Reaction Rate and Equilibrium Chapter 19 Assignment & Problem Set
|
|
- MargaretMargaret Berry
- 6 years ago
- Views:
Transcription
1 Reaction Rate and Equilibrium Name Warm-Ups (Show your work for credit) Date 1. Date 2. Date 3. Date 4. Date 5. Date 6. Date 7. Date 8.
2 Reaction Rate and Equilibrium 2 Study Guide: Things You Must Know Vocabulary (know the definition and what it means): rate of reaction collision theory molecular orientation during a collision potential energy and kinetic energy potential Energy diagram activation energy transition state or activated complex catalyst and inhibitor endothermic and exothermic heat of reaction or enthalpy reversible reaction equilibrium (both chemical and physical) and the extent of a reaction Honors: equilibrium constant (K eq) LeChatelier s principle stress to an equilibrium thermodynamics spontaneous and nonspontaneous reaction entropy and randomness Honors: Gibbs free energy Learning Objectives: factors that influence the rate of a reaction. collision theory. how to draw, label and interpret potential energy diagrams including: determining the heat of a reaction determining whether a reaction is endo- or exothermic calculating the activation energy of the forward and reverse reaction. how to determine the heat of a reaction using Table I. how a catalyst and inhibitor affect the rate of a reaction. what is meant by a reversible reaction. Honors: how to calculate the equilibrium constant for a chemical reaction. Honors: how to determine whether there are mostly reactants or products at equilibrium given K eq. how to determine shifts in equilibrium due to changes in concentration, pressure, volume, and temperature using Le Chatelier s principle. factors that determine entropy. how to determine whether a chemical reaction is spontaneous or nonspontaneous by evaluating enthalpy and entropy. Honors: how to calculate Gibbs free energy to determine whether a chemical reaction is spontaneous or nonspontaneous. Key Reference Tables Table I: Heats of Reaction at kpa and 298 K
3 Reaction Rate and Equilibrium 3 Read Chapter 19: Reaction Rate and Equilibrium. All students skip entropy calculations and free-energy calculations (pp ) and rate law & reaction mechanisms (pp ). Lab 20: Equilibrium & LeChatelier s Principle Regents Table I: Heats of Reaction Warm-ups and problems will be collected before you take the test. Answer all problems in the space provided. For problems involving an equation, carry out the following steps: 1. Write the equation. 2. Substitute numbers and units. 3. Show the final answer with units. There is no credit without showing work. Collision Theory 1. What is meant by rate of a chemical reaction? 2. Define activation energy. 3. Define collision theory? 4. Does every collision between reacting particles lead to products? Explain. 5. Draw a potential energy diagram (potential energy vs. reaction progress) for the reaction below. On your diagram, be sure to label both axes. Draw a vertical double-arrow showing the energy of the reactants, the energy of the products, the activation energy, and H. CO(g) + NO 2(g) CO 2(g) + NO(g) H = -54 kcal 6. For the reaction in the above problem, how much heat is released when 25 grams of NO are produced? 7. Sketch an energy profile curve (potential energy diagram) for the gas-phase reaction shown below. The reaction has an activation energy of 22 kj, and the total energy change ( H) is -103 kj. F(g) + H 2(g) HF(g) + H(g)
4 Reaction Rate and Equilibrium 4 8. For the reaction A + B C, the activation energy of the forward reaction is 5kJ and the total energy change is -20kJ. What is the activation energy of the reverse reaction? 9. How does each factor affect the rate of a chemical reaction (increase or decrease)? a. temperature b. concentration c. particle size d. catalyst 10. Refrigerated food stays fresh for long periods. The same food stored at room temperature quickly spoils. Why? 11. Where is the formula of a catalyst written in a chemical equation? Why? 12. The reaction of hydrogen and oxygen gas to produce water is very slow at room temperature but occurs with explosive rapidity in the presence of a flame or ignition wire. Explain. Chemical Equilibrium and the Equilibrium Constant 13. What is the significance of double arrows in an equation? 14. Define chemical equilibrium. How do the rates of the forward and reverse reactions compare at equilibrium? 15. How do the amounts of reactants and products change once a reaction has achieved chemical equilibrium? 16. Give two examples of physical equilibria. 17. Honors Write the expression for the equilibrium constant for each reaction. a. 4H 2(g) + CS 2(g) CH 4(g) + 2H 2S(g) b. 2NO(g) + O 2(g) 2NO 2(g) 18. Honors Imagine you have determined the following equilibrium constants for several reactions. State which of these reactions favor products and which favor reactants? a. K eq = 1 x 10 2 b. K eq = c. K eq = 3.5 d. K eq = 6 x 10-4
5 Reaction Rate and Equilibrium Honors Analysis of an equilibrium mixture of nitrogen, hydrogen, and ammonia contained in a 3.0 L flask at 300 o C gives the following results: 0.15 mol hydrogen; 0.25 mol nitrogen; 0.10 mol ammonia. Calculate K eq for the reaction: N 2(g) + 3H 2(g) 2NH 3(g) 20. Honors Suppose the following system reaches equilibrium at a high temperature. N 2(g) + O 2(g) 2NO(g) An analysis of the equilibrium mixture in a 0.50 L flask gives the following results: nitrogen, 0.50 mol; oxygen, 0.50 mol; nitrogen monoxide, mol. Calculate K eq for the reaction. 21. Honors For the following reaction at equilibrium at 827 o C, the following amounts were determined: mol CO 2, mol H 2, mol CO and mol H 2O. What is the value of K eq? CO 2(g) + H 2(g) CO(g) + H 2O(g). Chemical Equilibrium and LeChatelier s Principle 22. Define LeChatelier s Principle. 23. How is the equilibrium position (right or left) of this reaction affected by the following changes? C(s) + H 2O(l) + heat CO(g) + H 2(g) a. lowering the temperature b. decreasing the pressure c. removing H 2 d. adding H What would be the effect on the equilibrium position (shift to products or reactants) if the volume were decreased in each reaction? a. 4HCl(g ) + O 2(g) 2Cl 2(g) + 2H 2O(g) b. CO 2(s) CO 2(g) c. CaCO 3(s) CaO(s) + CO 2(g)
6 Reaction Rate and Equilibrium How does the equilibrium shift (right or left) in the reaction below? N 2(g) + 3H 2(g) 2NH 3(g) a. if the pressure is increased b. if volume is increased c. if heat is added d. if a catalyst is added e. if the temperature is decreased f. if ammonia is removed 26. Honors Is eating sugar candy really bad for your teeth? Tooth decay is the result of the dissolving of tooth enamel (Ca 3(PO 4) 3OH). In the mouth the following equilibrium is established. Ca 3(PO 4) 3OH 5Ca +2 (aq) + 3PO 4-3 (aq) + OH - (aq) When sugar ferments on teeth, H + is produced. What effect does increased H + have on tooth enamel? Explain 27. Honors The freezing of liquid water at 0 o C can be represented as follows: H 2O(l,d=1.00g/cm 3 ) H 2O(s,d = 0.92g/cm 3 ) where d = density. Explain why the application of pressure causes ice to melt. Thermodynamics 28. Define spontaneous reaction. 29. What two factors determine whether a reaction is spontaneous? 30. Define entropy and enthalpy. 31. Which system has the lower entropy? a. completed jigsaw puzzle or separate jigsaw pieces b. 50 ml of liquid water or 50 ml of ice c. 10g of sodium chloride crystals or a solution containing 10 g of sodium chloride d. a solid at 30 o C or the same solid at 400 o C e. clean water or dirty water
7 Reaction Rate and Equilibrium Predict the direction of the entropy change (increase or decrease?) in each reaction. a. CaCO 3(s) CaO(s) + CO 2(g) b. 2NH 3(g) + HCl(g) NH 4Cl(s) c. 2NaHCO 3(s) Ca 2CO 3(s) + H 2O(l) + CO 2(g) d. C(s) + O 2(g) CO 2(g) 33. Describe how entropy and enthalpy are related in predicting whether a reaction is spontaneous. 34. Use Regents Table I and your prediction of entropy change to predict whether the following reaction is spontaneous: N 2(g) + 2O 2(g) 2NO 2(g) 35. Is it true that all spontaneous processes are exothermic? Explain your answer. 36. Honors What single thermodynamic quantity tells you if a reaction is spontaneous? How? 37. Honors What is the equation relating entropy and enthalpy to free energy? 38. Honors For the reaction: 2NO(g) + O 2(g) 2NO 2(g) predict whether this reaction is spontaneous at -100 o C and at +800 o C given that H =-27.4 kcal and S = cal/k. Review 39. What is wrong with saying that solid potassium chloride is composed of KCl molecules? 40. Name the following compounds and give the charge on the anion for each. a. NaClO 4 b. Ca 3(PO 4) 2 c. Na 2SO 4 d. SnO e. MgCO 3 f. K 2Cr 2O 7
Reaction Rates & Equilibrium. What determines how fast a reaction takes place? What determines the extent of a reaction?
Reaction Rates & Equilibrium What determines how fast a reaction takes place? What determines the extent of a reaction? Reactants Products 1 Reaction Rates Vary TNT exploding. A car rusting. Dead plants
More informationReaction Rates & Equilibrium. What determines how fast a reaction takes place? What determines the extent of a reaction?
Reaction Rates & Equilibrium What determines how fast a reaction takes place? What determines the extent of a reaction? Reactants Products 1 Reaction Rates Vary TNT exploding. A car rusting. Dead plants
More informationName: Unit!!: Kinetics and Equilibrium REGENTS CHEMISTRY
Name: Unit!!: Kinetics and Equilibrium REGENTS CHEMISTRY 1 Name: Unit!!: Kinetics and Equilibrium Collision theory states that a reaction is most likely to occur if reactant particles collide with the
More informationChapter Seven. Chemical Reactions: Energy, Rates, and Equilibrium
Chapter Seven Chemical Reactions: Energy, Rates, and Equilibrium Endothermic vs. Exothermic 2 Endothermic: A process or reaction that absorbs heat and has a positive ΔH. Exothermic: A process or reaction
More information1. As the number of effective collisions between reacting particles increases, the rate of reaction (1) decreases (3) remains the same (2) increases
1. As the number of effective collisions between reacting particles increases, the rate of reaction (1) decreases (3) remains the same (2) increases 2. The energy needed to start a chemical reaction is
More information(g) burns according to this reaction? D) CH 4 (g) + 2O 2 (g) CO 2 (g) + 2H 2 O(l)
Name: 7171-1 - Page 1 1) In a chemical reaction, the difference between the potential energy of the products and the potential energy of the reactants is defined as the A) heat of reaction B) ionization
More informationKinetics & Equilibrium Review Packet. Standard Level. 1. Which quantities in the enthalpy level diagram are altered by the use of a catalyst?
Kinetics & Equilibrium Review Packet Standard Level 1. Which quantities in the enthalpy level diagram are altered by the use of a catalyst? Enthalpy I II III Time A. I and II only B. I and III only C.
More informationCHAPTER 16 REVIEW. Reaction Energy. SHORT ANSWER Answer the following questions in the space provided.
CHAPTER 16 REVIEW Reaction Energy SECTION 1 SHORT ANSWER Answer the following questions in the space provided. 1. For elements in their standard state, the value of H 0 f is 0. 2. The formation and decomposition
More informationUnit 2 Pre-Test Reaction Equilibrium
Unit 2 Pre-Test Reaction Equilibrium Multiple Choice Identify the choice that best completes the statement or answers the question. 1. Consider the following equilibrium system: 2HF(g) F 2(g) + H 2 (g)
More information8. A piece of Mg(s) ribbon is held in a Bunsen burner flame and begins to burn according to the equation: 2Mg(s) + O2 (g) 2MgO(s).
1. Which event must always occur for a chemical reaction to take place? A) formation of a precipitate B) formation of a gas C) effective collisions between reacting particles D) addition of a catalyst
More information(b) Describe, and explain, what would happen to the position of the NO 2 /N 2 O 4 equilibrium if the following changes are made
1. Nitrogen dioxide, NO 2, and dinitrogen tetroxide, N 2 O 4, take part in the following equilibrium. 2NO 2 (g) N 2 O 4 (g) ΔH = 58 kj mol 1 (a) State le Chatelier s principle. (b) Describe, and explain,
More informationF322: Chains, Energy and Resources Rates and Equilibria
F322: Chains, Energy and Resources 2.3.2 Rates and Equilibria 1. Dilute aqueous hydrogen peroxide, H 2 O 2 (aq), is used to sterilise contact lenses. Dilute H 2 O 2 (aq) slowly decomposes at room temperature
More informationAP Chapter 14: Chemical Equilibrium & Ksp
AP Chapter 14: Chemical Equilibrium & Ksp Warm-Ups (Show your work for credit) Name Date 1. Date 2. Date 3. Date 4. Date 5. Date 6. Date 7. Date 8. AP Chapter 14: Chemical Equilibrium & Ksp 2 Warm-Ups
More informationEquilibrium & Reaction Rate
Equilibrium & Reaction Rate 1. One of the important reactions in coal gasification is the catalytic methanation reaction: CO(g) + H (g) H O(g) + CH 4 (g) H 06 kj a) Predict the direction in which this
More informationUnit 13 Kinetics & Equilibrium Page 1 of 14 Chemistry Kinetics, Entropy, Equilibrium, LeChatelier s Principle, K, Unit 13 Quiz: Unit 13 Test:
Unit 13 Kinetics & Equilibrium Page 1 of 14 Chemistry Kinetics, Entropy, Equilibrium, LeChatelier s Principle, K, Unit 13 Quiz: Unit 13 Test: Final Project: VOCABULARY: 1 Chemical equilibrium 2 equilibrium
More informationThermodynamics. 1. Which of the following processes causes an entropy decrease?
Thermodynamics 1. Which of the following processes causes an entropy decrease? A. boiling water to form steam B. dissolution of solid KCl in water C. mixing of two gases in one container D. beach erosion
More informationCHEMISTRY 12 UNIT II EQUILIBRIUM D Learning Goals
CHEMISTRY 12 UNIT II EQUILIBRIUM D Learning Goals 1. Chemical equilibrium is said to by dynamic because a. The reaction proceeds quickly b. The mass of the reactants is decreasing c. The macroscopic properties
More informationKinetics and Equilibrium Extra Credit
1. The potential energy diagram below represents the reaction 2 KClO3 2 KCl + 3 O2. 4. When AgNO3(aq) is mixed with NaCl(aq), a reaction occurs which tends to go to completion and not reach equilibrium
More informationREACTION RATES AND EQUILIBRIUM
Name Date Class 18 REACTION RATES AND EQUILIBRIUM SECTION 18.1 RATES OF REACTION (pages 541 547) This section explains what is meant by the rate of a chemical reaction. It also uses collision theory to
More informationHonors Chemistry Unit 4 Exam Study Guide Solutions, Equilibrium & Reaction Rates
Honors Chemistry Unit 4 Exam Study Guide Solutions, Equilibrium & Reaction Rates Define the following vocabulary terms. Solute Solvent Solution Molarity Molality Colligative property Electrolyte Non-electrolyte
More informationCollision Theory. Unit 12: Chapter 18. Reaction Rates. Activation Energy. Reversible Reactions. Reversible Reactions. Reaction Rates and Equilibrium
Collision Theory For reactions to occur collisions between particles must have Unit 12: Chapter 18 Reaction Rates and Equilibrium the proper orientation enough kinetic energy See Both In Action 1 2 Activation
More informationREACTION EQUILIBRIUM
REACTION EQUILIBRIUM A. REVERSIBLE REACTIONS 1. In most spontaneous reactions the formation of products is greatly favoured over the reactants and the reaction proceeds to completion (one direction). In
More informationName: Kinetics & Thermodynamics Date: Review
Name: Kinetics & Thermodynamics Date: Review 1. What is required for a chemical reaction to occur? A) standard temperature and pressure B) a catalyst added to the reaction system C) effective collisions
More informationAP Chemistry Chapter 16 Assignment. Part I Multiple Choice
Page 1 of 7 AP Chemistry Chapter 16 Assignment Part I Multiple Choice 1984 47. CH 4 (g) + 2 O 2 (g) CO 2 (g) + 2 H 2 O(l) H = 889.1 kj H f H 2 O(l) = 285.8 kj mol 1 H f CO 2 (g) = 393.3 kj mol 1 What is
More informationUNIT 15 - Reaction Energy & Reaction Kinetics. I. Thermochemistry: study of heat in chemical reactions and phase changes
I. Thermochemistry: study of heat in chemical reactions and phase changes II. A. Heat equation (change in temperature): Q = m. C. p T 1. Q = heat (unit is Joules) 2. m = mass (unit is grams) 3. C p = specific
More informationUnit 6 Kinetics and Equilibrium.docx
6-1 Unit 6 Kinetics and Equilibrium At the end of this unit, you ll be familiar with the following: Kinetics: Reaction Rate Collision Theory Reaction Mechanism Factors Affecting Rate of Reaction: o Nature
More informationHC- Kinetics and Thermodynamics Test Review Stations
HC- Kinetics and Thermodynamics Test Review Stations Station 1- Collision Theory and Factors Affecting Reaction Rate 1. Explain the collision theory of reactions. 2. Fill out the following table to review
More informationCH302 Spring 2009 Practice Exam 1 (a fairly easy exam to test basic concepts)
CH302 Spring 2009 Practice Exam 1 (a fairly easy exam to test basic concepts) 1) Complete the following statement: We can expect vapor pressure when the molecules of a liquid are held together by intermolecular
More informationWrite equilibrium law expressions from balanced chemical equations for heterogeneous and homogeneous systems. Include: mass action expression.
Equilibrium 1 UNIT 3: EQUILIBRIUM OUTCOMES All important vocabulary is in Italics and bold. Relate the concept of equilibrium to physical and chemical systems. Include: conditions necessary to achieve
More informationIn previous chapters we have studied: Why does a change occur in the first place? Methane burns but not the reverse CH 4 + 2O 2 CO 2 + 2H 2 O
Chapter 19. Spontaneous Change: Entropy and Free Energy In previous chapters we have studied: How fast does the change occur How is rate affected by concentration and temperature How much product will
More informationSurface Area (not in book) Reality Check: What burns faster, large or small pieces of wood?
Concentration Flammable materials burn faster in pure oxygen than in air because the of O 2 is greater. Hospitals must make sure that no flames are allowed near patients receiving oxygen. Surface Area
More informationGummy Bear Demonstration:
Name: Unit 8: Chemical Kinetics Date: Regents Chemistry Aim: _ Do Now: a) Using your glossary, define chemical kinetics: b) Sort the phrases on the SmartBoard into the two columns below. Endothermic Rxns
More informationUNIT 8 KINETICS & EQ: NOTE & PRACTICE PACKET
UNIT 8 KINETICS & EQ: NOTE & PRACTICE PACKET 1 2 Lesson 1: Kinetics = study of the RATE or SPEED at which REACTIONS occur A REACTION is the Reaction Mechanism = STEP BY STEP PROCESS needed to make a product;
More informationThe Factors that Determine the Equilibrium State
The Factors that Determine the Equilibrium State The equilibrium state (or the ratio of products to reactants) is determined by two factors: 1. Energy Systems tend to move toward a state of minimum potential
More informationA reversible reaction is a chemical reaction where products can react to form the reactants and vice versa.
Chemistry 12 Unit II Dynamic Equilibrium Notes II.1 The Concept of Dynamic Equilibrium A reversible reaction is a chemical reaction where products can react to form the reactants and vice versa. A reversible
More informationUnit 9 Kinetics SA Review
1. Base your answer to the following question on the information below. The equilibrium equation below is related to the manufacture of a bleaching solution. In this equation, means that chloride ions
More informationQ1. (a) State what is meant by the term activation energy of a reaction. (1)
Q1. (a) State what is meant by the term activation energy of a reaction. (c) State in general terms how a catalyst increases the rate of a chemical reaction. The curve below shows the Maxwell Boltzmann
More informationEquilibrium and Reaction Rate
Equilibrium and Reaction Rate Multiple Choice Questions - Answers 1. Activation energy could be considered as the minimum energy required to do which of these? A. change the orientation of the reactant
More informationUnit 8: Equilibrium Unit Review
1. Predict the effect of increasing pressure on the position of equilibrium in the following systems: a. CH 4 (g) + 2H 2 O(g) CO 2 (g) + 4H 2 (g) b. N 2 O 5 (g) + NO(g) 3NO 2 (g) c. NO(g) + NO 2 (g) N
More informationChapter 18. Reversible Reactions. A chemical reaction in which the products can react to re-form the reactants is called a reversible reaction.
Section 1 The Nature of Chemical Equilibrium Reversible Reactions A chemical reaction in which the products can react to re-form the reactants is called a reversible reaction. Section 1 The Nature of Chemical
More information8. The table below describes two different reactions in which Reaction 1 is faster. What accounts for this observation? Reaction 1 Reaction 2.
Public Review - Rates and Equilibrium June 2005 1. What does X represent in the diagram below? (A) activation energy for the forward reaction (B) activation energy for the reverse reaction (C) heat of
More informationCollision Theory. Collision theory: 1. atoms, ions, and molecules must collide in order to react. Only a small number of collisions produce reactions
UNIT 16: Chemical Equilibrium collision theory activation energy activated complex reaction rate reversible reaction chemical equilibrium law of chemical equilibrium equilibrium constant homogeneous equilibrium
More informationChapter 6: Chemical Equilibrium
Chapter 6: Chemical Equilibrium 6.1 The Equilibrium Condition 6.2 The Equilibrium Constant 6.3 Equilibrium Expressions Involving Pressures 6.4 The Concept of Activity 6.5 Heterogeneous Equilibria 6.6 Applications
More informationJanuary 03, Ch 13 SB equilibrium.notebook
Ch 13: Chemical Equilibrium exists when 2 opposing reactions occur simultaneously at the same rate (dynamic rather than static) Forward rate = reverse rate https://www.youtube.com/watch?v=wld_imyqagq The
More informationNotes: Unit 10 Kinetics and Equilibrium
Name: Regents Chemistry: Mr. Palermo Notes: Unit 10 Kinetics and Equilibrium Name: KEY IDEAS Collision theory states that a reaction is most likely to occur if reactant particles collide with the proper
More informationUnit 13: Rates and Equilibrium- Funsheets
Name: Period: Unit 13: Rates and Equilibrium- Funsheets Part A: Reaction Diagrams 1) Answer the following questions based on the potential energy diagram shown here: a. Does the graph represent an endothermic
More informationEnergy Changes, Reaction Rates and Equilibrium. Thermodynamics: study of energy, work and heat. Kinetic energy: energy of motion
Energy Changes, Reaction Rates and Equilibrium Thermodynamics: study of energy, work and heat Kinetic energy: energy of motion Potential energy: energy of position, stored energy Chemical reactions involve
More informationCHEMICAL EQUILIBRIUM. I. Multiple Choice 15 marks. 1. Reactions that can proceed in both the forward and reverse directions are said to be:
Name: Unit Test CHEMICAL EQUILIBRIUM Date: _ 50 marks total I. Multiple Choice 15 marks 1. Reactions that can proceed in both the forward and reverse directions are said to be: A. complete B. reversible
More informationc) Explain the observations in terms of the DYNAMIC NATURE of the equilibrium system.
Chemical Equilibrium - Part A: 1. At 25 o C and 101.3 kpa one mole of hydrogen gas and one mol of chlorine gas are reacted in a stoppered reaction vessel. After a certain time, three gases are detected
More information(03) WMP/Jun10/CHEM4
Thermodynamics 3 Section A Answer all questions in the spaces provided. 1 A reaction mechanism is a series of steps by which an overall reaction may proceed. The reactions occurring in these steps may
More informationChemistry 12: Dynamic Equilibrium Practice Test
Chemistry 12: Dynamic Equilibrium Practice Test A. Multiple Choice: For each question, select the best answer and record your choice on the answer key provided. /25 1) A system at equilibrium is said to
More informationA.P. Chemistry. Unit #11. Chemical Equilibrium
A.P. Chemistry Unit #11 Chemical Equilibrium I. Chemical Equilibrium the point in a reaction at which the concentrations of products and reactants remain constant Dynamic Equilibrium the equilibrium condition
More informationChapter 19 Chemical Thermodynamics
Chapter 19. Chemical Thermodynamics Sample Exercise 19.2 (p. 819) Elemental mercury is a silver liquid at room temperature. Its normal freezing point is -38.9 o C, and its molar enthalpy of fusion is H
More informationName Unit 10 Practice Test
1. Increasing the temperature increases the rate of a reaction by A) lowering the activation energy B) increasing the activation energy C) lowering the frequency of effective collisions between reacting
More informationWarm up. 1) What is the conjugate acid of NH 3? 2) What is the conjugate base of HNO 2? 3) If the ph is 9.2, what is the [H 3 O + ], poh, and [OH - ]?
Warm up 1) What is the conjugate acid of NH 3? 2) What is the conjugate base of HNO 2? 3) If the ph is 9.2, what is the [H 3 O + ], poh, and [OH - ]? 4) What is the concentration of H 2 SO 4 if 30.1 ml
More informationUnit 10 Thermodynamics, Kinetics and Equilibrium Notes
Unit 10 Thermodynamics, Kinetics and Equilibrium Notes What is Thermodynamics? Almost all chemical reactions involve a between the and its. Thermo = Dynamics = What is energy? What is heat? Thermochemistry
More informationName period AP Unit 8: equilibrium
Name period AP Unit 8: equilibrium 1. What is equilibrium? Rate of the forward reaction equals the rate of the reverse reaction 2. How can you tell when equilibrium has been reached? The concentrations
More informationUnit 13: Rates and Equilibrium- Guided Notes
Name: Period: What is a Chemical Reaction and how do they occur? Unit 13: Rates and Equilibrium- Guided Notes A chemical reaction is a process that involves of atoms Law of Conservation of : Mass is neither
More informationThe Equilibrium State. Chapter 13 - Chemical Equilibrium. The Equilibrium State. Equilibrium is Dynamic! 5/29/2012
Chapter 13 - Chemical Equilibrium The Equilibrium State Not all chemical reactions go to completion; instead they attain a state of equilibrium. When you hear equilibrium, what do you think of? Example:
More informationBased on the kinetic molecular theory of gases, which one of the following statements is INCORRECT?
1 Based on the kinetic molecular theory of gases, which one of the following statements is INCORRECT? A) The collisions between gas molecules are perfectly elastic. B) At absolute zero, the average kinetic
More information1. The reaction between solid barium hydroxide and solid ammonium chloride can be represented by the equation below.
1. The reaction between solid barium hydroxide and solid ammonium chloride can be represented by the equation below. Ba(OH) 2 (s) + 2NH 4 Cl(s) BaCl 2 (s) + 2NH 3 (g) + 2H 2 O(l) ΔH ο = +51.1 kj mol 1
More informationNotes: Unit 11 Kinetics and Equilibrium
Name: Regents Chemistry: Notes: Unit 11 Kinetics and Equilibrium Name: KEY IDEAS Collision theory states that a reaction is most likely to occur if reactant particles collide with the proper energy and
More informationChapter 6: Chemical Equilibrium
Chapter 6: Chemical Equilibrium 6.1 The Equilibrium Condition 6. The Equilibrium Constant 6.3 Equilibrium Expressions Involving Pressures 6.4 The Concept of Activity 6.5 Heterogeneous Equilibria 6.6 Applications
More informationUnit 9 Kinetics SA Review
1. Base your answer to the following question on the information below. The equilibrium equation below is related to the manufacture of a bleaching solution. In this equation, means that chloride ions
More informationKWANTLEN UNIVERSITY COLLEGE DEPARTMENT OF CHEMISTRY
KWANTLEN UNIVERSITY COLLEGE DEPARTMENT OF CHEMISTRY NAME: CHEM. 1210 FINAL EXAMINATION December 13, 2001 Time: 3 hours INSTRUCTIONS: 1. Read all questions thoroughly and answer each question completely.
More informationThermodynamically Favored Reactions
Thermodynamically Favored Reactions Will go on its own- may need a little push activation energy Speed of the reaction doesn t matter 18.1 Rates of Reaction The heat given off by the corrosion reaction
More information6. Which will react faster: Magnesium and 2M hydrochloric acid, or Magnesium and 0.5M hydrochloric acid?
REACTION RATES WORKSHEET WS#1 1. Identify the three components of collision theory. What are the three factors that must be true for a collision to be successful? a. b. c. 2. Do all collisions result in
More information(02) WMP/Jun10/CHEM2
Energetics 2 Section A Answer all the questions in the spaces provided. 1 An equation for the equilibrium reaction between hydrogen, iodine and hydrogen iodide is shown below. H 2 (g) + I 2 (g) 2HI(g)
More informationChapter 16. Thermodynamics. Thermochemistry Review. Calculating H o rxn. Predicting sign for H o rxn. Creative Commons License
Chapter 16 Thermodynamics GCC CHM152 Creative Commons License Images and tables in this file have been used from the following sources: OpenStax: Creative Commons Attribution License 4.0. ChemWiki (CC
More informationChemistry Grade : 11 Term-3/Final Exam Revision Sheet
Chemistry Grade : 11 Term-3/Final Exam Revision Sheet Exam Date: Tuesday 12/6/2018 CCS:Chem.6a,6b,6c,6d,6e,6f,7a,7b,7d,7c,7e,7f,1g Chapter(12):Solutions Sections:1,2,3 Textbook pages 378 to 408 Chapter(16):Reaction
More informationFree-energy change ( G) and entropy change ( S)
Free-energy change ( G) and entropy change ( S) A SPONTANEOUS PROCESS (e.g. diffusion) will proceed on its own without any external influence. A problem with H A reaction that is exothermic will result
More informationChapter 6: Chemical Bonds
Chapter 6: Chemical Bonds Section 6.1: Ionic Bonding I. Stable Electron Configurations Group # II. III. Ionic Bonds Group # A. Transfer of Electrons Group # B. Formation of Ions Group # C. Formation of
More informationChemistry Chapter 16. Reaction Energy
Chemistry Reaction Energy Section 16.1.I Thermochemistry Objectives Define temperature and state the units in which it is measured. Define heat and state its units. Perform specific-heat calculations.
More informationThird Quarter Cumulative Review Questions. 1. Which factor distinguishes a metallic bond from an ionic bond or a covalent bond?
Name: Thursday, March 27, 2008 Third Quarter Cumulative Review Questions 1. Which factor distinguishes a metallic bond from an ionic bond or a covalent bond? 1. the mobility of electrons 3. the equal sharing
More informationChem GENERAL CHEMISTRY II
GENERAL CHEMISTRY II CHEM 206 /2 51 Final Examination December 19, 2006 1900-2200 Dr. Cerrie ROGERS x x programmable calculators must be reset Chem 206 --- GENERAL CHEMISTRY II LAST NAME: STUDENT NUMBER:
More informationQuiz B3: Le Chatelier s Principle Block:
Quiz B3: Le Chatelier s Principle Name: Block: 1. Consider the following reaction: 2SO2(g) + O2(g) 2SO3(g) H = -197 kj/mol Which of the following will not shift the equilibrium to the right? A. Adding
More information(i.e., equilibrium is established) leads to: K = k 1
CHEMISTRY 104 Help Sheet #8 Chapter 12 Equilibrium Do the topics appropriate for your lecture http://www.chem.wisc.edu/areas/clc (Resource page) Prepared by Dr. Tony Jacob Nuggets: Equilibrium Constant
More informationEnergy Diagram Endothermic Reaction Draw the energy diagram for exothermic and endothermic reactions. Label each part.
CP Chapter 18 Notes A Model for Reaction Rates Expressing Reaction Rates Average Rate = Δquantity Δtime The amount of increase or decrease depends on their mole ratios Units = or mol/ls Expressing Reaction
More informationName AP CHEM / / Collected AP Exam Essay Answers for Chapter 16
Name AP CHEM / / Collected AP Exam Essay Answers for Chapter 16 1980 - #7 (a) State the physical significance of entropy. Entropy (S) is a measure of randomness or disorder in a system. (b) From each of
More informationQ.1 Write out equations for the reactions between...
1 CHEMICAL EQUILIBRIUM Dynamic Equilibrium not all reactions proceed to completion some end up with a mixture of reactants and products this is because some reactions are reversible; products revert to
More informationCHAPTER 16: REACTION ENERGY AND CHAPTER 17: REACTION KINETICS. Honors Chemistry Ms. Agostine
CHAPTER 16: REACTION ENERGY AND CHAPTER 17: REACTION KINETICS Honors Chemistry Ms. Agostine 16.1 Thermochemistry Definition: study of the transfers of energy as heat that accompany chemical reactions and
More information1 A reaction that is spontaneous.
Slide 1 / 55 1 A reaction that is spontaneous. A B C D E is very rapid will proceed without outside intervention is also spontaneous in the reverse direction has an equilibrium position that lies far to
More informationCh 10 Practice Problems
Ch 10 Practice Problems 1. Which of the following result(s) in an increase in the entropy of the system? I. (See diagram.) II. Br 2(g) Br 2(l) III. NaBr(s) Na + (aq) + Br (aq) IV. O 2(298 K) O 2(373 K)
More informationENTHALPY, ENTROPY AND FREE ENERGY CHANGES
ENTHALPY, ENTROPY AND FREE ENERGY CHANGES Refer to the following figures for Exercises 1-6. The lines on the vertical axis represent the allowed energies. Assume constant spacing between levels to determine
More information5.2 Energy. N Goalby chemrevise.org Lattice Enthalpy. Definitions of enthalpy changes
5.2 Energy 5.2.1 Lattice Enthalpy Definitions of enthalpy changes Enthalpy change of formation The standard enthalpy change of formation of a compound is the energy transferred when 1 mole of the compound
More informationChemical Equilibrium
Chemical Equilibrium Concept of Equilibrium Equilibrium Constant Equilibrium expressions Applications of equilibrium constants Le Chatelier s Principle The Concept of Equilibrium The decomposition of N
More information3. Indicate the mass action expression for the following reaction: 2X(g) + Y(g) 3W(g) + V(g) a) [X] 2 [Y][W] 3 [V] [W] 3 [V] [X] 2 [Y] [3W][V] [2X][Y]
1. Which of the following statements concerning equilibrium is not true? a) A system that is disturbed from an equilibrium condition responds in a manner to restore equilibrium. b) Equilibrium in molecular
More informationDYNAMIC EQUILIBRIUM STUDY GUIDE multiple choice
DYNAMIC EQUILIBRIUM STUDY GUIDE multiple choice Multiple Choice Section: This study guide is a compilation of questions from provincial exams since April 1994. I urge you to become intimately familiar
More informationThermochemistry: Heat and Chemical Change
Thermochemistry: Heat and Chemical Change 1 Heat or Thermal Energy (q) Heat is a form of energy Is heat the same as temperature? Heat flows between two objects at different temperatures. Hot Cold 2 Chemical
More informationCHEMISTRY 12 EQUILIBRIUM PROPERTIES & ENTROPY AND ENTHALPY WORKSHEET CHEMISTRY 12 EQUILIBRIUM PROPERTIES WORKSHEET
CHEMISTRY 12 EQUILIBRIUM PROPERTIES & ENTROPY AND ENTHALPY WORKSHEET CHEMISTRY 12 EQUILIBRIUM PROPERTIES WORKSHEET 1) Write six statements that apply to all chemical equilibrium systems. (2 marks) System
More informationName Date Class THE ARITHMETIC OF EQUATIONS
12.1 THE ARITHMETIC OF EQUATIONS Section Review Objectives Calculate the amount of reactants required or product formed in a nonchemical process Interpret balanced chemical equations in terms of interacting
More informationChem. 1A Final. Name. Student Number
Chem. 1A Final Name Student Number All work must be shown on the exam for partial credit. Points will be taken off for incorrect or no units. Calculators are allowed. Cell phones may not be used for calculators.
More informationSaturday Study Session 1 3 rd Class Student Handout Thermochemistry
Saturday Study Session 1 3 rd Class Student Handout Thermochemistry Multiple Choice Identify the choice that best completes the statement or answers the question. 1. C 2 H 4 (g) + 3 O 2 (g) 2 CO 2 (g)
More informationName Energy Test period Date
Name Energy Test period Date 1. The temperature 30. K expressed in degrees Celsius is 1) 243ºC 2) 243ºC 3) 303ºC 4) 303ºC 2. The potential energy diagram for a chemical reaction is shown below. 4. A sample
More informationBCIT Winter Chem Exam #1
BCIT Winter 2014 Chem 0012 Exam #1 Name: Attempt all questions in this exam. Read each question carefully and give a complete answer in the space provided. Part marks given for wrong answers with partially
More informationCHAPTER 12: Thermodynamics Why Chemical Reactions Happen
CHAPTER 12: Thermodynamics Why Chemical Reactions Happen Useful energy is being "degraded" in the form of unusable heat, light, etc. A tiny fraction of the sun's energy is used to produce complicated,
More information1 A burning splint will burn more vigorously in pure oxygen than in air because
Slide 1 / 38 1 burning splint will burn more vigorously in pure oxygen than in air because oxygen is a reactant in combustion and concentration of oxygen is higher in pure oxygen than is in air. oxygen
More informationEquilibrium. What is equilibrium? Hebden Unit 2 (page 37 69) Dynamic Equilibrium
Equilibrium What is equilibrium? Hebden Unit (page 37 69) Dynamic Equilibrium Hebden Unit (page 37 69) Experiments show that most reactions, when carried out in a closed system, do NOT undergo complete
More information6. [EXO] reactants have more energy 7. [EXO] H is negative 8. [ENDO] absorbing sunlight to make sugar 9. [ENDO] surroundings get cold
10.A Thermo: Endo/Exo and ΔH 1. For each of the following laws of thermodynamics, what does each actually mean in terms of the behavior of energy and particles? 1 st Law of Thermodynamics? Energy is neither
More informationB 2 Fe(s) O 2(g) Fe 2 O 3 (s) H f = -824 kj mol 1 Iron reacts with oxygen to produce iron(iii) oxide as represented above. A 75.
1 2004 B 2 Fe(s) + 3 2 O 2(g) Fe 2 O 3 (s) H f = -824 kj mol 1 Iron reacts with oxygen to produce iron(iii) oxide as represented above. A 75.0 g sample of Fe(s) is mixed with 11.5 L of O 2 (g) at 2.66
More information