Supporting Information
|
|
- Deborah Adams
- 6 years ago
- Views:
Transcription
1 Supporting Information Facile Synthesis of Black Phosphorus: an Efficient Electrocatalyst for the Oxygen Evolving Reaction Qianqian Jiang, Lei Xu, Ning Chen, Han Zhang,* Liming Dai,* and Shuangyin Wang* anie_ _sm_miscellaneous_information.pdf
2 Supporting information Experimental Section Pre-treatment of Red Phosphorus The red phosphorus is usually kept in the kerosene solution in order to prevent it reaction with the oxygen in the air. Although the storage method can reduce the reaction with oxygen, there still exist some oxides or oxide layers on the surface of red phosphorus. Therefore, the red phosphorus pre-treatment is very necessary in our experiment, which has the same effect to the pre-treatment in the literature reports. [1-6] Physicochemical characterization X-ray diffraction (XRD) patterns are collected on a powder X-ray diffractometer at 40 kv and 15 ma using Co-Kα radiation (D/MAX-2200V, Rigaku, Japan). The morphology, selected-area electron diffraction (SAED) and crystal lattice of the sample are characterized by the Transmission Electron Microscope (TEM) (Tecnai g2 F20). Raman spectroscopy is performed (England, invia-reflex) in a backscattering configuration excited with a visible laser light under a 633 nm excitation laser. Scanning electron microscopy (SEM) images are recorded using a scanning electron microscope (Hitachi S-4800, Japan). X-ray photoelectron spectra (XPS) are obtained on an ESCALAB 250Xi photoelectron spectrometer and curve fitting and background subtraction are accomplished. Thermogravimetric analysis (TG) is measured using a Thermogravimetric Analyzer (HENVEN, HTG-1) in argon, over a range from room temperature to 1000 C with a heating rate of 10 C/min. Electrochemical impedance spectroscopy (EIS) measurements are performed by applying an AC voltage with 5 mv amplitude in a frequency range from to 1 Hz and recorded at 1.64 V vs. RHE. Electrochemical characterization The electrocatalytic performance is measured with an electrochemical workstation (CHI 760E, CH Instrument) and a rotating disk electrode apparatus (RDE-3A, ALS, Japan) in a three-electrode system. The counter electrode and the reference electrode are a platinum foil and the saturated calomel electrode (SCE), respectively. BP-Ti was used as the working electrode directly. The BP-CNT electrode was prepared by depositing BP-CNT suspension in ethanol (8.9 μl, 4 mg/ml) onto the glassy carbon electrode (4 mm in diameter), followed by dripping with 5 μl Nafion solution (0.05 wt% in isoproponal, Sigma Aldrich, USA). Linear sweep voltammetry (LSV) is employed using the rotating disk electrode (RDE) at a rotation rate of 1600 rpm in 0.1 M KOH solution saturated with O2. All the tests are carried out at room temperature (about 25 C). Potentials are referenced to a reversible hydrogen electrode (RHE) [7]. All LSV data are presented with IR correction. In order to study the reaction mechanism for OER, rotating ring-disk electrode (RRDE) voltammograms are carried out based on a Pt ring electrode and a glassy carbon disk electrode. The as-prepared BP-CNT catalyst is coated onto the RRDE using above method. To detect the content of the formed peroxide intermediates, the ring potential is fixed constantly at 1.5 V vs. RHE in O2-saturated 0.1 M KOH solution and recorded the data under a rotation rate of 1600 rpm at a scan rate of 5 mv/s -1. Specifically, in order to determine the reaction pathway for OER by detecting the HO2 - formation, the ring potential is held constantly at 1.50 V vs. RHE for oxidizing HO2 - intermediate in O2-saturated 0.1 M KOH; on the other hand, to ensure that the oxidation current originates from oxygen evolution rather than other side reactions and to calculate the Faradaic efficiency of the system, the ring potential is held constantly at 0.54 V vs. RHE to reduce the O2 formed from the catalyst on the disk electrode in N2-saturated 0.1 M KOH solution. The calculation of Faradaic efficiency is as follows: ε = Ir/(IdN), where Id is the disk current, Ir is the ring current, and N is correspond to the current collection efficiency of the RRDE (N = 0.2) (see J. Am. Chem. Soc. 2014, 136, ). To properly calculate the Faradaic efficiency of the system, the disk electrode is held at a relatively small constant current of 125 µa (~1 ma/cm 2 ); this current is sufficiently large to ensure an appreciable O2 production and sufficiently small to minimize local saturation and bubble formation at the disk electrode (see J. Am. Chem. Soc. 2013, 135, 16977).
3 Figure S1. TGA results of BP-Ti (a) and BP-CNT (b), showing the BP contents in the BP-Ti and BP-CNT are 13.41% and 15.46%, respectively. Figure S2. a) TEM image of BP separated from Ti foil, Inset in a1) the SAED pattern taken from the same region as in a); b-d) EDS elemental mapping of sample BP separated from Ti foil, corresponding elemental mappings of e) P and d) Ti. The TEM images for BP-Ti prepared by the efficient TVT method are shown in Figure S2a. It shows the product with the particle size about 70 nm which is consist with the result of the SEM images. The selected area electron diffraction patterns in Figure S2a1 are assigned to the (021), (041) and (002) planes of the BP crystal, respectively, which is consistent with the well-known BP lattice parameters. [8, 9] In order to further confirm the distribution of orthorhombic black phosphorus on the Ti foil, the TEM and EDS mapping images of BP-Ti are tested in Fig.S2b-d.
4 Figure S3. SEM images of BP-Ti with different temperature: a, b) 550 º C; c,d) 650 º C; e,f) 750 º C. In Figure S3, we can see that the reaction temperature can impact the morphology of the black phosphorus on the Ti foil. When the reaction temperature is 550 C, the morphology of BP-Ti (Fig.S2a) is close to the polyhedral structure, but the BP texture (Fig.S3b) is not very obvious. However, the BP-Ti with reaction temperature 650 C shows a surface morphology with well-defined polyhedral structures (Fig. S3c). Under a high-magnification (Fig.S3d), a uniformly-distributed BP texture is clearly evident. When the reaction temperature is increased to 750 C, it can be clearly find that the size of the polyhedral particles (Fig. S3e) become larger than that of BP-Ti (650 C), and the BP texture becomes more tightly. Therefore, we can confirm that the reaction temperature can impact the partial size of BP and further for the BP texture. Figure S4. SEM images BP-Ti with different amount of red phosphorus: a) 0.25 g; b) 0.5 g; c) 0.75 g. In order to further study the influence factor of BP-Ti, SEM images of BP-Ti with different amount of red phosphorus is shown in Fig.S4. We can find that the amount of red phosphorus can affect the morphology of the material, and when the amount of red phosphorus is 0.5 g, the BP-Ti has the best morphology and BP texture, which will be good for its OER activity.
5 Figure S5. SEM images BP-Ti prepared for different time: a) 3 h; b) 5 h; c) 7 h. Figure S5 shows the images of BP-Ti prepared for different time, from 3h to 7h. From the three images, it can be seen that the reaction time can hardly affect the morphology of BP-Ti. Figure S6. a) The photograph of Ti foil and the BP-Ti; b) SEM image of the cut up surface of BP-Ti Figure S7. XRD patterns of BP-Ti prepared at different temperatures. Figure S8. Raman spectra of orthorhombic black phosphorus directly grown on Ti foil: a) with different amount of red phosphorus; b) with different temperature; c) with different time.
6 Figure S9. High-resolution P 2p XPS spectra of a) BP; b) BP-Ti; c) BP-CNT. Figure S10. Polarization curves of orthorhombic black phosphorus directly grown on Ti foil: a) with different amount of red phosphorus; b) with different temperature; c) with different times. Figure S11. a) Cyclic voltammograms (CVs) of BP-Ti measured at different scan rates from 2 to 10 mv/s; b) Plot of the current density at 1.14 V vs. the scan rate. Figure S12. XRD of a) BP-Ti and BP-CNT b) after the chronoamperometric response In order to study the structural change of BP-Ti and BP-CNT after OER testing, XRD patterns of BP-Ti and BP-CNT after the chronoamperometric response are investigated in Figure S12. From the results, we can clearly see that all the diffraction peaks of the BP-Ti except those from Ti or CNT can be indexed to an orthorhombic black phosphorus, which indicates that the structure of BP on both Ti and CNT keep very well. It further illustrates that the BP is relatively stable.
7 Figure S13. SEM images of RP, CNT-650 and BP-CNT with different time: a) RP; b) CNT-650; c,d) 3 h; e,f) 5 h; g,h) 7 h. Figure S14. a) TEM image of BP-CNT; b-d) EDS elemental mapping of sample BP-CNT, corresponding elemental mappings of c) C and (d) P.
8 Figure S15. The polarization curves of commercial IrO2, RuO2 and BP-CNT catalysts for OER. Figure S16 a) Experimental phenomena of the titration experiments with the K3PO4 resolution with different mole content); b) Fourier transform infrared spectroscopy (FTIR) spectrum of the KOH resolution before and after the chronoamperometric response From the result of the chronoamperometric response, we can see that sample BP-Ti is relatively stable, possibly due to the uniform grown on the Ti foil. In order to confirm whether the black phosphorus films dissolute in KOH/O2 solution, the titration experiments and the Fourier transform infrared spectroscopy (FTIR) of BP-Ti after the chronoamperometric response are performed in Figure S16. First of all, we prepared serials of control samples. To make the experimental phenomena more obvious, we put K3PO4 with mole content of 2.5*10-3, 2.5*10-4, 5*10-5, 2.5*10-5, 1.25*10-5 and 2.5*10-6 into the each transparent glass bottle, respectively. We could observe obvious color changes with the control experiments. To examine the electrolyte solution (KOH) in this work before and after the long-time chronoamperometric response, we put 1 ml AgNO3 (0.1 mol/l) into the used KOH solution after the durability testing. It can be seen that the KOH solutions before and after the chronoamperometric response both show similar color, the milk white, which is different from any bottles with the K3PO4 species in the control bottles (Fig. S16a). These phenomena indicate the KOH solution after the chronoamperometric response has no or very little (less than 2.5*10-6 mol) PO4 3- species in the solution after the OER reaction. In order to further confirm whether there is any other P-containing species existing in the KOH solution after the durability testing, FTIR spectra of the KOH solution before and after the chronoamperometric response are collected as shown in Figure S16b. The label shows that only the bands intrinsic to KOH and H2O are observed, which indicates that no impurity phase pollutes the solution. The characteristic peak of P-containing species at cm -1 is not observed in the FTIR of the KOH resolution after the chronoamperometric response (KOH-A). This result can further illustrate that black phosphorus is relatively stable in the KOH/O2 solution. Therefore, there may be very little or no dissolution of BP in KOH/O2 solution.
9 Figure S17. Polarization curves of BP-CNT: a) with different amount of red phosphorus; b) with different temperature; c) with different times. Figure S18. a) Cyclic voltammograms (CVs) of BP-CNT measured at different scan rates from 2 to 10 mv/s; b) Plot of the current density at 1.14 V vs the scan rate. Figure S19. Polarization curves of :a) BP-Ti; b) BP-CNT; c) Tafel plots of BP-Ti; d) Tafel plots of BP-CNT in an O2-saturated 0.1 M and 1 M KOH solution (scan rate: 5 mv/s). BP-Ti (Figure S14a) shows a larger current density and much lower Tafel slope (Figure S14b) of mv/dec in 1 M KOH than that in 0.1 M KOH (91.52 mv/dec). More clearly, BP-CNT has much larger current density and much lower Tafel slope (Figure S14d) of mv/dec in 1 M KOH in comparison to that in 0.1 M KOH (72.88 mv/dec). All the results demonstrate the excellent OER activity of the BP in concentrated alkaline electrolyte solutions.
10 Table S1 Lattice parameters of samples BP-Ti prepared at different hydrothermal temperature Sample a (Å) c (Å) c (Å) V/ (Å 3 ) BP-Ti BP-Ti BP-Ti Table S2. Comparison of the OER activity of BP-CNT with metal oxide-based electrocatalysts in literatures. Potential at the Samples Onset potential (V) current density of 10 Electrolyte References ma/cm 2 (V) BP-CNT M KOH This work Co3O4/N-graphene M KOH [7] Mn3O4/CoSe2 hybrids M KOH [14] Mesoporous Co3O4 Nanowires M KOH [15] RuO M KOH [16] IrO2/C (20%) M KOH [17] _ENREF _7 IrO M KOH [11] Co3O4/C-NA M KOH [18] Co3O4 thin film M NaOH [19] CoOx@CN hybrids M KOH [20] References [S1] L. Wang, X. He, J. Li, W. Sun, J. Gao, J. Guo, C. Jiang, Angew. Chem. Internat. Edit. 2012, 51, [S2] Z. Shen, Z. Hu, W. Wang, S. F. Lee, D. K. Chan, Y. Li, T. Gu, J. C. Yu, Nanoscale 2014, 6, [S3] L. Q. Sun, M. J. Li, K. Sun, S. H. Yu, R. S. Wang, H. M. Xie, J. Phys. Chem. C 2012, 116, [S4] Z. Shen, S. Sun, W. Wang, J. Liu, Z. Liu, J. Yu, J. Mater. Chem. A 2015, 3, [S5] F. Wang, W. K. H. Ng, J. C. Yu, H. Zhu, C. Li, L. Zhang, Z. Liu, Q. Li, Appl. Catal. B-Environ. 2011, 111, [S6] Y. Zhu, Y. Wen, X. Fan, T. Gao, F. Han, C. Luo, S. C. Liou, C. Wang, ACSNano 2015, 9, [S7] L. Yongye, L. Yanguang, W. Hailiang, Z. Jigang, W. Jian, R. Tom, D. Hongjie, Nat. Mater. 2011, 10, [S8] L. Stefan, S. Peer, N. Tom, Cheminform 2007, 38, [S9] R. Ahuja, Phys. Status Solidi 2003, 235, [S10] Z. Y. Lu, H. T. Wang, D. S. Kong, K. Yan, P. C. Hsu, G. Y. Zheng, H. B. Yao, Z. Liang, X. M. Sun, Y. Cui, Nat. Commun. 2014, 5. [S11] S. Fang, H. Xile, J. Am. Chem. Soc. 2014, 136, [S12] S. Chen, J. J. Duan, M. Jaroniec, S. Z. Qiao, Adv. Mater. 2014, 26, [S13] J. T. Zhang, Z. H. Zhao, Z. H. Xia, L. M. Dai, Nat. Nanotechnol. 2015, 10, [S14] G. Min-Rui, X. Yun-Fei, J. Jun, Z. Ya-Rong, Y. Shu-Hong, J. Am. Chem. Soc. 2012, 134, [S15] Y. Wang, T. Zhou, K. Jiang, P. Da, Z. Peng, J. Tang, B. Kong, W. B. Cai, Z. Yang, G. Zheng, Adv. Energy Mater. 2014, 4, [S16] T. Sun, L. Xu, Y. Yan, A. A. Zakhidov, R. H. Baughman, J. Chen, Acs Catal. 2016, 193, 1-8. [S17] Y. Zhao, K. Kamiya, K. Hashimoto, S. Nakanishi, J.Phy. Chem. C 2015, 119, [S18] M. Tian Yi, D. Sheng, J. Mietek, Q. Shi Zhang, J. Am. Chem. Soc. 2014, 136, [S19] H. S. Jeon, M. S. Jee, H. Kim, S. J. Ahn, Y. J. Hwang, B. K. Min, Artificial Organs 2015, 7, [S20] J. Haiyan, W. Jing, S. Diefeng, W. Zhongzhe, P. Zhenfeng, W. Yong, J. Am. Chem. Soc. 2015, 137,
Carbon Quantum Dots/NiFe Layered Double Hydroxide. Composite as High Efficient Electrocatalyst for Water
Supplementary Information Carbon Quantum Dots/NiFe Layered Double Hydroxide Composite as High Efficient Electrocatalyst for Water Oxidation Di Tang, Juan Liu, Xuanyu Wu, Ruihua Liu, Xiao Han, Yuzhi Han,
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information Phosphorus-Doped CoS 2 Nanosheet Arrays as
More informationSupporting Information. Phenolic/resin assisted MOFs derived hierarchical Co/N-doping carbon
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2018 Electronic Supplementary Material (ESI) for Journal of Materials Chemistry
More informationElectronic Supplementary Information (ESI)
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information (ESI) Synthesis of 1T-MoSe 2 ultrathin
More informationJaemin Kim, Xi Yin, Kai-Chieh Tsao, Shaohua Fang and Hong Yang *
Jaemin Kim, Xi Yin, Kai-Chieh Tsao, Shaohua Fang and Hong Yang * Department of Chemical and Biomolecular Engineering, University of Illinois at Urbana-Champaign, 114 Roger Adams Laboratory, MC-712, 600
More informationAchieving Stable and Efficient Water Oxidation by Incorporating NiFe. Layered Double Hydroxide Nanoparticles into Aligned Carbon.
Electronic Supplementary Material (ESI) for Nanoscale Horizons. This journal is The Royal Society of Chemistry 2015 Achieving Stable and Efficient Water Oxidation by Incorporating NiFe Layered Double Hydroxide
More informationNickel Sulfides Freestanding Holey Films as Air-Breathing Electrodes for. Flexible Zn-Air Batteries
Nickel Sulfides Freestanding Holey Films as Air-Breathing Electrodes for Flexible Zn-Air Batteries Kyle Marcus, 1,# Kun Liang, 1,# Wenhan Niu, 1,# Yang Yang 1,* 1 NanoScience Technology Center, Department
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Supporting Information Experimental section Synthesis of Ni-Co Prussian
More informationNitrogen and sulfur co-doped porous carbon derived from human hair as. highly efficient metal-free electrocatalyst for hydrogen evolution reaction
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information Nitrogen and sulfur co-doped porous
More informationDivision of Physics and Semiconductor Science, Dongguk University, Seoul 04620, South Korea
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Supplementary information for Self-assembled Two-dimensional Copper Oxide
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information Three-dimensional amorphous tungsten-doped
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information Experimental Section Materials: Ti
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 Electronic Supplementary Information One-Dimensional MoO2-Co2Mo3O8@C Nanorods: A Novel and High
More informationSupporting Information for. Highly active catalyst derived from a 3D foam of Fe(PO 3 ) 2 /Ni 2 P for extremely efficient water oxidation
Supporting Information for Highly active catalyst derived from a 3D foam of Fe(PO 3 ) 2 /Ni 2 P for extremely efficient water oxidation Haiqing Zhou a,1, Fang Yu a,1, Jingying Sun a, Ran He a, Shuo Chen
More informationSupporting Information. Facile in situ synthesis of carbon quantum dots/graphene heterostructure
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2019 Supporting Information Facile in situ synthesis of carbon quantum dots/graphene heterostructure
More informationSupporting information for
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2018 Supporting information for N-doped Carbon Shelled Bimetallic Phosphates for Efficient Electrochemical
More informationRevelation of the Excellent Intrinsic Activity. Evolution Reaction in Alkaline Medium
Supporting Information Revelation of the Excellent Intrinsic Activity of MoS2 NiS MoO3 Nanowires for Hydrogen Evolution Reaction in Alkaline Medium Chuanqin Wang a,b, Bin Tian b, Mei Wu b, Jiahai Wang
More informationSupporting information
a Supporting information Core-Shell Nanocomposites Based on Gold Nanoparticle@Zinc-Iron- Embedded Porous Carbons Derived from Metal Organic Frameworks as Efficient Dual Catalysts for Oxygen Reduction and
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information Nickel Cobalt Phosphides Quasi-Hollow Nanocubes as an Efficient
More informationN-doped Carbon-Coated Cobalt Nanorod Arrays Supported on a Titanium. Mesh as Highly Active Electrocatalysts for Hydrogen Evolution Reaction
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information N-doped Carbon-Coated Cobalt Nanorod
More informationSupporting Information
Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2016 Supporting Information Single-crystalline Pd square nanoplates enclosed by {100}
More informationSUPPLEMENTARY INFORMATION
SUPPLEMENTARY INFORMATION An Oxygen Reduction Electrocatalyst Based on Carbon Nanotube- Nanographene Complexes Yanguang Li, Wu Zhou, Hailiang Wang, Liming Xie, Yongye Liang, Fei Wei, Juan-Carlos Idrobo,
More informationSupporting information:
Supporting information: The Role of Anisotropic Structure and Its Aspect Ratio: High-Loading Carbon Nanospheres Supported Pt Nanowires and Their High Performance Toward Methanol Electrooxidation Feng-Zhan
More informationSupplementary Information for
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2017 Supplementary Information for Cu Nanowires Shelled with NiFe Layered Double
More informationAchieving High Electrocatalytic Efficiency on Copper: A Low-Cost Alternative to Platinum for Hydrogen Generation in Water
Supporting Information Achieving High Electrocatalytic Efficiency on Copper: A Low-Cost Alternative to Platinum for Hydrogen Generation in Water Jian Zhao, a,b,c,d Phong D. Tran,* a,c Yang Chen, a,c Joachim
More informationSelf-Growth-Templating Synthesis of 3D N,P,Co-Doped. Mesoporous Carbon Frameworks for Efficient Bifunctional
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information Self-Growth-Templating Synthesis of
More informationSupporting Information
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2014 Supporting Information Hydrothermal synthesis of - alloy nanooctahedra and their enhanced electrocatalytic
More informationSupplementary Information. Unusual High Oxygen Reduction Performance in All-Carbon Electrocatalysts
Supplementary Information Unusual High Oxygen Reduction Performance in All-Carbon Electrocatalysts Wei Wei 1, 4,, Ying Tao 1, 4,, Wei Lv 2,, Fang-Yuan Su 2, Lei Ke 2, Jia Li 2, Da-Wei Wang 3, *, Baohua
More informationPt-Ni alloyed nanocrystals with controlled archtectures for enhanced. methanol oxidation
Supplementary Information Pt-Ni alloyed nanocrystals with controlled archtectures for enhanced methanol oxidation Xiao-Jing Liu, Chun-Hua Cui, Ming Gong, Hui-Hui Li, Yun Xue, Feng-Jia Fan and Shu-Hong
More informationA Robust and Highly Active Copper-Based Electrocatalyst. for Hydrogen Production at Low Overpotential in Neutral
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Supporting information A Robust and Highly Active Copper-Based Electrocatalyst for Hydrogen Production
More informationFacile Synthesis of Hybrid Graphene and Carbon Nanotube as. Metal-Free Electrocatalyst with Active Dual Interfaces for
Facile Synthesis of Hybrid Graphene and Carbon Nanotube as Metal-Free Electrocatalyst with Active Dual Interfaces for Efficient Oxygen Reduction Reaction Jang-Soo Lee, a Kiyoung Jo, b Taemin Lee, a Taeyeong
More informationSupplementary Material (ESI) for Chemical Communications This journal is (c) The Royal Society of Chemistry Supporting Information
Supporting Information A facile approach to the synthesis of highly electroactive Pt nanoparticles on graphene as anode catalyst for direct methanol fuel cells Yi-Ge Zhou, Jing-Jing Chen, Feng-bin Wang*,
More informationElectronic Supplementary Information (ESI )
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information (ESI ) Hollow nitrogen-doped carbon spheres as an efficient
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 Electronic Supplementary Information Experimental section Materials: Tannic acid (TA), silver nitrate
More informationZhengping Zhang, Junting Sun, Meiling Dou, Jing Ji, Feng Wang*
Supporting Information Nitrogen and Phosphorus Codoped Mesoporous Carbon Derived from Polypyrrole as Superior Metal-Free Electrocatalyst towards the Oxygen Reduction Reaction Zhengping Zhang, Junting Sun,
More informationSupplementary Information:
Supplementary Information: One-Step and Rapid Synthesis of Clean and Monodisperse Dendritic Pt Nanoparticles and Their High Performance Toward Methanol Oxidation and p-nitrophenol Reduction Jun Wang, Xin-Bo
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information Carbon coated nickel phosphides porous
More informationSupporting Information. MOF Templated Nitrogen Doped Carbon Stabilized Pt-Co Bimetallic
Supporting Information MOF Templated Nitrogen Doped Carbon Stabilized Pt-Co Bimetallic Nanoparticles: Low Pt Contents and Robust Activity towards Electrocatalytic Oxygen Reduction Reaction Li-Li Ling,
More informationElectronic Supplementary Information. Three-Dimensional Carbon Foam/N-doped 2. Hybrid Nanostructures as Effective Electrocatalysts for
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information Three-Dimensional Carbon Foam/N-doped
More informationSupporting Information
Supporting Information Facet-Selective Deposition of FeO x on α-moo 3 Nanobelts for Lithium Storage Yao Yao, 1 Nuo Xu, 2 Doudou Guan, 1 Jiantao Li, 1 Zechao Zhuang, 1 Liang Zhou,*,1 Changwei Shi 1, Xue
More informationFeP and FeP 2 Nanowires for Efficient Electrocatalytic Hydrogen Evolution Reaction
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2016 Supporting Information and Nanowires for Efficient Electrocatalytic Hydrogen Evolution Reaction
More informationSchool of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, , Singapore. b
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Dopamine-Mo VI complexation-assisted large-scale aqueous synthesis of single-layer MoS 2 /carbon
More informationSupporting Information
Supporting Information Oxygen Reduction on Graphene-Carbon Nanotube Composites Doped Sequentially with Nitrogen and Sulfur Drew C. Higgins, Md Ariful Hoque, Fathy Hassan, Ja-Yeon Choi, Baejung Kim, Zhongwei
More informationSupplementary Figure 1. (a-b) EDX of Mo 2 and Mo 2
Supplementary Figure 1. (a-b) EDX of Mo 2 C@NPC/NPRGO and Mo 2 C@NPC. Supplementary Figure 2. (a) SEM image of PMo 12 2-PPy, (b) TEM, (c) HRTEM, (d) STEM image and EDX elemental mapping of C, N, P, and
More informationNanomaterials and Chemistry Key Laboratory, Wenzhou University, Wenzhou, (P. R. China).
Electronic Supplementary Material (ESI) for Nanoscale Synergistically enhanced activity of graphene quantum dot/multi-walled carbon nanotube composites as metal-free catalysts for oxygen reduction reaction
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Supporting Information NiSe 2 Pyramids Deposited on N-doped Graphene Encapsulated
More informationLow-cost and high energy density asymmetric supercapacitors based on polyaniline nanotubes and MoO 3 nanobelts
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information Low-cost and high energy density asymmetric
More informationPhoto of the mass manufacture of the Fe-rich nanofiber film by free-surface electrospinning technique
Supporting Information Design 3D hierarchical architectures of carbon and highly active transition-metals (Fe, Co, Ni) as bifunctional oxygen catalysts for hybrid lithiumair batteries Dongxiao Ji, Shengjie
More informationSupporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 Supporting Information A Cu 2 Se-Cu 2 O Film Electrodeposited on Titanium Foil as a Highly Active
More informationSupporting Information
Supporting Information Bamboo-Like Carbon Nanotube/Fe 3 C Nanoparticle Hybrids and Their Highly Efficient Catalysis for Oxygen Reduction Wenxiu Yang a,b, Xiangjian Liu a,b, Xiaoyu Yue a,b, Jianbo Jia,
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information MoS 2 nanosheet/mo 2 C-embedded N-doped
More informationSupporting Information for:
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Supporting Information for: A Highly Efficient Electrocatalyst Based on
More informationSupporting Information
Supporting Information Hierarchical Porous N-doped Graphene Monoliths for Flexible Solid-State Supercapacitors with Excellent Cycle Stability Xiaoqian Wang, Yujia Ding, Fang Chen, Han Lu, Ning Zhang*,
More informationSupporting Information
Supporting Information Wiley-VCH 2013 69451 Weinheim, Germany Hierarchical Nanosheet-Based MoS 2 Nanotubes Fabricated by an Anion-Exchange Reaction of MoO 3 Amine Hybrid Nanowires** Sifei Zhuo, You Xu,
More informationRole of iron in preparation and oxygen reduction reaction activity of nitrogen-doped carbon
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information Role of iron in preparation and oxygen reduction reaction
More informationSynthesis of Oxidized Graphene Anchored Porous. Manganese Sulfide Nanocrystal via the Nanoscale Kirkendall Effect. for supercapacitor
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2015 Synthesis of Oxidized Graphene Anchored Porous Manganese Sulfide Nanocrystal
More informationSelf-assembled pancake-like hexagonal tungsten oxide with ordered mesopores for supercapacitors
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2018 Electronic Supporting Information Self-assembled pancake-like hexagonal
More informationCobalt Ferrite bearing Nitrogen Doped Reduced. Graphene Oxide Layers Spatially Separated with. Electrocatalyst
Supporting Information Cobalt Ferrite bearing Nitrogen Doped Reduced Graphene Oxide Layers Spatially Separated with Microporous Carbon as Efficient Oxygen Reduction Electrocatalyst Varchaswal Kashyap,,
More informationElectronic Supplementary Information
Electronic Supplementary Information Graphene-based Hollow Spheres as Efficient Electrocatalyst for Oxygen Reduction Longfei Wu, Hongbin Feng, Mengjia Liu, Kaixiang Zhang and Jinghong Li* * Department
More informationSupporting Information
Supporting Information A General Strategy for the Synthesis of Transition-Metal Phosphide/N-doped Carbon Frameworks for Hydrogen and Oxygen Evolution Zonghua Pu, Chengtian Zhang, Ibrahim Saana Amiinu,
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2018 Electronic Supplementary Information Magnesium-Regulated Oxygen Vacancies
More informationLotus root-like porous carbon nanofiber anchored with CoP nanoparticles as all-ph hydrogen evolution electrocatalysts
Electronic Supplementary Material Lotus root-like porous carbon nanofiber anchored with CoP nanoparticles as all-ph hydrogen evolution electrocatalysts Hengyi Lu 1, Wei Fan 2 ( ), Yunpeng Huang 1, and
More informationCo-vacancy-rich Co 1 x S nanosheets anchored on rgo for high-efficiency oxygen evolution
Electronic Supplementary Material Co-vacancy-rich Co 1 x S nanosheets anchored on rgo for high-efficiency oxygen evolution Jiaqing Zhu 1, Zhiyu Ren 1 ( ), Shichao Du 1, Ying Xie 1, Jun Wu 1,2, Huiyuan
More informationSupporting information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 Supporting information Self-Supported Three-dimensional Cu/Cu 2 O-CuO/rGO Nanowire Arrays Electrode
More informationExperimental Section Materials. Synthesis of as-prepared SnPi. Synthesis of nanocomposite. Characterizations.
Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2017 Experimental Section Materials. Triblock copolymer poly(ethylene glycol)-block-poly-(propylene
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information Hierarchical MoS 2 microboxes constructed
More information1D N-Doped Hierarchically Porous Hollow Carbon Tubes Derived. from Supramolecular Template as Metal-Free Electrocatalysts for
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2018 Supporting Information 1D N-Doped Hierarchically Porous Hollow Carbon Tubes
More informationSupporting Information. Mixed-Node Metal-Organic Frameworks as Efficient Electrocatalysts for Oxygen Evolution Reaction
Supporting Information Mixed-Node Metal-Organic Frameworks as Efficient Electrocatalysts for Oxygen Evolution Reaction Xiaohua Zhao, a Brian Pattengale, b Donghua Fan, c Zehua Zou, a Yongqing Zhao, a Jing
More informationEasy synthesis of hollow core, bimodal mesoporous shell carbon nanospheres and their. application in supercapacitor
Electronic Electronic Supplementary Information Easy synthesis of hollow core, bimodal mesoporous shell carbon nanospheres and their application in supercapacitor Bo You, Jun Yang,* Yingqiang Sun and Qingde
More informationCdS layer as a superior electrocatalyst for hydrogen evolution
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2017 Ni 3 S 2 @MoO 3 core/shell arrays on Ni foam modified with Ultrathin CdS layer as a superior electrocatalyst
More informationMg, Zn) as High Voltage Layered Cathodes for
Supporting Information for Honeycomb-Ordered Na 3 Ni 1.5 M 0.5 BiO 6 (M = Ni, Cu, Mg, Zn) as High Voltage Layered Cathodes for Sodium-Ion Batteries Peng-Fei Wang, a,d, Yu-Jie Guo, a,d, Hui Duan, a,d Tong-Tong
More informationGeneral Synthesis of Graphene-Supported. Bicomponent Metal Monoxides as Alternative High- Performance Li-Ion Anodes to Binary Spinel Oxides
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information (ESI) General Synthesis of Graphene-Supported
More informationElectronic supplementary information for Chemical Communications
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 Electronic supplementary information for Chemical Communications Synthesis of hierarchical Pd 4
More informationDetermination of Electron Transfer Number for Oxygen Reduction Reaction: from Theory to Experiment
Supporting Information Determination of Electron Transfer Number for Oxygen Reduction Reaction: from Theory to Experiment Ruifeng Zhou 1, 2, Yao Zheng 1, Mietek Jaroniec 3 and Shi-Zhang Qiao 1, * 1 School
More informationSupporting Information
Supporting Information A Novel Potassium-Ion Hybrid Capacitor Based on an Anode of K 2 Ti 6 O 13 Micro-Scaffolds Shengyang Dong,, Zhifei Li, Zhenyu Xing, Xianyong Wu, Xiulei Ji*, and Xiaogang Zhang*, Jiangsu
More informationSupplementary Information
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2017 Supplementary Information The electrochemical discrimination of pinene enantiomers by
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 Electronic Supplementary Information Experimental section Materials: Ti mesh (TM) was provided
More informationSupplementary Information for
Supplementary Information for Facile transformation of low cost thiourea into nitrogen-rich graphitic carbon nitride nanocatalyst with high visible light photocatalytic performance Fan Dong *a, Yanjuan
More informationSupporting Information
Supporting Information MoSe2 embedded CNT-Reduced Graphene Oxide (rgo) Composite Microsphere with Superior Sodium Ion Storage and Electrocatalytic Hydrogen Evolution Performances Gi Dae Park, Jung Hyun
More informationFlexible Asymmetrical Solid-state Supercapacitors Based on Laboratory Filter Paper
SUPPORTING INFORMATION Flexible Asymmetrical Solid-state Supercapacitors Based on Laboratory Filter Paper Leicong Zhang,,,# Pengli Zhu,,,#, * Fengrui Zhou, Wenjin Zeng, Haibo Su, Gang Li, Jihua Gao, Rong
More informationAtomic H-Induced Mo 2 C Hybrid as an Active and Stable Bifunctional Electrocatalyst Supporting Information
Atomic H-Induced Mo 2 C Hybrid as an Active and Stable Bifunctional Electrocatalyst Supporting Information Xiujun Fan, * Yuanyue Liu, ς Zhiwei Peng, Zhenhua Zhang, # Haiqing Zhou, Xianming Zhang, Boris
More informationSupporting Information. High Wettable and Metallic NiFe-Phosphate/Phosphide Catalyst Synthesized by
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2018 Supporting Information High Wettable and Metallic NiFe-Phosphate/Phosphide
More informationbifunctional electrocatalyst for overall water splitting
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Hierarchical Ni/NiTiO 3 derived from NiTi LDHs: a bifunctional electrocatalyst
More informationSupporting Information. for Water Splitting. Guangxing Zhang, Jie Yang, Han Wang, Haibiao Chen, Jinlong Yang, and Feng Pan
Supporting Information Co 3 O 4-δ Quantum Dots as a Highly Efficient Oxygen Evolution Reaction Catalyst for Water Splitting Guangxing Zhang, Jie Yang, Han Wang, Haibiao Chen, Jinlong Yang, and Feng Pan
More informationSupporting Information
Supporting Information High Performance Electrocatalyst: Pt-Cu Hollow Nanocrystals Xiaofei Yu, a Dingsheng, a Qing Peng a and Yadong Li* a a Department of Chemistry, Tsinghua University, Beijing, 100084
More informationElectronic Supplementary Information
Electronic Supplementary Information Nano-Tungsten Carbide Decorated Graphene as Co-catalyst for Enhanced Hydrogen Evolution on Molybdenum Disulfide Ya Yan, a Baoyu Xia, a Xiaoying Qi, c Haibo Wang, a
More informationFlexible Waterproof Rechargeable Hybrid Zinc Batteries Initiated. by Multifunctional Oxygen Vacancies-Rich Cobalt Oxide
Flexible Waterproof Rechargeable Hybrid Zinc Batteries Initiated by Multifunctional Oxygen Vacancies-Rich Cobalt Oxide Longtao Ma 1, Shengmei Chen 1, Zengxia Pei 1, Hongfei Li 1, Zifeng Wang 1, Zhuoxin
More informationHigh Salt Removal Capacity of Metal-Organic Gel Derived. Porous Carbon for Capacitive Deionization
Supporting Information High Salt Removal Capacity of Metal-Organic Gel Derived Porous Carbon for Capacitive Deionization Zhuo Wang, Tingting Yan, Guorong Chen, Liyi Shi and Dengsong Zhang* Research Center
More informationShape-selective Synthesis and Facet-dependent Enhanced Electrocatalytic Activity and Durability of Monodisperse Sub-10 nm Pt-Pd Tetrahedrons and Cubes
Supporting Information Shape-selective Synthesis and Facet-dependent Enhanced Electrocatalytic Activity and Durability of Monodisperse Sub-10 nm Pt-Pd Tetrahedrons and Cubes An-Xiang Yin, Xiao-Quan Min,
More informationBoron-doped graphene as high-efficiency counter electrode for dye-sensitized solar cells
Electronic Supplementary Information Boron-doped graphene as high-efficiency counter electrode for dye-sensitized solar cells Haiqiu Fang #, Chang Yu #, Tingli Ma, and Jieshan Qiu* Carbon Research Laboratory,
More informationSupporting Information
Supporting Information Universal, In-Situ Transformation of Bulky Compounds into Nanoscale Catalysts by High Temperature Pulse Shaomao Xu 1, (a), Yanan Chen 1, (a), Yiju Li 1, (a), Aijiang Lu 1, Yonggang
More informationTailorable and Wearable Textile Devices for Solar Energy Harvesting and Simultaneous Storage
Supporting Information Tailorable and Wearable Textile Devices for Solar Energy Harvesting and Simultaneous Storage Zhisheng Chai,, Nannan Zhang,, Peng Sun, Yi Huang, Chuanxi Zhao, Hong Jin Fan, Xing Fan,*,
More informationFabrication of Metallic Nickel-Cobalt Phosphide Hollow Microspheres for. High-Rate Supercapacitors
Supporting Information Fabrication of Metallic Nickel-Cobalt Phosphide Hollow Microspheres for High-Rate Supercapacitors Miao Gao, Wei-Kang Wang, Xing Zhang, Jun Jiang, Han-Qing Yu CAS Key Laboratory of
More informationHydrogen Evolution Electrocatalysts in Basic Solutions
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Supporting Information for Interlaced NiS 2 -MoS 2 Nanoflake-Nanowires
More informationBioinspired Cobalt-Citrate Metal-Organic Framework as An Efficient Electrocatalyst for Water Oxidation
Supporting Information Bioinspired Cobalt-Citrate Metal-Organic Framework as An Efficient Electrocatalyst for Water Oxidation Jing Jiang*, Lan Huang, Xiaomin Liu, Lunhong Ai* Chemical Synthesis and Pollution
More informationSupplementary Information
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2014 Supplementary Information A honeycomb-like porous carbon derived from pomelo peel for use in high-performance
More informationSupporting information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2015 Supporting information The Assembly of Vanadium (IV)-Substituted Keggin-type
More informationSupporting Information. Electronic Modulation of Electrocatalytically Active. Highly Efficient Oxygen Evolution Reaction
Supporting Information Electronic Modulation of Electrocatalytically Active Center of Cu 7 S 4 Nanodisks by Cobalt-Doping for Highly Efficient Oxygen Evolution Reaction Qun Li, Xianfu Wang*, Kai Tang,
More informationNickel Phosphide-embedded Graphene as Counter Electrode for. Dye-sensitized Solar Cells **
Nickel Phosphide-embedded Graphene as Counter Electrode for Dye-sensitized Solar Cells ** Y. Y. Dou, G. R. Li, J. Song, and X. P. Gao =.78 D 1359 G 163 a =.87 D 138 G 159 b =1.3 D 1351 G 1597 c 1 15 1
More informationMultiply twinned Pt Pd nanoicosahedrons as highly active electrocatalyst for methanol oxidation
Supporting Information for Multiply twinned Pt Pd nanoicosahedrons as highly active electrocatalyst for methanol oxidation An-Xiang Yin, Xiao-Quan Min, Wei Zhu, Hao-Shuai Wu, Ya-Wen Zhang* and Chun-Hua
More information