Name Date Class THE ARITHMETIC OF EQUATIONS

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1 Name Date Class 12.1 THE ARITHMETIC OF EQUATIONS Section Review Objectives Calculate the amount of reactants required or product formed in a nonchemical process Interpret balanced chemical equations in terms of interacting es, representative particles, masses, and gas volume at STP Vocabulary stoichiometry Part A Completion Use this completion exercise to check your understanding of the concepts and terms that are introduced in this section. Each blank can be completed with a term, short phrase, or number. The coefficients of a balanced chemical equation indicate 1. the relative number of 1 of reactants and products. All 2. stoichiometric calculations begin with a 2. Only 3 3. and 4 are conserved in every reaction; es, volumes, 4. and representative particles may not be. 5. In solving stoichiometric problems, conversion factors 6. relating es of reactants to If you assume about the volumes of gases. Part B True-False of products are used., the balanced equation also tells you Classify each of these statements as always true, AT; sometimes true, ST; or never true, NT The coefficients in a balanced chemical equation can be used to form e ratios relating reactants to products. 8. The coefficients in a balanced chemical equation tell the relative volumes of reactants and products, expressed in any suitable unit of volume. 9. To calculate the mass of a ecule in grams, you can use the ar mass and Avogadro s number. Chapter 12 Stoichiometry 289

2 Name Date Class 10. Because the mass of the reactants equals the mass of the products of a reaction, the number of es will be conserved. 11. If the ratio of ecules in the reaction 2A 2 B 2 y 2A 2 B is 2:1:2, we can predict that 4 ecules of A 2 react with 2 ecules B 2 to produce 4 ecules of A 2 B. 12. One e of any gas occupies a volume of 22.4 L. Part C Matching Match each description in Column B to the correct term in Column A Column A stoichiometry product coefficient C, kpa Column B a. Avogadro s number b. the calculations of quantities in chemical reactions c. STP d. a substance formed in a chemical reaction e. gives the relative number of ecules involved in a reaction Part D Questions and Problems Answer the following in the space provided. Show your work. 18. Interpret the following equation using es, ecules, and volumes (assume STP). Compare the mass of the reactants to the mass of the product. 2N 2 (g) 3O 2 (g) y 2N 2 O 3 (g) 19. How many es of chlorine gas will be required to react with sufficient iron to produce 14 es of iron(iii) chloride? 2Fe(s) 3Cl 2 (g) y 2FeCl 3 (g) 290 Core Teaching Resources

3 Name Date Class 12.2 CHEMICAL CALCULATIONS Section Review Objectives Construct e ratios from balanced chemical equations and apply these ratios in e-e stoichiometric calculations Calculate stoichiometric quantities from balanced chemical equations, using units of es, mass, representative particles, and volumes of gases at STP Key Equations e-e relationship used in every stoichiometric calculation: ag uy bw (given quantity) (wanted quantity) x G b W x b W a G a Given Mole Ratio Calculated Part A Completion Use this completion exercise to check your understanding of the concepts and terms that are introduced in this section. Each blank can be completed with a term, short phrase, or number. Mole ratios from balanced equations may be used to solve 1. problems with other units such as numbers of 1 and 2 2. of gases at STP. The 3 from the balanced equation are used 3. to write conversion factors called 4. These conversion factors 4. are used to calculate the numbers of es of 5 from a given 5. number of es of 6. In mass-mass calculations, the ar 6. mass is used to convert mass to Part B True-False Classify each of these statements as always true, AT; sometimes true, ST; or never true, NT. 8. In mass-mass calculations, the ar mass is used to convert mass to es. 9. The e ratio 2 HF/1 SnF 2 can be used to determine the mass of SnF 2 produced according to the equation: Sn(s) 2HF(g) y SnF 2 (s) H 2 (g) Chapter 12 Stoichiometry 291

4 Name Date Class 10. In a volume-volume problem, the 22.4 L/ factors always cancel out. 11. In stoichiometric problems, volume is expressed in terms of liters. 12. For a mass-e problem, the first conversion from mass to es is skipped. 13. For a mass-mass problem, the first conversion is from es to mass. 14. Because e ratios from balanced equations are exact numbers, they do not enter into the determination of significant figures. Part C Matching Match each conversion problem in Column A to the correct solution in Column B. Column A Column B 15. es O 2 y grams O 2 a. ecules g ecules 16. liters SO 2 y grams SO 2 at STP b. liters g L 17. ecules He y liters He(g) at STP c g 18. grams Sn y ecules Sn d. ecules L ecules 19. ecules H 2 O y grams H 2 O ecules e. grams 1 19 g Part D Questions and Problems Answer the following questions in the space provided. 20. How many liters of carbon monoxide (at STP) are needed to react with 4.8 g of oxygen gas to produce carbon dioxide? 2CO(g) O 2 (g) y 2CO 2 (g) 21. What mass of ammonia, NH 3, is necessary to react with ecules of oxygen in the following reaction? 4NH 3 (g) 7O 2 (g) y 6H 2 O(g) 4NO 2 (g) 292 Core Teaching Resources

5 Name Date Class 12.3 LIMITING REAGENT AND PERCENT YIELD Section Review Objectives Identify and use the limiting reagent in a reaction to calculate the maximum amount of product(s) produced and the amount of excess reagent Calculate theoretical yield, actual yield, or percent yield given the appropriate information Vocabulary limiting reagent excess reagent theoretical yield actual yield percent yield Key Equations actual yield percent yield 100 the oretical yield Part A Completion Use this completion exercise to check your understanding of the concepts and terms that are introduced in this section. Each blank can be completed with a term, short phrase, or number. Whenever quantities of two or more reactants are given in a 1. stoichiometric problem, you must identify the 1. This is the 2. reagent that is completely 2 in the reaction. The amount of 3. limiting reagent determines the amount of 3 that is formed. 4. When an equation is used to calculate the amount of product 5. that will form during a reaction, the value obtained is the This is the 5 amount of product that could be formed from a given amount of reactant. The amount of product that forms when the reaction is carried out in the laboratory is called the 6. Part B True-False Classify each of these statements as always true, AT; sometimes true, ST; or never true, NT. 7. Normally, the actual yield in a chemical reaction will be equal to or less than the theoretical yield. 8. The actual yield of a chemical reaction can be calculated using e ratios. Chapter 12 Stoichiometry 293

6 Name Date Class 9. The amount of product can be determined from the amount of excess reagent. 10. The percent yield of a product is 100 percent. 11. If you had 100 steering wheels, 360 tires, and enough of every other part needed to assemble a car, the limiting reagent would be tires. 12. The theoretical yield is the maximum amount of product that could be formed in a chemical reaction. Part C Matching Match each description in Column B to the correct term in Column A Column A actual yield limiting reagent theoretical yield percent yield Column B a. the ratio of the actual yield to the theoretical yield 100 b. the amount of product actually formed when a reaction is carried out in the laboratory c. the reactant that determines the amount of product that can be formed in a reaction d. the reactant that is not completely used up in a chemical reaction 17. excess reagent Part D Questions and Problems e. the maximum amount of product that can be formed during a reaction Answer the following in the space provided. 18. a. What is the limiting reagent when 3.1 of SO 2 react with 2.7 of O 2 according to the equation: 2SO 2 (g) O 2 (g) y 2SO 3 (g) b. Calculate the maximum amount of product that can be formed and the amount of unreacted excess reagent. 294 Core Teaching Resources