B. The rate will increase by a factor of twelve. C. The rate will increase by a factor of twenty-four. D. The rate will decrease by a factor of six.

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1 1. If O 2 (g) disappears at a rate of M/s at a particular moment in the reaction below, what is the rate of appearance of H 2 O(g) at the same time? C 3 H 8 (g) + 5 O 2 (g) 3 CO 2 (g) + 4 H 2 O(g) A M/s C M/s B M/s D M/s 2. For the reaction 2 H 2 (g) + 2 NO(g) N 2 (g) + 2 H 2 O(g) rate = k[h 2 ][NO] 2 what is the effect on the rate if the concentration of H 2 is tripled and that of NO is doubled? A. The rate will increase by a factor of six. B. The rate will increase by a factor of twelve. C. The rate will increase by a factor of twenty-four. D. The rate will decrease by a factor of six. 3. According to the plot, which of these reactions demonstrates first-order kinetics? A. Reaction 1 C. Reaction 3 B. Reaction 2 D. Reaction 4

2 4. Consider the following second-order reaction below. Starting with a concentration of M, what is the NO 2 concentration after 3.00 minutes? 2 NO 2 (g) 2 NO(g) + O 2 (g) k = M 1 s 1 A M C M B M D M 5. The decomposition of azomethane at 300 o C follows first-order kinetics with a half-life of 272 s. How long must the reaction run for the final concentration of CH 3 N 2 CH 3 to be 20.0% of the initial concentration? CH 3 N 2 CH 3 (g) N 2 (g) + C 2 H 6 (g) A minutes C minutes B minutes D minutes 6. A plot of ln k versus (1/T) yields a line with a slope of K. What information can we calculate from the slope? A. frequency factor, A C. activation energy, E a B. rate constant, k D. ideal gas constant, R

3 7. The following mechanism has been proposed for the reaction: 2 O 3 (g) 3 O 2 (g) Step 1 O 3 (g) + NO(g) O 2 (g) + NO 2 (g) Step 2 NO 2 (g) NO(g) + O(g) Step 3 O(g) + O 3 (g) 2 O 2 (g) What are the functions of NO(g) and NO 2 (g) in the reaction mechanism? A. NO and NO 2 are both intermediates. B. NO and NO 2 are both catalysts. C. NO is an intermediate and NO 2 is a catalyst. D. NO is a catalyst and NO 2 is an intermediate. 8. Given the balanced chemical equation and the experimental rate law, determine which is the slow (rate-determining) step in the proposed mechanism: 2 H 2 (g) + 2 NO(g) N 2 (g) + 2 H 2 O(g) Rate = k[h 2 ][NO] 2 2 NO(g) N 2 O 2 (g) Step 1 N 2 O 2 (g) + H 2 (g) N 2 O(g) + H 2 O(g) Step 2 N 2 O(g) + H 2 (g) N 2 (g) + H 2 O(g) Step 3 A. Step 1 C. Step 3 B. Step 2 D. The slow step cannot be determined from the information given.

4 9. Which statement is false concerning a catalyst? A. Catalysts increase the reaction rate by increasing the temperature of a reaction. B. A catalyst is a reactant in an elementary step of a mechanism but is not consumed in the overall reaction. C. Catalysts increase the reaction rate by decreasing the activation energy of the ratedetermining step. D. Catalysts can be homogenous or heterogeneous. 10. The reaction below has reached a state of dynamic equilibrium. Which one of the following statements about this reaction is true? 4 HCl(g) + O 2 (g) 2 Cl 2 (g) + 2 H 2 O(g) A. The forward and reverse reactions have stopped. B. The concentration of O 2 (g) must be half the concentration of Cl 2 (g). C. The rates of the forward and reverse reactions are equal. D. The concentrations of the reactants and products are still changing with time. 11. Initially, atm of CO(g) and 2.40 atm of H 2 (g) are placed in a reaction vessel. Given the balanced chemical equation and K p, what can be said about the equilibrium concentrations of reactants and products? CO(g) + 3 H 2 (g) CH 4 (g) + H 2 O(g) K p = A. The equilibrium lies far to the right and the partial pressures of the reactants will be significantly higher than the partial pressures of products. B. The equilibrium lies far to the right and the partial pressures of the products will be significantly higher than the partial pressures of reactants. C. The equilibrium lies far to the left and the partial pressures of the reactants will be significantly higher than the partial pressures of products. D. The equilibrium lies far to the left and the partial pressures of the products will be significantly higher than the partial pressures of reactants.

5 12. Given 2 H 2 (g) + O 2 (g) 2 H 2 O(g) K c1 = N 2 (g) + 3 H 2 (g) 2 NH 3 (g) K c2 = what will be the expression, K c3, for 4 NH 3 (g) + 3 O 2 (g) 2 N 2 (g) + 6 H 2 O(g) K c3 =? A. C. B. D. 13. Given 2 CH 4 (g) C 2 H 2 (g) + 3 H 2 (g) K c = at 1973 K what is the value of K p at 1973 K? A C B D

6 14. Calcium sulfate undergoes thermal decomposition according to the reaction 2 CaSO 4 (s) 2 CaO(s) + 2 SO 2 (g) + O 2 (g) K c =? What is K c for this reaction? A. C. B. D. 15. A reaction mixture initially contains 0.10 M CO and 0.10 M H 2 O. What is the equilibrium concentration of CO 2 in the reaction below? CO(g) + H 2 O(g) CO 2 (g) + H 2 (g) K c = 23 A M C M B M D M 16. Which way will the reaction proceed given the following initial concentrations? [SO 2 ] = M, [O 2 ] = M, [SO 3 ] = M 2 SO 2 (g) + O 2 (g) 2 SO 3 (g) K c = 1.98 at 1303 K A. to the left because Q > K C. to the right because Q > K B. to the left because Q < K D. to the right because Q < K

7 17. If the initial concentrations of hydrogen and iodine are both 0.15 M, what is the equilibrium concentration of HI? H 2 (g) + I 2 (g) 2 HI(g) K c = 60. at 25 C A M C M B M D M 18. Given PCl 3 (g) + Cl 2 (g) PCl 5 (g) H = 92.5 kj which changes will shift the equilibrium in favor of the reactants? A. increasing temperature, increasing P PCl5, and increasing volume B. decreasing temperature, increasing P PCl5, and increasing volume C. decreasing temperature, decreasing P PCl5, and decreasing volume D. increasing temperature, decreasing P PCl5, and decreasing volume 19. Given the following reaction 2 Mo(s) + CH 4 (g) Mo 2 C(s) + 2 H 2 (g) K p = 3.55 at 973 K which one of the following will result in the largest increase in the concentration of CH 4 (g)? A. remove Mo(s) C. remove Mo 2 C(s) B. increase the partial pressure of H 2 (g) D. add Ne(g) to increase the total pressure

8 20. Which pair identifies a Brønsted-Lowry conjugate acid-base pair and the function of each substance in the reaction below? NH 4 + (aq) + H 2 O(l) NH 3 (aq) + H 3 O + (aq) A. H 2 O, base; NH 3, conjugate acid C. H 2 O, acid; H 3 O +, conjugate base B. NH 4 +, base; H 2 O, conjugate acid D. NH 4 +, acid; NH 3, conjugate base 21. Which one of the following acids has the highest percent ionization at M? A. HCN, K a = C. HC 9 H 7 O 4, K a = B. H 3 BO 3, K a = D. HNO 2, K a = K w for water is at 50 C. Which of the following statements about water at 50 C is false? A. [H + ] = M for pure water at 50 C. B. [OH ] = M for pure water at 50 C. C. pk w = for water at 50 C. D. ph = for pure water at 50 C.

9 23. A solution contains M HClO 4, M HClO 2, M HClO, and M HCl. Which acidic species contribute significantly to the [H + ] and must be included in the ph calculation? A. HClO 4 and HClO 2 C. HClO 2 and HClO B. HClO 4 and HCl D. HClO and HCl 24. What is the percent ionization of a M solution of benzoic acid (HC 7 H 5 O 2, K a = )? A. 20.% C. 1.8% B. 9.0% D % 25. Which M solution will have the lowest ph? A. piperidine, C 5 H 10 NH, K b = B. ammonia, NH 3, K b = C. pyridine, C 5 H 5 N, K b = D. NaOH

10 Answer Key: 1. D 2. B 3. C 4. A 5. B 6. C 7. D 8. B 9. A 10. C 11. B 12. A 13. D 14. D 15. C 16. A 17. C 18. A 19. B 20. D 21. D 22. A 23. B 24. C 25. C

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