Partial molal volume and partial molal compressibility of polyethylene glycol in water
|
|
- Ethan Booth
- 6 years ago
- Views:
Transcription
1 Indian Journal of Chemistry Vol. 41 A, April 02, pp Partial molal volume and partial molal compressibility of polyethylene glycol in water A K Puri, N K Soni*, Amit Pandey & Ashish K Sharma Department of Chemistry, Uni versity of Allahabad, Allahabad , India Received 14 Jllly 00; re vised 31 Jllly 01 Using the ex perimental data of Gerecze [ACIISlica, 38 ( 1977) 51 Ion ultrasonic ve locity, density and refractive index or aqueous polyethylene glycol, the va lues of partial molal volume (<1»'), experimental slope (S v) and partial molal compressibility (<I>KO) at different temperatures, interac tion coefficient (Q ), mo lal volume of Vand's eq uati on at C (V) and mol ar refraction (Rill) have been calculated. Validity of Vand's equati on and molar refraction equation for polyethylene glycol is displayed. Temperature dependence hydrati on nature of polyethylene glyco l has also been di scussed. In recent years, there has been considerable interest in the solute-solvent interactions of dilute solutions of non-electrolytes. Enhanced stabilisation of water structure around the solute molecule in the form of clusters or cages in the ethylene-glycol water system has been discussed by Glew l. Abnormalities in many thermodynamic behaviour including partial molal volume and partial molal compressibility were discussed by Frank and Ives 2. According Hioland 3, parti al molal vo lume (<Pvo) and partial molal compressibility (<PKO) of polyfunctional alcohols having several hydroxy l groups, are capable of hydrogen bonding water molecul e. Adi abatic and isothermal apparent molal compressibilities of secondary alcohols and ethers in water were reported by Cabini4. Viscosity of non-electrolyte solutes in water was anal yzed in the light of Vand 5, Moulik 6 and Thomson 7 equations.. AI exan d er el a, propose d an equation. describe the viscosity B-coefficient for dilute so lutions of non-electrolytes in water. Islam et al. 11 reported B-coefficient and apparent molal volume at infinite dilution (<Pvo) for tetraalkyl halides in ethyl ene gycol-water mixture. RecentlyI 2-16, ultrasoni c velocity, density and viscosity data have been used sati s facrily study various types of interactions in multicomponent systems contammg some very important bio molecules and ions. In the present note, we present the results of calculations of partial molal volume (<Pvo) and parti al molal compressibility (<PK 0), interaction coefficient (Q), molar volume of Vand's equation (V) and molar refraction (Rm) of aqueous polyethylene glycol solutions using the volumetric, ultrasonic, viscometric and refracmetric data of Gerecze l7. Equations used Apparent molal volume, (<Pv), has been calculated using the relation (d o - d) M v = +- m.d o do... (I) where do and d are the density of solvent and soluti on respectively, and other sy mbol s have their usual notation. The apparent molal volume (<Pvo) at infinite dilution has been obtained using equation (2).... (2) Isentropic compressibility, (Ks) has been obtained from sound velocity (u) and density (d) data using the relation: Apparent molal compressibility, (<PK) from the equation:... (3) t S computed... (4) where Ks and Ks.o are the isentropi c compressibility coefficients of solution and solvent respectively. Apparent molal compress ibility at infinite dilution, (<PKO) has been obtained from ex pression,... (5) Refractive index data have been used for obtaining the mol ar refraction (Rill) using the relation 2 2 RIll=(no - lin D + I) + Mid... (6) where no is the index of refraction (sodium D line) and M is the molec ul ar of polyethylene glyco l.
2 752 INDIAN J CHEM, SEC A, APRIL 02 Table I-Apparent molal volume, (<I>v), apparent molal compressibility, (<I>K), and isentropic compressibility, (f3s), of polyethylene glycol in water at, and C <l>v x 10 3 <l>k X IO J f3s X Weight (mol kg- I) (011 mo)'l) (cm 3 mol-i bar- I) Cll1 2 dyne- I At C, Al C, ! ! Al C, (Comd)
3 NOTES 753 Table I-Apparent molal volume, (<!>v), apparent molal compressibility, (<!>K), and isentropic compressibility, (~s), 01" polyethylene glycol in water at, and C-Contd <!>vx 10) <!>K X 10.1 ~sx Weight (mol r l) (mlmorl) (cm) mol- I bar- I) cm 2 dyne- 1 At C Q Table 2:-Apparent molal volume at infinite dilution, (<!>vo) and experimental slope, Sv of polyethylene glycol at different temperatures and concentrations T (mol kg- I) <!>VOx 10 2 (ml mor l ) Sv, Table 3-Apparent molal compressibility at infinite dilution, (<!>KO) of polyethylene glycol at different temperatures and concentrations,000 T (0C) Concentration range m m <!>KOX 10) (cm' mol bar- I) III OO53m m I I Q m O.lm m 0.34m Results and discussion In Table 1, values of apparent molal volume (<Pv), apparent molal compressibility (<PK) along with the values of isentropic compressibility (~s) have been recorded for polyethylene glycol in water at, and C. The values of partial molal volume (<Pvo) for the systems under present investigation are presented in Table 2 along with the experimental slope, Sv. The values of partial molar compressibility (<PKO) are recorded in Table 3. The values estimated for interaction coefficient, Q, molar volume of Yand's euqation (V), at 0 e are recorded in Table 4. It is obvious from Table 2, that the values of apparent molal volume at infinite dilution (<Pvo) are gradually decreasing with increase in concentration. It is concluded that, polyethylene glycol is more hydrated
4 754 INDIAN J CHEM, SEC A, APRIL 02 at higher temperatures than at lower temperatures. Thus, both temperature and concentration are responsible for the solute-solvent interaction with respect molecular of solute. On the other hand, Sv values considerably increase with temperature but the trend is not the same in the entire range of concentration. It IS evident from the recorded values, Sv are hi gher at high temperatures, suggesting strong solutesolute interaction. rt is evident from Table 3, that va lues of <PK 0 increase with temperature and decrease Table 5- refraction of polyethylenc glycol- Col/ld (mol kg-i) " Rill, Table 4- The coefficicnt Q and molar volume V of Vand's viscosity equati on at C we ight,000 (mol kg l ) Q V Table 5- refraction of polyethylene glycol,000,000,000 T (0C) (mol kg- I) (Con/d) h J
5 NOTES 755 sharply with increase in concentration. The values of <PKO are highly influenced by the molecular size of solute. In the present investigation, negative values for <PK 0 can be associated wi th structure promoti ng ability of solvent, i.e., loss of structure compressibility of water on account of increase in population of four bonded water molecule. Critical evaluation of physico-chemical data leads the conclusion that there must be reinforcement of water structure in the neighbourhood of alcohol molecule in dilute solution. It is seen from Table 4 that viscosity interaction coefficient, Q, is constant for all ranges of concentration with respect molecular size of solute molecule. It is concluded, therefore, that hydrophobic interactions are mainly dependent on size of polyethylene glycol. The stability of solvent water increase with decrease in molecular size of polyethylene glycol. On the other hand, molar volume, (V) decreases with increase in polyethylene glycol concentration and can be ascribed the decrease in hydrophobic interaction between water dipole and ion of polyethylene glycol with respect molecular size. It is evident from Table 5 that the molar refraction, Rnll values increase with increase in the molecular of polyethylene glycol but is almost constant between the temperature range 10 C and C. Acknowledgement The authors are thankful Prof. J. D. Pandey (Former Head) and Dr Ranjan Dey, Department of Chemistry, University of Allahabad, for valuable suggestions. References I Glew D N & Rath N S, Can J Chem, 45 ( 1970) Frnnk F & Ives, D J G, QU[/I'I Rev Chelll Soc, ( 1966) I. 3 Hioland & Halvik H J, J.wln Ch em, I ( 1878) Cabini S & Cant G, J.1'0/11 Ch elll, 8 ( 1979) II. 5 Vand V, J {lhys Colloid Chem, 52 ( 1948) Moulik, J Indian chelll Soc, 79 (1984) Thompson P T, Fisher B & Wood R N, J.1'0/11 Chelll, II (1982) I. 8 Alexander D M & May DC, AIISI J Chelll, 35 ( 1982) Alexander D M & May DC, AuSI J Ch ell1, 35 ( 198 1) Alexander D M & May DC, AUSI J Chell1, 34 ( 1984) II Islam N & Qudesia Rehana, Indian J Chern, 2 1 A ( 1982) Pandey J D, Puri A K, Tiwari A & Sharma A K, Proc Indiall Acad Sci, III (1999) Pandey J D, Haroon S, Puri A K & Misra K, Indiall J Ch elll, 36A (1997) 393, Pandey J D, Misra K & Mushran V, ACLIslica, 80 ( 1994) Pandey 1 D, Misra K & Mushran V, ACLIslica, 8 1 ( 1994) Pandey J D, Haroon S, Dey R, Upadhyay M & Mi sra K, Call J Chem, 78 (00) Gerecze N G. AClIslica, 38 (1977) 51.
Partial molar properties of homologous dicarboxylic acids in aqueous acetone solutions at different temperatures
Indian Journal of Chemistry Vol. 35A, March 1996, pp. 188-194 Partial molar properties of homologous dicarboxylic acids in aqueous acetone solutions at different temperatures UN Dash & B K Mohantv Department
More informationA study of partial molar volumes of citric acid and tartaric acid in water and binary aqueous mixtures of ethanol at various temperatures
J. Chem. Sci., Vol. 116, No. 1, January 2004, pp. 33 38. Indian Academy of Sciences. A study of partial molar volumes of citric acid and tartaric acid in water and binary aqueous mixtures of ethanol at
More informationPelagia Research Library. Der Chemica Sinica, 2016, 7(4): Kanchan S Hade*
Available online at www.pelagiaresearchlibrary.com Der Chemica Sinica, 2016, 7(4):42-46 ISSN : 0976-8505 CDEN (USA): CSHIA5 Partial Molar Volume, Partial Molar Adiabatic Compressibility and Viscosity Coefficient
More informationAcademic Sciences. International Journal of Chemistry Research
Academic Sciences International Journal of Chemistry Research ISSN- 0976-5689 Vol 3, Issue 1, 2012 Research Article PARTIAL MOLAL VOLUME AND PARTIAL MOLAL ISENTROPIC COMPRESSIBILITY OF L-ISOLEUCINE IN
More informationCHAPTER INTRODUCTION
48 CHAPTER 3 PARTIAL MOLAL VOLUME, PARTIAL MOLAL COMPRESSIBILITY AND VISCOSITY B-COEFFICIENT OF FOUR HOMOLOGOUS -AMINO ACIDS IN AQUEOUS SODIUM FLUORIDE SOLUTIONS AT DIFFERENT TEMPERATURES 3.1 INTRODUCTION
More informationInternational Journal of Pharma and Bio Sciences
Original Research Article Allied science International Journal of Pharma and Bio Sciences ISSN 0975-6299 STUDY OF SOLVATION EFFECT OF AMMONIUM SULPHATE AND AMMONIUM CHLORIDE FERTILIZER SOLUTIONS K.RENUKA
More informationSHORT COMMUNICATION. Ultrasonic Studies of Amino Acids in Aqueous Sucrose Solution at Different Temperatures
Journal of Physical Science, ol. 22(1), 131 141, 211 SHORT COMMUNICATION Ultrasonic Studies of Amino Acids in Aqueous Sucrose Solution at Different Temperatures R. Palani*, S. Balakrishnan and G. Arumugam
More informationJOURNAL OF INTERNATIONAL ACADEMIC RESEARCH FOR MULTIDISCIPLINARY Impact Factor 1.393, ISSN: , Volume 2, Issue 4, May 2014
THERMODYNAMICAL STUDY OF PHLOROGLUCINOL AT DIFFERENT CONCENTRATIONS B.S.SRIKANTH* DR.R.RAMASAMY** DR.S.SEKAR*** *Dept. of Physics, National College, Tiruchy, Tamil Nadu, India **Dept. of Physics, National
More informationApparent molar volume of sodium chloride in mixed solvent at different temperatures
Ultra Chemistry Vol. 8(2), 205-210 (2012). Apparent molar volume of sodium chloride in mixed solvent at different temperatures C.K. RATH 1, N.C. ROUT 2, S.P. DAS 3 and P.K. MISHRA 4 1 Department of Chemistry,
More informationJournal of Chemical and Pharmaceutical Research, 2013, 5(7): Research Article
Available online www.jocpr.com Journal of Chemical and Pharmaceutical Research, 213, 5(7):256-261 Research Article ISSN : 975-7384 CODEN(USA) : JCPRC5 Influence of surfactants on the solute-solvent interactions
More informationApparent Molar Volume and Viscometric Study of Alcohols in Aqueous Solution
in Aqueous Solution SUNIL KUMAR SIKARWAR 1, V. R. CHOUREY 2 3 1 Department of Chemistry, S. C. S. A. Govt. College Jhabua (M. P.), India 2 Department of Chemistry, Holkar Science College Indore (M. P.),
More informationVol. 114 (2008) ACTA PHYSICA POLONICA A No. 6 A
Vol. 114 (2008) ACTA PHYSICA POLONICA A No. 6 A Optical and Acoustical Methods in Science and Technology Effects of Solvation of 2-Methylpyridine and 2,6-Dimethylpyridine in Dilute Solutions in Water and
More informationWarm Up. 1. What causes the high surface tension of water? 2. In the formation of a solution, how does the solvent differ from the solute?
Warm Up 1. What causes the high surface tension of water? 2. In the formation of a solution, how does the solvent differ from the solute? 3. Why are all ionic compounds electrolytes? 4. How do you write
More informationULTRASONIC INVESTIGATIONS IN A LIQUID MIXTURE OF ETHYLENEGLYCOL WITH n-butanol
ULTRASONIC INVESTIGATIONS IN A LIQUID MIXTURE OF ETHYLENEGLYCOL WITH n-butanol *D.NAGENDRA 1, D. RAMACHANDRAN 2 1 Department of Chemistry, RGUKT(APIIIT), Nuzvid. *Corresponding author : nagendrad.che @gmail.com.
More informationEvaluation of apparent and partial molar volume of potassium ferro- and ferricyanides in aqueous alcohol solutions at different temperatures
Indian Journal of Chemical Technology ol. 11, September 4, pp. 714-718 Evaluation of apparent and partial molar volume of potassium ferro- and ferricyanides in aqueous alcohol solutions at different temperatures
More informationULTRASONIC INVESTIGATIONS ON BINARY MIXTURE OF ACETOPHENONE WITH N-BUTANOL AT TEMPERATURES K K
INTERNATIONAL JOURNAL OF RESEARCH IN PHARMACY AND CHEMISTRY Available online at www.ijrpc.com Research Article ULTRASONIC INVESTIGATIONS ON BINARY MIXTURE OF ACETOPHENONE WITH N-BUTANOL AT TEMPERATURES
More informationViscosities of oxalic acid and its salts in water and binary aqueous mixtures of tetrahydrofuran at different temperatures
J. Chem. Sci., Vol. 117, No. 4, July 2005, pp. 351 357. Indian Academy of Sciences. Viscosities of oxalic acid and its salts in water and binary aqueous mixtures of tetrahydrofuran at different temperatures
More informationOverview. Types of Solutions. Intermolecular forces in solution. Concentration terms. Colligative properties. Osmotic Pressure 2 / 46
1 / 46 2 / 46 Overview Types of Solutions. Intermolecular forces in solution Concentration terms Colligative properties Osmotic Pressure 3 / 46 Solutions and Colloids A solution is a homogeneous mixture
More informationChapter 4 Study of solute-solute and solute-solvent interactions of l-histidine in aqueous-sucrose solutions at different temperatures using
Study of solute-solute and solute-solvent interactions of l-histidine in aqueous-sucrose solutions at different temperatures using volumetric, ultrasonic and viscometric methods 4.1. INTRODUCTION The physicochemical
More informationAvailable online Research Article
Available online www.jocpr.com Journal of Chemical and Pharmaceutical Research, 2015, 7(8):987-992 Research Article ISSN : 0975-7384 CODEN(USA) : JCPRC5 Estimation of hydration number and its allied parameters
More informationChem 1515 Section 2 Problem Set #4. Name Spring 1998
Chem 1515 Section 2 Problem Set #4 Name Spring 1998 TA Name Lab Section # ALL work must be shown to receive full credit. Due Wednesday, February 4th PS4.1. Describe all the energy changes which must be
More informationSoluble: A solute that dissolves in a specific solvent. Insoluble: A solute that will not dissolve in a specific solvent. "Like Dissolves Like"
Solutions Homogeneous Mixtures Solutions: Mixtures that contain two or more substances called the solute and the solvent where the solute dissolves in the solvent so the solute and solvent are not distinguishable
More informationResearch Article. Ultrasonic investigation of molecular interaction in aqueous glycerol and aqueous ethylene glycol solution
Available online www.jocpr.com Journal of Chemical and Pharmaceutical Research, 2014, 6(1):714-720 Research Article ISSN : 0975-7384 CODEN(USA) : JCPRC5 Ultrasonic investigation of molecular interaction
More informationComparative Study On Hydration Properties Of Ammonium Sulphate With Potassium Nitrate And Ammonium Sulphate With Sodium Nitrate Solutions At 303k
218 IJEDR Volume 6, Issue 1 ISSN: 2321-9939 Comparative Study On Hydration Properties Of Ammonium Sulphate With Potassium Nitrate And Ammonium Sulphate With Sodium Nitrate Solutions At 33 1 Rathia S, 2
More informationor supersaturatedsaturated Page 1
Solutions Unit #9 Chapter #11 A solution is a HOMOGENEOUS mixture of 2 or more substances in a single phase. One constituent is usually regarded as the SOLVENT and the others as SOLUTES. 1 Definitions
More informationSolvation Studies on Sodium Dodecyl Sulphate in aqueous solutions at different temperatures
IOSR Journal of Applied Physics (IOSR-JAP) e-issn: 2278-4861.Volume 6, Issue 5 Ver. I (Sep.-Oct. 2014), PP 63-67 Solvation Studies on Sodium Dodecyl Sulphate in aqueous solutions at different temperatures
More informationCHEM 1032 PRACTICE EXAM I CLASS SPRING 2017
1 CHEM 1032 PRACTICE EXAM I CLASS SPRING 2017 1. Select the characteristic(s) of the liquid phase: (You may need a periodic table. Useful information appears on page 5.) (i) adopts the shape of the container
More informationUltrasonic velocity and viscosity studies of tramacip and parvodex in binary mixtures of alcohol + water
Indian Journal of Pure & Applied Physics Vol. 46, December 2008, pp. 839-843 Ultrasonic velocity and viscosity studies of tramacip and parvodex in binary mixtures of alcohol + water Poonam Sharma*, S Chauhan,
More informationSalinity Gradients for Sustainable Energy: Primer, Progress, and Prospects
Supporting Information Salinity Gradients for Sustainable Energy: Primer, Progress, and Prospects Ngai Yin Yip *,, Doriano Brogioli, Hubertus V. M. Hamelers, and Kitty Nijmeijer Department of Earth and
More informationMOLECULAR INTERACTION STUDIES OF GLYCYLGLYCINE IN AQUEOUS SODIUM HALIDE SOLUTIONS AT 303, 308 AND 313K
OL. 5, NO. 12, DECEMBER 21 ISSN 1819-668 26-21 Asian Research Publishing Network (ARPN). All rights reserved. MOLECULAR INTERACTION STUDIES OF GLYCYLGLYCINE IN AQUEOUS SODIUM HALIDE SOLUTIONS AT 33, 38
More informationSpeeds of sound and isothermal compressibility of ternary liquid systems: Application of Flory s statistical theory and hard sphere models
PRAMANA c Indian Academy of Sciences Vol. 70, No. 4 journal of April 2008 physics pp. 731 738 Speeds of sound and isothermal compressibility of ternary liquid systems: Application of Flory s statistical
More informationUltrasonic studies of aqueous solutions of poly diallyl dimethyl ammonium chloride
Indian Journal of Pure & Applied Physics Vol. 42, October 2004, pp. 735-740 Ultrasonic studies of aqueous solutions of poly diallyl dimethyl ammonium chloride V Seetharaman, S Kalyanasundaram & A Gopalan*
More informationLIMITING IONIC PARTIAL MOLAR VOLUMES OF R 4 N + AND I IN AQUEOUS METHANOL AT K
Int. J. Chem. Sci.: 11(1), 2013, 321-330 ISSN 0972-768X www.sadgurupublications.com LIMITING IONIC PARTIAL MOLAR VOLUMES OF R 4 N + AND I IN AQUEOUS METHANOL AT 298.15 K N. P. NIKAM * and S. V. PATIL a
More informationThermodynamic and Viscometric Study of Calix (6) Arene and their Derivatives
Research Journal of Chemical Thermodynamic and Viscometric Study of Calix (6) Arene and their Derivatives Abstract Sciences E-ISSN 2231-606X Rakhi R. Kale and Yogita S. Thakare* Department of Chemistry,
More informationULTRASONIC AND MOLECULAR INTERACTION STUDIES OF CINNAMALDEHYDE WITH ACETONE IN n-hexane
ISSN: 0974-1496 e-issn: 0976-0083 CODEN: RJCABP http://www.rasayanjournal.com http://www.rasayanjournal.co.in ULTRASONIC AND OLECULAR INTERACTION STUDIES OF CINNAALDEHYDE WITH ACETONE IN n-hexane C. Senthamil
More informationPelagia Research Library
Available online at www.pelagiaresearchlibrary.com Der Chemica Sinica, 01, 3(4):948-95 ISSN: 0976-8505 CODEN (USA) CSHIA5 Apparent molar volume and viscometric study of carbohydrate in aqueous solution
More informationResearch Article. Volumetric study of strong electrolytes-metal chlorides and metal sulphates in aqueous medium at different temperatures
Available online www.jocpr.com Journal of Chemical and Pharmaceutical Research, 215, 7(7):14-144 Research Article ISSN : 975-7384 CODEN(USA) : JCPRC5 Volumetric study of strong electrolytes-metal chlorides
More informationMolecular Interactions in Binary Mixture of Sucrose in Aqueous NaCl Solution
International Journal of Scientific and Research Publications, Volume 4, Issue 8, August 2014 1 Molecular Interactions in Binary Mixture of Sucrose in Aqueous NaCl Solution Sunil Kumar Singh and Subhash
More informationThermodynamic and Interactions studies of D(+) Fructose with aqueous alkali metals halides at different molalities and constant temperature
International Journal of Science, Technology and Society 2015; 3(1-2): 1-5 Published online November 21, 2014 (http://www.sciencepublishinggroup.com/j/ijsts) doi: 10.11648/j.ijsts.s.2015030102.11 ISSN:
More informationSITARAM K. CHAVAN * and MADHURI N. HEMADE ABSTRACT INTRODUCTION
Int. J. Chem. Sci.: 11(1), 013, 619-67 ISSN 097-768X www.sadgurupublications.com DENSITIES, VISCOSITIES AND EXCESS THERMODYNAMIC PROPERTIES OF MONOMETHYL AMMONIUM CHLORIDE IN TETRAHYDROFURAN AND WATER
More informationStudy of molecular interactions between L-aspartic acid and aqueous 1,2-propanediol solution at T = K
Study of molecular interactions between L-aspartic acid and aqueous 1,2-propanediol solution at T = 303.15 K Ruby Rani, Ashwani Kumar, Tanu Sharma, and Rajinder K. Bamezai* Department of Chemistry, University
More informationIC1001 Kick-Off Meeting - 1
IC1001 Kick-Off Meeting - 1 DENSITY STUDIES ON ION-ION AND ION-SOLVENT INTERACTIONS OF AQUEOUS SOLUTIONS OF IMIDAZOLIUM CHLORIDE IONIC LIQUIDS [MIm][Cl] AND [BMIm][Cl] AT DIFFERENT TEMPERATURES Associate
More informationINTERNATIONAL JOURNAL OF PHARMACEUTICAL RESEARCH AND BIO-SCIENCE
INTERNATIONAL JOURNAL OF PHARMACEUTICAL RESEARCH AND BIO-SCIENCE STUDY OF ION SOLVENT INTERACTION OF GLUCOSE IN WATER-METHANOL AND ETHANOL- ULTRASONICALLY VERMA RC 1, SINGH AP 1, GUPTA J 2, GUPTA R 2 1.
More informationStudy of Structure Making/Breaking Properties of Glucose, Fructose, Sucrose and Maltose in Aqueous KCl at Various Temperatures
Chem Sci Trans., 2013, 2(2), 485-490 Chemical Science Transactions DOI:10.7598/cst2013.421 ISSN/E-ISSN: 2278-3458/2278-3318 RESERCH RTICLE Study of Structure Making/Breaking Properties of Glucose, Fructose,
More informationCHAPTER -VIII. Ion-Solvent Interactions of Sodium Molybdate in Oxalic acid-water Systems at Various Temperatures.
CHAPTER -III Ion-Solvent Interactions of Sodium Molybdate in Oxalic acid-water Systems at arious Temperatures. 8.. Introduction iscometric, volumetric and acoustic studies of solute in case of aqueous
More informationLECTURE 6 NON ELECTROLYTE SOLUTION
LECTURE 6 NON ELECTROLYTE SOLUTION Ch 45.5 pplied Phy Chem First Sem 2014-15 Ch 45.5 Exam II September 1/3 (Multiple Choice/Problem Solving) Coverage: Second/Third Laws of Thermodynamics Nonelectrolyte
More informationSOLUTION CONCENTRATIONS
SOLUTION CONCENTRATIONS The amount of solute in a solution (concentration) is an important property of the solution. A dilute solution contains small quantities of solute relative to the solvent, while
More informationUltrasonic Behaviour of Binary Mixtures Containing Stearates and Acetone
Ultrasonic Behaviour of Binary Mixtures Containing Stearates and Acetone 1 r. Kavitha, 2 s. Jayakumar, 3 r. Uma 1,3. Research scholar, Department of Chemistry, Pachaiyappa s College, Chennai 30. 2. Assoc
More informationAcoustic Studies on Different Binary Liquid Mixtures of LIX Reagents with Different Diluents
Journal of the Korean Chemical Society Printed in the Republic of Korea http://dx.doi.org/10.5012/jkcs.2012.56.5.548 Acoustic Studies on Different Binary Liquid Mixtures of LIX Reagents with Different
More informationSupporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 214 Supporting Information Theory: The physical properties of inary mixtures in different mass fractions
More informationPartial molar volumes and viscosities of some monovalent ions in ethanolamine and water--ethanolamine mixtures at K
Indian Journal of Chemistry Vol. 39A, June 2000, pp. 598-602 Partial molar volumes and viscosities of some monovalent ions in ethanolamine and water--ethanolamine mixtures at 298.15 K (Late) R K Wadi,
More informationProperties of Solutions. Chapter 13
Properties of Solutions Chapter 13 Sodium acetate crystals rapidly form when a seed crystal is added to a supersaturated solution of sodium acetate. Saturated solution: contains the maximum amount of a
More informationProperties of Aqueous Solutions
Properties of Aqueous Solutions Definitions A solution is a homogeneous mixture of two or more substances. The substance present in smaller amount is called the solute. The substance present in larger
More informationUltrasonic Studies on Molecular Interaction of Arginine in Aqueous Disaccharides at K
International Journal of ChemTech Research CODEN( USA: IJCRGG ISSN : 974-429 ol. 3, No.1, pp 284-289, Jan-Mar 211 Ultrasonic Studies on Molecular Interaction of Arginine in Aqueous Disaccharides at 298.15
More informationDip Singh Gil1* & Vazid Ali. Department of Chemistry, Panjab University, Chandigarh , India. Received 15 October 1998; revised 22 Febmary 1999
Indian Journal of Chemistry Vol. 38A, July 999, pp.65-655 Behaviour of bovine serum albumin in aqueous solutions of some sodium salts of organic acids, tetraethylammonium bromide and dextrose investigated
More informationInternational Journal of Applied Research 2016; 2(4): Keywords: PFP theory,binary mixture,dipropyleneglycolmonobutyl.
16; (4): 39-396 ISSN Print: 394-75 ISSN Online: 394-5869 Impact Factor: 5. IJAR 16; (4): 39-396 www.allresearchjournal.com Received: 16--16 Accepted: 19-3-16 Gurcharan Dass Director-Principal, Bharat Group
More informationUltrasonic studies of molecular interactions in binary mixtures of n-butanol with water at different temperatures (308K, 318K and 328K)
Journal of Advanced Applied Scientific Research - ISSN:2454-3225 Umaralikhan.L et.al JOAASR-Vol-1-1-May-2015:27-32 ISSN:2454-3225 Ultrasonic studies of molecular interactions in binary mixtures of n-butanol
More informationMolecular Interaction Studies with Zinc Stearate, Calcium Stearate and Ethylene Glycol
Molecular Interaction Studies with Zinc Stearate, Calcium Stearate and Ethylene Glycol C. Ravichandran 1, R. Kavitha 1, S. Jayakumar 2, R. Anusa 1 Department of Chemistry, Easwari Engineering College,
More informationCHAPTER 12 REVIEW. Solutions. Answer the following questions in the space provided. b. sea water. c. water-absorbing super gels
CHAPTER 12 REVIEW Solutions SECTION 1 SHORT ANSWER Answer the following questions in the space provided. 1. Match the type of mixture on the left to its representative particle diameter on the right. c
More informationTHE STUDY OF MOLECULAR INTERACTIONS IN STABILIZERS AND PLASTICIZER THROUGH ULTRASONIC MEASUREMENTS
27 THE STUDY OF MOLECULAR INTERACTIONS IN STABILIZERS AND PLASTICIZER THROUGH ULTRASONIC MEASUREMENTS 1 R. KAVITHA, 2 S. JAYAKUMAR, 3 R. UMA 1 Department of Chemistry, Easwari Engineering College, Chennai
More informationULTRASONIC AND CONDUCTOMETRIC STUDIES OF NACL SOLUTIONS THROUGH ULTRASONIC PARAMETERS
International Journal of Recent Innovation in Engineering and Research Scientific Journal Impact Factor - 3.605 by SJIF e- ISSN: 2456 2084 ULTRASONIC AND CONDUCTOMETRIC STUDIES OF NACL SOLUTIONS THROUGH
More informationPelagia Research Library
Available online at www.pelagiaresearchlibrary.com Der Pharmacia Sinica, 2011, 2 (5): 259-266 ISSN: 0976-8688 CODEN (USA): PSHIBD Studies in Partial Molar Volumes, Partial Molar Compressibilities and Viscosity
More informationOFB Chapter 6 Condensed Phases and Phase Transitions
OFB Chapter 6 Condensed Phases and Phase Transitions 6-1 Intermolecular Forces: Why Condensed Phases Exist 6- The Kinetic Theory of Liquids and Solids 6-3 Phase Equilibrium 6-4 Phase Transitions 6-5 Phase
More informationSubject : Chemistry Class : XII Chapter-2.Solutions Work Sheet ( WS 2. 1) Topic- 2.1 Henry s & Raoult s Laws
Work Sheet ( WS 2. 1) Topic- 2.1 Henry s & Raoult s Laws Name -. Class/ sec.. Roll No.. A. Fill in the blanks: 1. Solutions are mixtures of two or more than two components. 2. Generally, the component
More informationCHEMISTRY 110 EXAM 3 April 2, 2012 FORM A 1. Which plot depicts the correct relationship between the volume and number of moles of an ideal gas at constant pressure and temperature? 2. The height of the
More informationCHAPTER 6 THERMODYNAMIC AND TRANSPORT PROPERTIES OF GLYCINE IN AQUEOUS SOLUTIONS OF SODIUM CARBONATE AT DIFFERENT TEMPERATURES
198 CHAPTER 6 THERMODYNAMIC AND TRANSPORT PROPERTIES OF GLYCINE IN AQUEOUS SOLUTIONS OF SODIUM CARBONATE AT DIFFERENT TEMPERATURES 6.1 INTRODUCTION The characterization of thermodynamical properties of
More informationChapter 12. Properties of Solutions
Chapter 12. Properties of Solutions What we will learn: Types of solutions Solution process Interactions in solution Types of concentration Concentration units Solubility and temperature Solubility and
More informationUltrasonic Velocities of Acrylates with 2-Hexanol
Ultrasonic Velocities of Acrylates with 2-Hexanol SUJATA S. PATIL Dept. of App. Sci., MSS s College of Engineering and Technology, Jalna 431 203 (M. S.), India. E-mail: patil.sujata.1986@gmail.com Abstract
More informationChapter 12 & 13 Test Review. Bond, Ionic Bond
Chapter 12 & 13 Test Review A solid solute dissolved in a solid solvent is an Alloy What is happening in a solution at equilibrium? The Ionic rate of Bond dissolving is equal to the rate of crystallization.
More informationJournal of Chemical and Pharmaceutical Research
Available online www.jocpr.com Journal of Chemical and Pharmaceutical Research ISSN No: 0975-7384 CODEN(USA): JCPRC5 J. Chem. Pharm. Res., 2011, 3(5):348-358 Ultrasonic study of molecular dynamics in some
More informationThermodynamic Study of Copper Sulphate and Zinc Sulphate in Water and Binary Aqueous Mixtures of Propylene Glycol
ORIENTAL JOURNAL OF CHEMISTRY An International Open Free Access, Peer Reviewed Research Journal www.orientjchem.org ISSN: 97-2 X CODEN: OJCHEG 215, Vol. 31, No. (1): Pg. 363-369 Thermodynamic Study of
More information/15. Chem 202 Name KEY Exam 1 January 30, (3 pts total, 15 pts each) circle the best answer
Chem 202 KEY Exam 1 January 30, 2006 1. (3 pts total, 15 pts each) circle the best answer Which of the following is (are) true? a. Charles Law assume V and T are constant b. Boyles law assumes P and V
More informationApparent Molar Volume and Viscometric Study of Ammonium Sulphate in 10% DMF - Water at Temperature and K
Available online at www.scholarsresearchlibrary.com Scholars Research Library Der Pharmacia Lettre, 2017, 9 [11]: 16-21 [http://scholarsresearchlibrary.com/archive.html] ISSN 0975-5071 USA CODEN: DPLEB4
More information1) Define the following terms: a) solution, b) miscible, c) hydration, d) percent by mass (solute), e) colligative property, f) hypotonic.
Problems - Chapter 13 (with solutions) 1) Define the following terms: a) solution, b) miscible, c) hydration, d) percent by mass (solute), e) colligative property, f) hypotonic. a) solution - A homogeneous
More informationInterrelationship between Surface Tension and Sound Velocity & Thermodynamical studies of binary liquid mixtures
Available online at http://www.urpjournals.com International Journal of Research in Pure and Applied Physics Universal Research Publications. All rights reserved ISSN 2278-134X Original Article Interrelationship
More informationChapter Solutions. MockTime.com. (a) M urea (b) 0.01 M KNO3 (c) 0.01 M Na2 SO4 (d) M glucose Ans: (c)
47 Chapter Solutions 1. Freezing point of an aqueous solution is ( 0.186) C. Elevation of boiling point of the same solution is K b = 0.512 C,Kf = 1.86 C, find the increase in boiling point. [2002] (a)
More informationAmerican Journal of Energy Science 2015; 2(4): Published online June 10, 2015 (http://www.openscienceonline.com/journal/energy)
American Journal of Energy Science 2015; 2(4): 108-114 Published online June 10, 2015 (http://www.openscienceonline.com/journal/energy) Thermodynamic and Interactions Studies of Serine with Aqueous Sodium
More informationChapter 17 - Properties of Solutions
Chapter 17 - Properties of Solutions 17.1 Solution Composition 17.2 Thermodynamics of Solution Formation 17.3 Factors Affecting Solubility 17.4 Vapor Pressures of Solutions 17.5 Boiling-Point Elevation
More informationLecture outline: Chapter 13
Lecture outline: Chapter 13 Properties of solutions Why solutions form at the molecular l levell Units of solution concentration Colligative properties: effects of solutes on BP, MP, and vapor pressure
More informationChapter 11 Review Packet
Chapter 11 Review Packet Name Multiple Choice Portion: 1. Which of the following terms is not a quantitative description of a solution? a. molarity b. molality c. mole fraction d. supersaturation 2. Which
More informationInt. J. Pharm. Sci. Rev. Res., 35(1), November December 2015; Article No. 07, Pages: 25-29
ISSN 976 44X Research Article Volumetric and Viscometric Studies on Aqueous Ibuprofen Solutions at Temperatures Sulochana Singh*, Upendra Nath Dash Department Of Chemistry, I.T.E.R, Siksha O Anusandhana
More informationUltrasonic Studies of Some Biomolecules in Aqueous Guanidine Hydrochloride Solutions at K
ISSN: 973-4945; CODEN ECJHAO E- Chemistry http://www.e-journals.net 211, 8(3), 1146-1151 Ultrasonic Studies of Some Biomolecules in Aqueous Guanidine Hydrochloride Solutions at 298.15 R. PALANI *, A. GEETHA
More informationUltrasonic Velocity Determination in Binary Liquid Mixtures
J. Pure Appl. & Ind. Phys. Vol.1 (4), 252-258 (2011) Ultrasonic Determination in Binary Liquid Mixtures R. NATARAJAN* and P. RAMESH *Department of Physics, A. M. Jain College, Meenambakkam, Chennai 600114,
More informationCHEM-102 EXAM I Name Fall 2004 Section
CHEM-102 EXAM I Name Fall 2004 Section 10 11 12 Version A (Circle one) Instructions: 1. Put your name and section number on both page 1 and the answer key. Do not detach the answer key from the back of
More informationUniform properties throughout! SOLUTE(S) - component(s) of a solution present in small amounts.
54 SOLUTIONS - a SOLUTION is a HOMOGENEOUS MIXTURE. Uniform properties throughout! - parts of a solution: SOLUTE(S) - component(s) of a solution present in small amounts. SOLVENT - the component of a solution
More informationSY 2017/ nd Final Term Revision. Student s Name: Grade: 10 B & C. Subject: CHEMISTRY. Teacher Signature
SY 2017/2018 2 nd Final Term Revision Student s Name: Grade: 10 B & C Subject: CHEMISTRY Teacher Signature 1- Complete. a-avogadros law b-henrys law REVISION SHEET CHEMISTRY GR-10B 2-What is the difference
More informationSolution Concentration. Solute Solvent Concentration Molarity Molality ph
Solution Concentration Solute Solvent Concentration Molarity Molality ph http://en.wikipedia.org/wiki/homogeneou Lets Review Mixture: A mixture is a chemical substance which is a homogeneous or heterogeneous
More informationDirect acoustic impedance measurements of dimethyl sulphoxide with benzene, carbon tetrachloride and methanol liquid mixtures
Indian Journal of Pure & Applied Physics Vol. 48, January 2010, pp. 31-35 Direct acoustic measurements of dimethyl sulphoxide with benzene, carbon tetrachloride and methanol liquid mixtures Deepa Bhatnagar,
More informationMolecular Interaction Study of Binary Solutions of n-butyl Acetate and Isopropanol at Various Temperatures
Research Inventy: International Journal of Engineering And Science Vol.8, Issue 2 (May 2018), PP -54-59 Issn (e): 2278-4721, Issn (p):2319-6483, www.researchinventy.com Molecular Interaction Study of Binary
More information1) Define the following terms: a) solution, b) miscible, c) hydration, d) percent by mass (solute), e) colligative property, f) hypotonic.
Problems - Chapter 13 (with solutions) 1) Define the following terms: a) solution, b) miscible, c) hydration, d) percent by mass (solute), e) colligative property, f) hypotonic. a) solution - A homogeneous
More informationMixtures. Partial Molar Quantities
CHEM 331 Physical Chemistry Fall 2017 Mixtures Our current discussion takes up some general results for systems that are mixtures and/or open. The former involve systems that contain multiple components;
More informationJournal of Chemical and Pharmaceutical Research, 2012, 4(3): Research Article
Available online www.jocpr.com Journal of Chemical and Pharmaceutical Research, 2012, 4(3):1619-1624 Research Article ISSN : 0975-7384 CODEN(USA) : JCPRC5 Studies on ion association and solvation of multi-charged
More informationDensity, Viscosity and Refractive Index Studies of Metformin HCl in Aqueous System at K.
IOSR Journal of Engineering (IOSRJEN) ISSN (e): 2250-3021, ISSN (p): 2278-8719 Vol. 06, Issue 09 (Sep 2016), V1 PP 25-29 www.iosrjen.org Density, Viscosity and Refractive Index Studies of Metformin HCl
More information8. Relax and do well.
EM 1515.001-006 Exam II John II. Gelder March 5, 2002 Name TA's Name Section INSTRUTIONS: 1. This examination consists of a total of 8 different pages. The last three pages include a periodic table, a
More informationUniform properties throughout! SOLUTE(S) - component(s) of a solution present in small amounts.
52 SOLUTIONS - a SOLUTION is a HOMOGENEOUS MIXTURE. Uniform properties throughout! - parts of a solution: SOLUTE(S) - component(s) of a solution present in small amounts. SOLVENT - the component of a solution
More informationScholars Research Library
Available online at www.scholarsresearchlibrary.com Archives of Physics Research, 213, 4 (2):13-111 (http://scholarsresearchlibrary.com/archive.html) ISSN : 976-9 CODEN (USA): APRRC7 Adiabatic compressibility
More informationChapter 13 Properties of Solutions
Chapter 13 Properties of Solutions Learning goals and key skills: Describe how enthalpy and entropy changes affect solution formation. Describe the relationship between intermolecular forces and solubility,
More informationPelagia Research Library
Available online at www.pelagiaresearchlibrary.com Der Chemica Sinica, 2012, 3(6):1438-1443 Molecular interactions by ultrasonic velocity, viscosity and density measurements in binary mixtures at 298.15
More informationIJBPAS, September, 2012, 1(8): MOLECULAR INTERACTION STUDIES ON SOME BINARY ORGANIC LIQUID MIXTURES AT 303K SUMATHI T* AND GOVINDARAJAN S
: 1153-1165 ISSN: 2277 4998 MOLECULAR INTERACTION STUDIES ON SOME BINARY ORGANIC LIQUID MIXTURES AT 33K SUMATHI T* AND GOVINDARAJAN S *Department of Physics, Annamalai University, Annamalai Nagar, Tamil
More information