1. Following are structural formulas for two steroid hormones.
|
|
|
- Cecilia Morrison
- 6 years ago
- Views:
Transcription
1 CHEM 122: Introduction to rganic Chemistry Chapter 9: Aldehydes and Ketones. 1. Following are structural formulas for two steroid hormones. Cortisone Aldosterone Name the functional groups in each. b) Mark all stereocenters in each hormone and state how many stereoisomers are possible for each. 2. Draw structural formulas for the four aldehydes with the molecular formula C5H10. Which of these aldehydes are chiral? 3. Draw structural formulas for these aldehydes. Formaldehyde b) Propanal 3,7-Dimethyloctanal d) Decanal e) 4-hydroxybenzaldehyde f) 2,3-Dihydroxypropanal 4. Draw structural formulas for these ketones. Ethyl isopropyl ketone b) 2-Chlorocyclohexanone 2,4-Dimethyl-3-pentanone d) Diisopropyl ketone e) Acetone f) 2,5-Dimethylcyclohexanone
2 5. Write the IUPAC names for these compounds. CH CHH CHH CH H b) CH 2 H d) NH 2 6. Explain why each name is incorrect. Write the correct IUPAC name for the intended compound. 2-Pentanal b) Cyclopentanal 3-Ethyl-2-butanone d) 5-Aminobenzaldehyde 7. Acetone is completely soluble in water, but 4-heptanone is completely insoluble in water. Explain. 8. Account for the fact that acetone has a higher boiling point (56 o C) than ethyl methyl ether (11 o C) even though their molecular weights are almost the same. 9. Propanal (bp 49 o C) and 1-propanol (bp 97 o ) have about the same molecular weight, yet their boiling points differ by almost 50 o C. Explain this fact. 10. Draw a structural formula for the principal organic product formed when each compound is treated with Tollens reagent. If there is no reaction, say so. Butanal b) Benzaldehyde Cyclohexanone d) Cyclohexanol 11. Suppose that you take a bottle of benzaldehyde (a liquid, bp 179 o C) from a shelf and find a white solid in the bottom of the bottle. The solid turns litmus red; that is, it is acidic. Yet aldehydes are neutral compounds. How can you explain these observations?
3 12. Write a structural formula for the principal organic product formed by treating each compound with NaBH4 followed by H2. CH3CCH2CH3 b) CH3(CH2)4CH CH d) H 13. Draw a structural formula for the product formed by treatment of butanal with each set of reagents. H2/metal catalyst b) NaBH4, then H2 Ag(NH3)2 + (Tollens reagent) d) K2Cr27/H2S4 14. Draw a structural formula for the product formed by treatment of acetophenone, C6H5CCH3, with each set of reagents. H2/metal catalyst b) NaBH4, then H2 Ag(NH3)2 + (Tollens reagent) d) K2Cr27/H2S4 15. Draw all enol forms of each aldehyde and ketone. CH3CH2CH b) CH3CCH2CH3
4 16. Which compounds are hemiacetals, which acetals, and which are neither? CH b) CH3CH2CHCH3 CH3CH2CH3 d) CH 2 e) CH 2 f) H 17. Draw the hemiacetal and then acetal formed in each reaction. In each case, assume an excess of the alcohol. Propanal + methanol b) Cyclopentanone + methanol 18. Draw the structures of the aldehydes or ketones and alcohols formed when these acetals are treated with aqueous acid and hydrolyzed. b) d) 19. List the reagents and experimental conditions to convert cyclohexanone to each of the following compounds. 20. Draw a structural formula for an aldehyde or a ketone that can be reduced to produce each alcohol. If none exists, say so. H b) CH 2 H H 3 C CH H H d)
5 21. Show how to bring about these conversions. In addition to the given starting material, use any other organic or inorganic reagents as necessary. 22. Describe a simple chemical test by which you could distinguish between the members of each pair of compounds. Cyclohexanone and aniline b) Cyclohexene and cyclohexanol Benzaldehyde and cinnamaldehyde Hydroxyhexanal forms a six-membered cyclic hemiacetal, which predominates at equilibrium in aqueous solution. Draw a structural formula for this cyclic hemiacetal. b) How many stereoisomers are possible for 5-hydroxyhexanal? How many stereoisomers are possible for this cyclic hemiacetal? 24. The following molecule is an enediol; each carbon of the double bond carries an H group. Draw structural formulas for the -hydroxyketone and the -hydroxyaldehyde with which this enediol is in equilibrium. HC H -hydroxyaldehyde C H -hydroxyketone An enediol
6 25. Alcohols can be prepared by the acid-catalyzed hydration of alkenes and by the reduction of aldehydes and ketones. Show how you might prepare each of the following alcohols by 1) acid-catalyzed hydration of an alkene and 2) reduction of an aldehyde or a ketone. Ethanol b) Cyclohexanol 2-Propanol d) 1-Phenylethanol 26. Glucose, C6H126, contains an aldehyde group but exists predominantly in the form of the cyclic hemiacetal shown here. We will discuss this cyclic form of glucose in Chapter 12. CH 2 H H H H H H H H H H -D-Glucose A cyclic hemiacetal is formed when the H group of one carbon bonds to the carbonyl group of another carbon. Which carbon in glucose provides the H group and which provides the CH group?
14.1 Aldehydes and Ketones Copyright 2007 by Pearson Education, Inc. Publishing as Benjamin Cummings
Chapter 14 Aldehydes, Ketones, and Chiral Molecules 14.1 Aldehydes and Ketones Copyright 2007 by Pearson Education, Inc. Publishing as Benjamin Cummings Carbonyl Group in Aldehydes A carbonyl group and
Chemical Reactions - Oxidation. Reactions Involving Aldehydes and Ketones. Learning Check. Learning Check. Chemical Reactions - Addition of Hydrogen
Reactions Involving Aldehydes and Ketones Chemical Reactions - Oxidation When aldehydes are prepared by oxidizing primary alcohols with KMnO 4 or K 2 Cr 2 O 7, the reaction may continue and produce carboxylic
Carbonyl Group in Aldehydes and Ketones
Lecture 4: Aldehydes, Ketones, and Chiral Molecules 14.1 Aldehydes and Ketones Carbonyl Group in Aldehydes and Ketones A carbonyl group (C=) In an aldehyde is attached to at least one atom. In a ketone
1) Which type of compound does not contain a carbonyl group? A) ketone B) aldehyde C) amine D) ester E) carboxylic acid
1) Which type of compound does not contain a carbonyl group? ketone aldehyde amine ester carboxylic acid 2) Which functional group contains a carbonyl group and a hydroxyl group bonded to the same carbon
MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question.
Ch16_PT MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question. 1) Which type of compound does not contain a carbonyl group? ketone B) aldehyde C) amine D)
CHEM 203 Exam 2. Name Multiple Choice Identify the letter of the choice that best completes the statement or answers the question.
CHEM 203 Exam 2 Name Multiple Choice Identify the letter of the choice that best completes the statement or answers the question. 1. What is the IUPAC name of 5-ethyl-2,3-dimethyl-6-hexanol 2-ethyl-4-isopropyl-1-pentanol
UNIT (8) OXYGEN CONTAINING ORGANIC COMPOUNDS
UNIT (8) OXYGEN CONTAINING ORGANIC COMPOUNDS 8.1 Alcohols, Phenols, and Ethers An alcohol is an organic compound that contains the hydroxyl group (-OH) attached to an alkyl group. They are essentially
Chapter 16 Aldehydes and Ketones Based on Material Prepared by Andrea D. Leonard University of Louisiana at Lafayette
Chapter 16 Aldehydes and Ketones Based on Material Prepared by Andrea D. Leonard University of Louisiana at Lafayette Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
CH 320/328 N Summer II 2018
CH 320/328 N Summer II 2018 HW 1 Multiple Choice Identify the choice that best completes the statement or answers the question. There is only one correct response for each question. (5 pts each) 1. Which
Nomenclature of Aldehydes and Ketones
Aldehydes and Ketones Nomenclature of Aldehydes and Ketones Common aldehydes H H Methanl (formaldehyde) H3C H CH3CH2 ethanl (acetaldehyde) H propanal (propionaldehyde) CH3CH2CH2 butanal (n-butyraldehyde)
BRCC CHM102 Chapter 17 Notes Class Notes Page 1 of 8
BR HM102 hapter 17 Notes lass Notes Page 1 of 8 hapter 17 Aldehydes and Ketones arbonyl group - found in fats, carbohydrates, proteins, nucleic s, and other important biological compounds. * Aldehydes
1. What is the major organic product obtained from the following sequence of reactions?
CH320 N N_HW1 Multiple Choice Identify the choice that best completes the statement or answers the question. There is only one correct response for each question. Carefully record your answers on the Scantron
Q.8. Isomers are the compounds that must have same
Choose the single correct answer for each of the following questions: (1 Mark each). Q. 1. ow many lone pairs are present in C 3 --C 3 i) 3 ii) 2 iii) 1 iv) 4 Q.2. When any hydrocarbon is added to water,
Chapter 23 Aldehydes and Ketones
Chapter 23 Aldehydes and Ketones Ketones are common solvents for quickdrying paints. Introduction to General, Organic, and Biochemistry, 10e John Wiley & Sons, Inc Morris Hein, Scott Pattison, and Susan
SAN JOSE CITY COLLEGE INTRODUCTION TO CHEMISTRY 32B Spring March 9, 2009 Chapters 13, 14 and 17 Bettelheim, Brown, March
SAN JOSE CITY COLLEGE INTRODUCTION TO CHEMISTRY 32B Spring 2009 Name: ID#: Instructor: Dr. T. Johnson Time Allowed:1h 20 min March 9, 2009 Chapters 13, 14 and 17 Bettelheim, Brown, March 108 Points LEARNING
Chemistry 2050 Introduction to Organic Chemistry Fall Semester 2011 Dr. Rainer Glaser
Chemistry 2050 Introduction to Organic Chemistry Fall Semester 2011 Dr. Rainer Glaser Examination #4 Practice Edition Carbonyl Compounds and Amines. Wednesday, November 16, 2011, 10 10:50 am Name: Question
Aromatic Hydrocarbons
Aromatic Hydrocarbons Aromatic hydrocarbons contain six-membered rings of carbon atoms with alternating single and double carbon-carbon bonds. The ring is sometimes shown with a circle in the center instead
Chemistry 121(V84) Winter 2016
Chemistry 121(V84) Winter 2016 Introduction to Organic Chemistry and Biochemistry Instructor Dr. Upali Siriwardane (Ph.D. Ohio State) E-mail: upali@latech.edu Office: 311 Carson Taylor Hall ; Phone: 318-257-4941;
N_HW1 N_HW1. 1. What is the purpose of the H 2 O in this sequence?
N_HW1 N_HW1 Multiple Choice Identify the choice that best completes the statement or answers the question. There is only one correct response for each question. 1. What is the purpose of the H 2 O in this
Chem 2320 Final 210 points Dr. Luther Giddings
Chem 2320 Final 210 points Dr. Luther Giddings Name Phone or E-Mail Instructions: This is a closed book, closed notebook test. You may not discuss this exam with anyone, either during or after the exam,
3) Oxidation of tertiary alcohol yields A) Aldehyde B) No reaction C) Ketone D) Carboxylic acid
ALKYL HALIDES 18- The reaction of Propyl bromide with Na is A) Nucleophilic addition. B) Nucleophilic substitution. C) Electrophilic substitution. D) Electrophilic addition. 25) Which of the following
CHE 325 ALDEHYDES AND KETONES I CHAP 18 ASSIGN OCH 3 HCN C 4 H 7 NO. would be: CH 3 B. CH 3CH 2COOCH 3
CE 325 ALDEYDES AND KETNES I CAP 18 ASSIGN 1. What is the correct IUPAC name for the following compound A. 2-Methyl-5-heptanone B. 7-Methyl-4-octanone C. 6-Isopropyl-4-octanone D. Isobutyl propyl ketone
Chapter 9 Aldehydes and Ketones
Chapter 9 Aldehydes and Ketones 9.1 Nomenclature of Aldehydes and Ketones Aldehydes are named by replacing the -e of the corresponding parent alkane with -al The aldehyde functional group is always carbon
Aldehyde and Ketones with *Featured reactions
* Aldehyde and Ketones with *Featured reactions *1.What is the general structure for an aldehyde? A ketone? *2.How are the common names of aldehydes and ketones determined? How are aldehydes and ketones
Carbonyl Group. Chemistry 121(01) Winter Chapter 15: Aldehyde and Ketones. Chapter 15: Aldehyde and Ketones
Chemistry 121(01) Winter 2012 Introduction to rganic Chemistry and Biochemistry Instructor Dr. Upali Siriwardane (Ph.D. hio State) E-mail: upali@chem.latech.edu ffice: 311 Carson Taylor Hall ; Phone: 318-257-4941;
ALDEHYDES, KETONES AND CARBOXYLIC ACIDS
Unit - 12 ALDEHYDES, KETONES AND CARBOXYLIC ACIDS 1. Indicate the electrophilic and nucleophilic centres in acetaldehyde. 2. Write the IUPAC names of the following organic compounds : 122 XII Chemistry
Name: Date: I. Multiple Choice (Circle the letter for the best answer)
Organic Chemistry II Sample Exam 3 You should also be able to name compounds, draw structures from names, and complete reactions given the reactants and conditions of the reaction. Name: Date: I. Multiple
Part A - Multiple Choice Identify the letter of the choice that best completes the statement or answers the question.
SCH4U Unit Test Name: Date: Part A - Multiple Choice Identify the letter of the choice that best completes the statement or answers the question. 1. An amine is characterized by what functional group?
Aldehydes and Ketones
9 Aldehydes and Ketones hapter Summary The carbonyl group, =, is present in both aldehydes (=) and ketones ( 2 =). The IUPA ending for naming aldehydes is -al, and numbering begins with the carbonyl carbon.
An alcohol is a compound obtained by substituting a hydoxyl group ( OH) for an H atom on a carbon atom of a hydrocarbon group.
Derivatives of Hydrocarbons A functional group is a reactive portion of a molecule that undergoes predictable reactions. All other organic compounds can be considered as derivatives of hydrocarbons (i.e.,
Ch. 10 in- Class Exercise
Chemistry 123/125 Ch. 10 in- Class Exercise In a liquid, the molecules are very close to one another and are constantly moving and colliding. Molecules attract each other, and the force of attraction is
Chemistry 110. Bettelheim, Brown, Campbell & Farrell. Ninth Edition
hemistry 110 Bettelheim, Brown, ampbell & Farrell Ninth Edition Introduction to General, rganic and Biochemistry hapter 17 Aldehydes & Ketones hemistry of the arbonyl Group Aldehydes & Ketones The functional
ALDEHYDES AND KETONES
CE 325 ALDEYDES AND KETNES CAP 17 ASSGN NUCLEPLC ADDTN T TE CARBNYL GRUP 1. What is the correct UPAC name for the following compound A. 2-Methyl-5-heptanone B. 7-Methyl-4-octanone C. 6-sopropyl-4-octanone
I N V E S T I C E D O R O Z V O J E V Z D Ě L Á V Á N Í CARBONYL COMPOUNDS
= substances containing the carbonyl group Aldehydes have the C=O group at the end of the chain, the aldehydic group is then... Naming of aldehydes: In the systematic name there is a suffix after the stem
Class XII - Chemistry Aldehydes, Ketones and Carboxylic Acid Chapter-wise Problems
Class XII - Chemistry Aldehydes, Ketones and Carboxylic Acid Chapter-wise Problems I. Multiple Choice Questions (Type-I) 1. Addition of water to alkynes occurs in acidic medium and in the presence of Hg
Unit 2 Review: Organic Chemistry. 1. Terms for which you should be able to write or apply the definitions:
Unit 2 Review: Organic Chemistry 1. Terms for which you should be able to write or apply the definitions: organic compound aliphatic hydrocarbons saturated miscible functional group aromatic hydrocarbons
Chapter 9 Aldehydes and Ketones Excluded Sections:
Chapter 9 Aldehydes and Ketones Excluded Sections: 9.14-9.19 Aldehydes and ketones are found in many fragrant odors of many fruits, fine perfumes, hormones etc. some examples are listed below. Aldehydes
2. Which of the following statements is false concerning the structure of histidine?
Page 1 MULTIPLE CHOICE - Three (3) points each. Histidine, one of the 20 naturally occurring amino acids, has the following skeletal structure. Complete a Lewis structure for histidine and answer the following
Molecular Models and Isomerism
Name Lab Day Molecular Models and Isomerism Introduction: When two or more compounds have the same molecular formula but different structural arrangements of their atoms, the various individual compounds
CHAPTER 24 Organic Chemistry
CHAPTER 24 rganic Chemistry 1. The general formula for alkenes is A. C n H 2n+2 B. C 2n H 2n C. C n H n+2 D. C n H 2n E. C n H 2n 2 2. The general formula of an alkane is A. C n H 2n B. C n H 2n+2 C. C
ALDEHYDES AND KETONES
11 R R R ALDEYDES AND KETNES APTER SUMMARY 111 Structure of Aldehydes and Ketones Aldehydes and ketones both have a carbonyl group (carbonoxygen double bond); aldehydes have at least one carbon bonded
TOPIC 3 - ALDEHYDES AND KETONES (Chapters 12 & 16)
TPIC 3 - ALDEYDES AND KETNES (Chapters 12 & 16) Lecture 15 Web12 12.1 Introduction 16.1 Introduction 16.2 Nomenclature of Aldehydes and Ketones 16.3 ysical Properties 12.2 xidation Reduction Reactions
Dr. Mohamed El-Newehy
By Dr. Mohamed El-Newehy Chemistry Department, College of Science, King Saud University http://fac.ksu.edu.sa/melnewehy Aldehydes and Ketones 1 Structure of Aldehydes and Ketones - Aldehydes and ketones
HW #5: 16.20, 16.28, 16.30, 16.32, 16.40, 16.44, 16.46, 16.52, 16.60, 16.62, 16.64, 16.68
hemistry 131 Lecture 10: Aldehydes and Ketones: Structure, Nomenclature, Physical Properties, and Reactivity hapter 16 in McMurry, Ballantine, et. al. 7 th edition W #5: 16.20, 16.28, 16.30, 16.32, 16.40,
CHAPTER 21 HW: ALDEHYDES + KETONES
CAPTER 21 W: ALDEYDES + KETES MECLATURE 1. Give the name for each compound (IUPAC or common name). C Structure 2 ame Structure ame 2. Draw each compound. Structure ame dicyclohexyl ketone 1,1,1-trifluoro-3-pentanone
Experiment 7 Aldehydes, Ketones, and Carboxylic Acids
Experiment 7 Aldehydes, Ketones, and arboxylic Acids Aldehydes and ketones are molecules that contain a carbonyl group, which is an oxygen atom with a double bond to a carbon atom. In an aldehyde, the
Reactions of Chapter 10 Worksheet and Key
1) Alcohol Fermentation Reactions of Chapter 10 Worksheet and Key Alcohol fermentation is a series of chemical reaction that convert sugar molecules, such a glucose, into ethanol and C 2. The overall reaction
Full file at
Chapter 2 - Alkanes: The Nature of Organic Compounds 1. Which of the following functional group classifications do not contain oxygen? A. ether B. thiol C. aldehyde D. ester E. amide 2. To which functional
Chemistry 2050 Introduction to Organic Chemistry Fall Semester 2011 Dr. Rainer Glaser
Chemistry 2050 Introduction to Organic Chemistry Fall Semester 2011 Dr. Rainer Glaser Examination #4 Make-Up Carbonyl Compounds and Amines. Wednesday, November 30, 2011, 10 10:50 am Name: Answer Key Question
ALDEHYDES AND KETONES
ALDEHYDES AND KETONES IN WEEK 1, A STUDENT SHOULD BE ABLE TO: 1. Give the IUPAC name given the structure, and draw the structure given the name, of aldehydes and ketones. Also, draw the structure given
SECTION A. 1. Which is general formula of aldehyde and ketone? (c) CnHnO
SEM 4 SLE UNIT 5 SECTION A 1. Which is general formula of aldehyde and ketone? (a) CnH2n+1O (b) CnH2nO (c) CnHnO (d) CnH2n+2O Ans: (b) CnH2nO 2. Propanal and propan- 2- one are which type of isomers? (a)
Ch 19 Aldehydes and Ketones
Ch 19 Aldehydes and Ketones Aldehydes (RCHO), with the exception of formaldehyde (H 2 CO), are compounds with both an H and an organic group attached to a carbonyl. Ketones (R 2 CO) are compounds with
Hour Examination # 2
CHEM 343 Principles of Organic Chemistry II Summer 2014 Exam # 2 Solutions Key Page 1 of 7 CHEM 343 Principles of Organic Chemistry II Summer 2014 Instructor: Paul J. Bracher Hour Examination # 2 Tuesday,
CHEM 1412 SAMPLE FINAL EXAM
CHEM 1412 SAMPLE FINAL EXAM PART I - Multiple Choice (2 points each) 1. In which colligative property(ies) does the value decrease as more solute is added? A. boiling point B. freezing point and osmotic
Chemistry 2050 Introduction to Organic Chemistry Fall Semester 2011 Dr. Rainer Glaser
Chemistry 2050 Introduction to Organic Chemistry Fall Semester 2011 Dr. Rainer Glaser Examination #4 Carbonyl Compounds and Amines. Wednesday, November 16, 2011, 10 10:50 am Name: Answer Key Question 1.
Assistant Lecturer: Sahar Mohammed Shakir Assistant Lecturer: Sarah Sattar Jabbar
Assistant Lecturer: Sahar Mohammed Shakir Assistant Lecturer: Sarah Sattar Jabbar Structure Aldehydes are cpd.s of the general formula R ; Ketones are cpd.s of the general formula RŔ. The groups R and
CHEMISTRY 150. April 2012
CHEMISTRY 150 Dr. B. MacLean April 2012 NAME: (please print) ID #: This is a three hour exam. SUGGESTION: Read over the entire exam before beginning, and begin by doing those questions which you find easiest.
Chemical Properties of Aldehydes and Ketones
hemical Properties of Aldehydes and Ketones hemical Properties of Aldehydes and Ketones xidation of Aldehydes Aldehydes are very easily oxidized to carboxylic acids. R [] R [] R primary alcohol aldehyde
FUNCTIONAL GROUPS Functional Group Suffix Formula Other Info O. Ester. Amide --- R C N R' or R(CO)NR R
EMISTRY 10 elp Sheet # rganic (Part III hapters.7 (condensed, structural drawings, 6.3 (line drawings, 6.9a (benzene, 7.e (hybrid orbitals in organic structures, and Appendix E (functional groups Do topics
Organic Chemistry, Third Edition. Janice Gorzynski Smith University of Hawai i. Chapter 21. Aldehydes and Ketones Nucleophilic Addition
Organic Chemistry, Third Edition Janice Gorzynski Smith University of Hawai i Chapter 21 Aldehydes and Ketones Nucleophilic Addition Prepared by Rabi Ann Musah State University of New York at Albany Copyright
9. Which compound is an alcohol? A) methanol C) butane B) ethyne D) propanal
1. Given the structural formulas for two organic compounds: The differences in their physical and chemical properties are primarily due to their different A) number of hydrogen atoms B) number of carbon
Chapter 3. Organic Compounds: Alkanes and Their Stereochemistry
Chapter 3. Organic Compounds: Alkanes and Their Stereochemistry Functional Group: Be able to identify and name any of the functional groups listed on Table 3.1, pages 76-77. Summary of important functional
Important Concepts. Problems. Chapter Problems. Cuprate additions followed by enolate alkylations. 15. Michael Addition (Section 18-11)
Problems hapter 18 861 uprate additions followed by enolate alkylations P 1. R 2uLi, TF 2. RX A A R R N 15. Michael Addition (Section 18-11) D P D R P R A RR 16. Robinson Annulation (Section 18-11) Important
CHAPTER HYDROCARBONS. Chapterwise Previous year Qs. (a) Na (b) HCl in H2O (c) KOH in C2H5OH (d) Zn in alcohol. Ans: (c)
122 CHAPTER HYDROCARBONS 1. Acetylenic hydrogens are acidic because [1989] Sigma electron density of C Hbond in acetylene is nearer to carbon, which has 50% s- character Acetylene has only open hydrogen
Naming Aldehydes and Ketones
ASSIGNMENT 4 Task 4 Due: 11:59pm on Friday, October 5, 2018 You will receive no credit for items you complete after the assignment is due. Grading Policy Naming Aldehydes and Ketones The International
Chapter 11. Introduction to Organic Chemistry
hapter 11 Introduction to rganic hemistry Properties of arbon and its compounds 2 Properties of arbon and its compounds 3 Properties of arbon and its compounds 4 Properties of arbon and its compounds 5
DISTINCTION BETWEEN SOME PAIRS OF ORGANIC COMPOUNDS (Chemical Tests)
DISTINCTIN BETWEEN SME PAIRS F RGANIC CMPUNDS (Chemical Tests) 1. Cholorobenzene (C6H5) and chlorocyclohexane (C6H11) Add small quantity of aqueous K to each compound. Acidify with dil. HN3 and add AgN3
Unit 14: Organic Chemistry REGENTS CHEMISTRY
REGENTS CHEMISTRY 1 Organic compounds contain carbon atoms which bond to one another in chains, rings, and networks to form a variety of structures. Organic compounds can be named using the IUPAC system.
Chapter 22. Organic and Biological Molecules
Chapter 22 Organic and Biological Molecules 1 Organic Chemistry and Biochemistry The study of carbon-containing compounds and their properties. The vast majority of organic compounds contain chains or
Carbonyl Compounds. Introduction
Carbonyl Compounds Introduction 1 Introduction Two broad classes of compounds contain the carbonyl group: [1] Compounds that have only carbon and hydrogen atoms bonded to the carbonyl [2] Compounds that
+ (CH 3) 2 NH + Cl - CHEM1907/ J-6 June Complete the following table. CONSTITUTIONAL FORMULA(S) OF MAJOR ORGANIC PRODUCT(S)
EM1907/8 2003-J-6 June 2003 omplete the following table. AME (where required) DITIS STITUTIAL FRMULA(S) F MAJR RGAI PRDUT(S) 13 l excess ( 3 ) 2 + ( 3) 2 + l - ame: 3 M l / heat + excess 3 + / heat 3 3
Regents review Organic chemistry
2011-2012 1. Which structural formula represents a saturated hydrocarbon? 2. Which molecule contains ten hydrogen atoms? A) butane B) butene C) propane D) propene 3. A double carbon-carbon bond is found
Chem 263 March 7, 2006
Chem 263 March 7, 2006 Aldehydes and Ketones Aldehydes and ketones contain a carbonyl group, in which the carbon atom is doubly bonded to an oxygen atom. The carbonyl group is highly polarized, with a
ALDEH. I. Multiple Choice Questions (Type-I)
Unit 12 ALDEHYDE ALDEH YDES, KETONE KET ONES AND CARBOX C ARBOXYLIC ACIDS I. Multiple Choice Questions (Type-I) 1. Addition of water to alkynes occurs in acidic medium and in the presence of Hg 2+ ions
CHAPTER 21 HW: ALDEHYDES + KETONES
CAPTER 21 W: ALDEYDES + KETES MECLATURE 1. Give the name for each compound (IUPAC or common name). Structure 6 5 4 1 C 2 ame 3,3-dimethyl-2-pentanone (or 1,1-dimethylpropyl methyl ketone) 5-hydroxy-4-methylhexanal
Chemistry 2050 Introduction to Organic Chemistry Fall Semester 2011 Dr. Rainer Glaser
Chemistry 2050 Introduction to Organic Chemistry Fall Semester 2011 Dr. Rainer Glaser Examination #3 Alcohols, Ethers, Aldehydes & Ketones. Wednesday, October 26, 2011, 10 10:50 am Name: Question 1. Names,
Organic Chemistry. Pre-lab Assignment. Purpose. Background. Experiment 14. Before coming to lab: Hydrocarbons. Read the lab thoroughly.
Experiment 14 Pre-lab Assignment Before coming to lab: Read the lab thoroughly. rganic hemistry Answer the pre-lab questions that appear at the end of this lab exercise. The questions should be answered
Chemistry 110. Bettelheim, Brown, Campbell & Farrell. Ninth Edition
Chemistry 110 Bettelheim, Brown, Campbell & Farrell Ninth Edition Introduction to General, rganic and Biochemistry Chapter 14 Alcohols, Ethers and Thiols Alcohols have a ydroxyl Group, -, bonded to tetrahedral
ORGANIC - BROWN 8E CH ALDEHYDES AND KETONES.
!! www.clutchprep.com CONCEPT: ALDEHYDE NOMENCLATURE Replace the suffix of the alkane -e with the suffix On the parent chain, the carbonyl is always terminal, and receive a location As substituents, they
3.8 Aldehydes and ketones
3.8 Aldehydes and ketones Introduction: p's to p's Like the alkenes, the carbonyl group consists of a s bond and a p bond between the carbon and oxygen: Oxygen is more electronegative than carbon meaning
Naming Aldehydes and Ketones
Assignment 4 Task 3 Due: 11:59pm on Friday, October 5, 2018 You will receive no credit for items you complete after the assignment is due. Grading Policy Naming Aldehydes and Ketones The International
ST. JOSEPH S COLLEGE OF ARTS & SCIENCE (AUTONOMOUS) ST. JOSEPH S COLLEGE ROAD, CUDDALORE CH101T ORGANIC CHEMISTRY I (SEMESTER-I)
UNIT I 1. The hybridization involved in the formation of acetylene is a) sp b) sp 2 c) sp 3 d) sp 3 d 2. The IUPAC name of is 1. 3-hexene b) 4-hexene c) 3-hexyne d) 4-hexyne 3. -------- is the type of
Chapter 16 Aldehydes and Ketones I Nucleophilic Addition to the Carbonyl Group
Chapter 16 Aldehydes and Ketones I Nucleophilic Addition to the Carbonyl Group Nomenclature of Aldehydes and Ketones Aldehydes are named by replacing the -e of the corresponding parent alkane with -al
Aldehydes and Ketones Reactions. Dr. Sapna Gupta
Aldehydes and Ketones Reactions Dr. Sapna Gupta Reactions of Aldehydes and Ketones Nucleophilic Addition A strong nucleophile attacks the carbonyl carbon, forming an alkoxide ion that is then protonated.
CHEM 203 Exam 1. Name Multiple Choice Identify the letter of the choice that best completes the statement or answers the question.
CHEM 203 Exam 1 Name Multiple Choice Identify the letter of the choice that best completes the statement or answers the question. 1. Which of the following elements is a large percentage of both the earth's
MCAT Organic Chemistry Problem Drill 10: Aldehydes and Ketones
MCAT rganic Chemistry Problem Drill 10: Aldehydes and Ketones Question No. 1 of 10 Question 1. Which of the following is not a physical property of aldehydes and ketones? Question #01 (A) Hydrogen bonding
Lecture 2. The framework to build materials and understand properties
Lecture 2 The framework to build materials and understand properties 1 Trees are made into a solid materials/structures in an environment that consists of small molecules: CO 2, N 2, H 2 0, CH 4 O C 2.58Ǻ
DAMIETTA UNIVERSITY CHEM-103: BASIC ORGANIC CHEMISTRY LECTURE
DAMIETTA UNIVERSITY CHEM-103: BASIC ORGANIC CHEMISTRY LECTURE 6 Dr Ali El-Agamey 1 Oxidation States Easy for inorganic salts: CrO 4 2- reduced to Cr 2 O 3. KMnO 4 reduced to MnO 2. Oxidation: Gain of O,
Aldehydes and Ketones. Dr. Munther A. M. Ali
Aldehydes and Ketones Dr. Munther A. M. Ali ALDYHYDES AND KETONES Aldehydes are compounds of the general formula RCHO Ketones are compounds of the general formula RR'CO Aldehydes A ketone Both aldehydes
ALCOHOLS AND PHENOLS
ALCOHOLS AND PHENOLS ALCOHOLS AND PHENOLS Alcohols contain an OH group connected to a a saturated C (sp3) They are important solvents and synthesis intermediates Phenols contain an OH group connected to
Q. No. 4 Chlorination of toluene in the presence of light and heat followed by treatment with aqueous NaOH gives o cresol p cresol 2, 4 dihydroxy tolu
Q. No. 1 Glycerine has One primary and two secondary OH groups One secondary and two primary OH groups Three primary OH groups Three secondary OH groups Q. No. 2 The structural formula of cyclohexanol
Importance of Carbohydrates
Chapter 25 Importance of Carbohydrates Distributed widely in nature Key intermediates of metabolism (sugars) Structural components of plants (cellulose) Central to materials of industrial products: paper,
12. Aldehydes & Ketones (text )
2009, Department of Chemistry, The University of Western ntario 12.1 12. Aldehydes & Ketones (text 13.1 13.11) A. Structure and Nomenclature The carbonyl group is present in aldehydes and ketones and is
Reversible Additions to carbonyls: Weak Nucleophiles Relative Reactivity of carbonyls: Hydration of Ketones and Aldehydes
Reversible Additions to carbonyls: Weak Nucleophiles Weak nucleophiles, such as water, alcohols, and amines, require acid or base catalysis to undergo addition to carbonyl compounds Relative Reactivity
Chemistry 102 Organic Chemistry: Introduction to Isomers Workshop
Chemistry 102 Organic Chemistry: Introduction to Isomers Workshop What are isomers? Isomers are molecules with the same molecular formula, but different arrangements of atoms. There are different types
CPT-26 ANSWERS 73. (1) 145. (4) 2. (1) 74. (3) 146. (4) 3. (3) 75. (2) 147. (3) 4. (2) 5. (4) 76. (4) 77. (2) 148. (2) 149. (3) 6. (3) 78.
1 08/01/2018 COMMON PRACTICE TEST [PMT] : 2017-19 CPT-26 ANSWERS CODE GOL 1. (1) 37. (3) 73. (1) 109. (3) 145. (4) 2. (1) 38. (1) 74. (3) 110. (3) 146. (4) 3. (3) 39. (1) 75. (2) 111. (2) 147. (3) 4. (2)
Chemistry 234 Practice Exam 3. The Periodic Table
ame: Last First MI Chemistry 234 Practice Exam 3 Instructions: The first 15 questions of this exam should be answered on the provided Scantron. You must use a pencil for filling in the Scantron sheet.
Physical Properties. Alcohols can be: CH CH 2 OH CH 2 CH 3 C OH CH 3. Secondary alcohol. Primary alcohol. Tertiary alcohol
Chapter 10: Structure and Synthesis of Alcohols 100 Physical Properties Alcohols can be: CH 3 CH 3 CH CH 2 OH * Primary alcohol CH 3 OH CH * CH 2 CH 3 Secondary alcohol CH 3 CH 3 * C OH CH 3 Tertiary alcohol
Chemistry Questions ans Answers BASED ON HIGH ORDER THINKING SKILL (HOTS) UNIT- 12 ALDEHYDES, KETONES AND CARBXYLIC ACID
Chemistry Questions ans Answers BASED N IG RDER TINKING SKILL (TS) UNIT- 12 ALDEYDES, KETNES AND CARBXYLIC ACID 1 MARK QUESTINS Q. 1. Name the reaction and the reagent used for the conversion of acid chlorides
Chemistry 11 Hydrocarbon Alkane Notes. In this unit, we will be primarily focusing on the chemistry of carbon compounds, also known as.
1 Chemistry 11 Hydrocarbon Alkane Notes In this unit, we will be primarily focusing on the chemistry of carbon compounds, also known as. Why is organic chemistry so important? Many of the compounds that