NAME: SECOND EXAMINATION

Save this PDF as:

Size: px
Start display at page:

Download "NAME: SECOND EXAMINATION"

Transcription

1 1 Chemistry 64 Winter 1994 NAME: SECOND EXAMINATION THIS EXAMINATION IS WORTH 100 POINTS AND CONTAINS 4 (FOUR) QUESTIONS THEY ARE NOT EQUALLY WEIGHTED! YOU SHOULD ATTEMPT ALL QUESTIONS AND ALLOCATE YOUR TIME ACCORDINGLY ALL BOOKS AND PAPERS OTHER THAN TABLES WHICH HAVE BEEN HANDED OUT SHOULD BE PLACED ON THE FLOOR DURING THIS EXAMINATION IF YOU DO WORK ANYWHERE OTHER THAN THE SPACE PROVIDED FOR EACH QUESTION, INDICATE CLEARLY WHERE IT IS LOCATED The Periodic Table is provided as detachable Supplementary Material at the back of this exam. The Spectrochemical Series and Magnetic Moment information is provided below. Spectrochemical Series Increasing o (fixed metal): I < Br < Cl ~ SCN ~ N 3 < F < OH < CH 3 CO 2 < oxalate 2 < H 2 O < NCS < EDTA 4 < NH 3 ~ py < en ~ tren < o phen < NO 2 < H ~ CH 3 < CO ~ CN Spin-only formula: µ s = 2{S(S+1)} 1/2 BM = {n(n+2)} 1/2 BM Abbreviations: Me = methyl; t-bu = tert-butyl; dppe = 1,2-bis(diphenylphosphino)ethane; phen = 1,10-phenanthroline; en = ethylenediamine

2 2 FOR GRADING USE ONLY Question 1 (33 pts)... Question 2 (24 pts)... Question 3 (33 pts)... Question 4 (10 pts)... TOTAL (100 pts)...===========

3 3 Question 1 (33 pts) The reaction of BH 3 and CO gives the compound H 3 B-CO. (a) (4 pts) Identify the Lewis acid in this reaction and sketch its LUMO. (b) (4 pts) Identify the Lewis base in this reaction and sketch its HOMO. (c) (4 pts) Sketch the geometry at the boron atom in BH 3 and in the BH 3 -CO molecule. (d) (4 pts) Describe the energetic changes associated with the above changes in the geometry at boron.

4 4 (e) (4 pts) Explain why compound A is a stronger Brønsted base than is compound B, but is a weaker Lewis base towards BMe 3 than is compound B. Me N A N B (f) (4 pts) Explain why Me 3 B is a stronger Lewis acid than BCl 3 towards NMe 3.

5 5 (g) (9 pts) Predict whether the equilibrium constants for the following reactions are greater than or less than 1. Explain your answers. (i) (t-bu) 3 In-PMe 3 + Me 3 In Me 3 In-PMe 3 + (t-bu) 3 In (ii) HgF 2 + BeI 2 HgI 2 + BeF 2 (iii) GaH 3 -NMe 3 + BF 3 Me 3 N-BF 3 + GaH 3

6 6 Question 2 (24 pts) (a) (4 pts) The reaction of palladium(ii) with sources of chloride and ammonia ligands gives 2 compounds, whose empirical formulas are: A: PdCl 2 3NH 3 B: PdCl 2 KCl NH 3 Compounds A and B both contain ions, but only A reacts with Ag + to give a precipitate. IR spectroscopy shows that both palladium containing ions belong to the C 2v point group. Draw the structures of A and B. (b) (6 pts) Similarly, it is possible to make a series of compounds each of which has the empirical formula PdCl 2 2NH 3, as 3 isomers C, D, and E. Isomers C and D do not contain ions, but C has a molecular dipole moment and D has none. C belongs to the point group C 2v and D to the point group D 2h. Isomer E has a molecular weight twice the empirical formula weight, and contains two ions of equal but opposite charge, each of which belongs to the point group D 4h. Draw the structures of C, D, and E.

7 7 (c) (4 pts) The complex [Co(dppe) 2 Cl]+ can be isolated in two different crystalline forms, one red and the other green. Suggest possible structures for these 2 isomers (you do not have to explain the colors). (d) (4 pts) The compound Ni(en) 2 Cl 2 exists in two forms. Form A is yellow and diamagnetic, and gives a precipitate on treatment with Ag +. Form B is blue, paramagnetic, and does not give a precipitate on treatment with Ag +. Suggest structures for A and B, and explain your answers (again, you need not explain the colors).

8 (e) (6 pts) Assuming an octahedral geometry, sketch all the possible isomers (including enantiomers if appropriate) of [Co(NH 3 ) 2 (H 2 O) 2 Cl 2 ] +. Be sure to indicate how many isomers there are. 8

9 9 QUESTION 3 (33 pts) (a) (6 pts) Consider a tetragonal distortion (elongating the 2 M-L bonds along the z-axis) of the octahedral metal complex ML 6 shown below. Tetragonal distortion L L L M L L L z y x (i) Give the crystal field splitting of the metal d-orbitals in the original octahedral compound. Explain your answer. (ii) Show how this splitting pattern is changed by the tetragonal distortion. Explain your answer.

10 10 (b) (3 pts) At high temperatures, the complex Fe(phen) 2 (NCS) 2 shows a magnetic moment consistent with the presence of 4 unpaired electrons. When the compound is cooled to 175 K, however, the magnetic moment suddenly decreases and approaches zero. Explain these observations.

11 11 (c) (8 pts) Spinels are crystalline inorganic compounds of the formula AB 2 O 4, where A is a metal in the +2 oxidation state and B is a metal in the +3 oxidation state. Spinels adopt 2 different possible structures: In normal spinels the A(II) ions are tetrahedrally coordinated by the oxygen ligands, while the B(III) ions are octahedrally coordinated. In inverse spinels, however, the A(II) ions are octahedral, while the B(III) ions are equally divided between octahedral and tetrahedral coordination geometries. The compound NiFe 2 O 4 adopts the inverse spinel structure. Rationalize this observation. (HINT--LFSE).

12 12 (d) (16 pts) Give the metal oxidation state, the d n electron configuration, the LFSE, and the spin-only magnetic moment for each of the following compounds. If you assume that a particular complex is high or low spin, explain your reasoning. (i) [Co(H 2 O) 6 ] 3+ (ii) [Mn(H 2 O) 6 ] 2+ (iii) [CoCl 4 ] 2 (iv) [V(CO) 6 ]

13 13 QUESTION 4 (10 pts) Part of the molecular orbital diagram for an octahedral metal complex ML 6 (where L is a σ-only donor ligand) is shown below. e g t 2g o (a) Identify the MO's shown as bonding, non-bonding, or antibonding. (b) What changes in the diagram would occur if : (1) The ligands were π-acceptors (2) The ligands were π-donors Your answer should consider both (i) the nature of the MO's, as in part (a) above, and (ii) the magnitude of o, and should include an explanation for these results.

14 14 DETACHABLE, HANDY DANDY PERIODIC TABLE OF THE ELEMENTS 1 H Li Na K Rb Cs Fr 87 (223) Be Mg Ca Sr Ba Ra Sc Y La Ac Ti Zr Hf Unq (261) V Nb Ta (262) Unp Cr Mo W Unh (263) 25 Mn Tc (98) Re Uns (262) Fe Ru Os Uno (265) 27 Co Rh Ir Une (266) 28 Ni Pd Pt Cu Ag Au Zn Cd Hg B Al Ga In Tl C 6 N Si P Ge As Sn Sb Pb Bi O Se Te Po 84 (209) S F 9 2 He Ne Cl Ar Br I At (210) 85 Kr Xe Rn (222) Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho (145) Th Pa U Np Pu Am Cm Bk Cf Es Er Tm Yb Lu Fm Md No Lr (237) (244) (243) (247) (247) (251) (252) (257) (258) (259) (260)

15 15

16 16

17 17

18 18

19 19

20 20

21 21

22 22

NAME: FIRST EXAMINATION

NAME: FIRST EXAMINATION 1 Chemistry 64 Winter 1994 NAME: FIRST EXAMINATION THIS EXAMINATION IS WORTH 100 POINTS AND CONTAINS 4 (FOUR) QUESTIONS THEY ARE NOT EQUALLY WEIGHTED! YOU SHOULD ATTEMPT ALL QUESTIONS AND ALLOCATE YOUR

More information

The Periodic Table. Periodic Properties. Can you explain this graph? Valence Electrons. Valence Electrons. Paramagnetism

The Periodic Table. Periodic Properties. Can you explain this graph? Valence Electrons. Valence Electrons. Paramagnetism Periodic Properties Atomic & Ionic Radius Energy Electron Affinity We want to understand the variations in these properties in terms of electron configurations. The Periodic Table Elements in a column

More information

NAME: 3rd (final) EXAM

NAME: 3rd (final) EXAM 1 Chem 64 Winter 2003 AME: 3rd (final) EXAM THIS EXAM IS WORTH 100 POITS AD COTAIS 9 QUESTIOS THEY ARE OT EQUALLY WEIGHTED! YOU SHOULD ATTEMPT ALL QUESTIOS AD ALLOCATE YOUR TIME ACCORDIGLY IF YOU DO'T

More information

Ch. 9 NOTES ~ Chemical Bonding NOTE: Vocabulary terms are in boldface and underlined. Supporting details are in italics.

Ch. 9 NOTES ~ Chemical Bonding NOTE: Vocabulary terms are in boldface and underlined. Supporting details are in italics. Ch. 9 NOTES ~ Chemical Bonding NOTE: Vocabulary terms are in boldface and underlined. Supporting details are in italics. I. Review: Comparison of ionic and molecular compounds Molecular compounds Ionic

More information

CHEM 130 Exp. 8: Molecular Models

CHEM 130 Exp. 8: Molecular Models CHEM 130 Exp. 8: Molecular Models In this lab, we will learn and practice predicting molecular structures from molecular formulas. The Periodic Table of the Elements IA 1 H IIA IIIA IVA VA VIA VIIA 3 5

More information

Guide to the Extended Step-Pyramid Periodic Table

Guide to the Extended Step-Pyramid Periodic Table Guide to the Extended Step-Pyramid Periodic Table William B. Jensen Department of Chemistry University of Cincinnati Cincinnati, OH 452201-0172 The extended step-pyramid table recognizes that elements

More information

Last 4 Digits of USC ID:

Last 4 Digits of USC ID: Chemistry 05 B Practice Exam Dr. Jessica Parr First Letter of last Name PLEASE PRINT YOUR NAME IN BLOCK LETTERS Name: Last 4 Digits of USC ID: Lab TA s Name: Question Points Score Grader 8 2 4 3 9 4 0

More information

CHEM 10113, Quiz 5 October 26, 2011

CHEM 10113, Quiz 5 October 26, 2011 CHEM 10113, Quiz 5 October 26, 2011 Name (please print) All equations must be balanced and show phases for full credit. Significant figures count, show charges as appropriate, and please box your answers!

More information

Lab Day and Time: Instructions. 1. Do not open the exam until you are told to start.

Lab Day and Time: Instructions. 1. Do not open the exam until you are told to start. Name: Lab Day and Time: Instructions 1. Do not open the exam until you are told to start. 2. This exam is closed note and closed book. You are not allowed to use any outside material while taking this

More information

Circle the letters only. NO ANSWERS in the Columns!

Circle the letters only. NO ANSWERS in the Columns! Chemistry 1304.001 Name (please print) Exam 5 (100 points) April 18, 2018 On my honor, I have neither given nor received unauthorized aid on this exam. Signed Date Circle the letters only. NO ANSWERS in

More information

Circle the letters only. NO ANSWERS in the Columns! (3 points each)

Circle the letters only. NO ANSWERS in the Columns! (3 points each) Chemistry 1304.001 Name (please print) Exam 4 (100 points) April 12, 2017 On my honor, I have neither given nor received unauthorized aid on this exam. Signed Date Circle the letters only. NO ANSWERS in

More information

Solutions and Ions. Pure Substances

Solutions and Ions. Pure Substances Class #4 Solutions and Ions CHEM 107 L.S. Brown Texas A&M University Pure Substances Pure substance: described completely by a single chemical formula Fixed composition 1 Mixtures Combination of 2 or more

More information

02/05/09 Last 4 Digits of USC ID: Dr. Jessica Parr

02/05/09 Last 4 Digits of USC ID: Dr. Jessica Parr Chemistry 05 B First Letter of PLEASE PRINT YOUR NAME IN BLOCK LETTERS Exam last Name Name: 02/05/09 Last 4 Digits of USC ID: Dr. Jessica Parr Lab TA s Name: Question Points Score Grader 2 2 9 3 9 4 2

More information

M11/4/CHEMI/SPM/ENG/TZ2/XX CHEMISTRY STANDARD LEVEL PAPER 1. Monday 9 May 2011 (afternoon) 45 minutes INSTRUCTIONS TO CANDIDATES

M11/4/CHEMI/SPM/ENG/TZ2/XX CHEMISTRY STANDARD LEVEL PAPER 1. Monday 9 May 2011 (afternoon) 45 minutes INSTRUCTIONS TO CANDIDATES M11/4/CHEMI/SPM/ENG/TZ/XX 116116 CHEMISTRY STANDARD LEVEL PAPER 1 Monday 9 May 011 (afternoon) 45 minutes INSTRUCTIONS TO CANDIDATES Do not open this examination paper until instructed to do so. Answer

More information

610B Final Exam Cover Page

610B Final Exam Cover Page 1 st Letter of Last Name NAME: 610B Final Exam Cover Page No notes or calculators of any sort allowed. You have 3 hours to complete the exam. CHEM 610B, 50995 Final Exam Fall 2003 Instructor: Dr. Brian

More information

Lab Day and Time: Instructions. 1. Do not open the exam until you are told to start.

Lab Day and Time: Instructions. 1. Do not open the exam until you are told to start. Name: Lab Day and Time: Instructions 1. Do not open the exam until you are told to start. 2. This exam is closed note and closed book. You are not allowed to use any outside material while taking this

More information

Radiometric Dating (tap anywhere)

Radiometric Dating (tap anywhere) Radiometric Dating (tap anywhere) Protons Neutrons Electrons Elements on the periodic table are STABLE Elements can have radioactive versions of itself called ISOTOPES!! Page 1 in your ESRT has your list!

More information

M10/4/CHEMI/SPM/ENG/TZ2/XX+ CHEMISTRY. Wednesday 12 May 2010 (afternoon) 45 minutes INSTRUCTIONS TO CANDIDATES

M10/4/CHEMI/SPM/ENG/TZ2/XX+ CHEMISTRY. Wednesday 12 May 2010 (afternoon) 45 minutes INSTRUCTIONS TO CANDIDATES M10/4/CHEMI/SPM/ENG/TZ/XX+ 106116 CHEMISTRY standard level Paper 1 Wednesday 1 May 010 (afternoon) 45 minutes INSTRUCTIONS TO CANDIDATES Do not open this examination paper until instructed to do so. Answer

More information

PERIODIC TABLE OF THE ELEMENTS

PERIODIC TABLE OF THE ELEMENTS Useful Constants and equations: K = o C + 273 Avogadro's number = 6.022 x 10 23 d = density = mass/volume R H = 2.178 x 10-18 J c = E = h = hc/ h = 6.626 x 10-34 J s c = 2.998 x 10 8 m/s E n = -R H Z 2

More information

If anything confuses you or is not clear, raise your hand and ask!

If anything confuses you or is not clear, raise your hand and ask! CHM 1045 Dr. Light s Section December 10, 2002 FINAL EXAM Name (please print) Recitation Section Meeting Time This exam consists of six pages. Make sure you have one of each. Print your name at the top

More information

8. Relax and do well.

8. Relax and do well. CHEM 1515 Exam II John II. Gelder October 14, 1993 Name TA's Name Lab Section INSTRUCTIONS: 1. This examination consists of a total of 8 different pages. The last two pages include a periodic table, a

More information

Element Cube Project (x2)

Element Cube Project (x2) Element Cube Project (x2) Background: As a class, we will construct a three dimensional periodic table by each student selecting two elements in which you will need to create an element cube. Helpful Links

More information

CLASS TEST GRADE 11. PHYSICAL SCIENCES: CHEMISTRY Test 4: Matter and materials 1

CLASS TEST GRADE 11. PHYSICAL SCIENCES: CHEMISTRY Test 4: Matter and materials 1 CLASS TEST GRADE PHYSICAL SCIENCES: CHEMISTRY Test 4: Matter and materials MARKS: 45 TIME: hour INSTRUCTIONS AND INFORMATION. Answer ALL the questions. 2. You may use non-programmable calculators. 3. You

More information

Modified from: Larry Scheffler Lincoln High School IB Chemistry 1-2.1

Modified from: Larry Scheffler Lincoln High School IB Chemistry 1-2.1 Modified from: Larry Scheffler Lincoln High School IB Chemistry 1-2.1 The development of the periodic table brought a system of order to what was otherwise an collection of thousands of pieces of information.

More information

Chapter 3: Stoichiometry

Chapter 3: Stoichiometry Chapter 3: Stoichiometry Chem 6A Michael J. Sailor, UC San Diego 1 Announcements: Thursday (Sep 29) quiz: Bring student ID or we cannot accept your quiz! No notes, no calculators Covers chapters 1 and

More information

Atoms and the Periodic Table

Atoms and the Periodic Table Atoms and the Periodic Table Parts of the Atom Proton Found in the nucleus Number of protons defines the element Charge +1, mass 1 Parts of the Atom Neutron Found in the nucleus Stabilizes the nucleus

More information

CHEM 167 FINAL EXAM MONDAY, MAY 2 9:45 11:45 A.M GILMAN HALL

CHEM 167 FINAL EXAM MONDAY, MAY 2 9:45 11:45 A.M GILMAN HALL PROF. JOHN VERKADE SPRING 2005 THIS EXAM CONSISTS OF 12 QUESTIONS ON 9 PAGES CHEM 167 HOUR EXAM IV APRIL 20, 2005 SEAT NO. NAME RECIT. INSTR. RECIT. SECT. GRADING PAGE Page 2 Page 3 Page 4 Page 5 Page

More information

Made the FIRST periodic table

Made the FIRST periodic table Made the FIRST periodic table 1869 Mendeleev organized the periodic table based on the similar properties and relativities of certain elements Later, Henri Moseley organized the elements by increasing

More information

8. Relax and do well.

8. Relax and do well. CHEM 1225 Exam I John I. Gelder February 4, 1999 Name KEY TA's Name Lab Section Please sign your name below to give permission to post your course scores on homework, laboratories and exams. If you do

More information

Faculty of Natural and Agricultural Sciences Chemistry Department. Semester Test 1. Analytical Chemistry CMY 283. Time: 120 min Marks: 100 Pages: 6

Faculty of Natural and Agricultural Sciences Chemistry Department. Semester Test 1. Analytical Chemistry CMY 283. Time: 120 min Marks: 100 Pages: 6 Faculty of Natural and Agricultural Sciences Chemistry Department Semester Test 1 Analytical Chemistry CMY 283 Date: 5 September 2016 Lecturers : Prof P Forbes, Dr Laurens, Mr SA Nsibande Time: 120 min

More information

5 questions, 3 points each, 15 points total possible. 26 Fe Cu Ni Co Pd Ag Ru 101.

5 questions, 3 points each, 15 points total possible. 26 Fe Cu Ni Co Pd Ag Ru 101. Physical Chemistry II Lab CHEM 4644 spring 2017 final exam KEY 5 questions, 3 points each, 15 points total possible h = 6.626 10-34 J s c = 3.00 10 8 m/s 1 GHz = 10 9 s -1. B= h 8π 2 I ν= 1 2 π k μ 6 P

More information

(please print) (1) (18) H IIA IIIA IVA VA VIA VIIA He (2) (13) (14) (15) (16) (17)

(please print) (1) (18) H IIA IIIA IVA VA VIA VIIA He (2) (13) (14) (15) (16) (17) CHEM 10113, Quiz 3 September 28, 2011 Name (please print) All equations must be balanced and show phases for full credit. Significant figures count, show charges as appropriate, and please box your answers!

More information

8. Relax and do well.

8. Relax and do well. CHEM 1215 Exam III John III. Gelder November 11, 1998 Name TA's Name Lab Section INSTRUCTIONS: 1. This examination consists of a total of 7 different pages. The last page includes a periodic table and

More information

7. Relax and do well.

7. Relax and do well. CHEM 1014 Exam III John III. Gelder November 18, 1999 Name TA's Name Lab Section INSTRUCTIONS: 1. This examination consists of a total of 7 different pages. The last page includes a periodic table and

More information

The Periodic Table of Elements

The Periodic Table of Elements The Periodic Table of Elements 8 Uuo Uus Uuh (9) Uup (88) Uuq (89) Uut (8) Uub (8) Rg () 0 Ds (9) 09 Mt (8) 08 Hs (9) 0 h () 0 Sg () 0 Db () 0 Rf () 0 Lr () 88 Ra () 8 Fr () 8 Rn () 8 At (0) 8 Po (09)

More information

Marks for each question are as indicated in [] brackets.

Marks for each question are as indicated in [] brackets. Name Student Number CHEMISTRY 140 FINAL EXAM December 10, 2002 Numerical answers must be given with appropriate units and significant figures. Please place all answers in the space provided for the question.

More information

The exam must be written in ink. No calculators of any sort allowed. You have 2 hours to complete the exam. Periodic table 7 0

The exam must be written in ink. No calculators of any sort allowed. You have 2 hours to complete the exam. Periodic table 7 0 Email: The exam must be written in ink. No calculators of any sort allowed. You have 2 hours to complete the exam. CEM 610B Exam 3 Spring 2002 Instructor: Dr. Brian Pagenkopf Page Points 2 6 3 7 4 9 5

More information

INSTRUCTIONS: Exam III. November 10, 1999 Lab Section

INSTRUCTIONS: Exam III. November 10, 1999 Lab Section CHEM 1215 Exam III John III. Gelder November 10, 1999 Name TA's Name Lab Section INSTRUCTIONS: 1. This examination consists of a total of 7 different pages. The last page includes a periodic table and

More information

Nucleus. Electron Cloud

Nucleus. Electron Cloud Atomic Structure I. Picture of an Atom Nucleus Electron Cloud II. Subatomic particles Particle Symbol Charge Relative Mass (amu) protons p + +1 1.0073 neutrons n 0 1.0087 electrons e - -1 0.00054858 Compare

More information

Chemistry Standard level Paper 1

Chemistry Standard level Paper 1 M15/4/CHEMI/SPM/ENG/TZ1/XX Chemistry Standard level Paper 1 Thursday 14 May 2015 (afternoon) 45 minutes Instructions to candidates Do not open this examination paper until instructed to do so. Answer all

More information

7. Relax and do well.

7. Relax and do well. CHEM 1215 Exam II John II. Gelder October 7, 1998 Name TA's Name Lab Section INSTRUCTIONS: 1. This examination consists of a total of 5 different pages. The last page includes a periodic table and a solubility

More information

Lab Day and Time: Instructions. 1. Do not open the exam until you are told to start.

Lab Day and Time: Instructions. 1. Do not open the exam until you are told to start. Name: Lab Day and Time: Instructions 1. Do not open the exam until you are told to start. 2. This exam is closed note and closed book. You are not allowed to use any outside material while taking this

More information

Speed of light c = m/s. x n e a x d x = 1. 2 n+1 a n π a. He Li Ne Na Ar K Ni 58.

Speed of light c = m/s. x n e a x d x = 1. 2 n+1 a n π a. He Li Ne Na Ar K Ni 58. Physical Chemistry II Test Name: KEY CHEM 464 Spring 18 Chapters 7-11 Average = 1. / 16 6 questions worth a total of 16 points Planck's constant h = 6.63 1-34 J s Speed of light c = 3. 1 8 m/s ħ = h π

More information

K. 27 Co. 28 Ni. 29 Cu Rb. 46 Pd. 45 Rh. 47 Ag Cs Ir. 78 Pt.

K. 27 Co. 28 Ni. 29 Cu Rb. 46 Pd. 45 Rh. 47 Ag Cs Ir. 78 Pt. 1 IA 1 ydrogen 1.01 Atomic number Element symbol Element name Atomic mass VIIIA 1 1.01 IIA IIIA IVA VA VIA VIIA 2 e 4.00 Metalloids 3 Li 6.94 4 Be 9.01 5 B 10.81 6 C 12.01 7 N 14.01 8 O 16.00 9 F 19.00

More information

CHEM Come to the PASS workshop with your mock exam complete. During the workshop you can work with other students to review your work.

CHEM Come to the PASS workshop with your mock exam complete. During the workshop you can work with other students to review your work. It is most beneficial to you to write this mock midterm UNDER EXAM CONDITIONS. This means: Complete the midterm in 1.5 hours. Work on your own. Keep your notes and textbook closed. Attempt every question.

More information

8. Relax and do well.

8. Relax and do well. CHEM 1314 3;30 pm Theory Exam III John III. Gelder November 13, 2002 Name TA's Name Lab Section INSTRUCTIONS: 1. This examination consists of a total of 8 different pages. The last page include a periodic

More information

MANY ELECTRON ATOMS Chapter 15

MANY ELECTRON ATOMS Chapter 15 MANY ELECTRON ATOMS Chapter 15 Electron-Electron Repulsions (15.5-15.9) The hydrogen atom Schrödinger equation is exactly solvable yielding the wavefunctions and orbitals of chemistry. Howev er, the Schrödinger

More information

(C) Pavel Sedach and Prep101 1

(C) Pavel Sedach and Prep101 1 (C) Pavel Sedach and Prep101 1 (C) Pavel Sedach and Prep101 1 (C) Pavel Sedach and Prep101 2 (C) Pavel Sedach and Prep101 2 (C) Pavel Sedach and Prep101 3 (C) Pavel Sedach and Prep101 3 (C) Pavel Sedach

More information

Chemistry 431 Practice Final Exam Fall Hours

Chemistry 431 Practice Final Exam Fall Hours Chemistry 431 Practice Final Exam Fall 2018 3 Hours R =8.3144 J mol 1 K 1 R=.0821 L atm mol 1 K 1 R=.08314 L bar mol 1 K 1 k=1.381 10 23 J molecule 1 K 1 h=6.626 10 34 Js N A = 6.022 10 23 molecules mol

More information

CHEM 107 (Spring-2005) Exam 3 (100 pts)

CHEM 107 (Spring-2005) Exam 3 (100 pts) CHEM 107 (Spring-2005) Exam 3 (100 pts) Name: ------------------------------------------------------------------------, Clid # ------------------------------ LAST NAME, First (Circle the alphabet segment

More information

8. Relax and do well.

8. Relax and do well. CHEM 15 Exam II John II. Gelder March 4, 1999 Name TA's Name Lab Section INSTRUCTIONS: 1. This examination consists of a total of 7 different pages. The last two pages includes a periodic table, a solubility

More information

Transition Metals and Coordination Chemistry

Transition Metals and Coordination Chemistry Transition Metals and Coordination Chemistry Transition Metals Similarities within a given period and within a given group. Last electrons added are inner electrons (d s, f s). 20_431 Ce Th Pr Pa d U

More information

CHEM 172 EXAMINATION 1. January 15, 2009

CHEM 172 EXAMINATION 1. January 15, 2009 CHEM 17 EXAMINATION 1 January 15, 009 Dr. Kimberly M. Broekemeier NAME: Circle lecture time: 9:00 11:00 Constants: c = 3.00 X 10 8 m/s h = 6.63 X 10-34 J x s J = kg x m /s Rydberg Constant = 1.096776 x

More information

CHEM 10123/10125, Exam 2

CHEM 10123/10125, Exam 2 CHEM 10123/10125, Exam 2 March 7, 2012 (50 minutes) Name (please print) Please box your answers, and remember that significant figures, phases (for chemical equations), and units do count! 1. (13 points)

More information

Lab Day and Time: Instructions. 1. Do not open the exam until you are told to start.

Lab Day and Time: Instructions. 1. Do not open the exam until you are told to start. Name: Lab Day and Time: Instructions 1. Do not open the exam until you are told to start. 2. This exam is closed note and closed book. You are not allowed to use any outside material while taking this

More information

BROOKLYN COLLEGE Department of Chemistry. Chemistry 1 Second Lecture Exam Nov. 27, Name Page 1 of 5

BROOKLYN COLLEGE Department of Chemistry. Chemistry 1 Second Lecture Exam Nov. 27, Name Page 1 of 5 BROOKLYN COLLEGE Department of Chemistry Chemistry 1 Second Lecture Exam Nov. 27, 2002 Name Page 1 of 5 Circle the name of your lab instructor Kobrak, Zhou, Girotto, Hussey, Du Before you begin the exam,

More information

Instructions. 1. Do not open the exam until you are told to start.

Instructions. 1. Do not open the exam until you are told to start. Name: Lab Day and Time: Instructions 1. Do not open the exam until you are told to start. 2. This exam is closed note and closed book. You are not allowed to use any outside material while taking this

More information

PHYSICAL SCIENCES GRADE : 10

PHYSICAL SCIENCES GRADE : 10 PHYSICAL SCIENCES GRADE : 0 TIME : hour TOTAL : 75 INSTRUCTIONS AND INFORMATION. Write your full name on your answer book in the appropriate place. 2. The question paper consists of SEVEN questions. Answer

More information

Chemistry Standard level Paper 1

Chemistry Standard level Paper 1 Chemistry Standard level Paper 1 Thursday 12 May 2016 (morning) 45 minutes Instructions to candidates Do not open this examination paper until instructed to do so. Answer all the questions. For each question,

More information

Atomic Structure & Interatomic Bonding

Atomic Structure & Interatomic Bonding Atomic Structure & Interatomic Bonding Chapter Outline Review of Atomic Structure Atomic Bonding Atomic Structure Atoms are the smallest structural units of all solids, liquids & gases. Atom: The smallest

More information

Faculty of Natural and Agricultural Sciences Chemistry Department. Semester Test 1 MEMO. Analytical Chemistry CMY 283

Faculty of Natural and Agricultural Sciences Chemistry Department. Semester Test 1 MEMO. Analytical Chemistry CMY 283 Faculty of Natural and Agricultural Sciences Chemistry Department Semester Test 1 MEMO Analytical Chemistry CMY 283 Date: 5 September 2016 Lecturers : Prof P Forbes, Dr Laurens, Mr SA Nsibande Time: 90

More information

CHEM 108 (Spring-2008) Exam. 3 (105 pts)

CHEM 108 (Spring-2008) Exam. 3 (105 pts) CHEM 08 (Spring-008) Exam. (05 pts) Name: --------------------------------------------------------------------------, CLID # -------------------------------- LAST NAME, First (Circle the alphabet segment

More information

lectures accompanying the book: Solid State Physics: An Introduction, by Philip ofmann (2nd edition 2015, ISBN-10: 3527412824, ISBN-13: 978-3527412822, Wiley-VC Berlin. www.philiphofmann.net 1 Bonds between

More information

PART 1 Introduction to Theory of Solids

PART 1 Introduction to Theory of Solids Elsevier UK Job code: MIOC Ch01-I044647 9-3-2007 3:03p.m. Page:1 Trim:165 240MM TS: Integra, India PART 1 Introduction to Theory of Solids Elsevier UK Job code: MIOC Ch01-I044647 9-3-2007 3:03p.m. Page:2

More information

Chemistry 2 Exam Roane State Academic Festival. Name (print neatly) School

Chemistry 2 Exam Roane State Academic Festival. Name (print neatly) School Name (print neatly) School There are fifteen question on this exam. Each question is weighted equally. n the answer sheet, write your name in the space provided and your answers in the blanks provided.

More information

CHM 101 PRACTICE TEST 1 Page 1 of 4

CHM 101 PRACTICE TEST 1 Page 1 of 4 CHM 101 PRACTICE TEST 1 Page 1 of 4 Please show calculations (stuffed equations) on all mathematical problems!! On the actual test, "naked answers, with no work shown, will receive no credit even if correct.

More information

Lab Day and Time: Instructions. 1. Do not open the exam until you are told to start. Page # Points possible Points awarded

Lab Day and Time: Instructions. 1. Do not open the exam until you are told to start. Page # Points possible Points awarded Name: Lab Day and Time: Instructions 1. Do not open the exam until you are told to start. 2. This exam is closed note and closed book. You are not allowed to use any outside material while taking this

More information

Chem Exam 1. September 26, Dr. Susan E. Bates. Name 9:00 OR 10:00

Chem Exam 1. September 26, Dr. Susan E. Bates. Name 9:00 OR 10:00 Chem 1711 Exam 1 September 26, 2013 Dr. Susan E. Bates Name 9:00 OR 10:00 N A = 6.022 x 10 23 mol 1 I A II A III B IV B V B VI B VII B VIII I B II B III A IV A V A VI A VII A inert gases 1 H 1.008 3 Li

More information

CHEM 251 (Fall-2003) Final Exam (100 pts)

CHEM 251 (Fall-2003) Final Exam (100 pts) CEM 251 (Fall-2003) Final Exam (100 pts) Name: -------------------------------------------------------------------------------, SSN -------------------------------- LAST NAME, First (Circle the alphabet

More information

8. Relax and do well.

8. Relax and do well. CHEM 1225 Exam III John III. Gelder April 8, 1999 Name TA's Name Lab Section INSTRUCTIONS: 1. This examination consists of a total of 7 different pages. The last two pages includes a periodic table and

More information

Using the Periodic Table

Using the Periodic Table MATH SKILLS TRANSPARENCY WORKSHEET Using the Periodic Table 6 Use with Chapter 6, Section 6.2 1. Identify the number of valence electrons in each of the following elements. a. Ne e. O b. K f. Cl c. B g.

More information

Essential Chemistry for Biology

Essential Chemistry for Biology 1 Chapter 2 Essential Chemistry for Biology Biology and Society: More Precious than Gold A drought is a period of abnormally dry weather that changes the environment and one of the most devastating disasters.

More information

7. Relax and do well.

7. Relax and do well. CHEM 1215 Exam II John II. Gelder October 13, 1999 Name TA's Name Lab Section INSTRUCTIONS: 1. This examination consists of a total of 5 different pages. The last page includes a periodic table and a solubility

More information

Chemistry 1 First Lecture Exam Fall Abbasi Khajo Levine Mathias Mathias/Ortiz Metlitsky Rahi Sanchez-Delgado Vasserman

Chemistry 1 First Lecture Exam Fall Abbasi Khajo Levine Mathias Mathias/Ortiz Metlitsky Rahi Sanchez-Delgado Vasserman Chemistry 1 First Lecture Exam Fall 2011 Page 1 of 9 NAME Circle the name of your recitation/lab instructor(s) Abbasi Khajo Levine Mathias Mathias/Ortiz Metlitsky Rahi Sanchez-Delgado Vasserman Before

More information

Why all the repeating Why all the repeating Why all the repeating Why all the repeating

Why all the repeating Why all the repeating Why all the repeating Why all the repeating Why all the repeating Why all the repeating Why all the repeating Why all the repeating Patterns What Patterns have you observed in your life? Where to Get Help If you don t understand concepts in chapter

More information

8. Relax and do well.

8. Relax and do well. CHEM 1314.03 Exam I John I. Gelder September 25, 1997 Name TA's Name Lab Section Please sign your name below to give permission to post, by the last 4 digits of your student I.D. number, your course scores

More information

M14/4/CHEMI/SPM/ENG/TZ1/XX CHEMISTRY. Monday 19 May 2014 (afternoon) 45 minutes INSTRUCTIONS TO CANDIDATES

M14/4/CHEMI/SPM/ENG/TZ1/XX CHEMISTRY. Monday 19 May 2014 (afternoon) 45 minutes INSTRUCTIONS TO CANDIDATES M14/4/CEMI/SPM/ENG/TZ1/XX 22146110 CEMISTRY standard level Paper 1 Monday 19 May 2014 (afternoon) 45 minutes INSTRUCTIONS TO CANDIDATES Do not open this examination paper until instructed to do so. Answer

More information

Chem 6 Sample exam 2 (150 points total) NAME:

Chem 6 Sample exam 2 (150 points total) NAME: hem 6 Sample exam 2 (150 points total) @ This is a closed book exam to which the onor Principle applies. @ The last page contains equations and physical constants; you can detach it for easy reference.

More information

INSTRUCTIONS: 7. Relax and do well.

INSTRUCTIONS: 7. Relax and do well. EM 1314 Name Exam III TA Name John III. Gelder November 16, 1992 Lab Section INSTRUTIONS: 1. This examination consists of a total of 7 different pages. The last page includes a periodic table and some

More information

PHYSICAL SCIENCES MARCH CONTROLLED TEST GRADE

PHYSICAL SCIENCES MARCH CONTROLLED TEST GRADE PHYSICAL SCIENCES MARCH CONTROLLED TEST GRADE 11 018 MARKS : 75 TIME : 1.5 Hrs INSTRUCTIONS AND INFORMATION 1. Write your NAME and CLASS in your ANSWER BOOK.. This question paper consists of SIX questions.

More information

Chem 51, Spring 2015 Exam 8 (Chp 8) Use your Scantron to answer Questions There is only one answer for each Question. Questions are 2 pt each.

Chem 51, Spring 2015 Exam 8 (Chp 8) Use your Scantron to answer Questions There is only one answer for each Question. Questions are 2 pt each. Chem 51, Spring 2015 Exam 8 (Chp 8) Name 120 pt Use your Scantron to answer Questions 1-32. There is only one answer for each Question. Questions are 2 pt each. CHP 8.1 Solutions are Mixtures 1. A saturated

More information

DURATION: 2 HOUR 45 MINUTES

DURATION: 2 HOUR 45 MINUTES 1 Exam 9 Our country, our future 525/1 S6 CHEMISTRY PAPER 1 DURATION: 2 HOUR 45 MINUTES For Marking guide contact and consultations: Dr. Bbosa Science 0776 802709. Answer all question in part I and six

More information

DO NOW: Retrieve your projects. We will be reviewing them again today. Textbook pg 23, answer questions 1-3. Use the section 1.2 to help you.

DO NOW: Retrieve your projects. We will be reviewing them again today. Textbook pg 23, answer questions 1-3. Use the section 1.2 to help you. DO NOW: Retrieve your projects. We will be reviewing them again today. Textbook pg, answer questions. Use the section. to help you. Chapter test is FRIDAY. The Periodic Table of Elements 8 Uuo Uus Uuh

More information

Bonding/Lewis Dots Lecture Page 1 of 12 Date. Bonding. What is Coulomb's Law? Energy Profile: Covalent Bonds. Electronegativity and Linus Pauling

Bonding/Lewis Dots Lecture Page 1 of 12 Date. Bonding. What is Coulomb's Law? Energy Profile: Covalent Bonds. Electronegativity and Linus Pauling Bonding/Lewis Dots Lecture Page 1 of 12 Date Bonding What is Coulomb's Law? Energy Profile: Covalent Bonds Electronegativity and Linus Pauling 2.1 H 1.0 Li 0.9 Na 0.8 K 0.8 Rb 0.7 Cs 0.7 Fr 1.5 Be 1.2

More information

7. Relax and do well.

7. Relax and do well. CHEM 1215 Exam II John II. Gelder October 7, 1998 Name TA's Name Lab Section INSTRUCTIONS: 1. This examination consists of a total of 5 different pages. The last page includes a periodic table and a solubility

More information

Chemistry 185 Exam #2 - A November 5, Lab Day and Time: Instructions. 1. Do not open the exam until you are told to start.

Chemistry 185 Exam #2 - A November 5, Lab Day and Time: Instructions. 1. Do not open the exam until you are told to start. Name: Lab Day and Time: Instructions 1. Do not open the exam until you are told to start. 2. This exam is closed note and closed book. You are not allowed to use any outside material while taking this

More information

Instructions. 1. Do not open the exam until you are told to start.

Instructions. 1. Do not open the exam until you are told to start. Name: Lab Day and Time: Instructions 1. Do not open the exam until you are told to start. 2. This exam is closed note and closed book. You are not allowed to use any outside material while taking this

More information

Fall 2011 CHEM Test 4, Form A

Fall 2011 CHEM Test 4, Form A Fall 2011 CHEM 1110.40413 Test 4, Form A Part I. Multiple Choice: Clearly circle the best answer. (60 pts) Name: 1. The common constituent in all acid solutions is A) H 2 SO 4 B) H 2 C) H + D) OH 2. Which

More information

CHEM 107 (Spring-2004) Exam 2 (100 pts)

CHEM 107 (Spring-2004) Exam 2 (100 pts) CHEM 107 (Spring-2004) Exam 2 (100 pts) Name: ------------------------------------------------------------------------, SSN -------------------------------- LAST NAME, First (Circle the alphabet segment

More information

1 Genesis 1:1. Chapter 10 Matter. Lesson. Genesis 1:1 In the beginning God created the heavens and the earth. (NKJV)

1 Genesis 1:1. Chapter 10 Matter. Lesson. Genesis 1:1 In the beginning God created the heavens and the earth. (NKJV) 1 Genesis 1:1 Genesis 1:1 In the beginning God created the heavens and the earth. (NKJV) 1 Vocabulary Saturated having all the solute that can be dissolved at that temperature Neutron a particle with no

More information

8. Relax and do well.

8. Relax and do well. CHEM 1014 Exam I John I. Gelder September 16, 1999 Name TA's Name Lab Section Please sign your name below to give permission to post your course scores on homework, laboratories and exams. If you do not

More information

Chemistry Higher level Paper 1

Chemistry Higher level Paper 1 N15/4/EMI/PM/ENG/TZ0/XX hemistry igher level Paper 1 Friday 13 November 2015 (afternoon) 1 hour Instructions to candidates Do not open this examination paper until instructed to do so. Answer all the questions.

More information

Part 2. Multiple choice (use answer card). 90 pts. total. 3 pts. each.

Part 2. Multiple choice (use answer card). 90 pts. total. 3 pts. each. 1 Exam I CHEM 1303.001 Name (print legibly) Seat no. On my honor, I have neither given nor received unauthorized aid on this exam. Signed Date Part 1. Nomenclature. 10 pts. total. 2 pts. each. Fill in

More information

M09/4/CHEMI/HPM/ENG/TZ2/XX+ CHEMISTRY. Monday 18 May 2009 (afternoon) 1 hour INSTRUCTIONS TO CANDIDATES

M09/4/CHEMI/HPM/ENG/TZ2/XX+ CHEMISTRY. Monday 18 May 2009 (afternoon) 1 hour INSTRUCTIONS TO CANDIDATES M09/4/CEMI/PM/ENG/TZ/XX+ 096113 CEMISTRY igher level Paper 1 Monday 18 May 009 (afternoon) 1 hour INSTRUCTIONS TO CANDIDATES Do not open this examination paper until instructed to do so. Answer all the

More information

25 Mn Ni Co Rh Fe Ru Os Uns (262) Une (266) 195.

25 Mn Ni Co Rh Fe Ru Os Uns (262) Une (266) 195. 1 Chem 64 Solutions to Problem Set #1, REVIEW 1. AO n l m 1s 1 0 0 2s 2 0 0 2p 2 1 1,0,1 3d 3 2 2, 1,0,1,2 4d 4 2 2, 1,0,1,2 4f 4 3 3, 2, 1,0,1,2,3 2. Penetration relates to the radial probability distribution

More information

UNIVERSITY OF CALGARY FACULTY OF SCIENCE MIDTERM EXAMINATION CHEMISTRY 353 READ ALL THE INSTRUCTIONS CAREFULLY

UNIVERSITY OF CALGARY FACULTY OF SCIENCE MIDTERM EXAMINATION CHEMISTRY 353 READ ALL THE INSTRUCTIONS CAREFULLY WEDNESDAY MARCH 9th, 2016 UNIVERSITY OF CALGARY FACULTY OF SCIENCE MIDTERM EXAMINATION CHEMISTRY 353 Version 1 Time: 2 Hours READ ALL THE INSTRUCTIONS CAREFULLY PLEASE WRITE YOUR NAME, STUDENT I.D. NUMBER

More information

HANDOUT SET GENERAL CHEMISTRY II

HANDOUT SET GENERAL CHEMISTRY II HANDOUT SET GENERAL CHEMISTRY II Periodic Table of the Elements 1 2 3 4 5 6 7 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 IA VIIIA 1 2 H He 1.00794 IIA IIIA IVA VA VIA VIIA 4.00262 3 Li 6.941 11 Na 22.9898

More information

Secondary Support Pack. be introduced to some of the different elements within the periodic table;

Secondary Support Pack. be introduced to some of the different elements within the periodic table; Secondary Support Pack INTRODUCTION The periodic table of the elements is central to chemistry as we know it today and the study of it is a key part of every student s chemical education. By playing the

More information

Atomic Emission Spectra. and. Flame Tests. Burlingame High School Chemistry

Atomic Emission Spectra. and. Flame Tests. Burlingame High School Chemistry Atomic Structure Atomic Emission Spectra and Flame Tests Flame Tests Sodium potassium lithium When electrons are excited they bump up to a higher energy level. As they bounce back down they release energy

More information

INSTRUCTIONS: CHEM Exam I. September 13, 1994 Lab Section

INSTRUCTIONS: CHEM Exam I. September 13, 1994 Lab Section CHEM 1314.05 Exam I John I. Gelder September 13, 1994 Name TA's Name Lab Section Please sign your name below to give permission to post, by the last 4 digits of your student I.D. number, your course scores

More information