Name Date Class MOLECULAR COMPOUNDS. Distinguish molecular compounds from ionic compounds Identify the information a molecular formula provides

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1 8.1 MOLECULAR COMPOUNDS Section Review Objectives Distinguish molecular compounds from ionic compounds Identify the information a molecular formula provides Vocabulary covalent bond molecule diatomic molecule molecular compound molecular formula Part A Completion Use this completion exercise to check your understanding of the concepts and terms that are introduced in this section. Each blank can be completed with a term, short phrase, or number. Every substance is either an element or a(n) A compound is either 2 or ionic in nature. Most molecular 2. compounds are composed of two or more 3. Molecules 3. consisting of two atoms are 4 molecules. The chemical 4. formula of a molecular compound is a 5. Molecular 5. compounds tend to have 6 melting and boiling points, while 6. ionic compounds tend to have 7 melting and boiling points. 7. A molecular formula shows how many 8 of each 8. element a molecule contains, but it does not indicate the 9. 9 of the molecule. Part B True-False Classify each of these statements as always true, AT; sometimes true, ST; or never true, NT. 10. A diatomic molecule contains two or three atoms. 11. Molecular compounds have relatively high boiling points. Chapter 8 Covalent Bonding 181

2 12. The molecular structure of carbon dioxide is one carbon atom with two oxygen atoms on opposite sides of it. 13. Covalent bonds exist when combining atoms give up or accept electrons. 14. A molecule contains two atoms. Part C Matching Match each description in Column B to the correct term in Column A. Column A Column B molecule molecular compound covalent bond diatomic molecule molecular formula a. compound composed of molecules b. a molecule consisting of two atoms c. shows the kinds and numbers present in a molecule of a compound d. joins atoms held together by sharing electrons e. an electrically neutral group of atoms joined together by covalent bonds Part D Questions and Problems Answer the following in the space provided. 20. A compound has a boiling point of 40 C. Is this compound most likely an ionic or a molecular compound? 21. Identify the number and kinds of atoms present in a molecule of each compound. a. butane (C 4 H 10 ) b. fluorobenzene (C 6 H 5 F) 22. Classify each particle as an atom or a molecule. a. CH 4 d. He b. Ne e. CO 2 c. O Core Teaching Resources

3 8.2 THE NATURE OF COVALENT BONDING Section Review Objectives State a rule that usually tells how many electrons are shared to form a covalent bond Describe how electron dot formulas are used Predict when two atoms are likely to be joined by a double or a triple covalent bond Distinguish between a single covalent bond and other covalent bonds Describe how the strength of a covalent bond is related to its bond dissociation energy Describe how resonance structures explain bonding Identify some exceptions to the octet rule Vocabulary single covalent bond structural formulas unshared pairs double covalent bonds triple covalent bonds coordinate covalent bond polyatomic ion bond dissociation energy resonance structures Part A Completion Use this completion exercise to check your understanding of the concepts and terms that are introduced in this section. Each blank can be completed with a term, short phrase, or number. When atoms share electrons to gain the 1 configuration 1. of a noble gas, the bonds formed are 2. A 3 pair of 2. valence electrons constitutes a 4 covalent bond. Pairs of 3. valence electrons that are not shared between atoms are called Sometimes two or three pairs of electrons may be shared 5. to give 6 covalent bonds. In some cases, only one of the 6. atoms in a bond provides the pair of bonding electrons; this is a is required to break covalent bonds between 8. atoms. The total energy required to break the bond between two 9. covalently bonded atoms is known as the When it is possible to write two or more valid electron dot formulas for a molecule or ion, each formula is referred to as a 10. Chapter 8 Covalent Bonding 183

4 Part B True-False Classify each of these statements as always true, AT; sometimes true, ST; or never true, NT. 11. The modern interpretation of resonance is that electron pairs rapidly flip back and forth between the various electron dot structures. 12. The compound NH 3 contains two double covalent bonds. 13. The chemical formulas of molecular compounds show the number and type of atoms in each molecule. 14. A molecule of bromine has six unshared pairs of electrons. 15. Carbon forms four single covalent bonds with other atoms. 16. A bond in which one atom contributes both bonding electrons is called a polyatomic covalent bond. Part C Matching Match each description in Column B to the correct term in Column A. Column A Column B 17. single covalent bond 18. structural formula a. a chemical formula that shows the arrangement of atoms in a molecule or a polyatomic ion b. the amount of energy required to break a covalent bond between atoms 19. bond dissociation energy 20. polyatomic ion 21. coordinate covalent bond Part D Questions and Problems Answer the following in the space provided. 22. Draw electron dot structures for each of the following compounds a. Br 2 b. HCN c. a tightly bound group of atoms that has a positive or negative charge and behaves as a unit d. a covalent bond in which one atom contributes both bonding electrons e. a chemical bond in which only one pair of electrons is shared by two bonded atoms c. NH Core Teaching Resources

5 8.3 BONDING THEORIES Section Review Objectives Identify the difference between atomic and molecular orbits Describe how VSEPR theory helps predict the shapes of molecules Identify the ways in which orbital hybridization is useful in describing molecules Vocabulary molecular orbitals bonding orbital sigma bond pi bond tetrahedral angle VSEPR theory hybridization Part A Completion Use this completion exercise to check your understanding of the concepts and terms that are introduced in this section. Each blank can be completed with a term, short phrase, or number. The quantum mechanical model of bonding assumes that 1. atomic orbitals overlap to produce 1. A molecular orbit that 2. can be occupied by two electrons of a covalent bond is called a 3. 2, whose energy is 3 than that of the atomic orbitals 4. from which it formed. When two atomic orbitals combine to form 5. a molecular orbital that is symmetrical around the axis connecting 6. two atomic nuclei, a 4 bond is formed. When atomic 7. orbitals overlap side by side, they produce 5 bonds. 8. Electron dot structures fail to reflect the 6 shapes of molecules. 7 states that because electron pairs repel, molecular shape adjusts so the valence-electron pairs are as far apart as possible. Another way to describe molecules that provides information about both molecular bonding and molecular shape is 8. Chapter 8 Covalent Bonding 185

6 Part B True-False Classify each of these statements as always true, AT; sometimes true, ST; or never true, NT. 9. Unshared pairs of electrons affect the shape of molecules. 10. Molecular orbitals involve pi bonding. 11. A bonding orbital is a molecular orbital whose energy is higher than that of the atomic orbitals from which it is formed. 12. With hybridization, several atomic orbitals overlap to form the same total number of equivalent hybrid orbitals. 13. Sigma and pi bonds are found in the same molecule. 14. The methane molecule has four orbitals with tetrahedral angles of Part C Matching Match each description in Column B to the correct term in Column A. Column A Column B 15. sigma bond 16. pi bond a. states that because electron pairs repel, molecules adjust their shapes so that valence-electron pairs are as far apart as possible b. a process in which several atomic orbitals overlap to form the same number of equivalent hybrid orbitals 17. VSEPR theory 18. hybridization 19. linear molecule Part D Questions and Problems c. a term used to describe the shape of certain molecules such as CO 2 d. a bond formed when two atomic orbitals combine to form a molecular orbital that is symmetrical along the axis connecting the two atomic nuclei e. a bond in which the bonding electrons are most likely to be found in the sausage-shaped regions above and below the nuclei of the bonded atoms Answer the following in the space provided. 20. Indicate the hybrid orbitals used by each carbon atom in the following compound. H 3 C 2 C 3 C 2 C 4 C 2 CH 3 2 H 2 H 186 Core Teaching Resources

7 8.4 POLAR BONDS AND MOLECULES Section Review Objectives Describe how electronegativity values determine the charge distribution in a polar bond Describe what happens to polar molecules when placed between oppositely charged metal plates Distinguish intermolecular attractions from ionic bonds and from covalent bonds Identify the reason network solids have high melting points or decompose without melting Vocabulary nonpolar covalent bond polar covalent bond polar bond polar molecule dipole van der Waals forces dipole interactions dispersion forces hydrogen bonds network solids Part A Completion Use this completion exercise to check your understanding of the concepts and terms that are introduced in this section. Each blank can be completed with a term, short phrase, or number. When like atoms are joined by a covalent bond, the bonding 1. electrons are shared 1, and the bond is 2. When the 2. atoms in a bond are not the same, the bonding electrons are shared 3. 3, and the bond is 4. The degree of polarity of a bond 4. between any two atoms is determined by consulting a table of The attractions between opposite poles of polar molecules 6. are called 6. Another strong intermolecular attractive force 7. is the 7, in which a hydrogen covalently bonded to a very 8. 8 atom, such as 9, is also weakly bonded to an 9. unshared electron pair of another electronegative atom. Chapter 8 Covalent Bonding 187

8 Part B True-False Classify each of these statements as always true, AT; sometimes true, ST; or never true, NT. 10. In a polar covalent bond, the more electronegative atom has a slight positive charge. 11. In general, the electronegativity values of nonmetallic elements are greater than the electronegativity values of metallic elements. 12. A molecule with polar bonds is dipolar. 13. Covalent compounds are network solids. 14. If the electronegativity difference between two atoms is greater than 2.0, they will form an ionic bond. 15. Dispersion forces are weaker than hydrogen bonds. Part C Matching Match each description in Column B to the correct term in Column A. Column A Column B 16. nonpolar covalent bond 17. polar covalent bond 18. polar molecule 19. van der Waals forces 20. network solid a. a substance in which all of the atoms are covalently bonded to each other b. a bond formed when the atoms in a molecule are alike and the bonding electrons are shared equally c. a term used to describe the weakest intermolecular attractions; these include dispersion forces and dipole interactions d. a bond formed when two different atoms are joined by a covalent bond and the bonding electrons are shared unequally e. a molecule in which one end is slightly positive and the other end is slightly negative 188 Core Teaching Resources

9 Part D Questions and Problems Answer the following in the space provided. 21. Arrange the following intermolecular attractions in order of increasing strength: dipole interactions, dispersion forces, and hydrogen bonds. 22. State whether the following compounds contain polar covalent bonds, nonpolar covalent bonds, or ionic bonds, based on their electronegativities. a. KF a. b. SO 2 b. c. NO 2 c. d. Cl 2 d. Chapter 8 Covalent Bonding 189

Name Date Class MOLECULAR COMPOUNDS. Distinguish molecular compounds from ionic compounds Identify the information a molecular formula provides

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