Dave and the Dead Russians. Early Contributions by Russian Organic Chemists to the Development of the Discipline

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1 Dave and the Dead ussians Early Contributions by ussian Organic Chemists to the Development of the Discipline

2 Nikolai Nikolaevich Zinin ( ) kandidat Kazan' 1836 Dr. Chem. St. Petersburg 1841 Study abroad in western Europe included a year with Liebig in Giessen meant to be learning technology, not "new" chemistry Kazan' University Professor of Chemical Technology Medical-Surgical Academy, University of St. Petersburg Professor of Chemistry

3 N. N. Zinin ( ) CHO KCN O Ann. Chem. Pharm. 1840, 34, NO 2 NH3 /H 2 S NH 2 Bull. Sci. Acad. St. Petersburg 1842, 18. Bull. Phys.-Math. Acad. St. Petersburg 1852, 348. Ann. Chem. Pharm. 1842, 44, ; 1844, 52, ; 1853, 85,

4 Aleksandr Mikhailovich Butlerov ( ) kandidat Kazan' 1849 (entomology) M. Chem. Kazan' 1851 Dr. Chem. Moscow 1854 Study abroad in western Europe ; met Erlenmeyer and Kekulé spent six months with Wurtz in Paris not supposed to be a research trip Kazan' University Professor of Chemical Technology ector twice. University of St. Petersburg Professor of Chemistry

5 A. M. Butlerov (Butlerow) ( ) Structural Theory Ann. Chem. Pharm. 1859, 111, Textbook Introduction to the Study of Organic Chemistry (Kazan', 1861).Lehrbuch der organischen Chemie zur Einführung in das specielle Studien derselben (Leipzig, 1867) H 3 C C O (CH 3 ) 2 Zn/ H 3 C H 3 C C Cl H 3 C Jahresb. 1863, 475; 1864, 496. Ann. Chem. Pharm. 1867, 144, 132.

6 Aleksandr Mikhailovich Zaitsev ( ) diplom Kazan' 1862 (economics) kandidat Kazan' 1865 Ph.D. Leipzig 1866 M. Chem. Kazan' 1868 Dr. Chem. Kazan' 1870 Study abroad in western Europe studied with Kolbe at Marburg studied with Wurtz in Paris Kazan' University unpaid laboratory assistant 1865 Assistant in Agronomy Extraordinary Professor of Chemistry Professor of Chemistry served two terms as President of the ussian Physical- Chemical Society

7 A. M. Zaitsev (Saytzeff) ( ) Zaitsev's ule: Ann. Chem. Pharm. 1875, 179, S HNO 3 /H 2 O S O Ann. Chem. Pharm. 1866, 139, ; 1867, 144, Cl C O Na/Hg/Et 2 O HOAc Z. Chem., N.F. 1869, 5, ; 1870, 6, J. prakt. Chem., N.F. 1871, 3, 76-88, 427. Cl C O 2 Zn ' ' Cl C O 'I/Zn/Et 2 O ' ' Ann. Chem. Pharm. 1875, 175, , ; 1877, 185, , , J. prakt. Chem. 1885, 31,

8 Vladimir Vasil evich Markovnikov ( ) kandidat Kazan' 1860 (economic science) M. Chem. Kazan' 1865 Dr. Chem. Kazan' 1869 Study abroad in Germany studied with Kolbe at Leipzig studied with Erlenmeyer at Heidelberg Kazan' University Docent in Chemistry 1867 Extraordinary Professor of Chemistry 1868 Professor of Chemistry Odessa University Professor of Chemistry Moscow University Professor of Chemistry

9 V. V. Markovnikov (Markownikoff) ( ) Markovnikov's ule Ann. Chem. Pharm. 1870, 133, Compt. rend. 1875, 82, , , Synthesis of HO 2 C CO 2 H Ann. Chem. Pharm. 1881, 208, Synthesis of Compt. rend. 1892, 110, ; 115,

10 Sergei Nikolaevich eformatskii ( ) graduated Kostroma Spiritual Seminary 1878 kandidat Kazan' 1882 M. Chem. Kazan' 1889 Dr. Chem. Warsaw 1890 Study abroad in western Europe studied with Viktor Meyer at Heidelberg and Göttingen studied with Wilhelm Ostwald at Leipzig Kazan' University curator of museum Kiev University (St. Vladimir) Professor of Chemistry Corresponding member, USS Academy of Science 1928

11 S. N. eformatskii ( ) Br CO 2 Et Zn/Me 2 CO CO 2 Et Br CO 2 Et Zn/Me 2 CHCHO CO 2 Et Ber. Deut. chem. Ges. 1887, 20, ; 1895, 28, , , Textbook: A Beginner's Course of Organic Chemistry (Kiev, 1891)

12 Egor Egorevich Vagner ( ) kandidat Kazan' 1874 (juridicial science) M. Chem. St. Petersburg 1885 Dr. Chem. Warsaw 1888 St. Petersburg University Assistant in Chemistry (under Menshutkin) Novo-Aleksandriya Institute of Agriculture and Forestry Professor of Chemistry University of Warsaw Professor of Chemistry

13 E. E. Vagner (Wagner) ( ) CHO Et 2 Zn Ann. Chem. Pharm. 1875, 175, ; 1875, 179, , KMnO 4 H 2 O HO Ber. Deut. chem. Ges. 1888, 21, , , , H + Ber. Deut. chem. Ges. 1899, 32, ; 1900, 33,

14 Aleksandr Erminingel dovich Arbuzov ( ) diplom Kazan' 1900 M. Chem. Kazan' 1905 Dr. Chem. Kazan' 1914 Novo-Aleksandriya Institute of Agriculture and Forestry Assistant in Chemistry Professor of Chemistry Kazan' University Professor of Chemistry Deputy Dean, Physics-Mathematics Faculty Kazan' Technical Institute, USS Academy of Sciences Professor and Director 1930

15 A.E. Arbuzov ( ) PhO PhO P: PhO MeI PhO O P PhO Me + Ph + HI J. uss. Phys. Chem. Soc. 1910, 42, , Chem. Zentr. 1910, 11,

16 Nikolai Yakovlevich Demyanov ( ) kandidat Moscow 1886 M. Chem. Moscow 1895 Dr. Chem. Moscow 1899 Petrine Forestry and Agricultural Academy, Moscow Assistant Adjunct Professor Professor Institute of Organic Chemistry, USS Academy of Science Director

17 N. Ya. Demyanov (N. J. Demjanov) ( ) NH 2 HONO + NH 2 HONO + J. uss. Phys. Chem. Soc. 1903, 35, 26; , 186. Chem. Zentr. 1903, I, 828; 1904, I, Ber. Deut. chem. Ges. 1907, 40, 4393, 4961; 1908, 41, 43. Textbook Organic Chemistry (3rd edition printed 1944)

18 Nikolai Matveyevich Kizhner ( ) kandidat Moscow 1890 M. Chem. St. Petersburg 1895 Dr. Chem. Moscow 1900 Tomsk Technoological Institute Professor of Chemistry Shanyavskii Popular University, Moscow Professor of Chemistry Aniline Trust esearch Institute Director Corresponding Member, USS Academy of Sciences

19 N. M. Kizhner (Kishner) ( ) O NH 2 NH 2 NNH 2 K/ H H J. uss. Phys. Chem. Soc. 1911, 43, 582. (c.f. Chem. Abstr. 1912, 6, 347).

20 Aleksei Evgenievich Chichibabin ( ) kandidat Moscow 1892 M. Chem. Moscow 1904 Dr. Chem. St. Petersburg 1912 Moscow University Docent 1901, University of Warsaw Adjunct Professor Moscow Higher Technical School Professor Dean, Chemistry Faculty (intermittent) Left ussia 1930 worked with Tiffeneau at Hôtel Dieu worked at Collège de France Director, Scientific Department, Kuhlman Co technical advisor, Schering & oosevelt Co

21 A. E. Chichibabin ( ) N NaNH 2 N NH 2 J. uss. Phys. Chem. Soc. 1914, 46, CHO NH 3 J. uss. Phys. Chem. Soc. 1906, 37, J. prakt. Chem. 1924, 107, 122. N OEt OEt MgX H EtO 3 O OEt OEt Ber. Deut. chem. Ges. 1904, 37, 186; 850. CHO

22 Nikolai Dmitrievich Zelinskii ( ) kandidat Odessa 1884 M. Chem. Odessa 1889 Dr. Chem. Odessa 1891 Studied abroad studied with Wislicenus at Leipzig and V. Meyer at Göttingen Moscow University Professor of Chemistry St. Petersburg Polytechnical Institute Professor of Chemistry USS Academy of Sciences Corresponding Member 1926 Academician 1929 Head, N.D. Zelinskii Institute 1934

23 N. D. Zelinskii (Zelinsky) ( ) CHO +NH 4 Cl + KCN CN NH 2 J. uss. Phys. Chem. Soc. 1906, 38, 722; 1908, 40, 790. CO 2 H 1) Br 2 /P 2) H 2 O Br CO 2 H Ber. Deut. chem. Ges. 1887, 20, 2026.

24 Lev Aleksandrovich Chugaev ( ) M. Chem. Moscow 1903 Dr. Chem. Moscow 1906 Moscow University Adjunct in Bacteriological Institute St. Petersburg University Professor of Inorganic Chemistry

25 L A. Chugaev (Tschugaeff) ( ) 1) Na/CS 2 2) MeI 3) Ber. Deut. chem. Ges. 1899, 32, Development of α-dioximes as reagents for Group VIIIB metals (e.g. dimethylglyoxime for nickel) Z. anorg. allgem. Chem. 1905, 46, 144.

26 Nikolai Aleksandrovich Menshutkin ( ) kandidat St. Petersburg 1862 M. Chem. St. Petersburg 1866 Dr. Chem. St. Petersburg 1869 Study abroad in western Europe studied with Strecker in Tübingen, Wurtz in Paris, Kolbe in Leipzig St. Petersburg University Professor of Chemical Technology Medical-Surgical Academy, University of St. Petersburg Professor of Chemistry

27 N. A. Menshutkin (Menschutkin) ( ) eaction rate studies in alcohols and amines: N + X 2 N 4 X 3 3 Z. Phys. Chem. 1890, 5, 589; 1891, 6, 41.

28 Aleksandr Porfir evich Borodin ( ) kandidat St. Petersburg Medical-Surgical Academy 1855 M.D. St. Petersburg Medical-Surgical Academy 1858 Study in western Europe frequently travelled with Mendeleev delegate to Karlsruhe conference 1860 St. Petersburg Medical-Surgical Academy Extraordinary Professor of Organic Chemistry Professor of Organic Chemistry

29 A. P. Borodin (Borodine) ( ) CO2 Ag Br 2 Br Z. Chem. 1861, 4, 5; 1869, 12, 342. Ann. Chem. Pharm. 1861, 119, 121. CHO Na Ber. Deut. chem. Ges. 1873, 6, 982. CHO COCl KHF 2 COF Compt. rend. 1862, 55, 553. Z. Chem. 1862, 5, 576. Nuov. Cim. 1862, 15, 305. Ann. Chem. Pharm. 1863, 126, 58.

30 Aleksei Evgrafovich Favorskii ( ) kandidat St. Petersburg 1883 M. Chem. St. Petersburg 1891 Dr. Chem. St. Petersburg 1895 St. Petersburg Technical Institute Professor of Chemistry USS Academy of Sciences Associate Member 1921 Academician 1929

31 A. E. Favorskii (Favorsky) ( ) CH 2 C C H C C H H C H J. uss. Phys. Chem. Soc. 1887, 19, 414. Ber. Deut. chem. Ges. 1887, 20, 781. C C CH 3 C C H + O C C J. uss Phys. Chem. Soc. 1900, 32, 652; 1905, 37, 643. Chem. Zentr. 1905, II, O Br Na J. prakt. Chem. 1913, 88, 658. CO 2 H

32 Vyacheslav Evgenievich Tishchenko ( ) Ar CHO Al(OEt) 3 Ar O J. uss. Phys. Chem. Soc. 1906, 38, 355, 482, 540, 547. Chem. Zentr. 1906, II, 1309, 1552, 1555, c.f. Claisen, L., Ber. Deut. chem. Ges. 1887, 20, 646. O Ar

33 Ivan Nikolaevich Nazarov ( ) acid O O Izv. Akad. Nauk SSS, Otd. Khim. Nauk 1942, 200. Sergei Semenovich Nametkin ( ) H Liebigs Ann. Chem. 1923, 432, 207.

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