New analysis of the 3 & 4 bands of HNO 3 by high resolution Fourier transform spectroscopy in the 7.6 µm region
|
|
- Caroline Moore
- 6 years ago
- Views:
Transcription
1 New analysis of the 3 & 4 bands of HNO 3 by high resolution Fourier transform spectroscopy in the 7.6 µm region Agnés Perrin,, J.M.Flaud Laboratoire Interuniversitaire des Systémes Atmosphériques (LISA), CNRS, Université Paris Est, Créteil M.Ridolfi, M.Carlotti, Dipartimento di Chimica Fisica e Inorganica (DCFI), Universiy of Bologna, Viale del Risorgimento, , - Bologna, Italy. Agnes.Perrin@lisa.u-pec.fr A.Perrin: ASA-HITRAN 2012
2 HNO 3 in HITRAN-GEISA Intensities MW & 9 { 5,2 9 ) { 4, 3 } cm cm , 896cm , 1326cm cm -1 Far-IR 22µm 11µm 7.6µm 5.8µm Spectral range covered by ACE-FTS & MIPAS A.PerrinASA-HITRAN 2012
3 Intensities Up to now HNO 3 is measured (almost only) in the 11 µm region Which was updated recently in HITRAN MW & 9 { 5,2 9 ) { 4, 3 } cm cm , 896cm , 1326cm cm -1 Far-IR 22µm 11µm 7.6µm 5.8µm Improved line positions & intensities at 11 µm ( 5 and 2 9 bands): Coherence in the HNO 3 line intensities for the 11µm 7.6 µm 5.8 µm Perrin, Orphal, Flaud, Klee, Mellau, Mäder, Walbrodt & Winnewisser, i J. Mol. Spect 228 (2004) Flaud, Brizzi, Carlotti, A.Perrin: Perrin & Ridolfi Ohio-State Atmos. 67th Chem. Molecular Phys., Symposium, 6, 1 12, June 2012 Tran, Brizzi Gomez, Perrin, Hase, Ridolfi, Hartmann, JQSRT 110, (2009). Gomez, Tran, Perrin, Gamache, Laraia, Orphal, Chelin, Fellows, Hartmann JQSRT 110, (2009).
4 900 cm µm 1300 cm µm 1700 cm µm ACE-FTS
5 900 cm µm 1300 cm µm 1700 cm µm ACE-FTS Difference between the two profiles (900 cm -1 and 1700cm -1 bands) M. A. Wolff, Validation of HNO 3, ClONO 2, and N 2 O 5 from the the ACE-FTS spectrometer. Atmos. Chem. Phys., 8, , 2008
6 Only ONE source for the line positions & relative intensities parameters for HNO µm in the HITRAN or GEISA databases
7 Only ONE source for the line positions & relative intensities parameters for HNO µm in the HITRAN or GEISA databases Perrin, Lado-Bordowski d and dvalentin, «The 3 3 and 4 4 bands of HNO 3».Mol. Phys 67 p249 (1989) Perrin, et al. «Line intensities in the 11µm & 7.6 µm bands of HNO 3» J. Mol; Spectrosc. 160, p524 (1993)
8 Only ONE source for the line positions & relative intensities parameters for HNO µm in the HITRAN or GEISA databases Perrin, Lado-Bordowski d and dvalentin, «The 3 3 and 4 4 bands of HNO 3».Mol. Phys 67 p249 (1989) Perrin, et al. «Line intensities in the 11µm & 7.6 µm bands of HNO 3» J. Mol; Spectrosc. 160, p524 (1993) The HITRAN or GEISA updates of HNO3@7.6 µm concern only the total band intensity. Flaud, Bi Brizzi, i Carlotti, Perrin, and Ridolfi. MIPAS database: Validation of HNO 3 line parameters Atmos. Chem. Phys., 6, 1 12, 2006
9 Only ONE source for the line positions & relative intensities parameters for the HITRAN or GEISA databases Perrin, Lado-Bordowski d and dvalentin, «The 3 3 and 4 4 bands of HNO 3».Mol. Phys 67 p249 (1989) Perrin, et al. «Line intensities in the 11µm & 7.6 µm bands of HNO 3» J. Mol; Spectrosc. 160, p524 (1993) In 2011 Geoffrey Toon (JPL laboratory) evaluated the HNO 3 linelist in 7.6 µm by using it to fit the JPL MkIV balloon spectra and PNNL laboratory spectra. PNNL spectra: Chackerian, Sharpe & Blake JQSRT, 82, , 2003.
10 Geoffrey Toon powerpoint presentation PNNL spectra MkIV balloon born spectra
11 7.6 µm( 3 & 4 bands) in 1989 Only a partial analysis of the 3 and 4 bands was performed 1303 cm cm W Anh +C 3 1 Anh +C W The model did not account from the resonances involving the dark bands A.Perrin, O.Lado-Bordowski, & A. Valentin, Mol. Phys. 67, 249 (1989). Line position calculation: the calculated l energy levelsl were replaced A.Perrin: Ohio-State 67th Molecular Symposium, June 2012 by the observed ones (when existing)
12 This work FTS spectra recorded at Giessen (Germany) Bruker- 120HR in 2003 (7.6 µm) (1) FTS spectra recorded at Denver University (USA) for the hot band 12 µm (2) FTS spectra recorded at Orsay for the hot band 11 µm (3) Investigation of the PNNL HNO 3 cross sections (Pacific Northwest t National Laboratory)(4) Analyses of these spectra: New theoretical model (1)Perrin, Orphal,Flaud, Klee, Mellau,Mäder,Walbrodt,& Winnewisser, J. Mol. Spect 228 (2004) (2) Perrin, Flaud, Camy-Peyret, Winnewisser, Klee, Goldman, Murcray, Blatherwick, Bonomo, Murcray, J. Mol. Spectrosc. 166 (1994) (3) Flaud, Perrin; Orphal, Kou, Flaud, Dutkiewicz, Piccolo, JQSRT 77 (2003) A.Perrin: Ohio-State 67th Molecular Symposium, June 2012 (4) Chackerian; Sharpe, & Blake, JQSRT 82 (2003)
13 µm( 3 & 4 bands) in 2012 Two bright bands ( 3 & 4 ) four dark interacting bands.. (3 9, 2 6, & ) From the analysis of all investigated spectra: the number of assigned energy levels {3 1,4 1, 9 3, , 6 2, } is multiplied by a factor of ~2 as compared to the 1989 study A.Perrin: ASA-HITRAN 2012
14 Hamiltonian matrix A.Perrin: ASA-HITRAN 2012
15 Informations on the: * dark state from the Q branch of the hot band A.Perrin: ASA-HITRAN
16 Position of the dark band (center at cm -1 ) from the hot band Obs Orsay, 2003 (3) Flaud, Perrin; Orphal, Kou, Flaud, Dutkiewicz, Piccolo, JQSRT 77 (2003)
17 .3 9 Hamiltonian matrix E v = (cm -1 ) sym: A' A" A' A' A" A" W Fermi+C Fermi+C 9 3 W+Torsion B B strong Fermi 4 1 Fermi+C B W Anh 3 1 Fermi+C B Anh W A+B A+B strong Fermi A+B A+B W A+B A+B A+B W Informations on the: 9 3 dark state from the hot band 9 9 Large amplitude OH torsion
18 O O N O H 9 torsion OH/NO 2 (3 9 at cm -1 ) x O x H O H B N O N z y O y O z 9 torsion of OH /NO 2 large amplitude A.Perrin: Splitting Ohio-State of 62th ~ Molecular 0.06 cm Symposium, -1 in 9June
19 Obs Denver 1994 A.Perrin: Ohio-State 67th Molecular Symposium, June 2012 (2) Perrin, Flaud, Camy-Peyret, Winnewisser, Klee, Goldman, Murcray, Blatherwick, Bonomo, Murcray, J. Mol. Spectrosc. 166 (1994)
20 Transfert of the torsional splitting via the interaction Giessen 2003 A.Perrin: Ohio-State 67th Molecular Symposium, June 2012
21 Geoffrey Toon powerpoint presentation PNNL spectra MkIV balloon born spectra
22 Laboratory FTS spectrum (Univ. Giessen) Near 1320 cm -1 Spectre FTS de laboratoire (Univ. Giessen) A.Perrin ASA-HITRAN 2012
23 Laboratory FTS spectrum (Univ. Giessen) Near 1320 cm -1 Spectre FTS de laboratoire (Univ. Giessen) July 2012
24 Validation using MIPAS spectra A.Perrin: ASA-HITRAN 2012
25 HNO 3 detection by MIPAS at 1321 cm -1 MIPAS orbit 2081, July 2002, cm -1 resolution Obs HITRAN-GEISA NEW Obs-Calc HITRAN-GEISA NEW A.Perrin, ASA-HITRAN 2012
26 Geoffrey Toon powerpoint presentation PNNL spectra MkIV balloon born spectra
27 A.Perrin: Ohio-State 67th Molecular Symposium, June 2012
28 A.Perrin: ASA-HITRAN 2012
29 MIPAS orbit 2081, July 2002, cm -1 resolution Obs HITRAN NEW Obs-Calc HITRAN NEW A.Perrin: Ohio-State 67th Molecular Symposium, June 2012
30 Geoffrey Toon powerpoint presentation PNNL spectra MkIV balloon born spectra
31 Obs (Giessen, 2003)
32 Calc. 3 4 bands 2012 Obs (Giessen, 2003)
33 MIPAS orbit 2081, July 2002, cm -1 resolution Obs HITRAN NEW Obs-Calc HITRAN NEW A.Perrin: ASA-HITRAN 2012
34 What has still to be done: Try to get better fit for the line positions (if possible!!) Getting «absolute intensities» for all spectral ranges of the 3 & 4 bands at 7.6 µm Getting consistent t intensities iti for the 11 µm 7.6 µm 5.8 µm bands of HNO 3 I need high resolution data for HNO 3 for several infrared bands of HNO 3. ( band 3551 cm cm -1, 2 2 band@2645cm -1, etc..please contact me! A.Perrin: Ohio-State 67th Molecular Symposium, June 2012
35 CONCLUSION A new study of the 3 et 4 bands of HNO 3 was performed It is necessary to account for resonances involving the 3 9, 2 6 et & dark bands. I need high resolution data for HNO 3. PLEASE CONTACT ME!!!!!!!!!!!! Financial support from the French program «LEFE- CHAT» (Les Enveloppes Fluides et l'environnement, Chimie Atmosphérique) of CNRS-INSU is gratefully A.Perrin: Ohio-State 67th Molecular Symposium, June 2012 acknowledged.
Relief is on the Way: Status of the Line Positions and Intensities for Nitric Acid
Relief is on the Way: Status of the Line Positions and Intensities for Nitric Acid Agnés Perrin, J.M.Flaud, J.Orphal Laboratoire Interuniversitaire des Systémes Atmosphériques (LISA), CNRS, Université
More informationInfrared quantitative spectroscopy and atmospheric satellite measurements
Infrared quantitative spectroscopy and atmospheric satellite measurements Jean-Marie Flaud Laboratoire Interuniversitaire des Systèmes Atmosphériques CNRS, Universités Paris Est Créteil et Paris Diderot
More informationJournal of Quantitative Spectroscopy & Radiative Transfer
JQSRT : 4 Journal of Quantitative Spectroscopy & Radiative Transfer ] (]]]]) ]]] ]]] Contents lists available at ScienceDirect Journal of Quantitative Spectroscopy & Radiative Transfer journal homepage:
More informationQuantitative spectroscopy of several tropospheric or statospheric molecules: recent updates performed in the GEISA database
Quantitative spectroscopy of several tropospheric or statospheric molecules: recent updates performed in the GEISA database Agnés Perrin Agnes.Perrin@lisa.univ-paris12.fr Laboratoire Interuniversitaire
More informationDIODE- AND DIFFERENCE-FREQUENCY LASER STUDIES OF ATMOSPHERIC MOLECULES IN THE NEAR- AND MID-INFRARED: H2O, NH3, and NO2
DIODE- AND DIFFERENCE-FREQUENCY LASER STUDIES OF ATMOSPHERIC MOLECULES IN THE NEAR- AND MID-INFRARED: H2O, NH3, and NO2 Johannes ORPHAL, Pascale CHELIN, Nofal IBRAHIM, and Pierre-Marie FLAUD Laboratoire
More informationFIRST HIGH-RESOLUTION ANALYSIS OF PHOSGENE 35 Cl 2. CO AND 35 Cl 37 ClCO FUNDAMENTALS IN THE CM -1 SPECTRAL REGION
FIRST HIGH-RESOLUTION ANALYSIS OF PHOSGENE 35 Cl 2 CO AND 35 Cl 37 ClCO FUNDAMENTALS IN THE 250-480 CM -1 SPECTRAL REGION F. Kwabia Tchana 1, M. Ndao 1, L. Manceron 2, A. Perrin 1, J. M. Flaud 1, W.J.
More informationA Spectroscopic Database for MIPAS
A Spectroscopic Database for MIPAS J.-M. Flaud a, C. Piccolo b and B. Carli b a Laboratoire de Photophysique Moleculaire,CNRS, Bat. 350, Université de Paris Sud, 91405 Orsay cedex, France b IFAC-CNR, via
More informationLinda R. Brown. Jet Propulsion Laboratory California Institute of Technology Pasadena, CA
Infrared Laboratory Spectroscopy. of CH4 and CH3D for Atmospheric Studies Linda R. Brown Jet Propulsion Laboratory California Institute of Technology Pasadena, CA 91109 linda.brown@jpl.nasa.gov The part
More informationMolecular spectroscopy, besides its own interest. Infrared Spectroscopy and the Atmosphere
Gentner-Kastler-Preis Infrared Spectroscopy and the Atmosphere Measurements from space enable accurate monitoring of molecular abundances Jean-Marie Flaud In recent years, numerous studies concerning the
More informationAn Improved Version of the CO2 Line-mixing Database and Software: Update and Extension
An Improved Version of the CO2 Line-mixing Database and Software: Update and Extension ANNE L. LARAIA, JULIEN LAMOUROUX, ROBERT R. GAMACHE University of Massachusetts School of Marine Sciences, Department
More informationJournal of Quantitative Spectroscopy & Radiative Transfer ] (]]]]) ]]] ]]] Contents lists available at ScienceDirect
JQSRT : 6 Journal of Quantitative Spectroscopy & Radiative Transfer ] (]]]]) ]]] ]]] Contents lists available at ScienceDirect Journal of Quantitative Spectroscopy & Radiative Transfer journal homepage:
More informationWeak water absorption lines around and 1.66 lm by CW-CRDS
Journal of Molecular Spectroscopy 244 (2007) 170 178 www.elsevier.com/locate/jms Weak water absorption lines around 1.455 and 1.66 lm by CW-CRDS Semen N. Mikhailenko a, *, Wang Le b,c, Samir Kassi b, Alain
More informationASSESSMENT OF THE GEISA AND GEISA/IASI SPECTROSCOPIC DATA QUALITY: trough comparisons with other public database archives
ASSESSMENT OF THE GEISA AND GEISA/IASI SPECTROSCOPIC DATA QUALITY: trough comparisons with other public database archives N. Jacquinet-Husson, N.A. Scott, A. Chédin, R. Armante Laboratoire de Météorologie
More informationThe Smithsonian Astrophysical Observatory Database SAO92
The Smithsonian Astrophysical Observatory Database SAO92 K. Chance, K. W. Jucks, D. G. Johnson, and W. A. Traub Harvard-Smithsonian Center for Astrophysics, Cambridge, MA, USA ABSTRACT The Smithsonian
More informationRESULTS OF MID-LATITUDE MIPAS VALIDATION MEASUREMENTS OBTAINED BY THE SAFIRE-A AIRBORNE SPECTROMETER
(3) RESULTS OF MID-LATITUDE MIPAS VALIDATION MEASUREMENTS OBTAINED BY THE SAFIRE-A AIRBORNE SPECTROMETER U. Cortesi (1), G. Bianchini (1), L. Palchetti (1), E. Castelli (2), B.M. Dinelli (2), G. Redaelli
More informationTropospheric trace gas concentrations using infrared spectroscopy from space. Meeting report
Tropospheric trace gas concentrations using infrared spectroscopy from space International workshop held at the Laboratoire Interuniversitaire des Systèmes Atmosphériques (LISA, Universités Paris 7 and
More informationRESULTS OF MID-LATITUDE MIPAS VALIDATION MEASUREMENTS OBTAINED BY THE SAFIRE-A AIRBORNE SPECTROMETER
(3) RESULTS OF MID-LATITUDE MIPAS VALIDATION MEASUREMENTS OBTAINED BY THE SAFIRE-A AIRBORNE SPECTROMETER U. Cortesi * (1), G. Bianchini (1), L. Palchetti (1), E. Castelli (2), B.M. Dinelli (2), G. Redaelli
More informationJacquinet-Husson N., Capelle V., Crépeau L., Scott N.A., Armante R., Chédin A.
Jacquinet-Husson N., Capelle V., Crépeau L., Scott N.A., Armante R., Chédin A. Laboratoire de Météorologie Dynamique Atmospheric Radiation Analysis Group Ecole Polytechnique 91128, Palaiseau, France http://ara.lmd.polytechnique.fr
More informationN. Jacquinet-Husson, N.A. Scott, A. Chédin, R. Armante, K. Garceran, Th. Langlois.
Assessing Spectroscopic Parameter Archives for the Second Generation Vertical Sounders Radiance Simulation: Illustration through the GEISA/IASI database N. Jacquinet-Husson, N.A. Scott, A. Chédin, R. Armante,
More informationJacquinet-Husson N., Capelle V., Crépeau L., Scott N.A., Armante R., Chédin A.
Jacquinet-Husson N., Capelle V., Crépeau L., Scott N.A., Armante R., Chédin A. Laboratoire de Météorologie Dynamique Atmospheric Radiation Analysis Group Ecole Polytechnique 91128, Palaiseau, France http://ara.lmd.polytechnique.fr
More informationN. Jacquinet-Husson, R. Armante, T. Langlois, N.A. Scott, A. Chédin
N. Jacquinet-Husson, R. Armante, T. Langlois, N.A. Scott, A. Chédin Laboratoire de Météorologie Dynamique Atmospheric Radiation Analysis Group Ecole Polytechnique 91128, Palaiseau, France http://ara.lmd.polytechnique.fr
More informationRegistered for 10 th HITRAN Conference
Registered for 10 th HITRAN Conference Name Affiliation Title of Presentation Alain BARBE D. Chris BENNER Peter BERNATH Giovanni BIANCHINI William E. BLASS Chris BOONE Carolyn BRAUER Gabriele BRIZZI Linda
More informationSpectroscopic database GEISA-08 : content description and assessment through IASI/MetOp flight data
Spectroscopic database GEISA-08 : content description and assessment through IASI/MetOp flight data Jacquinet-Husson N., Capelle V., Crépeau L., Scott N.A., Armante R., Chédin A. Laboratoire de Météorologie
More informationGEISA 2013 Ozone and related atmospheric species contents description and assessment
GEISA 2013 Ozone and related atmospheric species contents description and assessment N. Jacquinet-Husson C. Boutammine, R. Armante, L.Crépeau, A. Chédin, N.A. Scott, C. Crevoisier, V.Capelle, A. Bouhdaoui
More informationMIPAS Level 2 Near Real Time processor performances
MIPAS Level 2 Near Real Time processor performances Piera Raspollini & the ORM team Page 1 ORM team B. Carli, S. Ceccherini, M. Prosperi and P. Raspollini IFAC-CNR - Italy M. Carlotti, L. Magnani, M. Ridolfi
More informationHDO and D 2 O long path spectroscopy: Ongoing work of the Brussels-Reims Team.
HDO and D 2 O long path spectroscopy: Ongoing work of the Brussels-Reims Team. Ludovic Daumont Groupe de Spectroscopie Moléculaire et Atmosphérique UMR CNRS 6089 Université de Reims Champagne Ardenne Reims,
More informationTERAHERTZ SPECTROSCOPY OF DEUTERATED ACETALDEHYDE: CH 2 DCHO
TERAHERTZ SPECTROSCOPY OF DEUTERATED ACETALDEHYDE: CH 2 DCHO L. Margulès, R. A. Motiyenko Laboratoire PhLAM, Université de Lille1, France L. H. Coudert LISA, CNRS, Universités Paris Est Créteil et Paris
More informationOVERVIEW OF MIPAS OPERATIONAL PRODUCTS
OVERVIEW OF MIPAS OPERATIONAL PRODUCTS Piera Raspollini (1), Ginette Aubertin (11), Sven Bartha (1), Manfred Birk (12), Bruno Carli (1), Massimo Carlotti (2), Simone Ceccherini (1), Thomas von Clarmann
More informationImpact of Spectroscopic Parameter Archive on Second Generation Vertical Sounders Radiance Simulation: the GEISA/IASI Database as an example
Impact of Spectroscopic Parameter Archive on Second Generation Vertical Sounders Radiance Simulation: the GEISA/IASI Database as an example N. Jacquinet-Husson, N.A. Scott, A. Chédin, R. Armante et co-authors
More informationFirst analysis of the high resolution FTIR spectrum of the nu2 band of the FCO2 radical at cm-1.
First analysis of the high resolution FTIR spectrum of the nu band of the FCO radical at 0. cm-. Agnes Perrin, Helmut Beckers, Helge Willner, Michal Strizik, Zdenek Zelinger, Petr Pracna, Eva Grigorova,
More informationMIPAS LEVEL 2 PROCESSOR PERFORMANCE AND VERIFICATION
MIPAS LEVEL 2 PROCESSOR PERFORMANCE AND VERIFICATION Marco Ridolfi a, Didem Alpaslan b, Bruno Carli c, Massimo Carlotti a, Elisa Castelli b, Simone Ceccherini c, Bianca Maria Dinelli b, Anu Dudhia d, Jean-Marie
More informationCOMBINED OZONE RETRIEVAL USING THE MICHELSON INTERFEROMETER FOR PASSIVE ATMOSPHERIC SOUNDING (MIPAS) AND THE TROPOSPHERIC EMISSION SPECTROMETER (TES)
COMBINED OZONE RETRIEVAL USING THE MICHELSON INTERFEROMETER FOR PASSIVE ATMOSPHERIC SOUNDING (MIPAS) AND THE TROPOSPHERIC EMISSION SPECTROMETER (TES) Claire Waymark, Anu Dudhia, John Barnett, Fred Taylor,
More informationNIR Solar Reference Spectrum Algorithm for the Orbiting Carbon Observatory (OCO)
NIR Solar Reference Spectrum Algorithm for the Orbiting Carbon Observatory (OCO) Hartmut Bösch and Geoffrey Toon Jet Propulsion Laboratory, California Institute of Technology OCO Mission Global, space-based
More informationA tool for IASI hyperspectral remote sensing applications: The GEISA/IASI database in its latest edition
A tool for IASI hyperspectral remote sensing applications: The GEISA/IASI database in its latest edition N. Jacquinet-Husson, C. Boutammine, R. Armante, L.Crépeau, A. Chédin, N.A. Scott, C. Crevoisier,
More informationSpectroscopic parameters for ozone and its isotopes: recent measurements, outstanding issues, and prospects for improvements to HITRAN
Journal of Quantitative Spectroscopy & Radiative Transfer 82 (2003) 207 218 www.elsevier.com/locate/jqsrt Spectroscopic parameters for ozone and its isotopes: recent measurements, outstanding issues, and
More informationHigh sensitivity CW-cavity ring down spectroscopy of N 2 O near 1.5lm (I)
Journal of Molecular Spectroscopy 244 (2007) 33 47 www.elsevier.com/locate/jms High sensitivity CW-cavity ring down spectroscopy of N 2 O near 1.5lm (I) A.W. Liu a,b, S. Kassi a, P. Malara a,c, D. Romanini
More informationENVISAT VALIDATION RESULTS OBTAINED WITH LPMA AND IASI-BALLOON FTIR
ENVISAT VALIDATION RESULTS OBTAINED WITH LPMA AND IASI-BALLOON FTIR G. Dufour (1), S. Payan (1), Y. Té (1), P. Jeseck (1), V. Ferreira (1), C. Camy-Peyret (1), M. Eremenko (1, *), A. Butz (2), K. Pfeilsticker
More informationSTUDIES ON THE CONFORMATIONAL LANDSCAPE OF TERT-BUTYL ACETATE USING MICROWAVE SPECTROSCOPY AND QUANTUM CHEMICAL CALCULATIONS
STUDIES ON THE CONFORMATIONAL LANDSCAPE OF TERT-BUTYL ACETATE USING MICROWAVE SPECTROSCOPY AND QUANTUM CHEMICAL CALCULATIONS Y. ZHAO, G. LI, H. MOUHIB, W. STAHL Institut fur Physikalische Chemie, Raum
More informationLine Intensities in the ν 6 Fundamental Band of CH 3 Br at 10 µm
Journal of Molecular Spectroscopy 216, 30 47 (2002) doi:10.1006/jmsp.2002.8640 Line Intensities in the ν 6 Fundamental Band of CH 3 Br at 10 µm E. Brunetaud, I. Kleiner, and N. Lacome Laboratoire de Dynamique,
More informationMeasurements and empirical modeling of pure CO 2 absorption in the 2.3- m region at room temperature: far wings, allowed and collision-induced bands
Measurements and empirical modeling of pure CO 2 absorption in the 2.3- m region at room temperature: far wings, allowed and collision-induced bands M. V. Tonkov, N. N. Filippov, V. V. Bertsev, J. P. Bouanich,
More informationGeoFIS (Geostationary
GeoFIS (Geostationary Fourier Imaging Spectrometer) ) as part of the GeoTROPE (Geostationary Tropospheric Pollution Explorer) mission: scientific objectives and capabilities J.-M. Flaud, J. Orphal, G.
More informationComment on Radiative transfer in CO 2 -rich atmospheres: 1. Collisional line mixing implies a colder early Mars
Comment on Radiative transfer in CO 2 -rich atmospheres: 1. Collisional line mixing implies a colder early Mars M. Turbet and H. Tran Laboratoire de Météorologie Dynamique, IPSL, UPMC Univ Paris 06, Ecole
More informationRotational Spectra of p-, m-, and o-cyanophenol and Internal Rotation of p-cyanophenol
Rotational Spectra of p-, m-, and o-cyanophenol and Internal Rotation of p-cyanophenol Andrew R. Conrad, Nathan Z. Barefoot, and Michael J. Tubergen Department of Chemistry Kent State University Background
More informationSubmillimeter measurements of isotopes of nitric acid
Journal of Molecular Spectroscopy 236 (2006) 29 34 www.elsevier.com/locate/jms Submillimeter measurements of isotopes of nitric acid Brian J. Drouin a, *, Charles E. Miller a, Juliane L. Fry b, Douglas
More informationIntroduction of Anmyeondo FTS Station as a New TCCON Site
Introduction of Anmyeondo FTS Station as a New TCCON Site Tae-Young GOO, Young-Suk OH, Jin-Ho Shin, Mi-Lim OU, and Chun-Ho CHOI Global Environment System Research Division National Institute of Meteorological
More informationInternational TOVS Study Conference-XIV Proceedings
Assessing Spectroscopic Parameter Archives for the Second Generation Vertical Sounders Radiance Simulation: Illustration through the GEISA/IASI Database Nicole Jacquinet, N.A. Scott, A. Chédin, R. Armante,
More informationAn assessment of the accuracy of the RTTOV fast radiative transfer model using IASI data
An assessment of the accuracy of the RTTOV fast radiative transfer model using IASI data Marco Matricardi, Tony McNally ECMWF Reading, Berkshire, UK Abstract IASI measurements of spectral radiances made
More informationRejuvenated spectroscopy of simple diatomic molecules in HITRAN
Rejuvenated spectroscopy of simple diatomic molecules in HITRAN Iouli Gordon, Laurence Rothman Halides: G. Li, P. Bernath, R. Le Roy, J. Coxon, P. Hajigeorgiou Oxygen: G. Toon, C. Mackie, A. Campargue,
More informationABSTRACT 1 INTRODUCTION
Terahertz atmospheric attenuation and continuum effects David M. Slocum,* a Thomas M. Goyette, a Elizabeth J. Slingerland, a Robert H. Giles, a and William E. Nixon b a Submillimeter-Wave Technology Laboratory,
More informationUNCORRECTED PROOF. The HITRAN 2004 molecular spectroscopic database ARTICLE IN PRESS
B2v8:06a=w ðdec 200Þ:c XML:ver::0: JQSRT : Prod:Type:FTP pp:266ðcol:fig::þ ED:BabuB: PAGN:VG SCAN:Bindu Journal of Quantitative Spectroscopy & Radiative Transfer ] (]]]]) ]]] ]]] www.elsevier.com/locate/jqsrt
More informationAbsorption cross-sections of NO 2 : simulation of temperature and pressure eects
Journal of Quantitative Spectroscopy & Radiative Transfer 76 (2003) 373 391 www.elsevier.com/locate/jqsrt Absorption cross-sections of NO 2 : simulation of temperature and pressure eects A.C. Vandaele
More informationAn Overview of Molecular Opacities
Experimental Molecular Spectroscopy & Data Compilations An Overview of Molecular Opacities Peter Peter Bernath Old Dominion University Norfolk, VA JWST Spectroscopy: mainly IR and low resolution Spectra
More informationJournal of Molecular Spectroscopy
Journal of Molecular Spectroscopy 282 (2012) 34 38 Contents lists available at SciVerse ScienceDirect Journal of Molecular Spectroscopy journal homepage: www.elsevier.com/locate/jms Additional bands of
More informationThe HITRAN 2004 molecular spectroscopic database
Journal of Quantitative Spectroscopy & Radiative Transfer 96 (2005) 139 204 www.elsevier.com/locate/jqsrt The HITRAN 2004 molecular spectroscopic database L.S. Rothman a,, D. Jacquemart a,1, A. Barbe b,
More informationSpectroscopic study of CH 4 at 3.24 µm for atmospheric applications. Development of the PicoSDLA-CH 4 sensor and the TRO-Pico balloon campaign
Spectroscopic study of CH 4 at 3.24 µm for atmospheric applications. Development of the PicoSDLA-CH 4 sensor and the TRO-Pico balloon campaign M. GHYSELS 1, J. COUSIN 1, L. GOMEZ 1,N. AMAROUCHE 3, E. D.
More informationRecent spectroscopy updates to the line-by-line radiative transfer model LBLRTM evaluated using IASI case studies
Recent spectroscopy updates to the line-by-line radiative transfer model LBLRTM evaluated using IASI case studies M.J. Alvarado 1, V.H. Payne 2, E.J. Mlawer 1, J.-L. Moncet 1, M.W. Shephard 3, K.E. Cady-Pereira
More informationPROD. TYPE: COM ARTICLE IN PRESS. Total internal partition sums for molecules of astrophysical interest. Jonathan Fischer, Robert R.
JQSRT 4 pp: -0 (col.fig.: Nil) PROD. TYPE: COM ED: Chanakshi PAGN: RDM -- SCAN: KALA Journal of Quantitative Spectroscopy & Radiative Transfer ( ) www.elsevier.com/locate/jqsrt 2 2 2 2 Total internal partition
More informationComparison of Column Abundances from Three Infrared Spectrometers During AASE II
Comparison of Column Abundances from Three Infrared Spectrometers During AASE II W. A. Traub, K. W. Jucks and D. G. Johnson Smithsonian Astrophysical Observatory, Cambridge, Massachusetts M. T. Coffey
More informationThe rotational spectrum of chlorine nitrate (ClONO 2 ): The m 5 /m 6 m 9 dyad
Journal of Molecular Spectroscopy 243 (2007) 1 9 www.elsevier.com/locate/jms The rotational spectrum of chlorine nitrate (ClONO 2 ): The m 5 /m 6 m 9 dyad Rebecca A.H. Butler a, Douglas T. Petkie b, Paul
More informationSpectral line-shape model to replace the Voigt profile in spectroscopic databases
Spectral line-shape model to replace the Voigt profile in spectroscopic databases D. Lisak 1, N.H. Ngo 2, H. Tran 2, J.-M. Hartmann 2 1 Institute of Physics, Faculty of Physics, Astronomy and Informatics,
More informationARTICLE IN PRESS. Australia. Received 28 September 2004; received in revised form 7 March 2005; accepted 7 March 2005
Journal of Quantitative Spectroscopy & Radiative Transfer 96 (2005) 301 309 www.elsevier.com/locate/jqsrt High spectral resolution solar absorption measurements of ethylene ðc 2 H 4 Þ in a forest fire
More informationROOM TEMPERATURE LINE LISTS FOR CO 2 ISOTOPOLOGUES WITH AB INITIO COMPUTED INTENSITIES
DEPARTMENT OF PHYSICS AND ASTRONOMY ROOM TEMPERATURE LINE LISTS FOR CO 2 ISOTOPOLOGUES WITH AB INITIO COMPUTED INTENSITIES Emil Żak a, Jonathan Tennyson a, Oleg L. Polyansky a, Lorenzo Lodi a Nikolay F.
More informationMIPAS level 2 operational analysis
Atmos. Chem. Phys., 6, 565 563, 26 www.atmos-chem-phys.net/6/565/26/ Author(s) 26. This work is licensed under a Creative Commons License. Atmospheric Chemistry and Physics MIPAS level 2 operational analysis
More informationMEASUREMENT AND MODELING OF OH, NO, AND CO 2 INFRARED RADIATION IN A LOW TEMPERATURE AIR PLASMA
MEASUREMENT AND MODELING OF OH, NO, AND CO 2 INFRARED RADIATION IN A LOW TEMPERATURE AIR PLASMA Denis M. Packan, * Richard J. Gessman, * Laurent Pierrot, Christophe O. Laux, and Charles H. Kruger Department
More informationEmpirical low energy values for methane transitions in the cm-1 region by absorption spectroscopy at 81 K.
Empirical low energy values for methane transitions in the 5852-6181 cm-1 region by absorption spectroscopy at 81 K. Bo Gao, Samir Kassi, Alain Campargue To cite this version: Bo Gao, Samir Kassi, Alain
More informationLine shape modeling and application to remote sensing
Line shape modeling and application to remote sensing Dr. Ha Tran Senior Researcher at CNRS, Paris, France Laboratoire de Météorologie Dynamique Sorbonne Université, Ecole Polytechnique, Ecole Normale
More informationSensitive multiplex spectroscopy in the molecular fingerprint 2.4 µm region with a Cr 2+ :ZnSe femtosecond laser
Sensitive multiplex spectroscopy in the molecular fingerprint 2.4 µm region with a Cr 2+ :ZnSe femtosecond laser E. Sorokin, I. T. Sorokina 2, J. Mandon 3, G. Guelachvili 3, and N. Picqué 3* Institut für
More informationA sensitivity study on spectroscopic parameter accuracies for a mm/sub-mm limb sounder instrument
Journal of Molecular Spectroscopy 229 (2005) 266 275 www.elsevier.com/locate/jms A sensitivity study on spectroscopic parameter accuracies for a mm/sub-mm limb sounder instrument C.L. Verdes a, *, S.A.
More informationTHE HITRAN MOLECULAR SPECTROSCOPIC DATABASE AND HAWKS (HITRAN ATMOSPHERIC WORKSTATION): 1996 EDITION
J. Quant. Spectrosc. Radiat. ¹ransfer Vol. 60, No. 5, pp. 665 710, 1998 Published by Elsevier Science Ltd Printed in Great Britain PII: S0022-4073(98)00078-8 0022 4073/98 $19.00#0.00 THE HITRAN MOLECULAR
More informationThe Rotational Spectrum of Chlorine Nitrate (CIONO 2 ): v 6 and the v 5 /v 6 v 9 Dyad
Wright State University CORE Scholar Physics Faculty Publications Physics 6-2008 The Rotational Spectrum of Chlorine Nitrate (CIONO 2 ): v 6 and the v 5 /v 6 v 9 Dyad Zbigniew Kisiel Ewa Bialkowska-Jaworska
More informationA Combined Gigahertz and Terahertz (FTIR) Spectroscopic Investigation of Meta-D-phenol: Observation of Tunneling Switching
A Combined Gigahertz and Terahertz (FTIR) Spectroscopic Investigation of Meta-D-phenol: Observation of Tunneling Switching Z. Chen, 1 S. Albert, 1, 2 C. Fábri, 1 R. Prentner 1 and M. Quack 1 1 Physical
More informationImpact of different spectroscopic datasets on CH 4 retrievals from Jungfraujoch FTIR spectra
Impact of different spectroscopic datasets on CH 4 retrievals from Jungfraujoch FTIR spectra P. Duchatelet (1), E. Mahieu (1), P. Demoulin (1), C. Frankenberg (2), F. Hase (3), J. Notholt (4), K. Petersen
More informationGas recognition with terahertz time-domain spectroscopy and spectral catalog: a preliminary study
Gas recognition with terahertz time-domain spectroscopy and spectral catalog: a preliminary study H. Lin, W. Withayachumnankul, B. M. Fischer, S. P. Mickan, and D. Abbott Centre for Biomedical Engineering
More informationVirginie Capelle. On behalf of Raymond Armante (*)
Interactive use of the new generation of TIR and SWIR space borne instruments to increase the performance of radiative transfer models, spectroscopic and atmospheric databases (4A, GEISA, ARSA) Virginie
More informationSpectral parameters for the region of HCOOH and its measurement in the infrared tropospheric spectrum
JOURNAL OF GEOPHYSICAL RESEARCH, VOL. 104, NO. D15, PAGES 18,661-18,666, AUGUST 20, 1999 Spectral parameters for the region of HCOOH and its measurement in the infrared tropospheric spectrum A. Pertin
More informationPROD. TYPE: COM ARTICLE IN PRESS. Methane line parameters in HITRAN. BP Reims, Cedex 2, France
pp: --20 (col.fig.: Nil) PROD. TYPE: COM ED: Nanda PAGN: Vidya -- SCAN: Abdul Journal of Quantitative Spectroscopy & Radiative Transfer ( ) www.elsevier.com/locate/jqsrt 2 2 2 2 2 Methane line parameters
More informationARTICLE IN PRESS. Journal of Quantitative Spectroscopy & Radiative Transfer
Journal of Quantitative Spectroscopy & Radiative Transfer 110 (2009) 533 572 Contents lists available at ScienceDirect Journal of Quantitative Spectroscopy & Radiative Transfer journal homepage: www.elsevier.com/locate/jqsrt
More informationTarget molecules and expected quality
6 Validation Plan 6.1 JEM/SMILES measurements 6.2 Basic strategy 6.3 Validation for O 3, HCl and ClO 6.4 Validation for BrO and HNO 3 6.5 Validation for other species 6.6 Collaboration for validation 6.7
More informationNew MIPAS V7 products
New MIPAS V7 products Piera Raspollini on behalf of the MIPAS Quality Working Group New MIPAS V7 products ATMOS 2015, Heraklion, 8-12 June 2015 Page 1 MIPAS Quality Working Group P. Raspollini, B. Carli,
More informationImproved diode laser spectrometer for ortho/para ratio measurements in water vapor
Improved diode laser spectrometer for ortho/para ratio measurements in water vapor A.I. Nadezhdinskii, D.Yu.Namestnikov, K.P.Pavlova, Ya.Ya. Ponurovskii, D.B. Stavrovskii A. M. Prokhorov General Physics
More informationRemote Measurement of Emissions by Scanning Imaging Infrared Spectrometry
Remote Measurement of Emissions by Scanning Imaging Infrared Spectrometry R. Harig *, M. Grutter 2, G. Matz, P. Rusch, J. Gerhard Hamburg University of Technology, Harburger Schlossstr. 2, 279 Hamburg,
More informationExperimental study of the 39 K g state by perturbation facilitated infrared-infrared double resonance and two-photon excitation spectroscopy
THE JOURNAL OF CHEMICAL PHYSICS 122, 074302 2005 Experimental study of the 39 K 2 2 3 g state by perturbation facilitated infrared-infrared double resonance and two-photon excitation spectroscopy Yizhuo
More informationUpdates to Spectroscopy for OCO-2
Updates to Spectroscopy for OCO-2 Vivienne Payne 1, Brian Drouin 1, Malathy Devi 2, Chris Benner 2, Fabiano Oyafuso 1, Linda Brown 1*, Thinh Bui 3, Matt Cich 1, David Crisp 1, Brendan Fisher 1, Iouli Gordon
More information(Picture courtesy of Python M)
(Picture courtesy of Python M) Where is Wuppertal? The Wuppertal monorail The general scheme of things (at least in this lecture.) Potential energy surface(s) Dipole moment surface(s)... in general obtained
More informationModerate Spectral Resolution Radiative Transfer Modeling Based on Modified Correlated-k Method
Moderate Spectral Resolution Radiative Transfer Modeling Based on Modified Correlated-k Method S. Yang, P. J. Ricchiazzi, and C. Gautier University of California, Santa Barbara Santa Barbara, California
More informationHigh-resolution rotational analysis of HDS: 2m 3, m 2 +2m 3,3m 3, and m 2 +3m 3 bands
Journal of Molecular Spectroscopy 232 (2005) 279 290 www.elsevier.com/locate/jms High-resolution rotational analysis of HDS: 2m 3, m 2 +2m 3,3m 3, and m 2 +3m 3 bands A.-W. Liu a, B. Gao a, G.-S. Cheng
More informationGEISA Release of updated database and way forward
GEISA Release of updated database and way forward N. Jacquinet, R. Armante N.A. Scott, A. Chédin, L. Crépeau, C. Boutammine, A. Bouhdaoui, C. Crevoisier, V. Capelle GEISA: Gestion et Etude des Informations
More informationCharacterization of the HCl-HBr-HI gas absorption cell for GIANO- TNG
Characterization of the HCl-HBr-HI gas absorption cell for GIANO- TNG Francesco D'Amato a, Silvia Viciani a, Ernesto Oliva *b, Livia Origlia c, Iacopo Mochi b a CNR Istituto Nazionale di Ottica Applicata,
More informationE. V. Karlovets ab, A. Campargue a*, D. Mondelain a, S. Kassi a, S. A. Tashkun b, V. I. Perevalov b
High sensitivity Cavity Ring Down spectroscopy of 18 O enriched carbon dioxide between 5850 and 7000 cm -1 : III. Analysis and theoretical modelling of the 12 C 17 O 2, 16 O 12 C 17 O, 17 O 12 C 18 O,
More informationIsotopic effect of Cl + 2 rovibronic spectra in the A X system
Vol 18 No 7, July 009 c 009 Chin. Phys. Soc. 1674-1056/009/1807)/74-05 Chinese Physics B and IOP Publishing Ltd Isotopic effect of Cl + rovibronic spectra in the A X system Wu Ling ) a)c), Yang Xiao-Hua
More informationMedium resolution transmission measurements of water vapor at high temperature
Medium resolution transmission measurements of water vapor at high temperature Sudarshan P. Bharadwaj, Michael F. Modest and Robert J. Riazzi Department of Mechanical and Nuclear Engineering The Pennsylvania
More informationInfrared and Microwave Spectra and Force Field of DBO: The Coriolis Interaction between the 1 and 2 3 States
JOURNAL OF MOLECULAR SPECTROSCOPY 192, 152 161 (1998) ARTICLE NO. MS987633 Infrared and Microwave Spectra and Force Field of DBO: The Coriolis Interaction between the 1 and 2 3 States Yoshiyuki Kawashima,*
More informationGeo-fit approach to the analysis of limb-scanning satellite measurements
Geo-fit approach to the analysis of limb-scanning satellite measurements Massimo Carlotti, Bianca Maria Dinelli, Piera Raspollini, and Marco Ridolfi We propose a new approach to the analysis of limb-scanning
More informationHigh Resolution Reference Solar Spectrum for TEMPO/GEMS and beyond
High Resolution Reference Solar Spectrum for TEMPO/GEMS and beyond Mina Kang 1, Myoung-Hwan Ahn 1, Xiong Liu 2, Kelly Chance 2, Kang Sun 2, and Jhoon Kim 3 [1] Department of Atmospheric Science and Engineering,
More informationCLOUD DETECTION AND DISTRIBUTIONS FROM MIPAS INFRA-RED LIMB OBSERVATIONS
CLOUD DETECTION AND DISTRIBUTIONS FROM MIPAS INFRA-RED LIMB OBSERVATIONS J. Greenhough, J. J. Remedios, and H. Sembhi EOS, Space Research Centre, Department of Physics & Astronomy, University of Leicester,
More informationAppendix IV: Spectroscopy of polyatomic molecules. Determination of the. rotational constants.
1 Appendix IV: Spectroscopy of polyatomic molecules. Determination of the rotational constants. IV.1. Glossary of expressions and notations used in spectroscopy IV.2. Selection rules IV.2.1 Electric dipole
More informationMODELING OF NO AND OH INFRARED RADIATION ON A CONVERGENT-DIVERGENT NOZZLE
28 TH INTERNATIONAL CONGRESS OF THE AERONAUTICAL SCIENCES MODELING OF NO AND OH INFRARED RADIATION ON A CONVERGENT-DIVERGENT NOZZLE Hyun Jae Nam, Jae Won Kim and Oh Joon Kwon* Korea Advanced Institute
More informationNew and improved infrared absorption cross sections for trichlorofluoromethane (CFC-11)
Atmos. Meas. Tech., 11, 5827 5836, 2018 https://doi.org/10.5194/amt-11-5827-2018 Author(s) 2018. This work is distributed under the Creative Commons Attribution 4.0 License. New and improved infrared absorption
More informationHigh Sensitivity Gas Sensor Based on IR Spectroscopy Technology and Application
PHOTONIC SENSORS / Vol. 6, No. 2, 2016: 127 131 High Sensitivity Gas Sensor Based on IR Spectroscopy Technology and Application Hengyi LI Department of Electronic Information Engineering, Jincheng College
More informationMagnetic Spin-Torsion Coupling in Methanol
Magnetic pin-torsion Coupling in Methanol L. H. Coudert, 1 C. Gutle, 1 T. R. Huet, 2 and Jens-Uwe Grabow 3 1 Laboratoire Interuniveristaire des ystèmes Atmosphériques, UMR 7583 CNR - Universités Paris
More information