A Site Location Map and Site and Surrounding Properties Map are attached as Figure 1 and Figure 2, respectively.

Transcription

1 February 23, 216 Mr. Shaun Lehman MDEQ-OOGM Lansing District Office Constitution Hall 2 South 525 West Allegan Street Lansing, MI Re: Groundwater Characterization Work Plan Hartland 36 Gas Plant SE/NE/NW Section 36, T3N-R6E Hartland Township, Livingston County, Michigan Dear Mr. Lehman: This Groundwater Characterization Work Plan (Work Plan) proposes additional groundwater assessment and sampling activities to address the sulfolane contaminant plume identified during facility decommissioning activities at the Hartland 36 Gas Plant (Site). Project Location The Site is located in the SE/NE/NW of Section 36, T3N-R6E, on the south side of Lone Tree Road between North Pleasant Valley Road and South Tipsico Lake Road in Hartland Township, Livingston County, Michigan. The closest surface waters to the Site are a pond located approximately.25 miles west, wetland located approximately 18 feet southwest, 775 feet southeast, and.25 miles northeast, and a sand and gravel pit located approximately.5 miles north-northeast. The closest water supply wells to the Site are located on the north adjacent Dunleavy property. A shallow seasonal well is located approximately 95 feet north of the Site and the residential supply well is located approximately 1,75 feet north of the Site. The well records were not available from the MDEQ GeoWebFace Application. A Site Location Map and Site and Surrounding Properties Map are attached as Figure 1 and Figure 2, respectively Veterans Drive Traverse City, MI (231) FAX (231) Project Background Contaminated soil was discovered in September 215 during facility decommissioning activities at the former sweetening plant/refrigeration building (sulfolane impact) and former inlet compressor building (used oil impact). Remediation activities (excavation) were completed from September 215 through December 215 resulted in disposal of 13,481.4 tons of soil at the Venice Park Landfill in Lennon, Michigan. Excavated areas are depicted on the attached Figure 3 Groundwater Flow & Contaminant Concentration Diagram. Verification of soil remediation (VSR) samples collected from the excavations confirmed remediation of impacted soils. Refer to the Soil Closure Report, dated February 15, 216, for a detailed summary of soil remediation and VSR An Equal Opportunity/Affirmative Action Employer

2 Groundwater Characterization Work Plan Hartland 36 Gas Plant February 23, 216 Page 2 sampling activities. However, sulfolane impacted soils extended to groundwater at the former sweetening plant/refrigeration building. A groundwater sample (W-Pit) collected on October 15, 215 from the excavation reported a concentration of sulfolane at 2, micrograms per liter (µg/l). A copy of the groundwater analytical report is attached. Initial Groundwater Characterization In order to gather characteristics with regard to sulfolane impact in groundwater, personnel from Environmental Consulting & Technology, Inc. (ECT) oversaw the installation of seven monitor wells (MW-1 through MW-7) and one temporary vertical profile monitor well (TMW-6) on October 29-3, 215. The monitor wells were installed by Shepler Well Drilling of Manton, Michigan utilizing a truck mounted drill rig equipped with 4¼-inch ID hollow stem augers (HSAs). The monitor wells (2-inch diameter PVC) were equipped with 5-foot long screens with the top of the screens situated near the groundwater table. Groundwater saturated soils were identified from approximately feet below ground surface (ft bgs), depending on location. TMW-6 was drilled to a depth of approximately 7 ft bgs and groundwater samples were collected from a 2-inch diameter temporary PVC monitor well from 65-7 ft bgs, 55-6 ft bgs, 45-5 ft bgs, and 35-4 ft bgs. Soil boring logs/monitor well construction diagrams will be provided with future submittals. Groundwater samples were collected from MW-1 through MW-7 on November 4-5, 215 and January 27, 216 (no sample from MW-3 on January 27, 216) and from the excavation on November 13, 215 for laboratory analysis of sulfolane by USEPA Method 827D. Groundwater samples from monitor wells were collected via low-stress sampling methods in general accordance with USEPA EQASOP-GW 1 Region 1 Low- Stress (Low-Flow) SOP Revision 3, dated January 19, 21. Groundwater samples were collected and analyzed in general accordance with MDEQ-RRD Operational Memorandum No. 2, dated October 22, 24. Laboratory analytical results reported sulfolane as non-detect from all monitor wells except MW-7, which reported sulfolane concentrations of 88 µg/l from the November 4-5, 215 sampling event and 44 µg/l from the January 27, 216 sampling event. The groundwater sample collected from the excavation reported a sulfolane concentration of 14, µg/l. Copies of groundwater analytical reports are attached. A vertical and horizontal control survey of the monitor wells and excavations was completed by Gourdie-Fraser, Inc. on November 18, 215. Static water levels and topof-casing (TOC) elevations from the monitor wells were utilized to calculate groundwater elevations for use with contouring software. The resulting groundwater flow direction trends to the northeast. It should be noted the groundwater elevation for MW-5 was not consistent with other elevations and was not utilized with the contouring software. The elevation discrepancy for MW-5 could be attributed to a clay layer identified at approximately 23 ft bgs (bottom of monitor well). Groundwater elevation data is included on the attached Table 2 and groundwater flow characteristics are depicted on the attached Figure 3.

3 Groundwater Characterization Work Plan Hartland 36 Gas Plant February 23, 216 Page 3 Groundwater Analytical Summary & Cleanup Criteria Comparison No cleanup criteria for sulfolane have been established via Part 21, Environmental Remediation, of the Natural Resources and Environmental Protection Act (NREPA), Public Act 451 of 1994, as amended (Part 21). As a result, MDEQ-Office of Oil, Gas, and Minerals (MDEQ-OOGM) established cleanup criteria for sulfolane of 9 µg/l. The following presents a summary and comparison of groundwater analytical results to sulfolane cleanup criteria: Although the samples of groundwater from the excavation were not collected in accordance with MDEQ-RRD Operational Memorandum No. 2 (grab samples from an excavation), the concentrations reported for sulfolane exceeded cleanup criteria. The concentration of sulfolane reported for MW-7 from the November 4-5, 215 sampling event exceeded cleanup criteria. Groundwater analytical results are summarized and compared to cleanup criteria on the attached Table 1. Residential Water Supply Well Sampling Water samples from the shallow well (W-1339 Shallow) and residential supply well (W and W-1339 Deep) on the Dunleavy property were collected by personnel from ECT on October 5, 19, and 3, 215. The samples were submitted for laboratory analysis of sulfolane, ethylene glycol, volatile organic compounds (VOCs), and polynuclear aromatic hydrocarbons (PNAs). Laboratory analytical results were reported non-detect for all parameters. Laboratory analytical reports are attached. Additional Groundwater Characterization Activities Additional activities are warranted to further refine the extent of groundwater impacted with sulfolane at the Site. Additional groundwater characterization activities will be completed with temporary monitor wells (TMWs) installed via a direct-push drill rig. Soil samples will be collected continuously from 15 ft bgs to the boring completion depth for visual characterization and classification. TMWs will be constructed of 1-inch diameter PVC equipped with 5-foot long screens generally situated to straddle the groundwater table. Groundwater samples will be collected from the TMWs (immediately following installation) with a peristaltic pump and disposable polyethylene tubing. Subsequent to sample collection, each boring will be abandoned with bentonite. TMWs are proposed as follows: Four TMWs to investigate concentrations of sulfolane reported at MW-7. Three TMWs to gather additional data between the source area and downgradient monitor wells MW-4 and MW-6. One TMW in the source area to accommodate monitoring worst-case contaminant concentrations. In addition, advance a vertical profile boring to an approximate depth of 7 ft bgs. Collect groundwater samples from a 1-inch diameter PVC TMW screened from 65-7 ft bgs, 5-55 ft bgs, and 35-4 ft bgs. The above activities are scheduled for late spring/early summer 216.

4 Groundwater Characterization Work Plan Hartland 36 Gas Plant February 23, 216 Page 4 Subsequent to receipt and review of data from additional groundwater characterization activities, additional permanent monitor wells will be installed, as warranted. The locations and screened intervals of new permanent monitor wells will be dependent upon data from additional groundwater characterization activities. In the event new permanent monitor wells are installed, locations and elevation data will be incorporated into existing data. Groundwater Monitoring Activities Quarterly groundwater monitoring of all monitor wells at the Site will be completed in 216. At a minimum, monitoring will include collecting static water levels and groundwater samples. Groundwater sampling will be completed in accordance with MDEQ-RRD Operational Memorandum No. 2, dated October 22, 24 and USEPA EQASOP-GW 1 Region 1 Low-Stress (Low-Flow) SOP Revision 3, dated January 19, 21. Groundwater samples will be submitted for analysis to a 3 rd party laboratory for sulfolane by USEPA Method 827D. Quarterly Project Status Reporting Data obtained from quarterly groundwater monitoring will be summarized in Quarterly Project Status Reports. At a minimum, the reports will include a narrative summary of activities completed during the quarter, groundwater elevation and analytical summary tables, groundwater flow data, cleanup criteria comparisons, and conclusions and recommendations for project progression. Closing ECT sincerely appreciates the opportunity to provide our consulting services on this important project. Should you have questions or require additional information, please do not hesitate to contact me at your convenience at or jlewandowski@ectinc.com. Sincerely, ENVIRONMENTAL CONSULTING & TECHNOLOGY, INC. Jeremy S. Lewandowski Senior Engineer CC: Sean Craven Merit Energy Company Attachments: Figure 1 Site Location Map Figure 2 Site and Surrounding Properties Map Figure 3 Groundwater Flow & Contaminant Concentration Diagram Table 1 Sulfolane Analytical Summary & Cleanup Criteria Comparison Table 2 Groundwater Elevation Data Laboratory Analytical Reports

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8 TABLE 1 SULFOLANE ANALYTICAL SUMMARY & CLEANUP CRITERIA COMPARISON Hartland 36 Gas Plant SE/NE/NW Section 36, T3N-R6E, Hartland Township, Livingston County, Michigan ECT Project # Sample Location W-Pit MW-1 MW-2 MW-3 MW-4 MW-5 MW-6 MW-7 Screened Interval (ft bgs) Collection Method Grab LF LF LF LF LF LF LF Date Sulfolane by EPA Method 827D (µg/l) 1/15/215 2, /4-5/ nd nd nd nd nd nd 88 11/13/215 14, /27/ nd nd --- nd nd nd 44 MDEQ-OOGM Cleanup Criteria 9 Notes 1) ft/bgs - Feet below ground surface. 2) Collection method - Grab, low flow (LF), Bailer. 3) µg/l - Micrograms per liter, equivalent to parts per billion (ppb). 4) (---) - Not sampled. 5) nd - Concentration not detected above reporting limit. 6) Cleanup criteria for sulfolane established by MDEQ-Office of Oil, Gas, and Minerals (MDEQ-OOGM). 7) Concentrations that are shaded and bold exceed cleanup criteria. Page 1 of 1

9 TABLE 2 GROUWATER ELEVATION DATA Hartland 36 Gas Plant SE/NE/NW Section 36, T3N-R6E, Hartland Township, Livingston County, Michigan ECT Project # /3/215 TOC GROU STATIC STATIC GROUWATER WELL WELL SCREENED ELEVATION ELEVATION WATER LEVEL WATER LEVEL ELEVATION DEPTH DEPTH INTERVAL LOCATION NORTHING EASTING (FT) (FT) (FT BTOC) (FT BGS) (FT) (FT BTOC) (FT BGS) (FT BGS) MW MW MW MW /4/215 TOC GROU STATIC STATIC GROUWATER WELL WELL SCREENED ELEVATION ELEVATION WATER LEVEL WATER LEVEL ELEVATION DEPTH DEPTH INTERVAL LOCATION NORTHING EASTING (FT) (FT) (FT BTOC) (FT BGS) (FT) (FT BTOC) (FT BGS) (FT BGS) MW MW MW MW MW MW MW /13/215 TOC GROU STATIC STATIC GROUWATER WELL WELL SCREENED ELEVATION ELEVATION WATER LEVEL WATER LEVEL ELEVATION DEPTH DEPTH INTERVAL LOCATION NORTHING EASTING (FT) (FT) (FT BTOC) (FT BGS) (FT) (FT BTOC) (FT BGS) (FT BGS) MW MW MW MW MW MW MW /27/216 TOC GROU STATIC STATIC GROUWATER WELL WELL SCREENED ELEVATION ELEVATION WATER LEVEL WATER LEVEL ELEVATION DEPTH DEPTH INTERVAL LOCATION NORTHING EASTING (FT) (FT) (FT BTOC) (FT BGS) (FT) (FT BTOC) (FT BGS) (FT BGS) MW MW MW MW MW MW MW Page 1 of 1

10 ALS Group USA, Corp Date: 8-Oct-15 Client: Merit Energy Work Order: Sample ID: W Lab ID: Collection Date: 1/5/215 2:25 PM Matrix: WATER Analyses Result Qual Report Dilution Limit Units Factor Date Analyzed SEMI-VOLATILE ORGANIC COMPOUS SW D Prep: SW351 / 1/6/15 Analyst: RM Sulfolane 1 µg/l 1 1/6/215 6:6 PM Surr: 2,4,6-Tribromophenol %REC 1 1/6/215 6:6 PM Surr: 2-Fluorobiphenyl %REC 1 1/6/215 6:6 PM Surr: 2-Fluorophenol %REC 1 1/6/215 6:6 PM Surr: 4-Terphenyl-d %REC 1 1/6/215 6:6 PM Surr: Nitrobenzene-d %REC 1 1/6/215 6:6 PM Surr: Phenol-d %REC 1 1/6/215 6:6 PM See Qualifiers page for a list of qualifiers and their definitions. Analytical Results Page 18 of 18

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12 ALS Group USA, Corp Date: 24-Oct-15 Client: Merit Energy Work Order: Sample ID: W-Pit Lab ID: Collection Date: 1/15/215 6:1 PM Matrix: GROUWATER Analyses Result Qual Report Dilution Limit Units Factor Date Analyzed SEMI-VOLATILE ORGANIC COMPOUS SW D Prep: SW351 / 1/2/15 Analyst: RM Sulfolane 2, 5 µg/l 5 1/21/215 4:51 PM Surr: 2,4,6-Tribromophenol 125 S %REC 5 1/21/215 4:51 PM Surr: 2-Fluorobiphenyl %REC 5 1/21/215 4:51 PM Surr: 2-Fluorophenol 75. S %REC 5 1/21/215 4:51 PM Surr: 4-Terphenyl-d %REC 5 1/21/215 4:51 PM Surr: Nitrobenzene-d %REC 5 1/21/215 4:51 PM Surr: Phenol-d6 119 S %REC 5 1/21/215 4:51 PM See Qualifiers page for a list of qualifiers and their definitions. Analytical Results Page 26 of 26

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14 3-Oct-215 Sean Craven Merit Energy 151 Thomas Rd PO Box 91 Kalkaska, MI Re: Hartland Gas Plant Work Order: Dear Sean, ALS Environmental received 1 sample on 2-Oct-215 1: AM for the analyses presented in the following report. The analytical data provided relates directly to the samples received by ALS Environmental and for only the analyses requested. Sample results are compliant with NELAP standard requirements and QC results achieved laboratory specifications. Any exceptions are noted in the Case Narrative, or noted with qualifiers in the report or QC batch information. Should this laboratory report need to be reproduced, it should be reproduced in full unless written approval has been obtained from ALS Environmental. Samples will be disposed in 3 days unless storage arrangements are made. The total number of pages in this report is 22. If you have any questions regarding this report, please feel free to contact me. Sincerely, Gary Byar Electronically approved by: Gary Byar Gary Byar Project Manager Certificate No: MI: 22 Report of Laboratory Analysis ADDRESS th Avenue Holland, Michigan PHONE (616) FAX (616) ALS GROUP USA, CORP Part of the ALS Laboratory Group A Campbell Brothers Limited Company

15 ALS Group USA, Corp Date: 3-Oct-15 Client: Merit Energy Work Order: Work Order Sample Summary Lab Samp ID Client Sample ID Matrix Tag Number Collection Date Date Received W-1339 Deep Water 1/19/215 9:3 1/2/215 1: Hold Sample Summary Page 1 of 1

16 ALS Group USA, Corp Date: 3-Oct-15 Client: Merit Energy Work Order: Sample ID: W-1339 Deep Lab ID: Collection Date: 1/19/215 9:3 AM Matrix: WATER Analyses Result Qual Report Dilution Limit Units Factor Date Analyzed ORGANIC COMPOUS BY GC-FID SW815M Analyst: KYM Ethylene glycol 5. mg/l 1 1/21/215 12:41 PM SEMI-VOLATILE ORGANIC COMPOUS SW D Prep: SW351 / 1/23/15 Analyst: RS 2-Methylnaphthalene 5. µg/l 1 1/23/215 9:12 PM Acenaphthene 5. µg/l 1 1/23/215 9:12 PM Acenaphthylene 5. µg/l 1 1/23/215 9:12 PM Anthracene 5. µg/l 1 1/23/215 9:12 PM Benzo(a)anthracene 5. µg/l 1 1/23/215 9:12 PM Benzo(a)pyrene 5. µg/l 1 1/23/215 9:12 PM Benzo(b)fluoranthene 5. µg/l 1 1/23/215 9:12 PM Benzo(g,h,i)perylene 5. µg/l 1 1/23/215 9:12 PM Benzo(k)fluoranthene 5. µg/l 1 1/23/215 9:12 PM Chrysene 5. µg/l 1 1/23/215 9:12 PM Dibenzo(a,h)anthracene 5. µg/l 1 1/23/215 9:12 PM Fluoranthene 5. µg/l 1 1/23/215 9:12 PM Fluorene 5. µg/l 1 1/23/215 9:12 PM Indeno(1,2,3-cd)pyrene 5. µg/l 1 1/23/215 9:12 PM Naphthalene 5. µg/l 1 1/23/215 9:12 PM Phenanthrene 5. µg/l 1 1/23/215 9:12 PM Pyrene 5. µg/l 1 1/23/215 9:12 PM Surr: 2,4,6-Tribromophenol %REC 1 1/23/215 9:12 PM Surr: 2-Fluorobiphenyl %REC 1 1/23/215 9:12 PM Surr: 2-Fluorophenol %REC 1 1/23/215 9:12 PM Surr: 4-Terphenyl-d %REC 1 1/23/215 9:12 PM Surr: Nitrobenzene-d %REC 1 1/23/215 9:12 PM Surr: Phenol-d %REC 1 1/23/215 9:12 PM VOLATILE ORGANIC COMPOUS SW826B Analyst: AK 1,1,1,2-Tetrachloroethane 1. µg/l 1 1/29/215 7:1 PM 1,1,1-Trichloroethane 1. µg/l 1 1/29/215 7:1 PM 1,1,2,2-Tetrachloroethane 1. µg/l 1 1/29/215 7:1 PM 1,1,2-Trichloroethane 1. µg/l 1 1/29/215 7:1 PM 1,1,2-Trichlorotrifluoroethane 1. µg/l 1 1/29/215 7:1 PM 1,1-Dichloroethane 1. µg/l 1 1/29/215 7:1 PM 1,1-Dichloroethene 1. µg/l 1 1/29/215 7:1 PM 1,2,3-Trichloropropane 1. µg/l 1 1/29/215 7:1 PM 1,2,4-Trichlorobenzene 1. µg/l 1 1/29/215 7:1 PM 1,2,4-Trimethylbenzene 1. µg/l 1 1/29/215 7:1 PM 1,2-Dibromo-3-chloropropane 1. µg/l 1 1/29/215 7:1 PM 1,2-Dibromoethane 1. µg/l 1 1/29/215 7:1 PM See Qualifiers page for a list of qualifiers and their definitions. Analytical Results Page 1 of 3

17 ALS Group USA, Corp Date: 3-Oct-15 Client: Merit Energy Work Order: Sample ID: W-1339 Deep Lab ID: Collection Date: 1/19/215 9:3 AM Matrix: WATER Analyses Result Qual Report Dilution Limit Units Factor Date Analyzed 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,3,5-Trimethylbenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 2-Butanone 2-Hexanone 2-Methylnaphthalene 4-Methyl-2-pentanone Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-dichloroethene cis-1,3-dichloropropene Dibromochloromethane Dibromomethane Dichlorodifluoromethane Diethyl ether Ethylbenzene Hexachloroethane Isopropylbenzene m,p-xylene Methyl iodide Methyl tert-butyl ether Methylene chloride Naphthalene n-propylbenzene o-xylene Styrene 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 5. µg/l 1 5. µg/l 1 5. µg/l 1 1. µg/l 1 1 µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 2. µg/l 1 1. µg/l 1 1. µg/l 1 5. µg/l 1 5. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM See Qualifiers page for a list of qualifiers and their definitions. Analytical Results Page 2 of 3

18 ALS Group USA, Corp Date: 3-Oct-15 Client: Merit Energy Work Order: Sample ID: W-1339 Deep Lab ID: Collection Date: 1/19/215 9:3 AM Matrix: WATER Analyses Result Qual Report Dilution Limit Units Factor Date Analyzed Tetrachloroethene Toluene trans-1,2-dichloroethene trans-1,3-dichloropropene trans-1,4-dichloro-2-butene Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylenes, Total Surr: 1,2-Dichloroethane-d4 Surr: 4-Bromofluorobenzene Surr: Dibromofluoromethane Surr: Toluene-d µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 2. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 3. µg/l %REC %REC %REC %REC 1 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM 1/29/215 7:1 PM See Qualifiers page for a list of qualifiers and their definitions. Analytical Results Page 3 of 3

19 ALS Group USA, Corp Client: Merit Energy Work Order: Date: 3-Oct-15 Case Narrative Batch R174943A The MS/MSD data for volatiles is not related tot his project's samples. No data requires qualification. Case Narrative Page 1 of 1

20 ALS Group USA, Corp Client: Merit Energy Work Order: Date: 3-Oct-15 QC BATCH REPORT Batch ID: R Instrument ID: GC11 Method: SW815M MBLK Sample ID: MB-R R Units: mg/l Client ID: Run ID: GC11_15121A SeqNo: Analysis Date: 1/21/215 11:1 A Prep Date: 1/21/215 DF: 1 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD Ethylene glycol 5. RPD Limit Qual LCS Sample ID: LCS-R R Units: mg/l Client ID: Run ID: GC11_15121A SeqNo: Analysis Date: 1/21/215 1:7 A Prep Date: 1/21/215 DF: 1 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD RPD Limit Qual Ethylene glycol MS Sample ID: A MS Units: mg/l Client ID: Run ID: GC11_15121A SeqNo: Analysis Date: 1/21/215 1:16 A Prep Date: 1/21/215 DF: 2 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD RPD Limit Qual Ethylene glycol MSD Sample ID: A MSD Units: mg/l Client ID: Run ID: GC11_15121A SeqNo: Analysis Date: 1/21/215 1:25 A Prep Date: 1/21/215 DF: 2 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD RPD Limit Qual Ethylene glycol The following samples were analyzed in this batch: A See Qualifiers Page for a list of Qualifiers and their explanation. QC Page: 1 of 13

21 Client: Merit Energy Work Order: QC BATCH REPORT Batch ID: Instrument ID: SVMS8 Method: SW D MBLK Sample ID: SBLKW Units: µg/l Client ID: Run ID: SVMS8_15123A SeqNo: Analysis Date: 1/23/215 3:37 P Prep Date: 1/23/215 DF: 1 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD RPD Limit Qual 2-Methylnaphthalene 5. Acenaphthene 5. Acenaphthylene 5. Anthracene 5. Benzo(a)anthracene 5. Benzo(a)pyrene 5. Benzo(b)fluoranthene 5. Benzo(g,h,i)perylene 5. Benzo(k)fluoranthene 5. Chrysene 5. Dibenzo(a,h)anthracene 5. Fluoranthene 5. Fluorene 5. Indeno(1,2,3-cd)pyrene 5. Naphthalene 5. Phenanthrene 5. Pyrene 5. Surr: 2,4,6-Tribromophenol Surr: 2-Fluorobiphenyl Surr: 2-Fluorophenol Surr: 4-Terphenyl-d Surr: Nitrobenzene-d Surr: Phenol-d See Qualifiers Page for a list of Qualifiers and their explanation. QC Page: 2 of 13

22 Client: Merit Energy Work Order: QC BATCH REPORT Batch ID: Instrument ID: SVMS8 Method: SW D LCS Sample ID: SLCSW Units: µg/l Client ID: Run ID: SVMS8_15123A SeqNo: Analysis Date: 1/23/215 3:57 P Prep Date: 1/23/215 DF: 1 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD RPD Limit Qual 2-Methylnaphthalene Acenaphthene Acenaphthylene Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Chrysene Dibenzo(a,h)anthracene Fluoranthene Fluorene Indeno(1,2,3-cd)pyrene Naphthalene Phenanthrene Pyrene Surr: 2,4,6-Tribromophenol Surr: 2-Fluorobiphenyl Surr: 2-Fluorophenol Surr: 4-Terphenyl-d Surr: Nitrobenzene-d Surr: Phenol-d See Qualifiers Page for a list of Qualifiers and their explanation. QC Page: 3 of 13

23 Client: Merit Energy Work Order: QC BATCH REPORT Batch ID: Instrument ID: SVMS8 Method: SW D MS Sample ID: B MS Units: µg/l Client ID: Run ID: SVMS8_15123A SeqNo: Analysis Date: 1/23/215 5:36 P Prep Date: 1/23/215 DF: 1 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD RPD Limit Qual 2-Methylnaphthalene Acenaphthene Acenaphthylene Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Chrysene Dibenzo(a,h)anthracene Fluoranthene Fluorene Indeno(1,2,3-cd)pyrene Naphthalene Phenanthrene Pyrene Surr: 2,4,6-Tribromophenol Surr: 2-Fluorobiphenyl Surr: 2-Fluorophenol Surr: 4-Terphenyl-d Surr: Nitrobenzene-d Surr: Phenol-d See Qualifiers Page for a list of Qualifiers and their explanation. QC Page: 4 of 13

24 Client: Merit Energy Work Order: QC BATCH REPORT Batch ID: Instrument ID: SVMS8 Method: SW D DUP Sample ID: B DUP Units: µg/l Client ID: Run ID: SVMS8_15123A SeqNo: Analysis Date: 1/23/215 6:15 P Prep Date: 1/23/215 DF: 1 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD RPD Limit Qual 2-Methylnaphthalene Acenaphthene Acenaphthylene Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Chrysene Dibenzo(a,h)anthracene Fluoranthene Fluorene Indeno(1,2,3-cd)pyrene Naphthalene Phenanthrene Pyrene Surr: 2,4,6-Tribromophenol Surr: 2-Fluorobiphenyl Surr: 2-Fluorophenol Surr: 4-Terphenyl-d Surr: Nitrobenzene-d Surr: Phenol-d The following samples were analyzed in this batch: B See Qualifiers Page for a list of Qualifiers and their explanation. QC Page: 5 of 13

25 Client: Merit Energy Work Order: QC BATCH REPORT Batch ID: R174943A Instrument ID: VMS8 Method: SW826B MBLK Sample ID: VBLKW R174943A Units: µg/l Client ID: Run ID: VMS8_15129A SeqNo: Prep Date: Analysis Date: 1/29/215 12:12 P DF: 1 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD 1,1,1,2-Tetrachloroethane 1. 1,1,1-Trichloroethane 1. 1,1,2,2-Tetrachloroethane 1. 1,1,2-Trichloroethane 1. 1,1,2-Trichlorotrifluoroethane 1. 1,1-Dichloroethane 1. 1,1-Dichloroethene 1. 1,2,3-Trichloropropane 1. 1,2,4-Trichlorobenzene 1. 1,2,4-Trimethylbenzene 1. 1,2-Dibromo-3-chloropropane 1. 1,2-Dibromoethane 1. 1,2-Dichlorobenzene 1. 1,2-Dichloroethane 1. 1,2-Dichloropropane 1. 1,3,5-Trimethylbenzene 1. 1,3-Dichlorobenzene 1. 1,4-Dichlorobenzene 1. 2-Butanone 5. 2-Hexanone 5. 2-Methylnaphthalene 5. 4-Methyl-2-pentanone 1. Acetone 1 Acrylonitrile 1. Benzene 1. Bromochloromethane 1. Bromodichloromethane 1. Bromoform 1. Bromomethane 1. Carbon disulfide 1. Carbon tetrachloride 1. Chlorobenzene 1. Chloroethane 1. Chloroform 1. Chloromethane 1. cis-1,2-dichloroethene 1. cis-1,3-dichloropropene 1. Dibromochloromethane 1. Dibromomethane 1. Dichlorodifluoromethane 1. Diethyl ether 1. Ethylbenzene 1. RPD Limit Qual See Qualifiers Page for a list of Qualifiers and their explanation. QC Page: 6 of 13

26 Client: Merit Energy Work Order: QC BATCH REPORT Batch ID: R174943A Instrument ID: VMS8 Method: SW826B Hexachloroethane 1. Isopropylbenzene 1. m,p-xylene 2. Methyl iodide 1. Methyl tert-butyl ether 1. Methylene chloride 5. Naphthalene 5. n-propylbenzene 1. o-xylene 1. Styrene 1. Tetrachloroethene 1. Toluene 1. trans-1,2-dichloroethene 1. trans-1,3-dichloropropene 1. trans-1,4-dichloro-2-butene 2. Trichloroethene 1. Trichlorofluoromethane 1. Vinyl acetate 1. Vinyl chloride 1. Xylenes, Total 3. Surr: 1,2-Dichloroethane-d Surr: 4-Bromofluorobenzene Surr: Dibromofluoromethane Surr: Toluene-d See Qualifiers Page for a list of Qualifiers and their explanation. QC Page: 7 of 13

27 Client: Merit Energy Work Order: QC BATCH REPORT Batch ID: R174943A Instrument ID: VMS8 Method: SW826B LCS Sample ID: VLCSW R174943A Units: µg/l Client ID: Run ID: VMS8_15129A SeqNo: Prep Date: Analysis Date: 1/29/215 1:56 A DF: 1 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD RPD Limit Qual 1,1,1,2-Tetrachloroethane ,1,1-Trichloroethane ,1,2,2-Tetrachloroethane ,1,2-Trichloroethane ,1-Dichloroethane ,1-Dichloroethene ,2,3-Trichloropropane ,2,4-Trichlorobenzene ,2,4-Trimethylbenzene ,2-Dibromo-3-chloropropane ,2-Dibromoethane ,2-Dichlorobenzene ,2-Dichloroethane ,2-Dichloropropane ,3,5-Trimethylbenzene ,3-Dichlorobenzene ,4-Dichlorobenzene Butanone Hexanone Methyl-2-pentanone Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-dichloroethene cis-1,3-dichloropropene Dibromochloromethane Dibromomethane Dichlorodifluoromethane Ethylbenzene Hexachloroethane Isopropylbenzene m,p-xylene See Qualifiers Page for a list of Qualifiers and their explanation. QC Page: 8 of 13

28 Client: Merit Energy Work Order: QC BATCH REPORT Batch ID: R174943A Instrument ID: VMS8 Method: SW826B Methyl iodide Methyl tert-butyl ether Methylene chloride Naphthalene n-propylbenzene o-xylene Styrene Tetrachloroethene Toluene trans-1,2-dichloroethene trans-1,3-dichloropropene trans-1,4-dichloro-2-butene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Surr: 1,2-Dichloroethane-d Surr: 4-Bromofluorobenzene Surr: Dibromofluoromethane Surr: Toluene-d See Qualifiers Page for a list of Qualifiers and their explanation. QC Page: 9 of 13

29 Client: Merit Energy Work Order: QC BATCH REPORT Batch ID: R174943A Instrument ID: VMS8 Method: SW826B MS Sample ID: A MS Units: µg/l Client ID: Run ID: VMS8_15129A SeqNo: Prep Date: Analysis Date: 1/29/215 8:39 P DF: 1 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD RPD Limit Qual 1,1,1,2-Tetrachloroethane ,1,1-Trichloroethane ,1,2,2-Tetrachloroethane ,1,2-Trichloroethane ,1-Dichloroethane ,1-Dichloroethene ,2,3-Trichloropropane ,2,4-Trichlorobenzene ,2,4-Trimethylbenzene ,2-Dibromo-3-chloropropane ,2-Dibromoethane ,2-Dichlorobenzene ,2-Dichloroethane ,2-Dichloropropane ,3,5-Trimethylbenzene ,3-Dichlorobenzene ,4-Dichlorobenzene Butanone Hexanone Methyl-2-pentanone Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-dichloroethene cis-1,3-dichloropropene Dibromochloromethane Dibromomethane Dichlorodifluoromethane Ethylbenzene Hexachloroethane Isopropylbenzene m,p-xylene See Qualifiers Page for a list of Qualifiers and their explanation. QC Page: 1 of 13

30 Client: Merit Energy Work Order: QC BATCH REPORT Batch ID: R174943A Instrument ID: VMS8 Method: SW826B Methyl iodide Methyl tert-butyl ether Methylene chloride Naphthalene n-propylbenzene o-xylene Styrene Tetrachloroethene Toluene trans-1,2-dichloroethene trans-1,3-dichloropropene trans-1,4-dichloro-2-butene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Surr: 1,2-Dichloroethane-d Surr: 4-Bromofluorobenzene Surr: Dibromofluoromethane Surr: Toluene-d S See Qualifiers Page for a list of Qualifiers and their explanation. QC Page: 11 of 13

31 Client: Merit Energy Work Order: QC BATCH REPORT Batch ID: R174943A Instrument ID: VMS8 Method: SW826B MSD Sample ID: A MSD Units: µg/l Client ID: Run ID: VMS8_15129A SeqNo: Prep Date: Analysis Date: 1/29/215 9:3 P DF: 1 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD RPD Limit Qual 1,1,1,2-Tetrachloroethane ,1,1-Trichloroethane ,1,2,2-Tetrachloroethane ,1,2-Trichloroethane ,1-Dichloroethane ,1-Dichloroethene ,2,3-Trichloropropane ,2,4-Trichlorobenzene ,2,4-Trimethylbenzene ,2-Dibromo-3-chloropropane ,2-Dibromoethane ,2-Dichlorobenzene ,2-Dichloroethane ,2-Dichloropropane ,3,5-Trimethylbenzene ,3-Dichlorobenzene ,4-Dichlorobenzene Butanone Hexanone Methyl-2-pentanone Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-dichloroethene cis-1,3-dichloropropene Dibromochloromethane Dibromomethane Dichlorodifluoromethane Ethylbenzene Hexachloroethane Isopropylbenzene m,p-xylene See Qualifiers Page for a list of Qualifiers and their explanation. QC Page: 12 of 13

32 Client: Merit Energy Work Order: QC BATCH REPORT Batch ID: R174943A Instrument ID: VMS8 Method: SW826B Methyl iodide Methyl tert-butyl ether Methylene chloride Naphthalene n-propylbenzene o-xylene Styrene Tetrachloroethene Toluene trans-1,2-dichloroethene trans-1,3-dichloropropene trans-1,4-dichloro-2-butene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Surr: 1,2-Dichloroethane-d Surr: 4-Bromofluorobenzene Surr: Dibromofluoromethane Surr: Toluene-d S The following samples were analyzed in this batch: A See Qualifiers Page for a list of Qualifiers and their explanation. QC Page: 13 of 13

33 ALS Group USA, Corp Client: Merit Energy WorkOrder: Date: 3-Oct-15 QUALIFIERS, ACRONYMS, UNITS Qualifier * a B E H J n O P R S U X Acronym DUP LCS LCSD LOD LOQ MBLK MDL MS MSD PQL RPD TDL TNTC A D E SW Units Reported µg/l mg/l Description Value exceeds Regulatory Limit Not accredited Analyte detected in the associated Method Blank above the Reporting Limit Value above quantitation range Analyzed outside of Holding Time Analyte is present at an estimated concentration between the MDL and Report Limit Not offered for accreditation Not Detected at the Reporting Limit Sample amount is > 4 times amount spiked Dual Column results percent difference > 4% RPD above laboratory control limit Spike Recovery outside laboratory control limits Analyzed but not detected above the MDL Analyte was detected in the Method Blank between the MDL and PQL, sample results may exhibit background or reag contamination at the observed level. Description Method Duplicate Laboratory Control Sample Laboratory Control Sample Duplicate Limit of Detection (see MDL) Limit of Quantitation (see PQL) Method Blank Method Detection Limit Matrix Spike Matrix Spike Duplicate Practical Quantitation Limit Relative Percent Difference Target Detection Limit Too Numerous To Count APHA Standard Methods ASTM EPA SW-846 Update III Description Micrograms per Liter Milligrams per Liter QF Page 1 of 1

34 ALS Group USA, Corp Sample Receipt Checklist Client Name: MERITENERGY Date/Time Received: 2-Oct-15 1: Work Order: Received by: DS Checklist completed by Diane Shaw Gary Byar 21-Oct-15 Reviewed by: esignature Date esignature 21-Oct-15 Date Matrices: Carrier name: Water FedEx Shipping container/cooler in good condition? Yes No Not Present Custody seals intact on shipping container/cooler? Yes No Not Present Custody seals intact on sample bottles? Yes No Not Present Chain of custody present? Yes No Chain of custody signed when relinquished and received? Yes No Chain of custody agrees with sample labels? Yes No Samples in proper container/bottle? Yes No Sample containers intact? Yes No Sufficient sample volume for indicated test? Yes No All samples received within holding time? Yes No Container/Temp Blank temperature in compliance? Yes No Sample(s) received on ice? Yes No Temperature(s)/Thermometer(s): 2.2/2.2 c SR2 Cooler(s)/Kit(s): Date/Time sample(s) sent to storage: Water - VOA vials have zero headspace? 1/21/215 8:11:49 AM Yes No No VOA vials submitted Water - ph acceptable upon receipt? Yes No N/A ph adjusted? Yes No N/A ph adjusted by: Login Notes: Client Contacted: Date Contacted: Person Contacted: Contacted By: Regarding: Comments: CorrectiveAction SRC Page 1 of 1

35

36 11-Nov-215 Sean Craven Merit Energy 151 Thomas Rd PO Box 91 Kalkaska, MI Re: Hartland Gas Plant Work Order: Dear Sean, ALS Environmental received 5 samples on 31-Oct-215 9:3 AM for the analyses presented in the following report. The analytical data provided relates directly to the samples received by ALS Environmental and for only the analyses requested. Sample results are compliant with NELAP standard requirements and QC results achieved laboratory specifications. Any exceptions are noted in the Case Narrative, or noted with qualifiers in the report or QC batch information. Should this laboratory report need to be reproduced, it should be reproduced in full unless written approval has been obtained from ALS Environmental. Samples will be disposed in 3 days unless storage arrangements are made. The total number of pages in this report is 27. If you have any questions regarding this report, please feel free to contact me. Sincerely, Gary Byar Electronically approved by: Gary Byar Gary Byar Project Manager Certificate No: MI: 22 Report of Laboratory Analysis ADDRESS th Avenue Holland, Michigan PHONE (616) FAX (616) ALS GROUP USA, CORP Part of the ALS Laboratory Group A Campbell Brothers Limited Company

37 ALS Group USA, Corp Date: 11-Nov-15 Client: Merit Energy Work Order: Work Order Sample Summary Lab Samp ID Client Sample ID Matrix Tag Number Collection Date Date Received TMW-6 (65-7') Water 1/3/215 12:15 1/31/215 9: TMW-6 (55-6') Water 1/3/215 12:25 1/31/215 9: TMW-6 (45-5') Water 1/3/215 12:35 1/31/215 9: TMW-6 (35-4') Water 1/3/215 12:45 1/31/215 9: W-1339 Shallow Water 1/3/215 15:2 1/31/215 9:3 Hold Sample Summary Page 1 of 1

38 ALS Group USA, Corp Date: 11-Nov-15 Client: Merit Energy Work Order: Sample ID: TMW-6 (65-7') Lab ID: Collection Date: 1/3/215 12:15 PM Matrix: WATER Analyses Result Qual Report Dilution Limit Units Factor Date Analyzed SEMI-VOLATILE ORGANIC COMPOUS SW D Prep: SW351 / 11/3/15 Analyst: RM Sulfolane 1 µg/l 1 11/4/215 7:59 PM Surr: 2,4,6-Tribromophenol %REC 1 11/4/215 7:59 PM Surr: 2-Fluorobiphenyl %REC 1 11/4/215 7:59 PM Surr: 2-Fluorophenol %REC 1 11/4/215 7:59 PM Surr: 4-Terphenyl-d %REC 1 11/4/215 7:59 PM Surr: Nitrobenzene-d %REC 1 11/4/215 7:59 PM Surr: Phenol-d %REC 1 11/4/215 7:59 PM See Qualifiers page for a list of qualifiers and their definitions. Analytical Results Page 1 of 7

39 ALS Group USA, Corp Date: 11-Nov-15 Client: Merit Energy Work Order: Sample ID: TMW-6 (55-6') Lab ID: Collection Date: 1/3/215 12:25 PM Matrix: WATER Analyses Result Qual Report Dilution Limit Units Factor Date Analyzed SEMI-VOLATILE ORGANIC COMPOUS SW D Prep: SW351 / 11/3/15 Analyst: RM Sulfolane 1 µg/l 1 11/4/215 8:19 PM Surr: 2,4,6-Tribromophenol %REC 1 11/4/215 8:19 PM Surr: 2-Fluorobiphenyl %REC 1 11/4/215 8:19 PM Surr: 2-Fluorophenol %REC 1 11/4/215 8:19 PM Surr: 4-Terphenyl-d %REC 1 11/4/215 8:19 PM Surr: Nitrobenzene-d %REC 1 11/4/215 8:19 PM Surr: Phenol-d %REC 1 11/4/215 8:19 PM See Qualifiers page for a list of qualifiers and their definitions. Analytical Results Page 2 of 7

40 ALS Group USA, Corp Date: 11-Nov-15 Client: Merit Energy Work Order: Sample ID: TMW-6 (45-5') Lab ID: Collection Date: 1/3/215 12:35 PM Matrix: WATER Analyses Result Qual Report Dilution Limit Units Factor Date Analyzed SEMI-VOLATILE ORGANIC COMPOUS SW D Prep: SW351 / 11/3/15 Analyst: RM Sulfolane 1 µg/l 1 11/4/215 8:39 PM Surr: 2,4,6-Tribromophenol %REC 1 11/4/215 8:39 PM Surr: 2-Fluorobiphenyl %REC 1 11/4/215 8:39 PM Surr: 2-Fluorophenol %REC 1 11/4/215 8:39 PM Surr: 4-Terphenyl-d %REC 1 11/4/215 8:39 PM Surr: Nitrobenzene-d %REC 1 11/4/215 8:39 PM Surr: Phenol-d %REC 1 11/4/215 8:39 PM See Qualifiers page for a list of qualifiers and their definitions. Analytical Results Page 3 of 7

41 ALS Group USA, Corp Date: 11-Nov-15 Client: Merit Energy Work Order: Sample ID: TMW-6 (35-4') Lab ID: Collection Date: 1/3/215 12:45 PM Matrix: WATER Analyses Result Qual Report Dilution Limit Units Factor Date Analyzed SEMI-VOLATILE ORGANIC COMPOUS SW D Prep: SW351 / 11/3/15 Analyst: RM Sulfolane 1 µg/l 1 11/4/215 8:59 PM Surr: 2,4,6-Tribromophenol %REC 1 11/4/215 8:59 PM Surr: 2-Fluorobiphenyl %REC 1 11/4/215 8:59 PM Surr: 2-Fluorophenol %REC 1 11/4/215 8:59 PM Surr: 4-Terphenyl-d %REC 1 11/4/215 8:59 PM Surr: Nitrobenzene-d %REC 1 11/4/215 8:59 PM Surr: Phenol-d %REC 1 11/4/215 8:59 PM See Qualifiers page for a list of qualifiers and their definitions. Analytical Results Page 4 of 7

42 ALS Group USA, Corp Date: 11-Nov-15 Client: Merit Energy Work Order: Sample ID: W-1339 Shallow Lab ID: Collection Date: 1/3/215 3:2 PM Matrix: WATER Analyses Result Qual Report Dilution Limit Units Factor Date Analyzed ORGANIC COMPOUS BY GC-FID SW815M Analyst: KYM Ethylene glycol 5. mg/l 1 11/9/215 9:34 AM SEMI-VOLATILE ORGANIC COMPOUS SW D Prep: SW351 / 11/3/15 Analyst: RM 2-Methylnaphthalene 5. µg/l 1 11/4/215 9:19 PM Acenaphthene 5. µg/l 1 11/4/215 9:19 PM Acenaphthylene 5. µg/l 1 11/4/215 9:19 PM Anthracene 5. µg/l 1 11/4/215 9:19 PM Benzo(a)anthracene 5. µg/l 1 11/4/215 9:19 PM Benzo(a)pyrene 5. µg/l 1 11/4/215 9:19 PM Benzo(b)fluoranthene 5. µg/l 1 11/4/215 9:19 PM Benzo(g,h,i)perylene 5. µg/l 1 11/4/215 9:19 PM Benzo(k)fluoranthene 5. µg/l 1 11/4/215 9:19 PM Chrysene 5. µg/l 1 11/4/215 9:19 PM Dibenzo(a,h)anthracene 5. µg/l 1 11/4/215 9:19 PM Fluoranthene 5. µg/l 1 11/4/215 9:19 PM Fluorene 5. µg/l 1 11/4/215 9:19 PM Indeno(1,2,3-cd)pyrene 5. µg/l 1 11/4/215 9:19 PM Naphthalene 5. µg/l 1 11/4/215 9:19 PM Phenanthrene 5. µg/l 1 11/4/215 9:19 PM Pyrene 5. µg/l 1 11/4/215 9:19 PM Sulfolane 1 µg/l 1 11/4/215 9:19 PM Surr: 2,4,6-Tribromophenol %REC 1 11/4/215 9:19 PM Surr: 2-Fluorobiphenyl %REC 1 11/4/215 9:19 PM Surr: 2-Fluorophenol %REC 1 11/4/215 9:19 PM Surr: 4-Terphenyl-d %REC 1 11/4/215 9:19 PM Surr: Nitrobenzene-d %REC 1 11/4/215 9:19 PM Surr: Phenol-d %REC 1 11/4/215 9:19 PM VOLATILE ORGANIC COMPOUS SW826B Analyst: BG 1,1,1,2-Tetrachloroethane 1. µg/l 1 11/1/215 7:27 AM 1,1,1-Trichloroethane 1. µg/l 1 11/1/215 7:27 AM 1,1,2,2-Tetrachloroethane 1. µg/l 1 11/1/215 7:27 AM 1,1,2-Trichloroethane 1. µg/l 1 11/1/215 7:27 AM 1,1,2-Trichlorotrifluoroethane 1. µg/l 1 11/1/215 7:27 AM 1,1-Dichloroethane 1. µg/l 1 11/1/215 7:27 AM 1,1-Dichloroethene 1. µg/l 1 11/1/215 7:27 AM 1,2,3-Trichloropropane 1. µg/l 1 11/1/215 7:27 AM 1,2,4-Trichlorobenzene 1. µg/l 1 11/1/215 7:27 AM 1,2,4-Trimethylbenzene 1. µg/l 1 11/1/215 7:27 AM 1,2-Dibromo-3-chloropropane 1. µg/l 1 11/1/215 7:27 AM See Qualifiers page for a list of qualifiers and their definitions. Analytical Results Page 5 of 7

43 ALS Group USA, Corp Date: 11-Nov-15 Client: Merit Energy Work Order: Sample ID: W-1339 Shallow Lab ID: Collection Date: 1/3/215 3:2 PM Matrix: WATER Analyses Result Qual Report Dilution Limit Units Factor Date Analyzed 1,2-Dibromoethane 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,3,5-Trimethylbenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 2-Butanone 2-Hexanone 2-Methylnaphthalene 4-Methyl-2-pentanone Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-dichloroethene cis-1,3-dichloropropene Dibromochloromethane Dibromomethane Dichlorodifluoromethane Diethyl ether Ethylbenzene Hexachloroethane Isopropylbenzene m,p-xylene Methyl iodide Methyl tert-butyl ether Methylene chloride Naphthalene n-propylbenzene o-xylene 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 5. µg/l 1 5. µg/l 1 5. µg/l 1 1. µg/l 1 1 µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 2. µg/l 1 1. µg/l 1 1. µg/l 1 5. µg/l 1 5. µg/l 1 1. µg/l 1 1. µg/l 1 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM See Qualifiers page for a list of qualifiers and their definitions. Analytical Results Page 6 of 7

44 ALS Group USA, Corp Date: 11-Nov-15 Client: Merit Energy Work Order: Sample ID: W-1339 Shallow Lab ID: Collection Date: 1/3/215 3:2 PM Matrix: WATER Analyses Result Qual Report Dilution Limit Units Factor Date Analyzed Styrene Tetrachloroethene Toluene trans-1,2-dichloroethene trans-1,3-dichloropropene trans-1,4-dichloro-2-butene Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylenes, Total Surr: 1,2-Dichloroethane-d4 Surr: 4-Bromofluorobenzene Surr: Dibromofluoromethane Surr: Toluene-d µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 2. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 1. µg/l 1 3. µg/l %REC %REC %REC %REC 1 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM 11/1/215 7:27 AM See Qualifiers page for a list of qualifiers and their definitions. Analytical Results Page 7 of 7

45 ALS Group USA, Corp Client: Merit Energy Work Order: Date: 11-Nov-15 Case Narrative Batch R175749A The MS/MSD data for volatiles is not related to this project's samples. No data requires qualification. Case Narrative Page 1 of 1

46 ALS Group USA, Corp Client: Merit Energy Work Order: Date: 11-Nov-15 QC BATCH REPORT Batch ID: R Instrument ID: GC11 Method: SW815M MBLK Sample ID: MB-R R Units: mg/l Client ID: Run ID: GC11_15119A SeqNo: Analysis Date: 11/9/215 9:16 AM Prep Date: 11/6/215 DF: 1 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD Ethylene glycol 5. RPD Limit Qual LCS Sample ID: LCS-R R Units: mg/l Client ID: Run ID: GC11_15119A SeqNo: Analysis Date: 11/9/215 8:22 AM Prep Date: 11/6/215 DF: 1 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD RPD Limit Qual Ethylene glycol The following samples were analyzed in this batch: B See Qualifiers Page for a list of Qualifiers and their explanation. QC Page: 1 of 13

47 Client: Merit Energy Work Order: QC BATCH REPORT Batch ID: Instrument ID: SVMS8 Method: SW D MBLK Sample ID: SBLKW Units: µg/l Client ID: Run ID: SVMS8_15114A SeqNo: Analysis Date: 11/4/215 1:44 PM Prep Date: 11/3/215 DF: 1 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD RPD Limit Qual 2-Methylnaphthalene 5. Acenaphthene 5. Acenaphthylene 5. Anthracene 5. Benzo(a)anthracene 5. Benzo(a)pyrene 5. Benzo(b)fluoranthene 5. Benzo(g,h,i)perylene 5. Benzo(k)fluoranthene 5. Chrysene 5. Dibenzo(a,h)anthracene 5. Fluoranthene 5. Fluorene 5. Indeno(1,2,3-cd)pyrene 5. Naphthalene 5. Phenanthrene 5. Pyrene 5. Sulfolane 1 Surr: 2,4,6-Tribromophenol Surr: 2-Fluorobiphenyl Surr: 2-Fluorophenol Surr: 4-Terphenyl-d Surr: Nitrobenzene-d Surr: Phenol-d See Qualifiers Page for a list of Qualifiers and their explanation. QC Page: 2 of 13

48 Client: Merit Energy Work Order: QC BATCH REPORT Batch ID: Instrument ID: SVMS8 Method: SW D LCS Sample ID: SLCSW Units: µg/l Client ID: Run ID: SVMS8_15114A SeqNo: 3553 Analysis Date: 11/4/215 2:4 PM Prep Date: 11/3/215 DF: 1 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD RPD Limit Qual 2-Methylnaphthalene Acenaphthene Acenaphthylene Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Chrysene Dibenzo(a,h)anthracene Fluoranthene Fluorene Indeno(1,2,3-cd)pyrene Naphthalene Phenanthrene Pyrene Surr: 2,4,6-Tribromophenol Surr: 2-Fluorobiphenyl Surr: 2-Fluorophenol Surr: 4-Terphenyl-d Surr: Nitrobenzene-d Surr: Phenol-d LCS Sample ID: SLCSW Units: µg/l Client ID: Run ID: SVMS8_15114A SeqNo: Analysis Date: 11/4/215 3:5 PM Prep Date: 11/3/215 DF: 1 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD RPD Limit Qual Sulfolane Surr: 2,4,6-Tribromophenol Surr: 2-Fluorobiphenyl Surr: 2-Fluorophenol Surr: 4-Terphenyl-d Surr: Nitrobenzene-d Surr: Phenol-d J See Qualifiers Page for a list of Qualifiers and their explanation. QC Page: 3 of 13

49 Client: Merit Energy Work Order: QC BATCH REPORT Batch ID: Instrument ID: SVMS8 Method: SW D LCSD Sample ID: SLCSDW Units: µg/l Client ID: Run ID: SVMS8_15114A SeqNo: Analysis Date: 11/4/215 3:26 PM Prep Date: 11/3/215 DF: 1 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD RPD Limit Qual Sulfolane Surr: 2,4,6-Tribromophenol Surr: 2-Fluorobiphenyl Surr: 2-Fluorophenol Surr: 4-Terphenyl-d Surr: Nitrobenzene-d Surr: Phenol-d J MS Sample ID: B MS Units: µg/l Client ID: Run ID: SVMS8_15114A SeqNo: Analysis Date: 11/4/215 6:59 PM Prep Date: 11/3/215 DF: 1 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD RPD Limit Qual 2-Methylnaphthalene Acenaphthene Acenaphthylene Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Chrysene Dibenzo(a,h)anthracene Fluoranthene Fluorene Indeno(1,2,3-cd)pyrene Naphthalene Phenanthrene Pyrene Surr: 2,4,6-Tribromophenol Surr: 2-Fluorobiphenyl Surr: 2-Fluorophenol Surr: 4-Terphenyl-d Surr: Nitrobenzene-d Surr: Phenol-d See Qualifiers Page for a list of Qualifiers and their explanation. QC Page: 4 of 13

50 Client: Merit Energy Work Order: QC BATCH REPORT Batch ID: Instrument ID: SVMS8 Method: SW D MSD Sample ID: B MSD Units: µg/l Client ID: Run ID: SVMS8_15114A SeqNo: Analysis Date: 11/4/215 7:19 PM Prep Date: 11/3/215 DF: 1 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD RPD Limit Qual 2-Methylnaphthalene Acenaphthene Acenaphthylene Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Chrysene Dibenzo(a,h)anthracene Fluoranthene Fluorene Indeno(1,2,3-cd)pyrene Naphthalene Phenanthrene Pyrene Surr: 2,4,6-Tribromophenol Surr: 2-Fluorobiphenyl Surr: 2-Fluorophenol Surr: 4-Terphenyl-d Surr: Nitrobenzene-d Surr: Phenol-d The following samples were analyzed in this batch: A A A A A See Qualifiers Page for a list of Qualifiers and their explanation. QC Page: 5 of 13

51 Client: Merit Energy Work Order: QC BATCH REPORT Batch ID: R175749A Instrument ID: VMS6 Method: SW826B MBLK Sample ID: VBLKW R175749A Units: µg/l Client ID: Run ID: VMS6_15119B SeqNo: Prep Date: Analysis Date: 11/9/215 11:42 PM DF: 1 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD 1,1,1,2-Tetrachloroethane 1. 1,1,1-Trichloroethane 1. 1,1,2,2-Tetrachloroethane 1. 1,1,2-Trichloroethane 1. 1,1,2-Trichlorotrifluoroethane 1. 1,1-Dichloroethane 1. 1,1-Dichloroethene 1. 1,2,3-Trichloropropane 1. 1,2,4-Trichlorobenzene 1. 1,2,4-Trimethylbenzene 1. 1,2-Dibromo-3-chloropropane 1. 1,2-Dibromoethane 1. 1,2-Dichlorobenzene 1. 1,2-Dichloroethane 1. 1,2-Dichloropropane 1. 1,3,5-Trimethylbenzene 1. 1,3-Dichlorobenzene 1. 1,4-Dichlorobenzene 1. 2-Butanone 5. 2-Hexanone 5. 2-Methylnaphthalene 5. 4-Methyl-2-pentanone 1. Acetone 1 Acrylonitrile 1. Benzene 1. Bromochloromethane 1. Bromodichloromethane 1. Bromoform 1. Bromomethane 1. Carbon disulfide 1. Carbon tetrachloride 1. Chlorobenzene 1. Chloroethane 1. Chloroform 1. Chloromethane 1. cis-1,2-dichloroethene 1. cis-1,3-dichloropropene 1. Dibromochloromethane 1. Dibromomethane 1. Dichlorodifluoromethane 1. Diethyl ether 1. Ethylbenzene 1. RPD Limit Qual See Qualifiers Page for a list of Qualifiers and their explanation. QC Page: 6 of 13

52 Client: Merit Energy Work Order: QC BATCH REPORT Batch ID: R175749A Instrument ID: VMS6 Method: SW826B Hexachloroethane 1. Isopropylbenzene 1. m,p-xylene 2. Methyl iodide 1. Methyl tert-butyl ether 1. Methylene chloride 5. Naphthalene n-propylbenzene 1. o-xylene 1. Styrene 1. Tetrachloroethene 1. Toluene 1. trans-1,2-dichloroethene 1. trans-1,3-dichloropropene 1. trans-1,4-dichloro-2-butene 2. Trichloroethene 1. Trichlorofluoromethane 1. Vinyl acetate 1. Vinyl chloride 1. Xylenes, Total 3. Surr: 1,2-Dichloroethane-d Surr: 4-Bromofluorobenzene Surr: Dibromofluoromethane Surr: Toluene-d J See Qualifiers Page for a list of Qualifiers and their explanation. QC Page: 7 of 13

53 Client: Merit Energy Work Order: QC BATCH REPORT Batch ID: R175749A Instrument ID: VMS6 Method: SW826B LCS Sample ID: VLCSW R175749A Units: µg/l Client ID: Run ID: VMS6_15119B SeqNo: Prep Date: Analysis Date: 11/9/215 1:5 PM DF: 1 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD RPD Limit Qual 1,1,1,2-Tetrachloroethane ,1,1-Trichloroethane ,1,2,2-Tetrachloroethane ,1,2-Trichloroethane ,1-Dichloroethane ,1-Dichloroethene ,2,3-Trichloropropane ,2,4-Trichlorobenzene ,2,4-Trimethylbenzene ,2-Dibromo-3-chloropropane ,2-Dibromoethane ,2-Dichlorobenzene ,2-Dichloroethane ,2-Dichloropropane ,3,5-Trimethylbenzene ,3-Dichlorobenzene ,4-Dichlorobenzene Butanone Hexanone Methyl-2-pentanone Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-dichloroethene cis-1,3-dichloropropene Dibromochloromethane Dibromomethane Dichlorodifluoromethane Ethylbenzene Hexachloroethane Isopropylbenzene m,p-xylene See Qualifiers Page for a list of Qualifiers and their explanation. QC Page: 8 of 13

54 Client: Merit Energy Work Order: QC BATCH REPORT Batch ID: R175749A Instrument ID: VMS6 Method: SW826B Methyl iodide Methyl tert-butyl ether Methylene chloride Naphthalene n-propylbenzene o-xylene Styrene Tetrachloroethene Toluene trans-1,2-dichloroethene trans-1,3-dichloropropene trans-1,4-dichloro-2-butene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Surr: 1,2-Dichloroethane-d Surr: 4-Bromofluorobenzene Surr: Dibromofluoromethane Surr: Toluene-d See Qualifiers Page for a list of Qualifiers and their explanation. QC Page: 9 of 13

55 Client: Merit Energy Work Order: QC BATCH REPORT Batch ID: R175749A Instrument ID: VMS6 Method: SW826B MS Sample ID: A MS Units: µg/l Client ID: Run ID: VMS6_15119B SeqNo: Prep Date: Analysis Date: 11/1/215 8:44 A DF: 1 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD RPD Limit Qual 1,1,1,2-Tetrachloroethane ,1,1-Trichloroethane ,1,2,2-Tetrachloroethane ,1,2-Trichloroethane ,1-Dichloroethane ,1-Dichloroethene ,2,3-Trichloropropane ,2,4-Trichlorobenzene ,2,4-Trimethylbenzene ,2-Dibromo-3-chloropropane ,2-Dibromoethane ,2-Dichlorobenzene ,2-Dichloroethane ,2-Dichloropropane ,3,5-Trimethylbenzene ,3-Dichlorobenzene ,4-Dichlorobenzene Butanone Hexanone Methyl-2-pentanone Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-dichloroethene cis-1,3-dichloropropene Dibromochloromethane Dibromomethane Dichlorodifluoromethane Ethylbenzene Hexachloroethane Isopropylbenzene m,p-xylene S See Qualifiers Page for a list of Qualifiers and their explanation. QC Page: 1 of 13

56 Client: Merit Energy Work Order: QC BATCH REPORT Batch ID: R175749A Instrument ID: VMS6 Method: SW826B Methyl iodide Methyl tert-butyl ether Methylene chloride Naphthalene n-propylbenzene o-xylene Styrene Tetrachloroethene Toluene trans-1,2-dichloroethene trans-1,3-dichloropropene trans-1,4-dichloro-2-butene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Surr: 1,2-Dichloroethane-d Surr: 4-Bromofluorobenzene Surr: Dibromofluoromethane Surr: Toluene-d S See Qualifiers Page for a list of Qualifiers and their explanation. QC Page: 11 of 13

57 Client: Merit Energy Work Order: QC BATCH REPORT Batch ID: R175749A Instrument ID: VMS6 Method: SW826B MSD Sample ID: A MSD Units: µg/l Client ID: Run ID: VMS6_15119B SeqNo: Prep Date: Analysis Date: 11/1/215 9:1 A DF: 1 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD RPD Limit Qual 1,1,1,2-Tetrachloroethane ,1,1-Trichloroethane ,1,2,2-Tetrachloroethane ,1,2-Trichloroethane ,1-Dichloroethane ,1-Dichloroethene ,2,3-Trichloropropane ,2,4-Trichlorobenzene ,2,4-Trimethylbenzene ,2-Dibromo-3-chloropropane ,2-Dibromoethane ,2-Dichlorobenzene ,2-Dichloroethane ,2-Dichloropropane ,3,5-Trimethylbenzene ,3-Dichlorobenzene ,4-Dichlorobenzene Butanone Hexanone Methyl-2-pentanone Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-dichloroethene cis-1,3-dichloropropene Dibromochloromethane Dibromomethane Dichlorodifluoromethane Ethylbenzene Hexachloroethane Isopropylbenzene m,p-xylene See Qualifiers Page for a list of Qualifiers and their explanation. QC Page: 12 of 13

58 Client: Merit Energy Work Order: QC BATCH REPORT Batch ID: R175749A Instrument ID: VMS6 Method: SW826B Methyl iodide Methyl tert-butyl ether Methylene chloride Naphthalene n-propylbenzene o-xylene Styrene Tetrachloroethene Toluene trans-1,2-dichloroethene trans-1,3-dichloropropene trans-1,4-dichloro-2-butene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Surr: 1,2-Dichloroethane-d Surr: 4-Bromofluorobenzene Surr: Dibromofluoromethane Surr: Toluene-d The following samples were analyzed in this batch: B See Qualifiers Page for a list of Qualifiers and their explanation. QC Page: 13 of 13

59 ALS Group USA, Corp Client: Merit Energy WorkOrder: Date: 11-Nov-15 QUALIFIERS, ACRONYMS, UNITS Qualifier * a B E H J n O P R S U X Acronym DUP LCS LCSD LOD LOQ MBLK MDL MS MSD PQL RPD TDL TNTC A D E SW Units Reported µg/l mg/l Description Value exceeds Regulatory Limit Not accredited Analyte detected in the associated Method Blank above the Reporting Limit Value above quantitation range Analyzed outside of Holding Time Analyte is present at an estimated concentration between the MDL and Report Limit Not offered for accreditation Not Detected at the Reporting Limit Sample amount is > 4 times amount spiked Dual Column results percent difference > 4% RPD above laboratory control limit Spike Recovery outside laboratory control limits Analyzed but not detected above the MDL Analyte was detected in the Method Blank between the MDL and PQL, sample results may exhibit background or reag contamination at the observed level. Description Method Duplicate Laboratory Control Sample Laboratory Control Sample Duplicate Limit of Detection (see MDL) Limit of Quantitation (see PQL) Method Blank Method Detection Limit Matrix Spike Matrix Spike Duplicate Practical Quantitation Limit Relative Percent Difference Target Detection Limit Too Numerous To Count APHA Standard Methods ASTM EPA SW-846 Update III Description Micrograms per Liter Milligrams per Liter QF Page 1 of 1

60 ALS Group USA, Corp Sample Receipt Checklist Client Name: MERITENERGY Date/Time Received: 31-Oct-15 9:3 Work Order: Received by: KRW Checklist completed by Keith Wierenga Gary Byar 31-Oct-15 Reviewed by: esignature Date esignature 2-Nov-15 Date Matrices: Carrier name: Water FedEx Shipping container/cooler in good condition? Yes No Not Present Custody seals intact on shipping container/cooler? Yes No Not Present Custody seals intact on sample bottles? Yes No Not Present Chain of custody present? Yes No Chain of custody signed when relinquished and received? Yes No Chain of custody agrees with sample labels? Yes No Samples in proper container/bottle? Yes No Sample containers intact? Yes No Sufficient sample volume for indicated test? Yes No All samples received within holding time? Yes No Container/Temp Blank temperature in compliance? Yes No Sample(s) received on ice? Yes No Temperature(s)/Thermometer(s): 4.8/4.8 C SR2 Cooler(s)/Kit(s): Date/Time sample(s) sent to storage: Water - VOA vials have zero headspace? 1/31/215 11:11:41 AM Yes No No VOA vials submitted Water - ph acceptable upon receipt? Yes No N/A ph adjusted? Yes No N/A ph adjusted by: Login Notes: Client Contacted: Date Contacted: Person Contacted: Contacted By: Regarding: Comments: CorrectiveAction SRC Page 1 of 1

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63 16-Nov-215 Sean Craven Merit Energy 151 Thomas Rd PO Box 91 Kalkaska, MI Re: Hartland Gas Plant Work Order: Dear Sean, ALS Environmental received 7 samples on 6-Nov-215 8: AM for the analyses presented in the following report. The analytical data provided relates directly to the samples received by ALS Environmental and for only the analyses requested. Sample results are compliant with NELAP standard requirements and QC results achieved laboratory specifications. Any exceptions are noted in the Case Narrative, or noted with qualifiers in the report or QC batch information. Should this laboratory report need to be reproduced, it should be reproduced in full unless written approval has been obtained from ALS Environmental. Samples will be disposed in 3 days unless storage arrangements are made. The total number of pages in this report is 13. If you have any questions regarding this report, please feel free to contact me. Sincerely, Gary Byar Electronically approved by: Gary Byar Gary Byar Project Manager Certificate No: MI: 22 Report of Laboratory Analysis ADDRESS th Avenue Holland, Michigan PHONE (616) FAX (616) ALS GROUP USA, CORP Part of the ALS Laboratory Group A Campbell Brothers Limited Company

64 ALS Group USA, Corp Date: 16-Nov-15 Client: Merit Energy Work Order: Work Order Sample Summary Lab Samp ID Client Sample ID Matrix Tag Number Collection Date Date Received MW-7 Groundwater 11/4/215 11:4 11/6/215 8: MW-3 Groundwater 11/4/215 13:45 11/6/215 8: MW-6 Groundwater 11/5/215 7:15 11/6/215 8: MW-5 Groundwater 11/5/215 7:55 11/6/215 8: MW-1 Groundwater 11/5/215 8:3 11/6/215 8: MW-2 Groundwater 11/5/215 9:5 11/6/215 8: MW-4 Groundwater 11/5/215 1:1 11/6/215 8: Hold Sample Summary Page 1 of 1

65 ALS Group USA, Corp Date: 16-Nov-15 Client: Merit Energy Work Order: Sample ID: MW-7 Lab ID: Collection Date: 11/4/215 11:4 AM Matrix: GROUWATER Analyses Result Qual Report Dilution Limit Units Factor Date Analyzed SEMI-VOLATILE ORGANIC COMPOUS SW D Prep: SW351 / 11/11/15 Analyst: RM Sulfolane 88 1 µg/l 1 11/14/215 2:57 PM Surr: 2,4,6-Tribromophenol %REC 1 11/12/215 11:14 PM Surr: 2-Fluorobiphenyl %REC 1 11/12/215 11:14 PM Surr: 2-Fluorophenol %REC 1 11/12/215 11:14 PM Surr: 4-Terphenyl-d %REC 1 11/12/215 11:14 PM Surr: Nitrobenzene-d %REC 1 11/12/215 11:14 PM Surr: Phenol-d %REC 1 11/12/215 11:14 PM See Qualifiers page for a list of qualifiers and their definitions. Analytical Results Page 1 of 7

66 ALS Group USA, Corp Date: 16-Nov-15 Client: Merit Energy Work Order: Sample ID: MW-3 Lab ID: Collection Date: 11/4/215 1:45 PM Matrix: GROUWATER Analyses Result Qual Report Dilution Limit Units Factor Date Analyzed SEMI-VOLATILE ORGANIC COMPOUS SW D Prep: SW351 / 11/11/15 Analyst: RM Sulfolane 1 µg/l 1 11/14/215 3:17 PM Surr: 2,4,6-Tribromophenol %REC 1 11/14/215 3:17 PM Surr: 2-Fluorobiphenyl %REC 1 11/14/215 3:17 PM Surr: 2-Fluorophenol %REC 1 11/14/215 3:17 PM Surr: 4-Terphenyl-d %REC 1 11/14/215 3:17 PM Surr: Nitrobenzene-d %REC 1 11/14/215 3:17 PM Surr: Phenol-d %REC 1 11/14/215 3:17 PM See Qualifiers page for a list of qualifiers and their definitions. Analytical Results Page 2 of 7

67 ALS Group USA, Corp Date: 16-Nov-15 Client: Merit Energy Work Order: Sample ID: MW-6 Lab ID: Collection Date: 11/5/215 7:15 AM Matrix: GROUWATER Analyses Result Qual Report Dilution Limit Units Factor Date Analyzed SEMI-VOLATILE ORGANIC COMPOUS SW D Prep: SW351 / 11/11/15 Analyst: RM Sulfolane 1 µg/l 1 11/14/215 3:37 PM Surr: 2,4,6-Tribromophenol %REC 1 11/14/215 3:37 PM Surr: 2-Fluorobiphenyl %REC 1 11/14/215 3:37 PM Surr: 2-Fluorophenol %REC 1 11/14/215 3:37 PM Surr: 4-Terphenyl-d %REC 1 11/14/215 3:37 PM Surr: Nitrobenzene-d %REC 1 11/14/215 3:37 PM Surr: Phenol-d %REC 1 11/14/215 3:37 PM See Qualifiers page for a list of qualifiers and their definitions. Analytical Results Page 3 of 7

68 ALS Group USA, Corp Date: 16-Nov-15 Client: Merit Energy Work Order: Sample ID: MW-5 Lab ID: Collection Date: 11/5/215 7:55 AM Matrix: GROUWATER Analyses Result Qual Report Dilution Limit Units Factor Date Analyzed SEMI-VOLATILE ORGANIC COMPOUS SW D Prep: SW351 / 11/11/15 Analyst: RM Sulfolane 1 µg/l 1 11/13/215 12:15 PM Surr: 2,4,6-Tribromophenol %REC 1 11/13/215 12:15 PM Surr: 2-Fluorobiphenyl %REC 1 11/13/215 12:15 PM Surr: 2-Fluorophenol %REC 1 11/13/215 12:15 PM Surr: 4-Terphenyl-d %REC 1 11/13/215 12:15 PM Surr: Nitrobenzene-d %REC 1 11/13/215 12:15 PM Surr: Phenol-d %REC 1 11/13/215 12:15 PM See Qualifiers page for a list of qualifiers and their definitions. Analytical Results Page 4 of 7

69 ALS Group USA, Corp Date: 16-Nov-15 Client: Merit Energy Work Order: Sample ID: MW-1 Lab ID: Collection Date: 11/5/215 8:3 AM Matrix: GROUWATER Analyses Result Qual Report Dilution Limit Units Factor Date Analyzed SEMI-VOLATILE ORGANIC COMPOUS SW D Prep: SW351 / 11/11/15 Analyst: RM Sulfolane 1 µg/l 1 11/13/215 12:36 PM Surr: 2,4,6-Tribromophenol %REC 1 11/13/215 12:36 PM Surr: 2-Fluorobiphenyl %REC 1 11/13/215 12:36 PM Surr: 2-Fluorophenol %REC 1 11/13/215 12:36 PM Surr: 4-Terphenyl-d %REC 1 11/13/215 12:36 PM Surr: Nitrobenzene-d %REC 1 11/13/215 12:36 PM Surr: Phenol-d %REC 1 11/13/215 12:36 PM See Qualifiers page for a list of qualifiers and their definitions. Analytical Results Page 5 of 7

70 ALS Group USA, Corp Date: 16-Nov-15 Client: Merit Energy Work Order: Sample ID: MW-2 Lab ID: Collection Date: 11/5/215 9:5 AM Matrix: GROUWATER Analyses Result Qual Report Dilution Limit Units Factor Date Analyzed SEMI-VOLATILE ORGANIC COMPOUS SW D Prep: SW351 / 11/11/15 Analyst: RM Sulfolane 1 µg/l 1 11/13/215 12:56 PM Surr: 2,4,6-Tribromophenol %REC 1 11/13/215 12:56 PM Surr: 2-Fluorobiphenyl %REC 1 11/13/215 12:56 PM Surr: 2-Fluorophenol %REC 1 11/13/215 12:56 PM Surr: 4-Terphenyl-d %REC 1 11/13/215 12:56 PM Surr: Nitrobenzene-d %REC 1 11/13/215 12:56 PM Surr: Phenol-d %REC 1 11/13/215 12:56 PM See Qualifiers page for a list of qualifiers and their definitions. Analytical Results Page 6 of 7

71 ALS Group USA, Corp Date: 16-Nov-15 Client: Merit Energy Work Order: Sample ID: MW-4 Lab ID: Collection Date: 11/5/215 1:1 AM Matrix: GROUWATER Analyses Result Qual Report Dilution Limit Units Factor Date Analyzed SEMI-VOLATILE ORGANIC COMPOUS SW D Prep: SW351 / 11/11/15 Analyst: RM Sulfolane 1 µg/l 1 11/13/215 1:17 AM Surr: 2,4,6-Tribromophenol %REC 1 11/13/215 1:17 AM Surr: 2-Fluorobiphenyl %REC 1 11/13/215 1:17 AM Surr: 2-Fluorophenol %REC 1 11/13/215 1:17 AM Surr: 4-Terphenyl-d %REC 1 11/13/215 1:17 AM Surr: Nitrobenzene-d %REC 1 11/13/215 1:17 AM Surr: Phenol-d %REC 1 11/13/215 1:17 AM See Qualifiers page for a list of qualifiers and their definitions. Analytical Results Page 7 of 7

72 ALS Group USA, Corp Client: Merit Energy Work Order: Date: 16-Nov-15 QC BATCH REPORT Batch ID: Instrument ID SVMS5 Method: SW D MBLK Sample ID: SBLKW Units: µg/l Client ID: Run ID: SVMS5_151111A SeqNo: Analysis Date: 11/11/215 5:33 PM Prep Date: 11/11/215 DF: 1 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD RPD Limit Qual Sulfolane 1 Surr: 2,4,6-Tribromophenol Surr: 2-Fluorobiphenyl Surr: 2-Fluorophenol Surr: 4-Terphenyl-d Surr: Nitrobenzene-d Surr: Phenol-d MBLK Sample ID: SBLKW Units: µg/l Client ID: Run ID: SVMS6_151112A SeqNo: Analysis Date: 11/12/215 1:32 PM Prep Date: 11/11/215 DF: 1 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD RPD Limit Qual Sulfolane 1 Surr: 2,4,6-Tribromophenol Surr: 2-Fluorobiphenyl Surr: 2-Fluorophenol Surr: 4-Terphenyl-d Surr: Nitrobenzene-d Surr: Phenol-d LCS Sample ID: SLCSW Units: µg/l Client ID: Run ID: SVMS6_151112A SeqNo: Analysis Date: 11/12/215 1:53 PM Prep Date: 11/11/215 DF: 1 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD RPD Limit Qual Sulfolane Surr: 2,4,6-Tribromophenol Surr: 2-Fluorobiphenyl Surr: 2-Fluorophenol Surr: 4-Terphenyl-d Surr: Nitrobenzene-d Surr: Phenol-d The following samples were analyzed in this batch: A A A A A A A See Qualifiers Page for a list of Qualifiers and their explanation. QC Page: 1 of 1

73 ALS Group USA, Corp Client: Merit Energy WorkOrder: Date: 16-Nov-15 QUALIFIERS, ACRONYMS, UNITS Qualifier * a B E H J n O P R S U X Acronym DUP LCS LCSD LOD LOQ MBLK MDL MS MSD PQL RPD TDL TNTC A D E SW Units Reported µg/l Description Value exceeds Regulatory Limit Not accredited Analyte detected in the associated Method Blank above the Reporting Limit Value above quantitation range Analyzed outside of Holding Time Analyte is present at an estimated concentration between the MDL and Report Limit Not offered for accreditation Not Detected at the Reporting Limit Sample amount is > 4 times amount spiked Dual Column results percent difference > 4% RPD above laboratory control limit Spike Recovery outside laboratory control limits Analyzed but not detected above the MDL Analyte was detected in the Method Blank between the MDL and PQL, sample results may exhibit background or reagent contamination at the observed level. Description Method Duplicate Laboratory Control Sample Laboratory Control Sample Duplicate Limit of Detection (see MDL) Limit of Quantitation (see PQL) Method Blank Method Detection Limit Matrix Spike Matrix Spike Duplicate Practical Quantitation Limit Relative Percent Difference Target Detection Limit Too Numerous To Count APHA Standard Methods ASTM EPA SW-846 Update III Description Micrograms per Liter QF Page 1 of 1

74 ALS Group USA, Corp Sample Receipt Checklist Client Name: MERITENERGY Date/Time Received: 6-Nov-15 8: Work Order: Received by: DS Checklist completed by Diane Shaw Gary Byar 6-Nov-15 Reviewed by: esignature Date esignature Matrices: Groundwater Carrier name: Courier 6-Nov-15 Date Shipping container/cooler in good condition? Yes No Not Present Custody seals intact on shipping container/cooler? Yes No Not Present Custody seals intact on sample bottles? Yes No Not Present Chain of custody present? Yes No Chain of custody signed when relinquished and received? Yes No Chain of custody agrees with sample labels? Yes No Samples in proper container/bottle? Yes No Sample containers intact? Yes No Sufficient sample volume for indicated test? Yes No All samples received within holding time? Yes No Container/Temp Blank temperature in compliance? Yes No Sample(s) received on ice? Yes No Temperature(s)/Thermometer(s): 4.4/4.4 c SR2 Cooler(s)/Kit(s): Date/Time sample(s) sent to storage: Water - VOA vials have zero headspace? 11/6/215 1:37:15 AM Yes No No VOA vials submitted Water - ph acceptable upon receipt? Yes No N/A ph adjusted? Yes No N/A ph adjusted by: Login Notes: Client Contacted: Date Contacted: Person Contacted: Contacted By: Regarding: Comments: CorrectiveAction: SRC Page 1 of 1

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76 ALS Group USA, Corp Date: 2-Nov-15 Client: Merit Energy Work Order: Sample ID: W-PIT-2 Lab ID: Collection Date: 11/13/215 9: AM Matrix: GROUWATER Analyses Result Qual Report Dilution Limit Units Factor Date Analyzed SEMI-VOLATILE ORGANIC COMPOUS SW D Prep: SW351 / 11/17/15 Analyst: JG Sulfolane 14, 1, µg/l 1 11/19/215 7:29 PM Surr: 2,4,6-Tribromophenol %REC 1 11/18/215 3:42 PM Surr: 2-Fluorobiphenyl %REC 1 11/18/215 3:42 PM Surr: 2-Fluorophenol %REC 1 11/18/215 3:42 PM Surr: 4-Terphenyl-d %REC 1 11/18/215 3:42 PM Surr: Nitrobenzene-d %REC 1 11/18/215 3:42 PM Surr: Phenol-d %REC 1 11/18/215 3:42 PM See Qualifiers page for a list of qualifiers and their definitions. Analytical Results Page 1 of 4

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78 3-Feb-216 Sean Craven Merit Energy 151 Thomas Rd PO Box 91 Kalkaska, MI Re: Merit (Former Hartland 36 NGP) Work Order: Dear Sean, ALS Environmental received 6 samples on 28-Jan-216 9: AM for the analyses presented in the following report. The analytical data provided relates directly to the samples received by ALS Environmental and for only the analyses requested. Sample results are compliant with NELAP standard requirements and QC results achieved laboratory specifications. Any exceptions are noted in the Case Narrative, or noted with qualifiers in the report or QC batch information. Should this laboratory report need to be reproduced, it should be reproduced in full unless written approval has been obtained from ALS Environmental. Samples will be disposed in 3 days unless storage arrangements are made. The total number of pages in this report is 14. If you have any questions regarding this report, please feel free to contact me. Sincerely, Gary Byar Electronically approved by: Gary Byar Gary Byar Project Manager Certificate No: MI: 22 Report of Laboratory Analysis ADDRESS th Avenue Holland, Michigan PHONE (616) FAX (616) ALS GROUP USA, CORP Part of the ALS Laboratory Group A Campbell Brothers Limited Company

79 ALS Group USA, Corp Date: 3-Feb-16 Client: Merit Energy Project: Merit (Former Hartland 36 NGP) Work Order: Work Order Sample Summary Lab Samp ID Client Sample ID Matrix Tag Number Collection Date Date Received MW-1 Water 1/27/216 12:3 1/28/216 9: MW-2 Water 1/27/216 13:3 1/28/216 9: MW-4 Water 1/27/216 17:5 1/28/216 9: MW-5 Water 1/27/216 11:35 1/28/216 9: MW-6 Water 1/27/216 1:25 1/28/216 9: MW-7 Water 1/27/216 15:2 1/28/216 9: Hold Sample Summary Page 1 of 1

80 ALS Group USA, Corp Date: 3-Feb-16 Client: Merit Energy Project: Merit (Former Hartland 36 NGP) Work Order: Sample ID: MW-1 Lab ID: Collection Date: 1/27/216 12:3 PM Matrix: WATER Analyses Result Qual Report Dilution Limit Units Factor Date Analyzed SEMI-VOLATILE ORGANIC COMPOUS SW D Prep: SW351 / 2/1/16 Analyst: RM Sulfolane 1 µg/l 1 2/2/216 1:7 AM Surr: 2,4,6-Tribromophenol %REC 1 2/2/216 1:7 AM Surr: 2-Fluorobiphenyl %REC 1 2/2/216 1:7 AM Surr: 2-Fluorophenol %REC 1 2/2/216 1:7 AM Surr: 4-Terphenyl-d %REC 1 2/2/216 1:7 AM Surr: Nitrobenzene-d %REC 1 2/2/216 1:7 AM Surr: Phenol-d %REC 1 2/2/216 1:7 AM See Qualifiers page for a list of qualifiers and their definitions. Analytical Results Page 1 of 6

81 ALS Group USA, Corp Date: 3-Feb-16 Client: Merit Energy Project: Merit (Former Hartland 36 NGP) Work Order: Sample ID: MW-2 Lab ID: Collection Date: 1/27/216 1:3 PM Matrix: WATER Analyses Result Qual Report Dilution Limit Units Factor Date Analyzed SEMI-VOLATILE ORGANIC COMPOUS SW D Prep: SW351 / 2/1/16 Analyst: RM Sulfolane 1 µg/l 1 2/2/216 1:27 AM Surr: 2,4,6-Tribromophenol %REC 1 2/2/216 1:27 AM Surr: 2-Fluorobiphenyl %REC 1 2/2/216 1:27 AM Surr: 2-Fluorophenol %REC 1 2/2/216 1:27 AM Surr: 4-Terphenyl-d %REC 1 2/2/216 1:27 AM Surr: Nitrobenzene-d %REC 1 2/2/216 1:27 AM Surr: Phenol-d %REC 1 2/2/216 1:27 AM See Qualifiers page for a list of qualifiers and their definitions. Analytical Results Page 2 of 6

82 ALS Group USA, Corp Date: 3-Feb-16 Client: Merit Energy Project: Merit (Former Hartland 36 NGP) Work Order: Sample ID: MW-4 Lab ID: Collection Date: 1/27/216 5:5 PM Matrix: WATER Analyses Result Qual Report Dilution Limit Units Factor Date Analyzed SEMI-VOLATILE ORGANIC COMPOUS SW D Prep: SW351 / 2/1/16 Analyst: RM Sulfolane 11 µg/l 1 2/2/216 1:47 AM Surr: 2,4,6-Tribromophenol %REC 1 2/2/216 1:47 AM Surr: 2-Fluorobiphenyl %REC 1 2/2/216 1:47 AM Surr: 2-Fluorophenol %REC 1 2/2/216 1:47 AM Surr: 4-Terphenyl-d %REC 1 2/2/216 1:47 AM Surr: Nitrobenzene-d %REC 1 2/2/216 1:47 AM Surr: Phenol-d %REC 1 2/2/216 1:47 AM See Qualifiers page for a list of qualifiers and their definitions. Analytical Results Page 3 of 6

83 ALS Group USA, Corp Date: 3-Feb-16 Client: Merit Energy Project: Merit (Former Hartland 36 NGP) Work Order: Sample ID: MW-5 Lab ID: Collection Date: 1/27/216 11:35 AM Matrix: WATER Analyses Result Qual Report Dilution Limit Units Factor Date Analyzed SEMI-VOLATILE ORGANIC COMPOUS SW D Prep: SW351 / 2/1/16 Analyst: RM Sulfolane 1 µg/l 1 2/2/216 2:7 AM Surr: 2,4,6-Tribromophenol %REC 1 2/2/216 2:7 AM Surr: 2-Fluorobiphenyl %REC 1 2/2/216 2:7 AM Surr: 2-Fluorophenol %REC 1 2/2/216 2:7 AM Surr: 4-Terphenyl-d %REC 1 2/2/216 2:7 AM Surr: Nitrobenzene-d %REC 1 2/2/216 2:7 AM Surr: Phenol-d %REC 1 2/2/216 2:7 AM See Qualifiers page for a list of qualifiers and their definitions. Analytical Results Page 4 of 6

84 ALS Group USA, Corp Date: 3-Feb-16 Client: Merit Energy Project: Merit (Former Hartland 36 NGP) Work Order: Sample ID: MW-6 Lab ID: Collection Date: 1/27/216 1:25 AM Matrix: WATER Analyses Result Qual Report Dilution Limit Units Factor Date Analyzed SEMI-VOLATILE ORGANIC COMPOUS SW D Prep: SW351 / 2/1/16 Analyst: RM Sulfolane 1 µg/l 1 2/2/216 2:27 AM Surr: 2,4,6-Tribromophenol %REC 1 2/2/216 2:27 AM Surr: 2-Fluorobiphenyl %REC 1 2/2/216 2:27 AM Surr: 2-Fluorophenol %REC 1 2/2/216 2:27 AM Surr: 4-Terphenyl-d %REC 1 2/2/216 2:27 AM Surr: Nitrobenzene-d %REC 1 2/2/216 2:27 AM Surr: Phenol-d %REC 1 2/2/216 2:27 AM See Qualifiers page for a list of qualifiers and their definitions. Analytical Results Page 5 of 6

85 ALS Group USA, Corp Date: 3-Feb-16 Client: Merit Energy Project: Merit (Former Hartland 36 NGP) Work Order: Sample ID: MW-7 Lab ID: Collection Date: 1/27/216 3:2 PM Matrix: WATER Analyses Result Qual Report Dilution Limit Units Factor Date Analyzed SEMI-VOLATILE ORGANIC COMPOUS SW D Prep: SW351 / 2/1/16 Analyst: RM Sulfolane 44 1 µg/l 1 2/2/216 2:47 AM Surr: 2,4,6-Tribromophenol %REC 1 2/2/216 2:47 AM Surr: 2-Fluorobiphenyl %REC 1 2/2/216 2:47 AM Surr: 2-Fluorophenol %REC 1 2/2/216 2:47 AM Surr: 4-Terphenyl-d %REC 1 2/2/216 2:47 AM Surr: Nitrobenzene-d %REC 1 2/2/216 2:47 AM Surr: Phenol-d %REC 1 2/2/216 2:47 AM See Qualifiers page for a list of qualifiers and their definitions. Analytical Results Page 6 of 6

86 ALS Group USA, Corp Client: Merit Energy Work Order: Project: Merit (Former Hartland 36 NGP) Date: 3-Feb-16 QC BATCH REPORT Batch ID: 8199 Instrument ID SVMS8 Method: SW D MBLK Sample ID: SBLKW Units: µg/l Client ID: Run ID: SVMS8_1621A SeqNo: Analysis Date: 2/1/216 9:27 PM Prep Date: 2/1/216 DF: 1 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD RPD Limit Qual Sulfolane 1 Surr: 2,4,6-Tribromophenol Surr: 2-Fluorobiphenyl Surr: 2-Fluorophenol Surr: 4-Terphenyl-d Surr: Nitrobenzene-d Surr: Phenol-d LCS Sample ID: SLCSW Units: µg/l Client ID: Run ID: SVMS8_1621A SeqNo: Analysis Date: 2/1/216 9:47 PM Prep Date: 2/1/216 DF: 1 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD RPD Limit Qual Sulfolane Surr: 2,4,6-Tribromophenol Surr: 2-Fluorobiphenyl Surr: 2-Fluorophenol Surr: 4-Terphenyl-d Surr: Nitrobenzene-d Surr: Phenol-d LCSD Sample ID: SLCSDW Units: µg/l Client ID: Run ID: SVMS8_1621A SeqNo: Analysis Date: 2/1/216 1:7 PM Prep Date: 2/1/216 DF: 1 SPK Ref Control RPD Ref Analyte Result PQL SPK Val Value %REC Limit Value %RPD RPD Limit Qual Sulfolane Surr: 2,4,6-Tribromophenol Surr: 2-Fluorobiphenyl Surr: 2-Fluorophenol Surr: 4-Terphenyl-d Surr: Nitrobenzene-d Surr: Phenol-d The following samples were analyzed in this batch: A A A A A A See Qualifiers Page for a list of Qualifiers and their explanation. QC Page: 1 of 1

87 ALS Group USA, Corp Client: Merit Energy Project: Merit (Former Hartland 36 NGP) WorkOrder: Date: 3-Feb-16 QUALIFIERS, ACRONYMS, UNITS Qualifier * a B E H J n O P R S U X Acronym DUP LCS LCSD LOD LOQ MBLK MDL MS MSD PQL RPD TDL TNTC A D E SW Units Reported µg/l Description Value exceeds Regulatory Limit Not accredited Analyte detected in the associated Method Blank above the Reporting Limit Value above quantitation range Analyzed outside of Holding Time Analyte is present at an estimated concentration between the MDL and Report Limit Not offered for accreditation Not Detected at the Reporting Limit Sample amount is > 4 times amount spiked Dual Column results percent difference > 4% RPD above laboratory control limit Spike Recovery outside laboratory control limits Analyzed but not detected above the MDL Analyte was detected in the Method Blank between the MDL and PQL, sample results may exhibit background or reagent contamination at the observed level. Description Method Duplicate Laboratory Control Sample Laboratory Control Sample Duplicate Limit of Detection (see MDL) Limit of Quantitation (see PQL) Method Blank Method Detection Limit Matrix Spike Matrix Spike Duplicate Practical Quantitation Limit Relative Percent Difference Target Detection Limit Too Numerous To Count APHA Standard Methods ASTM EPA SW-846 Update III Description Micrograms per Liter QF Page 1 of 1

88 ALS Group USA, Corp Sample Receipt Checklist Client Name: MERITENERGY Date/Time Received: 28-Jan-16 9: Work Order: Received by: DS Checklist completed by Diane Shaw Gary Byar 28-Jan-16 Reviewed by: esignature Date esignature Matrices: Water Carrier name: FedEx 28-Jan-16 Date Shipping container/cooler in good condition? Yes No Not Present Custody seals intact on shipping container/cooler? Yes No Not Present Custody seals intact on sample bottles? Yes No Not Present Chain of custody present? Yes No Chain of custody signed when relinquished and received? Yes No Chain of custody agrees with sample labels? Yes No Samples in proper container/bottle? Yes No Sample containers intact? Yes No Sufficient sample volume for indicated test? Yes No All samples received within holding time? Yes No Container/Temp Blank temperature in compliance? Yes No Sample(s) received on ice? Yes No Temperature(s)/Thermometer(s): 2.8/2.8, 3.2/3.2 c SR2 Cooler(s)/Kit(s): Date/Time sample(s) sent to storage: Water - VOA vials have zero headspace? 1/28/216 11:17:1 AM Yes No No VOA vials submitted Water - ph acceptable upon receipt? Yes No N/A ph adjusted? Yes No N/A ph adjusted by: Login Notes: Client Contacted: Date Contacted: Person Contacted: Contacted By: Regarding: Comments: CorrectiveAction: SRC Page 1 of 1

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