UNIVERSITI MALAYSIA PERLIS (UniMAP) Pusat Pengajian Kejuruteraan Bioproses COURSE OUTLINE

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1 (1) Kod kursus/ Course code: ERT 206 UNIVERSITI MALAYSIA PERLIS (UniMAP) Pusat Pengajian Kejuruteraan Bioproses COURSE OUTLINE (2) Tajuk kursus/ Course title: Termodinamik/ Thermodynamics (3) Nilai unit/ Number of unit: 4 (4) Jenis kursus/ Course type: Teras/ Core (5) Prasyarat/ Prerequisite: ERT 108 (6) Sinopsis kursus/ Course synopsis: This course covers the concept of chemical and biochemical engineering thermodynamics. It provides the basic tools necessary for the students to be exposed to the fundamentals properties of thermodynamics and the law of thermodynamics in engineering systems. Also are provided with a comprehensive exposure to the theory as well as to the application of thermodynamics solution and the equation of state for pure and mixture fluids, the phase equilibrium and chemical reaction equilibrium calculations. (7) ) Hasil Pembelajaran / Learning Outcomes: At the end of the course, students are expected to be: 1. Ability to analyze and evaluate the fundamental properties with tool of mathematics, science and engineering and apply the law of thermodynamics to perform team work through group weekly meetings. 2. Ability to design solution for heat, work and other thermodynamic properties ideal fluid and real fluid by using volumetric equations of state and formulate a sound proposal in bioprocess engineering project to develop thermodynamic properties relation. 3. Ability to identify theory of the solution thermodynamics as well as the equation of state for pure and mixture fluids to solve phase equilibrium and chemical reaction equilibrium calculation. (8) Senarai eksperimen yang mungkin/ List of possible experiments: NIL (9) Pendekatan pembelajaran/ Learning approach: i) Lecture= 56 hours (100 %)

2 (10) Sumbangan penilaian/ Evaluation contribution: (i) Peperiksaan/ Examination: 70% Midterm Examinations = 20% Final Examination = 50% (ii) Penilaian Berterusan/Continual Assessment: 30% Assignments /Quizzes = 15% Integrated project = 15% (11) Pensyarah /Lecturers i. Zulhaimi (C) ii. (12) Senarai buku teks dan rujukan/ List of text books and references : (Dahulukan dengan rujukan yang utama/ list main texts/references first) Buku Teks: i) Cengel, Y.A. and Boles, M.A., Thermodynamics-An engineering Approach, 7 th edition, McGraw-Hill, ii) Smith, J.M., Van Ness, H.C. and Abbort, M.M., introduction to Chemical Engineering Thermodynamics, Seventh Edition, McGraw-Hill, iii) Narayanan, K.V. A Text Book of Chemical Engineering Thermodynamics, Prentice-Hall India, iv) K. Iynkaran, J. David and Tandy, Basic Thermodynamics Applications and Pollution Control, 2 nd edition, Pearson Prentice Hall, v) Stanley I. Sandler, Chemical, biochemical, and engineering thermodynamics, Volume 1, 4 th edition, John Wiley & Sons, 2006.

3 RANCANGAN MENGAJAR/LESSON PLAN StudyWeek Week 1 (16 Feb 20 Feb) Week 2 (23 Feb 27 Feb) Week 3-4 (2 March 13 Week 5 (16 March 20 Week 6 (23 March 27 Week 7 30 March 3 Apr Kandungan Kursus / Course Contents (Panduan/Guidelines) Introduction to Thermodynamics Unique vocabulary and scope, dimensions and units, measure of amount or size, force, temperature, pressure, work, energy and heat General energy analysis and The first law of thermodynamics Forms of energy, the nature of internal energy, energy transfer by heat, First law of thermodynamics, energy balances and mechanisms of energy transfer. Volumetric properties of pure fluids Pure substances, phase- change processes, P- v, T- v, P- v property diagrams and P- v- T surfaces of pure substances, property tables, the ideal- gas equation of state, compressibility factor and other equations of state. Mass and Energy Analysis Moving boundary work, energy balance for closed systems, specific heat at constant volume and pressure, internal energy, enthalpy and specific heats of ideal gases and incompressible substances, mass and energy balances for steady- and unsteady- flow processes. Second law of thermodynamics Second law of thermodynamics, thermal energy reservoirs, heat engines, refrigerators and heat pumps, Kelvin- Planck and Clausius statements, reversible and irreversible processes, thermodynamics temperature scale. Entropy Entropy, some remark about entropy, entropy changes of pure substances, incompressible substances and ideal gases, isentropic processes, reversible steady- flow work Pensyarah/Lecturer

4 relations and the entropy balance to various systems. Week 8 (6 Apr 12 Apr) Week 9 (13 Apr 17 Apr) CUTI PERTENGAHAN SEMESTER/ MID- TERM BREAK Refrigeration Cycles Refrigerators and heat pumps, ideal vapor- compression refrigeration cycle and the actual vapor- compression refrigeration cycle, selecting the right refrigerant, heat pump systems, gas refrigeration systems and absorption- refrigeration systems. Week 10 (20 Apr 24 Apr) Week 11 (27 Apr 1 May) Week (4 May 15 May) Week (18 May 29 May) Thermodynamics property relations Partial derivatives and associated relations, Maxwell relation, Clapeyron equation and enthalpy of vaporization, general relation of Cv, Cp, du, dh and ds, the h, u, and s of real gases (enthalpy, internal energy and entropy changes of real gases). Vapor/ Liquid Equilibrium: Introduction The nature of equilibrium, the phase rule. Duhem s Theorem, VLE: Qualitative behavior, simple models for vapor/liquid equilibrium, VLE by modified Roult s Law and VLE from K- Value correlations. Solution Thermodynamics: Theory and Applications Fundamental property relation, the chemical potential and phase equilibrium, partial properties, the ideal- gas mixture model, fugacity and fugacity coefficient; Pure species and species in solution, generalized correlations for the fugacity coefficient, the ideal- solution model, excess properties, liquid- phase properties from VLE data, models for the excess Gibbs energy, property changes in mixing and heat effects of mixing processes. Chemical- Reaction Equilibrium The reaction coordinate, application of equilibrium criteria to chemical reactions, the standard Gibbs- energy change and equilibrium constant, effect of temperature on the equilibrium constant, evaluation of equilibrium constants, relation of equilibrium constants to

5 composition, equilibrium conversions for single reactions, phase rule and Duhem s Theorem for reacting systemsand multireaction equilibrium. Week 16 (1 st June 7 th June) Week (8 th June 28 th June) MINGGU ULANGKAJI / REVISION WEEK PEPERIKSAAN AKHIR SEMESTER / FINAL EXAMINATION