Experiment Correlations for Lehman, Microscale Operational Organic Chemistry 2/e

Size: px
Start display at page:

Download "Experiment Correlations for Lehman, Microscale Operational Organic Chemistry 2/e"

Transcription

1 Preface Introduction Laboratory Safety Chemistry and the Environment The Effect of ph on a Food Preservative. Learning Basic Operations. Separating the Components of Panacetin. Extraction and Evaporation. Identifying a Constituent of Panacetin. Recrystallization and Melting-Point Measurement. Synthesis of Salicylic Acid from Wintergreen Oil. Heating under Reflux. Preparation of Synthetic Banana Oil. Simple Distillation, Gas Chromatography. Separation of Petroleum Hydrocarbons. Fractional Distillation. A Green Synthesis of Camphor. Addition, Sublimation. Identification of a Petroleum Hydrocarbon. Boiling Point, Refractive Index. Isolation and Isomerization of Lycopene from Tomato Paste. Column Chromatography, UV-VIS. Isolation and Identification of the Major Constituent of Clove Oil. Steam Distillation, Infrared. Introduction; Laboratory Safety; Chemistry and the Environment; Minlab: Making Useful Laboratory Items; OP-1: Cleaning and Drying Glassware; OP-4: Weighing; OP-5: Measuring Volume; OP-6: Making Transfers; OP-16: Vacuum Filtration; OP-26: Washing and Drying Solids; Appendix: Laboratory Equipment; Appendix: Writing a Laboratory Report Chemistry and the Environment; The Effect of ph on a Food Preservative; Minilab: Extraction of Iodine by Dichloromethane; OP-4: Weighing; OP-5: Measuring Volume; OP-6: Making Transfers; OP-7a: Heat Sources; OP-16: Vacuum Filtration; OP- 18a: Liquid Liquid Extraction; OP-19: Evaporation; OP-26: Washing and Drying Solids Separating the Components of Panacetin; Minilab: Purification of an Unknown Compound by Recrystallization; OP-4: Weighing; OP-7a: Heat Sources; OP-26: Washing and Drying Solids; OP- 28a: Recrystallization from a Single Solvent; OP-33: Melting Point; Appendix: The Chemical Literature Synthesis and Spectral Analysis of Aspirin; Minilab: Developing and Testing a Hypothesis; OP-2: Using Specialized Glassware; OP-4: Weighing; OP-7a: Heat Sources; OP-7b: Smooth Boiling Devices; OP-7c: Heating Under Reflux; OP-16: Vacuum Recrystallization; OP-33: Melting Point; Appendix: Calculations for Organic Synthesis; Appendix: Planning an Experiment Synthesis of Salicylic Acid from Wintergreen Oil; Minilab: Preparation of Acetate Esters; OP-2: Using Specialized Glassware; OP-4: Weighing; OP-6: Making Transfers; OP-7: Heating; OP-10: Mixing; OP-24: Washing Liquids; OP-25: Drying Liquids; OP-30a: Distillation of Liquids; OP-37: Gas Chromatography; Appendix: Planning an Experiment Minilab: Gas Chromatographic Analysis of Commercial Xylene; OP-4: Weighing; OP-7: Heating; OP-32: Fractional Distillation; OP-37: Gas Chromatography Minilab: Isolation of an Expectorant from Cough Capsules; OP-4: Weighing; OP-8: Cooling; OP-10: Mixing; OP-11: Addition of Reactants; OP-16: Vacuum Filtration; OP-26: Washing and Drying Solids; OP-29: Sublimation; OP-33: Melting Point Minilab: A Missing-Label Puzzle; OP-4: Weighing; OP-5: Measuring Volume; OP-30: Simple Distillation; OP-34: Boiling Point; OP-35: Refractive Index Minilab: Paper Chromatography of Dyes in Commercial Drink Mixes; OP-6: Making Transfers; OP-17: Centrifugation; OP-18c: Liquid Solid Extraction; OP-19: Evaporation; OP-21a: Liquid Solid Column Chromatography; OP-24: Washing Liquids; OP-25: Drying Liquids; OP-41a: UV VIS Spectra Minilab: Gas Chromatographic Analysis of an Essential Oil from Orange Peel; OP-4: Weighing; OP-18: Extraction; OP-19: Evaporation; OP-20: Steam Distillation; OP-25: Drying Liquids; OP-39: Infrared

2 Identification of Unknown Ketones. Thin-Layer Chromatography, NMR. The Optical Activity of α-pinene: A Chemical Mystery. Vacuum Distillation, Optical Rotation. Investigation of a Chemical Bond by Infrared Properties of Common Functional Groups Thin-Layer Chromatographic Analysis of Drug Components Separation of an Alkane Clathrate Isomers and Isomerization Reactions Structures and Properties of Stereoisomers Bridgehead Reactivity in an S N 1 Solvolysis Reaction Minilab: Identification of an Unknown Felt-Tip-Pen Ink by TLC; OP-4: Weighing; OP-5: Measuring Volume; OP-16: Vacuum Filtration; OP-22: Thin-Layer Chromatography; OP-26: Washing and Drying Solids; OP-28b: Recrystallization from Mixed Solvents; OP-33: Melting Point; OP-40a: 1 H NMR ; Bibliography Minilab: Optical Rotation of Turpentine; OP-4: Weighing; OP-10: Mixing; OP-31: Vacuum Distillation; OP-34: Boiling Point; OP-36: Optical Rotation Minilab: The Structures of Organic Molecules; OP-39: Infrared Minilab: Who Else Has My Compound?; Qualitative Organic Analysis; OP-5: Measuring Volume; OP-30: Simple Distillation; OP-34: Boiling Point; OP-39: Infrared Minilab: Identification of an Unknown Felt-Tip-Pen Ink by TLC; ; OP-6: Making Transfers; OP-22: Thin-Layer Chromatography OP-10: Mixing; OP-16: Vacuum Filtration; OP-18: Extraction; OP- 19: Evaporation; OP-25: Drying Liquids; OP-26: Washing and Drying Solids; OP-39: Infrared Minilab: Isomers and Molecular Structure; OP-10: Mixing; OP-16: Vacuum Filtration; OP-26: Washing and Drying Solids; OP-33: Melting Point OP-7: Heating; OP-10: Mixing; OP-18: Extraction; OP-19: Evaporation; OP-25: Drying Liquids; OP-34: Boiling Point; OP- 35: Refractive Index; OP-36: Optical Rotation; OP-37: Gas Chromatography; OP-39: Infrared Minilab: Reactivities of Alkyl Halides in Nucleophilic Substitution Reactions; Minilab: An S N 1 Reaction of Bromotriphenylmethane; OP-5: Measuring Volume; OP-7: Heating; OP-10: Mixing Reaction of Iodoethane with Sodium Saccharin, an Ambident Nucleophile Dehydration of Methylcyclohexanols and the Evelyn Effect Testing Markovnikov s Rule Stereochemistry of Bromine Addition to trans -Cinnamic Acid A Green Synthesis of Adipic Acid Minilab: An S N 1 Reaction of Bromotriphenylmethane; OP-16: Vacuum Filtration; OP-26: Washing and Drying Solids; OP-33: Melting Point; OP-38: High-Performance Liquid Chromatography; OP-40: Nuclear Magnetic Resonance Minilab: Preparation and Properties of a Gaseous Alkene; ; OP-10: Mixing; OP-24: Washing Liquids; OP-25: Drying Liquids; OP-30: Simple Distillation; OP- 37: Gas Chromatography Minilab: Addition of Iodine to α-pinene; OP-7: Heating; OP-8: Cooling; OP-10: Mixing; OP-11: Addition of Reactants; OP-14: Trapping Gases; OP-18: Extraction; OP-18b: Salting Out; OP-19: Evaporation; OP-25: Drying Liquids; OP-30: Simple Distillation; OP:34: Boiling Point; OP-39: Infrared Minilab: Unsaturation in Commercial Products; OP-10: Mixing; OP-11: Addition of Reactants; OP-16: Vacuum Filtration; OP-26: Washing and Drying Solids; OP-28: Recrystallization; OP-33: Melting Point Minilab: The Nylon Rope Trick; OP-6: Making Transfers; OP-7: Heating; OP-8: Cooling; OP-10: Mixing; OP-16: Vacuum Recrystallization; OP-33: Infrared

3 Minilab: An S N 1 Reaction of Bromotriphenylmethane; Minilab: Free-Radical Stability; OP-6: Making Transfers; OP-7: Heating; OP-10: Mixing; OP-11: Addition of Reactants; OP-14: Trapping Gases; OP-15: Gravity Filtration; OP-16: Vacuum Filtration; OP- 19: Evaporation; OP-26: Washing and Drying Solids; OP-27: Cleaning and Drying Gases; OP-28: Recrystallization; OP-33: Preparation of Bromotriphenylmethane and the Trityl Free Radical Melting Point Minilab: The Nylon Rope Trick; OP-7: Heating; OP-10: Mixing; OP-16: Vacuum Filtration; OP-26: Washing and Drying Solids; Chain-Growth Polymerization of Styrene and Methyl Methacrylate OP-30: Simple Distillation; OP-39: Infrared OP-17: Centrifugation; OP-32: Fractional Distillation; OP-34: Synthesis of Ethanol by Fermentation Boiling Point Minilab: Nucleophilic Substitution Rates of Alcohols; OP-7: Heating; OP-10: Mixing; OP-14: Trapping Gases; OP-24: Washing Liquids; OP-25: Drying Liquids; OP-30: Simple Reaction of Butanols with Hydrobromic Acid Distillation; OP-34: Boiling Point; OP-39: Infrared Minilab: Oxidation of Alcohols by Potassium Permanganate; Borohydride Reduction of Vanillin to Vanillyl Alcohol Synthesis of Triphenylmethanol and the Trityl Carbocation An Unexpected Reaction of 2,3-Dimethyl-2,3-butanediol Identification of a Conjugated Diene from Eucalyptus Oil Spectral Identification of Monoterpenes Synthesis and Spectral Analysis of Aspirin Directive Effects in the Bromination of Vanillin Mechanism of the Nitration of Arenes by Nitronium Fluoborate Friedel Crafts Acylation of Anisole Minilab: Preparation of a Fluorescent Dye; OP-7: Heating; OP- 10: Mixing; OP-11: Addition of Reactants; OP-12a: Using Drying Tubes; OP-16: Vacuum Filtration; OP-17: Centrifugation; OP-19: Evaporation; OP-24: Washing Liquids; OP-25: Drying Liquids; OP-26: Washing and Drying Solids; OP-28: Recrystallization; OP- 33: Melting Point; OP-39: Infrared Minilab: Photoreduction of Benzophenone; Qualitative Organic Analysis; OP-7: Heating; OP-10: Mixing; OP-24: Washing Liquids; OP-25: Drying Liquids; OP-30: Simple Distillation; OP- 34: Boiling Point; OP-39: Infrared ; OP-40: Nuclear Magnetic Resonance Minilab: Diels Alder Reaction of Maleic Anhydride and Furan; OP-7: Heating; OP-16: Vacuum Filtration; OP-26: Washing and Drying Solids; OP-28: Recrystallization; OP-33: Melting Point; OP 37: Gas Chromatography; OP-39: Infrared Minilab: Identification of an Unknown Arene by NMR ; Minilab: Interpretation of a Mass Spectrum; OP-39: Infrared ; OP-40: Nuclear Magnetic Resonance ; OP-41: Ultraviolet Visible Minilab: Interpretation of a Mass Spectrum; OP-7: Heating; OP- 10: Mixing; OP-16: Vacuum Filtration; OP-26: Washing and Drying Solids; OP-28: Recrystallization; OP-39: Infrared ; OP-40: Nuclear Magnetic Resonance Minilab: Free-Radical Stability; OP-10: Mixing; OP-16: Vacuum Recrystallization; OP-33: Melting Point Minilab: Nitration of Naphthalene; OP-18: Extraction; OP-19: Evaporation; OP-24: Washing Liquids; OP-25: Drying Liquids; OP-37: Gas Chromatography Minilab: Preparation of Carbocations by the Friedel Crafts Reaction; OP-7: Heating; OP-10: Mixing; OP-11: Addition of Reactants; OP-12: Excluding Water from Reaction Mixtures; OP- 14: Trapping Gases; OP-16: Vacuum Filtration; OP-24: Washing Liquids; OP-25: Drying Liquids; OP-26: Washing and Drying Solids; OP-33: Melting Point; OP-39: Infrared

4 Determination of the Structure of a Natural Product in Anise Oil Identification of an Oxygen-Containing Organic Compound Oxidation of the Insect Repellent 6-12 Isomerization of a Cyclic Ketone A Wittig Reaction of trans -Cinnamaldehyde Effect of Reaction Conditions on the Condensation of Furfural with Cyclopentanone Electronic Effect of a para -Iodo Substituent Synthesis and Identification of an Unknown Carboxylic Acid Preparation of the Insect Repellent N,N -Diethyl-meta -toluamide Synthesis of Dimedone and Measurement of Its Tautomeric Equilibrium Constant Preparation of Para Red and Related Azo Dyes Isolation and Identification of the Major Constituent of Clove Oil; Minilab: Air Oxidation of Fluorene to 9-Fluorenone; OP-7: Heating; OP-10: Mixing; OP-16: Vacuum Filtration; OP-26: Washing and Drying Solids; OP-28: Recrystallization; OP-33: Melting Point; OP-39: Infrared Minilab: Oxidation of Alcohols by Potassium Permanganate; Minilab: Identification of an Unknown Arene by NMR ; ; OP-26: Washing and Drying Solids; OP-28: Recrystallization; OP-30: Simple Distillation; OP-33: Melting Point; OP-34: Boiling Point; OP-39: Infrared ; OP-40: Nuclear Magnetic Resonance ; Appendix: Properties of Organic Compounds OP-10: Mixing; OP-11: Addition of Reactants; OP-18: Extraction; OP-19: Evaporation; OP-25: Drying Liquids; OP-30: Simple Distillation; OP-39: Infrared Isomers and Isomerization Reactions; Qualitative Organic Analysis; OP-7: Heating; OP-8: Cooling; OP-10: Mixing; OP-18: Extraction; OP-19: Evaporation; OP-24: Washing Liquids; OP-25: Drying Liquids; OP-39: Infrared ; OP-40: Nuclear Magnetic Resonance Minilab: A Nucleophilic Addition-Elimination Reaction of Benzil; OP-7: Heating; OP-10: Mixing; OP-16: Vacuum Filtration; OP-18: Extraction; OP-19: Evaporation; OP-25: Drying Liquids; OP-26: Washing and Drying Solids; OP-28: Recrystallization; OP-33: Melting Point Minilab: Preparation of Aldol Condensation Products; OP-8: Cooling; OP-10: Mixing; OP-16: Vacuum Filtration; OP-17: Centrifugation; OP-18: Extraction; OP-19: Evaporation; OP-24: Washing Liquids; OP-25: Drying Liquids; OP-26: Washing and Drying Solids; OP-28: Recrystallization; OP-31: Vacuum Distillation; OP-33: Melting Point; OP-40: Nuclear Magnetic Resonance Minilab: Acid-Base Strengths of Organic Compounds; OP-7: Heating; OP-8: Cooling; OP-10: Mixing; OP-16: Vacuum Recrystallization Identification of a Conjugated Diene from Eucalyptus Oil; Minilab: Hydrolysis Rates of Esters; OP-10: Mixing: OP-15: Gravity Filtration; OP-16: Vacuum Filtration; OP-26: Washing and Drying Solids; OP-33: Melting Point; Appendix: Properties of Organic Compounds Minilab: Preparation of Benzamide; OP-7: Heating; OP-8: Cooling; OP-10: Mixing; OP-11: Addition of Reactants; OP-14: Trapping Gases; OP-18: Extraction; OP-19: Evaporation; OP-21: Column Chromatography; OP-24: Washing Liquids; OP-25: Drying Liquids; OP-37: Gas Chromatography; OP-39: Infrared ; OP-40: Nuclear Magnetic Resonance Minilab: Synthesis of Dimedone Derivatives of Benzaldehyde; OP-7: Heating; OP-10: Mixing: OP-13: Excluding Air from Reaction Mixtures; OP-16: Vacuum Filtration; OP-19: Evaporation; OP-26: Washing and Drying Solids; OP-28: Recrystallization; OP-33: Melting Point; OP-40: Nuclear Magnetic Resonance Minilab: A Diazonium Salt Reaction of 2-Aminobenzoic Acid; OP- 8: Cooling; OP-10: Mixing; OP-16: Vacuum Filtration; OP-26: Washing and Drying Solids

5 Reaction of Phthalimide with Sodium Hypochlorite Identification of an Unknown Amine Preparation and Mass Spectrum of 2-Phenylindole Nucleophilic Strength and Reactivity in S N Ar Reactions Structure of an Unknown D-Hexose Fatty Acid Content of Commercial Cooking Oils Structure of an Unknown Dipeptide Multistep Synthesis of Benzilic Acid from Benzaldehyde Using the Chemical Literature in an Organic Synthesis A Research Project in Organic Chemistry Minlab: Making Useful Laboratory Items Minilab: Extraction of Iodine by Dichloromethane Minilab: Purification of an Unknown Compound by Recrystallization Minilab: Developing and Testing a Hypothesis Minilab: Preparation of Acetate Esters Minilab: Gas Chromatographic Analysis of Commercial Xylene Minilab: Isolation of an Expectorant from Cough Capsules Minilab: A Missing-Label Puzzle Minilab: Paper Chromatography of Dyes in Commercial Drink Mixes Minilab: Gas Chromatographic Analysis of an Essential Oil from Orange Peel Minilab: Identification of an Unknown Felt-Tip Pen Ink by TLC Minilab: Optical Rotation of Turpentine Minilab: The Structures of Organic Molecules Minilab: Who Else Has My Compound? Minilab: Isomers and Molecular Structure Minilab: Reactivities of Alkyl Halides in Nucleophilic Substitution Reactions Minilab: An S N 1 Reaction of Bromotriphenylmethane Minilab: Preparation and Properties of a Gaseous Alkene Minilab: Beckmann Rearrangement of Benzophenone Oxime; OP-7: Heating; OP-8: Cooling; OP-9: Temperature Monitoring; OP-10: Mixing; OP-16: Vacuum Filtration; OP-26: Washing and Drying Solids; OP-28: Recrystallization; OP-33: Melting Point ; OP-26: Washing and Drying Solids; OP-28: Recrystallization; OP-30: Simple Distillation; OP-33: Melting Point; OP-34: Boiling Point; OP-39: Infrared ; Appendix: Properties of Organic Compounds Minilab: Dyeing with Indigo; OP-7: Heating; OP-9: Temperature Monitoring; OP-10: Mixing; OP-15: Gravity Filtration; OP-16: Vacuum Recrystallization; OP-29: Sublimation; OP-33: Melting Point; OP- 42: Mass OP-5: Measuring Volume; OP-10: Mixing; OP-41b: Colorimetry Minilab: Reactions of Monosaccharides with Phenols; OP-7: Heating; OP-8: Cooling; OP-10: Mixing; OP-16: Vacuum Recrystallization; OP-33: Melting Point; OP-36: Optical Rotation Minilab: Isolation of Trimyristin from Nutmeg; Minilab: Preparation of a Soap Using a Phase-Transfer Catalyst; OP-7: Heating; OP-18: Extraction; OP-19: Evaporation; OP-25: Drying Liquids; OP-37: Gas Chromatography Minilab: Isolation of a Protein from Milk; OP-3: Using Glass Rod and Tubing; OP-18: Extraction; OP-19: Evaporation; OP-22: Thin- Layer Chromatography; OP-23: Paper Chromatography; OP-24: Washing Liquids Minilab: A Spontaneous Reaction of Benzaldehyde; OP-7: Heating; OP-10: Mixing; OP-15: Gravity Filtration; OP-16: Vacuum Recrystallization; OP-33: Melting Point; OP-39: Infrared Appendix: Keeping a Laboratory Notebook; Appendix: The Chemical Literature; Bibliography Introduction; Appendix: Keeping a Laboratory Notebook; Appendix: The Chemical Literature Introduction Preparation of Bromotriphenylmethane and the Trityl Free Radical

6 Minilab: Addition of Iodine to α-pinene Minilab: Unsaturation in Commercial Products Minilab: Free-Radical Stability Minilab: The Nylon Rope Trick Minilab: Nucleophilic Substitution Rates of Alcohols Minilab: Photoreduction of Benzophenone Minilab: Oxidation of Alcohols by Potassium Permanganate Minilab: Preparation of a Fluorescent Dye Minilab: Diels Alder Reaction of Maleic Anhydride and Furan Identification of a Conjugated Diene from Eucalyptus Oil Minilab: Identification of an Unknown Arene by NMR Minilab: Interpretation of a Mass Spectrum Minilab: Nitration of Naphthalene Minilab: Preparation of Carbocations by the Friedel Crafts Reaction Minilab: Air Oxidation of Fluorene to 9-Fluorenone Minilab: A Nucleophilic Addition Elimination Reaction of Benzil Minilab: Preparation of Aldol Condensation Products Minilab: A Spontaneous Reaction of Benzaldehyde Minilab: Acid Base Strengths of Organic Compounds Minilab: Hydrolysis Rates of Esters Minilab: Preparation of Benzamide Minilab: Synthesis of Dimedone Derivatives of Benzaldehyde Minilab: A Diazonium Salt Reaction of 2-Aminobenzoic Acid Minilab: Beckmann Rearrangement of Benzophenone Oxime Minilab: Dyeing with Indigo Minilab: Reactions of Monosaccharides with Phenols Minilab: Isolation of Trimyristin from Nutmeg Minilab: Preparation of a Soap Using a Phase-Transfer Catalyst Minilab: Isolation of a Protein from Milk OP-1: Cleaning and Drying Glassware OP-2: Using Specialized Glassware OP-3: Using Glass Rod and Tubing OP-4: Weighing OP-5: Measuring Volume OP-6: Making Transfers OP-7: Heating OP-8: Cooling OP-9: Temperature Monitoring OP-10: Mixing OP-11: Addition of Reactants OP-12: Excluding Water from Reaction Mixtures OP-13: Excluding Air from Reaction Mixtures OP-14: Trapping Gases OP-15: Gravity Filtration OP-16: Vacuum Filtration OP-17: Centrifugation OP-18: Extraction OP-19: Evaporation OP-20: Steam Distillation OP-21: Column Chromatography OP-22: Thin-Layer Chromatography OP-23: Paper Chromatography OP-24: Washing Liquids Synthesis of Dimedone and Measurement of its Tautomeric Equilibrium Constant Identification of an Oxygen-Containing Organic Compound; Identification of an Unknown Amine; Appendix: Properties of Organic Compounds

7 OP-25: Drying Liquids OP-26: Washing and Drying Solids OP-27: Cleaning and Drying Gases OP-28: Recrystallization OP-29: Sublimation OP-30: Simple Distillation OP-31: Vacuum Distillation OP-32: Fractional Distillation OP-33: Melting Point OP-34: Boiling Point OP-35: Refractive Index OP-36: Optical Rotation OP-37: Gas Chromatography OP-38: High-Performance Liquid Chromatography OP-39: Infrared OP-40: Nuclear Magnetic Resonance OP-41: Ultraviolet Visible OP-42: Mass Appendix: Laboratory Equipment Appendix: Keeping a Laboratory Notebook Appendix: Writing a Laboratory Report Appendix: Calculations for Organic Synthesis Appendix: Planning an Experiment Appendix: Properties of Organic Compounds Appendix: The Chemical Literature Bibliography Bibliography Experiments Recommended to be Purchased Together: Basic Operations Set Learning Basic Operations. The Effect of ph on a Food Preservative Extraction and Evaporation. Separating the Components of Panacetin Recrystallization and Melting-Point Measurement. Identifying a Constituent of Panacetin Heating under Reflux. Synthesis of Salicylic Acid from Wintergreen Oil Simple Distillation, Gas Chromatography. Preparation of Synthetic Banana Oil Set Properties of Common Functional Groups Identification of an Oxygen-Containing Organic Compound Appendix: Properties of Organic Compounds

Introduction to Basic Laboratory Techniques Solubility Crystallization Extraction Chromatography Simple and Fractional Distillation Infrared

Introduction to Basic Laboratory Techniques Solubility Crystallization Extraction Chromatography Simple and Fractional Distillation Infrared Introduction to Basic Laboratory Techniques Solubility Crystallization Extraction Chromatography Simple and Fractional Distillation Infrared Spectroscopy and Boiling-Point Determination Essay: Aspirin

More information

Contents. ) 2013 Cengage Learning. All Rights May not be scanned, copied or or posted to a publicly accessible Website, in or in part.

Contents. ) 2013 Cengage Learning. All Rights May not be scanned, copied or or posted to a publicly accessible Website, in or in part. Contents Preface vii PART 1 Introduction to Basic Laboratory Techniques 1 1 Introduction to Microscale Laboratory 2 2 Solubility 12 3 Crystallization 22 3A Semimicroscale and Hirsch 23 3B Microscale 26

More information

Introduction Welcome to Organic Chemistry Laboratory Safety Organization of the Textbook Advance Preparation Budgeting Time Purpose The Techniques

Introduction Welcome to Organic Chemistry Laboratory Safety Organization of the Textbook Advance Preparation Budgeting Time Purpose The Techniques Introduction Welcome to Organic Chemistry Laboratory Safety Organization of the Textbook Advance Preparation Budgeting Time Purpose The Techniques Laboratory Safety The Laboratory Notebook, Calculations,

More information

KUT 206/2 Chemistry Practical I - Organic

KUT 206/2 Chemistry Practical I - Organic KUT 206/2 Chemistry Practical I - Organic Course Objective: 1) To become acquainted with the chemistry of functional groups and the principles of qualitative organic analysis. 2) To introduce the application

More information

Review Experiments Formation of Polymers Reduction of Vanillin

Review Experiments Formation of Polymers Reduction of Vanillin Review Experiments Formation of Polymers What is a polymer? What is polymerization? What is the difference between an addition polymerization and a condensation polymerization? Which type of polymerization

More information

CHE 171: Mechanistic Organic Chemistry I

CHE 171: Mechanistic Organic Chemistry I CHE 171: Mechanistic Organic Chemistry I Syllabus, Autumn Quarter 2003 Instructor: Dr. Matthew R. Dintzner Office hours: Mondays 9:00-11:30 AM, Tuesdays 10:00-12:30, or by appointment Office, Lab: O'Connell

More information

Keynotes in Organic Chemistry

Keynotes in Organic Chemistry Keynotes in Organic Chemistry Second Edition ANDREW F. PARSONS Department of Chemistry, University of York, UK Wiley Contents Preface xi 1 Structure and bonding 1 1.1 Ionic versus covalent bonds 1 1.2

More information

September [KV 804] Sub. Code: 3804

September [KV 804] Sub. Code: 3804 September 2009 [KV 804] Sub. Code: 3804 (Regulations 2008-2009) (Candidates admitted from 2008-2009 onwards) Paper IV PHARMACEUTICAL ORGANIC CHEMISTRY Time : Three hours Maximum : 70 marks Answer All questions

More information

PELLISSIPPI STATE TECHNICAL COMMUNITY COLLEGE MASTER SYLLABUS APPLIED ORGANIC CHEMISTRY W/ LAB CHT 2210

PELLISSIPPI STATE TECHNICAL COMMUNITY COLLEGE MASTER SYLLABUS APPLIED ORGANIC CHEMISTRY W/ LAB CHT 2210 PELLISSIPPI STATE TECHNICAL COMMUNITY COLLEGE MASTER SYLLABUS APPLIED ORGANIC CHEMISTRY W/ LAB CHT 2210 Class Hours: 3.0 Credit Hours: 4.0 Laboratory Hours: 3.0 Date Revised: Fall 2001 NOTE: This course

More information

CHEM2077 HONORS ORGANIC CHEMISTRY SYLLABUS

CHEM2077 HONORS ORGANIC CHEMISTRY SYLLABUS CHEM2077 HONORS ORGANIC CHEMISTRY SYLLABUS 1. STRUCTURE AND BONDING a] Atomic structure and bonding b] Hybridization and MO Theory c] Drawing chemical structures 2. POLAR COVALENT BONDS: ACIDS AND BASES

More information

KOT 222 Organic Chemistry II

KOT 222 Organic Chemistry II KOT 222 Organic Chemistry II Course Objectives: 1) To introduce the chemistry of alcohols and ethers. 2) To study the chemistry of functional groups. 3) To learn the chemistry of aromatic compounds and

More information

Alkyl phenyl ketones are usually named by adding the acyl group as prefix to phenone.

Alkyl phenyl ketones are usually named by adding the acyl group as prefix to phenone. Aldehydes, Ketones and Carboxylic Acids Nomenclature of aldehydes and ketones Aldehydes: Often called by their common names instead of IUPAC names. Ketones: Derived by naming two alkyl or aryl groups bonded

More information

3. Two unknown samples are found to have the same R f value under identical TLC conditions. Are they the same compound? Explain.

3. Two unknown samples are found to have the same R f value under identical TLC conditions. Are they the same compound? Explain. I. Techniques in Organic Lab and TLC Analysis a. Thin-Layer Chromatography 2. A TLC plate displays the compound spot approximately 3.2 cm above the base line upon visualization; the solvent ran 4.1 cm

More information

Organic Chemistry Review: Topic 10 & Topic 20

Organic Chemistry Review: Topic 10 & Topic 20 Organic Structure Alkanes C C σ bond Mechanism Substitution (Incoming atom or group will displace an existing atom or group in a molecule) Examples Occurs with exposure to ultraviolet light or sunlight,

More information

Module9. Nuclear Magnetic Resonance Spectroscopy Nuclear Magnetic Resonance (NMR) spectroscopy - Chemical shift - Integration of signal area

Module9. Nuclear Magnetic Resonance Spectroscopy Nuclear Magnetic Resonance (NMR) spectroscopy - Chemical shift - Integration of signal area 1 CHEMISTRY 263 HOME WORK Lecture Topics: Module7. Hydrogenation of Alkenes The Function of the Catalyst - Syn and anti- addition Hydrogenation of Alkynes - Syn- addition of hydrogen: Synthesis of cis-alkenes

More information

CHEMISTRY 263 HOME WORK

CHEMISTRY 263 HOME WORK Lecture Topics: CHEMISTRY 263 HOME WORK Module7: Hydrogenation of Alkenes Hydrogenation - syn and anti- addition - hydrogenation of alkynes - synthesis of cis-alkenes -synthesis of trans-alkenes Text sections:

More information

Course Outline For: Organic Chemistry I (CHM 270) Credits: 5 Contact Hours: Lecture: 3 Lab: 4

Course Outline For: Organic Chemistry I (CHM 270) Credits: 5 Contact Hours: Lecture: 3 Lab: 4 Course Outline For: Organic Chemistry I (CHM 270) Credits: 5 Contact Hours: Lecture: 3 Lab: 4 NOTE on Laboratory: Both Lecture and Laboratory must be taken simultaneously; separate grades will not be given

More information

Unit title: Organic Chemistry

Unit title: Organic Chemistry Unit title: Organic Chemistry Unit code: R/601/0352 QCF level: 4 Credit value: 15 Aim This unit develops the principles and practical techniques of organic chemistry. Rationalisation of structure and bonding

More information

Cape Cod Community College

Cape Cod Community College Cape Cod Community College Departmental Syllabus Prepared by the Department of Natural Sciences & Applied Technology Date of Departmental Approval: February 3, 2014 Date Approved by Curriculum and Programs:

More information

JEFFERSON COLLEGE COURSE SYLLABUS CHM201 ORGANIC CHEMISTRY II. 5 Credit Hours. Prepared by: Richard A. Pierce

JEFFERSON COLLEGE COURSE SYLLABUS CHM201 ORGANIC CHEMISTRY II. 5 Credit Hours. Prepared by: Richard A. Pierce JEFFERSON COLLEGE COURSE SYLLABUS CHM201 ORGANIC CHEMISTRY II 5 Credit Hours Prepared by: Richard A. Pierce Revised Date: January 2008 by Ryan H. Groeneman Arts & Science Education Dr. Mindy Selsor, Dean

More information

Review Questions for the Chem 2315 Final Exam

Review Questions for the Chem 2315 Final Exam Review Questions for the Chem 2315 Final Exam These questions do not have to be turned in, and will not be graded. They are intended to help you review the material we have covered in the lab so far, and

More information

Mechanisms. . CCl2 F + Cl.

Mechanisms. . CCl2 F + Cl. Mechanisms 1) Free radical substitution Alkane à halogenoalkane Initiation: Propagation: Termination: Overall: 2) Ozone depletion UV light breaks the C Cl bond releasing chlorine radical CFCl 3 F à. CCl2

More information

Hyperlearning MCAT Instructor Qualifying Exam Organic Chemistry

Hyperlearning MCAT Instructor Qualifying Exam Organic Chemistry Hyperlearning MCAT Instructor Qualifying Exam Organic Chemistry 30 Questions (5 pages); Time limit = 45 minutes Use of books or notes is not permitted. 1. When analyzed with a polarimeter, which of the

More information

Core. Topic 10: Organic chemistry. Essential idea: Organic chemistry focuses on the chemistry of compounds containing carbon.

Core. Topic 10: Organic chemistry. Essential idea: Organic chemistry focuses on the chemistry of compounds containing carbon. Core Chemistry guide 67 Essential idea: Organic chemistry focuses on the chemistry of compounds containing carbon. 10.1 Fundamentals of organic chemistry Nature of science: Serendipity and scientific discoveries

More information

Please bubble in your name (LAST NAME first) and student number on the scantron

Please bubble in your name (LAST NAME first) and student number on the scantron CHEM 2130 Final Exam NAME: Please bubble in your name (LAST NAME first) and student number on the scantron 1) To initiate enolate formation, which proton should be removed? 1) 1 2) 2 3) 3 4) 4 5) 5 2)

More information

Alabama Department of Postsecondary Education

Alabama Department of Postsecondary Education Alabama Department of Postsecondary Education Representing Alabama s Public Two-Year College System Jefferson State Community College CHM 221 Organic Chemistry I I. CHM 221 Organic Chemistry I - Prerequisite

More information

ORGANIC CHEMISTRY. Fifth Edition. Stanley H. Pine

ORGANIC CHEMISTRY. Fifth Edition. Stanley H. Pine ORGANIC CHEMISTRY Fifth Edition Stanley H. Pine Professor of Chemistry California State University, Los Angeles McGraw-Hill, Inc. New York St. Louis San Francisco Auckland Bogota Caracas Lisbon London

More information

WJEC Eduqas AS Chemistry - Component 2 THERMOCHEMISTRY

WJEC Eduqas AS Chemistry - Component 2 THERMOCHEMISTRY WJEC Eduqas AS Chemistry - Component 2 THERMOCHEMISTRY enthalpy change of reaction, enthalpy change of combustion and standard molar enthalpy change of formation, Δ fh ϴ Hess s law and energy cycles concept

More information

Experiment 1: Thin Layer Chromatography

Experiment 1: Thin Layer Chromatography Experiment 1: Thin Layer Chromatography Part A: understanding R f values Part B: R f values & solvent polarity Part C: R f values & compound functionality Part D: identification of commercial food dye

More information

Boardworks A2 Chemistry

Boardworks A2 Chemistry Boardworks A2 Chemistry Organic Synthesis 34 slides 13 Flash activities Optical isomerism Introduction to light waves Animation illustrating the nature of polarized light Optically active compounds, enantiomers

More information

CHEM 2240L Final Exam Review Topics

CHEM 2240L Final Exam Review Topics CHEM 2240L Final Exam Review Topics Many students do not adequately prepare for the final exam in 2240L.The average grade is typically in the mid 60 s. Each semester, some students score in the 90 s, and

More information

TUTORIAL LIST 2017/18

TUTORIAL LIST 2017/18 TUTORIAL LIST 2017/18 ATOMIC STRUCTURE & MOLE CALCULATIONS BONDING & INORGANIC CHEMISTRY PHYSICAL CHEMISTRY ORGANIC CHEMISTRY PRACTICAL CHEMISTRY PAST PAPER WALKTHROUGHS ATOMIC STRUCTURE & MOLE CALCULATIONS

More information

TOK: The relationship between a reaction mechanism and the experimental evidence to support it could be discussed. See

TOK: The relationship between a reaction mechanism and the experimental evidence to support it could be discussed. See Option G: Further organic chemistry (15/22 hours) SL students study the core of these options and HL students study the whole option (the core and the extension material). TOK: The relationship between

More information

CHEM ORGANIC CHEMISTRY

CHEM ORGANIC CHEMISTRY BRAZOSPORT COLLEGE LAKE JACKSON, TEXAS SYLLABUS CHEM 2423 - ORGANIC CHEMISTRY CATALOG DESCRIPTION: CHEM 2423 Organic Chemistry I. CIP 4005045203 A study of the nomenclature, classification and reactions

More information

Exercise 6 - Structure - Activity Relationships: Acidity and pk a Values

Exercise 6 - Structure - Activity Relationships: Acidity and pk a Values 107 Exercise 6 Structure Activity Relationships: Acidity and pk a Values For each pair of compounds, write the pertinent reaction and predict which compound of the pair should be the strongest acid. Explain

More information

Benzene and Aromatic Compounds. Chapter 15 Organic Chemistry, 8 th Edition John McMurry

Benzene and Aromatic Compounds. Chapter 15 Organic Chemistry, 8 th Edition John McMurry Benzene and Aromatic Compounds Chapter 15 Organic Chemistry, 8 th Edition John McMurry 1 Background Benzene (C 6 H 6 ) is the simplest aromatic hydrocarbon (or arene). Four degrees of unsaturation. It

More information

Exam 1 (Monday, July 6, 2015)

Exam 1 (Monday, July 6, 2015) Chem 231 Summer 2015 Assigned Homework Problems Last updated: Friday, July 24, 2015 Problems Assigned from Essential Organic Chemistry, 2 nd Edition, Paula Yurkanis Bruice, Prentice Hall, New York, NY,

More information

Chapter 24. Amines. Based on McMurry s Organic Chemistry, 7 th edition

Chapter 24. Amines. Based on McMurry s Organic Chemistry, 7 th edition Chapter 24. Amines Based on McMurry s Organic Chemistry, 7 th edition Amines Organic Nitrogen Compounds Organic derivatives of ammonia, NH 3, Nitrogen atom with a lone pair of electrons, making amines

More information

Detailed Course Content

Detailed Course Content Detailed Course Content Chapter 1: Carbon Compounds and Chemical Bonds The Structural Theory of Organic Chemistry 4 Chemical Bonds: The Octet Rule 6 Lewis Structures 8 Formal Charge 11 Resonance 14 Quantum

More information

Spring Term 2012 Dr. Williams (309 Zurn, ex 2386)

Spring Term 2012 Dr. Williams (309 Zurn, ex 2386) Chemistry 242 Organic Chemistry II Spring Term 2012 Dr. Williams (309 Zurn, ex 2386) Web Page: http://math.mercyhurst.edu/~jwilliams/ jwilliams@mercyhurst.edu (or just visit Department web site and look

More information

EASTERN ARIZONA COLLEGE General Organic Chemistry I

EASTERN ARIZONA COLLEGE General Organic Chemistry I EASTERN ARIZONA COLLEGE General Organic Chemistry I Course Design 2015-2016 Course Information Division Science Course Number CHM 235 (SUN# CHM 2235) Title General Organic Chemistry I Credits 4 Developed

More information

Montgomery County Community College CHE 261 Organic Chemistry I

Montgomery County Community College CHE 261 Organic Chemistry I Montgomery County Community College CHE 261 Organic Chemistry I 4-3-3 COURSE DESCRIPTION: This course covers the nomenclature, structure, properties and reactions of many important classes of organic compounds.

More information

15.1: Hydrocarbon Reactions

15.1: Hydrocarbon Reactions 15.1: Hydrocarbon Reactions Halogenation An alkane will react with a halogen to produce a halalkane and the corresponding hydrogen halide. The catalyst is ultraviolet radiation. Reaction 1 methane chlorine

More information

Chapter 10: Carboxylic Acids and Their Derivatives

Chapter 10: Carboxylic Acids and Their Derivatives Chapter 10: Carboxylic Acids and Their Derivatives The back of the white willow tree (Salix alba) is a source of salicylic acid which is used to make aspirin (acetylsalicylic acid) The functional group

More information

Chapter 23 Phenols CH. 23. Nomenclature. The OH group takes precedence as the parent phenol.

Chapter 23 Phenols CH. 23. Nomenclature. The OH group takes precedence as the parent phenol. CH. 23 Chapter 23 Phenols Nomenclature The OH group takes precedence as the parent phenol. Carboxyl and acyl groups take precedence over the OH group. The OH group is a strong electron-donating group through

More information

Aryl Halides. Structure

Aryl Halides. Structure Aryl Halides Structure Aryl halides are compounds containing halogen attached directly to an aromatic ring. They have the general formula ArX, where Ar is phenyl, substituted phenyl. X= F,Cl,Br,I An aryl

More information

A-LEVEL A-LEVEL CHEMISTRY CHEMISTRY NOTES

A-LEVEL A-LEVEL CHEMISTRY CHEMISTRY NOTES A-LEVEL A-LEVEL CHEMISTRY CHEMISTRY NOTES snaprevise.co.uk I have designed and compiled these beautiful notes to provide a detailed but concise summary of this module. I have spent a lot of time perfecting

More information

Multistep Synthesis of 5-isopropyl-1,3-cyclohexanedione

Multistep Synthesis of 5-isopropyl-1,3-cyclohexanedione Multistep Synthesis of 5-isopropyl-1,3-cyclohexanedione The purpose of this experiment was to synthesize 5-isopropyl-1,3-cyclohexanedione from commercially available compounds. To do this, acetone and

More information

DEPARTMENT: Chemistry

DEPARTMENT: Chemistry CODE CHEM 204 TITLE: Organic Chemistry II INSTITUTE: STEM DEPARTMENT: Chemistry COURSE DESCRIPTION: A continuation of CHEM-203, students will extend their studies into topics including aromatic hydrocarbons,

More information

ORGANIC CHEMISTRY. Wiley STUDY GUIDE AND SOLUTIONS MANUAL TO ACCOMPANY ROBERT G. JOHNSON JON ANTILLA ELEVENTH EDITION. University of South Florida

ORGANIC CHEMISTRY. Wiley STUDY GUIDE AND SOLUTIONS MANUAL TO ACCOMPANY ROBERT G. JOHNSON JON ANTILLA ELEVENTH EDITION. University of South Florida STUDY GUIDE AND SOLUTIONS MANUAL TO ACCOMPANY ORGANIC CHEMISTRY ELEVENTH EDITION T. W. GRAHAM SOLOMONS University of South Florida CRAIG B. FRYHLE Pacific Lutheran University SCOTT A. SNYDER Columbia University

More information

GUJARAT TECHNOLOGICAL UNIVERSITY

GUJARAT TECHNOLOGICAL UNIVERSITY GUJARAT TECHNOLOGICAL UNIVERSITY Pharm.D. 1 st year Subject Name: Pharmaceutical Organic Chemistry Subject Code: 818804 Teaching Scheme (Hours) Evaluation Scheme (Marks) Total marks Theory Tutorial Practical

More information

Course Outline. TERM EFFECTIVE: Fall 2016 CURRICULUM APPROVAL DATE: 03/14/2016

Course Outline. TERM EFFECTIVE: Fall 2016 CURRICULUM APPROVAL DATE: 03/14/2016 5055 Santa Teresa Blvd Gilroy, CA 95023 Course Outline COURSE: CHEM 12A DIVISION: 10 ALSO LISTED AS: TERM EFFECTIVE: Fall 2016 CURRICULUM APPROVAL DATE: 03/14/2016 SHORT TITLE: ORGANIC CHEMISTRY LONG TITLE:

More information

Chemistry of Benzene: Electrophilic Aromatic Substitution

Chemistry of Benzene: Electrophilic Aromatic Substitution Chemistry of Benzene: Electrophilic Aromatic Substitution Why this Chapter? Continuation of coverage of aromatic compounds in preceding chapter focus shift to understanding reactions Examine relationship

More information

to form _ nitrosalicylic acid _. This reaction is a _ electrophilic aromatic substitution reaction. COONO 2 produces 0.

to form _ nitrosalicylic acid _. This reaction is a _ electrophilic aromatic substitution reaction. COONO 2 produces 0. For Prelab Questions: Look at the Lab Experiment on the Chem 12B Lab Information webpage for the lab procedure instead of searching online for an experimental procedure. Lab Activity 10 1. Salicylic acid

More information

COURSE OBJECTIVES / OUTCOMES / COMPETENCIES.

COURSE OBJECTIVES / OUTCOMES / COMPETENCIES. COURSE OBJECTIVES / OUTCOMES / COMPETENCIES. By the end of the course, students should be able to do the following: See Test1-4 Objectives/Competencies as listed in the syllabus and on the main course

More information

Chapter 25: The Chemistry of Life: Organic and Biological Chemistry

Chapter 25: The Chemistry of Life: Organic and Biological Chemistry Chemistry: The Central Science Chapter 25: The Chemistry of Life: Organic and Biological Chemistry The study of carbon compounds constitutes a separate branch of chemistry known as organic chemistry The

More information

Chapter 1 Reactions of Organic Compounds. Reactions Involving Hydrocarbons

Chapter 1 Reactions of Organic Compounds. Reactions Involving Hydrocarbons Chapter 1 Reactions of Organic Compounds Reactions Involving Hydrocarbons Reactions of Alkanes Single bonds (C-C) are strong and very hard to break, therefore these compounds are relatively unreactive

More information

Downloaded from

Downloaded from Bal Bharati Public School, Pitampura CLASS X CHEMISTRY ASSIGNMENT CARBON AND ITS COMPOUNDS Q1. Write the IUPAC names of the following? (a) CH 3 OH. (b) CH 3 COOH. Q2. Which two of the following compounds

More information

Experiment 30: Identification of a Conjugated Diene from Eucalyptus Oil

Experiment 30: Identification of a Conjugated Diene from Eucalyptus Oil Name CHE 173 Sec 20# January 18, 2005 Experiment 30: Identification of a Conjugated Diene from Eucalyptus Oil Purpose: The purpose of this experiment was to determine the structure of the unknown conjugated

More information

JEFFERSON COLLEGE COURSE SYLLABUS CHM201 ORGANIC CHEMISTRY II. 5 Credit Hours. Prepared by: Richard A. Pierce. Revised by: Sean Birke October, 2013

JEFFERSON COLLEGE COURSE SYLLABUS CHM201 ORGANIC CHEMISTRY II. 5 Credit Hours. Prepared by: Richard A. Pierce. Revised by: Sean Birke October, 2013 JEFFERSON COLLEGE COURSE SYLLABUS CHM201 ORGANIC CHEMISTRY II 5 Credit Hours Prepared by: Richard A. Pierce Revised by: Sean Birke October, 2013 Ms. Linda Abernathy, Math, Science & Business Division Chair

More information

September 2011 BOTH THEORY AND LABORATORY PARTS OF THIS COURSE MUST BE TAKEN CONCURRENTLY IN ORDER TO RECEIVE CREDIT.

September 2011 BOTH THEORY AND LABORATORY PARTS OF THIS COURSE MUST BE TAKEN CONCURRENTLY IN ORDER TO RECEIVE CREDIT. FARMINGDALE STATE COLLEGE DEPARTMENT OF CHEMISTRY COURSE OUTLINE: COURSE TITLE: Dr. M. De Castro September 2011 Organic Chemistry I COURSE NUMBER: CHM 270 CREDITS: 5 CONTACT HOURS: Lecture: 3 Laboratory:

More information

Fundamentals of Organic Chemistry

Fundamentals of Organic Chemistry Fundamentals of Organic Chemistry CHEM 109 For Students of Health Colleges Credit hrs.: (2+1) King Saud University College of Science, Chemistry Department CHEM 109 CHAPTER 3. AROMATIC HYDROCARBONS Aromatic

More information

Expt 9: The Aldol Condensation

Expt 9: The Aldol Condensation Expt 9: The Aldol Condensation INTRDUCTIN Reactions that form carbon-carbon bonds are particularly important in organic chemistry as they allow the synthesis of more complex structures from simpler molecules.

More information

UNIT 4 REVISION CHECKLIST CHEM 4 AS Chemistry

UNIT 4 REVISION CHECKLIST CHEM 4 AS Chemistry UNIT 4 REVISION CHECKLIST CHEM 4 AS Chemistry Topic 4.1 Kinetics a) Define the terms: rate of a reaction, rate constant, order of reaction and overall order of reaction b) Deduce the orders of reaction

More information

Medicinal Chemistry. Lab Name Location Person in Charge Programs Served Courses Served. College of Pharmacy

Medicinal Chemistry. Lab Name Location Person in Charge Programs Served Courses Served. College of Pharmacy Medicinal Chemistry Laboratories Medicinal Chemistry Lab Name Location Person in Charge Programs Served Courses Served Medicinal Chemistry M12-128 Chefa a Alhourani Nabeel Baniodeh College of Pharmacy

More information

12/27/2010. Chapter 15 Reactions of Aromatic Compounds

12/27/2010. Chapter 15 Reactions of Aromatic Compounds Chapter 15 Reactions of Aromatic Compounds Electrophilic Aromatic Substitution Arene (Ar-H) is the generic term for an aromatic hydrocarbon The aryl group (Ar) is derived by removal of a hydrogen atom

More information

Chapter 15 Reactions of Aromatic Compounds

Chapter 15 Reactions of Aromatic Compounds Chapter 15 1 Chapter 15 Reactions of Aromatic Compounds Electrophilic Aromatic Substitution Arene (Ar-H) is the generic term for an aromatic hydrocarbon The aryl group (Ar) is derived by removal of a hydrogen

More information

PAPER No. 5: REACTION MECHANISM MODULE No. 2: Types of Organic Reaction Mechanisms

PAPER No. 5: REACTION MECHANISM MODULE No. 2: Types of Organic Reaction Mechanisms Subject Chemistry Paper No and Title Module No and Title Module Tag Paper No. 5:Organic Chemistry-II Module No. 2: Overview of different types of Organic Reaction Mechanisms CHE_P5_M2 TABLE OF CONTENTS

More information

Experimental Organic

Experimental Organic Experimental Organic A Small-Scale Approach Second Edition Charles F. Wilcox, Jr. Cornell University Mary F. Wilcox Ithaca College PRENTICE-HALL, Englewood Cliffs, New Jersey 07632 "»Ij ntents INTRODUCTION

More information

ExA1. Unsaturated Hydrocarbons. Olefins. Experiment: Next Week. Structure Addition Reactions Mechanisms

ExA1. Unsaturated Hydrocarbons. Olefins. Experiment: Next Week. Structure Addition Reactions Mechanisms ExA1 Unsaturated Hydrocarbons Olefins Structure Addition Reactions Mechanisms Experiment: part A - Setup part B - Reaction part C - Isolation part D - Analysis Next Week 1 Alkenes & Alkynes Hydrocarbons

More information

Chemistry 2030 Survey of Organic Chemistry Fall Semester 2015 Dr. Rainer Glaser

Chemistry 2030 Survey of Organic Chemistry Fall Semester 2015 Dr. Rainer Glaser Chemistry 2030 Survey of Organic Chemistry Fall Semester 2015 Dr. Rainer Glaser Examination #2 Reactions of Alkenes & Alkynes, Chemistry of Aromatic Compounds, and Stereochemistry Thursday, October 8,

More information

Course Syllabus. Department: Science & Technology. Date: April I. Course Prefix and Number: CHM 211. Course Name: Organic Chemistry I

Course Syllabus. Department: Science & Technology. Date: April I. Course Prefix and Number: CHM 211. Course Name: Organic Chemistry I Department: Science & Technology Date: April 2012 I. Course Prefix and Number: CHM 211 Course Name: Organic Chemistry I Course Syllabus Credit Hours and Contact Hours: 5 credit hours and 7 (3:3:1) contact

More information

AS Organic Chemistry Revision. Part 1

AS Organic Chemistry Revision. Part 1 AS Organic Chemistry Revision. Part 1 2.2 Nomenclature and isomerism in organic compounds 2.2.1 understand the terms empirical, molecular and structural formulae, homologous series and functional groups;

More information

Experiment 12: Grignard Synthesis of Triphenylmethanol

Experiment 12: Grignard Synthesis of Triphenylmethanol 1 Experiment 12: Grignard Synthesis of Triphenylmethanol Reactions that form carbon-carbon bonds are among the most useful to the synthetic organic chemist. In 1912, Victor Grignard received the Nobel

More information

Department Curriculum and Assessment Outline

Department Curriculum and Assessment Outline Timing Department: Science Year Group: 0 Teaching, learning and assessment during the course: Chemistry (Combined) C/C States of matter/methods of Separating and purifying substances C3 Atomic structure

More information

OH [H + ] KMnO 4 DME OH

OH [H + ] KMnO 4 DME OH 1.a. Reaction 1 is an elimination reaction which includes a rearrangement via a hydride shift. Reaction 2 is an oxidation reaction that leads to a cis-diol. This reaction was used to qualitatively confirm

More information

Organic Chemistry I Lesson Objectives, Lesson Problems, Course Outline Spring 2008

Organic Chemistry I Lesson Objectives, Lesson Problems, Course Outline Spring 2008 Organic Chemistry I Lesson Objectives, Lesson Problems, Course Outline Spring 2008 Lesson Date Assignment Lesson Objective Description Lesson Problems 4 14-Jan Chapter 1 Quiz Describe how bond polarity

More information

Chapter 17 Reactions of Aromatic Compounds. Electrophilic Aromatic Substitution

Chapter 17 Reactions of Aromatic Compounds. Electrophilic Aromatic Substitution Chapter 17 Reactions of Aromatic Compounds Electrophilic Aromatic Substitution Electrophile substitutes for a hydrogen on the benzene ring. Chapter 17: Aromatics 2-Reactions Slide 17-2 1 Mechanism Step

More information

Aliphatic Hydrocarbons Anthracite alkanes arene alkenes aromatic compounds alkyl group asymmetric carbon Alkynes benzene 1a

Aliphatic Hydrocarbons Anthracite alkanes arene alkenes aromatic compounds alkyl group asymmetric carbon Alkynes benzene 1a Aliphatic Hydrocarbons Anthracite alkanes arene alkenes aromatic compounds alkyl group asymmetric carbon Alkynes benzene 1a Hard coal, which is high in carbon content any straight-chain or branched-chain

More information

I. Multiple Choice Questions (Type-I)

I. Multiple Choice Questions (Type-I) Unit 13 HYDROCARBONS I. Multiple Choice Questions (Type-I) 1. Arrange the following in decreasing order of their boiling points. (A) n butane (B) 2 methylbutane (C) n-pentane (D) 2,2 dimethylpropane A

More information

1. CONCEPTS IN ORGANIC CHEMISTRY 2. SYNTHETIC ORGANIC CHEMISTRY 3. ISOMERISM II 4. HYDROCARBONS II 5. HALOALKANES. Vikasana - CET 2012

1. CONCEPTS IN ORGANIC CHEMISTRY 2. SYNTHETIC ORGANIC CHEMISTRY 3. ISOMERISM II 4. HYDROCARBONS II 5. HALOALKANES. Vikasana - CET 2012 CET OBJECTIVE QUESTION ON 1. CONCEPTS IN ORGANIC CHEMISTRY 2. SYNTHETIC ORGANIC CHEMISTRY 3. ISOMERISM II 4. HYDROCARBONS II 5. HALOALKANES 1.The inductive effect a. Implies the atoms ability to cause

More information

Objectives. Organic molecules. Carbon. Hydrocarbon Properties. Organic Chemistry Introduction. Organic versus Hydrocarbon 1/1/17

Objectives. Organic molecules. Carbon. Hydrocarbon Properties. Organic Chemistry Introduction. Organic versus Hydrocarbon 1/1/17 Objectives Organic Chemistry Introduction 8.1 To determine the properties of organic molecules and recognize a hydrocarbon. Use table P and Q to write structural and molecular formulas for hydrocarbons.

More information

Chem 263 Oct. 12, 2010

Chem 263 Oct. 12, 2010 Chem 263 ct. 12, 2010 Alkyl Side Chain xidation Reaction If the carbon directly attached to the aromatic ring has > 1 hydrogen attached to it, it can be oxidized to the corresponding carboxylic acid with

More information

Page 1 of 9. Sessional Examination (November 2017) Max Marks: 20 Date: Time: One Hour. Model Answers

Page 1 of 9. Sessional Examination (November 2017) Max Marks: 20 Date: Time: One Hour. Model Answers Page 1 of 9 Sessional Examination (November 2017) Class: B. Pharm-II yr (III sem) Subject: Pharma Org. Chem-II Max Marks: 20 Date: 14.11.2017 Time: One Hour Model Answers Q. 1. Solve the following (ANY

More information

COWLEY COLLEGE & Area Vocational Technical School

COWLEY COLLEGE & Area Vocational Technical School COWLEY COLLEGE & Area Vocational Technical School COURSE PROCEDURE FOR Student Level: This course is open to students on the college level in the sophomore year. Catalog Description: CHM4250 - ORGANIC

More information

ADVANCED CHEMISTRY 2

ADVANCED CHEMISTRY 2 ADVANCED CHEMISTRY 2 Philip Matthews ±m±l CAMBRIDGE UNIVERSITY PRESS Acknowledgements How to use this book INORGANIC CHEMISTRY 88 Periodicity of physical properties 88.1 Periodicity of ionisation energies

More information

Alabama. Department of. Postsecondary Education

Alabama. Department of. Postsecondary Education Date Adopted: July 1, 1998 Date Reviewed: December 1, 1999 Date Revised: 1999, 2007, 2011, 2013 Alabama Department of Postsecondary Education Representing Alabama s Public Two-Year College System Jefferson

More information

Class XII - Chemistry Aldehydes, Ketones and Carboxylic Acid Chapter-wise Problems

Class XII - Chemistry Aldehydes, Ketones and Carboxylic Acid Chapter-wise Problems Class XII - Chemistry Aldehydes, Ketones and Carboxylic Acid Chapter-wise Problems I. Multiple Choice Questions (Type-I) 1. Addition of water to alkynes occurs in acidic medium and in the presence of Hg

More information

SURVEY ON ARYL COMPOUNDS

SURVEY ON ARYL COMPOUNDS Journal of Plastic and Polymer Technology (JPPT) Vol. 1, Issue 1, Jun 2015, 111-132 TJPRC Pvt. Ltd SURVEY ON ARYL COMPOUNDS NAGHAM MAHMOOD ALJAMALI Organic Chemistry, Department of Chemistry, College of

More information

Organic Chemistry 112 A B C - Syllabus Addendum for Prospective Teachers

Organic Chemistry 112 A B C - Syllabus Addendum for Prospective Teachers Chapter Organic Chemistry 112 A B C - Syllabus Addendum for Prospective Teachers Ch 1-Structure and bonding Ch 2-Polar covalent bonds: Acids and bases McMurry, J. (2004) Organic Chemistry 6 th Edition

More information

Synthesis of Tetraphenylcyclopentadienone. Becky Ortiz

Synthesis of Tetraphenylcyclopentadienone. Becky Ortiz Synthesis of Tetraphenylcyclopentadienone Becky Ortiz Introduction An aldol reaction is a reaction in which aldehydes or ketones undergo a base- catalyzed carbonyl condensation reaction to form a beta-

More information

CARBOXYLIC ACIDS and their Derivatives Nucleophilic Acyl substitution - Review the nomenclature for these compounds in your textbook

CARBOXYLIC ACIDS and their Derivatives Nucleophilic Acyl substitution - Review the nomenclature for these compounds in your textbook CARBXYLIC ACIDS and their Derivatives Nucleophilic Acyl substitution - Review the nomenclature for these compounds in your textbook R Z R Z R Z - the basicity of Z determines the relative stability of

More information

Aromatic Compounds II

Aromatic Compounds II 2302272 Org Chem II Part I Lecture 2 Aromatic Compounds II Instructor: Dr. Tanatorn Khotavivattana E-mail: tanatorn.k@chula.ac.th Recommended Textbook: Chapter 17 in Organic Chemistry, 8 th Edition, L.

More information

DEPARTMENT: Chemistry

DEPARTMENT: Chemistry CODE: CHEM 203 TITLE: Organic Chemistry I INSTITUTE: STEM DEPARTMENT: Chemistry COURSE DESCRIPTION: Students will apply many concepts from general chemistry to a study of organic chemistry. They will be

More information

UNIT 3 CHEMISTRY. Fundamental Principles in Chemistry

UNIT 3 CHEMISTRY. Fundamental Principles in Chemistry UNIT 3 CHEMISTRY NOTE: This list has been compiled based on the topics covered in the 2016 Master Class program. Once all of the 2017 Chemistry program materials have been finalised, this summary will

More information

Chapter 22. Organic and Biological Molecules

Chapter 22. Organic and Biological Molecules Chapter 22 Organic and Biological Molecules The Bonding of Carbon Organic chemistry is the chemistry of compounds containing carbon. Because carbon can form single, double, and triple bonds, the following

More information

Subject Overview Curriculum pathway

Subject Overview Curriculum pathway Subject Overview Curriculum pathway Course Summary Course: A Level Chemistry Overall Summary Unit / Module Exam / Controlled % of course UMS allocation Marks available UMS / RAW mark grade boundaries from

More information

Required Materials For complete material(s) information, refer to

Required Materials For complete material(s) information, refer to Butler Community College Science, Technology, Engineering, and Math Division Robert Carlson Revised Fall 2017 Implemented Spring 2018 COURSE OUTLINE Organic Chemistry 1 Course Description CH 240. Organic

More information

Chapter 13 Alkenes and Alkynes Based on Material Prepared by Andrea D. Leonard University of Louisiana at Lafayette

Chapter 13 Alkenes and Alkynes Based on Material Prepared by Andrea D. Leonard University of Louisiana at Lafayette Chapter 13 Alkenes and Alkynes Based on Material Prepared by Andrea D. Leonard University of Louisiana at Lafayette 1 Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.

More information

Chemistry 2030 Survey of Organic Chemistry Fall Semester 2015 Dr. Rainer Glaser

Chemistry 2030 Survey of Organic Chemistry Fall Semester 2015 Dr. Rainer Glaser Chemistry 2030 Survey of Organic Chemistry Fall Semester 2015 Dr. Rainer Glaser Examination #2 Reactions of Alkenes & Alkynes, Chemistry of Aromatic Compounds, and Stereochemistry Thursday, October 8,

More information