1 Which is the equation for the reaction when steam passes over strongly heated magnesium? A. Mg(s) + 2H 2 O(l) Mg(OH) 2 (aq) + H 2 (g)

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1 1 Which is the equation for the reaction when steam passes over strongly heated magnesium? Mg(s) + 2H 2 O(l) Mg(OH) 2 (aq) + H 2 (g) Mg(s) + 2H 2 O(g) Mg(OH) 2 (s) + H 2 (g) Mg(s) + H 2 O(l) MgO(s) + H 2 (g) Mg(s) + H 2 O(g) MgO(s) + H 2 (g) 2 Which one of the following substances forms when a few drops of concentrated sulfuric acid is added to sodium chloride? H 2 O l 2 NaHSO 4 SO 2 PhysicsndMathsTutor.com

2 3 This question is about the reaction between sodium carbonate solution and dilute nitric acid. Na 2 O 3 (aq) + 2HNO 3 (aq) 2NaNO 3 (aq) + O 2 (g) + H 2 O(l) (a) What is the ionic equation for this reaction? Na 2 O 3 (aq) + 2H + (aq) 2Na + (aq) + O 2 (g) + H 2 O(l) Na + (aq) + N 3 (aq) NaNO 3 (aq) O 3 2 _ (aq) + 2H + (aq) O 2 (g) + H 2 O(l) O 3 2 _ (aq) + 2HNO 3 (aq) 2NO 3 (aq) + O 2 (g) + H 2 O(l) (b) What is the volume of carbon dioxide produced from the complete reaction of 0.10 mol of nitric acid at room temperature and pressure? [1 mol of any gas occupies 24 dm 3 at room temperature and pressure.] 1.2 dm dm dm dm 3 (c) What volume of sodium carbonate solution of concentration mol dm 3, would be needed to completely react with 25.0 cm 3 of nitric acid of concentration mol dm 3? 6.25 cm cm cm cm 3 = 3 marks) PhysicsndMathsTutor.com

3 4 In which of the following reactions is sulfuric(iv) acid, H 2 SO 3, acting as an oxidizing agent? H 2 SO 3 + H 2 O H 3 O + + HSO 3 H 2 SO 3 SO 2 + H 2 O H 2 SO 3 + 2Fel 3 + H 2 O 2Fel 2 + H 2 SO 4 + 2Hl H 2 SO 3 + 2H 2 S 3H 2 O + 3S 5 Which of the following is a redox reaction? r 2 O OH 2 2rO 4 + H 2 O [u(h 2 O) 6 ] l [ul 4 ] 2 + 6H 2 O 4OH 2 + 4MnO 4 4MnO 4 + 2H 2 O + O 2 [Fe(H 2 O) 6 ] OH [Fe(H 2 O) 3 (OH) 3 ] + 3H 2 O 6 The oxidation state of nickel is not +2 in [Ni(O) 4 ] [Ni(H 2 O) 4 (OH) 2 ] [Ni(NH 3 ) 6 ] 2+ [Ni(N) 4 ] 2 PhysicsndMathsTutor.com

4 7 What is the oxidation number of phosphorus in P 4 O 6? What is the oxidation number of chlorine in l 2 O 7? The thermite reaction, shown below, is a useful industrial process. The iron in this reaction undergoes Fe 2 O 3 (s) + 2l(s) 2Fe(l) + l 2 O 3 (s) disproportionation. oxidation. redox. reduction. PhysicsndMathsTutor.com

5 The equation representing the reaction between copper(ii) oxide and dilute sulfuric acid is uo(s) + H 2 SO 4 (aq)uso 4 (aq) + H 2 O(l) The ionic equation for the reaction is u 2+ (s) + SO 4 2 (aq)uso 4 (aq) O 2 (s) + H 2 SO 4 (aq)h 2 O(l) + SO 4 2 (aq) uo(s) + 2H + (aq)u 2+ (aq) + H 2 O(l) uo(s) + H 2 SO 4 (aq)u 2+ SO 4 2 (aq) + H 2 O(l) 12 The oxidation number of sulfur in sodium hydrogensulfide, NaHS, is PhysicsndMathsTutor.com

6 13 Which of the following is not a disproportionation reaction? l 2 + 2OH l + lo + H 2 O u 2 O + H 2 SO 4 uso 4 + u + H 2 O 3IO 2I + IO 3 u + 4HNO 3 u(no 3 ) 2 + 2H 2 O + 2NO 2 14 When solutions of iodine are titrated with aqueous sodium thiosulfate solution, Na 2 S 2 O 3 (aq), the thiosulfate ions are oxidized to S 2 O 4 2 S 2 O 6 2 S 2 O 8 2 S 4 O What is the oxidation number of chlorine in the lo 3 ion? PhysicsndMathsTutor.com

7 16 Which of these reactions is not a redox reaction? Mg(NO 3 ) 2 (s) MgO(s) + 2NO 2 (g) + ½O 2 (g) Hl(aq) + NaOH(aq) Nal(aq) + H 2 O(l) Fe(s) + uso 4 (aq) FeSO 4 (aq) + u(s) l 2 (aq) + 2r (aq) 2l (aq) + r 2 (aq) 17 Iodine can react with sodium hydroxide solution to form NaIO 3 (aq), according to the equation below. 3I 2 (aq) + 6NaOH(aq) 5NaI(aq) + NaIO 3 (aq) + 3H 2 O(l) Which of the statements about the reaction is false? The oxidation number of some iodine atoms goes up. t high temperatures NaIO(aq) also forms. Sodium ions are spectator ions. The oxidation number of some iodine atoms goes down. 18 When aqueous solutions of barium chloride and potassium sulfate are mixed, a white precipitate forms. The ionic equation for the reaction is + K (aq) + l (aq) Kl(s) K 2+ (aq) + 2l (aq) Kl 2 (s) a + (aq) + SO 4 (aq) aso (s) 4 a 2+ 2 (aq) + SO 4 (aq) aso (s) 4 PhysicsndMathsTutor.com

8 19 When g of copper (relative atomic mass, RM = 63.5) is added to an excess of silver nitrate solution, g of silver (RM = 107.9) form. The ionic equation for the reaction is u(s) + g 2+ (aq) u 2+ (aq) + g(s) u(s) + g + (aq) u + (aq) + g(s) 2u(s) + g 2+ (aq) 2u + (aq) + g(s) u(s) + 2g + (aq) u 2+ (aq) + 2g(s) 2 20 The oxidation number of sulfur in thiosulfate ions, S 2 O 3, is Which of the following is a redox reaction? a + 2H 2 O a(oh) 2 + H 2 MgO + H 2 O Mg(OH) 2 Nal + gno 3 gl + NaNO 3 Na 2 O 3 + 2Hl 2Nal + O 2 + H 2 O PhysicsndMathsTutor.com

9 22 What is the oxidation number of oxygen in OF 2? In which of the following reactions is sulfuric(iv) acid, H 2 SO 3, acting as an oxidizing agent? 2NaOH + H 2 SO 3 Na 2 SO 3 + 2H 2 O 2Fel 3 + H 2 SO 3 + H 2 O 2Fel 2 + H 2 SO 4 + 2Hl 2H 2 S + H 2 SO 3 3H 2 O + 3S H 2 SO 3 H 2 O + SO 2 24 For the oxidation of ammonia a NH 3 + b O 2 c NO + d H 2 O the values of the coefficients in the balanced equation are a 2, b 3, c 2 and d 3 a 4, b 7, c 4 and d 4 a 4, b 5, c 4 and d 6 a 6, b 7, c 6 and d 9 PhysicsndMathsTutor.com

10 25 hemical reactions may involve oxidation reduction no change in oxidation number disproportionation Which of the terms above best describes what happens to the chlorine in the following reactions? (a) l 2 (g) + H 2 O(l) Hl(aq) + HOl(aq) (b) 2(g) + 2Na(s) 2Nal(s) (c) Nal(s) + H 2 SO 4 (l) Hl(g) + NaHSO 4 (s) = 3 marks) PhysicsndMathsTutor.com

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