K; b, Hahn echo decay curve at 7 K together with stretched exponential fit, where T M = 3.97 μs, and x = 1.43; c, inversion recovery curve together with a biexponential fit at 7 K, where T 1,f = 2.5 ms and T 1,s = 41 ms. 6

7 Supplementary Figure 9 Nutation measurement of 1Cu 0.001%. Nutation measurement on a powder sample of 1Cu 0.001% at 15 K and different applied powers were performed at 34 GHz on a Bruker Elexsys E580 in Frankfurt. Pulse sequence: nutation pulse - τ nut - π/2 - τ fix - π - τ fix - echo with τ nut = 400 ns, τ fix = 140 ns. 7

8 Supplementary Figure 10 Inversion recovery traces of 1Cu 0.001%. Normalized echo intensity as a function of delay time T (inversion recovery sequence) at different temperatures. Black solid lines are biexponential (for 7-25 K) or monoexponential (for T > 25 K) fit functions resulting in the spin lattice relaxation times reported in Supplementary Table 2. The measurements were performed at 34 GHz on a Bruker Elexsys E580 in Frankfurt. Temperatures up to 275 K were achieved with an Oxford Instruments CF935 continuous flow cryostat (cryogenic liquid: He), room temperature measurements were done at approximately 294 K. 8

9 Intensity / arb. u. 0,05 0,04 0,03 0,02 0,01 0,00 1,16 1,20 1,24 1,28 Magnetic Field / mt a Echo Intensity / arb. u. 1,0 7 K b 50 K 150 K 0, / s 1,5 1,0 0,5 0,0-0,5-1, T / s c Supplementary Figure 11 Pulsed EPR on 1Cu 0.01% D. The measurements were performed at 35 GHz on a homebuilt pulsed Q-band EPR spectrometer in Stuttgart. a, echo detected EPR spectrum recorded at 7 K; b, Hahn echo decay curves together with fit functions at different temperatures; c, inversion recovery curves together with fit functions at different temperatures. Fit functions are bi- (7 K) or monoexponentials (50, 100 K) for both relaxation times and their results are reported in Supplementary Table 3. 9

10 Supplementary Table 1 Coherence times T M and stretch factors for 1Cu 0.001%. Parameters were extracted from fitting Hahn echo decay curves of Supplementary Figure 7 with stretched exponentials. T / K T M / μs x ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± rt ± ± Supplementary Table 2 Spin lattice relaxation times T 1 (fast and slow components) for Cu 0.001%. Parameters were extracted from fitting Inversion recovery traces of Supplementary Figure 10 with biexponential (for 7-25 K) or monoexponential (for T > 25 K) fit functions. T / K T 1,f / μs T 1,s / μs rt

11 Supplementary Table 3 Spin lattice relaxation times T 1 and spin-spin relaxation times T M (fast and slow components in both cases) for Cu 0.01% D. Parameters were extracted from fitting Inversion recovery traces and Hahn echo decays shown in Supplementary Figure 11 with biexponential (for 7 K) or monoexponential (for 50, 100 K) fit functions. T / K T 1,f / μs T 1,s / μs T M,f / μs T M,s / μs 7 7 ± ± ± ± ± ± ± ± 0.2 Supplemetary Methods Synthesis and Analysis All reagents and solvents were used as purchased from commercial sources. Bis-(tetraphenylphosphonium)-bis-(maleonitriledithiolato)cuprate, (PPh 4 ) 2 [Cu(mnt) 2 ] (1Cu): Sodium maleonitriledithiolate (279 mg, 1.5 mmol) was dissolved in 5 ml ethanol and 2 ml demineralized water. Subsequently copper chloride dihydrate (128 mg, 0.75 mmol), dissolved in 5 ml ethanol, and tetraphenylphosphonium bromide (629 mg, 1.50 mmol), dissolved in 15 ml ethanol were added under stirring. The brown product precipitated immediately and was separated from the solution after 5 min by vacuum filtration. Washing of the product with 3 x 5 ml ethanol and drying for 20 h under reduced pressure gave a yield of 576 mg (75.01 % based on Cu). Elemental analysis: found (calcd) for C 59 H 40 CuN 4 P 2 S 4 in %: C: (65.77), H: 3.90 (3.94), N: 5.48 (5.48), S: (12.54). UV/VIS (MeCN): λ max in nm: 478, 430, 369, 348, 317, 275. IR (KBr-pellet): in cm -1 and assignment in brackets: 2195 (ν C N ), 1459 (ν C=C ). Bis-(tetraphenylphosphonium)-bis-(maleonitriledithiolato)nickelate (PPh 4 ) 2 [Ni(mnt) 2 ] (1Ni): The same procedure as described for 1Cu was executed with nickel chloride hexahydrate (178 mg, 0.75 mmol) instead of copper chloride dihydrate. The red compound was isolated with a yield of 614 mg (80.4 % based on Ni). Elemental analysis: found (calcd) for C 59 H 40 NiN 4 P 2 S 4 : C: (66.08), H: 3.94 (3.96), N: 5.46 (5.50), S: (12.60). UV/VIS (MeCN): λ max in nm: 474, 379, 315, 270. IR (KBr-pellet): in cm -1 and assignment in brackets: 2196 (ν C N ), 1479 (ν C=C ). Perdeuterotetraphenylphosphonium bromide PPh 4 Br -d 20 : In a pressure cylinder, deuterated triphenylphosphine ( g, 3.6 mmol) was combined with anhydrous nickel(ii)bromide ( g, 1.8 mmol) and deuterated phenylbromide (0.76 ml, 7.2 mmol). The pressure cylinder was sealed and heated to 180 C for three hours. After cooling, 50 ml of demineralized water was added to the blue-green solid. After stirring for 15 min at 75 C, a watery blue solution and a fawn precipitate formed. The mixture was cooled in an ice bath and extracted with 3 x 50 ml of diethylether. The organic phase of the ether extraction was discarded and the aqueous phase was extracted with 3 x 50 ml chloroform. Subsequently, the solvent of the organic phase was removed and the resulting white solid was dried under reduced pressure. 13 C NMR (500MHz): (t), (td), (td), , ppm. 11

12 Bis-(perdeuterotetraphenylphosphonium)-bis-(maleonitriledithiolato)cuprate (PPh 4 -d 20 ) 2 [Cu(mnt) 2 ] (1CuD): The deuterated compound was synthesized following the same procedure as described for its protonated analogue, except that PPh 4 Br was replaced by d 20 -PPh 4 Br. UV/VIS in DCM: λ max in nm: 482, 388, 373, 328, 323, 287, 276, 268. IR (KBrpellet): in cm -1 and assignment in brackets: 2195 (ν C N ), 1459 (ν C=C ). Bis-(perdeuterotetraphenylphosphonium)-bis-(maleonitriledithiolato)nickelate (PPh 4 -d 20 ) 2 [Ni(mnt) 2 ] (1NiD): The deuterated complex was synthesized following the same procedure as given for its protonated analogue above, where PPh 4 Br was replaced by d 20 - PPh 4 Br. UV/VIS in DCM: λ max in nm: 481, 384, 318, 272, 229. IR (KBr-pellet): in cm -1 and assignment in brackets: 2195 (ν C N ), 1479 (ν C=C ). Doped powder: % of 1Cu in 1Ni (1Cu 0.001% ): Doped powders 1Cu 0.001% were obtained by dissolving compounds 1Cu and 1Ni in the molar ratio : in a minimum volume of acetone, which was subsequently evaporated under reduced pressure. The resulting powders were dried in vacuo and finely ground. Doped powder: 0.01 % of 1CuD in 1NiD (1Cu 0.01% D): Doped powders 1Cu 0.01% D wereobtained similarly to 1Cu 0.001% from 1CuD and 1NiD. Doped single crystal: 1.5 % of 1Cu in 1Ni (1Cu 1.5% ): X-ray quality single crystals were obtained by dissolving compounds 1Cu and 1Ni in the molar ratio 98.5 : 1.5 in a minimum volume of acetone, which was subsequently diluted with the same amount of methanol. Crystals were collected after one week of slow solvent evaporation under ambient conditions. Results of X-ray analysis of 1Cu 1.5% : monoclinic, a = (10), b = (13), c = (12) Å, β = (5), V = (4) Å 3, T = 110 K, space group P2 1 /n, Z = 4, reflections collected, 7183 unique, final R 1 = , wr 2 [I > 2σ(I)] = , GOF =

Room Temperature Quantum Coherence and Rabi Oscillations in Vanadyl Phthalocyanine: Toward Multifunctional Molecular Spin Qubits

Room Temperature Quantum Coherence and Rabi Oscillations in Vanadyl Phthalocyanine: Toward Multifunctional Molecular Spin Qubits Room Temperature Quantum Coherence and Rabi Oscillations in Vanadyl Phthalocyanine: Toward Multifunctional Molecular Spin Qubits Matteo Atzori, Lorenzo Tesi, Elena Morra, Mario Chiesa, Lorenzo Sorace,

More information

Rare double spin canting antiferromagnetic behaviours in a. [Co 24 ] cluster

Rare double spin canting antiferromagnetic behaviours in a. [Co 24 ] cluster Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2016 Rare double spin canting antiferromagnetic behaviours in a [Co 24 ] cluster Guang-Ming Liang, Qing-Ling

More information

A versatile electronic hole in one-electron oxidized Ni II bissalicylidene

A versatile electronic hole in one-electron oxidized Ni II bissalicylidene Electronic Supplementary Information for manuscript: A versatile electronic hole in one-electron oxidized Ni II bissalicylidene phenylenediamine complexes Olaf Rotthaus, Olivier Jarjayes,* Carlos Perez

More information

Supporting Information for

Supporting Information for Supporting Information for Nickel(I)-mediated transformations of carbon dioxide in closed synthetic cycles: reductive cleavage and coupling of CO 2 generating Ni I CO, Ni II CO 3 and Ni II C 2 O 4 Ni II

More information

Supporting Information

Supporting Information Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2015 A rare case of a dye co-crystal showing better dyeing performance Hui-Fen Qian, Yin-Ge Wang,

More information

Supplementary Material (ESI) for CrystEngComm. An ideal metal-organic rhombic dodecahedron for highly efficient

Supplementary Material (ESI) for CrystEngComm. An ideal metal-organic rhombic dodecahedron for highly efficient Supplementary Material (ESI) for CrystEngComm An ideal metal-organic rhombic dodecahedron for highly efficient adsorption of dyes in an aqueous solution Yuan-Chun He, Jin Yang,* Wei-Qiu Kan, and Jian-Fang

More information

Supporting Information

Supporting Information Supporting Information One Pot Synthesis of 1,3- Bis(phosphinomethyl)arene PCP/PNP Pincer Ligands and Their Nickel Complexes Wei-Chun Shih and Oleg V. Ozerov* Department of Chemistry, Texas A&M University,

More information

A supramolecular approach for fabrication of photo- responsive block-controllable supramolecular polymers

A supramolecular approach for fabrication of photo- responsive block-controllable supramolecular polymers Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2014 Supporting Information A supramolecular approach for fabrication of photo- responsive

More information

Supporting Information

Supporting Information Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2018 Supporting Information Content Synthesis of compounds 2a, 2b in Scheme

More information

Tuning Porosity and Activity of Microporous Polymer Network Organocatalysts by Co-Polymerisation

Tuning Porosity and Activity of Microporous Polymer Network Organocatalysts by Co-Polymerisation Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Information Tuning Porosity and Activity of Microporous Polymer Network Organocatalysts

More information

Supporting Information. (1S,8aS)-octahydroindolizidin-1-ol.

Supporting Information. (1S,8aS)-octahydroindolizidin-1-ol. SI-1 Supporting Information Non-Racemic Bicyclic Lactam Lactones Via Regio- and cis-diastereocontrolled C H insertion. Asymmetric Synthesis of (8S,8aS)-octahydroindolizidin-8-ol and (1S,8aS)-octahydroindolizidin-1-ol.

More information

Functional nickel complexes of N-heterocyclic carbene ligands in pre-organized and supported thin film materials

Functional nickel complexes of N-heterocyclic carbene ligands in pre-organized and supported thin film materials Supporting Information Functional nickel complexes of N-heterocyclic carbene ligands in pre-organized and supported thin film materials Xinjiao Wang, a Marek Sobota, b Florian T. U. Kohler, c Bruno Morain,

More information

Supporting Information

Supporting Information Supporting Information Exploring the detection of metal ions by tailoring the coordination mode of V-shaped thienylpyridyl ligand in three MOFs Li-Juan Han,, Wei Yan, Shu-Guang Chen, Zhen-Zhen Shi, and

More information

How to build and race a fast nanocar Synthesis Information

How to build and race a fast nanocar Synthesis Information How to build and race a fast nanocar Synthesis Information Grant Simpson, Victor Garcia-Lopez, Phillip Petemeier, Leonhard Grill*, and James M. Tour*, Department of Physical Chemistry, University of Graz,

More information

Electronic Supplementary Information (ESI)

Electronic Supplementary Information (ESI) Electronic Supplementary Information (ESI) S1 Experimental Section: Materials and methods: All commercially available chemicals were used as supplied without further purification. The Q[5] was synthesized

More information

Electronic Supplementary Information. ligands for efficient organic light-emitting diodes (OLEDs)

Electronic Supplementary Information. ligands for efficient organic light-emitting diodes (OLEDs) Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 27 Electronic Supplementary Information bis-zn II salphen complexes bearing pyridyl functionalized

More information

All materials and reagents were obtained commercially and used without further

All materials and reagents were obtained commercially and used without further Reversible shrinkage and expansion of a blue photofluorescene cadmium coordination polymer and in situ tetrazole ligand synthesis Hong Deng,* a Yong-Cai Qiu, a Ying-Hua Li, a Zhi-Hui liu, a Rong-Hua Zeng,

More information

Tetrahydrofuran (THF) was distilled from benzophenone ketyl radical under an argon

Tetrahydrofuran (THF) was distilled from benzophenone ketyl radical under an argon SUPPLEMENTARY METHODS Solvents, reagents and synthetic procedures All reactions were carried out under an argon atmosphere unless otherwise specified. Tetrahydrofuran (THF) was distilled from benzophenone

More information

Maksim A. Kolosov*, Olesia G. Kulyk, Elena G. Shvets, Valeriy D. Orlov

Maksim A. Kolosov*, Olesia G. Kulyk, Elena G. Shvets, Valeriy D. Orlov 1 Synthesis of 5-cinnamoyl-3,4-dihydropyrimidine-2(1H)-ones Supplementary Information Maksim A. Kolosov*, lesia G. Kulyk, Elena G. Shvets, Valeriy D. rlov Department of organic chemistry, V.N.Karazin Kharkiv

More information

Supporting Information

Supporting Information Supporting Information Wiley-VCH 2008 69451 Weinheim, Germany Supporting Information Unmasking Representative Structures of TMP-Active Hauser and Turbo Hauser Bases Pablo García-Álvarez, David V. Graham,

More information

Dynamics of Caged Imidazolium Cation Toward Understanding The Order-Disorder Phase Transition and Switchable Dielectric Constant

Dynamics of Caged Imidazolium Cation Toward Understanding The Order-Disorder Phase Transition and Switchable Dielectric Constant Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2015 Electonic Supporting Information Dynamics of Caged Imidazolium Cation Toward Understanding

More information

Electronic Supporting Information

Electronic Supporting Information Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2015 Electronic Supporting Information Nickel as a co-catalyst for photocatalytic hydrogen

More information

SUPPORTING INFORMATION

SUPPORTING INFORMATION SUPPORTING INFORMATION Table of Contents S1 1. General materials and methods S2 2. Syntheses of {Pd 84 } and {Pd 17 } S3-S4 3. MS studies of {Pd 84 }, {Pd 17 } and the two-component reactions S5-S6 4.

More information

Diastereoselectivity in the Staudinger reaction of. pentafluorosulfanylaldimines and ketimines

Diastereoselectivity in the Staudinger reaction of. pentafluorosulfanylaldimines and ketimines Supporting Information for Diastereoselectivity in the Staudinger reaction of pentafluorosulfanylaldimines and ketimines Alexander Penger, Cortney. von ahmann, Alexander S. Filatov and John T. Welch* Address:

More information

Electronic Supporting Information

Electronic Supporting Information Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2014 Electronic Supporting Information

More information

3-Bromomethyl pyridine

3-Bromomethyl pyridine M 3 L 2 metallo-cryptophanes: [2]catenane and simple cages James J. Henkelis, Tanya K. Ronson, Lindsay P. Harding and Michaele J. Hardie Supplementary Material Synthesis Chemicals were obtained from commercial

More information

Supplementary Information

Supplementary Information Supplementary Information Luminescence on-off switching via reversible interconversion between inter- and intramolecular aurophilic interactions Semi Han, a Yu Young Yoon, a Ok-Sang Jung b and Young-A

More information

Supporting Information. for. Angew. Chem. Int. Ed. Z Wiley-VCH 2002

Supporting Information. for. Angew. Chem. Int. Ed. Z Wiley-VCH 2002 Supporting Information for Angew. Chem. Int. Ed. Z19663 Wiley-VCH 2002 69451 Weinheim, Germany Selective Measurements of a itroxide-itroxide Distance of 5 nm and a itroxide-copper distance of 2.5 nm in

More information

Stoichiometric Reductions of Alkyl-Substituted Ketones and Aldehydes to Borinic Esters Lauren E. Longobardi, Connie Tang, and Douglas W.

Stoichiometric Reductions of Alkyl-Substituted Ketones and Aldehydes to Borinic Esters Lauren E. Longobardi, Connie Tang, and Douglas W. Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2014 Supplementary Data for: Stoichiometric Reductions of Alkyl-Substituted Ketones and Aldehydes

More information

One-pot Solvent-free Synthesis of Sodium Benzoate from the Oxidation of Benzyl Alcohol over Novel Efficient AuAg/TiO 2 Catalysts

One-pot Solvent-free Synthesis of Sodium Benzoate from the Oxidation of Benzyl Alcohol over Novel Efficient AuAg/TiO 2 Catalysts Electronic Supplementary Information One-pot Solvent-free Synthesis of Sodium Benzoate from the Oxidation of Benzyl Alcohol over Novel Efficient AuAg/TiO 2 Catalysts Ying Wang, Jia-Min Zheng, Kangnian

More information

A Novel Polytriazole-based Organogel Formed by the Effects. of Copper Ions

A Novel Polytriazole-based Organogel Formed by the Effects. of Copper Ions Supporting Information for A Novel Polytriazole-based Organogel Formed by the Effects of Copper Ions Key Laboratory for Specially Functional Polymeric Materials and Related Technology of the Ministry of

More information

Electronic Supplementary Information

Electronic Supplementary Information Electronic Supplementary Information Early-Late Heterobimetallic Rh-Ti and Rh-Zr Complexes via Addition of Early Metal Chlorides to Mono- and Divalent Rhodium Dan A. Smith and Oleg V. Ozerov* Department

More information

Supporting Information. Rh (III)-Catalyzed Meta-C H Olefination Directed by a Nitrile Template

Supporting Information. Rh (III)-Catalyzed Meta-C H Olefination Directed by a Nitrile Template Supporting Information Rh (III)-Catalyzed Meta-C H Olefination Directed by a Nitrile Template Hua-Jin Xu, Yi Lu, *, Marcus E. Farmer, Huai-Wei Wang, Dan Zhao, Yan-Shang Kang, Wei-Yin Sun, *, Jin-Quan Yu

More information

Supplementary Information

Supplementary Information Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 2015 Supplementary Information Efficient vapor-assisted aging synthesis of functional and high

More information

Electronic Supporting Information

Electronic Supporting Information Electronic Supporting Information Reactions of Tp(NH=CPh 2 )(PPh 3 )Ru Cl with HC CPh in the presence of H 2 O: Insertion/Hydration Products Chih-Jen Cheng, a Hung-Chun Tong, a Yih-Hsing Lo,* b Po-Yo Wang,

More information

Supplementary Information T. Ebert, a A. Wollbrink, b A. Seifert, a R. John, a and S. Spange a

Supplementary Information T. Ebert, a A. Wollbrink, b A. Seifert, a R. John, a and S. Spange a Electronic Supplementary Material (ESI for Polymer Chemistry. This journal is The Royal Society of Chemistry Please do 216 not adjust margins ARTICLE Supplementary Information T. Ebert, a A. Wollbrink,

More information

Synthesis of Trifluoromethylated Naphthoquinones via Copper-Catalyzed. Cascade Trifluoromethylation/Cyclization of. 2-(3-Arylpropioloyl)benzaldehydes

Synthesis of Trifluoromethylated Naphthoquinones via Copper-Catalyzed. Cascade Trifluoromethylation/Cyclization of. 2-(3-Arylpropioloyl)benzaldehydes Supporting Information to Synthesis of Trifluoromethylated Naphthoquinones via Copper-Catalyzed Cascade Trifluoromethylation/Cyclization of 2-(3-Arylpropioloyl)benzaldehydes Yan Zhang*, Dongmei Guo, Shangyi

More information

SYNTHESIS OF A 3-THIOMANNOSIDE

SYNTHESIS OF A 3-THIOMANNOSIDE Supporting Information SYNTHESIS OF A 3-THIOMANNOSIDE María B Comba, Alejandra G Suárez, Ariel M Sarotti, María I Mangione* and Rolando A Spanevello and Enrique D V Giordano Instituto de Química Rosario,

More information

A "turn-on" coumarin-based fluorescent sensor with high selectivity for mercury ions in aqueous media

A turn-on coumarin-based fluorescent sensor with high selectivity for mercury ions in aqueous media A "turn-on" coumarin-based fluorescent sensor with high selectivity for mercury ions in aqueous media Styliani Voutsadaki, George K. Tsikalas, Emmanuel Klontzas, George E. Froudakis, and Haralambos E.

More information

Synthesis of Vinyl Germylenes

Synthesis of Vinyl Germylenes Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Material for Synthesis of Vinyl Germylenes Małgorzata Walewska, Judith Baumgartner,*

More information

Supporting Information

Supporting Information Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2015 Supporting Information Single-Crystal-to-Single-Crystal Transformation of an Anion Exchangeable

More information

Influence of photo-isomerisation on host-guest interaction in poly(azocalix[4]arene)s

Influence of photo-isomerisation on host-guest interaction in poly(azocalix[4]arene)s Electronic Supplementary Information Influence of photo-isomerisation on host-guest interaction in poly(azocalix[4]arene)s Szymon Wiktorowicz, Heikki Tenhu and Vladimir Aseyev *, Department of Chemistry,

More information

ph-responsive Quantum Dots (RQDs) that Combine a Fluorescent Nanoparticle with a ph-sensitive Dye

ph-responsive Quantum Dots (RQDs) that Combine a Fluorescent Nanoparticle with a ph-sensitive Dye Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics. This journal is the Owner Societies 2014 ph-responsive Quantum Dots (RQDs) that Combine a Fluorescent Nanoparticle with

More information

Supporting Information

Supporting Information Supporting Information A strategy toward constructing bifunctionalized MF catalyst: post-synthesized modification of MFs on organic ligands and coordinatively unsaturated metal sites Baiyan Li, Yiming

More information

Electronic Supplementary Information for: agent. Adam J. Plaunt, Kasey J. Clear, and Bradley D. Smith*

Electronic Supplementary Information for: agent. Adam J. Plaunt, Kasey J. Clear, and Bradley D. Smith* Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information for: 19 F NMR indicator displacement assay using synthetic

More information

Supporting Information

Supporting Information Supporting Information Wiley-VCH 2006 69451 Weinheim, Germany Engineering Polymeric Chiral Catalyst Using Hydrogen Bonding and Coordination Interactions Lei Shi, 1,2 Xingwang Wang, 1 Christian A. Sandoval,

More information

SUPPLEMENTARY INFORMATION

SUPPLEMENTARY INFORMATION SUPPLEMENTARY INRMATIN doi:10.1038/nature16185 Improved Synthesis of P-CDP H H H 7 + 1 TH/DM: 9/1 K 2 C 3 / 85 o C 2 days / under N 2 45% H R R 7 P-CDP 2 n A flame dried 20 ml scintillation vial equipped

More information

Exceptional Organic Solvents Uptake by Disulfide linked Polymeric. Networks

Exceptional Organic Solvents Uptake by Disulfide linked Polymeric. Networks Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information Exceptional Organic Solvents Uptake by Disulfide linked

More information

Materials and Instrumentation. Preparation of ferrofluid [1] Preparation of polymer magnetic nanoparticles. Preparation of NHC ligand [2]

Materials and Instrumentation. Preparation of ferrofluid [1] Preparation of polymer magnetic nanoparticles. Preparation of NHC ligand [2] Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 204 Materials and Instrumentation. All the reagents and solvents were purchased from Sinopharm

More information

Highly Efficient Chemoselective N-TBS Protection of Anilines under Exceptional Mild Conditions in the Eco-Friendly Solvent 2- Methyltetrahydrofuran.

Highly Efficient Chemoselective N-TBS Protection of Anilines under Exceptional Mild Conditions in the Eco-Friendly Solvent 2- Methyltetrahydrofuran. Supporting Information For Highly Efficient Chemoselective N-TBS Protection of Anilines under Exceptional Mild Conditions in the Eco-Friendly Solvent 2- Methyltetrahydrofuran. Vittorio Pace, *a,b Andrés

More information

How does A Tiny Terminal Alkynyl End Group Drive Fully Hydrophilic. Homopolymers to Self-Assemble into Multicompartment Vesicles and

How does A Tiny Terminal Alkynyl End Group Drive Fully Hydrophilic. Homopolymers to Self-Assemble into Multicompartment Vesicles and Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 04 Electronic Supplementary Information for How does A Tiny Terminal Alkynyl End Group Drive

More information

Electronic Supplementary Information

Electronic Supplementary Information Electronic Supplementary Information 1. Reagents All the L-amino acids and L-glutathione (reduced form) were purchased from Sangon Biotch. o. (Shanghai, hina); Methyl orange, potassium tetrachloropalladate(ii),

More information

NTCDA-TTF First Axial Fusion: Emergent Panchromatic, NIR Optical, Multi-state Redox and High Optical Contrast Photooxidation

NTCDA-TTF First Axial Fusion: Emergent Panchromatic, NIR Optical, Multi-state Redox and High Optical Contrast Photooxidation NTCDA-TTF First Axial Fusion: Emergent Panchromatic, NIR Optical, Multi-state Redox and High Optical Contrast Photooxidation Deepak Asthana, a M. R. Ajayakumar, a Rajendra Prasad Pant b and Pritam Mukhopadhyay*

More information

Electronic Supplementary Information. A novel generation of hybrid photochromic. through fine-tuning of surface chemistry

Electronic Supplementary Information. A novel generation of hybrid photochromic. through fine-tuning of surface chemistry Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information A novel generation of hybrid photochromic vinylidene-naphthofuran

More information

An insulin-sensing sugar-based fluorescent hydrogel

An insulin-sensing sugar-based fluorescent hydrogel Supplementary Information An insulin-sensing sugar-based fluorescent hydrogel Sankarprasad Bhuniya and Byeang yean Kim* ational Research Laboratory, Department of Chemistry, Division of Molecular and Life

More information

Supplementary Information. Mapping the Transmission Function of Single-Molecule Junctions

Supplementary Information. Mapping the Transmission Function of Single-Molecule Junctions upplementary Information Mapping the Transmission Function of ingle-molecule Junctions Brian Capozzi 1, Jonathan Z. Low 2, Jianlong Xia 3, Zhen-Fei Liu 4, Jeffrey B. Neaton 5,6, Luis M. Campos 2, Latha

More information

Electronic Supplementary Information

Electronic Supplementary Information Electronic Supplementary Information Synthesis of borasiloxane-based macrocycles by multicomponent condensation reactions in solution or in a ball mill Mirela Pascu, Albert Ruggi, Rosario Scopelliti, and

More information

Synthesis and characterization of amino-functionalized Poly(propylene carbonate)

Synthesis and characterization of amino-functionalized Poly(propylene carbonate) Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Supplementary Information Synthesis and characterization of amino-functionalized Poly(propylene

More information

Supplementary Information

Supplementary Information Supplementary Information (1) Synthesis and Characterization Figure S1. 1 H-NMR of 3 (400 MHz; CDCl3; rt). Figure S2. 13 C-NMR of 3 (100 MHz; CDCl3; rt). S2 8000 7500 7000 6500 6000 5500 5000 4500 4000

More information

Supporting Information. Silylated Organometals: A Family of Recyclable. Homogeneous Catalysts

Supporting Information. Silylated Organometals: A Family of Recyclable. Homogeneous Catalysts Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 14 Supporting Information lylated rganometals: A Family of Recyclable Homogeneous Catalysts Jian-Lin

More information

Electronic Supplementary Information

Electronic Supplementary Information Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2014 pk a Modulation in Rhodamine Based Probes for Colorimetric Detection of

More information

Electronic Supplementary Material. Methods. Synthesis of reference samples in Figure 1(b) Nano Res.

Electronic Supplementary Material. Methods. Synthesis of reference samples in Figure 1(b) Nano Res. Electronic Supplementary Material Shaped Pt Ni nanocrystals with an ultrathin Pt-enriched shell derived from one-pot hydrothermal synthesis as active electrocatalysts for oxygen reduction Jun Gu 1,, Guangxu

More information

A selenium-contained aggregation-induced turn-on fluorescent probe for hydrogen peroxide

A selenium-contained aggregation-induced turn-on fluorescent probe for hydrogen peroxide Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information (ESI) A selenium-contained aggregation-induced

More information

Efficient Mono- and Bis-Functionalization of 3,6-Dichloropyridazine using (tmp) 2 Zn 2MgCl 2 2LiCl ** Stefan H. Wunderlich and Paul Knochel*

Efficient Mono- and Bis-Functionalization of 3,6-Dichloropyridazine using (tmp) 2 Zn 2MgCl 2 2LiCl ** Stefan H. Wunderlich and Paul Knochel* Efficient Mono- and Bis-Functionalization of 3,6-Dichloropyridazine using (tmp) 2 Zn 2Mg 2 2Li ** Stefan H. Wunderlich and Paul Knochel* Ludwig Maximilians-Universität München, Department Chemie & Biochemie

More information

Supporting information for Eddaoudi et al. (2002) Proc. Natl. Acad. Sci. USA 99 (8), ( /pnas ) Supporting Information

Supporting information for Eddaoudi et al. (2002) Proc. Natl. Acad. Sci. USA 99 (8), ( /pnas ) Supporting Information Supporting information for Eddaoudi et al. (2002) Proc. Natl. Acad. Sci. USA 99 (8), 4900 4904. (10.1073/pnas.082051899) Supporting Information Table 1. Syntheses of MOF-102 112 MOFn MOF- 102 Link and

More information

Facile Synthesis and Catalytic Properties of CeO 2 with Tunable Morphologies from Thermal Transformation of Cerium Benzendicarboxylate Complexes

Facile Synthesis and Catalytic Properties of CeO 2 with Tunable Morphologies from Thermal Transformation of Cerium Benzendicarboxylate Complexes Electronic Supplementary Information Facile Synthesis and Catalytic Properties of CeO 2 with Tunable Morphologies from Thermal Transformation of Cerium Benzendicarboxylate Complexes Yuhua Zheng, Kai Liu,

More information

Experiment 3. Condensation Reactions of Ketones and Aldehydes: The Aldol Condensation Reaction.

Experiment 3. Condensation Reactions of Ketones and Aldehydes: The Aldol Condensation Reaction. Experiment 3. Condensation Reactions of Ketones and Aldehydes: The Aldol Condensation Reaction. References: Brown & Foote, Chapters 16, 19, 23 INTRODUCTION: This experiment continues the saga of carbon-carbon

More information

Anion binding vs. sulfonamide deprotonation in functionalised ureas

Anion binding vs. sulfonamide deprotonation in functionalised ureas S Anion binding vs. sulfonamide deprotonation in functionalised ureas Claudia Caltagirone, Gareth W. Bates, Philip A. Gale* and Mark E. Light Supplementary information Experimental Section General remarks:

More information

Synthesis of borinic acids and borinate adducts using diisopropylaminoborane

Synthesis of borinic acids and borinate adducts using diisopropylaminoborane Synthesis of borinic acids and borinate adducts using diisopropylaminoborane Ludovic Marciasini, Bastien Cacciuttolo, Michel Vaultier and Mathieu Pucheault* Institut des Sciences Moléculaires, UMR 5255,

More information

GRIGNARD REACTION Synthesis of Benzoic Acid

GRIGNARD REACTION Synthesis of Benzoic Acid 1 GRIGNARD REACTION Synthesis of Benzoic Acid In the 1920 s, the first survey of the acceleration of chemical transformations by ultrasound was published. Since then, many more applications of ultrasound

More information

Modified Yamaguchi Reagent : Convenient and Efficient. Esterification

Modified Yamaguchi Reagent : Convenient and Efficient. Esterification Modified Yamaguchi Reagent : Convenient and Efficient Esterification Yoshinori Okuno*, Shigeki Isomura, Akihiro Nishibayashi, Aiko Hosoi, Kei Fukuyama, Masashi Ohba, Kazuyoshi Takeda Yokohama College of

More information

Carbonylative Coupling of Allylic Acetates with. Arylboronic Acids

Carbonylative Coupling of Allylic Acetates with. Arylboronic Acids Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Carbonylative Coupling of Allylic Acetates with Arylboronic Acids Wei Ma, a Ting Yu, Dong Xue,*

More information

Chapter IV. Secondary Ammonium Salts

Chapter IV. Secondary Ammonium Salts Chapter IV Secondary Ammonium Salts IV.1. Introduction Several secondary ammonium salts with hexafluorophosphate counterions were synthesized. To study the complexation behavior of these salts in solution

More information

Electronic Supplementary Information. Jiani Wang, Lei Zhang, Qiong Qi, Shunhua Li* and Yunbao Jiang

Electronic Supplementary Information. Jiani Wang, Lei Zhang, Qiong Qi, Shunhua Li* and Yunbao Jiang Electronic Supplementary Information Specific ratiometric fluorescent sensing of Hg 2+ via the formation of mercury(ii) barbiturate coordination polymers Jiani Wang, Lei Zhang, Qiong Qi, Shunhua Li* and

More information

Adsorption of Cd(II) ions by synthesize chitosan from fish shells

Adsorption of Cd(II) ions by synthesize chitosan from fish shells British Journal of Science 33 Adsorption of Cd(II) ions by synthesize chitosan from fish shells Angham G. Hadi Babylon University, College of Science, Chemistry Department. Abstract One of the major applications

More information

Simple and Versatile Synthesis of Copper and Silver N-Heterocyclic Carbene Complexes in Water or Organic Solvents

Simple and Versatile Synthesis of Copper and Silver N-Heterocyclic Carbene Complexes in Water or Organic Solvents Supporting Information for Simple and Versatile Synthesis of Copper and Silver -Heterocyclic Carbene Complexes in Water or Organic Solvents Cécilia A. Citadelle, Erwan Le ouy, Fabrice Bisaro, Alexandra

More information

Critical role of surface hydration on the dynamics of serum adsorption studied with monoethylene glycol adlayers on gold

Critical role of surface hydration on the dynamics of serum adsorption studied with monoethylene glycol adlayers on gold SUPPORTING INFORMATION Critical role of surface hydration on the dynamics of serum adsorption studied with monoethylene glycol adlayers on gold Ceren Avci, a Sonia Sheikh, b Christophe Blaszykowski b and

More information

Experiment : Reduction of Ethyl Acetoacetate

Experiment : Reduction of Ethyl Acetoacetate Experiment 7-2007: eduction of Ethyl Acetoacetate EXPEIMENT 7: eduction of Carbonyl Compounds: Achiral and Chiral eduction elevant sections in the text: Fox & Whitesell, 3 rd Ed. Chapter 12, pg.572-584.

More information

Ordnung muss sein: heteroelement order and disorder in polyoxovanadates

Ordnung muss sein: heteroelement order and disorder in polyoxovanadates Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2018 Ordnung muss sein: heteroelement order and disorder in polyoxovanadates M. Wendt a,

More information

Soluble Precursor of Hexacene and its Application on Thin Film Transistor

Soluble Precursor of Hexacene and its Application on Thin Film Transistor Soluble Precursor of Hexacene and its Application on Thin Film Transistor Supplementary Information Motonori Watanabe, a Wei-Ting Su, b Kew-Yu Chen,* c Ching-Ting Chien, a Ting-Han Chao, a Yuan Jay Chang,

More information

Supporting Information:

Supporting Information: Supporting Information: In Situ Synthesis of Magnetically Recyclable Graphene Supported Pd@Co Core-Shell Nanoparticles as Efficient Catalysts for Hydrolytic Dehydrogenation of Ammonia Borane Jun Wang,

More information

A TPE-oxazoline molecular switch with tunable multi-emission in. both solution and solid state

A TPE-oxazoline molecular switch with tunable multi-emission in. both solution and solid state Electronic Supplementary Information (ESI) A TPE-oxazoline molecular switch with tunable multi-emission in both solution and solid state Qingkai Qi a, Xiaofeng Fang b, Yifei Liu* b, Peng Zhou b, Yumo Zhang

More information

Responsive supramolecular polymer formed by orthogonal metal-coordination and cryptand-based host guest interaction

Responsive supramolecular polymer formed by orthogonal metal-coordination and cryptand-based host guest interaction Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Responsive supramolecular polymer formed by orthogonal metal-coordination and cryptand-based host

More information

Supporting Information for. An Approach to Tetraphenylenes via Pd-Catalyzed C H Functionalization

Supporting Information for. An Approach to Tetraphenylenes via Pd-Catalyzed C H Functionalization Supporting Information for An Approach to Tetraphenylenes via Pd-Catalyzed C H Functionalization Hang Jiang, Yu Zhang, Dushen Chen, Bo Zhou, and Yanghui Zhang * Department of Chemistry, and Shanghai Key

More information

Preparation of an unsymmetrically substituted push-pulltriphenodioxazine

Preparation of an unsymmetrically substituted push-pulltriphenodioxazine Preparation of an unsymmetrically substituted push-pulltriphenodioxazine Dietrich Döpp* and Stefan Neubauer Organische Chemie, Fakultät 4, Gerhard-Mercator-Universität Duisburg, Lotharstr. 1, D-47057 Duisburg,

More information

Electronic Supplementary Information

Electronic Supplementary Information Electronic Supplementary Information Facile synthesis of halogenated carbon quantum dots as an important intermediate for surface modification Jin Zhou, Pei Lin, Juanjuan Ma, Xiaoyue Shan, Hui Feng, Congcong

More information

Supplemental Information. Point-of-Use Detection of Amphetamine-Type. Stimulants with Host-Molecule-Functionalized. Organic Transistors

Supplemental Information. Point-of-Use Detection of Amphetamine-Type. Stimulants with Host-Molecule-Functionalized. Organic Transistors Chem, Volume 3 Supplemental Information Point-of-Use Detection of Amphetamine-Type Stimulants with Host-Molecule-Functionalized Organic Transistors Yoonjung Jang, Moonjeong Jang, Hyoeun Kim, Sang Jin Lee,

More information

Supporting Information. A fully earth-abundant photocatalytic system for the visible-light-driven reduction of CO 2 to CO

Supporting Information. A fully earth-abundant photocatalytic system for the visible-light-driven reduction of CO 2 to CO Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 2017 Supporting Information for A fully earth-abundant photocatalytic system for the visible-light-driven

More information

Supporting Information

Supporting Information Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting Information Au nanoparticles supported on magnetically separable Fe 2 O 3 - graphene

More information

Supporting Information. Corporation, 1-1 Kurosakishiroishi, Yahatanishi-ku, Kitakyushu , Japan

Supporting Information. Corporation, 1-1 Kurosakishiroishi, Yahatanishi-ku, Kitakyushu , Japan Supporting Information Facile Fullerene Modification: FeCl 3 -mediated Quantitative Conversion of C 60 to Polyarylated Fullerenes Containing Pentaaryl(chloro)[60]fullerenes Masahiko Hashiguchi,*,1 Kazuhiro

More information

Electronic Supplementary Information. Selective detection of Al 3+ and citric acid with a fluorescent amphiphile

Electronic Supplementary Information. Selective detection of Al 3+ and citric acid with a fluorescent amphiphile Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information Selective detection of Al 3+ and citric

More information

Tsuji Trost N-Allylation with Allylic Acetates by Using a Cellulose Palladium Catalyst

Tsuji Trost N-Allylation with Allylic Acetates by Using a Cellulose Palladium Catalyst University of Nebraska - Lincoln DigitalCommons@University of Nebraska - Lincoln U.S. Environmental Protection Agency Papers U.S. Environmental Protection Agency 2012 Tsuji Trost N-Allylation with Allylic

More information

Ondansetron Hydrochloride Tablets

Ondansetron Hydrochloride Tablets Ondansetron Hydrochloride Tablets Dissolution Perform the test with 1 tablet of Ondansetron Hydrochloride Tablets at 50 revolutions per minute according to the Paddle method, using 900 ml of water

More information

Influence of anellation in N-heterocyclic carbenes: Detection of novel quinoxalineanellated NHC by trapping as transition metal complexes

Influence of anellation in N-heterocyclic carbenes: Detection of novel quinoxalineanellated NHC by trapping as transition metal complexes Influence of anellation in N-heterocyclic carbenes: Detection of novel quinoxalineanellated NHC by trapping as transition metal complexes Shanmuganathan Saravanakumar, a Markus K. Kindermann, a Joachim

More information

Supporting Information

Supporting Information Supporting Information Catalyst- and solvent-free one-pot synthesis of some novel polyheterocycles from aryldiazenyl salicylaldehyde derivatives Narsidas J. Parmar 1, Rikin A. Patel 1, Shashikant B. Teraiya

More information

Convenient Synthesis of Nucleoside 5 -Triphosphates for RNA Transcription. Supplemental Materials

Convenient Synthesis of Nucleoside 5 -Triphosphates for RNA Transcription. Supplemental Materials Supplementary Material (ESI) for Chemical Communications This journal is The Royal Society of Chemistry 2010 Convenient Synthesis of ucleoside 5 -Triphosphates for RA Transcription Julianne Caton-Williams,

More information

Rational design of a ratiometric fluorescent probe with a large emission shift for the facile detection of Hg 2+

Rational design of a ratiometric fluorescent probe with a large emission shift for the facile detection of Hg 2+ Rational design of a ratiometric fluorescent probe with a large emission shift for the facile detection of Hg 2+ Weimin Xuan, a Chen Chen, b Yanting Cao, a Wenhan He, a Wei Jiang, a Kejian Li, b* and Wei

More information

Supporting Information

Supporting Information Supporting Information Wiley-VCH 2008 69451 Weinheim, Germany An Isolable Side-on Superoxonickel Complex [LNi(O 2 )] with Planar Tetracoordinate Ni II and Its Conversion to the Unusual LNi(μ-OH) 2 NiL

More information

Lab 6 Inorganic Syntheses using Mo catalysts

Lab 6 Inorganic Syntheses using Mo catalysts Lab 6 Inorganic Syntheses using Mo catalysts Literature References 1. Moore, F.W., et. al., "Dialkyldithiocarbamate Complexes of Molybdenum (V) and Molybdenum (VI)", Inorganic Chemistry 1967, 6, 998-1003.

More information

A Closer Look at the Bromine-Lithium Exchange with

A Closer Look at the Bromine-Lithium Exchange with SUPPRTIG IFRMATI A Closer Look at the Bromine-Lithium Exchange with tert-butyllithium in an Aryl Sulfonamide Synthesis Christopher Waldmann,*, tmar Schober, Günter Haufe, and Klaus Kopka, Department of

More information